Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Abstract View references (38)Silicalite-1 (S-1) and ZSM-5 membranes prepared by secondary growth on tubular ceramic supports were tested using a pervaporation set up for the desalination of aqueous solutions containing NaCl in concentrations corresponding to brackish (0.3-1wt%), sea (3.5wt%) and brine (7.5-15wt%) water. ZSM-5 membranes delivered higher water fluxes when compared with S-1 membranes due to enhanced hydrophilicity of the Al-rich zeolite structure leading to fluxes as high as 11.5kgm -2h -1 for 0.3wt% NaCl feed solutions at 75°C. At higher salt concentration the water flux decreased alongside with the salt rejection rate, however the hydrophilic ZMS-5 membrane became more susceptible to performance loss, particularly at high temperatures. Detailed stability experiments carried out for up to 560h showed the dissolution of both S-1 and ZSM-5 top layers. This was attributed to the combined effects of ion exchange and water dissolution mechanisms. Interesting though, the MFI structure zeolite was still observed on the XRD patterns whilst EDX depth profile showed the presence of silica up to 30μm depth into the support. These results suggest the formation/infiltration of a compact amorphous phase in the substrate, derived from the aggregation of the dissolved silicate species and possibly together with the arrangement of MFI nano-slabs during the desalination tests. Despite generating lower water fluxes, the S-1 membrane exhibited relatively high robustness under the long term testing conditions which included temperature cycling, delivering salt rejections from initial >99% to <80% at the end of the testing period (560h). © 2012 Elsevier B.V.
ISSN: 0376-7388

hal-01683201
https://hal.univ-antilles.fr/hal-01683201
DOI : 10.1016/j.memsci.2012.05.074

Éditeur(s) : HAL CCSD Springer/Terra Scientific Publishing Company
Résumé : International audience
We report oil the discovery of magnetite nanoparticles ranging in size from 2 to 14 full in the mineralized zones of the Pena Colorada iron-ore deposit, southern Mexico. Micrometric scale magnetite was magnetically reduced and divided into distinct size ranges: 85-56 mu m, 56-30 mu m, 30-22 mu m, 22-15 mu m, 15-10 mu m, 10-7 mu m and 7-2 mu m. Nanometric-scale magnetite in the size range 2-14 nm was identified. The magnetite was characterized by X-ray diffraction, transmitted and reflected light microscope, high-resolution transmission electron microscopy (TEM), high angle annular dark field, Mossbauer spectroscopy and its magnetic properties. Crystallographic identification of nanostructures Was performed using high-resolution TEM. Characteristic changes were observed when the particles make the size transition from micro- to nanometric sizes, as follows: (1) frequency-dependent magnetic Susceptibility percentage (chi FD%) measurements Show high Values (13%) for the 2-14 nm fractions attributed to dominant fractions of superparamagnetic particles; (2) variations of chi FD% < 4.5% in fractions of 56-0.2 mu m occur in association with the presence of microparticles formed by magnetite aggregates of nanoparticles (< 15 nm) embedded in berthierine; (3) Mossbauer spectroscopy results identified a superparamagnetic fraction; (4) nanometric and 0.2-3 mu m grain size magnetite particles require a magnetic field up to 152 mT to reach saturation during the isothermal remanent magnetization experiment; (5) coercivity and remanent magnetization of the magnetite increase when the particle size decreases, probably due to parallel Coupling effects; (6) two-magnetic Susceptibility versus temperature experiments of the same 2-14 nm sample show that the reversibility during the second heating is due to the formation of new magnetite nanoparticles and growth of those already present. during the first heating process.
ISSN: 1343-8832

hal-00413053
https://hal.archives-ouvertes.fr/hal-00413053

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The In-Ezzane volcanic district (EZD), located at the triple junction of Algeria, Niger and Libya belongs to the Eastern Hoggar, covers 350 km2 and includes 9 volcanic edifices that are probably aligned along NW-SE faults, parallel to the Tafassasset valley. The low volume (0.7 and 1 km3) of emitted lavas, the similar morphology of the monogenic cones and the lack of differentiated rocks indicate that the volcanic activity of the EZD was restricted in time and volume. The new K-Ar age (i.e. 2.86 ± 0.07 Ma) indicates that the EZD is contemporaneous with the last alkali volcanism paroxysm in Hoggar and with the nearby Libyan volcanics. The EZD alkali basalts (mainly basanite) show a remarkable homogeneous compositions both in major elements (44.8 ⩽ SiO2 ⩽ 45.8 wt.%; 5.2 ⩽ (Na2O + K2O) ⩽ 6.2 wt.%), trace elements (4.3 ⩽ Th ⩽ 5.5 ppm; 34.7 ⩽ La ⩽ 44.7 ppm; 16.1 < La/Yb(N) < 21.6) and radiogenic isotopes (0.70285 < 87Sr/86Sr < 0.70303; 0.51298 < 143Nd/144Nd < 0.51301; (19.212 < 206Pb/204Pb < 19.340, 15.589 < 207Pb/204Pb < 15.602 and 38.834 < 208Pb/204Pb < 38.903). Relative to the Hoggar alkaly basalts the EZD basalts appear systematically impoverished in incompatible elements and show a depleted signature both in Sr and Nd isotopes (almost MORB-like). The Pb isotopes are relatively enriched and intermediate between tholeiites and alkali basalts of the Hoggar. This unusual geochemical signature, is uneasy to reconcile with the known characteristics of the Hoggar swell, and would rather fingerprint a circum cratonic mantle lying beneath the west border of the Murzuq craton (Libya).
ISSN: 0899-5362

