Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
Dating the timing of motion on crustal shear zones is of tremendous importance for understanding the assembly of orogenic terranes. This objective is achieved in this paper by combining petrological and structural observations with novel developments in in situ U-Th-Pb geochronology of allanite. A greenschist facies shear zone within the Mont Blanc Massif is documented. Allanite is synkinematic and belongs to the mylonitic assemblage. LA-ICP-MS U-Th-Pb isotope analyses of allanite reveal high contents and highly radiogenic isotopic compositions of the common-Pb component. The use of measured Pb-isotope compositions of associated minerals (feldspars and chlorite) is critical for accurate common-Pb correction, and provides a powerful mechanism for linking allanite growth to the metamorphic assemblage. A mean 208Pb/232Th age of 29.44 ± 0.95 Ma is accordingly taken for synkinematic allanite crystallisation under greenschist facies conditions. This age reflects the timing of the Mont Blanc underthrusting below the Penninic Front and highlights the potential of directly dating deformation with allanite.
ISSN: 0954-4879

hal-00963545
https://hal.archives-ouvertes.fr/hal-00963545
DOI : 10.1111/ter.12066

Éditeur(s) : HAL CCSD Elsevier
Résumé : The dense hydrous magnesium silicate called the D phase is the most likely candidate to recycle hydrogen into the lower mantle in subduction zones. As seismology represents the preferred method to detect this mineral in subduction zones, the single crystal elastic tensor has been calculated using first principle methods. A triple cell (View the MathML source) was used to account for an ordered ideal composition of the D phase to lower mantle pressures. The elastic tensor of the mineral at ambient conditions is predicted to be C11 = 387.7, C33 = 287.7, C44 = 100.4, C12 = 108.0, C13 = 51.1, C14 = − 14.6 in GPa with bulk modulus at zero pressure Ko = 163 GPa and a statistical error of about 4.0 GPa for all constants. The pressure derivatives of the elastic constants have been determined to pressure of 80 GPa. Our tensor correctly predicts the published experimental measurements of linear compressibility along the a- and c-axes, the logarithmic pressure derivative of the c/a axial ratio and bulk modulus at zero pressure. It contradicts the experimentally measured elastic tensor reported by (Liu, L.-G., Okamoto, K., Yang, Y.-J., Chen, C.-C., Lin, C.-C., 2004. Elasticity of single-crystal phase D (a dense hydrous magnesium silicate) by Brillouin spectroscopy. Solid State Commun. 132, 517–520), which fails to reproduce the experimental compressibility data. Using the elastic constants and density predicted to 85 GPa, the seismic anisotropy of P- and S-waves has been calculated as a function of pressure. The single crystal has high P-wave velocities and shear wave splitting in the basal plane below 20 GPa. At high pressures, the maximum P-wave velocities have threefold symmetry normal to a-axes in the basal plane, whereas the maximum shear wave splitting is parallel to a-axes with twofold symmetry. The D phase has high Vp and Vs anisotropy at ambient pressure, 17.6% for Vp and 19.9% for Vs. The Vp anisotropy decreases with increasing pressure to about 30 GPa, while it remains constant at 8% from 30 to 85 GPa. The Vs anisotropy decreases to 17% at 20 GPa and then increases to 22% at 85 GPa. The isotropic velocity ratios of S to P (Rs/p), bulk sound to S (Rphi/s) and density to S (Rρ/s) are calculated as a function of pressure. The Rs/p shows very little variation with pressure with low value of 0.6, whereas both Rphi/s and Rρ/s increase with pressure to peak values of 2.8 and 2.0 respectively at about 60 GPa. The presence of the D phase in subducted horizontal ‘stagnant' plates in the circum Pacific could contribute to a number of seismic observations, such as the observed velocity heterogeneity at depths between 500 and 1000 km and the fast S-waves travelling horizontally with horizontal polarization in this depth range. Further the lower density of the D phase compared with anhydrous minerals could influence buoyancy of the hydrated ‘stagnant' slabs. The transformation of the D phase to perovskite plus ferripericlase during thermal annealing may be responsible for horizontal slab seismogenesis.
ISSN: 0012-821X

hal-00406379
https://hal.archives-ouvertes.fr/hal-00406379
DOI : 10.1016/j.epsl.2007.04.053

