Éditeur(s) : Springer
Résumé : We present the global general circulation model IPSL-CM5 developed to study the long-term response of the climate system to natural and anthropogenic forcings as part of the 5th Phase of the Coupled Model Intercomparison Project (CMIP5). This model includes an interactive carbon cycle, a representation of tropospheric and stratospheric chemistry, and a comprehensive representation of aerosols. As it represents the principal dynamical, physical, and bio-geochemical processes relevant to the climate system, it may be referred to as an Earth System Model. However, the IPSL-CM5 model may be used in a multitude of configurations associated with different boundary conditions and with a range of complexities in terms of processes and interactions. This paper presents an overview of the different model components and explains how they were coupled and used to simulate historical climate changes over the past 150 years and different scenarios of future climate change. A single version of the IPSL-CM5 model (IPSL-CM5A-LR) was used to provide climate projections associated with different socio-economic scenarios, including the different Representative Concentration Pathways considered by CMIP5 and several scenarios from the Special Report on Emission Scenarios considered by CMIP3. Results suggest that the magnitude of global warming projections primarily depends on the socio-economic scenario considered, that there is potential for an aggressive mitigation policy to limit global warming to about two degrees, and that the behavior of some components of the climate system such as the Arctic sea ice and the Atlantic Meridional Overturning Circulation may change drastically by the end of the twenty-first century in the case of a no climate policy scenario. Although the magnitude of regional temperature and precipitation changes depends fairly linearly on the magnitude of the projected global warming (and thus on the scenario considered), the geographical pattern of these changes is strikingly similar for the different scenarios. The representation of atmospheric physical processes in the model is shown to strongly influence the simulated climate variability and both the magnitude and pattern of the projected climate changes.
Climate Dynamics (0930-7575) (Springer), 2013-05 , Vol. 40 , N. 9-10 , P. 2123-2165

Droits : The Author(s) 2013. This article is published with open access at Springerlink.com
http://archimer.ifremer.fr/doc/00138/24966/23079.pdf
DOI:10.1007/s00382-012-1636-1
http://archimer.ifremer.fr/doc/00138/24966/

Éditeur(s) : HAL CCSD Geological Society of America
Résumé : If the net flux to the island arc crust is primitive arc basalt, the evolved composition of most arc magmas entails the formation of complementary thick ultramafic keels at the root of the island arc crust. Dunite, wehrlite, and Cr-rich pyroxenite from the Jijal complex, constituting the Moho transition zone of the Kohistan paleo–island arc (northern Pakistan), are often mentioned as an example of high-pressure cumulates formed by intracrustal fractionation of mantle-derived melts, which were later extracted to form the overlying mafic crust. Here we show that calculated liquids for Jijal pyroxenites-wehrlites are strongly rare earth element (REE) depleted and display flat or convex-upward REE patterns. These patterns are typical of boninites and are therefore unlike those of the overlying mafic crust that have higher REE concentrations and are derived from light rare earth element (LREE)–enriched melts similar to island arc basalt. This observation, along with the lower 208Pb/204Pb and 206Pb/204Pb ratios of Jijal pyroxenites-wehrlites relative to gabbros, rejects the hypothesis that gabbros and ultramafic rocks derive from a common melt via crystal fractionation. In the 208Pb/204Pb versus 206Pb/204Pb diagram, ultramafic rocks and gabbros lie on the same positive correlation, suggesting that their sources share a common enriched mantle 2 (EM2) signature but with a major depleted component contribution for the ultramafic rocks. These data are consistent with a scenario whereby the Jijal ultramafic section represents a Moho transition zone formed via melt-rock reaction between subarc mantle and incoming melt isotopically akin to Jijal gabbroic rocks. The lack in the Kohistan arc of cogenetic ultramafic cumulates complementary to the evolved mafic plutonic rocks implies either (1) that a substantial volume of such ultramafic cumulates was delaminated or torn out by subcrustal mantle flow from the base of the arc crust in extraordinarily short time scales (0.10–0.35 cm/yr), or (2) that the net flux to the Kohistan arc crust was more evolved than primitive arc basalt.
ISSN: 0091-7613

hal-00406688
https://hal.archives-ouvertes.fr/hal-00406688
DOI : 10.1130/G23675A.1

