Éditeur(s) : HAL CCSD BioMed Central
Résumé : International audience
ABSTRACT: BACKGROUND: The amount of lead in the environment has decreased significantly in recent years, and so did exposure. However, there is no known safe exposure level and, therefore, the exposure of children to lead, although low, remains a major public health issue. With the lower levels of exposure, it is becoming more difficult to identify lead sources and new approaches may be required for preventive action. This study assessed the usefulness of lead isotope ratios for identifying sources of lead using data from a nationwide sample of French children aged from six months to six years with blood lead levels (B-Pb) [greater than or equal to] 25 ug/L. METHODS: Blood samples were taken from 125 children, representing about 600,000 French children; environmental samples were taken from their homes and personal information was collected. Lead isotope ratios were determined using quadrupole ICP-MS (inductively coupled plasma - mass spectrometry) and the isotopic signatures of potential sources of exposure were matched with those of blood in order to identify the most likely sources. RESULTS: In addition to the interpretation of lead concentrations, lead isotope ratios were potentially of use for 57% of children aged from six months to six years with blood lead level [greater than or equal to] 25 ug/L (7% of overall children in France, about 332,000 children), with at least one potential source of lead and sufficiently well discriminated lead isotope ratios. Lead isotope ratios revealed a single suspected source of exposure for 32% of the subjects and were able to eliminate at least one unlikely source of exposure for 30% of the children. CONCLUSIONS: In France, lead isotope ratios could provide valuable additional information in about a third of routine environmental investigations.
ISSN: 1476-069X

inserm-00624817
http://www.hal.inserm.fr/inserm-00624817
http://www.hal.inserm.fr/inserm-00624817/document
http://www.hal.inserm.fr/inserm-00624817/file/1476-069X-10-75.pdf
DOI : 10.1186/1476-069X-10-75

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Coastal aquifers often display seawater intrusion resulting in the formation of a salty water wedge progressing inland. This study investigates the mass transfers in the mixing zone at the freshwater-seawater interface where the water is out of equilibrium with the rock-forming carbonates. Investigations were conducted in two boreholes, separated by 5 m, at the Ses Sitjoles test site (Mallorca Island, Spain) where repeated electrical conductivity logs of the formation and the saturating fluid, as well as regular pore-water sampling and permanent downhole multi-parameter monitoring of the water were performed over a period of 9 a. In the mixing zone, the significant acidification, the calcite saturation index profile and the Ca concentration profile cannot be explained by conservative mixing nor by dissolution-precipitation reactions only. Conversely, the analysis of organic C content and of the distinctly different time-resolved pH profiles measured in the two boreholes suggests the development of perennial biomass that triggers calcite dissolution. Moreover, the presence of biomass seems to be correlated with the permeability and vertical connectivity at the meter-scale. It is speculated that the mechanism could be self-activated because the microbiological activity induces calcite dissolution and tends to increase porosity and permeability that favors biomass development.
ISSN: 0883-2927

hal-00937665
https://hal.archives-ouvertes.fr/hal-00937665
DOI : 10.1016/j.apgeochem.2013.09.011

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Carbonation of peridotite is a widespread process in nature, with emerging societal and environmental implications through geological storage of CO2. We studied the micro- and nano-scale structures associated with the carbonation of peridotite pervaded by a CO2-rich water and the induced changes of its hydrodynamic properties. Focused ion beam (FIB) nanotomography was coupled with scanning electron microscopy (SEM) and transmission electron microscopy (TEM) observations. An experimental sample of dunite core percolated by a CO2-rich fluid (pCO2 = 11 MPa) at 160 °C was compared with a naturally carbonated sample from the Atlantic Ridge (Exp. IODP 304). Results of the 8-days percolation experiment show continuous alteration of olivine into magnesite locally associated with a poorly crystalline serpentine-type mineral referred to as proto-serpentine. The experiment is also characterized by an overall decrease in rock porosity (from 7.7 to 6.4%) and permeability (from 8.5 × 10− 16 to 1.7 × 10− 16 m2). The primary inter-granular porosity (1 to 10 μm) is progressively filled with magnesite, leading to the overall decrease of permeability. At the same time, a secondary small-scale porosity (10 nm to 1 μm) is created at the tip of the dissolution features along the (010) cleavage planes of olivine grains. Carbonate crystals grow within these etch-pit structures behind the dissolution front. Dissolution and precipitation occur at a relative rate that maintains the secondary porosity over the timescale of the experiment (i.e. carbonate growth has to be the slowest one). This process is interpreted as an interface coupled dissolution-precipitation mechanism of olivine carbonation. Proto-serpentine is only formed in highly reduced flow areas, such as small olivine etch-pits (10 to 500 nm wide), which are more isolated from CO2 input. SEM-FIB analyses show the 3D preferential orientation of the dissolution-precipitation planes within a given olivine grain. It suggests the formation of lateral connections between the etch-pits (infra-micrometric “channels”) providing access to reactants and removing reaction products at the reaction sites. The experimental results show that olivine dissolution and magnesite precipitation converge to a quasi-steady state resulting in a constant carbonation rate controlled by reaction kinetics and not by mass transfer for this flow regime. The system self-regulates, independently of the porosity change at least during this incipient stage of olivine carbonation. Similar textures are observed in natural samples collected at 170 m-depth in the vicinity of veinlets driving late fluids down into the cooling oceanic lithosphere. This suggests that similar mechanisms are active in nature and can play an important role in the late, low temperature alteration stages of fractured peridotite. These results also highlight the critical role of nm-scale spatial arrangement of dissolution and precipitation features on mass transfers and on the sustainability of olivine carbonation through coupled dissolution-precipitation processes.
ISSN: 0009-2541

hal-01684733
https://hal.archives-ouvertes.fr/hal-01684733
DOI : 10.1016/j.chemgeo.2017.11.013