hal-01054340
https://hal.archives-ouvertes.fr/hal-01054340
DOI : 10.1016/j.jafrearsci.2013.12.001

Éditeur(s) : HAL CCSD Taylor & Francis: SSH Journals
Résumé : International audience
We analysed stroke phases and arm and leg coordination during front crawl swimming with and without a wet suit. Twelve nationally and internationally ranked French male triathletes performed three swim trials in randomized order using the front crawl stroke with and without a wet suit. All triathletes swam at three different swim velocities, corresponding to the paces appropriate for the 800 m (V800), 100 m (V100) and 50 m (V50) events. The different stroke phases and arm and leg coordination were identified by video analysis. Arm coordination was quantified using a new index of coordination, which expresses the three major modalities of opposition, catch-up and superposition in swimming. At all swim velocities, no significant differences in leg movements with or without the wet suit were noted. However, the wearing of the wet suit was associated with a significantly greater stroke length at the paces appropriate for the 100 and 50 m events (+3.46% and +3.10% at V100 and V50, respectively; P<0.01); a significantly greater stroke index at all three velocities (+5.18%, +5.21% and +5.91% at V800, V100 and V50, respectively; P<0.01); a significantly shorter pulling phase (-10.97%; P<0.05) and lower index of coordination (-21.87%; P<0.01) at the pace appropriate for the 800 m; and a significantly greater entry and catch phase (+9.81%; P<0.05) at the pace appropriate for the 100 m. We conclude that the wet suit amplified the coordination mode of the triathletes (i.e. catch-up coordination) without modifying stroke rate, recovery phase or leg movements.
ISSN: 0264-0414

hal-00720724
https://hal.univ-antilles.fr/hal-00720724

Éditeur(s) : HAL CCSD BioMed Central
Résumé : International audience
BACKGROUND: Few studies have considered using environmental amenities to explain social health inequalities.Nevertheless, Green spaces that promote good health may have an effect on socioeconomic health inequalities. In developed countries, there is considerable evidence that green spaces have a beneficial effect on the health of urban populations and recent studies suggest they can have a positive effect on pregnancy outcomes. To investigate the relationship between green spaces and the spatial distribution of infant mortality taking account neighborhood deprivation levels. METHODS: The study took place in Lyon metropolitan area, France. All infant deaths that occurred between 2000 and 2009 were geocoded at census block level. Each census block was assigned greenness and socioeconomic deprivation levels. The spatial--scan statistic was used to identify high risk cluster of infant mortality according to these neighborhood characteristics. RESULTS: The spatial distribution of infant mortality was not random with a high risk cluster in the south east of the Lyon metropolitan area (p<0.003). This cluster disappeared (p=0.12) after adjustment for greenness level and socioeconomic deprivation, suggesting that these factors explain part of the spatial distribution of infant mortality. These results are discussed using a conceptual framework with 3 hypothetical pathways by which green spaces may have a beneficial effect on adverse pregnancy outcomes: (i) a psychological pathway, (ii) a physiological disruption process and (iii) an environmental pathway. CONCLUSIONS: These results add some evidence to the hypothesis that there is a relationship between access to green spaces and pregnancy outcomes but further research is required to confirm this.
BMC Pregnancy and Childbirth

hal-00876083
https://hal.archives-ouvertes.fr/hal-00876083
https://hal.archives-ouvertes.fr/hal-00876083/document
DOI : 10.1186/1471-2393-13-191

