Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
To quantify the seismic properties of lower crustal rocks and to better constrain the origin of the lower crustal seismic reflectivity, we determined the complete 3-D seismic properties of a lower crustal section. Eight representative samples of the main lithologic and structural units outcropping in the Val Sesia (Ivrea zone) were studied in detail. The seismic velocities were calculated using the single crystal stiffness coefficients and the lattice preferred orientation (LPO) of each mineral in all samples. The 21 stiffness coefficients characterizing the elastic behaviour of each rock are determined. Mafic and ultramafic rocks such as pyroxenite and pyroxene-bearing gabbros display complex shear wave properties. These rocks are weakly birefringent (maximum 0.1 kms-1) and it is difficult to find consistent relationships between the seismic properties and the rock structure. On the other hand, seismic properties of deformed felsic rocks are essentially controlled by mica. They display strong S-wave birefringence (0.3 km s-1) and relatively high Vp anisotropy (7.6 per cent). Amphibole also strongly influences the rock birefringence patterns. For both kind of rocks, the foliation is highly birefringent and the fast polarized shear wave is systematically oriented parallel to the foliation. We show that the number of mineral phases in the rock strongly controls the anisotropy. The seismic anisotropy has a complex role in the P-wave reflectivity. Compared to the isotropic case, anisotropy enhances the reflection coefficient for about 60 per cent of the possible lithological interfaces. For 40 per cent of the interfaces, the reflection coefficient is much lower when one considers the medium as anisotropic.
ISSN: 0956-540X

hal-01389122
http://hal.univ-reunion.fr/hal-01389122
http://hal.univ-reunion.fr/hal-01389122/document
http://hal.univ-reunion.fr/hal-01389122/file/Barruol_3D_velocities_GJI1993.pdf
DOI : 10.1111/j.1365-246X.1993.tb01519.x

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
The hydraulic and electrical properties of pyroclastic rocks have been investigated in laboratory on a representative sampling of Montagne Pelée (Martinique, France) deposits with renewed interest in geophysical applications. This sampling covers all the lithologic units of this volcano: lava dome and lava flows, pumices from ash-and-pumice fall and flow deposits, lava blocks from block-and-ash flow and Peléean “nuées ardentes” deposits, scoriae from scoria flow deposits. The connected porosity varies over a wide range from 3 to 62%. The unconnected porosity is important only on pumices where it can reach 15%. The permeability covers more than 5 orders of magnitude, ranging from 10−16 to 35 × 10−12 m2. The higher values are obtained on lava blocks and the scoriae, even if these rocks are less porous than the pumices. The formation factor ranges from 7 to 1139. The transport properties of these rocks are slightly correlated with porosity. This indicates that these properties are not only controlled by the connected porosity. To connect the transport properties to the textural characteristics of the pore network of pyroclastic rocks, different models, based on geometrical considerations or percolation theory, were tested. The pore access radius distribution and the tortuosity control the transport properties of pyroclastic rocks. Consequently, the models (electric and hydraulic) based on the concept of percolation (e.g., the models of Katz and Thompson), apply better than the equivalent channel model of Kozeny-Carman. In addition, the difference in transport properties observed on lava blocks and pumices confirms that the mechanisms of degassing and vesiculation are different for these two types of rock.
ISSN: 2169-9313

hal-00310237
https://hal.archives-ouvertes.fr/hal-00310237
DOI : 10.1029/2006JB004385, 2007

Éditeur(s) : HAL CCSD American Physical Society
Résumé : International audience
It is getting increasingly evident that physical properties such as elastoviscoplastic properties of living materials are quite important for the process of tissue development, including regulation of genetic pathways. Measuring such properties in vivo is a complicated and challenging task. In this paper, we present an instrument, a scanning air puff tonometer, which is able to map point by point the viscoelastic properties of flat or gently curved soft materials. This instrument is an improved version of the air puff tonometer used by optometrists, with important modifications. The instrument allows one to obtain a direct insight into gradients of material properties in vivo. The instrument capabilities are demonstrated on substances with known elastoviscoplastic properties and several biological objects. On the basis of the results obtained, the role of the gradients of elastoviscoplastic properties is outlined for the process of angiogenesis, limb development, bacterial colonies expansion, etc. which is important for bridging the gaps in the theory of the tissue development and highlighting new possibilities for tissue engineering, based on a clarification of the role of physical features in developing biological material.
ISSN: 1539-3755

hal-00666187
https://hal.archives-ouvertes.fr/hal-00666187
https://hal.archives-ouvertes.fr/hal-00666187/document
https://hal.archives-ouvertes.fr/hal-00666187/file/FLEURY_PRE_2010.pdf
DOI : 10.1103/PhysRevE.81.021920

