Éditeur(s) : Université de La Rochelle, Ecole doctorale Gay Lussac
Résumé : The thesis work is part of the very current issue on mass mortality outbreaks affecting Pacific oyster, C. gigas, spat and juveniles and questions about the involvement of pesticides in this phenomenon. The first part of this thesis was devoted to study the effects of pesticides on hemocyte parameters in the Pacific oyster (in vitro and in vivo). The immunomodulator effect of selected pesticides (alone or in mixture) has been explored principally through flow cytometry. The second part concerned the study of the effects of a pesticides mixture on OsHV-1 itself. No direct effects have been reported on the viral particles in presence of the pollutants. Moreover, pesticide effects on Pacific oysters were also explored through experimental pathology assays after treatment of animals with a polluant mixture. Results showed that pesticide treated oysters appeared more susceptible to the viral infection in experimental conditions. The third part concerned the study of autophagy in the Pacific oyster, C. gigas. The publication of the complete genome in 2012 has opened up new possibilities for the study of innate immunity in this species. The study of autophagy for the first time in oysters consisted in a first step in the in silico search for genes involved in this pathway and the corresponding proteins by Western blotting. Then, the role of this important process in innate immunity has been explored through reproduction infections tests with or without modulators of autophagy. Results showed that autophagy appeared as involved in defence mechanisms against viral and bacterial infection in Pacific oysters.
Le travail de thèse s’inscrit dans la problématique très actuelle des mortalités massives de naissain et de juvéniles d’huîtres creuses, C. gigas, et des questionnements autour de l’implication des pesticides dans ce phénomène. La première partie de la thèse a été consacrée à l’étude des effets de pesticides sur les capacités hémocytaires de l’huître creuse (in vitro et in vivo). L’effet immunomodulateur des xénobiotiques sélectionnés (seul ou en mélange) a été exploré principalement au travers de la cytométrie en flux. La deuxième partie de la thèse a concerné l’étude des effets d’un mélange de pesticides sélectionnés sur le virus OsHV-1 et l’infection qu’il induit chez l’huître creuse. Les effets des pesticides sur le virus lui-même ont été évalués. Les expériences réalisées non pas permis de mettre en évidence dans les conditions testées, de dégradation des particules virales en présence des polluants. D’autre part, leurs effets sur les huîtres elles-mêmes ont été explorés après traitement des animaux avec un mélange de pesticides lors d’essais de pathologie expérimentale. Il a ainsi pu être montré que des huîtres préalablement comtaminées par un mélange de pesticides à des concentrations retrouvées dans l’environnement semblaient être plus sensibles à l’infection virale. La troisième partie de la thèse a concerné l’étude de l’autophagie chez l’huître creuse, C. gigas. La publication du génome complet de cette espèce en 2012 a ouvert de nouvelles possibilités pour étudier l'immunité innée. L’étude de l’autophagie réalisée pour la première fois chez l’huître creuse a consisté lors d’une première étape en la recherche in silico de gènes impliqués dans cette voie et des protéines correspondantes par western blotting. Puis, le rôle de ce processus important dans l’immunité innée a été exploré au travers d’essais de reproduction d’infections en présence ou non de modulateurs de l’autophagie. Les résultats obtenus semblent montrer que l’autophagie soit un processus important pouvant être impliqué dans les capacités de défense de l’huître creuse vis-à-vis d’infections virales et bactériennes.

Droits : 2014 Université de La Rochelle
http://archimer.ifremer.fr/doc/00226/33740/32149.pdf
http://archimer.ifremer.fr/doc/00226/33740/

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
The New Jersey continental shelf extends 150 km off the shoreline. During IODP Expedition 313, siliciclastic deposits of late Eocene to late Pleistocene age were drilled down to 631, 669 and 755 m below seafloor at sites 27A, 28A and 29A respectively in very shallow waters (33.5 to 36 m depth). Pore water salinities display multilayered brackish-salty-brine units 10 to 170 m thick, where low-salinity water is preferentially stored in fine-grained sediments. The sharp boundaries of these buried aquifers are often marked by cemented layers a few centimetres thick. The mineralogy and scanning electron microscope observations of these layers show two phases of cementation by authigenic minerals: (1) the early carbonate cement is frequently associated with pyrite, and (2) the late silicate cement infills the residual porosity. The isotopic compositions of the carbonate cements vary widely: −2.4 < δ¹⁸O ‰ VPDB < +2.8; −15.1 < δ¹³C ‰ VPDB < +15.6. The δ¹⁸O values indicate that the carbonate cements precipitated with pore waters comprising variable mixtures of seawater and ¹⁸O-depleted fresh water originating from submarine groundwater discharge. The δ¹³C values of the carbonate cements are related to organic matter diagenesis, providing ¹³C-depleted dissolved inorganic carbon during bacterial sulphate reduction and anaerobic oxidation of methane, and ¹³C-rich dissolved inorganic carbon during methanogenesis. The diagenetic cementation processes included chemical weathering of reactive silicate minerals by the CO²-rich pore waters issued from organic matter diagenesis that released bicarbonate, cations and dissolved silica, which were further precipitated as carbonate and silicate cements. The estimated range of temperature (18±4 °C) during carbonate precipitation is consistent with carbonate cementation at moderate burial depths; however, silicate cementation occurred later during diagenesis at deeper burial depths.
ISSN: 0276-0460

hal-01559985
https://hal.archives-ouvertes.fr/hal-01559985
DOI : 10.1007/s00367-017-0506-6

