Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
Crystallization experiments were conducted at 200 MPa to determine the effect of small amounts of H2O on the liquidus temperature of basaltic melts in which plagioclase is the liquidus phase. The H2O concentrations in the quenched glasses, determined by infrared spectroscopy and Karl-Fischer titration, ranged from 0.02 to 4.2 wt% H2O. The dry liquidus temperature at 200 MPa was estimated from experiments at 1 atm (H2O-free) and from the known pressure dependence of plagioclase crystallization temperature. The effect of water (expressed as wt% H2O) on the plagioclase liquidus temperature is nonlinear and diminishing with increasing melt H2O concentrations. According to our new experimental data, it can be empirically predicted with following equation: Formula where CH2O is the water concentration in the melt (wt%), TDRY, and TWET are plagioclase crystallization temperatures in water-free and water-bearing systems, respectively. The relationship between CH2O and liquidus temperature worked out in this study is valid for a range of basaltic compositions, ranging from high-alumina basalts to basaltic andesites. The combination of the empirical equation predicting the liquidus depression of plagioclase with previous models predicting the olivine liquidus curve is useful to determine the liquidus temperature in various H2O-bearing basaltic systems in which either plagioclase or olivine is the liquidus phase.
ISSN: 0003-004X

hal-00757600
https://hal.archives-ouvertes.fr/hal-00757600
DOI : 10.2138/am.2012.4100

Éditeur(s) : New York : C. T. Dillingham Boston : Lee and Shepard
Description : Immersion in the history, culture and way of life of the Caribs of the amazing Lesser Antilles.
Siècle(s) traité(s) : 19
Droits : Domaine public
Provenance : Ville de Pointe-à-Pitre. Réseau des bibliothèques
Permalien : http://www.manioc.org/patrimon/PAP11013
PAP11013

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The main goal of the monitoring stage of Carbon Capture and Storage (CCS) is to obtain an accurate estimation of the subsurface CO2 accumulation and to detect any possible leakage. Laboratory experiments are necessary to investigate the small scale processes governing the CO2–brine–rock interaction. They also provide a means to calibrate the results coming from field scale geophysical methods. In this work we set up an experimental system which is able to perform Electrical Resistivity Tomography (ERT) measurements on centimeter-scale rock samples at various P–T conditions. We present the results of two new experiments related to CO2 monitoring, performed on a cylindrical (4 × 8 cm) Fontainebleau rock sample. In the first one, we have quantified the CO2 saturation at different volume fractions, representing zones from a deep saline aquifer with varying degrees of saturation. In the second one, we have monitored and quantified the effect of CO2 dissolution in the brine at a pressure of 40 bar during eight days, emulating the invasion of CO2 into a shallow aquifer. Results highlight the importance of accounting for the contribution of surface conductivity in highly CO2-saturated regions, even in clay-free rocks, and also for brine conductivity variation due to CO2 dissolution. Ignoring any of these effects will end up in a CO2 saturation underestimation. We present a modified CO2 saturation equation to account for these two influences.
ISSN: 0926-9851

hal-01356323
https://hal.archives-ouvertes.fr/hal-01356323
DOI : 10.1016/j.jappgeo.2016.03.039

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Continuous Global Positioning System (CGPS) position time series from eastern North America constrain the pattern and magnitude of regional crustal deformation. Initial analysis delineates consistent uplift patterns, as expected from glacial isostatic adjustment (GIA) predictions, but the associated horizontal deformation is not definitive, in part due to the short time periods for a significant number of the available stations. We employ an eigenpattern decomposition in order to define a unique, finite set of deformation patterns for this continuous GPS data. Similar in nature to the empirical orthogonal functions historically employed in the analysis of atmospheric and oceanographic phenomena, the method derives the eigenvalues and eigenstates from the diagonalization of the correlation matrix using a Karhunen-Loeve expansion (KLE). The KLE technique is used to identify the important modes in both time and space for the CGPS data, modes that potentially include signals such as horizontal and vertical GIA, tectonic strain, and seasonal effects. Here we filter both the vertical and horizontal velocity patterns on different spatiotemporal scales in order to study the potential geophysical sources, after the removal of correlated and random noise. The method is successful in disaggregating the linear vertical signal from more variable and less spatially correlated signals. The vertical and horizontal results are compared to the predictions of the ICE-3G GIA loading model with a number of plausible mantle viscosity profiles. The horizontal velocity analysis allows for qualitative differentiation between several potential GIA models and suggests that, with longer time series, this technique can be employed to remove correlated noise and improve estimates of crustal strain patterns and their sources.
ISSN: 0033-4553

hal-00795454
https://hal.archives-ouvertes.fr/hal-00795454
DOI : 10.1007/s00024-011-0420-1