Éditeur(s) : Université de Bucarest - Université de Bretagne occidentale
Résumé : This study is focusing on the architecture and recent sedimentary evolution of the Danube channel, the youngest channel-levee system in the Danube deep-sea fan. The study was conducted as part of the BlaSON French-Romanian Project, and combined high-resolution seismic-reflection profiles and chirp profiles with multibeam bathymetry and piston cores. This data set was acquired in 1998 during a joint survey IFREMER-GeoEcoMar of the north-western Black Sea. Previous seismic and acoustic data were also used. The Danube deep-sea fan is a large passive-margin mud-rich fan. Like the other systems of this type (Amazon fan, Mississippi fan or Indus fan) the Danube fan consists of stacked channel-levee systems intercalated with mass-transport deposits. Seismic and sedimentary facies in the Danube fan are similar to those identified in most of the mud-rich systems. Nevertheless, the Danube fan is distinguished by a specific feature: its development in a freshwater environment. This is due to the peculiar water-level history of the Black Sea controlled by the link to the Mediterranean through the Strait of Bosphorus and the Sea of Marmara. This connexion was successively interrupted (during sea level lowstands) and re-established (when the sea level was rising above the Bosphorus). Temporary absence of marine water influx during lowstands together with large freshwater inputs from the Danube and other major rivers changed the Black Sea into a freshwater lake during times of fan activity. This peculiarity possibly favourised the development of hyperpycnal flow at the Danube mouth and the initiation of turbidity currents in the deep-sea fan. The Danube channel is directly connected to the large shelf-indenting Danube canyon (also known as Viteaz canyon). The Danube canyon is deeply incised into the shelf margin for 26 km landward of the shelfbreak. During lowstands this canyon acted as the most important path for sediment supply to the deep sea in this part of the continental margin. It consists of a main trough with steep flanks, and a meandering thalweg cut into the flat canyon floor, attesting for the development of the canyon by erosion in the entrenched axial thalweg. Sections with specific morphology, orientation and gradient identified along the canyon, are interpreted as phases of landward expansion of the canyon. Internal structure of the canyon shows several erosional surfaces, which indicate that the present morphology of the canyon is the result of its polyphasic evolution. Instability in the zone of the canyon is related to the important sediment supply at the Danube mouth, to the presence of the gas in the surficial sediment, and possibly under a structural control. The upper part of the Danube channel (between the Danube canyon and ~1400 m depth) consists in a single leveed-channel that has undergone significant overbank deposition, as attested by the well-developed levees. The levees are strongly asymmetrical, being higher and wider on the right-hand side looking downstream. This type of asymmetry is rather common in deep-sea fans, and is generally attributed to the Coriolis effect (Menard, 1955). The channel is slightly sinuous, partially filled and incised by an entrenched thalweg, connected to the axial thalweg of the Danube canyon. Detailed seismic investigation inside the channel trough documented several depositional phases within the channel fill, separated by erosional surfaces. These surfaces are associated with distinct terraces identified on the multibeam bathymetry, that can be followed downward along the main trough axis. The valley fill deposits (where not removed by the subsequent erosional event) show an axial HAR (High Amplitude Reflections) seismic facies with lateral lower amplitude continuous reflections consisting in a levee facies, as proved by sampling. This indicates that filling up was associated with flow within the channel, and not with interruption of fan activity. On the middle slope below 1400 m, this single channel bifurcates through repeated avulsions. As a result, several highly meandering channels developed. The onlap relationships between these channels indicate that only one channel was active at a time. Each phase of avulsion resulted in a depositional unit consisting in a basal unchannelized lobe defined as High Amplitude Reflection Packets (HARP, Flood et al., 1991) that underlies a channel-levee system. The deposition of HARPs was associated with the readjustment of the longitudinal profile of the channel after the breaching of a levee, which resulted in remobilization of upslope channel deposits and eroded levees. When this adjustment was complete, erosion ceased and levees began to develop above the HARPs (Pirmez et al., 1997). All the identified phases of avulsion followed the same pattern: (1) breaching of the lower and narrower left levee; (2) building of a unit of High Amplitude Reflector Packets (HARP) basinward of the bifurcation point by the unchannelized flow, while the former channel was abandoned; and (3) initiation of a new meandering leveed channel. The northward migration of the resulting units through repeated bifurcations is influenced by the asymmetry between levees (hence by the Coriolis effect), and confined between the high levees of the initial phase of the Danube channel (to the south) and the steep relief of the Dniepr fan (to the north). Structure of the fan valley fill indicate that the erosional surfaces inside the upper channel could be formed in response of successive avulsions, by the adjustment of the longitudinal profile of the channel following the breaching of a levee wall. Sediments removed by erosion formed the HARP lobes basinward of the avulsion point. When this adjustment was complete, a channel-levee system developed downward of the bifurcation, overlying the HARPs, but also upward of this point, as a confined channel-levee system inside the erosional trough of the fan valley. Fluvial incisions identified on the continental shelf, together with the coastline location during the last active period of the Danube channel, indicated that the paleo-Danube was directed towards the head of the Danube canyon. Paleo-Danube mouth was fairly close (ca. 10 km) to the Danube canyon, supplying sediment to the Danube channel. Furthermore, hyperpycnal flow probably prevailed in the freshwater environment that characterized the Black Sea during times of fan activity. These conditions would have enabled the development of a quasi-continuous river-canyon-deep-sea fan system, ensuring the effective transfer of the sediment between the coastal zone and the deep sea.