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Nanotribological properties of NbSe2 are studied using an atomic friction force microscope. The friction force is measured as a function of normal load and scan speeds ranging from 10 nm s−1 to 40 μm s−1 under two atmospheres (air and argon). At low speed, no effect of atmosphere is noticed and a linear relationship between the friction and normal forces is observed leading to a friction coefficient close to 0.02 for both atmospheres. At high speed, the tip/surface contact obeys the JKR theory and the tribological properties are atmosphere dependent: the shear stress measured in air environment is three times lower than the one measured under argon atmosphere. A special attention is paid to interpret these results through numerical data obtained from a simple athermal model based on Tomlinson approach.
ISSN: 1023-8883

hal-00780496
https://hal.archives-ouvertes.fr/hal-00780496
https://hal.archives-ouvertes.fr/hal-00780496/document
https://hal.archives-ouvertes.fr/hal-00780496/file/Delbe_6345.pdf
DOI : 10.1007/s11249-008-9400-8

Éditeur(s) : HAL CCSD Elsevier
Résumé : Reliable measurements of the intensity of the palaeomagnetic field are notoriously difficult to obtain. The approach generally taken is to produce multiple estimates per rock unit and assume that those which meet certain minimum standards of technical quality will combine to produce an accurate mean. However, here, using results produced from a package of 20th century basaltic lava flows from Mount Etna in Sicily, we demonstrate that this approach can fail. In this case, the application of typical sets of selection criteria actually introduces bias into the mean determination that we measure. We demonstrate that this is caused by two types of non-ideal behaviour acting in combination. The first is a result of the multidomain grains that the samples contain and the second is caused by differences in the natural and laboratory cooling rates. We discuss means of avoiding these sources of error in future palaeointensity studies performed on ancient rocks. We also develop a new, more general reliability criterion which is effective here and which we argue should be applied wherever possible in future palaeointensity studies in conjunction with standard criteria. It requires two distinct types of materials which both produce some good-quality palaeointensity measurements and uses their range of overlap to constrain the true palaeointensity. Both the application of this criterion and general reliability considerations require that future palaeointensity studies should measure many samples per cooling unit and that these should be as diverse in terms of their rock magnetic properties and cooling histories as possible.
ISSN: 0012-821X

hal-00407943
https://hal.archives-ouvertes.fr/hal-00407943
DOI : 10.1016/j.epsl.2007.03.017

Éditeur(s) : HAL CCSD Copernicus Publications
Résumé : International audience
During Ocean Drilling Program Leg 134, a mixed sequence of volcaniclastic and carbonate sediments was cored together with basaltic breccias and a single basalt sill in Hole 833B. In this study, data from Schlumberger's Geochemical Logging Tool, together with physical property logs, characterise part of the section and establish a complete log-derived lithostratigraphy. The major transition between the sedimentary rocks and a basaltic sill at 830 mbsf (metres below sea floor) is clearly seen as well as the distinction between the silicate-rich sediments and the carbonate-rich part of the section. The transition between the volcanic sandstone interbedded with basaltic and sed-lithic breccia of Unit III, and the volcanic sandstone of Unit IV is clearly marked by the physical property logs. The accuracy of the logging data was evaluated and discussed with an improved log versus core correlation. The cluster analysis of the complete data set shows a correlation with the data provided by the mechanical caliper device, which in turn indicates the quality of the borehole.
ISSN: 1816-8957

hal-00642165
http://hal.upmc.fr/hal-00642165
http://hal.upmc.fr/hal-00642165/document
http://hal.upmc.fr/hal-00642165/file/Rabaute_et_al-SciDrilling-1997.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Numerical programs for simulating flow and reactive transport in porous media is essential for predicting reservoir properties related to CO2 sequestration performance, subsurface storage and risk assessment. In this paper we solve the Navier Stokes' equation using finite difference method, on a simulated porous rock structure, to study the velocity distribution of fluid flowing through it under a constant pressure gradient. A reactive solute carried through the fluid is allowed to interact with the minerals in the rock. This chemical reaction dissolves the mineral which changes the rock structure thus affecting its flow properties. These changes of flow properties are studied with variation in reactive solute concentration and pressure field. The different mechanisms of dissolution responsible for the variation of flow properties for the different parameters is predicted. Before the onset of homogeneous dissolution, variation in porosity follows a power-law behaviour with change in permeability when the latter is scaled by the concentration of the reactive species. The simulation results are compared with available experimental data and found to give a reasonable match.
ISSN: 0022-1694

hal-00757760
https://hal.archives-ouvertes.fr/hal-00757760
DOI : 10.1016/j.jhydrol.2012.05.024