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Although magmatism may occur during the earliest stages of continental rifting, its role in strain accommodation remains weakly constrained by largely 2-D studies. We analyze seismicity data from a 13 month, 39-station broadband seismic array to determine the role of magma intrusion on state-of-stress and strain localization, and their along-strike variations. Precise earthquake locations using cluster analyses and a new 3-D velocity model reveal lower crustal earthquakes beneath the central basins and along projections of steep border faults that degas CO2. Seismicity forms several disks interpreted as sills at 6-10 km below a monogenetic cone field. The sills overlie a lower crustal magma chamber that may feed eruptions at Oldoinyo Lengai volcano. After determining a new ML scaling relation, we determine a b-value of 0.87±0.03. Focal mechanisms for 65 earthquakes, and 13 from a catalogue prior to our array reveal an along-axis stress rotation of ∼60° in the magmatically active zone. New and prior mechanisms show predominantly normal slip along steep nodal planes, with extension directions ∼N90°E north and south of an active volcanic chain consistent with geodetic data, and ∼N150°E in the volcanic chain. The stress rotation facilitates strain transfer from border fault systems, the locus of early-stage deformation, to the zone of magma intrusion in the central rift. Our seismic, structural, and geochemistry results indicate that frequent lower crustal earthquakes are promoted by elevated pore pressures from volatile degassing along border faults, and hydraulic fracture around the margins of magma bodies. Results indicate that earthquakes are largely driven by stress state around inflating magma bodies.
ISSN: 1525-2027

hal-01667198
https://hal.archives-ouvertes.fr/hal-01667198
DOI : 10.1002/2017GC007027

Éditeur(s) : HAL CCSD
International statistical ecology conference 2014
Montpellier, France

hal-01503286
https://hal-agroparistech.archives-ouvertes.fr/hal-01503286

Éditeur(s) : HAL CCSD Taylor & Francis
Résumé : Modern geochronology has moved beyond the acquisition of dates: the goal is to understand the significance of these numbers for the geodynamic evolution of Earth at all scales. The coupling of the laser-ablation microprobe (LAM) to inductively coupled plasma mass spectrometers (ICPMS, multicollector (MC)-ICPMS) has revolutionised geochronology and geochemistry over the last 10 years. These systems enable the rapid and precise in situ analysis of trace-element patterns and isotopic systems, while adding information related to microstructural context and major-element composition. The integration of these multiple sources of data is crucial in constraining the origin of the sample and the processes leading to its formation, so that we can understand the meaning of a date in terms of geological events. LAM-ICPMS measurement of U-Pb ages and trace-element patterns in zircon, coupled with LAM-MC-ICPMS analysis of Hf isotopes in the same grains, gives new insights into the processes of magma genesis. Applied to detrital zircons from modern drainages or sedimentary rocks (the TerraneChron approach), it becomes a powerful tool to investigate problems of crustal evolution on scales ranging from single terranes to continents. The in situ analysis (LAM-MC-ICPMS) of Re-Os systematics in single grains of sulfides in mantle-derived peridotites has demonstrated that most mantle rocks contain several generations of Os-bearing sulfides; whole-rock analyses are mixtures reflecting multiple melting and metasomatic events in the lithospheric mantle. These deep-seated events are commonly mirrored in the crust; Os model-age spectra from xenolith suites show age 'peaks' that correspond to the ages of thermal/tectonic events in the overlying crust, suggesting strong linkages between crust and mantle. Integrated studies of the timing and nature of crustal and mantle events, using these techniques, will be important for understanding the large-scale dynamics of the Earth.
ISSN: 0812-0099

hal-00411328
https://hal.archives-ouvertes.fr/hal-00411328
DOI : 10.1080/08120090802097450

