Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Blake excursion was among the first recognized with directional and intensity behavior known mainly from marine sediment and Chinese loess. Age estimates for the directional shifts in sediments are poorly constrained to about 118−100 ka, i.e., at the marine isotope stage (MIS) 5e/5d boundary. Moreover, sediments at Lac du Bouchet maar, France and along the Portuguese margin reveal what may be a "post-Blake" excursion at about 105−95 ka. The excursional directions are associated with a prominent paleointensity minimum between about 125 and 95 ka in global stacked records. Lava flow recordings of the Blake excursion(s) have, however, been questionable because precise ages required for correlation with these sediment records are lacking. To establish new, independent records of the Blake excursion, and link these into a larger Quaternary GITS, we have undertaken 40Ar/39Ar incremental heating and unspiked K-Ar experiments on groundmass from the transitionally magnetized Inzolfato flow on Lipari Island. We also obtained 40Ar/39Ar incremental heating results for a lava flow on Amsterdam Island originally thought to record the Mono Lake excursion and from the transitionally magnetized El Calderon basalt flow, New Mexico that was K-Ar dated by Champion et al. (1988) at 128 ± 66 ka. Unspiked K-Ar ages of four samples from the Inzolfato flow are 102.5 ± 4.7, 101.3 ± 3.3, 97.1 ± 2.6, and 96.8 ± 3.1 ka and thus indistinguishable from one another. 40Ar/39Ar results are more complex, with three samples yielding discordant age spectra. Based on incremental heating data obtained in both the UW-Madison and Gif-sur-Yvette 40Ar/39Ar laboratories, a fourth sample yields six concordant age plateaus and a weighted mean age of 105.2 ± 1.4 ka that we take as the best estimate of time since the flow erupted. Five 40Ar/39Ar incremental heating experiments on the Amsterdam Island lava yield a plateau age of 120 ± 12 ka, whereas ages from two sites in the Calderon flow are 112 ± 23 and 101 ± 14 ka, together giving a weighted mean of 104 ± 12 ka. The age of 120 ± 12 ka from Amsterdam Island, though imprecise, correlates with the Blake excursion. In contrast, the 104-105 ka age obtained from both Lipari and New Mexico indicates that these lavas record a younger period of dynamo instability, most probably associated with the post-Blake excursion. These radioisotopic ages are consistent with the astronomical ages of two paleointensity minima in the PISO-1500 global stack. Our findings indicate that the Blake and post-Blake excursions are both global features of past geodynamo behavior and support the hypothesis that Brunhes chron excursions are temporally clustered into two groups of at least a half-dozen each spanning over 220 to 30 ka and 720 to 520 ka.
ISSN: 1871-1014

hal-01054336
https://hal.archives-ouvertes.fr/hal-01054336
DOI : 10.1016/j.quageo.2012.12.005

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Deformation of the continental lithosphere is traditionally modeled assuming that heat production in the subcontinental lithospheric mantle is negligible. Although this may be appropriate for highly depleted Archean lithosphere, studies of mantle xenoliths and lithospheric-derived mafic rocks suggest that heat productions of up to 0.4 ;μW/m3 may be attained in the mantle of Phanerozoic and Neoproterozoic regions due to modal metasomatism. To investigate the effect of a local enrichment in heat-producing elements within the lithospheric mantle on the continental deformation, we performed a series of 2D thermo-mechanical models simulating the deformation of a lithospheric plate 1000 km long, which contains in its central part a 200 km wide and 20 km-thick mantle layer with a heat production of 0.05;–0.25 ;μW/m3 between 40 and 80 km depth, leading to a local enhancement of the surface heat flow by 1;–5 mW/m2. Compression models show that a 20 km-thick layer with a heat production as low as 0.05 ;μW/m3 within the shallow lithospheric mantle leads to strain localization in both the enriched mantle and the overlying crust. Strain localization depends exponentially on the temperature increase in the lithosphere section, which is controlled by the volume of metasomatized mantle and the intensity of the metasomatic enrichment in heat-producing elements. A heat production of 0.25 μW/m3 between 60 and 80 km depth results, for instance, in strains within and above the metasomatized mantle 5 times higher than in the surrounding lithosphere. Strain localization also depends on the location of the heat-producing domain and on the plate rheological structure; deeper heat-producing domains and weaker plates leading to stronger localization. These results provide an explanation for strain localization in intraplate environments, leading to the formation of orogenic belts situated hundreds to thousands of kilometers away from known plate boundaries, as observed in the Neoproterozoic belts of Gondwana and in the present-day deformation of the Asian plate.
ISSN: 0012-821X

hal-00411386
https://hal.archives-ouvertes.fr/hal-00411386
DOI : 10.1016/j.epsl.2008.07.040

Éditeur(s) : HAL CCSD Elsevier Masson
Résumé : Normal faulting mechanisms observed in the northern foothills of the Central–Western Pyrenees are remarkable, since one expects thrust faults at a convergent plate boundary. To understand the mechanisms involved, we used numerical modeling and investigated the impact of the following processes: gravitational potential energy associated with topography and dense crustal blocks; isostatic compensation in response to denudation and/or sedimentation. To decipher the effects of each process, we designed three model geometries and added a pre-existing weak fault where most of the seismicity occurs. To evaluate our model results, we derived the fault slip rate from the focal mechanisms in the region where we have the fault in our model. We found a slip rate of ∼15 m/Ma, which is in agreement with our modelling results. We conclude that flexural rebound induced by surface processes is able to explain the seismicity in Central–Western Pyrenees.
ISSN: 1631-0713

hal-01346028
https://hal.archives-ouvertes.fr/hal-01346028
https://hal.archives-ouvertes.fr/hal-01346028/document
https://hal.archives-ouvertes.fr/hal-01346028/file/Genti.pdf
DOI : 10.1016/j.crte.2015.08.004