Éditeur(s) : HAL CCSD American Geophysical Union (AGU) AGU and the Geochemical Society
Résumé : International audience
To study how an impacting plume modifies the mantle lithosphere, we analyzed the microstructures and crystal preferred orientations (CPO) of 29 peridotites and 37 pyroxenites that sample the mantle root of the Ontong Java Plateau (OJP) from 60 to 120 km depth. The peridotites show a strong compositional variability, but homogeneous coarse granular to tabular microstructures, except for those equilibrated at the shallowest and deepest depths, which are porphyroclastic. All peridotites have clear olivine CPO, with dominant fiber-[010] patterns. Low intragranular misorientations and straight grain boundaries in olivine suggest that, above 100 km depth, annealing often followed deformation. Calculated density and P wave velocities of the peridotites decrease weakly with depth. S wave velocities decrease faster, resulting in increasing Vp/Vs ratio with depth. Calculated densities and seismic velocity profiles are consistent with those estimated for normal mantle compositions under a cold oceanic geotherm. Enrichment in pyroxenites may further increase seismic velocities. The calculated seismic properties cannot therefore explain the low S waves velocities predicted by Rayleigh wave tomography and ScS data in the mantle beneath the OJP. Calculated P and S waves anisotropy is variable (2–12%). It is higher on average in the deeper section of the lithosphere. Because olivine has dominantly [010]-fiber CPO patterns, if foliations are horizontal, vertically propagating S waves and Rayleigh waves will sample very weak anisotropy in the OJP mantle lithosphere. Moreover, if the orientation of the lineation changes with depth, the anisotropy-induced contrast in seismic properties might produce an intralithospheric reflector marking the stratification of the OJP mantle root.
ISSN: 1525-2027

hal-01116428
https://hal.archives-ouvertes.fr/hal-01116428
DOI : 10.1002/2014GC005452

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This paper examines the thermal properties of cement composites reinforced with vegetable bagasse fibres (1.5% and 3% wrtc). Thermal properties have been correlated to macroscopic density and porosity in order to estimate thermal conductivity of fibres using a calculation inspired from the Maxwell-Eucken modelling. Experimental investigations reveal that adding retified bagasse fibres reduces composites thermal conductivity and yields a weaker specific heat in comparison with composites made with alkaline bagasse fibres. Moreover, the more the fibres, the lighter the specimen; lower its thermal conductivity and lower its specific heat. Thermal conductivity of alkaline fibres is lower than retified fibres one.
ISSN: 1359-835X

hal-00809831
https://hal.univ-antilles.fr/hal-00809831
DOI : 10.1016/j.compositesa.2010.01.002