Éditeur(s) : HAL CCSD
Résumé : International audience
Up-to-date estimates of the health outcomes of preterm children are needed for assessing perinatal care, informing parents, making decisions about care, and providing evidence for clinical guidelines. To determine survival and neonatal morbidity of infants born from 22 through 34 completed weeks' gestation in France in 2011 and compare these outcomes with a comparable cohort in 1997. The EPIPAGE-2 study is a national, prospective, population-based cohort study conducted in all maternity and neonatal units in France in 2011. A total of 2205 births (stillbirths and live births) and terminations of pregnancy at 22 through 26 weeks' gestation, 3257 at 27 through 31 weeks, and 1234 at 32 through 34 weeks were studied. Cohort data were collected from January 1 through December 31, 1997, and from March 28 through December 31, 2011. Analyses for 1997 were run for the entire year and then separately for April to December; the rates for survival and morbidities did not differ. Data are therefore presented for the whole year in 1997 and the 8-month and 6-month periods in 2011. Survival to discharge and survival without any of the following adverse outcomes: grade III or IV intraventricular hemorrhage, cystic periventricular leukomalacia, severe bronchopulmonary dysplasia, retinopathy of prematurity (stage 3 or higher), or necrotizing enterocolitis (stages 2-3). A total of 0.7% of infants born before 24 weeks' gestation survived to discharge: 31.2% of those born at 24 weeks, 59.1% at 25 weeks, and 75.3% at 26 weeks. Survival rates were 93.6% at 27 through 31 weeks and 98.9% at 32 through 34 weeks. Infants discharged home without severe neonatal morbidity represented 0% at 23 weeks, 11.6% at 24 weeks, 30.0% at 25 weeks, 47.5% at 26 weeks, 81.3% at 27 through 31 weeks, and 96.8% at 32 through 34 weeks. Compared with 1997, the proportion of infants surviving without severe morbidity in 2011 increased by 14.4% (P < .001) at 25 through 29 weeks and 6% (P < .001) at 30 through 31 weeks but did not change appreciably for those born at less than 25 weeks. The rates of antenatal corticosteroid use, induced preterm deliveries, cesarean deliveries, and surfactant use increased significantly in all gestational-age groups, except at 22 through 23 weeks. The substantial improvement in survival in France for newborns born at 25 through 31 weeks' gestation was accompanied by an important reduction in severe morbidity, but survival remained rare before 25 weeks. Although improvement in survival at extremely low gestational age may be possible, its effect on long-term outcomes requires further studies. The long-term results of the EPIPAGE-2 study will be informative in this regard.
ISSN: 2168-6211

hal-01258705
http://hal.univ-brest.fr/hal-01258705
PUBMED : 25621457
DOI : 10.1001/jamapediatrics.2014.3351

Éditeur(s) : HAL CCSD Elsevier
Résumé : This contribution reports our preliminary work to determine Cu isotope ratios for various granite rocks and examine the Cu isotope systematics within granite suites. A chemical procedure, modified from Marechal [Marechal, C.N., Telouk, R and Albarede, F., 1999. Precise analysis of copper and zinc isotopic compositions by plasma-source mass spectrometry. Chemical Geology, 156(1-4): 251-273.], Was used to separate Cu from rock matrix. Quantitative recovery (100.6 +/- 1.6%), with a low total procedural blank (2.65 +/- 0.66 ng) for Cu, has been achieved, allowing Cu isotopic measurements on samples with as little as 10 ppm Cu. The Cu isotope ratios (delta Cu-65 relative to NIST SRM 976) of 32 rock samples, ranging from mafic to felsic compositions, from 3 batholiths (2 I-type, 1 S-type) from the Lachlan Fold Belt in southeastern Australia. vary from -0.46 parts per thousand to 1.51 parts per thousand. Most of them cluster around zero, With mean values for the I-type and S-type granites of 0.03 +/- 0.15 parts per thousand and - 0.03 +/- 0.42 parts per thousand (2 sigma) respectively. These data, together with Cu isotope ratios of two loess samples, provide preliminary evidence that the baseline Cu isotopic composition of the crystalline part of upper continental crust is close to zero. The tight clustering of Cu isotope ratios of rocks from the I-type suites Suggests that high-temperature magmatic processes do not produce significant Cu isotope fractionation. However, two granites with abnormally heavy Cu isotope signatures (up to 1.51 parts per thousand) appears to be the result of localized hydrothermal alteration. Measurable variation in Cu isotopic composition of the S-type granite may reflect isotopic heterogeneity in the sedimentary Source region as a result of redox processes or may be due to hydrothermal overprinting. Thus, Cu isotope geochemistry may be a useful tracer for studying hydrothermal alteration and Source heterogeneity of granitic rocks.
ISSN: 0009-2541