Éditeur(s) : HAL CCSD
Résumé : High Pressure - Low Temperature (HP-LT) rocks testify for burying and exhumation of crustal material in subduction zones. Their complete exhumation is the result of processes acting during (syn-orogenic) and after (post-orogenic) subduction is active, the latter partly obliterating the first. In the Aegean domain, the Attic-Cycladic Blueschist unit (ACBU) is a HP-LT unit exhumed in metamorphic core complexes (MCCs) in the back-arc domain of the Hellenic subduction zone. This study is an attempt to distinguish features related to syn-orogenic exhumation processes responsible for the first stages of exhumation This syn-orogenic "message" has to be read through the post-convergence structural and thermal overprint that accompanied the formation of the MCCs. Particularly, the geometry, the timing and the amount of the syn-orogenic exhumation has to be determined. We investigate these features with coupled field, metamorphic petrology and radiochronology studies First, based on observations on Ios (southern Cyclades), it has recently been proposed that syn-orogenic exhumation of the ACBU was accommodated by a basal thrust over the Cycladic Basement (CB) [Huet, et al., 2009]. The peak conditions, deduced from pseudosections calculation for the Ios main lithologies, are 500 °C-19 kbar for the ACBU and 550 °C-16 kbar for the CB. Exhumation until 400 °C-8 kbar is considered as syn-orogenic. Second, phengites populations, single grains and in situ 40Ar-39Ar geochronology has been carried out on samples from Tinos and Andros (northern Cyclades), Syros (central Cyclades) and Ios. The results gather in several clusters: 50-55 Ma, 40-45 Ma, 30-35 Ma, and 22-26 Ma. Based on these new P-T-t data and a synthesis of published data, we are able to refine the geometry and the timing of the exhumation of the ACBU. Data from the whole Cyclades exhibit little differences in ages and P-T conditions for the successive stages of exhumation. The peak of pressure (500±50 °C-18±1 kbar) has been reached at 50-55 Ma from Tinos to Ios. The onset of the exhumation occurred at 40-45 Ma in blueschist facies conditions, between a thrust at their bottom and a detachment at their top. The following decompression was accompanied by cooling until 30-35 Ma (400±50 °C-8±1 kbar). At that time, the boundary conditions switched to extension. Finally, we propose a model for the exhumation of HP-LT units accounting for these data. We also consider the rheological implications of the syn-orogenic structuration of the Aegean wedge on the post-orogenic evolution. B. Huet, L. Labrousse, and L. Jolivet [2009] Thrust or detachment? Exhumation processes in the Aegean: Insight from a field study on Ios (Cyclades, Greece), Tectonics, 28, 3, doi:10.1029/2008TC002397.
EGU General Assembly
Vienne, Austria

insu-00839054
https://hal-insu.archives-ouvertes.fr/insu-00839054
BIBCODE : 2010EGUGA..1214098H

Éditeur(s) : Pergamon-elsevier Science Ltd
Résumé : The south-west lagoon of New Caledonia is a wide semi-open coral reef lagoon bounded by an intertidal barrier reef and bisected by numerous deep inlets. This paper synthesizes findings from the 2000-2008 French National Program EC2CO-PNEC relative to the circulation and the transport of suspended particles in this lagoon. Numerical model development (hydrodynamic, fine suspended sediment transport, wind-wave, small-scale atmospheric circulation) allowed the determination of circulation patterns in the lagoon and the charting of residence time, the later of which has been recently used in a series of ecological studies. Topical studies based on field measurements permitted the parameterisation of wave set-up induced by the swell breaking on the reef barrier and the validation of a wind-wave model in a fetch-limited environment. The analysis of spatial and temporal variability of suspended matter concentration over short and long time-scales, the measurement of grain size distribution and the density of suspended matter (1.27 kg 1(-1)), and the estimation of erodibility of heterogeneous (sand/mud, terrigenous/biogenic) soft bottoms was also conducted. Aggregates were shown to be more abundant near or around reefs and a possible biological influence on this aggregation is discussed. Optical measurements enabled the quantification of suspended matter either in situ (monochromatic measurements) or remotely (surface spectral measurements and satellite observations) and provided indirect calibration and validation of a suspended sediment transport model. The processes that warrant further investigation in order to improve our knowledge of circulation and suspended sediment transport in the New Caledonia lagoon as well as in other coral reef areas are discussed, as are the relevance and reliability of the numerical models for this endeavour.
Marine Pollution Bulletin (0025-326X) (Pergamon-elsevier Science Ltd), 2010 , Vol. 61 , N. 7-12 , P. 269-296