Ce travail est consacré à l'étude de l'architecture et de l'évolution sédimentaire récente de l'éventail profond du Danube, en particulier de son dernier système chenal-levée: le chenal du Danube. L'étude a été réalisée dans le cadre du projet de coopération franco-roumaine BlaSON, à partir des données sismiques, bathymétriques-acoustiques et sédimentologiques acquises en 1998 lors d'une campagne en mer Noire réalisée par IFREMER et GeoEcoMar. Des données sismiques et acoustiques antérieures ont été également utilisées. L'éventail profond du Danube s'enserre dans la catégorie des grands éventails vaseux. Comme les autres systèmes de ce genre (tel que les éventails de l'Amazone, du Mississippi ou de l'Indus) il est constitué d'une succession de systèmes chenaux-levées intercalés avec des dépôts de transport en masse. Le fonctionnement de l'éventail était conditionné par la baisse du niveau marin lors des périodes glaciaires. Ses faciès sismiques et sédimentaires s'apparentent aux faciès qui caractérisent la plupart des éventails de ce type. L'éventail du Danube constitue néanmoins un cas particulier parmi les autres systèmes étudiés, du fait de son fonctionnement dans un bassin lacustre. Ceci est dû à la situation spécifique de la mer Noire dont la connexion avec la Méditerranée, par le détroit de Bosphore et la mer de Marmara, a été successivement interrompue (au cours de périodes de bas niveau) et reprise (quand le niveau marin remontait en dépassant le seuil du Bosphore). L'absence de l'apport d'eau salée pendant les périodes glaciaires, associée avec l'augmentation de l'apport fluvial, ont déterminé l'installation d'un milieu d'eau douce dans la mer Noire à chaque fois que la baisse du niveau permettait la reprise du fonctionnement de l'éventail profond. Cette situation particulière aurait favorisé la formation des courants hyperpycnaux à l'embouchure d'un fleuve du débit du Danube qui déversait ses eaux turbides dans un bassin lacustre, et aurait donc influencé l'apparition de courants de turbidité dans l'éventail profond. Le chenal du Danube s'est développé sur la pente continentale en prolongation du canyon du Danube (ou Viteaz) auquel il est directement connecté. Le canyon est incisé de manière significative (26 km) dans la plate-forme continentale. Au cours de bas-niveaux marins il constituait la principale voie de transfert des sédiments terrigènes vers le bassin profond dans cette partie de la marge. Le canyon est constitué par une entaille avec des flancs abrupts et un talweg axial incisé, qui montre l'importance du processus d'érosion du fond pour le développement du canyon. Les segments qui ont été identifiés le long du canyon, avec des morphologies, des orientations et des pentes spécifiques, sont interprétés comme des phases d'avancement du canyon vers la côte. Plusieurs incisions sont visibles dans la structure interne du canyon et témoignent que la morphologie actuelle du canyon est le résultat de son évolution polyphasée. L'instabilité de la zone du canyon est en relation avec les apports sédimentaires importants à l'embouchure du Danube, avec la présence du gaz dans les sédiments superficiels, et possiblement sous un contrôle structural. Sur la pente supérieure (entre le canyon du Danube et environ 1400 m de profondeur) le chenal du Danube présente des levées bien développées et fortement asymétriques, avec la levée droite plus haute et plus large que la levée gauche. Ce type d'asymétrie, fréquemment décrit dans les éventails profonds est généralement attribué à l'effet Coriolis (Menard, 1955). Le chenal est légèrement sinueux, partiellement comblé et incisé par un talweg axial qui représente la continuation sur la pente du talweg incisé dans le canyon du Danube. L'analyse sismique détaillée du remplissage de la vallée montre plusieurs phases de dépôt, séparées par des discontinuités érosives. Ces surfaces d'érosion correspondent à des terrasses emboîtées, relativement parallèles le long de la vallée, visibles dans la bathymétrie. Les dépôts qui constituent le remplissage du chenal présentent un faciès sismique de type HAR (High Amplitude Reflections) dans l'axe du chenal, partiellement (ou parfois totalement) enlevé par les phases d'érosion subséquentes, qui continue latéralement avec des réflexions litées correspondant à un faciès sédimentaire de levée. Le remplissage de la vallée a été donc associé avec des écoulements dans le chenal, et non pas avec l'interruption de son fonctionnement. Sur la pente inférieure, le chenal unique bifurque plusieurs fois par avulsion et forme de nouveaux systèmes chenaux-levées méandriformes. Ces systèmes se succèdent verticalement en onlap, ce qui montre qu'un seul chenal a été actif à la fois. Chaque phase d'avulsion a eu comme résultat la mise en place d'une unité constituée par un lobe défini comme "High Amplitude Reflection Packets" (HARP, Flood et al., 1991) à la base, et un système chenal-levée au sommet. Le dépôt d'un lobe HARP est associé avec de l'érosion dans le chenal en amont du point d'avulsion pour l'ajustement de son profil après la rupture de la levée. Quand le chenal a retrouvé son profil d'équilibre, l'érosion a cessé et des levées ont commencé à se développer au-dessus des HARPs (Pirmez et al., 1997). Toutes les phases d'avulsion se sont développées d'après le même modèle: (1) la rupture de la levée gauche, plus étroite; (2) le dépôt d'un lobe HARP par les écoulements non-chenalisés en aval du point d'avulsion, et l'abandon de l'ancien chenal; (3) l'initiation d'un nouveau système chenal-levée. La migration systématique du chenal vers le nord est influencée par l'assymétrie des levées (donc par la force de Coriolis), et confinée entre les grandes levées de la phase initiale du chenal du Danube, au sud, et le relief abrupt de l'éventail du Dniepr au nord. La structure sédimentaire du chenal du Danube indique que les surfaces érosives à l'intérieur du remplissage du chenal se seraient formées en réponse aux avulsions, du fait de l'ajustement du profil du chenal après la rupture d'une levée. Les sédiments du chenal érodés au cours de ce processus ont formé les lobes HARP. Quand le chenal a retrouvé son profil d'équilibre, un système chenal-levée s'est développé en aval du point d'avulsion au dessus du lobe HARP, mais aussi en amont de ce point, où il se trouve confiné dans la vallée érosive. Les incisions fluviatiles identifiés sur la plate-forme continentale et la position de la ligne de côte pendant la dernière période d'activité du chenal du Danube montrent que le paléo-Danube se dirigeait directement vers la tête du canyon du Danube. Son embouchure était située à proximité du canyon, qui alimentait le chenal du Danube. Cependant, les courants hyperpycnaux devaient prévaloir dans le milieu de salinité réduite qui caractérisait la mer Noire lors des périodes actives de l'éventail. Ces conditions auraient favorisé la mise en place d'un système quasi-continu fleuve-canyon-éventail profond, qui contrôlait le transfert des sédiments entre la côte et le bassin profond.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/2002/these-1206.pdf
http://archimer.ifremer.fr/doc/00000/1206/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
People are exposed to multiple pollutants, especially indoors. In the perspective of a cumulative risk assessment, a multi-residue analytical method was developed to assess the contamination of indoor suspended particulate matter by 55 semi-volatile organic compounds (SVOCs) including musk fragrances, organochlorines (OCs), organophosphates (OPs), polycyclic aromatic hydrocarbons (PAHs), polybromodiphenylethers (PBDEs), polychlorobiphenyls (PCBs), phthalates and pyrethroids. It is based on thermal desorption (TD) coupled with gas chromatography/mass spectrometry (GC/MS). Once the thermal desorption conditions were optimized, the method was validated in terms of quantification limits and accuracy using a standard reference material (SRM 2585). Instrumental quantification limits were 10pg (some OCs, some pyrethroids, musk fragrances, OPs, PAHs, PBDEs and PCBs), 100pg (phthalates and other OCs) and 1000pg (other pyrethroids) corresponding respectively to method quantification limits of 1, 10, and 100pg/m(3) for a sampled air volume of 20m(3). Calibration quadratic curves for ranges of 10-1000, 100-10,000, and 1000-100,000pg, depending on the substance, exhibit determination coefficients above 0.999. Recoveries were between 61 and 96% for chlorinated pesticides, PAHs, PBDEs and PCBs present in the SRM 2585. A test of the method on indoor particulate matter samples (PM(10)) collected on quartz fiber filters in French dwellings demonstrated its ability to quantify SVOCs from a small amount of PM.
ISSN: 0021-9673

