Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report concentrations of hydrogen (H) in upper mantle minerals of peridotites (olivine and pyroxenes) transported by alnöitic lavas, which erupted on the southwestern border of the Ontong Java Plateau (Malaita, Solomon Islands, West Pacific). Unpolarized FTIR analyses show that olivine, orthopyroxene, and diopside contain 2–32 ppm, 162–362 ppm and 159–459 ppm wt H2O, respectively. In the studied lherzolites, garnets are anhydrous. The concentration of hydrogen within individual olivine and pyroxene grains is almost homogeneous, indicating no evidence of dehydration or hydration by ionic diffusion. In the lherzolite, the concentration of hydrogen in olivine tends to increase weakly with depth (based on geothermobarometry), consistent with the increase of water solubility with increasing water fugacity as a function of pressure, but concentrations remain well below water-saturation values determined experimentally. The highest concentration of H in olivine (32 ppm wt H2O) is, however, found in refractory spinel harzburgites, which equilibrated at depths of 85 km., while deeper specimens as the high-temperature spinel harzburgites, and some of the garnet lherzolites, contain less hydrogen in olivine. Olivines from pyroxene- or pargasite-rich peridotites have also lower hydrogen concentrations. We interpret the high hydrogen concentrations in olivine from the refractory spinel harzburgites as due to (1) simultaneous hydration and metasomatism of the lithospheric mantle by a water-rich silicate melt/fluid, during which hydrogen follows MREE and where spinel harzburgite have experienced ‘stealth’ metasomatism, and/or (2) to a late ‘fleeting’ hydrogen metasomatism, which would hydrate the rock after this first ‘stealth’ metasomatism event. In the second case, the composition of the ‘fleeting’ percolating fluid (small volume fraction of very evolved fluids, with high volatiles concentration and transient properties) is likely to be linked to the decrease of the plume activity and resulting in the downwelling of the lithosphere asthenosphere boundary. The difference in hydrogen concentration between harzburgites and lherzolites could be linked to variation in trace elements in olivine induced by the first ‘stealth’ metasomatism alone or associated to the late ‘fleeting’ hydrogen metasomatism, triggered by the lack of secondary crystallization of clinopyroxenes in the harzburgite. To conclude, H concentrations in upper mantle minerals may thus be correlated to metasomatic events, with the later yielding variation of the mineral assemblage and trace element composition that constitute the peridotites.
ISSN: 0024-4937

hal-01143385
https://hal.archives-ouvertes.fr/hal-01143385
DOI : 10.1016/j.lithos.2014.11.005

Éditeur(s) : HAL CCSD
Résumé : International audience
This paper deals with the study of the kinematic dimension of scribbling activities executed by kindergarten children aged from 3 to 6 years old from three grades. For this purpose, three sigma-lognormal features, six classical ones and one hybrid feature related to visuo-motor skills are extracted from scribbles realized using five different Type Grib. The statistical analysis of these data illustrates that sigma-lognormal modeling can satisfactorily reconstruct kindergarten children’s scribbles. Moreover, this preliminary study confirms that there are significant differences between grades with respect to six of the features we studied, regardless of the nature of the scribbling movement made by children. These features are related to rapidity, fluidity and precision of linear and curvilinear movements used for scribbling tasks.
17th Biennial Conference of the International Graphonomics Society
Pointe-à-Pitre, Guadeloupe

hal-01165910
https://hal.univ-antilles.fr/hal-01165910
https://hal.univ-antilles.fr/hal-01165910/document
https://hal.univ-antilles.fr/hal-01165910/file/IGS_2015_submission_28.pdf

Éditeur(s) : HAL CCSD American Society of Mechanical Engineers
Résumé : International audience
The isothermal flow in a model channel of plate-fin heat exchanger with periodically arranged embossed-like vortex generators is investigated. Velocity measurements are performed by LDA in the transitional regime (Reynolds number from 1000 up to 5000). Strong longitudinal vortices are observed downstream of each generator. The vortex roll-up process is highlighted by the evolution of the velocity vector field in the cross section of the flow. The modifications of the vortex characteristics after successively encountered generators are investigated. This work shows most of the flow features which are known to produce heat transfer enhancement, and shows that these smooth shaped vortex generators are very promising for enhanced heat exchangers.
ISSN: 0098-2202

hal-01582938
https://hal.archives-ouvertes.fr/hal-01582938
https://hal.archives-ouvertes.fr/hal-01582938/document
https://hal.archives-ouvertes.fr/hal-01582938/file/Dupont_heat_exchanger_JFE2002_preprint.pdf
DOI : 10.1115/1.1595675