Éditeur(s) : Gauthier-Villars
Résumé : Preparative pyrolysis followed by liquid chromatographic separation and gas chromatography of hydrocarbons (Pyrolysis-LC-GC) were used to study the participation of terrestrial and/or aquatic compounds in the formation of humic substances in sediments. Analyses performed on humic substances from recent sediments sampled in the Elorn river estuary (France) show that these substances are similar in many respects to other lacustrine or marine humic substances, with regard, for instance, to their high nitrogen and sulphur content and their low aromaticity. Mass balances on pyrolysis products and group composition of the C-14+ fraction of the pyrolysates were performed. The distribution of the total alkane and alkene fraction, isocyclo alkanes and alkenes from these humic acid pyrolysates was compared to that of various reference humic acid pyrolysates. The biomarker study (distribution and hopanes/steranes ratios from humic acid pyrolysates) confirms the participation throughout the estuary of algal precursors in the formation of the studied compounds, irrespective of the location of the sampling zone (upstream, median or downstream part of the estuary).
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1994 , Vol. 17 , N. 1 , P. 43-53

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00099/21029/18655.pdf
http://archimer.ifremer.fr/doc/00099/21029/

Éditeur(s) : HAL CCSD
Résumé : International audience
The Imiter silver mine is a world-class deposit located in the Easternpart of the Anti-Atlas (Morocco). The deposit is hosted by Cryogenianblack shales and Ediacaran volcanics, and unconformablyoverlain byPaleozoic sedimentary rocks. The paragenetic sequence for the ganguemineral is composedby amacroscopically white quartz (Qz1) associatedwith the deposition of galena and scarce silver mineralsas matrixof hydraulic breccias, followed by a grey quartz (Qz2) associated withthe main silver deposition event and a first generation of scarcedolomite(Dol1). A third episode is characterized by massive pink dolomite precipitation(Dol2) with minor quartz (Qz3) and base metals. Finally, asurficial event affects the mineralisation and is responsible for a secondaryore enrichment.Microthermometry study coupled with Raman analyses reveals thatfluid inclusions are CaCl2-dominated. The general trend is a decreaseof temperature from Qz1 (250°C) to Dol1 (80°C) then Dol 2 (probablybelow 70°C) depositions. Fluid salinity increases from Qz1 (6.3 to 19.0wt % NaCleq) to Dol1 (27.2 % wt NaCleq), and decreases with the precipitationof Dol2 associated with quartz 3 (15 %wt NaCleq). The 18Oisotopic composition of fluids in equilibrium with quartz and dolomitesuggestsamagmatic,metamorphic and/or basinal origin for the fluid atthe origin of Qz1, and that meteoric / surficial basinal brinesmay be atthe origin of Dol2.The proposed model to explain the ore forming processes in Imiter is amixing of Ca-brines, probably providing chloride complexes, with a hotNaCl fluid of lower salinity, leading to the precipitation of silver.Theresults favour the important role of calcic brines, whose origin remainsmatter to debate in such a giant depositand for whom age of emplacementis strongly discussed.
24 ème Réunion des sciences de la Terre 2014
Pau, France

insu-01080858
https://hal-insu.archives-ouvertes.fr/insu-01080858

Éditeur(s) : Pêche thonière et dispositifs de concentration de poissons, Caribbean-Martinique, 15-19 Oct 1999
Résumé : Yellowfin tuna (Thunnus albacares) is a main target for the fisheries at Fish Aggregating Devices (FADs) off the south of Okinawa island. Catch and weight composition of the tuna were monitored at a fisheries cooperative market from 1989 to 1998. Some distinct weight groups (considered to represent cohorts) appeared in the catch and the weight of these groups increased monthly - presumably as individual tuna grew. Although small, light weight fish were caught year-round, the 2 kg weight group that was recruited in May grew to about 15 kg by May of the next year. There was a significant seasonal cycle in the monthly catches. The catch of heavier weight groups decreased in winter indicating the tuna moved out of this FAD area. At one of huge FADs (Nirai), fifteen nautical miles southeast of Okinawa island (depth about 1.300 m), a current meter (Aanderaa RCM-7) recorded current and water temperature from June 1995 to March 1996. The current meter was attached to the FAD at 4 m depth. When typhoons attacked Okinawa, the water temperature drastically dropped. Typically, average current speed was 29 cm/s and eastward current was most frequent. Being affected by tide, the current was averaged over twenty-five hours. Current speed was correlated with the yellowfin catch in 120 daily sets at the FAD; the weaker the current speed, the greater the catch. Although not significant, the catch was greater with northeastward current than with southwestward current.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00042/15300/12662.pdf
http://archimer.ifremer.fr/doc/00042/15300/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The crust of the Paleoproterozoic West African Craton in northern Ghana is dominantly made of Tonalite-Trondhjemite-Granodiorite (TTG) suites, low-K to high-K calc-alkaline granites, with minor LILE-enriched diorites, and chemically related lavas. Results of zircon U-Pb dating indicate that all these different rock types were formed together over a prolonged period of ca. 100 Ma, between 2.21 and 2.11 Ga. Zircon Hf isotope compositions of five samples are supra-chondritic (εHft from +1 to +6) indicating that the granitoids derive from the reworking of juvenile crustal components as old as 2.60 Ga. Geochemical data show that the TTGs were derived from the reworking of a low-K mafic crust, while biotite granites formed by the reworking of older felsic crustal rocks, and diorites derived from the melting of LILE-enriched mantle sources.The combined datasets support a three-step model for the formation of the crust of the West African craton in northern Ghana: (1) a juvenile, mafic proto-crust was extracted from the depleted mantle between 2.60 and 2.30 Ga, in an oceanic environment remote from any pre-existing continental nucleus; (2) the mafic proto-crust was reworked in several primitive magmatic arcs or in accreted oceanic plateaux. Crustal reworking initially produced minor felsic magmatism between 2.35 and 2.21 Ga, followed by the 2.21–2.15 Ga emplacement of low- to medium-P TTG and K-rich calc-alkaline granitoid suites, and was coeval with the formation of an enriched mantle source. (3) Various proto-continental terranes collided during the Eburnean orogeny between 2.14 and 2.11 Ga, triggering intense reworking of the composite crust and mantle reservoirs formed in the previous two steps, i.e. remnants of the juvenile mafic crust, older TTGs and biotite granites, and previously enriched mantle sources. The emplacement of high-P TTGs, granites and LILE-enriched diorites resulted from lower crustal heating in response to the delamination of the lower crust and lithospheric mantle. The Eburnean collision therefore marks the final stages of a 200–500 Ma long period of juvenile continental crust formation and stabilisation. The datasets further reveal that the Paleoproterozoic West African Craton comprises a minimum of two distinct crustal blocks, with north-western Ghana lying at their interface.
ISSN: 0301-9268