Éditeur(s) : Université de la Rochelle
Résumé : In order to better understand the functioning of the Brouage intertidal mudflat (Marennes- Oléron Basin, France), its carbon-based trophic web has been modelled and analyzed. The foodweb building is based on the 4 step method of Inverse Analysis: 1) conceive an a priori model as the graph of compartments (nodes) between which exist fluxes of material (vertices). These vertices are the unknowns for the problem; 2) gather all the existing knowledge about the ecosystem and translate it into linear equations and inequalities involving the fluxes; 3) complete this set of data by common knowledge on the behaviour of the compartments and translate it into inequalities, 4) solve the obtained linear system under the parsimony principle to find a unique solution vector. The food-web analysis is based on. The first purpose of this work was a methodological one: inverse analysis method has been adapted to consider the seasonal and spatial variability of the temperate ecosystem: two seasons have been coupled in the computation and the area has been divided into three geographical zones along a cross-shore gradient. Hence, two types of physical exchanges are involved: the benthicpelagic ones and the advection ones. Statistical results can also be obtained by coupling Monte Carlo methods to Inverse Analysis. To study the obtained networks, new indices based on Markov Chains take delay into account in describing integrative transfers of material between compartments. This lets emerge the systems' properties that are not obvious at first sight and emphasizes the role of peculiar components. The second purpose was to apply such methods to the Brouage mudflat ecosystem in order to better understand its functioning. As the knowledge and methods evolve, various food webs were computed and analyzed with the help such indices and existing ones. Sensitivity analyses allow to point at the most crucial lacks of knowledge, which can orientate future field research. New data would improve the quality of the model in two ways: one the one hand, they would validate or invalidate the outcomes and on the other hand, they would give useful information to better constrain some of the black boxes and most uncertain fluxes, especially the advection and vertical flows. The main results of the study show a strongly seasonal system in which benthic and pelagic components are linked with intensity. The system is driven by its high local benthic primary production, but also depends on imports from the basin. Each of the 3 geographic zones has a peculiar functioning. The central zone corresponds to the classical description of European intertidal mudflats: very productive, it can feed the other regions. It is a production zone. The upper part is less productive but is fed by the middle one via the water column and can be exploited by shorebirds. It is a degradation zone (material is transformed for less qualitative). The lower part strongly depends on the basin imports for its functioning, as the cultivated bivalves act as a pump for pelagic material of which a great part is deposited under the cultivation structures (oyster racks or mussels "bouchots"). It is a transformation zone.
Un double objectif (méthodologique et appliqué) a été visé par une modélisation du réseau trophique de la vasière de Brouage (Bassin de Marennes Oléron, France) à l'aide de l'analyse inverse, et son étude à l'aide de l'analyse des réseaux. L'Analyse Inverse permet en effet de reconstruire l'ensemble du réseau à partir de données éparses, le problème du manque de données étant récurrent en Ecologie. Au plan méthodologique, l'analyse inverse a été adaptée à la prise en compte des caractères saisonnier et spatialement hétérogène d'un écosystème tempéré de zone intertidale : deux saisons ont ainsi été couplées et la vasière a été considérée le long d'un transect perpendiculaire au rivage et divisé en trois zones spatiales. Deux types de flux physiques interviennent donc : les flux verticaux de dépôt et remise en suspension, et les flux d'advection via la colonne d'eau. Des pistes d'amélioration et de nouvelles méthodes sont proposées. Un résultat sous forme statistique peut être obtenu en couplant l'utilisation de méthodes de Monte Carlo à l'analyse inverse pour la construction des réseaux trophiques. Les moyens d'étude des modèles ont été enrichis par la mise au point d'indices issus de la construction de chaînes de Markov et prenant en compte le caractère temporel des transferts de matière entre compartiments. Enfin, la transformation mathématique du modèle statique pour une étude dynamique de la stabilité de l'équilibre décrit est abordée. Plusieurs modèles ont été construits au cours de l'évolution des méthodes et de l'acquisition de connaissances sur le site. Des méthodes d'analyses existantes et d'autres mises au point dans le cadre de cet ouvrage ont été appliquées aux réseaux obtenus afin de faire émerger les propriétés du fonctionnement de la vasière et de souligner le rôle de certains compartiments. Des analyses de sensibilité permettent d'évaluer la robustesse des résultats et d'orienter les recherches futures en mettant en évidence les manques les plus cruciaux. Des données supplémentaires, notamment concernant les foraminifères benthiques, le zooplancton ou les mouvements verticaux du microphytobenthos permettront de fournir de meilleures contraintes et de valider (ou non) les résultats obtenus. Les principaux résultats montrent un système au fort caractère saisonnier dont les compartiments benthiques et pélagiques sont très liés. La production primaire benthique locale est un moteur important, mais qui ne suffirait pas à suppléer l'indispensable importation de matériel détritique. Le découpage de la vasière en trois zones fait apparaître les particularités de chacune. La zone centrale correspond à la description classique des « vasières intertidales européennes » : très productive, elle peut alimenter les autres régions. C'est une zone de production et d'exportation. La partie supérieure est moins productive et reçoit de la matière de la zone de milieu d'estran via la colonne d'eau. Sa production secondaire peut alors être exploitée par les limicoles, nombreux en hiver. C'est une zone de dégradation et d'exportation. Le bas d'estran dépend fortement des importations extérieures, « pompées » par les bivalves cultivés qui sont ainsi directement responsables d'une forte sédimentation sous les structures mytilicoles et ostréicoles. C'est une zone de transformation.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/2005/these-2260.pdf
http://archimer.ifremer.fr/doc/00000/2260/