Éditeur(s) : HAL CCSD National Institute of Environmental Health Sciences (NIEHS) National Institute of Environmental Health Sciences
Résumé : International audience
Long-term exposure to persistent pollutants with hormonal properties (endocrine-disrupting chemicals, EDCs) may contribute to the risk of prostate cancer (PCa). However, epidemiological evidence remains limited. We investigated the relationship between PCa and plasma concentrations of universally widespread pollutants, in particular p,p'-dichlorodiphenyl dichloroethene (DDE) and the non-dioxin like polychlorinated biphenyl congener 153 (PCB153). We evaluated before treatment 576 men with newly diagnosed PCa and 655 controls in Guadeloupe (French West Indies). Exposure was analyzed according to case-control status. Associations were assessed by unconditional logistic regression analysis, controlling for confounding factors. Missing data were handled by multiple imputation. We estimated a significant positive association between DDE and PCa (adjusted odds ratio [OR] 1.53; 95% CI 1.02, 2.30 for the highest versus lowest quintile of exposure; PTrend = 0.01). PCB153 was inversely associated with PCa (OR 0.30; 95% CI 0.19, 0.47 for the highest versus lowest quintile of exposure values; PTrend < 0.001). Also, PCB153 was more strongly associated to low-grade than high grade PCa. Associations of PCa with DDE and PCB153 were in opposite directions. This may reflect differences in the mechanisms of action of these EDCs, and although our findings need to be replicated in other populations, they are consistent with complex effects of EDCs on human health.
ISSN: 0091-6765

hal-01118553
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01118553
DOI : 10.1289/ehp.1408407
PUBMED : 25493337

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We present GPS observations in Morocco and adjacent areas of Spain from 15 continuous (CGPS) and 31 survey-mode (SGPS) sites extending from the stable part of the Nubian plate to central Spain. We determine a robust velocity field for the W Mediterranean that we use to constrain models for the Iberia-Nubia plate boundary. South of the High Atlas Mountain system, GPS motions are consistent with Nubia plate motions from prior geodetic studies. We constrain shortening in the Atlas system to <1.5 mm/yr. 95% confidence level. North of the Atlas Mountains, the GPS velocities indicate Nubia motion with respect to Eurasia, but also a component of motion normal to the direction of Nubia-Eurasia motion, consisting of southward translation of the Rif Mountains in N Morocco at rates exceeding 5 mm/yr. This southward motion appears to be directly related to Miocene opening of the Alboran Sea. The Betic Mountain system north of the Alboran Sea is characterized by WNW motion with respect to Eurasia at 1-2 mm/yr. paralleling Nubia-Eurasia relative motion. In addition, sites located in the Betics north of the southerly moving Rif Mountains also indicate a component of southerly motion with respect to Eurasia. We interpret this as indicating that deformation associated with Nubia-Eurasia plate motion extends into the southern Betics, but also that the Betic system may be affected by the same processes that are causing southward motion of the Rif Mountains south of the Alboran Sea. Kinematic modeling indicates that plate boundary geometries that include a boundary through the Straits of Gibraltar are most compatible with the component of motion in the direction of relative plate motion, but that two additional blocks (Alboran-Rif block, Betic Mountain block), independent of both Nubia and Eurasia are needed to account for the motions of the Rif and Betic Mountains normal to the direction of relative plate motion. We speculate that the southward motions of the Alboran-Rif and Betic blocks may be related to mantle flow, possibly induced by southward rollback of the subducted Nubian plate beneath the Alboran Sea and Rif Mountains.
ISSN: 0264-3707

hal-00475538
https://hal.archives-ouvertes.fr/hal-00475538
DOI : 10.1016/j.jog.2009.10.007

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In this study, we report new U-Pb zircon ages and amphibole and biotite 40Ar-39Ar cooling ages for igneous and metaigneous rocks from the eastern portion of the Borborema Province (NE Brazil). We combine these results with preliminary thermobarometric estimates and existing data to place constraints on the timing and duration of the Brasiliano-Pan-African Orogeny in northeastern Brazil and on the subsequent late- to post-orogenic history. The Alcantil orthogneiss contains a complex zircon population, but the youngest concordant analyses yielded an age of 632 ± 17 Ma (2σ). These grains have low Th/U ratios (<0.1), and the age of 632 Ma is therefore interpreted as dating the metamorphic event responsible for the acquisition of the gneissic fabric. In the Caruaru biotite amphibole orthogneiss, concordant analyses provided an age of 618 ± 4 Ma (2σ), which we relate to emplacement of the protolith of the Caruaru orthogneiss. Together with available U-Pb data from the literature, the 632-600 Ma age range is regarded as dating development of a regional flat-lying foliation coeval with high-grade metamorphism (upper amphibolite facies conditions). The 586 ± 3 Ma age (2σ) of the Panelas pluton is similar to those of other granitic plutons associated with a voluminous plutonism of high-K calc-alkaline to shoshonitic nature that occurred at 590-580 Ma. This plutonism slightly predated or was synchronous with development of large strike-slip shear zones. Amphibole grains yielded 40Ar-39Ar ages ranging from 584 ± 4 Ma to about 530 Ma, suggesting that regional temperatures remained near the closing temperature of this mineral (≈500 °C) for a long time. Most 40Ar-39Ar biotite ages range from 552 to 533 Ma, but two samples yielded plateau ages of 519 ± 5 Ma and 509 ± 5 Ma. The inferred rather slow cooling of the studied region possibly reflects low rates of unroofing, allowing persistence of a protracted thermal anomaly caused by the massive injection of magmas at the end of the Neoproterozoic.
ISSN: 0895-9811

hal-00745698
https://hal.archives-ouvertes.fr/hal-00745698
DOI : 10.1016/j.jsames.2012.06.003