hal-00413130
https://hal.archives-ouvertes.fr/hal-00413130
DOI : 10.1016/j.chemgeo.2008.06.047

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The processes active in the deep crust above an oceanic subduction zone during its evolution have been constrained through a detailed geochemical study (major and trace elements and Sr, Nd and Pb isotopes) of representative samples through an 30 km thick exhumed crustal section of the Cretaceous Kohistan oceanic island arc (Northern Pakistan). The use of both trace elements and radiogenic isotopes reveals two distinct geochemical suites (suites A and B) within the JijalPatanKiruKamila (JPKK) complex. Suite A is characterized by a progressive enrichment in Pb-207 and a decrease in Nd-143/Nd-144 with increasing La-N/Sm-N. Suite B has higher Pb-207/Pb-204 and lower Nd-143/Nd-144 ratios with approximately constant La-N/Sm-N. By combining trace elements with different partitioning behaviour it is demonstrated that there is an increasing contribution of the subduction component in the magmas with time. It is also possible to distinguish a slab component imprint carried by aqueous fluids from one corresponding to sediment melts. Intrusive granites are abundant in the upper levels of the JPKK section. All were generated at the arc root level (Jijal crustal section) during dehydration-melting of hornblende-rich plutonic rocks. A three-stage geodynamic model is proposed for the evolution of the arc over a period of 30 Myr. The first stage (117105 Ma) starts with the onset of subduction, which was followed by the building of the volcanic arc. The second stage (10599 Ma to 9691 Ma) corresponds to a major igneous event, which was characterized by abundant magma underplating and granulite-facies metamorphism at the arc base. Recycling of the residualcumulative lower crust into the convective asthenospheric mantle was efficient during this stage, and was probably related to thermo-mechanical erosion of the base of the crust. The last stage (9585 Ma) corresponds to a period of low magmatic activity, which marked the end of the intra-oceanic subduction. This is related to the formation of a cold blanket above the slab surface as a result of thermo-mechanical erosion of the cold walls of the subduction zone (i.e. the upper part of the slab and the base of the overriding plate), and corner flow dragging the cold material into the zone of melt generation. Ultimately, a voluminous magmatic pulse occurred around 85 Ma (forming the Chilas complex), before arccontinent collision.
ISSN: 0022-3530

hal-00420068
https://hal.archives-ouvertes.fr/hal-00420068
DOI : 10.1093/petrology/egp010