Éditeur(s) : HAL CCSD Public Library of Science
Résumé : International audience
Challenging evaluation of tropical forest biodiversity requires the reporting of taxonomic diversity but also the systematic characterization of wood properties in order to discover new promising species for timber industry. Among wood properties, the dimensional stability is regarded as a major technological characteristic to validate whether a wood species is adapted to commercial uses. Cell structure and organization are known to influence the drying shrinkage making wood density and microfibrils angle markers of choice to predict wood dimensional stability. On the contrary the role of wood extractive content remains unclear. This work focuses on the fast-growing tropical species Bagassa guianensis and we report herein a correlation between heartwood drying shrinkage and extractive content. Chemical extractions and shrinkage experiments were performed on separate wood twin samples to better evaluate correctly how secondary metabolites influence the wood shrinkage behaviour. Extractive content were qualitatively and quantitatively analysed using HPLC and NMR spectroscopy. We found that B guianensis heartwood has a homogeneous low shrinkage along its radius that could not be explained only by its basic density. In fact the low drying shrinkage is correlated to the high extractive content and a corrected model to improve the prediction of wood dimensional stability is presented. Additionally NMR experiments conducted on sapwood and heartwood extracts demonstrate that secondary metabolites biosynthesis occurs in sapwood thus revealing B. guianensis as a Juglans-Type heartwood formation. This work demonstrates that B. guianensis, a fast-growing species associated with high durability and high dimensional stability, is a good candidate for lumber production and commercial purposes.
ISSN: 1932-6203

hal-01392725
https://hal.archives-ouvertes.fr/hal-01392725
https://hal.archives-ouvertes.fr/hal-01392725/document
https://hal.archives-ouvertes.fr/hal-01392725/file/2016_BossuBeaucheneEstevezDuplaisClair_PlosOne_WoodDimentionalStabilityAndSecondaryMetabolites.pdf
DOI : 10.1371/journal.pone.0150777.s005

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The present work is concerned with the study of the tribological properties of various fluorinated carbon phases obtained at room temperature and then post-treated under fluorine atmosphere at different temperatures. The tribological tests evidence good intrinsic properties for all the compounds (friction coefficient in the range 0.07-0.09). Differences appear after few cycles. Friction measurements after 100 cycles and complementary Raman analyses of the tribofilm remaining in the wear scar point out that long term tribologic properties of the fluorinated compounds strongly depend on the evolution undergone by the materials under friction. The release of HF molecules, the loss of fluorine and partial rebuilding of graphitic phases are at the origin of the degradation of the friction properties. The good properties of the compounds post-treated at temperature in the range 150-300 °C are attributed to the chemical and structural stability of these compounds under friction.
ISSN: 0022-3697

hal-00756133
https://hal.archives-ouvertes.fr/hal-00756133
https://hal.archives-ouvertes.fr/hal-00756133/document
https://hal.archives-ouvertes.fr/hal-00756133/file/Delbe_6346.pdf
DOI : 10.1016/j.jpcs.2006.01.084

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : Production rates in horizontal shale gas wells display declines that are controlled by the low permeability and the intrinsic heterogeneity of the shale matrix. We present an original multi-continuum approach that yields a physical model able to reproduce the complexity of the decreasing gas rates. The model describes the dynamics of gas rate as function of the physical reservoir parameters and geometry, while the shale matrix heterogeneity is accounted for by a stochastic description of transmissivity field. From the 3D (Dimensional) problem setting, including the heterogeneous shale matrix, the fractures generated by the hydrofracking operations, as well as the production well characteristics, we establish an effective upscaled 1D model for the gas pressures in fracture and matrix as well as the volumetric flux. We analyse the decline curves behaviour, and we identify the time scales that characterize the dynamics of the gas rate decline using explicit analytical Laplace space solutions of the upscaled process model. Asymptotically, the flux curves decrease exponentially, while in an intermediate regime we find a power-law behaviour, in which the flux scales with a power law in time as (t^{-beta }), where (beta ) reflects the medium heterogeneity. We use this solution to fit a set of real data displaying distinctly different decline trends and study the sensitivity of the model to the reservoir parameters in order to identify their respective controls at the different stages of the decline curve dynamics. Results indicate that the initial value of the gas rate is determined by the transmissivity of the fractures and the initial pressure of the gas in the shale matrix. The latter causes mainly a shift in the entire decline curve. The early time of decline curve shape is primarily controlled by the fracture properties (compressibility and transmissivity). During the main part of the economically valuable production times, i.e. before the production rate drops exponentially, the decline curve is strongly controlled by the properties of the shale rocks including their heterogeneity, which is modelled by two parameters describing the non-Fickian pressure diffusion effects in a stochastic framework.
ISSN: 0169-3913

