Éditeur(s) : Printed for E. Cave Printed for E. Cave ( London )
Caribbean area
Florida
West Indies

Droits : All rights to images are held by the respective holding institution. This image is posted publicly for non-profit educational uses, excluding printed publication. For permission to reproduce images and/or for copyright information contact Special Collections & University Archives, University of Central Florida Libraries, Orlando, FL 32816 phone (407) 823-2576, email: speccoll@mail.ucf.edu
001421795
247463567
G4900 1740.B69

Éditeur(s) : HAL CCSD Wiley
Résumé : A standardized rapid inventory method providing information on both tree species diversity and aboveground carbon stocks in tropical forests will be an important tool for evaluating efforts to conserve biodiversity and to estimate the carbon emissions that result from deforestation and degradation (REDD). Herein, we contrast five common plot methods differing in shape, size, and effort requirements to estimate tree diversity and aboveground tree biomass (AGB). We simulated the methods across six Neotropical forest sites that represent a broad gradient in forest structure, tree species richness, and floristic composition, and we assessed the relative performance of methods by evaluating the bias and precision of their estimates of AGB and tree diversity. For a given sample of forest area, a several small' (<1ha) sampling strategy led to a smaller coefficient of variation (CV) in the estimate of AGB than a few large' one. The effort (person-days) required to achieve an accurate AGB estimate (<10% CV), however, was greater for the smallest plots (0.1ha) than for a compromise approach using 0.5ha modified Gentry plots, which proved to be the most efficient method to estimate AGB across all forest types. Gentry plots were also the most efficient at providing accurate estimates of tree diversity (<10% CV of Hill number). We recommend the use of the 0.5ha modified Gentry plot method in future rapid inventories, and we discuss a set of criteria that should inform any choice of inventory method.
ISSN: 0006-3606

hal-01032408
https://hal.archives-ouvertes.fr/hal-01032408
DOI : 10.1111/btp.12006

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
In the Oman ophiolite crustal section, a contact zone between the gabbro unit and the volcanics and diabase sheeted dikes, called the root zone of the sheeted dike complex, has been recently mapped at a fine scale in a selected area. The Oman ophiolite is derived from a fast spreading ridge which had a melt lens located between the main gabbro unit and the root zone of the sheeted dike complex. With a few exceptions accounted for, this horizon has a fairly constant thickness, similar to 100 m, and a crude internal pseudo-stratigraphy. At the base of the root zone are isotropic ophitic gabbros interpreted as a thermal boundary layer. This layer is transitional between the magmatic system of the melt lens, convecting at 1200 degrees C, and a high-temperature (< 1100 degrees C) hydrothermal system, convecting within the root zone. Above this level, the isotropic gabbros have been, locally, largely molten due to an influx of seawater, at similar to 1100 degrees C, thus generating varitextured ophitic and pegmatitic gabbros. These latter gabbros constitute the upper part of the root zone and are associated with trondjhemitic intrusions as screens in the lower sheeted dikes. Diorites and trondjhemites were also generated by hydrous melting, at temperatures below 1000 degrees C. The whole root zone is a domain of very sharp average thermal gradient (similar to 7 degrees C/m). At the top of the root zone, a new thermal boundary layer, with diabase dikes hydrated in amphibolite facies conditions, separates the preceding high- temperature convective system from the well-known greenschist facies (< 450 degrees C) hydrothermal system operating throughout the sheeted dike complex, up to the seafloor. The isotropic gabbros near the base of the root zone are intruded by protodikes with distinctive microgranular margins and an ophitic center. Protodike swarms are exceptional because, intruding a medium at similar to 1100 degrees C, they are largely destroyed by dike-in-dike intrusions and by hydrous melting. However, they demonstrate that this zone was generated by melt conduits issued from the underlying melt lens. Each dike of the sheeted dike complex is thus fed by one protodike. As this zone has been recently drilled by IODP in the eastern Pacific Ocean, a brief comparison is proposed.
ISSN: 1525-2027

hal-00411331
https://hal.archives-ouvertes.fr/hal-00411331
DOI : 10.1029/2007GC001918