Droits : 2010 Elsevier Ltd All rights reserved.
http://archimer.ifremer.fr/doc/00014/12526/9401.pdf
DOI:10.1016/j.marpolbul.2010.06.023
http://archimer.ifremer.fr/doc/00014/12526/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The lithospheric mantle is intrinsically heterogeneous and anisotropic. These two properties govern the repartition of deformation, controlling intraplate strain localization and development of new plate boundaries. Geophysical and geological observations provide clues on the types, ranges, and characteristic length scales of heterogeneity and anisotropy in the lithospheric mantle. Seismic tomography points to variations in geothermal gradient and hence in rheological behavior at scales of hundreds of km. Seismic anisotropy data substantiate anisotropic physical properties consistent at scales of tens to hundreds of km. Receiver functions imply lateral and vertical heterogeneity at scales < 10 km, which might record gradients in composition or anisotropy. Observations on naturally deformed peridotites establish that compositional heterogeneity and Crystal Preferred Orientations (CPOs) are ubiquitous from the mm to the km scales. These data allow discussing the processes that produce/destroy heterogeneity and anisotropy and constraining the time scales over which they are active. This analysis highlights: (i) the role of deformation and reactive percolation of melts and fluids in producing compositional and structural heterogeneity and the feedbacks between these processes, (ii) the weak mechanical effect of mineralogical variations, and (iii) the low volumes of fine-grained microstructures and difficulty to preserve them. In contrast, olivine CPO and the resulting anisotropy of mechanical and thermal properties are only modified by deformation. Based on this analysis, we propose that strain localization at the plate scale is, at first order, controlled by large-scale variations in thermal structure and in CPO-induced anisotropy. In cold parts of the lithospheric mantle , grain size reduction may contribute to strain localization, but the low volume of fine-grained domains limits this effect.
ISSN: 0040-1951

hal-01277174
https://hal.archives-ouvertes.fr/hal-01277174
DOI : 10.1016/j.tecto.2015.07.026

Résumé : Ce travail est l'expression d'une volonté de chercheurs, de la Carabe d'améliorer les connaissances scientifiques méso- et micro-météorologiques appliquées aux milieux insulaires sous influence des alizés et de développer la recherche dans ces domaines.On sait que le phénomène météorologique le plus remarquable impactant les îles de la Caraïbe reste le cyclone tropical. Mais d'autres phénomènes, a des échelles inferieures, telles que les pluies intenses, les houles, la dégradation de la qualité de l'air ont une importance aigüe en termes de risques naturels ou de risques sur la sante. Ces exemples attestent la nécessité d'utiliser des méthodes de descente d'échelle pour exploiter l'information météorologique et/ou climatique de grande échelle et dériver des scenarios locaux et régionaux appliques aux territoires insulaires. Ce défi est important car l'attente d'analyses scientifiques pertinentes dans ces domaines est grande.Les travaux présentés dans ce mémoire ont pour principaux objectifs la simulation numérique puis l'analyse des mécanismes méso- et micro-échelles qui induisent des circulations locales diurnes et nocturnes sur l'archipel de la Guadeloupe à l'aide de codes numériques météorologiques éprouves car largement utilises en recherche et en prévision opérationnelle.Ils constituent donc la première étude de modélisation numérique à haute résolution en basse atmosphère, par descente d'échelle dynamique, pour des intervalles d'espace compris entre 1 km et 111 m sur cet archipel.Le modelé atmosphérique Weather Research and Forecasting ARW V3.4 (WRF ARW), non-hydrostatique, a été utilise pour l'ensemble des simulations pour modéliser la troposphère depuis l'échelle globale à l'échelle de la turbulence.Trois situations météorologiques classiques réelles d'une durée de 48 heures, correspondant à 80 % des situations météorologiques observées dans la zone, alizes soutenus (AS), alizes moyens (AM), alizes faibles (AF) ont été examinées. Ces situations sont caractérisées par les valeurs du nombre de Froude local suivantes : 0,82 (AS), 0,41 (AM) et 0,21 (AF). Six domaines de modélisation ont été sélectionnés pour effectuer les descentes d'échelle dynamiques : D01 (maille de 27 km), D02 (maille de 9 km), D03 (maille de 3 km), D04 (maille de 1 km), D05 (maille de 333 m) et D06 (maille de 111 m) avec soixante-dix niveaux verticaux. Les quatre premiers domaines (D01 à D04) couvrent l'archipel de la Guadeloupe et sont utilisés en mode méso-échelle à l'aide d'un schéma d'ensemble de couche limite planétaire YSU. Les domaines D05 (couvrant l'île de la Basse-Terre et le centre de l'archipel) et D06 (couvrant la zone littorale et rurale du Petit Cul-de-Sac Marin et la zone urbaine de l'agglomération pointoise) sont utilisés en mode Large Eddy Simulation avec une fermeture de la turbulence 1,5 TKE 3D. Le modèle WRF a été forcé toutes les six heures par l'assimilation des champs d'analyses globales du modèle NCEP FNL (1° de résolution). Les simulations effectuées ont permis d'obtenir des champs de variables météorologiques 10-minutes à très hautes résolutions spatiales.Les résultats des simulations méso- et micro-échelles ont été confrontés aux valeurs expérimentales obtenues à l'aide de capteurs places sur des mâts météorologiques (campagne Atmo-Mangrov et réseau de mesure Météo-France). Il s'agissait d'optimiser l'utilisation des couplages de codes numériques tout en conservant la possibilité de les confronter aux observations expérimentales.Les résultats des simulations numériques micro-échelles, des différents cas (AS, AM, AF) sont utilisées pour forcer (c'est-à-dire définir les conditions limites) un modèle lagrangien de dispersion de particules : FLEXPART. Le système couple FLEXPART-WRF a été employé dans le domaine D06 pour étudier la dispersion du panache d'oxydes d'azote émis par la principale usine de production d'électricité de l'île.
The present work expresses the will of Caribbean researchers to improve the meso- and micro-meteorological scientific knowledge of the trade winds influenced island areas, and to develop research in these domains.It is well known that tropical hurricanes remain the most remarkable meteorological phenomena that affect the Caribbean islands. But some other phenomena, of smaller scale, such as intense rainfall events, swells, or air quality degradation, are of extreme importance for natural or health hazards. These examples show the need to use downscaling methods to exploit large scale meteorological or climatic information, and to obtain local and regional scenarios for the island areas. This is an important challenge, as sound scientific studies in these matters are eagerly expected. The aim of the research works exposed in the present dissertation is numerical simulation and analysis of the meso- and microscale mechanisms that induce diurnal and nocturnal local circulations in the Guadeloupe archipelago, using numerical meteorological models that are widely used in research and in operational forecasting.These works represent the first high-resolution (1 km to 111 m) numerical study of the lower atmosphere over the Guadeloupe archipelago. The Weather Research and Forecasting ARW 3.4 (WRF-ARW) model is used to simulate the troposphere from global scale to turbulence scale. Real cases of three typical weather types (80% of cases during a year) are examined during 48 hours : strong trade winds (STW), medium trade winds (MTW) and weak trade winds (WTW). These weather types are characterized by values of the local Froude number : 0.82 (STW), 0.41 (MTW) and 0.21 (WTW). Six domains have been selected for the dynamical downscaling : D01 (grid spacing of 27 km), D02 (grid spacing of 9 km), D03 (grid spacing of 3 km), D04 (grid spacing of 1 km), D05 (grid spacing of 333 m) and D06 (grid spacing of 111 m), including 70 vertical levels. The first four domains (D01 to D04) cover the Guadeloupe archipelago and are used in the meso-scale simulations with the planetary boundary layer scheme YSU (ensemble mean). Domain D05 (covering the Basse-Terre island and the middle of the archipelago) and domain D06 (covering the coastal and rural area of Le Petit Cul-de-Sac Marin and the urban area of Pointe-à-Pitre), are employed in the micro-scale simulation (LES) with the 3D TKE 1.5 order closure scheme. WRF has been 6 hourly reinitialized with the NCEP FNL global analyses (resolution of 1°). These simulations permitted to obtain 10-minutes meteorological variable fields with a very high resolution (111 m).Meso-scale and micro-scale model results have been evaluated with observational data from meteorological stations (field campaign Atmo-Mangrov, French Met Office).Once validated, the micro-scale model outputs have been used for the assimilation of the lagrangian particle dispersion model : FLEXPART. The coupling FLEXPART-WRF has been employed in domain D06, in order to analyze the dispersion of the nitrogen oxide plume emitted by the main power plant of the archipelago.