Éditeur(s) : HAL CCSD National Institute of Environmental Health Sciences
Résumé : International audience
BACKGROUND: Glycol ethers are present in a wide range of occupational and domestic products. Animal studies have suggested that some of them may affect ovarian function. OBJECTIVE: To study the relation between women's exposure to glycol ethers and time to pregnancy. METHODS: Urine from randomly selected women in the PELAGIE mother-child cohort who had samples collected before 19 weeks of gestation was tested to measure eight glycol ether metabolites by chromatography coupled to mass spectrometry. Time to pregnancy was collected at the beginning of the pregnancy by asking women how many months they took to conceive. Associations between metabolite levels and time to pregnancy were estimated in 519 women with complete data using discrete-time Cox proportional hazards models to adjust for potential confounders. RESULTS: Glycol ether metabolites were detected in 6% (for ethoxyacetic acid) to 93% (for phenoxyacetic and butoxyacetic acids) of urine samples. Phenoxyacetic acid was the only metabolite with a statistically significant association with longer time to pregnancy (fecundability OR 0.82; 95% CI: 0.63, 1.06 for the second and third quartile combined; fecundability OR 0.70; 95% CI: 0.52, 0.95 for a fourth-quartile (≥1.38 mg/L) vs. first-quartile concentration (<0.14 mg/L)). This association remained stable after multiple sensitivity analyses. CONCLUSION: Phenoxyacetic acid, which was present in most of the urine samples tested in our study, was associated with increased time to pregnancy. This metabolite and its main parent compound, 2-phenoxyethanol, are plausible causes of decreased fecundability, but may also be surrogates for potential co-exposures frequently present in cosmetics.
ISSN: 0091-6765

hal-00866023
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00866023
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00866023/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00866023/file/Urinary_Glycol_Ether-accepted.pdf
DOI : 10.1289/ehp.1206103

Éditeur(s) : HAL CCSD ACSM
Résumé : International audience
PURPOSE AND METHODS: This study was designed to compare the physiological responses and performance of well trained cyclists riding with two different chainring designs, round or eccentric, during a brief and intense cycling exercise: an "all-out" 1-km laboratory test. The eccentrically designed chainring was made of two crank arms sliding into each other, with the inside arm fixed on the center of the arm of a circular chainring and the outside arm sliding along the inside and revolving around an elliptical cam. This design increases crank arm length at the downstroke and decreases it during the upstroke, thus increasing and decreasing the torque. In terms of the chainring's revolution, the crank arm length at 0 degrees and 180 degrees is similar to the arm length of circular chainrings (175 mm). However, during the downstroke (0-180 degrees ), it increases to its maximum length of 200 mm at 90 degrees and then returns to its original length of 175 mm at 180 degrees. During the upstroke, it decreases to a minimum length of 150 mm at 270 degrees and then increases to 175 mm at 360 degrees. Eleven cyclists performed an all-out 1-km laboratory test using each chainring. The study was conducted over two consecutive weeks with the order of chainring use randomized. During all trials, ventilatory data were collected every minute using an automated breath-by-breath system. Heart rate was measured using a telemetry system. RESULTS: None of the cardiorespiratory variables showed significant differences between chainring trials. Performance, however, was significantly improved using the eccentric design (64.25 +/- 1.05 vs 69.08 +/- 1.38 s, P < 0.004, with the eccentric and the round design, respectively). CONCLUSION: We concluded that the eccentric chainring significantly improved the cycling performance during an all-out 1-km test. Further testing with indoor cycling specialists performing on a velodrome would be helpful to define the maximal possibilities of such a chainring.
Medicine & Science in Sports & exercise