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Mesoporous cobalt oxide silica matrices and membranes were successfully prepared using a dual acid-base catalysed sol-gel and interlayer-free approach for desalination applications. The effects of cobalt addition (0-35 mol%) on the structure-property relationship of the silica materials and membrane performance were systematically studied as a function of feed salt concentration (0.3-7.5 wt.% NaCl) and temperature (22-60 °C). As cobalt concentration increases beyond 5 mol%, the concentration of tricobalt tetroxide and proportion of silica mesopores were found to increase within the matrices. Silica membranes with high amount of tricobalt tetroxide (35 mol%) were found to be highly mesoporous with water fluxes of 20, 11.3 and 7.7 kg m-2 h-1 for the 0.3, 3.5 and 7.5 wt.% solutions at 60 °C, respectively, with >99.7% salt rejection at all times. This is attributed to the high pore volume (mesopores formation) and structural robustness of the silica network provided by the presence of tricobalt tetroxide. Even higher performance was achieved for low tricobalt tetroxide (mol%) silica membranes with water fluxes of 47.6 (0.3 wt.%) and 31.5 (3.5 wt.%) kg m-2 h-1 at 60 °C, respectively, though with reduced salt rejections of 90%. © 2015 Elsevier B.V.
ISSN: 0011-9164

hal-01683209
https://hal.univ-antilles.fr/hal-01683209
DOI : 10.1016/j.desal.2015.02.034

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Talc is a hydrous magnesium rich layered silicate that is widely disseminated in the Earth from the seafloor to over 100 km depth, in ultra-high pressure metamorphism of oceanic crust. In this paper we determine the single crystal elastic constants at pressures from 0 to 12 GPa of talc triclinic (C 1¯) and monoclinic (C2/c) polytypes using ab initio methods. We find that talc has an extraordinarily high elastic anisotropy at zero pressure that reduces with increasing pressure. The exceptional anisotropy is complemented by a negative Poisson's ratio for many directions in crystal space. Calculations show that talc is not only one of very few common minerals to exhibit auxetic behaviour, but the magnitude of this effect may be the largest reported so far for a mineral. The compression (Vp) and shear (Vs) wave velocity anisotropy is 80% and 85% for the triclinic polytype. At pressures where talc is known be stable in the Earth (up to 5 GPa) the Vp and Vs anisotropy is reduced to about 40% for both velocities, which is still a very high value. Vp is slow parallel to the c-axis and fast perpendicular to it. This remains unchanged with increasing pressure and is observed in both polytypes. The shear wave splitting (difference between fast and slow S-wave velocities) at low pressure has high values in the plane normal to the c-axis, with a maximum near the alow asterisk-axis in the triclinic and the b-axis in the monoclinic polytype. The c-axis is the direction of minimum splitting. The pattern of shear wave splitting does not change significantly with pressure. The volume fraction of talc varies between 11 and 41% for hydrated mantle rocks, but the lack of data on the crystallographic preferred orientation (CPO) precludes a detailed analysis of the impact of talc on seismic anisotropy in subduction zones. However, it is highly likely that CPO can easily develop in zones of deformation due to the platy habit of talc crystals. For random aggregates of talc, the isotropic Vp, Vs and Vp/Vs ratio have significantly lower values than those of antigorite and may explain low-velocity regions in the mantle wedge. Vp/Vs ratios are more complex in anisotropic media because there are fast and slow S-waves, resulting in Vp/Vs1 and Vp/Vs2 ratios for every propagation direction, making interpretation difficult in deformed polycrystalline talc with a CPO. Talc on the subduction plate boundary can strongly influence guided wave velocity as CPO would develop in this region of intense shearing. The very low coefficient of friction (< 0.1) of talc above 100 °C could also explain silent earthquakes at shallow depths (ca 30 km) along the subduction plate boundaries, frequently responsible for tsunami.
ISSN: 0012-821X

hal-00411481
https://hal.archives-ouvertes.fr/hal-00411481
DOI : 10.1016/j.epsl.2008.07.047

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report trace element concentrations of silicate phases in chondrules from LL3 ordinary chondrites Bishunpur and Semarkona. Results are similar to previously reported data for carbonaceous chondrites, with rare earth element (REE) concentrations increasing in the sequence olivine < pyroxene < mesostasis, and heavy REE (HREE) being enriched by 1–2 orders of magnitude (CI-normalized) relative to light REE (LREE) in ferromagnesian silicates, although no single olivine with very large LREE/HREE fractionation has been found. On average, olivine in type II chondrules is poorer in refractory lithophile incompatible elements (such as REE) than its type I counterpart by a factor of ∼2. This suggests that olivine in type I and II chondrules formed by batch and fractional crystallization, respectively, implying that type II chondrules formed under faster cooling rates (>∼10 K/h) than type I chondrules. Appreciable Na concentrations (3–221 ppm) are measured in olivine from both chondrule types; type II chondrules seem to have behaved as closed systems, which may require chondrule formation in the vicinity of protoplanets or planetesimals. At any rate, higher solid concentrations in type II chondrule forming regions may explain the higher oxygen fugacities they record compared to type I chondrules. Type I and type II chondrules formed in different environments and the correlation between high solid concentrations and/or oxygen fugacities with rapid cooling rates is a key constraint that chondrule formation models must account for.
ISSN: 0016-7037

hal-01174084
https://hal.archives-ouvertes.fr/hal-01174084
DOI : 10.1016/j.gca.2015.02.005