hal-01467999
https://hal.archives-ouvertes.fr/hal-01467999
DOI : 10.1016/j.precamres.2016.10.011

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The Ronda orogenic peridotite (southern Spain) contains a variety of pyroxene-rich rocks ranging from high-pressure garnet granulites and pyroxenites to low-pressure plagioclasespinel websterites. The 'asthenospherized' part of the Ronda peridotite contains abundant layered websterites ('group C' pyroxenites), without significant deformation, that occur as swarms of layers showing gradual modal transitions towards their host peridotites. Previous studies have suggested that these layered pyroxenites formed by the replacement of refractory spinel peridotites. Here, we present a major- and trace-element, and numerical modelling study of a layered outcrop of group C pyroxenite near the locality of Tolox aimed at constraining the origin of these pyroxenites after host peridotites by pervasive pyroxene-producing, refertilization meltrock reactions. Mg-number [=Mg/(Mg + Fe) cationic ratio] numerical modelling shows that decreasing Mg-number with increasing pyroxene proportion, characteristic of Ronda group C pyroxenites, can be accounted for by a melt-consuming reaction resulting in the formation of mildly evolved, relatively low Mg-number melts (similar to 0.65) provided that the melt fraction during reaction and the time-integrated melt/rock ratio are high enough (>0.1 and >1, respectively) to balance Mg-Fe buffering by peridotite minerals. This implies strong melt focusing caused by melt channelling in high-porosity domains resulting from compaction processes in a partial melted lithospheric domain below a solidus isotherm represented by the Ronda peridotite recrystallization front. The chondrite-normalized rare earth element (REE) patterns of group C whole-rocks and clinopyroxenes are convex-upward. Numerical modeling of REE variations in clinopyroxene produced by a pyroxene-forming, melt-consuming reaction results in curved trajectories in the (Ce/Nd)(N) vs (Sm/Yb)(N) diagram (where N indicates chondrite normalized). Based on (Ce/Nd)(N) values, two transient, enriched domains between the light REE (LREE)-depleted composition of the initial peridotite and that of the infiltrated melt may be distinguished in the reaction column: (1) a lower domain characterized by convex-upward REE patterns similar to those observed in Ronda group C pyroxeniteperidotite; (2) an upper domain characterized by melts with strongly LREE-enriched compositions. The latter are probably volatile-rich, small-volume melt fractions residual after the refertilization reactions that generated group C pyroxenites, which migrated throughout the massifincluding the unmelted lithospheric spinel-tectonite domain. The Ronda mantle domains affected by pyroxenite- and dunite- or harzburgite-forming reactions (the 'layered granular' subdomain and 'plagioclase-tectonite' domain) are on average more fertile than the residual, 'coarse granular' subdomain at the recrystallization front. This indicates that refertilization traces the moving boundaries of receding cooling of a thinned and partially melted subcontinental lithosphere. This refertilization process may be widespread during transient thinning and melting of depleted subcontinental lithospheric mantle above upwelling asthenospheric mantle.
ISSN: 0022-3530

hal-00412200
https://hal.archives-ouvertes.fr/hal-00412200
DOI : 10.1093/petrology/egn014