Éditeur(s) : HAL CCSD IWA Publishing
Résumé : International audience
This study proposes a new approach for improving resource quality management, monitoring and treatment plant management, whatever the environmental and climatic stressors. First trend analysis of water quality at a river basin scale, based on historical water quality data and multivariate exploitation (principal component analysis, PCA), led to a classification of the monitoring stations with regard to the main pressures (land use, urbanization and hydroclimatic impacts). This method was applied to the Vilaine's watershed, the largest river basin in Brittany, western France, and one which is under agricultural and urban pressure. A complementary research using a UV index was proposed for the evaluation of spatial and temporal variations of water quality. This approach may be considered as a useful and relevant tool to quickly assess the variation of water quality and the main explanatory factors. It also points out monitoring stations under specific stressors considered as outliers regarding UV parameters. Finally, PCA and UV index give complementary results. PCA allows factors influencing drinking water resource to be highlighted and the UV index allows global water quality under specific times and impacts to be reflected.
Water Science and Technology: Water Supply

hal-00878159
https://hal.archives-ouvertes.fr/hal-00878159
DOI : 10.2166/ws.2012.047

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Borborema Province of northeastern Brazil is divided into three main domains: northern, central, and southern. Several U-Pb zircon ages of plutons and orthogneisses became available in the recent years in the central and northern domains, but similar results are scarce in the southern domain. This study reports U-Pb dates for single zircon grains from one orthogneiss (Jupi orthogneiss) and two plutons (Cachoeirinha syenitic pluton and Cabanas granite) south of the East Pernambuco shear zone system (EPSZ). The results provide geochronological constraints on the timing of deformation and magmatism in this part of the southern domain and allow correlations with the central domain. The Jupi orthogneiss was emplaced and deformed during development of the regional flat-lying foliation. A Pb-206/U-238 weighted apparent mean age of 606 +/- 8 Ma is interpreted as the crystallization age of the protolith of the orthogneiss and consequently the age of high-grade Brasiliano metamorphism. The NNE-trending Cachoeirinha pluton is only locally affected by strike-slip deformation, whereas the ENE-trending Cabanas granite is intensely affected by deformation related to the EPSZ. The 587 8 Ma and 573 4 Ma ages of the Cachoeirinha pluton and Cabanas granite, respectively, bracket the main period of activity of the EPSZ. Tectonomagmatic activity in the study area is similar to the age of Brasiliano events in the central domain, north of the EPSZ. In addition, xenocrystic zircons in the Jupi orthogneiss and Cabanas granite are interpreted as inherited from Paleoproterozoic source rocks, suggesting the presence of widespread reworked old crust in the southern domain, similar to the central domain. These results support the idea that the central and southern domains belonged to the same crustal block before the onset of the Brasiliano orogeny.
ISSN: 0895-9811

hal-00411394
https://hal.archives-ouvertes.fr/hal-00411394
DOI : 10.1016/j.jsames.2007.06.003

Éditeur(s) : HAL CCSD Water Quality Research Journal of Canada
Résumé : International audience
The adsorption of some major pharmaceutical products (sulfamethoxazole, caffeine, iopromide and carbamazepine) in water was evaluated using four types of activated carbon, three powdered activated carbon (PAC) and one fluidized, coagulated and flocculated activated carbon (FAC) extracted from a Carboplus®P pilot. These substances were the most frequently quantified (in 50% of samples at least) in surface waters of the Vilaine's basin (Brittany, France) during three sampling campaigns. Jar test experiments were carried out in order to assess the removal efficiency of the four activated carbons. Carbamazepine and caffeine were well removed with PAC with a maximum removal rate of 80% whereas it was more difficult for sulfamethoxazole and iopromide with a maximum of 39%. For each molecule, removal rates are clearly dependent on PAC nature. The overall results with FAC are clearly distinguishable from PAC tests with gains of performance on all target molecules (from 80 to >95%).
Water Quality Research Journal of Canada

hal-00878098
https://hal.archives-ouvertes.fr/hal-00878098
DOI : 10.2166/wqrjc.2013.138