hal-00732133
https://hal.archives-ouvertes.fr/hal-00732133
DOI : 10.1016/j.chroma.2012.07.025
PUBMED : 22840824

Éditeur(s) : HAL CCSD Ecological Society of America
Résumé : CABI:20153174020
Understanding how plants are constructed - i.e., how key size dimensions and the amount of mass invested in different tissues varies among individuals - is essential for modeling plant growth, carbon stocks, and energy fluxes in the terrestrial biosphere. Allocation patterns can differ through ontogeny, but also among coexisting species and among species adapted to different environments. While a variety of models dealing with biomass allocation exist, we lack a synthetic understanding of the underlying processes. This is partly due to the lack of suitable data sets for validating and parameterizing models. To that end, we present the Biomass And Allometry Database (BAAD) for woody plants. The BAAD contains 259634 measurements collected in 176 different studies, from 21084 individuals across 678 species. Most of these data come from existing publications. However, raw data were rarely made public at the time of publication. Thus, the BAAD contains data from different studies, transformed into standard units and variable names. The transformations were achieved using a common workflow for all raw data files. Other features that distinguish the BAAD are: (i) measurements were for individual plants rather than stand averages; (ii) individuals spanning a range of sizes were measured; (iii) plants from 0.01-100 m in height were included; and (iv) biomass was estimated directly, i.e., not indirectly via allometric equations (except in very large trees where biomass was estimated from detailed sub-sampling). We included both wild and artificially grown plants. The data set contains the following size metrics: total leaf area; area of stem cross-section including sapwood, heartwood, and bark; height of plant and crown base, crown area, and surface area; and the dry mass of leaf, stem, branches, sapwood, heartwood, bark, coarse roots, and fine root tissues. We also report other properties of individuals (age, leaf size, leaf mass per area, wood density, nitrogen content of leaves and wood), as well as information about the growing environment (location, light, experimental treatment, vegetation type) where available. It is our hope that making these data available will improve our ability to understand plant growth, ecosystem dynamics, and carbon cycling in the world's vegetation.
ISSN: 0012-9658

hal-01535227
https://hal.archives-ouvertes.fr/hal-01535227
DOI : 10.1890/14-1889.1
PRODINRA : 306122

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
: Human exposure to xenobiotics is usually estimated by indirect methods. Biological monitoring has emerged during the last decade to improve assessment of exposure. However, biomonitoring is still an analytical challenge, because the amounts of sample available are often very small yet analysis must be as thorough and sensitive as possible. The purpose of this work was to develop an untargeted "exposomics" approach by using ultra-high-performance liquid chromatography coupled to high-resolution mass spectrometry (UHPLC-HRMS), which was applied to the characterization of pesticide metabolites in urine from pregnant women from a French epidemiological cohort. An upgradable list of pesticides commonly used on different crops, with their metabolites (more than 400 substances) was produced. Raw MS data were then processed to extract signals from these substances. Metabolites were identified by tandem mass spectrometry; putative identifications were validated by comparison with standards and metabolites generated by experiments on animals. Finally, signals of identified compounds were statistically analyzed by use of multivariate methods. This enabled discrimination of exposure groups, defined by indirect methods, on the basis of four metabolites from two fungicides (azoxystrobin, fenpropimorph) used in cereal production. This original approach applied to pesticide exposure can be extended to a variety of contaminant families for upstream evaluation of exposure from food and the environment.
ISSN: 1618-2642

hal-00875889
https://hal.archives-ouvertes.fr/hal-00875889
DOI : 10.1007/s00216-013-7136-2
PUBMED : 23892877