Éditeur(s) : IEEE
Résumé : This paper aims at studying the quality of the sea surface salinity (SSS) retrieved from soil moisture and ocean salinity (SMOS) data in coastal areas. These areas are characterized by strong and variable SSS gradients [several practical salinity units (psu) on relatively small scales: the extent of river plumes is highly variable, typically at kilometric and daily scales. Monitoring this variability from SMOS measurements is particularly challenging because of their resolution (typically 30-100 km) and because of the contamination by the nearby land. A set of academic tests was conducted with a linear coastline and constant geophysical parameters, and more realistic tests were conducted over the Bay of Biscay. The bias of the retrieved SSS has been analyzed, as well as the root mean square (rms) of the bias, and the retrieved SSS compared to a numerical hydrodynamic model in the semirealistic case. The academic study showed that the Blackman apodization window provides the best compromise in terms of magnitude and fluctuations of the bias of the retrieved SSS. Whatever the type of vegetation cover, a strong negative bias, greater than 1 psu, was found when nearer than 36 km from the coast. Between 44 and 80 km, the type of vegetation cover has an impact of less than a factor 2 on the bias, and no influence further than 80 km from the coast. The semirealistic study conducted in the Bay of Biscay showed a bias over ten days lower than 0.2 psu for distances greater than 47 km, due to an averaging over various geometries (coastline orientation, swath orientation, etc.). The bias showed a weak dependence on the location of the grid point within the swath. Despite the noise on the retrieved SSS, contrasts due to the plume of the Loire River and the Gironde estuary remained detectable on ten-day averaged maps with an rms of 0.57 psu. Finally, imposing thresholds on the major axis of the measurements brought little improvement to the bias, whereas it increased the rms and- could lead to strong swath restriction: a 49-km threshold on the major axis resulted in an effective swath of 800-900 km instead of 1200 km. NOT CONTROLLED OCR
Transactions on geoscience an remote sensing IEEE (0196-2892) (IEEE), 2007-07 , Vol. 45 , N. 7 , P. 2061-2072

Droits : 2007 IEEE
http://archimer.ifremer.fr/doc/2007/publication-3643.pdf
DOI:10.1109/TGRS.2007.894934
http://archimer.ifremer.fr/doc/00000/3643/

Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
The Lanzo peridotite massif is a fragment of oceanic lithosphere generated in an ocean-continent transition context and eclogitized during alpine collision. Despite the subduction history, the massif has preserved its sedimentary oceanic cover, suggesting that it may have preserved its oceanic structure. It is an exceptional case for studying the evolution of a fragment of the lithosphere from its oceanization to its subduction and then exhumation. We present a field and petrological study retracing the different serpentinization episodes and their impact on the massif structure. The Lanzo massif is composed of slightly serpentinized peridotites (<20% serpentinization) surrounded by an envelope of foliated serpentinites (100% serpentinization) bordered by oceanic metabasalts and metasedimentary rocks. The limit between peridotites and serpentinites defines the front of serpentinization. This limit is sharp: it is marked by the presence of massive serpentinites (80% serpentinization) and, locally, by dykes of metagabbros and mylonitic gabbros. The deformation of these gabbros is contemporaneous with the emplacement of the magma. The presence of early lizardite in the peridotites testifies that serpentinization began during the oceanization, which is confirmed by the presence of meta-ophicarbonates bordering the foliated serpentinite envelope. Two additional generations of serpentine occur in the ultramafic rocks. The first is a prograde antigorite that partially replaced the lizardite and the relict primary minerals of the peridotite during subduction, indicating that serpentinization is an active process at the ridge and in the subduction zone. Locally, this episode is followed by the deserpentinization of antigorite at peak P-T (estimated in eclogitized metagabbros at 2-2.5 GPa and 550-620 °C): it is marked by the crystallization of secondary olivine associated with chlorite and/or antigorite and of clinopyroxene, amphibole and chlorite assemblages. A second antigorite formed during exhumation partially to completely obliterating previous textures in the massive and foliated serpentinites. Serpentinites are an important component of the oceanic lithosphere generated in slow to ultraslow spreading settings, and in these settings, there is a serpentinization gradient with depth in the upper mantle. The seismic Moho limit could correspond to a serpentinization front affecting the mantle. This partially serpentinized zone constitutes a less competent level where, during subduction and exhumation, deformation and fluid circulation are localized. In this zone, the reaction kinetics are increased and the later steps of serpentinization obliterate the evidence of this progressive zone of serpentinization. In the Lanzo massif, this zone fully recrystallized into serpentinite during alpine subduction and collision. Thus, the serpentinite envelope represents the oceanic crust as defined by geophysicists, and the sharp front of serpentinization corresponds to an eclogitized seismic palaeo-Moho.
ISSN: 0263-4929

hal-00823051
https://hal.archives-ouvertes.fr/hal-00823051
DOI : 10.1111/jmg.12008