hal-00720551
https://hal.univ-antilles.fr/hal-00720551
https://hal.univ-antilles.fr/hal-00720551/document
https://hal.univ-antilles.fr/hal-00720551/file/Article.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Melt generation in the continental crust is thought to significantly influence seismic bulk velocities and anisotropy, although existing laboratory data provide limited constraints on such seismic attributes. In this study we measured ultrasonic compressional wave speeds (Vp) and anisotropy during sample compaction, mica-breakdown and melt-generation in synthetic, foliated quartz–muscovite aggregates. Measurements were performed at peak conditions of 300 MPa hydrostatic confining pressure and 750 °C, over a six hour time period, for three separate samples where wave propagation directions were aligned at 0°, 45° and 90° with respect to the foliation plane. The experiments are initially marked by sample compaction and rapid reduction in porosity (from 25% to <2 vol%), with a corresponding increase in Vp. During initial stages of the experiment Vp ranges from 4.65 to 5.45 km/s, depending on the direction of the P wave propagation, resulting in up to ∼16% anisotropy, which originates mainly from the preferred orientation of muscovite and possible incipient melt lenses oriented parallel to foliation. As the experiment progresses the bulk Vp decreases gradually and Vp anisotropy drops from ∼16% to ∼2% after five hours into the experiment. The drop in anisotropy is caused by muscovite-breakdown and increasing amount of partial melting of the aggregate. The bulk velocities are considerably lower than predicted for a mixture of muscovite and β-quartz (stable at 300 MPa and 750 °C). Thermodynamic modeling indicates that mica breakdown and production of melt with ∼2 wt% dissolved water in the aggregate can explain the low Vp, even though β-quartz is stable; the modeled Vp is ∼4.75 km/s at 300 MPa and 750 °C. These ultrasonic attributes signify movement of the melt to fill vacant pores and coating grain boundaries, effectively connecting melt films and reducing seismic anisotropy. The results may apply to regions where crustal melting is on-going, in particular regions of elevated temperature that are only weakly deforming, with coupled anomalously low bulk velocities and seismic anisotropy.
ISSN: 0012-821X

hal-01243569
https://hal.archives-ouvertes.fr/hal-01243569
DOI : 10.1016/j.epsl.2015.05.039

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
Background: Squamous cell carcinoma (SCC) is considered the most frequent skin cancer in black people. Its incidence is not known in the Afro-Caribbean population.Objective: To assess the incidence of SCC in Guadeloupe, the largest island of the Lesser Antilles (405 000 inhabitants, mostly black people of African and European descent). The second objective was to characterize clinical and histological patterns of SCC occurring in the Afro-Caribbean community.Methods: This retrospective study was conducted over an 11-year period (2000-2010). Data regarding 723 histological confirmed cases of SCC identified using the three Guadeloupean pathology laboratories computerized databases were retrieved from the records of 551 patients. Private practice dermatologists and general practitioners were contacted to obtain any missing data. Results: The annual age-adjusted incidence of SCC was 15 per 100.000 residents in Guadeloupe. In the Afro-Caribbean community, SCC had a greater size (i.e.: 2.8±2.8 cm versus 1.5±1.0 cm, p<0.001), was more often located on the anogenital area (i.e. :48/79-60.8% versus 14/320-4.4%, p<0.001) in association with an underlying dermatosis due to HPV infection (15/71- 21.1% versus 3/366, 0.8%, p<0.001) and led more frequently to metastasis (13/84-15.5% versus 10/366-2.7%, p<0.001) and/or fatal evolution (11/83-13.3% versus 7/365-1.9%, p<0.001). Conclusions: The results of this original study, which first estimated the incidence of SCC in West Indies, suggest that anogenital examination should be routinely performed in skin cancer screening of Afro-Caribbean people in order to detect the presence of SCC at an early stage.
ISSN: 0926-9959

inserm-01513116
http://www.hal.inserm.fr/inserm-01513116
http://www.hal.inserm.fr/inserm-01513116/document
http://www.hal.inserm.fr/inserm-01513116/file/2017%2C%20Cordel%20-%20Squamous%20cell%20carcinoma%20in%20the%20Afro-Caribbean%20community.pdf
http://www.hal.inserm.fr/inserm-01513116/file/CordeletalJ%20Eur%20Acad%20Dermatol%20Venereol2017.pdf