Éditeur(s) : HAL CCSD
Résumé : In order to minimize CO2 atmospheric concentration, a solution consists in sequestrating CO2 in geological reservoirs. To estimate long term risks, it is necessary to quantify the couplings between reaction processes as well as structural and hydrodynamical modifications. We realised two experimental benches enabling injecting CO2-enriched-brine in conditions corresponding to in situ storage (T < 200 oC and P < 200 bar) and developed
an experimental protocol using X-Ray microtomography and fluid and rock analyses in order to measure the variations of physical and chemical parameters.
The study of carbonated reservoirs near the injection well, allows quantifying different k-phi relationships depending on the dissolution processes and triggered by the local fluid chemical composition and initials conditions. Away from the injection well, we observe carbonate precipitation decreasing the permeability. The study of fracturated caprock samples shows that alternative percolation of CO2-enriched-brine and CO2 gas increases the fracture permeability.
The study of silicated rocks indicates carbonate precipitation in zeolite sandstone and sintered dunite grains. Nevertheless, in zeolite sandstone we also observe the precipitation of clay particles located in the uid pathways which decrease strongly the permeability.
Afin de minimiser la concentration en CO2 dans l'atmosphère une solution consiste à le séquestrer dans les réservoirs géologiques. Pour évaluer les risques à long terme, il est nécessaire de quantifier les couplages entre les processus réactionnels et les modifications structurales et hydrodynamiques. Dans cette optique, nous avons construit deux dispositifs expérimentaux permettant d'injecter des saumures chargées en CO2 dans les conditions de stockage (T < 200 °C et P < 200 bar) et mis en oeuvre un protocole expérimental utilisant la microtomographie RX et l'analyse des roches et des fuides pour quantifier les variations des paramètres physiques et chimiques. Dans le cas des réservoirs carbonatés, on observe, près du puits d'injection, une forte variabilité des relations k-phi en fonction du régime de dissolution contrôlé par la chimie locale du fluide, ainsi que par les conditions initiales. A plus grande distance, on observe des processus de précipitation diminuant fortement la perméabilité. L'étude des roches de couverture fracturées (argilite) a montré qu'une percolation alternée d'une saumure chargée en CO2 et de CO2 gaz augmentait la perméabilité de fracture. Dans le cas des roches silicatées, la précipitation de carbonates est mise en évidence aussi bien dans les grès à zéolites que dans les frittés de dunite de San Carlos. Cependant, dans les grès à zéolites, la précipitation d'une phase argileuse est observée dans les chemins d'écoulement et engendre une forte diminution de la perméabilité.
https://tel.archives-ouvertes.fr/tel-00416408

tel-00416408
https://tel.archives-ouvertes.fr/tel-00416408
https://tel.archives-ouvertes.fr/tel-00416408/document
https://tel.archives-ouvertes.fr/tel-00416408/file/These_Luquot.pdf

Éditeur(s) : Paris : l'auteur
Siècle(s) traité(s) : 20
Provenance : Archives départementales de Guadeloupe
Permalien : http://www.manioc.org/patrimon/ADG18218
ADG18218