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Tsavorite, the vanadian variety of green grossular, is a high value economic gemstone. It is hosted exclusively in the metasedimentary formations from the Neoproterozoic Metamorphic Mozambique Belt. The deposits are mined in Kenya, Tanzania and Madagascar and other occurrences are located in Pakistan and East Antarctica. They are located within metasomatized graphitic rocks such as graphitic gneiss and calc-silicates, intercalated with meta-evaporites. Tsavorite is found as primary deposits either in nodule (type I) or in quartz vein (type II), and in placers (type III). The primary mineralizations (types I and II) are controlled by lithostratigraphy and/or structure. For the African occurrences, the protoliths of the host-rocks were deposited at the beginning of the Neoproterozoic within a marine coastal sabkha environment, located at the margin of the Congo-Kalahari cratons in the Mozambique Ocean. During the East African-Antarctican Orogeny, the rocks underwent high amphibolite to granulite facies metamorphism and the formation of tsavorite deposits occurred between 650 and 550 Ma. The nodules of tsavorite were formed during prograde metamorphism, calcium coming from sulphates and carbonates, whereas alumina, silicates, vanadium and chromium probably came from clays and chlorite. The veins were formed during the deformation of the metasedimentary platform units which experienced shearing, leading to the formation of fault-filled veins. Metasomatism developed during retrograde metamorphism. The metasedimentary sequences are characterized by the presence of evaporitic minerals such as gypsum and anhydrite, and scapolite. Evaporites are essential as they provide calcium and permit the mobilization of all the chemical elements for tsavorite formation. The H2S-S8 metamorphic fluids characterized in primary fluid inclusions of tsavorites and the δ11B values of coeval dravite confirm the evaporitic origin of the fluids. The V2O3 and Cr2O3 contents of tsavorite range respectively from 0.05 to 7.5 wt.%, while their δ18O values are in the range of 9.5-21.1‰. The genetic model proposed for tsavorite is metamorphic, based on chemical reactions developed between an initial assemblage composed of gypsum and anhydrite, carbonates and organic matter deposited in a sabkha-like sedimentary basin.
ISSN: 0169-1368

hal-00853279
https://hal.archives-ouvertes.fr/hal-00853279
DOI : 10.1016/j.oregeorev.2013.01.016

Éditeur(s) : HAL CCSD Coastal Education and Research Foundation
Résumé : International audience
ISSN: 0749-0208

hal-00905651
https://hal.archives-ouvertes.fr/hal-00905651

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Several epidemiologic studies have shown an interactive effect of heavy smoking and heavy alcohol drinking on the development of hepatocellular carcinoma. It has also been recently described that chronic hepatocyte death can trigger excessive compensatory proliferation resulting later in the formation of tumors in mouse liver. As we previously demonstrated that both benzo[a]pyrene (B[a]P), an environmental agent found in cigarette smoke, and ethanol possess similar targets, especially oxidative stress, to trigger death of liver cells, we decided to study here the cellular and molecular mechanisms of the effects of B[a]P/ethanol coexposure on cell death. After an 18-h incubation with 100nM B[a]P, primary rat hepatocytes were supplemented with 50mM ethanol for 5 or 8h. B[a]P/ethanol coexposure led to a greater apoptotic cell death that could be linked to an increase in lipid peroxidation. Plasma membrane remodeling, as depicted by membrane fluidity elevation and physicochemical alterations in lipid rafts, appeared to play a key role, because both toxicants acted with specific complementary effects. Membrane remodeling was shown to induce an accumulation of lysosomes leading to an important increase in low-molecular-weight iron cellular content. Finally, ethanol metabolism, but not that of B[a]P, by providing reactive oxygen species, induced the ultimate toxic process. Indeed, in lysosomes, ethanol promoted the Fenton reaction, lipid peroxidation, and membrane permeabilization, thereby triggering cell death. To conclude, B[a]P exposure, by depleting hepatocyte membrane cholesterol content, would constitute a favorable ground for a later toxic insult such as ethanol intoxication. Membrane stabilization of both plasma membrane and lysosomes might be a potential target for further investigation considering cytoprotective strategies.
ISSN: 0891-5849

hal-01018147
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01018147
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01018147/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01018147/file/Cooperative-interaction_final.pdf
PUBMED : 24681337