Éditeur(s) : HAL CCSD Université des Antilles
Résumé : International audience
The history of international tourism of the last fifty years can be divided into three stages: 1 / decades from 1950 to 1980, characterized by a progressive democratization of tourism supported by an unparalleled economic growth, 2 / the last decade of the twentieth century, euphoria of a tourist who sees the borders open. The end of a bipolar world announcement many hopes naive. The scope of territories open to tourism continues to widen. 3 / The end of the century announces the age of maturity of tourism. After the euphoria, illusions and disillusions of a space tourist world without borders, facts, often dramatic raised awareness tourists to the complexity of a world where wars have never ceased. The global space tourism is articulated around three regional basins: more than 75% of international tourist flows, driven by the rich European cities, North American and Asian, are confined to their regional area of origin. The distribution of tourist flows draws an organization into three distinct basins: in order of importance, 1 / Euro-Mediterranean basin, focusing on the Mediterranean Sea, 2 / Basin East Asia-Pacific, around the shores of the Sea of China, 3 / basin North America-Caribbean, organized around the "American Mediterranean." Space discontinuities increase between peripheries unstable, extensions selective and margins forgotten or excluded. The climate of insecurity that affect certain touristic territories aimed at weakening the outskirts most sensitive and oblige the international space tourist to retract.
L’histoire du tourisme international des cinquante dernières années peut être décomposée en trois temps : 1/ les décennies de 1950 à 1980, caractérisées par une démocratisation progressive du tourisme soutenue par une croissance économique inégalée ; 2/ la dernière décennie du vingtième siècle, celle d’une euphorie touristique qui voit les frontières s’ouvrir. La fin d’un monde bipolaire annonce bien des espoirs naïfs. Le champ des territoires ouverts au tourisme ne cesse de s’élargir. 3/ La fin du siècle annonce l’âge de maturité du tourisme. Après l’euphorie, les illusions et les désillusions d’un espace touristique mondial sans frontières, les faits, souvent dramatiques ont fait prendre conscience aux touristes la complexité d’un monde où les guerres n’ont jamais cessé. L’espace touristique mondial est articulé autour de trois bassins régionaux : plus de 75 % des flux touristiques internationaux, impulsés par les riches métropoles européennes, nord-américaines et asiatiques, se cantonnent à dans leur espace régional d’origine. La distribution des flux touristiques dessine une organisation en trois bassins distincts : par ordre d’importance, 1/ le bassin euro-méditerranéen, centré sur la Mer méditerranée, 2/ le bassin Asie orientale-Pacifique, autour des rivages de la mer de Chine, 3/ le bassin Amérique du Nord — Caraïbes, organisé autour de la « Méditerranée américaine ». Les discontinuités s’affirment entre des périphéries mal stabilisées, des prolongements très sélectifs, des marges oubliées ou exclues. Les climats d’insécurité qui touchent certains territoires touristiques visent à fragiliser des périphéries plus sensibles et contraignent l’espace touristique international à se rétracter.
ISSN: 1779-0980

hal-01624746
https://hal.archives-ouvertes.fr/hal-01624746
DOI : 10.4000/etudescaribeennes.882

Éditeur(s) : HAL CCSD
Résumé : site web du Colloque disparu
Parmi les stratégies innovantes visant à promouvoir des agricultures doublement performantes, figure l’utilisation de la biodiversité. Dans cet article, nous nous interrogeons sur les processus d’apprentissage qui favorisent la conception « intelligente » de systèmes de culture. A partir de l’exemple de la valorisation des mycorhizes indigènes à la Martinique (symbioses entre plantes et champignons du sol), nous déterminons les freins et les leviers à la co-construction et à l’adoption d’innovations de rupture pour la modernisation écologique de l’agriculture. Les résultats d’une démarche participative conduite avec un échantillon d’agriculteurs ouverts aux pratiques agroécologiques montrent que l’importance et la nature des freins diffèrent selon la dynamique d’apprentissage dans laquelle ils s’insèrent. Ainsi, les « mieux apprenants » passent plus facilement de la phase de partage de connaissances (K) à la conception d’innovations (C) en identifiant mieux que les « moins apprenants » les leviers d’action (P) à mettre en œuvre.
51. Colloque ASRDLF : Métropolisation, cohésion et performance, quels futurs pour nos territoires ?
Marne La Vallée, France

hal-01606460
https://hal.archives-ouvertes.fr/hal-01606460
PRODINRA : 387727

Éditeur(s) : HAL CCSD EDP Sciences
Résumé : International audience
This paper reports the first outcomes of a research program “Environment and Sustainable Development in the Caribbean space” co-funded by the European Union, the Région Martinique and the Université des Antilles et de la Guyane under the European Union operational programme 2007-2013. Since the middle of the last century, the Caribbean countries, regardless of their great diversity and political fragmentation, are faced with the recurring problem of development. Having explored different paths, they are looking now for new development models. This challenge which becomes obsessive over the decades, is now a major concern: indeed, the Caribbean territories are per se vulnerable and highly exposed to natural risks due to climate change. In addition, this relates to areas where tensions between exploitation and conservation of a rich biodiversity are particularly strong. Based on the promotion of tourism and services as part of an “open regionalism” at the intersection of global and local scales of public action, the current development strategies give rise to a dual approach with, however, rather mixed results: on the one hand, a discursive use of sustainable development, apprehended through its environmental dimension, evidences a new way of looking at the region and a change in the way the region sees itself; on the other hand, a political use of sustainable development through cross-cutting policies, is hindered by the complexity of structures, the multiple levels of action and regulation, and the difficult appropriation of public-policy organization by local communities and people.
Cet article rend compte des premiers résultats d’un programme de recherche « Environnement et développement durable dans l’espace caraïbe » cofinancé par l’Union européenne, la région Martinique et l’Université des Antilles et de la Guyane dans le cadre des programmes opérationnels européens 2007-2013. Il montre que les territoires de la Caraïbe, après avoir exploré plusieurs voies en matière de développement, privilégient désormais des stratégies axées sur le tourisme et les services. S’inscrivant dans un « régionalisme ouvert » au croisement des échelles globale et locale d’intervention en matière d’action publique, ces stratégies débouchent sur une double démarche aux résultats contrastés : d’un côté, une mise en discours du développement durable, appréhendé notamment à travers sa dimension environnementale, témoigne d’un changement de regard sur la région et de celle-ci sur elle-même ; de l’autre, une mise en politique du développement durable à travers des dispositifs à caractère transversal, se heurte à la complexité des structures, à la multiplicité des échelles d’intervention et de régulation ainsi qu’à la difficile appropriation desdits dispositifs par les populations locales.
ISSN: 1240-1307