Éditeur(s) : HAL CCSD
Résumé : 1 p.
International audience
The 12th May 2008 Wenchuan earthquake in the Longmen Shan occurred on a large thrust fault largely inherited from an Indosinian structure itself probably controlled by an older structural heritage of the South China block continental margin. Within the whole northeast Tibet region, such a structural inheritance has had a major impact on the Tertiary deformation. It appears of primary importance to assess the pre-Tertiary tectonic evolution of the main blocks involved to understand the actual deformation in the eastern edge of Tibet. Over the past decades, the Proterozoic to Cenozoic tectonic, metamorphic and geochronologic history of the Longmen Shan and Songpan Garzê area have been largely studied. We present a synthesis of the tectonic evolution of the Songpan Garzê fold and thrust belt from Triassic to present. The Songpan-Garzê belt was formed during closure of a wide oceanic basin ?lled with a thick (5 to 15 km) sequence of Triassic ?yschoid sediments. Closure of the basin due to Triassic subduction involved strong shortening, intense folding and faulting of the Triassic series. A large-scale décollement, that presently outcrops along the eastern boundary of the belt (Danba area), allowed the growth of a wide and thick accretionary wedge. It develops in the Paleozoic and Triassic series and separates the accretionary prism from an autochthonous crystalline basement which shares many similarities with the basement of the Yangtze Craton (0.7-0.9 Ga). To the north and northwest, below the thickened Triassic series of the belt, the composition (oceanic or continental) of the basement remains unknown. During the Indosinian orogeny the emplacement of orogenic granites (220 - 150 Ma) was associated to crustal thickening. The isotopic composition of granitoids shows that their magma source were predominantly derived from melting of the proterozoic basement with varying degrees of sedimentary material and negligible mantle source contribution. In the Danba area, the décollement outcrops in a large tertiary antiform with a NNW-SSE axis. It has been exhumed too in the hanging wall of the NE-SW faults of the Tertiary Longmen-Shan belt that marks the present day transition from the Tibetan plateau to the Sichuan basin. These faults have episodically absorbed signi?cant shortening since the Late Triassic. The amount and precise timing of post-triassic deformation are dif?cult to constrain especially because of the dif?culty to isolate the tertiary thermochronological signal from the protracted late Triassic - Cretaceous thermal history. Nonetheless it is generally accepted that Jurassic - Cretaceous tectonism did not modi?ed the general Triassic architecture of eastern Tibet contrarily to the Tertiary deformation. The long-term cooling histories obtained on Mesozoic granites and on the metamorphic series of the Danba dome are very similar showing a very slow and regular cooling during Jurassic andCretaceous, con?rming the absence of major tectonic event between c.a. 150 and 30 Ma. Low temperature thermochronology data indicate that ?nal exhumation and cooling occurred in theTertiary with an acceleration between 10 and 5 Ma along the major tectonic structures. Within the Longmen Shan range, a total denudation of 7 to 10 km is estimated for the late Cenozoic period. Similar amounts of late Tertiary denudation have been estimated along an east-west section across the Xianshuihe fault
Asian climate and tectonics seminar
Utrecht, Netherlands

insu-00610298
https://hal-insu.archives-ouvertes.fr/insu-00610298
DOI : 10.1016/j.jseaes.2010.03.008

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
To test the impact of fluid flow on the reactivity of porous (ultra-)mafic rocks, reactive percolation experiments were realized during which CO2-enriched water was injected at two different injection rates (Q = 0.1 and 1 mL h−1) through sintered analogues of olivine-accumulation zones in basaltic flows at temperature and fluid composition conditions (T = 180 °C; NaHCO3 buffered solution) favorable for CO2-mineralization (carbonation).All experiments resulted in silicate dissolution, carbonate precipitation upstream and (proto-)serpentine formation downstream indicating a decrease in the fluid reactivity along flow paths. The measured bulk carbonation rates ranged from 4 to 7 × 10−8 s−1; these values were significantly lower than previously published values of olivine carbonation rate obtained on powders in closed batch and flow-through reactors. Our study show complex couplings, at pore scale, between fluid flow, localization of reaction zones, and chemical reaction kinetics which in turn control hydrodynamic properties, carbonation rate and efficiency and fluid reactivity. This results in carbonation rates being higher when injection rates are high and permeability ultimately controlling carbonation reactions by limiting fluid input. During experiments, notable changes in permeability occurred for only minor changes in porosity indicating a control by the geometry of the porous network: heterogeneities in the distribution of flow paths favored the localization of precipitated minerals which in turn resulted in the closure of flow paths. This mechanism was particularly efficient at low injection rates. These results imply that controlling the injection rate could allow enhancing/limiting the efficiency of in situ carbonation.
ISSN: 0883-2927

hal-01115284
https://hal.archives-ouvertes.fr/hal-01115284
DOI : 10.1016/j.apgeochem.2014.11.024