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : International audience
La Cabaña peridotite is part of a dismembered ophiolite complex located within the metamorphic basement of the Coastal Cordillera of south-central Chile, and is the only location in Chile were Cr-spinels have been described so far. The La Cabaña peridotite is part of the Western Series unit, which comprises meta-sedimentary rocks, metabasites, and serpentinized ultramafic rocks. This unit has been affected by greenschist-facies metamorphism with reported peak PT conditions of 7.0–9.3 kbar and 380°–420 °C. Within La Cabaña peridotite Cr-spinels are present in two localities: Lavanderos and Centinela Bajo. In Lavanderos, Cr-spinel occurs in small chromitite pods and as accessory/disseminated grains with a porous or spongy texture in serpentinite, whereas in Centinela Bajo Cr-spinel is present as accessory zoned grains in partly serpentinized dunites, and in chromitite blocks. All Cr-spinels display variable degrees of alteration to Fe2+-rich chromite with a variation trend of major elements from chromite to Fe2+-rich chromite similar to those observed in other locations, i.e., an increase in Fe2O3 and FeO, a decrease in Al2O3 and MgO. Cr2O3 content increases from chromite to Fe2+-rich chromite in chromitite pods from Lavanderos and chromitite blocks from Centinela Bajo, but decreases in ferrian chromite zones in accessory grains from Centinela Bajo. The minor element (Ti, V, Zn, Ni) content is mostly low and does not exceed 0.4 wt.%, with the exception of MnO (<0.9 wt.%), which shows a correspondence with increasing degree of alteration. Cr# (Cr/Cr + Al) versus Mg# (Mg/Mg + Fe2+) and Fe3+/Fe3++Fe2+ versus Mg# plots are used to illustrate the Cr-spinel alteration process. Overall, the Cr-spinels from Lavanderos (chromitite pods and disseminated grains) exhibit Cr# values ranging from 0.6 to 1.0, Mg# (Mg/Mg + Fe2+) below 0.5, and (Fe3+/Fe3++Fe2+) <0.4. Cr-spinels from chromitites in Centinela Bajo have Cr# and Mg# values that range from 0.65 to 1.0, and 0.7-0.3, respectively, and (Fe3+/Fe3++Fe2+) < 0.4. Accessory Cr-spinels from Centinela Bajo have Cr# and Mg# values that range from 0.55 to 1.0, and 0.6- < 0.1, respectively. The (Fe3+/Fe3++Fe2+) ratio is less than 0.4 in chromite cores and Fe2+-rich chromite, and >0.5 in ferrian chromite and Cr-magnetite. Interpretation of the data obtained and Cr-spinel textures indicate that the alteration of Cr-spinel is a progressive process that involves in its initial stages the reaction of chromite with olivine under water-saturated conditions to produce clinochlore and Fe2+-rich chromite. During this stage the chromite can also incorporate Ni, Mn, and/or Zn from the serpentinization fluids. As alteration progresses, Fe2+-rich chromite loses mass resulting in the development of a spongy texture. In a later stage and under more oxidizing conditions Fe3+ is incorporated in chromite/Fe2+-rich chromite shifting its composition to an Fe3+-rich chromite (i.e., ferrian chromite). Depending on the fluid/rock and Cr-spinel/silicate ratios, Cr-magnetite can also form over Fe2+-rich chromite and/or ferrian chromite as a secondary overgrowth. The compositional changes observed in Cr-spinels from La Cabaña reflect the initial stages of alteration under serpentinization conditions. Results from this study show that the alteration of Cr-spinels is dependent on temperature. The degree and extent of alteration (formation of Fe2+-rich and/or ferrian chromite) are controlled by the redox nature of the fluids, the Cr-spinel/silicate and the fluid/rock ratios.
ISSN: 0930-0708

hal-01172266
https://hal.archives-ouvertes.fr/hal-01172266
DOI : 10.1007/s00710-014-0335-5

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
Accessory phases are important hosts of trace elements; allanite may contain >90% of the REE in a bulk rock. The mobility and redistribution of several trace elements, notably HREE, Th, U, and Y is thus controlled by reactions involving allanite and other REE phases, as well as several rock-forming minerals. As these elements are commonly concentrated in mature elastic sediments, a suite of impure quartzite was studied. Two eclogite facies samples from the Monometamorphic Cover Complex of the Sesia Zone (Western Italian Alps) are presented in some detail, as they reveal a remarkably rich spectrum of reaction relationships that involve REE phases.;Two allanite-forming reactions were inferred from textures and phase compositions;(1) monazite + Ca-silicate(?) + fluid -> allanite + apatite + thorite;;(2) monazite + thorite + Ca-silicate(?) + fluid -> Th-rich allanite + auerlite +/- apatite.;Petrographic observations and thermodynamic models suggest that allanite entered the HP assemblage at similar to 530 degrees C and 17-18 kbar during prograde metamorphism.;In one sample, allanite is rimmed by epidote rich in Y and HREE that grew at the expense of xenotime. Two net transfer reactions were derived;(3) xenotime + allanite + fluid -> Y-rich epidote + apatite + thorite;;(4) xenotime + allanite + fluid -> Y-rich epidote + aeschynite + thorite + (phosphate?).;Textural relationships and trace element analyses of coexisting allanite/monazite and xenotime/Y-rich epidote reveal systematic partitioning of the REE. Partition coefficients for the HREE are compatible with equilibrium fractionation, whereas those for the LREE show patterns that seem to be inherited from the precursor phases, in this case zircon with variable LREE composition.
ISSN: 0003-004X

hal-00745674
https://hal.archives-ouvertes.fr/hal-00745674
DOI : 10.2138/am.2012.3832