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The ultramafic rocks of the Collo region in northeastern Algeria crop out as “stratified” masses that cut across older metamorphic formations of the Petite Kabylie basement. Based on petrological compositions and mineralogical observations, these rocks are mainly peridotites and serpentinites. The peridotites are identified as lherzolites, but dunites may occur rarely. The lherzolites are composed of olivine, orthopyroxene, clinopyroxene and chromian spinel. Their chemical composition shows high MgO (34.4–37.5 wt%), Cr (0.14–0.27 wt%), Ni (0.14–0.26 wt%) and Co (34–133 ppm) contents and low CaO and Al2O3 concentrations (0.02–2.2 wt% and 0.5 to 2.8 wt%, respectively). The chromite, which represents approximately 1–3% of the rock, is ubiquitous and shows two different generations: primary millimetric euhedral crystals and secondary fine xenomorphic grains and interstitial aggregates. The primary chromites are alumino-ferro-magnesian crystals that show high Al2O3 (25.77%–27.36%) and MgO (10.70%–13.36%). Cr# (100 × Cr/(Al + Cr)) ranges from 45 to 48, and Mg# (100 × Mg/(Mg + Fe2+)) from 49 to 59. The secondary interstitial grains are iron-rich chromites. They show low Al2O3 (4.67%–9.54%) and MgO (4.60%–4.65%). Cr# is relatively high (77–88), whereas Mg# shows relatively low values, ranging from 22 to 25. Primary chromite and whole-rock chemistry show that the Collo ultramafic rocks belong to Alpine-type peridotites that were emplaced within an orogenic setting. The oxygen isotopic composition of both peridotites and chromites is consistent with their derivation from a mantle source (δ18O ranges from +3.0 to +5.9‰). Low δ18O values (<+4.4‰) are recorded in serpentinites and are attributed to the effect of serpentinization processes through high-temperature metasomatic fluids. Magnesite-bearing serpentinites show the lowest δ18O values. These are interpreted as the result of surface water input.
ISSN: 0899-5362

hal-01468003
https://hal.archives-ouvertes.fr/hal-01468003
DOI : 10.1016/j.jafrearsci.2016.10.012

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
[1] Zircons and monazites from 6 samples of the North Ayilari dextral shear zone (NAsz), part of the Karakorum fault zone (KFZ), have been dated with the U-Th-Pb method, using both ID-TIMS and SIMS techniques. The ages reveal (1) inheritance from several events spanning a long period between the late Archean and the Jurassic; (2) an Eocene-Oligocene magmatic event (similar to 35-32 Ma); (3) an Oligo-Miocene magmatic event (similar to 25-22 Ma), at least partly synkinematic to the right-lateral deformation; and (4) a period of metamorphism metasomatism (similar to 22-14 Ma) interpreted as thermal and fluid advection in the shear zone. The Labhar Kangri granite located similar to 375 km farther Southeast along the KFZ is dated at 21.1 +/- 0.3 Ma. Such occurrence of several Oligo-Miocene granites along the KFZ, some of which show evidence for synkinematic emplacement, suggests that the fault zone played an important role in the genesis and /or collection of crustal melts. We discuss several scenarios for the onset and propagation of the KFZ, and offset estimates based on the main sutures zones. Our preferred scenario is an Oligo-Miocene initiation of the fault close to the NA range, and propagation along most of its length prior to similar to 19 Ma. In its southern half, the averaged long-term fault-rate of the KFZ is greater than 8 to 10 mm/a, in good agreement with some shorter-term estimates based on the Indus river course, or Quaternary moraines and geodesy. Our results show the KFZ cannot be considered as a small transient fault but played a major role in the collision history.
ISSN: 0278-7407

hal-00412570
https://hal.archives-ouvertes.fr/hal-00412570
DOI : 10.1029/2007TC002184

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report new data on the geochemical evolution, metasomatic and deformation processes in the lower layers of cratonic lithospheric mantle based on a detailed study of extraordinarily fresh and large deformed peridotite xenoliths from the Udachnaya kimberlite pipe, Siberia. Based on our T-P estimates, the deformed peridotites are localized in a depth range of 170 to 220 km near the base of cratonic mantle. The degree of deformation is not correlated with the depth and equilibration temperatures of the xenoliths. The deformed peridotites are depleted in magmaphile major elements indicating their residual nature, but are enriched in incompatible trace elements, Fe and K. The deformed peridotites experienced a complex evolution, i.e., they were formed initially as high-degree melt extraction residues and later were subjected to three main stages of metasomatic modification. (1) An old, mostly cryptic metasomatism by melt/fluid of carbonatitic composition, which formed garnets with sinusoidal REE patterns (Smn/Ern > 1). (2) Silicate metasomatism, which led to the most significant changes in mineralogical and chemical composition of the deformed peridotites. (3) Fe and Ti metasomatism just before the entrainment of the deformed rocks into kimberlite magma. Enrichment of the peridotites in large-ion lithophile elements (K, Rb, Ba) is related to the formation of kelyphitic rims around garnet. The nature of the metasomatic agent of silicate metasomatism was evaluated from mass-balance of measured and calculated whole-rock compositions, ratios of highly incompatible elements (D < 0.1) and fractional crystallization modeling. All this evidence indicates that the agent of silicate metasomatism had a composition intermediate between that of kimberlites and HIMU OIB. The metasomatic processes responsible for the formation of deformed peridotites and precipitation of megacryst suites cannot be widespread at the base of the cratonic mantle. Rather, they are local features only existing in the cratonic mantle below kimberlite fields and localized along the metasomatic vein system.
ISSN: 0024-4937

hal-00941010
https://hal.archives-ouvertes.fr/hal-00941010
DOI : 10.1016/j.lithos.2012.11.014

Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
Serpentinization of the oceanic lithosphere contributes significantly to the geochemical cycle from spreading ridges to subduction zones. In situ trace element analysis of oceanic serpentinites from the Mid-Atlantic Ridge and the Greater Antilles (Cuba, Dominican Republic) shows that all serpentine minerals are enriched in fluid-mobile elements (FME: As, Sb, B, Li, Cs, Pb, U, Ba, Sr). We observe no loss of these elements from abyssal to subduction environments during prograde metamorphism. Moreover, the transition from lizardite/chrysotile to antigorite during subduction is marked by a strong over-enrichment in As and Sb in antigorite, indicating late contamination by a sedimentary source. This suggests that a second stage of serpentinization occurs in the earlier stages of subduction, when newly formed or reactivated normal faults ease fluid penetration, and/or in the subduction channel. Our study shows that, from spreading ridges to forearc environments, serpentines act as sponges for FME. We posit that, until ultimate antigorite breakdown, serpentinites efficiently transport significant amounts of FME down to great depths in the mantle.
ISSN: 0954-4879

insu-00603792
https://hal-insu.archives-ouvertes.fr/insu-00603792
DOI : 10.1111/j.1365-3121.2011.00995.x

Éditeur(s) : HAL CCSD
Résumé : International audience
The Jaca basin is a thrust-sheet top basin transported southward andunderlain by basement and cover thrusts separated by a Triassic décollement.Basin-fill upper Cretaceous to lower Oligocene synorogenic sequencesrecord a southward depocenter migration, while growth stratadate a shift of deformation from the mid-Eocene in the N to the earlyMiocene in the S (S-Pyrenean front). However, the deep geometry andkinematic relationships between the cover and basement thrusts remainnon-consensual. We present a new structural and kinematic interpretationfor the eastern Jaca basin, based on subsurface structural maps andcross-sections constructed using industrial seismic reflection profiles.Raman Spectroscopy of Carbonaceous Material (RSCM), vitrinite reflectanceand apatite fission track (AFT) thermochronology data givefurther constraints for the restoration of the deformation and burialexhumationsequence. We define 3 main basement thrusts under thenorthern part of the basin, from N to S the Broto, Fiscal and Guargathrusts. The study also clarifies the deep structure of the cover thrustsand their links with these basement thrusts and those located more tothe north in the Axial Zone (AZ), which altogether define the timing ofthe basement thrust sequence as follows : the Lakoura-Eaux Chaudesthrust system (northern AZ) active up to the end Bartonian, the Gavarnie(central AZ) and Broto thrusts during the Priabonian-Rupelian andthe Fiscal and Guarga thrusts during the late Oligocene-early Miocene.AFT results in the basin fill and AZ date the exhumation of the basinto the late Oligocene-early Miocene, in relation to the Fiscal-Guargathrusting. AFT partial reset argues for a maximum burial < 6 km forthe base of the Eocene detrital sequence (Hecho Group turbidites). Bycontrast, RSCM and vitrinite thermometry at the same level indicatesTmax around 180°C, locally up to 240°C, attesting to a temperature anomalypossibly related to transient fluid circulation.
24 ème Réunion des sciences de la Terre 2014
Pau, France

insu-01080836
https://hal-insu.archives-ouvertes.fr/insu-01080836

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
At the North-Ecuadorian convergent margin (1°S–1.5°N), the subduction of the rough Nazca oceanic plate leads to tectonic erosion of the upper plate and complex seismogenic behavior of the megathrust. We used three selected pre-stack depth migrated, multi-channel seismic reflection lines collected during the SISTEUR cruise to investigate the margin structure and decipher the impact of the subducted Atacames seamounts on tectonic erosion, interseismic coupling, and seismogenesis in the region of the 1942 Mw7.8 earthquake.This dataset highlights a subducted ∼30×40 km∼30×40 km, double-peak seamount that belongs to the Atacames seamount chain and that is associated with a deep morphologic re-entrant containing mass transport deposits.The seamount subduction uplifted the margin basement by ∼1.6 km and pervasively broke the margin by deep and intense reverse faulting ahead of the seamount, a process that is likely to weaken considerably the margin. In the seamount wake, the basement reverse fault system rotated counter-clockwise. This faulted basement is overlain with slope sediment sliding along listric normal faults that sole out onto the BSR. This superposition of deep tectonic contraction within the basement and shallow gravitational extension deformation within the sediment highlights the key role of gas hydrate on outer slope erosion.In addition to long-term regional basal erosion, the margin basement has thinned locally by an extra 0.8–1 km in response to the subduction of the Atacames seamount chain and hydrofracturing by overpressured fluids at the margin toe. This pervasively and deeply fractured margin segment is associated with a seismically quiet and GPS-modeled low interseismic coupling corridor that terminates downdip near the 1942 epicenter and locked zone. We suggest that the deeply buried double-peak Atacames seamount triggered the 1942 earthquake ahead of its leading flank. This result supports previous studies proposing that subducted seamounts provide unfavorable conditions for locking the updip segment of the plate boundary limiting the updip extent of seismogenic zones, but may favor large subduction earthquakes at greater depths.
ISSN: 0012-821X

hal-01256399
https://hal.archives-ouvertes.fr/hal-01256399
DOI : 10.1016/j.epsl.2015.10.043