Éditeur(s) : HAL CCSD
Résumé : International audience
Two opposing visions of the Aegean backarc tectonics implicitly contain contrasting images of the rheological behaviour of the lihosphere, supported by different sets of observations. The propagation of the NAF and extension in the Corinth Rift suggest a strongly localising rheology whereas the formation of MCC in the Cyclades and the Rhodope suggests instead a more viscous behaviour. This paradox was the seminal question addressed by the ANR-EGEO programme (2007-2010) that leads to the following conclusions: (1) The exhumation of the Cycladic MCC's is accommodated by the N-dipping North Cycladic Detachment System (NCDS) that partly reworks the Vardar suture and at the base by a series of thrusts, including the basal contact of the Cycladic Blueschists (CBS) over the Cycladic Basement (CB). The activity of LANF is due to the reactivation of pre-existing discontinuities such as thrusts or earlier detachments and much less to the interaction with granitic plutons. (2) Exhumation in the Cyclades has proceeded in two stages: (a) Eocene syn-orogenic exhumation within the subduction lower/upperplate interface while the post-orogenic Rhodope MCC formed further north, (b) Oligo-Miocene post-orogenic extension in an MCC mode coeval with syn-orogenic exhumation in Crete and the Peloponnese. (3) Both stages were associated with slab retreat, as early as the Eocene with an acceleration at 30-35 Ma. (4) The localisation of the presently active steeply-dipping normal faults on the southern margin of the Corinth Rift may have been preceded by a partial reworking of thrusts and syn-orogenic detachments by shallow-dipping decollements. (5) The localisation of the NAF in the Marmara Sea region and the Northern Aegean Sea is now accurately dated between 5.3 and 5 Ma Ma using the erosion and deposition surfaces that mark the Messinian salinity Crisis and nannofossils ages. (6) The formation of MCCs in the Cyclades resulted in the draining of the low viscosity lower crust from the northern Aegean Sea and led to an easier coupling between upper mantle and upper crust, easing the localisation and propagation of the NAF. (7) A comparison between crustal and mantle finite strain suggests that mantle flow due to slab retreat controls the stretching of the crust. Our model involves progressive slab retreat and mantle flow below the overriding plate inducing the observed succession of tectonic episodes with a progressive localisation of extension due to several slab tearing events. There is no paradox in the tectonic history and rheological behaviour of the Aegean lithosphere but an evolution of the kinematic boundary conditions due to slab deformation at depth.
American Geophysical Union
San Francisco, United States

insu-00860518
https://hal-insu.archives-ouvertes.fr/insu-00860518
BIBCODE : 2010AGUFM.T13G..04J

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Intraplate deformation is most often linked to major stress applied on plate margins. When such intraplate events are accompanied by magmatism, the use of several dating methods integrated within a multidisciplinary approach can bring constraints on the age, nature and source mobilized for generating the magma and in turn on the nature of the intraplate deformation. This study focuses on the large gabbro Arrikine sill (35 km in extension) emplaced within the Silurian sediments of the western margin of the Murzuq cratonic basin in southeastern Algeria. Its emplacement is dated during the early Devonian (415-400 Ma) through the determination of a reliable paleomagnetic pole by comparison with the Gondwana Apparent Polar Wander Path (APWP). This age can be correlated with deep phreatic eruptions before Pragian time thought to be at the origin of sand injections and associated circular structures in Algeria and Libya. For the sill, the K–Ar age of 325.6 ± 7.7 Ma is related to a K-rich aplitic phase that has K-enriched by more than 20% the Devonian gabbro. Laser-ICP-MS U–Pb method dates only inherited zircons mostly at c. 2030 Ma with additional ages at c. 2700 Ma and younger ones in the 766-598 Ma age range. The Arrikine sill is a high-Ti alkaline gabbro having the geochemical composition of a hawaiite akin to several intraplate continental and oceanic provinces, including the contemporaneous Aïr ring complexes province in Niger, but also to the Mauna Loa volcano in Hawaii. This peculiar composition akin to that of the contemporaneous Aïr province is in agreement with a lower Devonian age for the Arrikine sill.The lower Devonian Arrikine sill emplacement is related to a “Caledonian” transtensive reactivation of the western metacratonic boundary of the Murzuq craton. This event also generated in the Saharan platform the so-called “Caledonian unconformity” of regional extension, the Aïr ring complexes and magmatic rocks that produced sand injections. It could be related to rifting of the Hun terranes that occurred at the plate margin to the north (Stampfli and Borel, 2002, Blackey, 2008 and references therein). The mid-Carboniferous (c. 326 Ma) reactivation corresponds to Variscan compression on NW Africa generating aplitic fluids, but also to the major “Hercynian unconformity” of regional extension. The generation of the Arrikine magma is attributed to partial melting through adiabatic pressure release of uprising asthenosphere along tectonically reactivated mega-shear zones, here bordering the relictual Murzuq craton enclosed in the Saharan metacraton.
ISSN: 0899-5362