Éditeur(s) : HAL CCSD Ocean Drilling Programm
Résumé : This paper provides a summary of postcruise scientific results from Ocean Drilling Program (ODP) Leg 209 available to date, building upon shipboard observations and syntheses summarized in the Leg 209 Initial Results volume. During Leg 209, 19 holes were drilled at 8 sites along the Mid-Atlantic Ridge from 14°43´ to 15°44´N, mainly in residual mantle peridotite intruded by gabbroic rocks, in order to understand the tectonic and structural processes responsible for formation of oceanic lithosphere with abundant residual peridotite exposed on the seafloor coupled with a relatively low proportion of volcanic rocks. Based on proportions of recovered lithologies, the entire area may be underlain by mantle peridotite with ~20%–40% gabbroic intrusions and impregnations. Impregnated peridotites with olivine + two pyroxenes + plagioclase + spinel that apparently formed in equilibrium probably record crystallization from primitive mid-ocean-ridge basalt at pressures of 0.5–0.6 GPa. Metamorphic equilibria record isobaric cooling to ~1100°C at this pressure. Thus, the conductively cooled thermal boundary layer beneath the Mid-Atlantic Ridge in this region is >15 km thick. Combined crystallization and reaction with residual peridotite formed a series of impregnated peridotites recording increasing Na content at nearly constant Mg#; this process could explain some of the variation in fractionation-corrected Na (e.g., Na = 8.0) observed in mid-ocean-ridge basalts. Clinopyroxene textures and compositions record such impregnation processes, and they are particularly well documented for Site 1274. Other Leg 209 gabbroic rocks formed from extensive crystallization of highly evolved melts, indicating that a substantial proportion of melt entering the thermal boundary layer crystallizes entirely beneath the seafloor, with no volcanic equivalent. Alteration of peridotites occurred over a range of temperatures and is the result of three distinct processes: rock-dominated serpentinization with formation of brucite in olivine-rich lithologies, fluid-dominated serpentinization with formation of magnetite and no brucite, and fluid-dominated talc alteration with addition of SiO2 as well as H2O and oxygen. The latter two processes also exhibit detectable trace element metasomatism that is distinct in its character from the igneous impregnation described in the previous paragraph. Microstructures show that most residual peridotites were not ductilely deformed at temperatures less than ~1200°C. Structural and paleomagnetic data require tectonic rotations of relatively undeformed blocks; some rotations probably exceeded 60° around nearly horizontal axes parallel to the rift axis. Rotations occurred along several generations of high-temperature mylonitic shear zones extending deeper than 15 km depth and numerous faults at lower temperature. Early formed shear zones and faults were passively rotated around later features; such a process could have produced low-angle fault surfaces without slip on low-angle faults. This region provides end-member examples of processes that are common at many or most slow-spreading ridges. Osmium isotope ratios indicate an ancient history of depletion for residual peridotites from the 14°–16°N region along the Mid-Atlantic Ridge. Though depleted Os isotope ratios in peridotite have been reported elsewhere along the global ridge system, the values from this region are among the most depleted. In general, Os isotope ratios from mid-ocean-ridge basalts are systematically more radiogenic than Os isotope ratios from ridge peridotite samples, suggesting a polygenetic heterogeneous source for mid-ocean-ridge basalts. Geochemical studies of zircons from Leg 209 gabbroic rocks and impregnated peridotites, together with other ridge and arc-related zircons, indicate that ridge zircons have systematically lower fractionation-corrected U and Th concentrations compared to arc zircons. This observation provides a tool for interpreting the tectonic provenance of ancient detrital zircons and indicates an arclike provenance for Hadean detrital zircons. Geobiological studies and aerobiological studies were also undertaken during Leg 209. The geobiological work found no measurable microbial enhancement of olivine dissolution rate, possibly because the samples from Leg 209 were sterile. The aerobiological study determined that dust from North Africa, collected from the derrick of the JOIDES Resolution during Leg 209, contains a variety of abundant microorganisms.
Proceedings ODP, scientific results, 209

hal-00407966
https://hal.archives-ouvertes.fr/hal-00407966
DOI : 10.2973/odp.proc.sr.209.001.2007