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Recently it has become clear that exposure to xenobiotics may result in various forms of cell death; not only passive cell deaths like necrosis, or programmed cell deaths such as apoptosis, but also regulated necrosis, autophagy, senescence, or mitotic catastrophe. Complex cell signaling networks influence the processing of cell death. Furthermore, recent research has revealed early complex molecular interactions between organelles prior to the final triggering of cell death. The plasma membrane may play an important role in the early cell death signaling events. Regarding this latter aspect, drugs and environmental pollutants have been reported to affect plasma membrane characteristics which may further affect cell fate. Changes in membrane fluidity or in composition and function of specialized membrane microdomains (plasma membrane remodeling) have been proven to be involved in the regulation of many important physiological signaling pathways, including cell death. Furthermore, it has been suggested that a crosstalk between chemical-induced cellular membrane effects and other organelles may be of vital importance to explain the final outcome of chemical exposure. Here, we review the effects of plasma membrane remodeling on cell survival and cell death; we describe how the cell signaling pathways activated by changes in plasma membrane characteristics may influence cell fate. Since plasma membrane function plays an important role in the regulation of a number of cellular responses, it has been implicated in the development or progress of several diseases. A better knowledge of the effects of various chemicals on plasma membrane remodeling may be important for understanding the pathogenesis of major diseases, and may assist in developing new therapeutic strategies.
ISSN: 0300-483X

inserm-00818916
http://www.hal.inserm.fr/inserm-00818916
DOI : 10.1016/j.tox.2012.12.014
PUBMED : 23287390