Droits : info:eu-repo/semantics/OpenAccess
hal-01675012
https://hal.univ-antilles.fr/hal-01675012
https://hal.univ-antilles.fr/hal-01675012/document
https://hal.univ-antilles.fr/hal-01675012/file/NSS_La%20mise%20en%20discours.pdf
DOI : 10.1051/nss/2015043

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
[1] The Pyrenees, north of the North Pyrenean fault, display a complex structure involving a succession of peridotite massifs, basement massifs, and mid-Cretaceous to Late Cretaceous basins located in a narrow domain, which was affected by a mid-Cretaceous, preorogenic, high-temperature, low-pressure metamorphism. The Late Cretaceous basins were interpreted either as pull-apart basins formed during transcurrent motion of Iberia relative to Eurasia or as remnants of a larger extensional basin. Recent models support that peridotite massifs result from the exhumation of the mantle during this preorogenic event. The northern boundary of the Agly basement massif shows evidence of ductile deformation of the basal formations of the Agly sedimentary cover. Macroscopic and microscopic kinematics indicators consistent with asymmetry of crystallographic fabrics suggest normal sense of shear and thus suggest detachment, at least partial, of the Mesozoic cover from its basement. Triassic to Early Cretaceous limestones are mylonitic and consistently shows a foliation, a NS- to NE-trending lineation, shear criteria suggesting top-to-the-north shearing and locally boudinage. At the microscopic scale, mylonites are characterized by a very fine grain size, frequently <10 µm. They contain larger, partially recrystallized calcite parent grains and undeformed quartz grains with calcite fringes crystallized in pressure shadows. In these mylonites, calcite systematically shows a weak but well-defined crystallographic-preferred orientations, suggesting HT dislocation creep combined to diffusion creep and possibly grain boundary sliding in the finest fraction of the mylonites. Paleotemperatures determined using Raman spectrometry suggest synkinematic temperature conditions in the range 340-390°C, in good agreement with observed microstructures and calcite CPO. The mylonitic fabric in Mesozoic limestones is folded by EW-trending Pyrenean folds north of the Agly basement massif, attesting that this fabric formed before the Pyrenean orogeny. These data consistently support preorogenic extension under medium-temperature conditions of the northern Agly massif and likely of the massif itself. Since simultaneously (~100 Ma) a mid-Cretaceous basin opened south of the basement massif, we suggest a model of preorogenic exhumation of the Agly massif in response to the regional extension associated to the rotation of Iberia. This model may explain the exhumation of the North Pyrenean massifs during a single preorogenic event that allowed the opening of extensional basins and the exhumation of the lithospheric mantle. All these structures being subsequently reworked during the Pyrenean orogeny.
ISSN: 0278-7407

hal-00852833
https://hal.archives-ouvertes.fr/hal-00852833
DOI : 10.1002/tect.20015

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
B-type olivine fabrics are pervasive within highly depleted dunites of the small-sized Imono peridotite body located within the subduction-type Sanbagawa metamorphic belt of the southwest Japan arc. The dunites contain various microstructures, ranging from porphyroclastic to fine-grained intensely sheared textures. The Mg/(Mg+Fe) atomic ratios (Fo number) of olivine within these dunites are consistently around 0.9, as are the Cr/(Cr+Al) atomic ratios (Cr number) of chromian spinel, suggesting their evolution from a highly depleted magma (boninite). These data provide strong thermal constraints on the formation of the highly depleted dunites,as their formation requires hot, hydrous, shallow mantle (> 1250 degrees C at < 30 km depth) in the mantle wedge. Because the Sanbagawa metamorphic belt finally entrained these peridotites during progressive retrogression, B-type olivine fabrics probably developed in the fore-arc side of the subduction zone, above or along the subducting slab, possibly in association with dehydration fluids derived from the slab. The previously documented small magnitude of S-wave splitting can be explained by the seismic properties of B-type peridotites within an anisotropic layer of approximately several kilometers in thickness, oriented by flow parallel to the subducting slab, under maximum temperatures of 880-1030 degrees C depending on the flow stress. These findings indicate that such a B-type layer could constitute a dominant source of seismic S- and P-wave anisotropy in mantle wedge regions. (c) 2008 Elsevier B.V. All rights reserved.
ISSN: 0012-821X

hal-00412594
https://hal.archives-ouvertes.fr/hal-00412594
DOI : 10.1016/j.epsl.2008.06.014