hal-01306637
https://hal.archives-ouvertes.fr/hal-01306637
DOI : 10.1016/j.jafrearsci.2015.11.019

Éditeur(s) : HAL CCSD Elsevier
Résumé : The ultramafic–mafic complexes located at the base of obducted paleo-island arcs are commonly interpreted as evidence for intra-crustal fractionation of primitive (high-Mg#) mantle melts. The present study, realized on the Jijal mafic–ultramafic basal section of the Cretaceous Kohistan oceanic arc (N Pakistan), discards a crystal fractionation model from a single parental magma to take into account the geochemical and isotope variations observed between the plutonic crust and the underlying ultramafic section. The basal ultramafic rocks, i.e. dunites, wehrlites and clinopyroxenites, show high Mg#, extremely depleted REE patterns, no marked HFSE anomalies and high LILE enrichment. Cpx and leached whole rocks from this unit yield restricted εNd values (+ 5.5 to + 6.8), a large εSr range (− 5.9 to + 8.8) and mainly radiogenic 207Pb/204Pb ratios. The overlying mafic section, i.e. gabbroic rocks, displays low Mg# (46 < Mg# < 54), enriched REE patterns and marked HFSE anomalies. These plutonic rocks have also very homogeneous Sr and Pb isotopic compositions defining a restricted domain, which does not overlap that of the ultramafic samples. Moreover, Cpx from the basal ultramafics yield an Sm–Nd isochron at 117 ± 7 Ma interpreted as dating crystallization of the ultramafic section. Together, these results indicate that the mafic rocks on one hand and the ultramafic rocks on the other hand, originate from separate sources with specific emplacement underneath the subduction zone. A lherzolite lens, collected from the top of the mafic section, plots on the early Cretaceous Sm–Nd isochron and therefore yields the same 143Nd/144Nd initial ratio. This suggests that the ultramafic part of the lower Kohistan arc complex sampled the initiation stages of the subduction with production of magmas with boninite-like features. At this stage, the mantle wedge has been already modified by percolation of the first slab-derived fluids. On such a scenario the lherzolite lens would correspond to the lithospheric mantle underneath the arc before its initiation. A multi-stage history is proposed for the evolution for the Kohistan arc through not, vert, similar 30 Ma. Stage #1 reflects the spontaneous initiation of subduction associated with extensive boninitic affinity magmatism, stages #2 and #3 are related to arc building by tholeiitic melts and, a fourth step (stage #4) corresponds to the intra-crustal differentiation.
ISSN: 0012-821X

hal-00407206
https://hal.archives-ouvertes.fr/hal-00407206
DOI : 10.1016/j.epsl.2007.06.026