Éditeur(s) : HAL CCSD
Résumé : This study provides additional constraints on the relations between deformation, hydration and percolation of fluids and melts in the subcontinental lithospheric mantle beneath a craton and a rift, as well as their implication on its geodynamical behaviour. I have analysed the microstructures, the CPOs, and the hydrogen content of mantle xenoliths from the Kaapvaal craton, and two sets of xenoliths from different localities along the East African Rift (North Tanzanian Divergence and SE Ethiopia).The coarse-granular microstructures and the well-defined CPOs in Kaapvaal peridotites suggest a deformation followed by a long quiescence time. Orthorhombic olivine CPOs predominates, but axial-[100] and axial-[010] are also measured. Cratonic peridotites record multiple metasomatic episodes, leading to a significant compositional heterogeneity, which cannot be imaged by seismic studies. Olivine hydrogen contents are variable, but tend to increase until 150 km depth, reaching up to 50 ppm wt. H2O. The deeper samples are almost dry. Piston-cylinder experiments on hydrogen diffusion between a volatile-rich kimberlitic melt and forsterite suggest that the presence of CO2 in the system could significantly decrease water fugacity and thus forsterite hydration. These experimental results indicate that the hydrogen contents measured in olivine were acquired during a metasomatic event rather than during xenolith extraction by kimberlites. However, this metasomatism was not followed by remobilization of the cratonic root.In the North Tanzanian Divergence, localities within the rift axis and the volcanic transverse belt (Lashaine and Olmani) show significant differences in microstructures and olivine CPO patterns. In Lashaine, coarse-granular microstructures and orthorhombic to axial-[100] CPO patterns in olivine can be explained by transpressional deformation during the formation of the Mozambique belt, or by the occurrence of a remnant of a cratonic domain embedded within the Mozambique belt. Within the rift axis, porphyroclastic to mylonitic microstructures suggest a recent rift-related deformation accompanied by syn-kinematic melt-rock reactions, and followed by variable annealing. The strong heterogeneity in microstructures and olivine CPO suggests that this deformation was acquired during multiple tectonic events probably linked to episodic magma percolation, separated by quiescence episodes. The axial-[100] patterns in olivine and the oblique fast directions reported by SKS studies are coherent with transtensional deformation within the lithospheric mantle beneath the rift.The peridotites from SE Ethiopia are less recrystallized than the rift-axis Tanzanian peridotites, displaying coarse-porphyroclastic microstructures. Microstructures and orthorhombic CPOs in olivine suggest syn- to post-metasomatic deformation. S-waves polarization anisotropies calculated for these samples cannot explain alone the delay times reported by SKS studies in this part of the East-African Rift.
Les travaux réalisés durant cette thèse apportent de nouvelles contraintes sur les relations entre déformation, hydratation et percolation de fluides et/ou de magmas dans le manteau subcontinental sous un craton et sous un rift, et leurs implications sur son comportement rhéologique. Il repose sur l'analyse des microstructures, des OPRs et des teneurs en hydrogène de xénolites mantelliques du craton du Kaapvaal, et sur deux séries de xénolites provenant de différentes localités le long du rift Est-Africain (Divergence Nord Tanzanienne et SE de l'Ethiopie). Les microstructures granulaires à gros grains et les OPRs bien définies des péridotites du craton du Kaapvaal sont cohérentes avec un épisode de déformation suivi d'une longue période de quiescence. Les OPRs de l'olivine sont majoritairement à symétrie orthorhombique, mais des symétries axiale-[100] et axiale-[010] sont aussi mesurées. Les péridotites cratoniques enregistrent de multiples épisodes métasomatiques, ayant entraîné une hétérogénéité de compositions à petite échelle ne pouvant être détectée par les études sismiques. Les teneurs en hydrogène mesurées dans l'olivine sont variables, mais ont tendance à augmenter jusqu'à 150 km de profondeur, atteignant alors jusqu'à 50 ppm wt. H2O. En dessous de cette profondeur, les échantillons montrent des teneurs en hydrogène très faibles. Les expériences réalisées en piston-cylindre sur la diffusion de l'hydrogène issue d'un liquide kimberlitique vers de la forstérite suggèrent que la fugacité en eau pourrait fortement être diminuée par la présence de CO2, empêchant l'hydratation de l'olivine durant extraction des xénolites par les kimberlites. Ces résultats expérimentaux suggèrent que les teneurs en hydrogène dans l'olivine des péridotites du craton du Kaapvaal ont été acquises durant un épisode métasomatique en profondeur et non pendant leur extraction par les kimberlites. Ces teneurs n'ont toutefois pas à ce jour entraîné de remobilisation de la racine cratonique. Enfin, le calcul des propriétés sismiques des péridotites cratoniques révèle que les anisotropies générées par les OPRs de ces échantillons sont suffisantes pour expliquer les anisotropies mesurées par les ondes SKS et les ondes de surface.Les xénolites de la Divergence Nord-Tanzanienne, montrent des variations significatives de microstructures et d'OPR de l'olivine entre les péridotites des localités dans l'axe du rift et celles de la chaîne volcanique transverse (Lashaine et Olmani). A Lashaine, les microstructures granulaires à gros grains et les OPRs de type orthorhombique et axial-[010] peuvent être expliquée par une déformation en transpression liée à la formation de la chaîne Mozambique ou par la présence d'une relique d'un domaine cratonique à l'intérieur de la chaîne Mozambique. Dans l'axe du rift, les microstructures porphyroclastiques à mylonitiques suggèrent une déformation plus récente, accompagnée de réactions magma-roche sous des conditions proches du solidus, suivie d'un recuit variable. L'hétérogénéité des microstructures enregistrées par les échantillons du rift suggère de multiples épisodes de déformation localisée, probablement liés à l'injection percolation épisodique de magmas, espacés de périodes d'accalmie. Les OPRs de l'olivine de type axial-[100] et l'orientation des directions de polarisation des ondes SKS suggère que le rift s'est formé en régime de transtension Les péridotites du Sud-Est de l’Éthiopie présentent des microstructures porphyroclastiques à gros grains moins recristallisées qu'en Tanzanie. Les microstructures et les OPRs principalement de type orthorhombique suggèrent une déformation syn- à post-métasomatisme. Les anisotropies de polarisation des ondes S calculées pour ces échantillons sont insuffisantes pour expliquer à elles seules les déphasages des ondes SKS dans cette partie du rift.
https://tel.archives-ouvertes.fr/tel-01684759

Droits : info:eu-repo/semantics/OpenAccess
NNT : 2014MON20139
tel-01684759
https://tel.archives-ouvertes.fr/tel-01684759
https://tel.archives-ouvertes.fr/tel-01684759/document
https://tel.archives-ouvertes.fr/tel-01684759/file/43443_BAPTISTE_2014_archivage_cor.pdf

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Electrical resistivity soundings are used by geophysicists to determine the structure and composition of the Earth's crust and mantle and to explore natural resources (ore, oil, gas, water). Their interpretations in terms of composition and in-situ physical conditions depend mainly on laboratory measurements of electrical conductivity of rocks at simulated crustal conditions of temperature, pressure, saturation and pore pressures. These measurements present a numbers of limitations, in particular, in the case where conductive pore fluids are present, as in the case of deep reservoir conditions, where temperature exceeds 250 A degrees C. Here, we present a new cell capable of measuring electrical conductivity of large saturated samples at confining pressure up to 200 MPa, pore pressure up to 50 MPa, and temperature up to 500 A degrees C. The measurement cell has been developed in a commercial, internally heated, gas pressure apparatus (Paterson press). It is based on the concept of "guard ring" electrode, which is adapted to samples that are jacketed by a very conductive, metallic material. Numerical modeling of the current flow in the electrical cell allowed defining the optimal cell geometry. Calibration tests have been performed on Fontainebleau sandstones saturated with electrolytes of different conductivities, up to 350 A degrees C. The resulting electrical formation factor and temperature dependence of electrical conductivity are in very good agreement with previous studies. This new cell will improve the exploration and exploitation of deep fluid reservoirs, as in unconventional, high enthalpy geothermal fields. In particular, the investigations address possible effects of fluid-rock interactions on electrical resistivity of a reservoir host rock.
ISSN: 0169-3913

hal-00681997
https://hal.archives-ouvertes.fr/hal-00681997
DOI : 10.1007/s11242-011-9846-2