Éditeur(s) : HAL CCSD IOS Press
Résumé : International audience
The hematocrit-to-viscosity ratio (HVR) has been widely used has an estimate of red blood cell (RBC) oxygen transport effectiveness into the microvasculature or as an oxygen delivery index. However, no study investigated the possibility of HVR to truly reflect RBC oxygen transport effectiveness or to be an oxygen delivery index. We measured blood viscosity at high shear rate (225 s-1), hematocrit, HVR, as well as the microvascular oxyhemoglobin saturation (TOI; tissue oxygen index) by spatial resolved near-infrared spectroscopy (NIRS) at cerebral and muscle levels in three population known to have various degrees of hemorheological abnormalities: healthy subjects (AA), patients with sickle cell SC disease (SC) characterized by moderate anemia and patients with sickle cell anemia (SS) marked by severe anemia. At both the cerebral and muscle level, HVR was positively correlated with TOI (r = 0.28; p = 0.03 and r = 0.38; p = 0.003, at the cerebral and muscle level, respectively). These findings suggest that HVR probably play a key role in blood flow and hemodynamic regulation in the microvasculature, hence modulating the amount of oxygen available for tissues. Nevertheless, the strengths of the associations are weak (R2 < 0.50), suggesting that other determinants modulate microvascular blood flow and oxygenation, such as vascular geometry and vasomotor reserve.
ISSN: 1386-0291

inserm-01081701
http://www.hal.inserm.fr/inserm-01081701
http://www.hal.inserm.fr/inserm-01081701/document
http://www.hal.inserm.fr/inserm-01081701/file/2013%2C%20Waltz%20-%20Is%20there%20a%20relationship%20between%20the%20hematocrit-to-viscosity%20ratio%20and%20microvascular%20oxygenation%20in%20brain%20and%20muscle.pdf
PUBMED : 23719422

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The influence of redox alteration on the growth and proteomic pattern of Listeria monocytogenes was investigated. A redox shock was induced in cultures by addition of 3mM ferricyanide (FeCN) and 6mM dithiothreitol (DTT) to increase or to decrease respectively the redox potential naturally occurring at the beginning of growth. In both conditions, the reducing and oxidizing redox shock had a strong influence, decreasing the maximum growth rate by half compared to a control culture. The proteomic analysis of L. monocytogenes performed by two-dimensional difference gel electrophoresis (2D-DIGE) exhibited twenty-three proteins differentially expressed (P<0.05), among these, many were oxidoreductases, and proteins involved in cellular metabolism (glycolysis, protein synthesis), detoxification (kat) or adhesion (Lmo1634).
ISSN: 1874-3919

hal-00877138
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00877138
DOI : 10.1016/j.jprot.2012.11.010
PUBMED : 23195917

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Whole-rock concentrations of Se and Te were determined in 53 peridotite samples collected in orogenic bodies from the Eastern Pyrenees, including the Lherz massif (33 samples), the type-locality of Iherzolite. Orogenic Iherzolites tectonically emplaced into the continental crust escaped devolatilisation that may strongly alter concentrations of those volatile trace elements in basalt-hosted peridotite xenoliths. The Se and Te concentration ranges (<3.5-100.7 ppb; <1-11 ppb) are consistent with the few analyses of mantle samples yet available, yet extending to higher Se concentrations. In-situ analyses performed by LAM-ICPMS on base metal sulfides indicate that the Se budget is controlled by sulfides whereas a large fraction of Te (50 +/- 30%) does not reside in sulfides. The missing fraction is accounted for by fractional crystallization of Pt-Pd tellurides from Cu-Ni sulfide melts. A maximum of one third of the S budget of Eastern Pyrenean peridotites was added by assimilation of crustal sulfides, which crystallized as pyrite. Disregarding those contaminated samples, some features of the Se and Te systematics (e.g. bivariate plots vs. fertility index) cannot be explained by partial melting processes. The best fit for 33 peridotites (mostly from Lherz) yields higher than chondritic S/Se (3.1213 +/- 500; r(2) = 0.96) for near chondritic Se/Te (8.6 +/- 2; r(2) = 0.9). Our study suggest that such superchondritic S/Se ratios are better explained by petrogenetic processes involving refertilization of harzburgitic lithosphere by metal (Cu,Ni)-rich sulfide melts precipitated along with clinopyroxene and Al-spinel from silicate melts en-route to the surface.
ISSN: 0009-2541

hal-00544577
https://hal.archives-ouvertes.fr/hal-00544577
DOI : 10.1016/j.chemgeo.2010.09.007