Éditeur(s) : Academic Press Ltd- Elsevier Science Ltd
Résumé : The high heterogeneity of silica cycling in coastal margins and the lack of silica data (compared to nitrogen and phosphorus) prevent the estimation of global silica retention in estuaries. In this study, the spatial and temporal variability of porewater silicic acid (Si(OH)4) profiles e that integrate benthic transport and reaction processes e was investigated at different spatial (metre, longitudinal and crosssection, intra-estuary) and temporal (tidal, seasonal) scales in two macrotidal estuaries, very close geographically but essentially differing in their shape. Studying the spatial and temporal variability of Si(OH)4 concentrations in porewaters provided evidence for the importance of transport processes, e.g. bio-irrigation, tidal pumping, resuspension and any combination of these processes, in affecting Si(OH)4 concentrations and fluxes and therefore temporary or permanent retention along the landeocean continuum. We confirm that aSiO2 (amorphous silicate) transported by rivers and estuaries clearly needs to be better characterized as it provides an important source of reactive aSiO2 to sediments. This study allows us to: (1) interrogate spatial and temporal scales, although both are most often in complete interaction; (2) design the most appropriate sampling schemes to be representative of any given system and to extrapolate at the scale of the whole estuary; (3) quantify uncertainty associated to the estimations of Si(OH)4 stocks and fluxes in this type of ecosystem, essential for budget calculations. We showed that two adjacent small macrotidal estuaries, may exhibit different behaviours regarding Si retention. Temporary retention has been observed in the meanders of the Aulne Estuary and not along the more linear Elorn Estuary, demonstrating the importance of the morphology and hydrodynamic components of the estuarine filter. Research is needed in other systems and climatic zones, but our study suggests that the typology should not only account for the different types of landeocean continuum (fjord, delta, mangrove.), but also incorporate the physical or biological attributes of the estuarine filter.
Estuarine Coastal And Shelf Science (0272-7714) (Academic Press Ltd- Elsevier Science Ltd), 2013-03 , Vol. 119 , P. 31-43

Droits : 2013 Elsevier Ltd. All rights reserved.
http://archimer.ifremer.fr/doc/00124/23529/22370.pdf
DOI:10.1016/j.ecss.2012.12.008
http://archimer.ifremer.fr/doc/00124/23529/

Éditeur(s) : HAL CCSD
Résumé : The Deep Basin of the Gulf of Mexico (DBGM) extends over eastern Mexico, the southeastern part of the United States, west of the Atlantic Ocean. This study, based on the interpretation and integration of seismic profiles, exploration wells and outcrop studies, focus on the deep part of the Gulf of Mexico, where bathymetry varies from 200 to 3750 m, thus comprising both the continental slope and the abyssal plain. The first part of this thesis focus on the description of the sedimentary infill of the western part of the Gulf of Mexico, in the Veracruz State, and to its geodynamic controls. The geodynamic evolution of the Deep Basin of the Gulf of Mexico (DBGM) begins during the Triassic-Jurassic with the break-up and the opening of a continental rift, in the southern part of the North American lithospheric plate. This opening induced a relative movement of the Yucatan Block towards the southeast. This intra-continental rifting episode was followed by a stage of post-rift thermal subsidence in the basins of the continental margin in the west, coeval with oceanic accretion in the DBGM. The thermal subsidence of the margin was subsequently modified by the Laramian orogeny, which impacted strongly the overall architecture of the margin as well as its litho-stratigraphic evolution, inducing the deposition of siliciclastic deposits in various morphotectonic provinces: i.e., near the tectonic front of the Sierra Madre Oriental (SMO), within the adjacent Chicontepec foreland basin, over the Tuxpan Platform (Golden Lane), across the continental slope and up to the deep abyssal plain, these two last morphotectonic provinces belonging to the DBGM. During the Early Paleogene, the effects of the thermal subsidence of the passive margin were stressed by the tectonic load of the Laramian orogen (i.e., the Sierra Madre Oriental, SMO), thus allowing the development of a foreland basin flexural. In this geodynamic framework, the main sedimentary transfers developed from the tectonic front "SMO" in the west, towards the DBGM in the east, the main source for clastic sediments being linked to the erosion of the "SMO" mountains. During the Paleocene and the Early Eocene, the architecture of the silici-clastic syn-tectonic sediments deposited in submarine fans was characterized by sliding, turbidites with A and B Bouma facies, as well as levees and channels. After the stop of the flexural subsidence, the thermal subsidence of the passive margin resumed during the Late Eocene, the Oligocene and the Neogene, allowing the development of a new sedimentary prism, prograding eastwards toward the DBGM. This sedimentary infill was again made up of levees-channels, sand bars and delta systems. During the Neogene, an extensional system with listric faults and roll-over features developed across the slope of the DBGM, due to an active detachment developing within overpressured Eocene-Oligocene clays. This gravitational gliding of Neogene series accounted also for the development of compressional features at the toe of the slope. Approximately 60% of the Miocene siliciclastic sediments have been trapped in growth strata and slope basins associated with this complex gravitational system, ranging from river-delta features towards gravity slides associated with slump facies. The second part of this thesis aims at a quantification of these various processes, including the construction of balanced cross sections, forward Thrustpack kinematic modelling coupling the development of a basal detachment, lithospheric flexure, erosion and sedimentation, as well as subsequent stratigraphic modelling with the Dionisos software, the later aiming at predicting the sand versus clay ratios in Neogene siliciclastic deposits of the DBGM and its surroundings.
Le bassin profond du Golfe du Mexique (BPMG) est localisé à l'est du Mexique, au sud-est des États-Unis et à l'ouest de l'Océan Atlantique. Cette étude de la partie profonde du Golfe du Mexique est basée sur l'intégration de données de sismique, de forages pétroliers et d'études de terrain; elle comprend toute la pente continentale et la plaine abyssale, avec une bathymétrie qui varie de 200 à 3750 m. La première partie de cette thèse est consacrée à la description du remplissage sédimentaire de la bordure occidentale du Golfe du Mexique, dans le secteur de Veracruz, en liaison avec son évolution géodynamique. L'évolution géodynamique du BPMG commence au Trias-Jurassique avec la rupture et la propagation d'un rift continental, dans le secteur sud de la plaque nord américaine. Cette ouverture et le déplacement relatif vers le sud-est du bloc crustal du Yucatan sont à l'origine du BPGM. Cette géodynamique de rift continental est suivie d'une étape post-rift accompagnée de l'océanisation du bassin. Les bassins de la marge passive ont poursuivi leur évolution sous l'effet de la subsidence thermique à l'ouest du Golfe du Mexique, tandis que de la croûte océanique se formait dans le BPGM. Cette subsidence thermique de la marge a ensuite été perturbée par l'orogénèse Laramienne, qui a remodelé l'architecture stratigraphique silico-clastique des dépôts du Tertiaire entre les éléments morphotectoniques suivants: lefront tectonique de la Sierra Madre Orientale (SMO), le bassin d'avant-pays Chicontepec, la Plateforme de Tuxpan-Faja de Oro, la pente continentale et la plaine abyssale, ces deux dernières provinces morphotectoniques appartenant au BPGM. Pendant le Paléogèneinférieur, les effets de la subsidence thermique de la marge passive ont été accentués par la charge tectonique de l'orogénèse laramienne (SMO), permettant ainsi le développement d'un bassin flexural d'avant-pays. Au cours de cette étape, les principaux transferts sédimentaires se sont effectués du front tectonique "SMO" vers le BPGM. La source principale de sédiments clastiques est liée à l'érosion de la chaîne de montagnes "SMO". Pendant le Paléocène et l'Éocène inférieur, l'architecture des premiers sédiments silico-clastiques syn-tectoniques déposés dans des éventails sous-marins sont caractérisés par des figures de glissement, des faciès turbiditiques A et B de Bouma, des chenaux-levées. Après l'arrêt de la subsidence flexurale, la subsidence thermique de la marge passive s'est poursuivie pendant l'Éocène supérieur, l'Oligocène et le Néogène, permettant le développement d'un nouveau prisme sédimentaire progradant. Les remplissages sédimentaires sont encore constitués de chenaux et de levées, avec des barres de sable associées à des systèmes deltaïques sur la plateforme. Pendant le Néogène, un système de failles listriques s'est développé sur la pente du BPGM, au-dessus d'une surface de décollement située, dans la région d'étude, dans les argiles de l'Éocène-Oligocène. Ce système de failles de croissance a piégé plus de 60% des sédiments silico-clastiques du Miocène. Ce remplissage sédimentaire évolue latéralement de faciès fluviaux deltaïques vers des faciès de pente affectés de glissements gravitaires et associés à des turbidites. La deuxième partie de cette thèse est consacrée à une approche quantitative basée sur des modélisations structurales (coupes équilibrées et modélisations cinématiques directes avec Thrustpack, couplant décollement gravitaire, flexure lithosphérique, érosion et sédimentation), puis sédimentaires (prise en compte des transferts de matériel clastique depuis la partie émergée de la chaîne jusqu'au bassin profond, à l'aide du logiciel Dionisos, afin de mieux comprendre les processus de piégeage des sédiments grossiers dans les structures de croissance et les bassins perchés de la marge.
https://tel.archives-ouvertes.fr/tel-00435120