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
An inter-laboratory exercise was organized under the PHARMAS EU project, by the Advanced School of Public Health (EHESP), in order to evaluate the performances of analytical methods for the measurement of antibiotics in waters (surface and tap). This is the first time such an exercise on antibiotics has been organized in Europe, using different kinds of analytical methods and devices. In this exercise thirteen laboratories from five countries (Canada, France, Italy, the Netherlands and Portugal) participated, and a total number of 78 samples were distributed. During the exercise, 2 testing samples (3 bottles of each) prepared from tap water and river water, respectively, spiked with antibiotics, were sent to participants and analyzed over a period of one month. A final number of 77 (98.7%) testing samples were considered. Depending on substances studied by each participant, 305 values in duplicate were collected, with the results for each sample being expressed as the target concentration. A statistical study was initiated using 611 results. The mean value, standard deviation, coefficient of variation, standard uncertainty of the mean, median, the minimum and maximum values of each series as well as the 95% confidence interval were obtained from each participant laboratory. In this exercise, 36 results (6% of accounted values) were outliers according to the distribution over the median (box plot). The outlier results were excluded. In order to establish the stability of testing samples in the course of the exercise, differences between variances obtained for every type of sample at different intervals were evaluated. The results showed no representative variations and it can be considered that all samples were stable during the exercise. The goals of this inter-laboratory study were to assess results variability when analysis is conducted by different laboratories, to evaluate the influence of different matrix samples, and to determine the rate at which participating laboratories successfully completed the tests initiated.
Talanta

hal-00878118
https://hal.archives-ouvertes.fr/hal-00878118
DOI : 10.1016/j.talanta.2012.06.064
PUBMED : 22939142

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
Facts -The capacity to exercise is markedly reduced in hot environments. -High humidity imposes further physiological strain on the body. -The combination of exercise and hot environments increases the risk of heat illness and heatstroke. Recommendations for players -Fluid intake should be sufficient to restrict body mass loss to o2% of the pre-exercise mass. -A minimum of 1-2 weeks of acclimatization should be undertaken before playing in a hot environment. Recommendations for organizers -Perform pre-participation screenings before competing in the heat. -Watch at-risk individual (e.g. sickle cell trait, vascular disease) and observe signs and symptoms if WBGT > 28°C. -Add additional fluid breaks and foresee medical coverage if WBGT > 30°C. -Reconsider event if WBGT > 32°C. Future research should investigate -The optimal cooling strategies prior and during sporting activities, i.e., halftime in football games. -The influence of acclimatization on football performance. -The impact of heat on decision making in players and match officials. -The impact of heat on spectators from cooler regions.
ISSN: 0905-7188

hal-00706256
https://hal.univ-antilles.fr/hal-00706256

Éditeur(s) : HAL CCSD Elsevier
Résumé : In situ analysis of major elements, platinum-group elements and Os isotope composition data for 170 grains of Ru–Os–Ir alloys from podiform chromitites in the Luobusa and Dongqiao ophiolites, Tibet, provide new constraints on the sources of the alloy grains, the Os-isotope composition of the Neo-Tethyan oceanic upper mantle, and the timing of melt–rock reactions in the ultramafic peridotites of the host ophiolites. Most alloy grains are osmiridium and iridosmine. Based on elemental and isotopic compositions, two populations can be identified. Group I, found in both ophiolite bodies, has fractionated PGE patterns typical of alloys and homogeneous 187Os/188Os 0.12645 ± 4 (2s; n = 145). Group II alloys from the Dongqiao ophiolites show smooth PGE patterns and 187Os/188Os ranges from 0.12003 to 0.12194 (yielding Re-depletion ages ≥ 1.1 Ga). Both the PGE patterns and the Os isotopic compositions of Group II resemble those of sulfides residual after melting. Group I alloys represent an early cumulate phase during the crystallization of magmas and are interpreted as derived from an asthenospheric melt. In contrast, Group II alloys are inferred to derive from the breakdown of residual sulfides from the mantle section of the ophiolite, which may represent relics of a sub-continental lithospheric mantle. The coexistence of the two groups of alloys in Dongqiao samples reflects interaction between asthenosphere-derived melts and old depleted lithospheric mantle and suggests that the chromitites originated through melt–rock reactions. The data on the Group I alloys support the hypothesis that the Re–Os evolution of the convective oceanic mantle resembles that of enstatite chondrites.
ISSN: 0012-821X

hal-00404967
https://hal.archives-ouvertes.fr/hal-00404967
DOI : 10.1016/j.epsl.2007.05.044