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
This paper investigates the orientation and sources of stress in the forearc of the Cascadia subduction zone in southwest British Columbia, using Bayesian inversion results from focal mechanism data and comparing results with GPS derived short-term strain rates. The subduction margin in this region includes a change in orientation from N-S in Washington State to NW-SE in British Columbia. Over 1000 focal mechanisms from North American crustal earthquakes have been calculated to identify the dominant style of faulting, and ∼600 were inverted to estimate the principal stress orientations and the stress ratio. Our results indicate the maximum horizontal compressive stress orientation changes with distance to the trench, from approximately margin-normal along the coast to approximately margin-parallel 100-150 km inland from the coast. Comparing stress orientations with GPS data, we relate the margin-normal stress direction to subduction-related strain rates due to the locked interface between the North American and Juan de Fuca plates just west of Vancouver Island. Further from the margin the plates are coupled less strongly, and the margin-parallel maximum horizontal compressive stress in the North American Plate relates to the northward push of the Oregon Block, which is also observed in the horizontal shortening direction of the residual strain rates, after the subduction component is removed.
ISSN: 0148-0227

hal-00853734
https://hal.archives-ouvertes.fr/hal-00853734
DOI : 10.1029/2010JB008003

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We present GravProcess, a set of MATLAB routines to process gravity data from complex campaign surveys and calculate the associated gravity field. Data reduction, analysis, and representation are done using the MATLAB Graphical User Interface Tool, which can be installed on most systems and platforms. Data processing is divided into several steps: (1) Integration of gravity data, station location, and gravity line connection input files; (2) Gravity data reduction applying solid-Earth tide and instrumental drift corrections and, depending on the required processing level, air pressure and oceanic tidal corrections; (3) Automatic network adjustment and alignment to absolute base stations; (4) Free air and terrain corrections to calculate gravity values and anomalies, and to estimate the associated errors. The final step is dedicated to post-processing and includes graphical representations of data and an output text file, which can be used by Geographic Information System software. An example of this processing chain applied to a recent survey in northern Morocco is given and compared with previous available results.
ISSN: 0098-3004

hal-01217120
https://hal.archives-ouvertes.fr/hal-01217120
DOI : 10.1016/j.cageo.2015.04.005

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In order to estimate the seismic anisotropy of subducted crust, polycrystalline samples of KA1Si(3)O(8) K-lingunite (25% of the total subducted transformed sediments), have been synthesized and deformed under the temperature and pressure conditions of the subducted slabs. Transmission electron microscopy (TEM) characterizations of the recovered samples reveal that the microstructures are clearly dominated by [001] glide involving screw dislocations. For this reason, only {100} could be identified as glide planes, the question of [001] slip on {110} remains open. Few 1/2 < 111 > dislocations were observed gliding on {110} planes, which implies that 1/2 < 111 > {110} is a harder slip system than those involving [001] slip. The occurrence of sub-grain boundaries suggests that diffusion and climb might be active under these conditions.;To assess the texture of polycrystalline K-lingunite, the crystal preferred orientations (CP05) were calculated using visco-plastic self-consistent (VPSC) polycrystalline plasticity model in simple shear using the slip systems identified by TEM. Finally, the seismic properties of K-lingunite aggregates were calculated from the CPO and single crystal elasticity tensor. K-lingunite is predicted to have a high seismic anisotropy, which could combine constructively with one of the stishovite (same proportion as K-lingunite at the transition zone depth ranges).
ISSN: 0031-9201

hal-00534050
https://hal.archives-ouvertes.fr/hal-00534050
DOI : 10.1016/j.pepi.2010.06.013