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The high proportion of crystallized apatite forming the bones and teeth should theoretically allow the use of fission track analysis to date vertebrate fossils when burying of the fossiliferous series did not subject them to temperatures exceeding 60 degrees C. However several major obstacles arise such as the complexity of fossils' internal structures, diagenetic modifications and substitutions of the hydroxyapatite by other minerals, and massive U uptake or loss during diagenesis. In this work, those various problems are addressed combining optical microscope observation of the fossils, a systematic fission track analysis of the best samples, alpha and gamma spectrometry and Secondary Ion Mass Spectrometry. Even if the problems caused by internal structures and mineral substitutions can be solved, U movements in and out of the fossils are generally too complex to allow fission track analysis dating of the fossils.
ISSN: 0009-2541

hal-00411880
https://hal.archives-ouvertes.fr/hal-00411880
DOI : 10.1016/j.chemgeo.2007.10.009

Éditeur(s) : Gauthier-Villars
Résumé : Cyprideis torosa (Crustacea, Ostracoda), which is well known for its ability to live in a wide range of salinity and for the variability of its ornamentation, was sampled in the paralic environment. in the Camargue (France) and in the area of Santa-Pola (south-east Spain), in ambient waters whose salinity varies from 1 to 120 g/l. The collected valves. which are smooth, punctuated, reticulated or have nodes on their surface, were analyzed by means of spark-source mass spectrometry. We detected twenty-six chemical elements, and found a clear relationship between the chemical composition, the ornamentation of the valves and the environmental parameters. In the oligohaline environment, the carapaces are thick, reticulated or node-bearing ; they are enriched in Si, Al, Fe, Mn and Ba which are terrigenous elements introduced by fresh water. In an open hypersaline environment, the carapaces are reticulated or punctuated ; they are chemically characterized by P, Sr and Li, typical for concentrated seawater. Finally, in a closed hypersaline environment. the collected individuals are smooth, and their carapaces are very thin ; their content S is related to the abundant organic matter provided by the development of algal and cyanobacterial mats. Salinity and confinement, which are the main parameters characteristic of the studied ecosystems, are also the two factors that control the ornamentation of the valves. The chemical analysis and the field observations reveal that the granulometric characteristics of the microhabitats must be considered because they control the exchanges at the water-sediment interface. The anthropic influences on the chemical composition of the carapace must be emphasized: it is possible to detect industrial and domestic wastes. But the ornamentation of the carapace is not related to these pollutants - chiefly heavy metals (Pb, Ni Sn) - and depends mainly on the open or closed character of the ambient environment. The present method highlights, on the basis of the chemical composition, a relationship between ornamentation and environmental parameters. It is particularly efficient in the interpretation of the morphology of the valves in relation to the palaeoenvironment.
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1991 , Vol. 14 , N. 5 , P. 505-514

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00103/21378/18978.pdf
http://archimer.ifremer.fr/doc/00103/21378/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Oman ophiolite, a fossil fast-spreading oceanic ridge had a melt lens perched on top of the magma chamber wherein the gabbro unit was crystallizing. In ophiolites, this melt lens is reduced to a horizon that has been identified in the field. The gabbros that subsided from the lens horizon and drifted out of the magma chamber, while developing a steep magmatic foliation, provide insights into the active melt lens processes. A gabbro, sampled right below the horizon where the lens closed, has virtually not subsided and it offers a direct glance at the floor of the lens. Below, the deeper the gabbros are sampled, the more they have subsided before drifting out of the magma chamber, and the closer they derive from the center of the lens floor. Cross sections in these gabbros record successive events occurring within the lens. In particular, anorthosite layers and lenses that are interlayered within the foliated gabbros record the intrusion of a new melt where plagioclase is the first mineral to crystallize on liquidus. Detailed mapping of anorthosite swarms suggest that melt intrusions are massive, lasting less than 4 yr and that their frequency is similar to 100 yr. Their large volume controls the stability of melt lenses. A new melt surge induces rapid and large inflation of the lens. Melt lens deflation follows, that is due to the ongoing process of crustal accretion both in the gabbro unit by continuous subsidence of a thick gabbroic mush from the lens floor, and in the lid above the lens roof by sheeted dike intrusions feeding basalt extrusions at the higher frequency of similar to 10 yr.
ISSN: 0012-821X

hal-00617444
https://hal.archives-ouvertes.fr/hal-00617444
DOI : 10.1016/j.epsl.2011.01.029