http://www.theses.fr/2014AGUY0735/document

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The platinum-group element (PGE) systematics of continental mantle peridotites show large variability, reflecting petrogenetic processing of the upper mantle during partial melting and melt/fluid percolation inside the lithosphere. By removing Pd-Cu-Ni rich sulfides, partial melting events that have stabilized the sub-continental mantle lithosphere fractionated PPGEs (Palladium-group PGE; Pt, Pd) relative to IPGEs (Iridium-group PGE; Os, Ir, Ru, Rh). Residual base-metal sulfides (BMS) survive as enclosed IPGE-enriched Monosulfide Solid Solutions (Mss), which otherwise decompose into Ru-Os-Ir-rich refractory platinum-group minerals (PGMs) once the partial melts become S-undersaturated. The small-scale heterogeneous distribution of these microphases may cause extreme nugget effects, as seen in the huge variations in absolute PGE concentrations documented in cratonic peridotites. Magmas fluxing through the lithospheric mantle may change the initial PGE budgets inherited from the melting events, resulting in the great diversity of PGE systematics seen in peridotites from the sub-continental lithosphere. For instance, melt-rock reactions at increasing melt/rock ratios operate as open-system melting processes removing residual BMS/PGMs. Highly percolated peridotites are characterized by extreme PGE depletion, coupled with PGE patterns and Os-isotope compositions that gradually evolve toward that of the percolating melt. Reactions at decreasing melt-rock ratios (usually referred to as "mantle metasomatism") precipitate PPGE-enriched BMS that yield suprachondritic Pd/Ir and occasionally affect Pt/Ir and Rh/Ir ratios as well. Moreover, volatile-rich, small volume melts fractionate Os relative to Ir and S relative to Se, thereby producing rocks with supra-chondritic Os/Ir and S/Se coupled with supra-chondritic Pd/Ir and Pt/Ir. Major magmatic inputs at the lithosphere-asthenosphere boundary may rejuvenate the PGE systematics of the depleted mantle. Integrated studies of "refertilized" peridotites with worldwide provenance provide evidence for mixing between old PGM-rich harzburgitic protoliths and newly-precipitated BMS. Long-lived PGMs carry the Os-isotope compositions of ancient melt‐depletion events into seemingly undepleted fertile lherzolites. Another diagnostic feature of major refertilization processes is the increasing modal abundance of Pt-Pd-Te-Bi or Pt-As-S microphases. Due to regional-scale refertilization processes, sizeable (> 100 km) domains of the upper lithospheric mantle are now significantly enriched in Pd, Au, Cu, Se, and other incompatible chalcophile elements that are of considerable importance in PGE-ore forming events.
ISSN: 0024-4937

hal-00828626
https://hal.archives-ouvertes.fr/hal-00828626
DOI : 10.1016/j.lithos.2012.08.017