hal-01217247
https://hal.archives-ouvertes.fr/hal-01217247
DOI : 10.1007/s11242-015-0504-y

Éditeur(s) : HAL CCSD European Geosciences Union
Résumé : We designed a thermo-mechanical numerical model for fast-spreading mid-ocean ridge with variable viscosity, hydrothermal cooling, latent heat release, sheeted dyke layer, and variable melt intrusion possibilities. The model allows for modulating several accretion possibilities such as the "gabbro glacier" (G), the "sheeted sills" (S) or the "mixed shallow and MTZ lenses" (M). These three crustal accretion modes have been explored assuming viscosity contrasts of 2 to 3 orders of magnitude between strong and weak phases and various hydrothermal cooling conditions depending on the cracking temperatures value. Mass conservation (stream-function), momentum (vorticity) and temperature equations are solved in 2-D cartesian geometry using 2-D, alternate direction, implicit and semi-implicit finite-difference scheme. In a first step, an Eulerian approach is used solving iteratively the motion and temperature equations until reaching steady states. With this procedure, the temperature patterns and motions that are obtained for the various crustal intrusion modes and hydrothermal cooling hypotheses display significant differences near the mid-ocean ridge axis. In a second step, a Lagrangian approach is used, recording the thermal histories and cooling rates of tracers travelling from the ridge axis to their final emplacements in the crust far from the mid-ocean ridge axis. The results show that the tracer's thermal histories are depending on the temperature patterns and the crustal accretion modes near the mid-ocean ridge axis. The instantaneous cooling rates obtained from these thermal histories betray these discrepancies and might therefore be used to characterize the crustal accretion mode at the ridge axis. These deciphering effects are even more pronounced if we consider the average cooling rates occurring over a prescribed temperature range. Two situations were tested at 1275-1125 °C and 1050-850 °C. The first temperature range covers mainly the crystallization range that is characteristic of the high temperature areas in the model (i.e. the near-mid-oceanic-ridge axis). The second temperature range corresponds to areas in the model where the motion is mainly laminar and the vertical temperature profiles are closer to conductive. Thus, this situation results in less discriminating efficiency among the crustal accretion modes since the thermal and dynamic properties that are described are common to all the crustal accretion modes far from the ridge axis. The results show that numerical modeling of thermo-mechanical properties of the lower crusts may bring useful information to characterize the ridge accretion structure, hydrothermal cooling and thermal state at the fast-spreading ridges and may open discussions with petrological cooling rate results.
ISSN: 1991-959X

hal-00907012
https://hal.archives-ouvertes.fr/hal-00907012
DOI : 10.5194/gmd-6-1659-2013

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
A set of synthetic aggregates, containing mixtures of calcite and muscovite, were compacted with varying uniaxial loads ranging from 20 MPa up to 400 MPa. Their elastic properties have been measured using compressional and shear waves in confining hydrostatic pressures up to 475 MPa. Measured seismic velocities are shown to depend on 1) the ratio of calcite to muscovite, 2) the uniaxial load used during sample manufacturing, and 3) the porosity amount prior to velocity measurements. The matrix framework may also affect the seismic velocities, but this effect is not easily quantifiable. In general, measured seismic velocities decrease with increasing muscovite content and porosity. Elastic properties have been calculated based on texture measurements, which were obtained by neutron diffraction. The calculated velocities are based on the calcite and muscovite single crystal elastic tensors, their orientation distribution functions, and their modal fractions. A large discrepancy is apparent between calculated and measured velocities, where the former always overestimate the actual velocities. Shear waves display less of a difference between calculated and measured values, than do compressional waves, indicating that waves propagating by shearing are less affected by sample porosity and matrix framework. A better agreement between measured and calculated seismic velocities arises when the initial porosity is taken into account, using a differential effective medium model. Seismic anisotropy is evident from both measured and calculated velocities, and is low for samples containing pure calcite, but becomes prominent as the muscovite concentration increases. The intensity of anisotropy further depends on the uniaxial load used during sample compaction and the initial porosity.
ISSN: 0148-0227

hal-00512666
https://hal.archives-ouvertes.fr/hal-00512666
DOI : 10.1029/2009JB006523