Éditeur(s) : HAL CCSD Taylor & Francis
Résumé : Modern geochronology has moved beyond the acquisition of dates: the goal is to understand the significance of these numbers for the geodynamic evolution of Earth at all scales. The coupling of the laser-ablation microprobe (LAM) to inductively coupled plasma mass spectrometers (ICPMS, multicollector (MC)-ICPMS) has revolutionised geochronology and geochemistry over the last 10 years. These systems enable the rapid and precise in situ analysis of trace-element patterns and isotopic systems, while adding information related to microstructural context and major-element composition. The integration of these multiple sources of data is crucial in constraining the origin of the sample and the processes leading to its formation, so that we can understand the meaning of a date in terms of geological events. LAM-ICPMS measurement of U-Pb ages and trace-element patterns in zircon, coupled with LAM-MC-ICPMS analysis of Hf isotopes in the same grains, gives new insights into the processes of magma genesis. Applied to detrital zircons from modern drainages or sedimentary rocks (the TerraneChron approach), it becomes a powerful tool to investigate problems of crustal evolution on scales ranging from single terranes to continents. The in situ analysis (LAM-MC-ICPMS) of Re-Os systematics in single grains of sulfides in mantle-derived peridotites has demonstrated that most mantle rocks contain several generations of Os-bearing sulfides; whole-rock analyses are mixtures reflecting multiple melting and metasomatic events in the lithospheric mantle. These deep-seated events are commonly mirrored in the crust; Os model-age spectra from xenolith suites show age 'peaks' that correspond to the ages of thermal/tectonic events in the overlying crust, suggesting strong linkages between crust and mantle. Integrated studies of the timing and nature of crustal and mantle events, using these techniques, will be important for understanding the large-scale dynamics of the Earth.
ISSN: 0812-0099

hal-00411328
https://hal.archives-ouvertes.fr/hal-00411328
DOI : 10.1080/08120090802097450

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Oman ophiolite includes both a fossil fast spreading axis, defined by five mantle diapirs, and an off-axis mantle diapir emplaced 30 km from the axis, providing a natural laboratory for the study of off-axis magmatic processes. We compare field and petrological observations coupled with geochemical and isotopic analyses of samples from the off-axis diapir with those of the nearest on-axis diapir, with a particular focus on the Moho Transition Zone (MTZ). Both diapirs are defined by the presence of steeply plunging lineations, but in the on-axis case, these lineations rotate gradually into parallelism with the horizontal magmatic lineations of the overlying crust, while in the off-axis case, a shear zone separates the steeply plunging lineations from the horizontal lineations of the surrounding mantle. In the on-axis diapir, the MTZ is 50 to 500 m thick and composed of dunite with layered gabbro lenses whereas in the off-axis diapir, the MTZ is thicker and composed of dunite with massive (∼20% of MTZ) clinopyroxenite lenses and a notable absence of plagioclase. Moreover, the off-axis diapir is associated with amphibole-bearing intrusions, consisting of Mg-rich gabbroic sills in the mantle peripheral to the diapir, and microgabbroic lenses of broadly basaltic composition in the overlying crust. The ε Nd values of the pyroxenites in the MTZ of the off-axis diapir fully overlap with those of the intrusions in the surrounding mantle and crust, suggesting that they are genetically related. Calculated rare earth element (REE) abundances of liquids in equilibrium with clinopyroxene imply that the magmas that traversed the MTZ of the off-axis diapir were more depleted in highly incompatible elements than their counterparts in the MTZ of the on-axis diapir. On the other hand, Nd isotopic compositions of the off-axis samples (εNd=6.2–7.9εNd=6.2–7.9 in 18 of 19 samples) indicate derivation of their parental magmas from a less depleted source than that which produced the magma associated with the on-axis gabbro (εNd=7.8–9.2εNd=7.8–9.2, 10 analyses).To explain these observations, we suggest that the earliest magmas in the uprising off-axis diapir formed from the partial melting of pyroxenite veins with less radiogenic Nd isotopic compositions than those of the ambient peridotite. As the diapir traversed the cool, hydrated lithosphere these early melts interacted with depleted harzburgites, lowering the incompatible element contents of the melt products while having little effect on their Nd isotopic compositions. The great abundance of clinopyroxene in the off-axis MTZ might be explained by the high pyroxene component in the original melt but perhaps also by the presence of water in the lithosphere, which would favor the crystallization of clinopyroxene while inhibiting that of plagioclase. The intrusions in the overlying crust could represent, to first order, the secondary melts produced by the melt–harzburgite reaction, while the sills in the surrounding mantle may be cumulates from such secondary melts.These results shed light on processes occurring during interaction between rising off-axis material and depleted, hydrated lithospheric mantle. Furthermore, if our interpretation is correct, the low εNd values of the off-axis samples contribute to the growing body of evidence for the presence of pyroxenite veins in the MORB mantle source.
ISSN: 0012-821X

hal-01306575
https://hal.archives-ouvertes.fr/hal-01306575
DOI : 10.1016/j.epsl.2015.12.005

Éditeur(s) : HAL CCSD Wiley-VCH Verlag
Résumé : International audience
Deciphering the assembly history of the Milky Way is a formidable task, which becomes possible only if one can produce high-resolution chrono-chemo-kinematical maps of the Galaxy. Data from large-scale astrometric and spectroscopic surveys will soon provide us with a well-defined view of the current chemo-kinematical structure of the Milky Way, but will only enable a blurred view on the temporal sequence that led to the present-day Galaxy. As demonstrated by the (ongoing) exploitation of data from the pioneering photometric missions CoRoT, Kepler, and K2, asteroseismology provides the way forward: solar-like oscillating giants are excellent evolutionary clocks thanks to the availability of seismic constraints on their mass and to the tight age-initial-mass relation they adhere to. In this paper we identify five key outstanding questions relating to the formation and evolution of the Milky Way that will need precise and accurate ages for large samples of stars to be addressed, and we identify the requirements in terms of number of targets and the precision on the stellar properties that are needed to tackle such questions. By quantifying the asteroseismic yields expected from PLATO for red-giant stars, we demonstrate that these requirements are within the capabilities of the current instrument design, provided that observations are sufficiently long to identify the evolutionary state and allow robust and precise determination of acoustic-mode frequencies. This will allow us to harvest data of sufficient quality to reach a 10% precision in age. This is a fundamental pre-requisite to then reach the more ambitious goal of a similar level of accuracy, which will only be possible if we have to hand a careful appraisal of systematic uncertainties on age deriving from our limited understanding of stellar physics, a goal which conveniently falls within the main aims of PLATO's core science.
ISSN: 0004-6337

hal-01541393
https://hal.archives-ouvertes.fr/hal-01541393
ARXIV : 1706.3778
BIBCODE : 2017AN....338..644M
DOI : 10.1002/asna.201713385