tel-00435120
https://tel.archives-ouvertes.fr/tel-00435120
https://tel.archives-ouvertes.fr/tel-00435120/document
https://tel.archives-ouvertes.fr/tel-00435120/file/thesealzaga.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : High-precision Ni isotopic variations are reported for the metal phase of equilibrated and unequilibrated ordinary chondrites, carbonaceous chondrites, iron meteorites, mesosiderites, and pallasites. We also report new Zn and Cu isotopic data for some of these samples and combine them with literature Fe, Cu, and Zn isotope data to constrain the fractionation history of metals during nebular (vapor/solid) and planetary (metal/sulfide/silicate) phase changes. The observed variations of the Ni-62/Ni-58, Ni-61/Ni-58, and Ni-60/Ni-58 ratios vary linearly with mass difference and define isotope fractionation lines in common with terrestrial samples. This implies that Ni was derived from a single homogeneous reservoir. While no Ni-60 anomaly is detected within the analytical uncertainties, Ni isotopic fractionation up to 0.45 parts per thousand per mass-difference unit is observed. The isotope compositions of Ni and Zn in chondrites are positively correlated. We suggest that, in ordinary chondrites, exchange between solid phases, in particular metal and silicates, and vapor followed by mineral sorting during accretion are the main processes controlling these isotopic variations. The positive correlation between Ni and Zn isotope compositions contrasts with a negative correlation between Ni (and Zn) and Cu isotope compositions, which, when taken together, do not favor a simple kinetic interpretation. The observed transition element similarities between different groups of chondrites and iron meteorites are consistent with the genetic relationships inferred from oxygen isotopes (IIIA/pallasites and IVA/L chondrites). Copper is an exception, which we suggest may be related to separate processing of sulfides either in the vapor or during core formation. (C) 2007 Elsevier Ltd. All rights reserved.
ISSN: 0016-7037

hal-00408304
https://hal.archives-ouvertes.fr/hal-00408304
DOI : 10.1016/j.gca.2007.06.049

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The interplay between fault zone cataclasis and cementation is important since both processes can drastically reduce the permeability of faults in porous sandstones. Yet the prediction of fault cementation in high-porosity sandstone reservoirs remains elusive. Nevertheless, this process has rarely been investigated in shallowly buried faults (<2 km; T°<80 °C) where its sealing capacity could be acquired early in the geological history of a reservoir. In this paper, the macro- and microscopic analysis of a fault zone in the porous Cenomanian quartz arenite sands of Provence (France) shows that silica diagenesis occurs in the most intensely-deformed cataclastic parts of the fault zone. This fault zone shows 19–48% of its total thickness occupied by low-porosity quartz-cemented cataclastic shear bands whose porosities range from 0 – ca. 5%. The analysis of the weathering profile around the fault zone reveals the presence of groundwater silcretes in the form of tabular, tightly silicified concretions cross-cut by the fault. Detailed transmitted light, cold-cathodoluminescence and scanning electron microscopy analyses of the silica cements (from the fault and the silcrete) reveal that all the silica cements originate from groundwater diagenetic processes. This study therefore shows that silica cementation can occur specifically in fault zones and as groundwater silcrete in the shallow context of a groundwater system, generated at the vicinity of an erosional unconformity.
ISSN: 0191-8141

hal-01278286
https://hal.archives-ouvertes.fr/hal-01278286
DOI : 10.1016/j.jsg.2015.10.001