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Spinel lherzolite xenoliths from Mont Briancon, French Massif Central, retain evidence for multiple episodes of melt depletion and melt/fluid infiltration (metasomatism). Evidence for primary melt depletion is still preserved in the co-variation of bulk-rock major elements (MgO 38.7-46.1 wt.%; CaO 0.9-3.6 wt.%), and many samples yield unradiogenic bulk-rock Os isotope ratios (Os-187/Os-188 = 0.11541-0.12626). However, many individual xenoliths contain interstitial glasses and melt inclusions that are not in equilibrium with the major primary minerals. Incompatible trace element mass balance calculations demonstrate that metasomatic components comprise a significant proportion of the bulk-rock budget for these elements in some rocks, ranging to as much as 25%, of Nd and 40% of Sr Critically, for Re-Os geochronology, melt/fluid infiltration is accompanied by the mobilisation of Sulfide. Consequently, bulk-rock isotope measurements, whether using lithophile (e.g. Rb-Sr, Sm-Nd) or siderophile (Re-Os) based isotope systems, may only yield a perturbed and/or homogenised average of these multiple events.;Osmium mass balance calculations demonstrate that bulk-rock Os in peridotite is dominated by contributions from two populations of sulfide grain: (i) interstitial, metasomatic Sulfide with low [Os] and radiogenic Os-187/Os-188, and (ii) primary sulfides with high [Os] and unradiogenic Os-187/Os-188, which have been preserved within host silicate grains and shielded from interaction with transient melts and fluid. The latter can account for >97% of bulk-rock Os and preserve geochronological information of the melt from which they originally precipitated as an immiscible liquid. The Re-depletion model ages of individual primary sulfide grains preserve evidence for melt depletion beneath the Massif Central from at least 1.8 Gyr ago despite the more recent metasomatic event(s). (C) 2009 Elsevier Ltd. All rights reserved.
ISSN: 0016-7037

hal-00454537
https://hal.archives-ouvertes.fr/hal-00454537
DOI : 10.1016/j.gca.2009.09.031

Éditeur(s) : HAL CCSD
Résumé : International audience
The way faults control upward fluid flow in extensive hydrothermal systems without an abnormal heat source such as volcanic or plutonic activity is still unclear. In the Eastern Pyrénées, an alignment of 29 hot springs (from 29 • C to 73 • C) along the Têt normal Fault offers the opportunity to study this process. Using an integrated multi-scale geological approach including mapping, remote sensing, macro and microscopic analyses of fault zones, we show that hot springs locate close to high topographic reliefs related to fault throw and segmentation. Emergences are always in crystalline rocks at gneiss-metasediments contacts, mostly in the Têt Fault footwall. In more details, they localize either (1) in brittle fault damage zones at the intersection between the Têt Fault and subsidiary faults, and (2) into hercynian ductile faults where dissolution cavities run along shear zones. Using these observations and 2D preliminary numerical simulations, we propose a hydrogeological model of upward hydrothermal flow. Meteoric fluids infiltrate at high altitude in the fault footwall relief where they acquire temperature because of the geothermal gradient. Hydraulic gradient and buoyancy forces allow them to upflow along fault-related permeability anisotropies. The identification and prioritization of the features controlling this kind of system have important implications for geothermal exploration and for the understanding of fluid-flow into the brittle Earth's crust in general.
EGU 2017
Vienne, Austria

hal-01491096
https://hal-brgm.archives-ouvertes.fr/hal-01491096
https://hal-brgm.archives-ouvertes.fr/hal-01491096/document
https://hal-brgm.archives-ouvertes.fr/hal-01491096/file/EGU2017-Taillefer-etal_4996.pdf