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Despite the dramatic reductions in children's blood lead levels (BLLs), there is considerable evidence that low-level lead exposure is associated with intellectual deficits and behavioral problems, without apparent threshold. There are limited data, however, about the contribution of residential sources of lead to contemporary children's blood lead levels. The aim of this study is to calculate the contributions of residential sources of lead to assess the potential impact of setting new standards for lead levels in residential dust, soil and water. We enrolled 484 French children aged from 6 months to 6 years, and collected data on social, housing and individual characteristics. Lead concentrations in blood and environmental samples (water, soils, and dusts) were measured using inductively coupled plasma mass spectrometry. Data were analyzed using a multivariate generalized additive model accounting for the sampling design and the sampling weights. We found that exceedingly low concentrations of lead in dust, soil and water were significant predictors of children's BLLs, after adjustment for potential confounding variables. Lead-contaminated floor dust was the main source of lead in blood. BLLs (GM: 14μg/L) increased by 65%, 13%, 25%, and 5% when lead content in floor dust, loose soil, hard soil and water increased from their 25th percentile to their 95th percentile, respectively. We also observed that the steepest increase in BLLs occurred at the lowest levels of lead-contaminated floor dust, which indicates that lead contamination should be kept as low as possible. Impact of different possible standards on children's BLLs was also tabulated and indicated that unless standards are set low, they will only benefit a small proportion of children who have the highest exposures.
ISSN: 1438-4639

inserm-00821999
http://www.hal.inserm.fr/inserm-00821999
DOI : 10.1016/j.ijheh.2013.02.007
PUBMED : 23528234

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Addressing data quality issues in information systems remains a challenging task. Many approaches only tackle this issue at the extract, transform and load steps. Here we define a comprehensive method to gain greater insight into data quality characteristics within data warehouse. Our novel architecture was implemented for an hydroecological case study where massive French watercourse sampling data are collected. The method models and makes effective use of spatial, thematic and temporal accuracy, consistency and completeness for multidimensional data in order to offer analysts a “data quality” oriented framework. The results obtained in experiments carried out on the Saône River dataset demonstrated the relevance of our approach
ISSN: 0098-3004

hal-01223918
https://hal.archives-ouvertes.fr/hal-01223918
https://hal.archives-ouvertes.fr/hal-01223918/document
https://hal.archives-ouvertes.fr/hal-01223918/file/final-cogeo.pdf
DOI : 10.1016/j.cageo.2015.09.012

Éditeur(s) : HAL CCSD Taylor & Francis
Résumé : International audience
Humans may be exposed via their environment to multiple chemicals as a consequence of human activities and use of synthetic products. Little knowledge is routinely generated on the hazards of these chemical mixtures. The metabolomic approach is widely used to identify metabolic pathways modified by diseases, drugs, or exposures to toxicants. This review, based on the state of the art of the current applications of metabolomics in environmental health, attempts to determine whether metabolomics might constitute an original approach to the study of associations between multiple, low-dose environmental exposures in humans. Studying the biochemical consequences of complex environmental exposures is a challenge demanding the development of careful experimental and epidemiological designs, in order to take into account possible confounders associated with the high level of interindividual variability induced by different lifestyles. The choices of populations studied, sampling and storage procedures, statistical tools used, and system biology need to be considered. Suggestions for improved experimental and epidemiological designs are described. Evidence indicates that metabolomics may be a powerful tool in environmental health in the identification of both complex exposure biomarkers directly in human populations and modified metabolic pathways, in an attempt to improve understanding the underlying environmental causes of diseases. Nevertheless, the validity of biomarkers and relevancy of animal-to-human extrapolation remain key challenges that need to be properly explored.
ISSN: 1093-7404

hal-00976116
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00976116
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00976116/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00976116/file/Potential_input_from_metabolomics_accepted.pdf
DOI : 10.1080/10937404.2013.860318

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Prediction of ice mass flow and associated dynamics is pivotal at a time of climate change. Ice flow is dominantly accommodated by the motion of crystal defects – the dislocations. In the specific case of ice, their observation is not always accessible by means of the classical tools such as X-ray diffraction or transmission electron microscopy (TEM). Part of the dislocation population, the geometrically necessary dislocations (GNDs) can nevertheless be constrained using crystal orientation measurements via electron backscattering diffraction (EBSD) associated with appropriate analyses based on the Nye (1950) approach. The present study uses the Weighted Burgers Vectors, a reduced formulation of the Nye theory that enables the characterization of GNDs. Applied to ice, this method documents, for the first time, the presence of dislocations with non-basal or Burgers vectors. These or dislocations represent up to of the GNDs observed in laboratory-deformed ice samples. Our findings offer a more complex and comprehensive picture of the key plasticity processes responsible for polycrystalline ice creep and provide better constraints on the constitutive mechanical laws implemented in ice sheet flow models used to predict the response of Earth ice masses to climate change.
ISSN: 0012-821X

hal-01685565
https://hal.archives-ouvertes.fr/hal-01685565
DOI : 10.1016/j.epsl.2017.06.020