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
Abstract View references (60)Here we show the long term performance at high temperatures of a multi-tube module containing 8 membranes in 4 parallel lines with a total of 545 cm 2 area. The membranes were prepared via thin film dip coating of cobalt oxide silica (CoO xSi) sol-gel on tubular alumina supports. A preliminary study found that the sol-gel containing 20 mol% cobalt oxide formed the best microporous structure with the highest surface area and pore volume. All resulting membranes delivered permeances of ∼1 × 10 -7 mol m -2 s -1 Pa -1 at 500 °C, indicating a high repeatability for the membrane fabrication process. The permselectivities of helium (He) and hydrogen (H 2) over carbon dioxide (CO 2) and nitrogen (N 2) increased from 10-20 at 100 °C to values close to 1000 at 500 °C. Additionally, the apparent energies of activation (E act) for the smaller kinetic diameter gases He and H 2 at 12.2 and 19.5 kJ mol -1 were high and contrary to the negative values for larger gases N 2 and CO 2 at -1.8 and -7.4 kJ mol -1. These remarkable results were attributed to the molecular sieving mechanism of the microporous silica which was enhanced by the embedding of cobalt oxide into the matrix, delivering structural control with an average pore size of 3 Å. The E act for H 2 permeance was higher than that of He, indicating that the cobalt oxide played an important role in H 2 transport. Two membrane lines performed exceptionally well for binary gas mixture processing with H 2 purity reaching values close to 100% in the permeate stream for argon (Ar) concentrations of up to 80% in the retentate stream. A major finding here is that the binary gas selectivity was independent of temperature, contrary to the permselectivity observed for single gas permeance. Further, the H 2 flow rate was greatly affected by the concentration of Ar in the mixture, while the temperature dependency played only a marginal role. In particular, competitive adsorption in the percolative pathways containing pore constrictions or bottlenecks of the anisotropic CoO xSi matrix allowed Ar to impede H 2 diffusion. Finally, the CoO xSi membranes proved thermally stable and robust for 2000 h of testing for various thermal cycles up to 500 °C. © The Royal Society of Chemistry 2012.
Energy & Environmental Science

hal-01683199
https://hal.univ-antilles.fr/hal-01683199
DOI : 10.1039/c2ee03247c

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Island arc picrites and boninites are magnesian magmatic rocks believed to be generated by high degrees of melting of depleted mantle sources fluxed by subduction-derived, volatile-rich components. These magmas can be probes of both the mantle wedge protoliths and subduction components, but are rare among other, usually more evolved, types of arc lavas. Furthermore, many arc picrites and boninites show evidence for late-stage differentiation prior to or during eruption, masking their primary, mantle-derived geochemical signatures. We report textural and chemical data on spinel-hosted melt inclusions of mantle origin in amphibole-bearing websterite veins cross-cutting spinel harzburgite xenoliths from the active andesitic Avacha volcano (south Kamchatka, Russia). The data are used to constrain the composition and origin of melts that formed the websterite veins in the sub-arc lithospheric mantle. The melt inclusions typically contain euhedral orthopyroxene and clinopyroxene and occasionally minor amphibole in silicate glass. The melt inclusions were homogenized using heating stages and gas-mixing furnaces. The homogenized glasses range from subalkaline primitive silica-rich picrite and high-Ca boninite (>15 wt % MgO, 48–54 wt % SiO2) to rhyolite. High-Ca boninite glasses have moderate volatile and low heavy rare earth element contents and elevated Cs, Rb, Ba, U, Sr, and Li abundances, with extremely high U/Th. In turn, the glasses display no negative spikes in the high field strength elements Nb, Ta, Zr, Hf, and Ti. We show that the silica-rich picrite and high-Ca boninite liquids in this study formed by high degrees of melting (>25%), at volatile under-saturation, of hybrid melt-depleted but silica-rich mantle sources at ≥1·5 GPa. The hybrid sources formed in two stages: first, by extraction of ∼15% melt from the convecting mantle to form a refractory protolith, which was subsequently enriched in silica via interaction with subduction-derived components prior to or during remelting in the mantle wedge. The subduction-derived components were enriched in fluid-mobile elements and probably oxidized. Overall, our results suggest that silica-rich picrites and high-Ca boninites can be primary melts in mature subduction zones and differentiate within the mantle wedge and the deep arc crust to form more evolved andesite magmas.
ISSN: 0022-3530

hal-01553676
https://hal.archives-ouvertes.fr/hal-01553676
DOI : 10.1093/petrology/egw066