Éditeur(s) : HAL CCSD
Résumé : International audience
The Kazdağ Massif exposes a metamorphic dome in the Biga Peninsula of northwest Turkey. An extensional origin has been proposed for the dome, limited on both flanks by detachments and/or shear zones. The northern flank is bounded by the extensional Alakeçi Shear Zone (ASZ), whose P-T-t path is still poorly known. We therefore focus on its metamorphic conditions and related temporal history to precise its tectono-metamorphic evolution. The local tectonostratigraphy in structurally ascending order comprises: (i) the high-grade metamorphic core rocks of the Kazdaǧ Massif (gneisses and micaschists intercalated with amphibolites and marbles); (ii) the two kilometer-thick ASZ; (iii) the overlaying unmetamorphosed pre-Cenomanian accretionary Çetmi mélange; and (iv) Neogene sedimentary and volcanic cover rocks. ASZ mylonites were derived from both the core rocks and the mélange lithologies. From the north to the south the mylonitic fabrics in the ASZ depict a top-to-the N-NNE shearing, parallel to the NNE-plunging stretching lineation and NNW-dipping mylonitic foliation. This geometry implies normal sense movement i.e. north-side down-dip extensional displacement along this flank of the Kazdaǧ Massif. The northward transition from ductile to brittle-ductile regime through the ASZ shows that the deformation occurred at decreasing temperatures and degree of metamorphism. The paragenesis in equilibrium within the mylonitic gneisses and schists contains Qtz + Fs + Ms + Bt + Grt ± St ± Sill, with late retrogressive chlorite after biotite and garnet. Four samples of ASZ rocks yielded pressures between 6.9-5.7 kbar and temperatures between 706-587°C. Three samples from the mylonitic rocks supplied in situ isochron 36Ar/40Ar mica ages between 31.2-24.2 Ma, which we interpret to date the cooling of the mylonites following the P-T decrease across the ASZ. The metamorphic and structural results support the extensional character of the ASZ, and sketch transition from sillimanite core gneisses in the deeper structural levels to chlorite schists towards the top of the shear zone. These new data allow to precise the peak P-T conditions and the temporal evolution in the northern flank of the Kazdaǧ Massif, where Late Oligocene extensional exhumation was assisted by NNE-directed ductile-brittle ASZ, which had operated from amphibolite to greenschist facies. At the regional scale, this tectono-metamorphic pattern is similar to those observed on other places of the north Aegean domain.
IOP Conference Series
Austin, TE, United States

hal-00642725
https://hal-brgm.archives-ouvertes.fr/hal-00642725
DOI : 10.1088/1755-1307/2/1/012012

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : International audience
This special issue includes papers covering various topics of importance in the Caribbean such as geodynamics, environmental evolutions and natural hazards (fig. 1). This collection of articles focuses in particular on geodynamic processes occurring along the Caribbean plate boundaries, on volcanic hazards and on flooding. Given the recently increased societal importance of these subjects, we hope that the regional geological community and the local policy makers and government officials of the Caribbean countries will find this a timely and valuable update regarding research advances on these topics. We decided to publish this issue following the Caribbean Geological Conference, which has been held every 3 years since 1955 and took place in Guadeloupe for its 19th meeting from the 21st to the 24th of March 2011.
EISSN: 1777-5817

hal-00830337
https://hal.archives-ouvertes.fr/hal-00830337
DOI : 10.2113/gssgfbull.184.1-2.3

Résumé : En 2003 des mesures au spectromètre IR à Transformée de Fourier (FTIR) ont permis d'identifier et de mesurer les COV émis par la décharge à ciel ouvert de la Gabarre, principale de l'île Guadeloupe, située entre une zone urbaine et une mangrove. Ces COV ont été retrouvés (2004) la nuit dans les cités, justifiant les plaintes des riverains. Dans le cadre de cette thèse, des mesures au spectromètre de masse portatif MS 200 ont validé ces résultats du FTIR. De nouvelles mesures au MS 200 ont été menées dans toute la zone de la décharge. Les cités concernées étant à l'opposé du flux synoptique d'Alizés-Est, les facteurs météorologiques permettant la dispersion et le transport des COV de la décharge vers la zone urbaine ont été recherchés. La diminution nocturne de l'intensité des Alizés au dessus de l'ile peut laisser place à des phénomènes locaux tels les brises. L'idée d'une brise terre-mer a été éliminée. Un maillage autou~ de la décharge (cités et mangrove) avec 8 thermomètres a révélé un îlot de chaleur urbain nocturnegénérant une brise thermique d'environ Ims- I (mesurée et calculée). Avec les radiosondages Météo France et un SODAR installé dans la décharge, une très forte stabilité dans les basses couches atmosphériques de la couche limite nocturne avec une inversion de surface d'environ 120mvv apparait. Ces facteurs expliquent la pollution des cités par les COV de la décharge, Un modèlevGaussien en tenant compte a été validé par les mesures de COV.vCette étude peut être étendue à d'autres décharges à ciel ouvert et à d'autres types de traitement de polluants de décharge.
In 2003, the VOC emissions coming from "La Gabarre", the main open landfill in Guadeloupe, located in-between an urban area and a mangrove, were identified and quantified with a portable FTIR spectrometer. In 2004, COVs found at nighttime in the urban area nearby confirmed why residents complain about. As part of this thesis, portable mass spectrometer MS 200 measurements validated these FTIR figures. New systematic SM measurements have been carried on around the landfill. Since the polluted urban area stands on the opposite way of the East Trade winds synoptic flux, aIl the weather factors likely to scatter and transport the dump COVs were scrutinized. At night, the strength of the Trade winds decreases over Guadeloupe, which may give way to local phenomena such as breezes. The occurrence of land/sea breeze was eliminated. A close surveying surrounding the landfill with 8 thermometers both in the projects and in the mangrove revealed an urban heat island causing thermal breezes of about lms-l (measured and calculated). Using soundings from Meteo France, and a SODAR inside the dump, we found a great stability of the night boundary layer with a surface inversion near 120m. Pollution of the nearby urban area with landfill COVs is elucidatcd by the above factors. A transport Gaussian model is in agreement with COV measurements. This study can be extended to different open landfills and different types of polluting matters processes in dumps