Éditeur(s) : HAL CCSD
Résumé : The geological storage of CO 2 is considered as one of the solutions to the problem of global warming. The most possible scenarios of geological behavior of soil in the long term conditions has to be precisely defined to avoid catastrophic damages in the future. Chemical properties of saline water in the aquifer after the CO 2 injection becomes more acidic with time. Therefore, chemical degradation of rock occurs, which leads to modifications of its mechanical properties (chemo-mechanical coupling) [1]. In this paper an incremental model of chemo-mechanical coupling using homogenization approach (asymptotic expansion method [2,3]) is proposed. The paper is focused on the numerical computations for the X-ray tomography image of carbonate rock microstructure [4]. The chemical degradation of the microstructure is obtained as a homogeneous dissolution in each direction (Fig.1. – Fig.2.) For every porosity state numerical computations to obtain full, orthotropic elasticity tensor are performed. Therefore, the degradations functions for all components of the rigidity tensor were defined (Fig.3.). Moreover, results of numerical calculations of diffusion, tortuosity and permeability tensors are presented [5,6]. The link between geometrical properties and mechanical and transport parameters are discussed. The numerical analysis of the carbonate rock sample in long term conditions shows the increase of porosity and associated mechanical weakening of the rock. Moreover, the increase of diffusion, tortuosity and permeability tensors elements with time were observed. Finally, the solution of the one-dimensional macroscopic problem of soil settlement due to chemical dissolution of rock at constant load is presented. The method is universal, in the sense that the non-dimensional time scale is used.
ALERT Workshop 2013
Aussois, France

hal-01103175
https://hal.archives-ouvertes.fr/hal-01103175

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Polarized emittance measurements were acquired for synthetic forsterite, the pure magnesium end member of the olivines group, on the whole infrared spectral range and up to the melting point by using CO2 laser heating. The experimental data, fitted with a semi-quantum dielectric function model, allowed the retrieval of the temperature dependence of the absorption coefficient of forsterite both in the opaque and semi-transparent regions. The analysis of the phonon parameters indicates that the lattice dynamics evolve drastically with increasing temperature. The normal modes involving motions of the magnesium cations located in site 1 are the more impacted, and some of them vanish around 1,200 K. The results confirm that the enhancement of the lattice anharmonicity and the increasing mobility of the magnesium cations are closely linked and are at the origin of the anomalies observed in the evolution of the thermophysical properties. This complete set of spectroscopic data may be a step toward a more precise evaluation of the impact of thermal radiation heat transfer inside systems involving forsterite and quantification of their heat budget.
ISSN: 0342-1791

hal-00817079
https://hal.archives-ouvertes.fr/hal-00817079
DOI : 10.1007/s00269-013-0570-z

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Upon subduction, the oceanic crust transforms to blueschists and eclogites, with seismic properties that gradually become similar to those of the surrounding mantle. In order to evaluate the anisotropy of blueschists and glaucophane-bearing eclogites, the elastic constants of glaucophane single-crystal plates from the Sesia-Lanzo Zone (Aosta Valley, Western Alps) were measured using Brillouin spectroscopy at ambient conditions. The mean P- and S-wave velocities are 7.8 and 4.6 km s−1 respectively, and the anisotropy is high (38.1% (AVP) and 27.3% (AVS)). Glaucophane develops strong LPO, characterized by the [001]-axes concentrated sub-parallel to the lineation, and the {110} poles concentrated sub-perpendicular to the foliation in both blueschist and eclogite rocks. The measured LPO is in good agreement with viscoplastic selfconsistent numerical models. Seismic properties of glaucophane-bearing blueschist and eclogite are calculated by combining measured LPO and the single-crystal elastic moduli of glaucophane with the other main mineral constituents of the rock: mostly epidote for blueschist, and omphacite and garnet for eclogite. Blueschists present stronger anisotropies (AVP=16.1% and AVS=10.3%) than eclogites (AVP=2.9% and AVS=1.7%). The shear-wave splitting and resulting delay times for a 7-km thick layer of eclogite or blueschist are low for the eclogite (b0.03 s), but signi!cant for blueschist (0.16 s). Application to the subducted oceanic crust yields a decrease of velocity contrast with the surrounding mantle and of anisotropy at depth depending on the temperature of the slab. The details of the velocity variations in subducted oceanic crust are dif!cult to reconcile with the blueschist-eclogite transition as probed by exhumed metamorphic rocks and may require additional phases such as lawsonite or chemical variations such as oxidation state.
ISSN: 0040-1951

hal-00564518
https://hal.archives-ouvertes.fr/hal-00564518
DOI : 10.1016/j.tecto.2010.09.011