Éditeur(s) : HAL CCSD
Résumé :  
Afin de comprendre l'organisation des communautés de chauves-souris ainsi que la coexistence de nombreuses espèces sympatriques, il est essentiel de déterminer comment les espèces utilisent et se partagent les ressources. Dans un premier temps, nous décrivons un peuplement de chauves-souris en forêt primaire de Guyane Française. Les facteurs locaux tels que la présence de gîtes particuliers comme les grottes, ou l'absence de perturbation anthropique ont une influence sur la structure et la composition des communautés. Au cours de cette étude, nous nous sommes concentrés sur les trois espèces les plus communes de chaque guilde végétarienne (frugivores de sous-bois, frugivores de canopée et nectarivores). Leur coexistence est possible grâce au partage des ressources alimentaires, de l'espace et/ou du temps. Au sein d'une même guilde, les plus petites espèces ont une bonne manoeuvrabilité et semblent occuper davantage les espaces fermés, moins attractifs pour leurs compétiteurs. Elles ont aussi un domaine vital plus petit que les grandes espèces. De même, le décalage des rythmes d'activités que nous avons observé, peut réduire la compétition entre les chauves-souris frugivores en diminuant les interférences directes lors de l'alimentation. En plus d'un intérêt pour l'écologie des communautés, cette étude décrivant des peuplements de chiroptères dans une forêt primaire intacte, peut servir de référence en biologie de conservation.
Revue d'écologie

hal-01032160
https://hal.archives-ouvertes.fr/hal-01032160

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Fault affecting silicoclastic sediments are commonly enriched in clay minerals. Clays are sensitive to fluid–rock interactions and deformation mechanisms; in this paper, they are used as proxy for fault activity and behavior. The present study focuses on clay mineral assemblages from the Point Vert normal fault zone located in the Annot sandstones, a Priabonian-Rupelian turbidite succession of the Alpine foredeep in SE France. In this area, the Annot sandstones were buried around 6–8 km below the front of Alpine nappes soon after their deposition and exhumed during the middle-late Miocene. The fault affects arkosic sandstone beds alternating with pelitic layers, and displays throw of about thirty meters. The fault core zone comprises intensely foliated sandstones bounding a corridor of gouge about 20 cm thick. The foliated sandstones display clay concentration along S–C structures characterized by dissolution of K-feldspar and their replacement by mica, associated with quartz pressure solution, intense microfracturation and quartz vein precipitation. The gouge is formed by a clayey matrix containing fragments of foliated sandstones and pelites. However, a detailed petrographical investigation suggests complex polyphase deformation processes. Optical and SEM observations show that the clay minerals fraction of all studied rocks (pelites and sandstones from the damage and core zones of the fault) is dominated by white micas and chlorite. These minerals have two different origins: detrital and newly-formed. Detrital micas are identified by their larger shape and their chemical composition with a lower Fe–Mg content than the newly-formed white micas. In the foliated sandstones, newly-formed white micas are concentrated along S–C structures or replace K-feldspar. Both types of newly formed micas display the same chemical composition confirmed microstructural observations suggesting that they formed in the same conditions. They have the following structural formulas: Na0.05 K0.86 (Al 1.77 Fe0.08 Mg0.15) (Si3.22 Al0.78) O10 (OH)2. They are enriched in Fe and Mg compared to the detrital micas. Newly-formed chlorites are associated with micas along the shear planes. According to microprobe analyses, they present the following structural formula: (Al1,48 Fe2,50 Mg1,84) (Si2,82 Al1,18) O10 (OH)8. All these data suggest that these clay minerals are synkinematic and registered the fault activity. In the gouge samples, illite and chlorite are the major clay minerals; smectite is locally present in some samples.In the foliated sandstones, Kubler Index (KI) ((001) XRD peak width at half height) data and thermodynamic calculations from synkinematic chlorite chemistry suggest that the main fault deformation occurred under temperatures around 220 °C (diagenesis to anchizone boundary). KI measured on pelites and sandstones from the hanging and footwall, display similar values coherent with the maximal burial temperature of the Annot sandstones in this area. The gouge samples have a higher KI index, which could be explained by a reactivation of the fault at lower temperatures during the exhumation of the Annot sandstones formation
ISSN: 0191-8141

hal-01172423
https://hal.archives-ouvertes.fr/hal-01172423
DOI : 10.1016/j.jsg.2015.03.012