Éditeur(s) : HAL CCSD MDPI
Résumé : International audience
AbstractThis review provides a global overview of microporous silica based membranes for desalination via pervaporation with a focus on membrane synthesis and processing, transport mechanisms and current state of the art membrane performance. Most importantly, the recent development and novel concepts for improving the hydro-stability and separating performance of silica membranes for desalination are critically examined. Research into silica based membranes for desalination has focussed on three primary methods for improving the hydro-stability. These include incorporating carbon templates into the microporous silica both as surfactants and hybrid organic-inorganic structures and incorporation of metal oxide nanoparticles into the silica matrix. The literature examined identified that only metal oxide silica membranes have demonstrated high salt rejections under a variety of feed concentrations, reasonable fluxes and unaltered performance over long-term operation. As this is an embryonic field of research several target areas for researchers were discussed including further improvement of the membrane materials, but also regarding the necessity of integrating waste or solar heat sources into the final process design to ensure cost competitiveness with conventional reverse osmosis processes. © 2012 by the authors.
ISSN: 2073-4441

hal-01683200
https://hal.univ-antilles.fr/hal-01683200
DOI : 10.3390/w4030629

Éditeur(s) : HAL CCSD Public Library of Science
Résumé : International audience
Ro 31-8220 is a potent protein kinase C (PKC) inhibitor belonging to the chemical class of bisindolylmaleimides (BIMs). Various PKC-independent effects of Ro 31-8220 have however been demonstrated, including inhibition of the ATP-binding cassette drug transporter breast cancer resistance protein. In the present study, we reported that the BIM also blocks activity of the solute carrier organic cation transporter (OCT) 1, involved in uptake of marketed drugs in the liver, in a PKC-independent manner. Ro 31-8220, in contrast to other pan-PKC inhibitors such as staurosporine and chelerythrine, was thus shown to cis-inhibit uptake of the reference OCT1 substrate tetraethylammonium in OCT1-transfected HEK293 cells in a concentration-dependent manner (IC50 = 0.18 μM) and without altering membrane expression of OCT1. This blockage of OCT1 was also observed in human hepatic HepaRG cells that constitutionally express OCT1. It likely occurred through a mixed mechanism of inhibition. Ro 31-8220 additionally trans-inhibited TEA uptake in OCT1-transfected HEK293 cells, which likely discards a transport of Ro 31-8220 by OCT1. Besides Ro 31-8220, 7 additional BIMs, including the PKC inhibitor LY 333531, inhibited OCT1 activity, whereas 4 other BIMs were without effect. In silico analysis of structure-activity relationships next revealed that various molecular descriptors, especially 3D-WHIM descriptors related to total size, correspond to key physico-chemical parameters for inhibition of OCT1 activity by BIMs. In addition to activity of OCT1, Ro 31-8220 inhibited those of other organic cation transporters such as multidrug and toxin extrusion protein (MATE) 1 and MATE2-K, whereas, by contrast, it stimulated that of OCT2. Taken together, these data extend the nature of cellular off-targets of the BIM Ro 31-8220 to OCT1 and other organic cation transporters, which has likely to be kept in mind when using Ro 31-8220 and other BIMs as PKC inhibitors in experimental or clinical studies
ISSN: 1932-6203

hal-01255837
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01255837
DOI : 10.1371/journal.pone.0144667
PUBMED : 26657401
PUBMEDCENTRAL : PMC4675551

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Carbonised template silica membranes were synthesised and investigated for water desalination for brackish (0.3wt%), sea water (3.5wt%) and brine (7.5wt%) NaCl solutions at temperatures range from 22 to 60°C. The membranes were prepared by a two-step base catalysed sol-gel method using tetraethyl orthosilicate TEOS as the silica precursor and triblock copolymer of Pluronic® P123 as the templating agent. The P123 silica membranes calcined under vacuum only produced high quality membranes by the interlayer-free method. The membranes were stable during testing of up to 250h under different thermal and salt concentration solutions, always delivering very high salt rejections >99.5%. It was found that by increasing the template concentration in the silica matrix from 5 to 50wt%, salt concentration polarisation was greatly reduced. As such, high water fluxes were measured up to 8.5kgm-2h-1 for brackish water and 6.6kgm-2h-1 for brine water. © 2014 Elsevier B.V.
ISSN: 0376-7388

hal-01683210
https://hal.univ-antilles.fr/hal-01683210
DOI : 10.1016/j.memsci.2014.10.026

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Abstract View references (38)Silicalite-1 (S-1) and ZSM-5 membranes prepared by secondary growth on tubular ceramic supports were tested using a pervaporation set up for the desalination of aqueous solutions containing NaCl in concentrations corresponding to brackish (0.3-1wt%), sea (3.5wt%) and brine (7.5-15wt%) water. ZSM-5 membranes delivered higher water fluxes when compared with S-1 membranes due to enhanced hydrophilicity of the Al-rich zeolite structure leading to fluxes as high as 11.5kgm -2h -1 for 0.3wt% NaCl feed solutions at 75°C. At higher salt concentration the water flux decreased alongside with the salt rejection rate, however the hydrophilic ZMS-5 membrane became more susceptible to performance loss, particularly at high temperatures. Detailed stability experiments carried out for up to 560h showed the dissolution of both S-1 and ZSM-5 top layers. This was attributed to the combined effects of ion exchange and water dissolution mechanisms. Interesting though, the MFI structure zeolite was still observed on the XRD patterns whilst EDX depth profile showed the presence of silica up to 30μm depth into the support. These results suggest the formation/infiltration of a compact amorphous phase in the substrate, derived from the aggregation of the dissolved silicate species and possibly together with the arrangement of MFI nano-slabs during the desalination tests. Despite generating lower water fluxes, the S-1 membrane exhibited relatively high robustness under the long term testing conditions which included temperature cycling, delivering salt rejections from initial >99% to <80% at the end of the testing period (560h). © 2012 Elsevier B.V.
ISSN: 0376-7388

hal-01683201
https://hal.univ-antilles.fr/hal-01683201
DOI : 10.1016/j.memsci.2012.05.074