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Polygonal faulting is a widespread phenomenon in sedimentary basins worldwide. It changes basin-scale fluid flow patterns and alters the physical properties of the sediments making it important for hydrocarbon exploration and geohazard analysis. It is generally accepted that polygonal fault patterns derive from dewatering and compaction of the host sediments, but there is debate regarding the processes that control polygonal faulting. New multibeam-bathymetry data from the Hatton Basin, NE Atlantic, show up to 10 m deep and 200-600 m wide troughs at the seabed. They connect to each other forming polygons that are several hundred metres across, i.e. of similar size as buried polygonal fault systems observed in 3D seismic data. The troughs are symmetrical and resemble elongated pockmarks. Previously unpublished high-resolution 2D seismic data from the same area show seismic disturbance zones similar to pipes observed under pockmarks elsewhere as well as faults that have all the characteristics of polygonal fault systems. The observation of the wide disturbance zones is enigmatic, as they appear to follow the polygonal seafloor pattern. The observed extent of the polygonal sediment contraction system is substantial covering almost 37,000 km2. We calculate that some 2600 km3 of possibly carbon-bearing fluids have been expelled from this system and we expect that this will affect the benthic ecosystems, although so far there is only limited evidence for chemosynthetic habitats.
ISSN: 0025-3227

hal-00772468
https://hal.archives-ouvertes.fr/hal-00772468
DOI : 10.1016/j.margeo.2012.09.013

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Thermal diffusivity of synthetic quartz single-crystals and natural polycrystalline aggregates were measured using a modified Angstrom method at ambient pressure and up to 800 degrees C in order to investigate the effect of crystal preferred orientation on thermal diffusivity of quartz rich rocks. The thermal diffusivity tensor of quartz was determined by measuring the thermal diffusivity of an oriented synthetic quartz single-crystal along the [100] and [001] directions. A naturally deformed, fine-grained quartzite mylonite, was used to compare the single crystal properties with aggregate properties. Using the crystal preferred orientations (CPO) measured by the Electron Back Scattered Diffraction (EBSD) method and the measured thermal diffusivity tensor of quartz, the three-dimensional aggregate thermal diffusivity was modelled using volume averaging models. In order to test the validity of these models that are only based on the properties of the constituent minerals, the thermal diffusivity was then measured on oriented cores as a function of temperature, along three orthogonal directions, parallel to the (X-lineation, Y, Z-pole to foliation) structural frame. Both modelled and direct measurement of thermal diffusivity show an anisotropy of thermal diffusivity, heat transport being more effective parallel to Y-direction and less effective parallel to the lineation X-direction. Thermal diffusivities measured in a given direction on the natural rock are lower by less than 10% than the modelled thermal diffusivity in the same direction, showing that rock imperfections have a weak effect on heat transport. In addition, the modelled thermal diffusivity anisotropy based on the characterization of crystal orientations and thermal diffusivity tensor shows a good agreement with measurements in both alpha and beta stability field. This validation of the petrophysical simulation allows for evaluating the 3D thermal diffusivity of quartz rich rocks in different crustal conditions. The 3D thermal diffusivity of five naturally deformed quartzites displaying quartz fabrics expected in different crustal pressure and temperature ranges were simulated. The resulting thermal diffusivity anisotropies of quartzites range between 40% and 10%, depending on temperature, crystallographic fabric patterns and fabric strength. Under crustal conditions, quartzites deformed in the granulite facies display a high thermal diffusivity in the (XZ) foliation plane, whereas quartzites deformed in greenschist facies have highest thermal diffusivity in the (Z) direction normal to the foliation plane.
ISSN: 0040-1951

hal-00413568
https://hal.archives-ouvertes.fr/hal-00413568
DOI : 10.1016/j.tecto.2008.11.006