Éditeur(s) : HAL CCSD
Résumé : The Restefond fault, located in the Late Eocene-Early Oligocene Alpine foreland basin, affects the well lithified and low porosity Grès d'Annot. The fault core zone is characterized by the occurrence of highly deformed sandstone lenses. Deformation inside the lenses corresponds to mm to sub-mm-spaced cleavage planes rich in phyllosilicates and up to cm-thick and dm-long quartz-calcite pure extensional veins. The cleavages are mostly composed of newly-formed synkinematic white mica and chlorite. By using thermodynamic thermometers based on the chemical composition of chlorite, a temperature of 200 ± 20 °C of fault activity was computed. This temperature shows that the Restefond fault was active at burial conditions comprised between 6.5 and 8 km, assuming a mean geothermal gradient between 25 and 30 °Ckm−1. The petrophysic properties of sandstones from the core zone and in the hanging and foot wall of the fault were determined on drilled plugs following three spacial directions. The permeability of the highly deformed sandstone from the core zone is about one order of magnitude higher than in the host rock. This increase in permeability occurs in the direction parallel to the S-C structures and is explained by the occurrence of well-connected micropores localized between platy phyllosilicates. This study shows that the fault petrophysic properties are mostly controlled by the precipitation of synkinematic phyllosilicates under deep burial conditions.
Swiss Journal of Geosciences

hal-00795551
https://hal.archives-ouvertes.fr/hal-00795551
DOI : 10.1007/s00015-012-0099-z

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
A full equilibrium treatment of molecular aggregation is presented for prototypes of 1D and 3D aggregates, with and without nucleation. By skipping complex kinetic parameters like aggregate size-dependent diffusion, the equilibrium treatment allows to predict directly time-independent quantities such as critical concentrations. The relationships between the macroscopic equilibrium constants for the different paths are first established by statistical corrections and so as to comply with the detailed balance constraints imposed by nucleation, and the composition of the mixture resulting from homogeneous aggregation is then analyzed using the polylogarithm function. Several critical concentrations are distinguished: the residual monomer concentation in equilibrium (RMC) and the critical nucleation concentration (CNC), that is the threshold concentration of total subunits necessary for initiating aggregation. When increasing the concentration of total subunits, the RMC converges more strongly to its asymptotic value, the equilibrium constant of depolymerization, for 3D aggregates and in case of nucleation. The CNC moderately depends on the number of subunits in the nucleus, but sharply increases with the difference between the equilibrium constants of polymerization and nucleation. As the RMC and CNC can be numerically but not analytically determined, ansatz equations connecting them to thermodynamic parameters are proposed
PCCP : Physical chemistry chemical physics

Droits : info:eu-repo/semantics/OpenAccess
hal-01565995
https://hal.archives-ouvertes.fr/hal-01565995
https://hal.archives-ouvertes.fr/hal-01565995/document
https://hal.archives-ouvertes.fr/hal-01565995/file/Aggregates_in_equilibrium.pdf
DOI : 10.1039/c6cp08369b

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Over the last decades, numerous studies have emphasized the role of serpentinites in the subduction zone geodynamics. Their presence and role in subduction environments are recognized through geophysical, geochemical and field observations of modern and ancient subduction zones and large amounts of geochemical database of serpentinites have been created. Here, we present a review of the geochemistry of serpentinites, based on the compilation of ~ 900 geochemical data of abyssal, mantle wedge and exhumed serpentinites after subduction. The aim was to better understand the geochemical evolution of these rocks during their subduction as well as their impact in the global geochemical cycle. When studying serpentinites, it is essential to determine their protoliths and their geological history before serpentinization. The geochemical data of serpentinites shows little mobility of compatible and rare earth elements (REE) at the scale of hand-specimen during their serpentinization. Thus, REE abundance can be used to identify the protolith for serpentinites, as well as magmatic processes such as melt/rock interactions before serpentinization. In the case of subducted serpentinites, the interpretation of trace element data is difficult due to the enrichments of light REE, independent of the nature of the protolith. We propose that enrichments are probably not related to serpentinization itself, but mostly due to (sedimentary-derived) fluid/rock interactions within the subduction channel after the serpentinization. It is also possible that the enrichment reflects the geochemical signature of the mantle protolith itself which could derive from the less refractory continental lithosphere exhumed at the ocean-continent transition. Additionally, during the last ten years, numerous analyses have been carried out, notably using in situ approaches, to better constrain the behavior of fluid-mobile elements (FME; e.g. B, Li, Cl, As, Sb, U, Th, Sr) incorporated in serpentine phases. The abundance of these elements provides information related to the fluid/rock interactions during serpentinization and the behavior of FME, from their incorporation to their gradual release during subduction. Serpentinites are considered as a reservoir of the FME in subduction zones and their role, notably on arc magma composition, is underestimated presently in the global geochemical cycle.
ISSN: 0024-4937

hal-00903601
https://hal.archives-ouvertes.fr/hal-00903601
DOI : 10.1016/j.lithos.2013.05.019