http://www.theses.fr/2013AGUY0700/document

Éditeur(s) : HAL CCSD
Résumé : International audience
In boundary lubrication regime, friction reduction and antiwear processes are associated to the presence of additives in the lubricating oils or greases. These processes are due to the formation of protective tribofilms resulting from chemical reactions between the additives and the sliding surfaces, in the physico-chemical conditions of the sliding contact. Conventional antiwear additives mainly consist of transition metal organo phosphate or thiophosphates which present a remarkable efficiency in the case of contacts between ferrous alloys. In the case of non reacting surfaces, these additives become inactive. Recently developped lubrication strategies consist in the use of dispersion in oils of nano additives able to build the protective tribofilm in the sliding contact without reaction with the surfaces. Carbon fluorinated phases, due to their lamellar structure and their high chemical stability even at relatively high temperature (400°C) represent interesting candidates as lubricant nano-additives subjected to present friction reduction, anti wear and anti corrosion actions. This work presents the tribologic behaviour of some carbon fluorinated derivatives such as graphite fluorides, fluorinated carbon nanofibers, fluorinated carbon nanodiscs and fluorinated carbon blacks. The influence, on the tribologic performances, of the structure of the initial carbon phases, of the fluorination rate (0
World Tribology Congress 2013
Torino, Italy

Droits : info:eu-repo/semantics/OpenAccess
hal-00926514
https://hal.archives-ouvertes.fr/hal-00926514
https://hal.archives-ouvertes.fr/hal-00926514/document
https://hal.archives-ouvertes.fr/hal-00926514/file/Delbe_9783.pdf
OATAO : 9783

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Let H1,H2,H3 be real Hilbert spaces, let C⊂H1, Q⊂H2 be two nonempty closed convex level sets, let A:H1→H3, B:H2→H3 be two bounded linear operators. Our interest is in solving the following new convex feasibility problem Find x∈C,y∈Q such that Ax=By, which allows asymmetric and partial relations between the variables x and y. In this paper, we present and study the convergence of a relaxed alternating CQ-algorithm (RACQA) and show that the sequences generated by such an algorithm weakly converge to a solution of (1.1). The interest of RACQA is that we just need projections onto half-spaces, thus making the relaxed CQ-algorithm implementable. Note that, by taking B=I, in (1.1), we recover the split convex feasibility problem originally introduced in Censor and Elfving (1994) [13] and used later in intensity-modulated radiation therapy (Censor et al. (2006) [11]). We also recover the relaxed CQ-algorithm introduced by Yang (2004) [8] by particularizing both B and a given parameter.
ISSN: 0362-546X

hal-00776638
https://hal.univ-antilles.fr/hal-00776638
DOI : 10.1016/j.na.2012.11.013

Éditeur(s) : HAL CCSD Society for Molecular Biology and Evolution
Résumé : International audience
Vibrio metoecus is the closest relative of Vibrio cholerae, the causative agent of the potent diarrheal disease cholera. Although the pathogenic potential of this new species is yet to be studied in depth, it has been co-isolated with V. cholerae in coastal waters and found in clinical specimens in the USA. We used these two organisms to investigate the genetic interaction between closely related species in their natural environment. The genomes of twenty V. cholerae and four V. metoecus strains isolated from a brackish coastal pond on the US east coast, as well as four clinical V. metoecus strains were sequenced and compared to reference strains. Whole genome comparison shows 86-87% average nucleotide identity (ANI) in their core genes between the two species. On the other hand, the chromosomal integron, which occupies approximately 3% of their genomes, shows higher conservation in ANI between species than any other region of their genomes. The ANI of 93-94% observed in this region is not significantly greater within than between species, meaning that it does not follow species boundaries. V. metoecus does not encode toxigenic V. cholerae major virulence factors, the cholera toxin and toxin co-regulated pilus. However, some of the pathogenicity islands found in pandemic V. cholerae were either present in the common ancestor it shares with V. metoecus, or acquired by clinical and environmental V. metoecus in partial fragments. The virulence factors of V. cholerae are therefore both more ancient and more widespread than previously believed. There is high interspecies recombination in the core genome, which has been detected in 24% of the single-copy core genes, including genes involved in pathogenicity. V. metoecus was six times more often the recipient of DNA from V. cholerae as it was the donor, indicating a strong bias in the direction of gene transfer in the environment.
ISSN: 1759-6653

Droits : http://creativecommons.org/licenses/by/
hal-01264332
http://hal.upmc.fr/hal-01264332
http://hal.upmc.fr/hal-01264332/document
http://hal.upmc.fr/hal-01264332/file/Genome%20Biol%20Evol-2015-Orata-gbe_evv193.pdf
DOI : 10.1093/gbe/evv193