Éditeur(s) : HAL CCSD Elsevier
Résumé : Carbon emission at volcanic centers requires a constant balance between output (mostly by volcanism, either at plate boundaries or intraplate) and input (mostly at trench settings) of carbon from and to the Earth's mantle. The form of carbon that resides in the mantle is controlled by depth (pressure) and oxygen fugacity, the latter in turn depending on the depth and the concentration of iron in the mantle. In the shallow, lithospheric mantle, carbon is likely to be present in the oxidized form of CO2 (except under cratons where carbon is reduced to graphite or diamond). Below approximately 90 km, in the asthenosphere, the oxidized form of carbon is carbonate, either mineral or melt, depending on the thermal regime. At depths greater than approximately 150 km, the asthenospheric mantle is too reducing for carbon to stay in its oxidized form and only diamond is present, unless there is sufficient hydrogen to form reduced C–H fluids. Hence, the region located in the depth range of 90 to 150 km deep is where carbonatitic melts can most likely be produced and impregnate the surrounding mantle through metasomatism. The upper bound of this region is called the carbonate ledge. This limit prevents carbonate (either solid or molten) from ascending because of degassing and CO2 liberation. The lower bound is a redox front where redox melting (that is, melting caused by oxidation) may take place in an ascending portion of carbon-containing mantle. Carbonatite eruptions and presence of carbonate mineral inclusions in deep-seated diamonds provide evidence that these boundaries can be trespassed in some cases.An analysis of the experimental data that has bearing on silicate melting in the presence of carbon further shows that the carbonate ledge is a melting curve with a negative or flat Clapeyron (dP/dT) slope. In the carbonated ultrabasic (peridotite) systems, the carbonate ledge is located between ~ 2–3 GPa. The ledge divides the pressure–temperature space into a region of low-pressure silicate melt production, and a high-pressure region where carbonatites can be produced. Carbonatitic melts in equilibrium with mantle peridotite have compositions close to dolomitic (approximately equal amounts of Ca and Mg) with a general trend of becoming markedly more magnesian with increasing pressure. Calcic carbonatites may be stable at pressures < 2 GPa if clinopyroxene is absent. At mantle transition zone pressure range, there seems to be a melting temperature decrease (negative fusion slope), which may be caused by the stabilization of majoritic garnet.The carbonated basic (broadly eclogitic) system is more complex than the peridotitic one, because of the strong control of bulk silicate composition on melting temperatures, and hence, on melt composition. In carbonated eclogite systems, we propose that the effect of bulk composition upon all observed features can perhaps be related to silica super-saturation, or lack thereof. In some cases, high calcium (> 80 mol% CaCO3) melts can be produced, making the melting of carbonated eclogites an appealing scenario for the genesis of calcio-carbonatites in the Earth's mantle. Comparison with modeled pressure–temperature paths of subducted oceanic lithosphere shows that fusion of carbonated eclogite at depths shallower than 200 km should be expected for hot (Cascadian-type) subduction thermal regimes. On the other hand, in the case of cooler thermal regimes (Honshu-type, for instance), subducted carbonates may be stable to greater depths in Earth at trench settings, depending on the bulk composition of the system.Furthermore, high-pressure experiments show evidence of a continuum among carbonatitic, kimberlitic, melilititic, and basaltic liquids, for increasing melting degree of carbonated peridotite. This continuum has not been documented in the case of fusion of carbonated eclogite. It may be present, however, when certain sediments are fused, although the silicate melts are granitic to rhyodacitic instead of being kimberlitic in composition. Additional high-pressure work on phase relations in the simple binary system CaCO3–MgCO3 and specific focus on oxide solubility in the vapor phase have the potential to further clarify phase relations on complex silicate–carbonate systems at mantle conditions.
ISSN: 0009-2541

hal-01277770
https://hal.archives-ouvertes.fr/hal-01277770
DOI : 10.1016/j.chemgeo.2015.05.018

Éditeur(s) : HAL CCSD Elsevier
Résumé : The slow advance of a crack in soda-silicate glasses was studied at nanometer scale by in-situ and real-time atomic force microscopy (AFM) in a well-controlled atmosphere. An enhanced diffusion of sodium ions in the stress-gradient field at the sub-micrometric vicinity of the crack tip was revealed through several effects: growth of nodules in AFM height images, changes in the AFM tip–sample energy dissipation. The nodules patterns revealed a dewetting phenomenon evidenced by ‘breath figures'. Complementary chemical micro-analyses were done. These experimental results were explained by a two-step process: (i) a fast migration (typical time: few milliseconds) of sodium ions towards the fracture surfaces as proposed by Langford et al. [J. Mat. Res. 6 (1991) 1358], (ii) a slow backwards diffusion of the cations as evidenced in these AFM experiments (typical time: few minutes). Measurements of the diffusion coefficient of that relaxing process were done at room temperature. Our results strengthen the theoretical concept of a near-surface structural relaxation due to the stress-gradient at the vicinity of the crack tip. The inhomogeneous migration of sodium ions might be a direct experimental evidence of the presence of sodium-rich channels in the silicate structure [A. Meyer et al., Phys. Rev. Let. 93 (2004) 027801].
ISSN: 0022-3093

hal-00407634
https://hal.archives-ouvertes.fr/hal-00407634
DOI : 10.1016/j.jnoncrysol.2006.09.034

Éditeur(s) : HAL CCSD Nature Publishing Group
Résumé : International audience
Abstract The functionality or oxidation state of cobalt within a silica matrix can be tailored through the use of cationic surfactants and their halide counter ions during the sol-gel synthesis. Simply by adding surfactant we could significantly increase the amount of cobalt existing as Co3O4 within the silica from 44% to 77%, without varying the cobalt precursor concentration. However, once the surfactant to cobalt ratio exceeded 1, further addition resulted in an inhibitory mechanism whereby the altered pyrolysis of the surfactant decreased Co3O4 production. These findings have significant implications for the production of cobalt/silica composites where maximizing the functional Co3O4 phase remains the goal for a broad range of catalytic, sensing and materials applications.
ISSN: 2045-2322

hal-01683204
https://hal.univ-antilles.fr/hal-01683204
DOI : 10.1038/srep02449