Éditeur(s) : Gauthier-Villars
Résumé : The analysis of humic compounds by elemental analysis, PY-GC-MS and HPLC techniques permitted determination of the origin of organic inputs, essentially terrestrial, and the effects of environmental conditions in the deposits along a north-south transect through the Rhone delta, from the river mouth to the open sea. In the prodelta the sedimentation of fine particles enriches the sediments in organic matter. The humic compound contents were relatively low in sediments, perhaps due to a rapid burying of organic matter which leads to anoxic conditions. In sediments fulvic acids are more abundant than humic acids. Elemental analysis indicated that fulvic acids were enriched in hydrogen and nitrogen as compared to humic acids. Furthermore, H/C and N/C ratios increased in the fulvic and humic acids towards the open sea, related to a more marine character. Pyrolysis analysis showed some differences between the chemical composition of fulvic acids which correspond to low molecular weights enriched in carbohydrates, and that of humic acids, high molecular weight compounds which are enriched in phenols and aromatic hydrocarbons. The pyrolysis-derived phenols were abundant near the river mouth, decreasing towards the open sea as nitrogen-containing-compounds increased. Near the river mouth, the abundance of phenolic aldehydes demonstrated by HPLC emphasized the existence of fresh organic matter. On the other hand, off the mouth, an increase in phenolic acids could indicate a more degraded organic material. The fractionation of humic acids in various classes of molecular weight species using ultrafiltration (Amicon membranes) and their analysis showed that, close to the river mouth, the large proportion of the high molecular weight humic compounds observed was enriched in phenols and carbohydrates, probably inherited from the terrestrial ligno-cellulosic complex. This process seemed to be superimposed on the increase of molecular weights which is usually observed as the environment becomes purely marine. These humic compounds would derived either from organic matter from terrestrial soils swept along by the river flow, after deposition on its bed or, more probably, from high molecular weight compounds which, associated with the mineral phase, flocculated when reaching the fluvio-marine front. Generally, the low molecular weight fractions were enriched in hydrogen and nitrogen. Near the river mouth, nitrogen-containing compounds were concentrated in the low molecular weight classes which correspond to organic molecules regarded as humic precursors. Off the mouth, they were incorporated into the high molecular weight complexes, certainly of marine origin.
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1992 , Vol. 15 , N. 1 , P. 61-74

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00101/21187/18804.pdf
http://archimer.ifremer.fr/doc/00101/21187/

Éditeur(s) : HAL CCSD Elsevier Masson
Résumé : International audience
Late Jurassic coral reefs are present in the Western High Atlas of Morocco along the eastern paleomargin of the young Atlantic Ocean. The Izwarn section shows two reef units made of scleractinian corals and microbialites, included in a progradational shallowing-upward succession. Changes in reefal composition and structure observed in a ca. 50 cm-thick interval at the base of the reef unit 1 are interpreted to represent the first well-documented ecological succession in Late Jurassic reefs. Bioclastic deposits, sparse and poorly diversified corals (five genera) preserved in life position, and finally a more diversified coral assemblage (11 genera) building a reef framework with stromatolitic crusts reflect pioneer, colonization and diversification stages, respectively. A specific depth window, where light was reduced but sufficient for a catch-up growth mode and below the erosive action of waves, probably at the lower slope of a fore-reef area, has made possible the development and the record of this ecological succession. With a more diversified coral assemblage (16 genera), the reef unit 2 reflects shallower and well-agitated waters of a fore-reef area. Overlaying this second reef unit, the upper part of the section reveals back-reef deposits made of reworked reef elements, whereas a putative reef crest area is not recorded.
ISSN: 0016-6995

hal-00795549
https://hal.archives-ouvertes.fr/hal-00795549
DOI : 10.1016/j.geobios.2012.05.002

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The nature and extent of the regional lithosphere-asthenosphere interaction beneath Ireland and Britain remains unclear. Although it has been established that ancient Caledonian signatures pervade the lithosphere, tertiary structure related to the Iceland plume has been inferred to dominate the asthenosphere. To address this apparent contradiction in the literature, we image the 3-D lithospheric and deeper upper-mantle structure beneath Ireland via non-linear, iterative joint teleseismic-gravity inversion using data from the ISLE (Irish Seismic Lithospheric Experiment), ISUME (Irish Seismic Upper Mantle Experiment) and GRACE (Gravity Recovery and Climate Experiment) experiments. The inversion combines teleseismic relative arrival time residuals with the GRACE long wavelength satellite derived gravity anomaly by assuming a depth-dependent quasilinear velocity-density relationship. We argue that anomalies imaged at lithospheric depths probably reflect compositional contrasts, either due to terrane accretion associated with Iapetus Ocean closure, frozen decompressional melt that was generated by plate stretching during the opening of the north Atlantic Ocean, frozen Iceland plume related magmatic intrusions, or a combination thereof. The continuation of the anomalous structure across the lithosphere-asthenosphere boundary is interpreted as possibly reflecting sub-lithospheric small-scale convection initiated by the lithospheric compositional contrasts. Our hypothesis thus reconciles the disparity which exists between lithospheric and asthenospheric structure beneath this region of the north Atlantic rifted margin.
ISSN: 0956-540X

hal-00617815
https://hal.archives-ouvertes.fr/hal-00617815
DOI : 10.1111/j.1365-246X.2011.04921.x