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Spinel lherzolite xenoliths from Mont Briancon, French Massif Central, retain evidence for multiple episodes of melt depletion and melt/fluid infiltration (metasomatism). Evidence for primary melt depletion is still preserved in the co-variation of bulk-rock major elements (MgO 38.7-46.1 wt.%; CaO 0.9-3.6 wt.%), and many samples yield unradiogenic bulk-rock Os isotope ratios (Os-187/Os-188 = 0.11541-0.12626). However, many individual xenoliths contain interstitial glasses and melt inclusions that are not in equilibrium with the major primary minerals. Incompatible trace element mass balance calculations demonstrate that metasomatic components comprise a significant proportion of the bulk-rock budget for these elements in some rocks, ranging to as much as 25%, of Nd and 40% of Sr Critically, for Re-Os geochronology, melt/fluid infiltration is accompanied by the mobilisation of Sulfide. Consequently, bulk-rock isotope measurements, whether using lithophile (e.g. Rb-Sr, Sm-Nd) or siderophile (Re-Os) based isotope systems, may only yield a perturbed and/or homogenised average of these multiple events.;Osmium mass balance calculations demonstrate that bulk-rock Os in peridotite is dominated by contributions from two populations of sulfide grain: (i) interstitial, metasomatic Sulfide with low [Os] and radiogenic Os-187/Os-188, and (ii) primary sulfides with high [Os] and unradiogenic Os-187/Os-188, which have been preserved within host silicate grains and shielded from interaction with transient melts and fluid. The latter can account for >97% of bulk-rock Os and preserve geochronological information of the melt from which they originally precipitated as an immiscible liquid. The Re-depletion model ages of individual primary sulfide grains preserve evidence for melt depletion beneath the Massif Central from at least 1.8 Gyr ago despite the more recent metasomatic event(s). (C) 2009 Elsevier Ltd. All rights reserved.
ISSN: 0016-7037

hal-00454537
https://hal.archives-ouvertes.fr/hal-00454537
DOI : 10.1016/j.gca.2009.09.031

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In fold-and-thrust belts, shortening is mainly accommodated by thrust faults which are preferential zones for recrystallisation and mass transfer. This study focuses on a detachment fault related to the emplacement of the Monte Perdido thrust unit in the southern Pyrenees. The studied fault zone consists of a 10 m thick intensively foliated phyllonite developed within the Millaris marls, of Eocene age. The lithological homogeneity of the hanging wall and footwall allows us to compare the Millaris marls outside the fault zone with the highly deformed marls located in the fault zone and to quantify the chemical, mineralogical and volumetric changes related to deformation processes along the fault. The Millaris marls are composed of detrital quartz, illite, chlorite, minor albite and pyrite, in a micritic calcite matrix. In the fault zone, the cleavage planes are marked by clay minerals and calcite ± chlorite veins attest to fluid-mineral interactions during deformation. The mineral proportions in all samples from both the fault zone and Millaris marls have been quantified by two methods: (1) X-ray diffraction and Rietveld refinement, and (2) bulk chemical analyses as well as microprobe analyses to calculate modal composition. The excellent agreement between the results of these two methods allows us to estimate mineralogical variations using a modification of the Gresens' equation. During fault activation, up to 45 wt% of calcite was lost while the amounts of quartz and chlorite remained unchanged. Illite content remained constant to slightly enriched. The mineralogical variations were coupled with a significant volume loss (up to 45%) mostly due to the dissolution of micritic calcite grains. Deformation was accompanied by pressure solution and phyllosilicates recrystallisation. These processes accommodated slip along the fault. They required fluids as catalyst, but they did not necessitate major chemical transfers.
ISSN: 0264-8172

hal-00976361
https://hal.archives-ouvertes.fr/hal-00976361
DOI : 10.1016/j.marpetgeo.2013.12.016

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
Wadsleyites with various iron contents were synthesized at ~12-14 GPa and 1400 °C under oxidizing and hydrous conditions in coexistence with enstatite. The samples were studied using micro-X-ray absorption near edge structure (XANES) and micro-Mössbauer spectroscopy to determine the ferric iron contents in polyphasic samples and secondary ion mass spectrometry (SIMS) to determine the water concentrations. XANES and Mössbauer analyses show that ferric iron content increases with increasing total iron content, and reaches a maximum of ~30% Fe3+/Fetotal. Two XANES results were cross-checked by Mössbauer analysis and both methods are in reasonable agreement. The use of Fourier transform infrared spectroscopy reveals a new protonation scheme in wadsleyite, with a significant proportion of protons associated with the high-frequency band at 3611 cm−1 and a new band located at 3500 cm−1. The intensity of these two bands is higher for Fe3+-rich wadsleyite. SIMS analyses show that water contents in wadsleyite vary from 4500 to 9400 ppm H2O by weight. Pyroxene water contents range from 790 to 1600 ppm wt H2O. The concentration of water in both phases decreases with increasing iron content. The partition coefficient of water between wadsleyite and pyroxene varies between 5 and 9 and increases with increasing Fe-number of wadsleyite [i.e., XFe/(XFe + XMg) × 100 ratio]. The divalent cation concentrations (i.e., Mg2+ + Fe2+), the Si as well as the H content in wadsleyite decrease with increasing Fe3+ content, indicating an incorporation mechanism via substitution into the metal (Me = Mg2+ and Fe2+) and Si sites with a ratio of 5/3 for (Fe3++H+):Me and of 5/1 for (Fe3++H+):Si, similarly as in the dry system. Thus, coupled substitution of Fe3+ and H+ does not affect the incorporation mechanism of Fe3+, but does affect the location of H+, which is partly incorporated at tetrahedral edges forming [FeSi′-(OH)o*]X neutral defects substituting for Si. In this model 25% of the ferric iron occupies the tetrahedral sites.
ISSN: 0003-004X

hal-00758071
https://hal.archives-ouvertes.fr/hal-00758071
DOI : 10.2138/am.2012.3869