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Melt generation in the continental crust is thought to significantly influence seismic bulk velocities and anisotropy, although existing laboratory data provide limited constraints on such seismic attributes. In this study we measured ultrasonic compressional wave speeds (Vp) and anisotropy during sample compaction, mica-breakdown and melt-generation in synthetic, foliated quartz–muscovite aggregates. Measurements were performed at peak conditions of 300 MPa hydrostatic confining pressure and 750 °C, over a six hour time period, for three separate samples where wave propagation directions were aligned at 0°, 45° and 90° with respect to the foliation plane. The experiments are initially marked by sample compaction and rapid reduction in porosity (from 25% to <2 vol%), with a corresponding increase in Vp. During initial stages of the experiment Vp ranges from 4.65 to 5.45 km/s, depending on the direction of the P wave propagation, resulting in up to ∼16% anisotropy, which originates mainly from the preferred orientation of muscovite and possible incipient melt lenses oriented parallel to foliation. As the experiment progresses the bulk Vp decreases gradually and Vp anisotropy drops from ∼16% to ∼2% after five hours into the experiment. The drop in anisotropy is caused by muscovite-breakdown and increasing amount of partial melting of the aggregate. The bulk velocities are considerably lower than predicted for a mixture of muscovite and β-quartz (stable at 300 MPa and 750 °C). Thermodynamic modeling indicates that mica breakdown and production of melt with ∼2 wt% dissolved water in the aggregate can explain the low Vp, even though β-quartz is stable; the modeled Vp is ∼4.75 km/s at 300 MPa and 750 °C. These ultrasonic attributes signify movement of the melt to fill vacant pores and coating grain boundaries, effectively connecting melt films and reducing seismic anisotropy. The results may apply to regions where crustal melting is on-going, in particular regions of elevated temperature that are only weakly deforming, with coupled anomalously low bulk velocities and seismic anisotropy.
ISSN: 0012-821X

hal-01243569
https://hal.archives-ouvertes.fr/hal-01243569
DOI : 10.1016/j.epsl.2015.05.039

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Longmen Shan (Sichuan, China) is characterised by an unusual morphology which results from a Triassic prism tectonics and a more recent Neogene thick-skin thrusting. Among its specific features is the high elevation of the internal zones in continuity with the Songpan Garze fold-and-thrust belt (SG), which is associated with an abrupt 20 km Moho offset between the Sichuan Basin and the Tibetan plateau as revealed by the analysis of teleseismic data acquired by a dense seismic network. The jump in crustal thickness is located at the apex of the Wenchuan shear zone (WSZ) and marks the western boundary of the metamorphosed units of SG characterized by temperatures varying from 590 degrees C down to 300 degrees C as commonly observed in mature accretionary wedges. Both the structural style marked by intense shortening in tight kink folds and geophysical data suggest the presence of an horizontal discontinuity at similar to 15 km depth over a thick crust (similar to 63 km).;The Longmen Shan east of the WSZ is characterized by thick-skin detachment which thrusts the internal sedimentary units and the Proterozoic basement over the series of the Sichuan Basin deposited on a thinner crust of similar to 44 km thick. The major front is the Beichuan Fault Zone (BFZ) which brought the internal zones onto Triassic and Jurassic series with lower temperatures (less than 400 degrees C). Locally, temperatures of similar to 425 degrees C are found just below the klippes.;These results are in agreement with an original contact of the SG zone represented by an accretionary wedge of sediments thrusted over the margin of the continental crust of the Yangtze craton in the early stage (Indosinian) of the evolution. The present-day slow E-W component of the convergence, added to the difference in crustal thickness caused the Yangtze crust to indent the Songpan Tibetan crust which was softened by a high thermal regime. As a response the edge of the Tibet crust was inflated to the bottom (up to 70 km), whereas to the top, the crystalline massif were exhumed and pushed the deformation eastward as emerging and blind thrusts. This configuration reflects a moderate shortening of the crust which behaves as a soft thick material abutting the resistant and cold Yangtze crust.
ISSN: 0040-1951

hal-00534849
https://hal.archives-ouvertes.fr/hal-00534849
DOI : 10.1016/j.tecto.2010.03.018

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Continental rifts and passive continental margins show fundamental along-axis segmentation patterns that have been attributed to one or a number of different processes: extensional fault geometry, variable stretching along strike, preexisting lithospheric compositional and structural heterogeneities, oblique rifting, and the presence or absence of eruptive volcanic centers. The length and width scales of the rift stage fault-bounded basin systems change during the late evolution of the new plate boundary, and the role of magmatism may increase as rifting progresses to continental rupture. Along obliquely spreading ridges, first-order mid-ocean ridge geometries originate during the synrift stage, indicating an intimate relationship between magma production and transform fault spacing and location. The Gulf of Aden rift is a young ocean basin in which the earliest synrift to breakup structures are well exposed onshore and covered by thin sediment layers offshore. This obliquely spreading rift is considered magma-poor and has several large-offset transforms that originated during late stage rifting and control the first-order axial segmentation of the spreading ridge. Widely spaced geophysical transects of passive margins that produce only isolated 2-D images of crust and uppermost mantle structure are inadequate for evaluation of competing rift evolution models. Using closely spaced new geophysical and geological observations from the Gulf of Aden we show that rift sectors between transforms have a large internal variability over short distances (∼10 km): the ocean-continent transition (OCT) evolves from a narrow magmatic transition to wider zones where continental mantle is probably exhumed. We suggest that this small-scale variability may be explained (1) by the distribution of volcanism and (2) by the along-strike differences in time-averaged extension rate of the oblique rift system. The volcanism may be associated with (1) the long-offset Alula-Fartak Fracture Zone, which may enhance magma production on its younger side, or (2) channeled flow from the Afar plume material along the newly formed OCT and the spreading ridge. Oblique extension and/or hot spot interactions may thereby have a significant control on the styles of rifting and continental breakup and on the evolution of many magma-poor margins.
ISSN: 1525-2027

hal-00504866
https://hal.archives-ouvertes.fr/hal-00504866
https://hal.archives-ouvertes.fr/hal-00504866/document
https://hal.archives-ouvertes.fr/hal-00504866/file/G3-Leroy_al-2010.pdf
DOI : 10.1029/2009GC002963