Éditeur(s) : HAL CCSD Wiley
Résumé :  
The forests in Cat Tien National Park, appear as a mosaic of different communities, distinct from each other with respect to their floristic and structural parameters. The objectives of this study are (1) to characterize the different formations occurring in the lowland part and (2) to identify the main successional trends in the area. Understanding forest succession is important for silviculture and restoration of forests and land rehabilitation, as adequate information on the ecological role of local species in the functioning of the forests is not available in Vietnam. Five plots (1 ha each) were established in the lowland part of Cat Tien National Park, where all the trees ≥ 10 cm d.b.h. (diameter at breast height) were located, measured and identified. A systematic sampling was made to assess the regeneration. Three plots (A, C and D) can be considered as secondary forests on the basis of their structural parameters. Plots A and C are dominated by Lagerstrmia calyculata and plot D by Dipterocarpus alatus. The other two plots can be regarded as mature forests. Plot B corresponds to a semideciduous formation dominated by Lagerstrmia calyculata and Fabaceae species, and plot E to an evergreen one dominated by dipterocarp species. The floristic composition of plots A and C will change in the future because dominant canopy species are rare or absent in regeneration. A correspondence analysis performed on the number of trees per species shows two kinds of successional trends: one from A to B on shallow and drier soils, and another from C to E on deeper and wetter soils.
ISSN: 0305-0270

hal-01032094
https://hal.archives-ouvertes.fr/hal-01032094
DOI : 10.1046/j.1365-2699.2000.00347.x

Éditeur(s) : HAL CCSD
Résumé : Processes that occur within and across the oceanic crust–in particular along mid-ocean ridges and oceanic spreading centers—play a huge role in the dynamics of the Earth. The largest fluxes of heat and material between the Earth's mantle, crust, and seawater occur via magmatic, tectonic, and hydrothermal processes along oceanic spreading centers and their vast flanks. Roughly two thirds of the Earth's surface is accreted through magmatic and tectonic processes along mid-ocean ridges, and subduction of this ocean crust in turn influences mantle compositions. Exchange of elements between ocean crust and seawater strongly influences seawater compositions and leaves a geologic record of fluid-rock reactions in altered ocean crust. Some of these reactions contribute energy to microbial activity of a largely unexplored biosphere. The dynamics of ridge and ocean crustal processes therefore have enormous implications for thermal, chemical, and biological exchanges between the solid Earth and the hydrosphere.
EOS

hal-00564842
https://hal.archives-ouvertes.fr/hal-00564842
DOI : 10.1029/2010EO150001

Éditeur(s) : EDP Sciences
Résumé : Market position and its evolution were analysed in nine key fish and cephalopod species subject to long-term changes, using the Bay of Biscay fisheries as a case study. Although such long term changes have already been documented, and in some cases shown to be related to the impacts of fishing, changes in the physical environment, or both, relatively little work has been devoted to their potential consequences in economic terms. The nature and extent of these consequences was determined in the present study by looking at the composition of the affected fish production, and the status of different fish products on the markets. We propose a methodology to characterize market position for this set of nine species. The selected species represent a significant part of the gross turnover of French fishing fleets operating in the bay. These species were characterized in terms of their potential sensitivity to fishing and changes in environmental conditions due to global warming. We separated species potentially positively (Engraulis encrasicolus and Lophius budegassa) and negatively affected (Pollachius pollachius and Lophius piscatorius) by warming. Evolution of the value of production of the nine species was then depicted using analysis of macro-economic index (production and potential consumption) and price indices. This revealed the relatively high sensitivity of domestic production to the market crisis that occurred in France in the early 1990s, compared to imported and exported products. The relative position of individual species, with respect to the market and its evolution between 1990 and 2005, was analyzed by multi-factorial analysis. Results derived from the analysis clearly distinguish two groups of species, the first characterized by higher prices (monkfish, Nephrops, sole, seabass) and the second by larger volumes available on the French market (pollack, hake, anchovy, sardine, cuttlefish). We conclude that a major part (69 to 87%) of the gross turnover associated with catches of these fish species in the Bay of Biscay remains potentially unaffected by long-term changes related to climate.
Aquatic Living Resources (0990-7440) (EDP Sciences), 2008-07 , Vol. 21 , N. 3 , P. 307-316

Droits : EDP Sciences, IFREMER, IRD 2008
http://archimer.ifremer.fr/doc/2008/publication-4716.pdf
DOI:10.1051/alr:2008047
http://archimer.ifremer.fr/doc/00000/4716/