Éditeur(s) : HAL CCSD
Résumé : International audience
De nombreux pieds de marges continentales passives sont caractériséspar la présence de manteau exhumé (Galice, Angola, Scandinavie, MerRouge, Mer Tyrrhénienne, Australie, ...). Dans le cas des marges pyrénéennes,le manteau est exhumé en contexte extensif suite à l’amincissementcrustal extrême et mis en contact avec les sédiments sus-jacentsde la couverture pré-rift. Les chaînons Béarnais (Pyrénées Occidentales)sont les restes de cette couverture sédimentaire Mésozoïque associée àdes pointements de socle Paléozoïque et de manteau. Le massif du Saraillé(anticlinal de Sarrance) où sont rassemblées toutes ces lithologiesest un endroit idéal pour l’étude de la genèse des marges à manteau exhumé.Ce massif a fait l’objet d’une étude détaillée : cartographie, structure,évolution métamorphique, géochimie isotopique. La cartographiea révélé que la structure est une tête anticlinale couchée affectant l’ensemblede la couverture Mésozoïque pré-rift et dont le coeur est constituéde lentilles de socle et de manteau. Nous nous sommes particulièrementintéressés au contact entre la couverture Mésozoïque, dont labase est métamorphique et le socle. Un intense métasomatisme précoce,syn-extension est révélé par la présence de lentilles pluri-métriques detalc et chloritites, ainsi que par le développement de filonets d’albitites.Les analyses d’isotopes stables (18O, 13C) réalisées dans la couverturesédimentaire montrent l’importance des circulations de fluides métamorphiquesdurant l’exhumation du manteau et font du massif du Sarailléune référence pour les systèmes d’interactions fluide/roche au pieddes marges continentales distales. Nos analyses couplées aux observationsde terrain permettent de compléter les modèles d’amincissementcrustal extrême et de remontée du manteau. Nous montrons donc quela déformation ductile de la croûte continentale le long d’un grand détachement,s’accompagne de boudinage et se résout par l’individualisationde minces écailles de socle réparties sur le manteau exhumé.
24 ème Réunion des sciences de la Terre 2014
Pau, France

insu-01080825
https://hal-insu.archives-ouvertes.fr/insu-01080825

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
We report structural evidence of ductile strain localization in mantle pyroxenite from the spinel to plagioclase websterite transition in the Ronda Peridotite (southern Spain). Mapping shows that, in this domain, small-scale shear zones occurring at the base of the lithospheric section are systematically located within thin pyroxenite layers, suggesting that the pyroxenite was locally weaker than the host peridotite. Strain localization is associated with a sudden decrease of grain size and increasing volume fractions of plagioclase and amphibole as a result of a spinel to plagioclase phase transformation reaction during decompression. This reaction also fostered hydrogen extraction ('dehydroxylation') from clinopyroxene producing effective fluid saturation that catalyzed the synkinematic net-transfer reaction. This reaction produced fine-grained olivine and plagioclase, allowing the onset of grain-size sensitive creep and further strain localization in these pyroxenite bands. The strain localization in the pyroxenites is thus explained by their more fertile composition, which allowed earlier onset of the phase transition reactions. Geothermobarometry undertaken on compositionally zoned constituent minerals suggests that this positive feedback between reactions and deformation is associated with cooling from at least 1000°C to 700°C and decompression from 1*0 to 0*5 GPa.
ISSN: 0022-3530

hal-00941293
https://hal.archives-ouvertes.fr/hal-00941293
DOI : 10.1093/petrology/egt039

Éditeur(s) : HAL CCSD BioMed Central
Résumé : International audience
Background: Neonatal infection constitutes one of Senegal’s most important public health problems, with amortality rate of 41 deaths per 1,000 live births.Methods: Between January 2007 and March 2008, 242 neonates with suspected infection were recruited at threeneonatal intensive care units in three major tertiary care centers in Dakar, the capital of Senegal. Neonatal infections wereconfirmed by positive bacterial blood or cerebrospinal fluid culture. The microbiological pattern of neonatal infectionsand the antibiotic susceptibility of the isolates were characterized. In addition, the genetic basis for antibiotic resistanceand the genetic background of third-generation cephalosporin-resistant (3GC-R) Enterobacteriaceae were studied.Results: A bacteriological infection was confirmed in 36.4 % (88/242) of neonates: 22.7 % (30/132) during the early-onsetand 52.7 % (58/110) during the late-onset periods (p > 0.20). Group B streptococci accounted for 6.8 % of the 88 collectedbacterial isolates, while most of them were Enterobacteriaceae (n = 69, 78.4 %). Of these, 55/69 (79.7 %) were 3GC-R. TheblaCTX-M-15 allele, the blaSHV and the blaTEM were highly prevalent (63.5, 65.4 and 53.8 %, respectively), usually associatedwith qnr genes (65.4 %). Clonally related strains of 3GC-R Klebsiella pneumoniae and 3GC-R Enterobacter cloacae, the twomost commonly recovered 3GC-R Enterobacteriaceae (48/55), were detected at the three hospitals, underlining the roleof cross-transmission in their spread. The overall case fatality rate was 18.6 %.Conclusions:Measures should be taken to prevent nosocomial infections and the selection of resistant bacteria
ISSN: 1471-2334

Droits : http://creativecommons.org/licenses/by/
hal-01473613
https://hal.archives-ouvertes.fr/hal-01473613
https://hal.archives-ouvertes.fr/hal-01473613/document
https://hal.archives-ouvertes.fr/hal-01473613/file/High%20third-generation%20cephalosporin%20resistant%20Enterobacteriaceae%20prevalence%20rate%20among%20neonatal%20infections%20in%20Dakar%2C%20Senegal.pdf
DOI : 10.1186/s12879-016-1935-y