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Synkinematic phyllosilicates in fault zones can be used to deduce the deformation mechanisms and the conditions of fault activity, as their chemical composition, crystal structure and texture can record the different stages of deformation and fluid-rock interactions. The Pic de Port Vieux, a second-order thrust related to the major Gavarnie thrust in the southern central part of the Pyrenees Axial Zone, juxtaposes Triassic pelites of the hanging wall and Cretaceous limestones of the footwall. In order to investigate the mineralogical and geochemical changes and constrain the deformation conditions of thrusting, characterization of phyllosilicates was performed along a transect in the fault hanging wall pelites. The Triassic pelites are mainly composed of quartz, calcite, phyllosilicates (chlorite and K-white mica) and ± hematite. The core fault zone thickness is estimated to be about one meter of intensively foliated green pelites, whereas the damage zone is composed of several meters of red pelites. XRD data demonstrated that the difference in color is related to hematite which is only present in the damage zone. Phyllosilicates of the damage zone are mainly inherited/diagenetic K-white mica and chlorite. In the core zone, newly formed chlorite is abundant and preferentially located in veins. It is enriched in Fe compared to the chlorite of the red pelites. The well-defined foliation in the core zone is overlaid by preferentially oriented muscovite grains which have homogeneous compositions, with less Na and relatively more Fe than mica from the red pelites. Newly formed chlorite and muscovite in the core zone are synkinematic to the fault activity. They are both related to deformation processes and fluid rock interactions. Kübler index measurements and chlorite thermometry show that synkinematic phyllosilicates have registered a temperature of 270°C ± 23°C for the damage zone and 285°C ± 28°C for the core zone which are corresponding to lower-anchizone/epizone grade conditions. Numerical modelling with the geochemical modelling program PhreeqC was performed to determine the favorable conditions for the mineralogical change between red and green pelites. It suggests that the main critical parameter favoring hematite dissolution and chlorite precipitation in the core zone, is the redox conditions. According to the model, the chemical changes in the core zone occurred due to interactions with highly reductive fluids. In addition, the hematite dissolution maybe the source of iron for newly formed phyllosilicates in the core zone that are more iron rich compared to those from the red pelites.
ISSN: 0169-1317

hal-01536006
https://hal.archives-ouvertes.fr/hal-01536006
DOI : 10.1016/j.clay.2017.05.008

Éditeur(s) : Paris : Firmin Didot Frères

Droits : Domaine public
Provenance : Archives territoriales de Guyane
Permalien : http://www.manioc.org/patrimon/GAD12001
GAD12001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Northwest Iran is characterized by a high level of historical and instrumental seismicity related to the ongoing convergence between the Arabian and Eurasian plates. In this region, the main right-lateral strike-slip fault known as the North Tabriz fault (NTF) forms the central portion of a large crustal fault system called the Tabriz fault system (TFS). The NTF is a major seismic source along which at least three strong and destructive earthquakes have occurred since 858 AD. The two most recent destructive seismic events occurred in 1721 AD and 1780 AD, rupturing the SE and NW fault segments, respectively. This paper reports paleoseismological and quantitative geomorphologic investigations on the SE segment of the NTF, between the cities of Bostanabad and Tabriz. These observations help to improve our understanding of the seismic hazard for Tabriz city and its surrounding areas. Our field investigations revealed evidence of successive faulting events since the Late Quaternary. Paleoseismic investigations indicate that since 33.5 kyr, the SE segment of the NTF has experienced at least three major (M>7.5) seismic events, including the 1721 AD earthquake (M=7.6–7.7). Along the NW segment of the fault, however, our results suggest that the amount of strong (M~7.5) seismic events during the same period is significantly greater than along the SE segment. One possible explanation of such a difference in seismic activity is that the Late Quaternary-Holocene coseismic slip rate is decreasing along the NTF from the northwest to the southeast. This explanation contradicts the former hypothesis of a constant slip rate along the whole length of the NTF. In addition, more distributed deformation along several parallel fault branches, in a wider fault zone of the SE segment of the NTF may be considered as additional evidence for the estimation of lower rate of deformation along the fault segment. Such a slip distribution pattern can explain the existence of smaller (~300 m) Pliocene-Quaternary cumulative dextral offsets along the SE fault segment than the measured cumulative offsets along the NW segment (~800 m) of the NTF.
ISSN: 0040-1951

hal-01089420
http://hal.upmc.fr/hal-01089420
http://hal.upmc.fr/hal-01089420/document
http://hal.upmc.fr/hal-01089420/file/Solaymani%20Azad%20et%20al.%2C%202014%20%28accepted%29.pdf
DOI : 10.1016/j.tecto.2014.11.010

Éditeur(s) : Bordeaux : Charles Lawalle
Siècle(s) traité(s) : 19
Droits : Domaine public
Provenance : Archives départementales de Guadeloupe
Permalien : http://www.manioc.org/patrimon/ADG18145
ADG18145

Éditeur(s) : Paris : Baudouin
Siècle(s) traité(s) : 18
Droits : Domaine public
Provenance : Collectivité territoriale de Guyane. Bibliothèque Alexandre-Franconie
Permalien : http://www.manioc.org/patrimon/HASH43ad1e21867b317547541e
HASH43ad1e21867b317547541e