Éditeur(s) : American Geophysical Union
Résumé : The origins and fates of the Atlantic salinity maximum water (SMW), formed through excess evaporation in the tropics and subtropics of both hemispheres, are studied using monthly mean outputs of a numerical simulation of the world ocean climatological circulation. After defining formation domains from the surface salinity field and the vertical stratification, a Lagrangian technique is used to estimate the formation rates and main pathways in each hemisphere and the role of this water in the framework of the warm water return flow of the meridional overturning cell. Formation rates around 9 and 11 Sv are found in the Southern and Northern Hemispheres, respectively. While the export of the southern SMW from its formation area is realized by the western boundary currents, that of the northern SMW mainly results from interior subduction. Equatorward of the formation regions, a fraction of each SMW variety is entrained in the subtropical cells that connect the subtropics to the equatorial region. Poleward of them, both varieties are seen to feed the regions of subtropical mode water (STMW) formation around 35degrees of latitude in both hemispheres. The bulk of the transport associated with each variety eventually turns northward: This amounts to similar to6 Sv of southern SMW gathered in the North Brazil Undercurrent (NBUC), and similar to10 Sv of northern SMW found in the Gulf Stream at 35degreesN, of which 8 Sv have gone through the Caribbean Sea. Of the 13.4-Sv northward transport of the meridional overturning cell estimated by the model at 47degreesN, more than 50% (6.9 Sv) is found to have transited through at least one of the SMW regions. This gives an indication of the likely important role of SMW formation in the observed northward salinity increase of the upper Atlantic Ocean.
Journal of Geophysical Union - Research C - Oceans (0148-0227) (American Geophysical Union), 2002-09 , Vol. 107 , N. C10 , P. NIL_610-NIL_624

Droits : 2002 by the American Geophysical Union
http://archimer.ifremer.fr/doc/2002/publication-769.pdf
DOI:10.1029/2002JC001318
http://archimer.ifremer.fr/doc/00000/769/

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
In this paper we investigate finite-frequency effects in crustal tomography. We developed an inversion procedure based on an exact numerical computation of the sensitivity kernels. In this approach we compute the 3D travel-time sensitivity kernels by using (1) graph theory and an additional bending to estimate accurately both rays and travel-times between source/receiver and diffraction points and (2) paraxial ray theory to estimate the amplitude along theses rays. We invert both the velocity and the hypocentre parameters, using these so-called banana-doughnut kernels and the LSQR iterative solver. We compare the ray-theoretical and the finite-frequency tomography to image the intermediate structures beneath the Gulf of Corinth (Greece), which has long been recognized as the most active continental rifting zone in the Mediterranean region. Our dataset consists of 451 local events with 9233 P- firstarrival times recorded in the western part of the Gulf (Aigion area) in the framework of the 3F-Corinth European project. Previous tomographic images showed a complex velocity crustal model and a low-dip surface that may accommodate the deformation. Accurate velocity models will help to better constrain the rifting process, which is still a subject of debate. The main results of this study show that finite-frequency tomography improves crustal tomographic images by providing better resolved images of the 3D complicated velocity structure. Because the kernels spread the information over a volume, finite-frequency tomography results in a sharpening of layer boundaries as we observed for the shallower part of the crust (down to 5 km depth) beneath the Gulf of Corinth.
ISSN: 0016-8025

insu-00354702
https://hal-insu.archives-ouvertes.fr/insu-00354702
DOI : 10.1111/j.1365-2478.2007.00683.x

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
In order to constrain the vertical and lateral extent of deformation and the interactions between lithosphere and asthenosphere in a context of a transpressional plate boundary, we performed teleseismic shear wave splitting measurements for 65 permanent and temporary broadband stations in central California. We present evidence for the presence of two anisotropic domains: (1) one with clear E–W trending fast directions and delay times in the range 1.5 to 2.0 s and (2) the other closely associated with the San Andreas Fault system with large azimuthal variations of the splitting parameters that can be modeled by two anisotropic layers. The upper of the two layers provides fast directions close to the strike of the main Californian faults and averaged delay times of 0.7 s; the lower layers show E–W directions and delay times in the range 1.5 to 2.5 s and thus can be compared to what is observed in stations that require a single layer. We propose the E–W trending anisotropic layer to be a 150 to 200 km thick asthenospheric layer explained by the shearing associated with the absolute plate motion of the North American lithosphere. The shallower anisotropic layer ought to be related to the dynamics of the San Andreas Fault system and thus characterized by a vertical foliation with lineation parallel to the strike of the faults localized in the lithosphere. We also propose that the anisotropic layer associated with each fault of the San Andreas Fault system is about 40 km wide at the base of the lithosphere.
ISSN: 0148-0227

hal-01236161
http://hal.univ-reunion.fr/hal-01236161
http://hal.univ-reunion.fr/hal-01236161/document
http://hal.univ-reunion.fr/hal-01236161/file/Bonnin_SKS_California_JGR2010.pdf
DOI : 10.1029/2009JB006438