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We performed torsional deformation experiments on pre-hydrated fine-grained olivine aggregates using an innovative experimental assembly to investigate water weakening in mantle rocks at high shear strains. San Carlos olivine powder was cold-pressed and then hot-pressed under hydrous conditions, producing aggregates with average grain sizes of 7 or 15 μm. Deformation experiments were performed in a high-resolution gas-medium apparatus equipped with a torsional actuator, under a confining pressure of 300 MPa, a temperature of 1200 °C, and constant shear strain rates ranging from 8 × 10−5 to 1.4 × 10−4 s−1. Maximum shear stresses range from 150 to 195 MPa. These values are 30% lower relative to those determined in previous torsion experiments on dry, fined-grained dunites under similar conditions. Textures and microstructures of the starting and deformed specimens were characterized by scanning and transmission electron microscopy. All deformed aggregates exhibit a shape-preferred orientation marking a foliation and lineation, as well as a reduction in mean grain size from 15 μm down to 3-4 μm due to dynamic recrystallization. Olivine crystallographic fabrics developed rapidly (γ < 0.1), but their strength, characterized by the J-index, is low compared to naturally deformed peridotites or to polycrystalline olivine deformed at similar finite shear strains under dry conditions. The crystallographic fabrics are consistent with deformation by a dislocation accommodated creep mechanism with activation of multiple {0 k l}[1 0 0] systems, among which the (0 1 0)[1 0 0] slip system is dominant, and minor participation of the (0 1 0)[0 0 1] slip system. Transmission electron microscopy confirmed the occurrence of dislocations with [1 0 0] and [0 0 1] Burgers vectors in most grains. Analysis of unpolarized infrared spectra indicates that hydrogen concentration in the olivine lattice is below the saturation level of 18 ppm wt H2O, which is similar to those typically observed in spinel-bearing peridotite xenoliths, and also provide evidence for water-rich inter-granular material trapped in pores and grain boundaries. Seismic properties computed from the CPO observations correspond to those most commonly observed in naturally deformed mantle peridotites with fast P-wave propagation and S-wave polarization subparallel to the shear direction. These torsion experiments on fine-grained olivine polycrystals under hydrous conditions indicate that water weakening under lithospheric conditions is linked to various defects with hydrogen in the olivine structure, as well as with water-derived species in grain boundaries or pores.
ISSN: 0031-9201

hal-00745170
https://hal.archives-ouvertes.fr/hal-00745170
DOI : 10.1016/j.pepi.2012.05.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This work shows the preparation and separation performance assessment of carbon membranes derived from phenolic resin by a vacuum-assisted method and carbonisation in an inert atmosphere. The vacuum time played an important role in tailoring the structure of the membranes. For instance, pore volumes and surface areas increased from 0.81 and 834 to 2.2 cm3g−1and 1910 m2g−1, respectively, as the vacuum time exposure increased from 0 to 1200 s. The significant structural changes correlated very well with water permeation, as fluxes increased by 91% as the vacuum time increased from 0 to 1200 s reaching up to 169 L m−2h−1at 5 bar. Molecular weight cut-off tests showed no rejection for the smaller glucose and sucrose molecules, though this increased to ~ 80% and full rejection for 36 kDa and 400 kDa polyvinyl pyrrolidine. Interestingly, FTIR spectra showed that the peaks of C–H stretching vibration (2800–3200 cm−1) and C–O stretching (1030 cm−1) became more pronounced as a function of increasing vacuum time, strongly suggesting that the use of vacuum further assisted in the polycondensation of phenolic oligomers. Based on these outcomes, a cluster to cluster model is proposed, whereby vacuum application promoted crosslinking reactions of the phenolic resin, creating microporous regions within the clusters, and mesoporous regions between the clusters. © 2016 Elsevier B.V
ISSN: 0376-7388

hal-01683220
https://hal.univ-antilles.fr/hal-01683220
DOI : 10.1016/j.memsci.2016.11.002

Éditeur(s) : HAL CCSD
Résumé : International audience
The Cenozoic weathering of peninsular India has been advocated as a major driver of globalcooling, however, its timing remains virtually unconstrained such that proposed links betweentropical weathering of the Deccan Traps, regional monsoonal intensity and global climate remainsspeculative. To solve this conundrum we present here a revised weathering chronologybased on the identification of lateritic paleosurfaces and their dating using 40Ar/39Ar on supergeneK-rich manganese oxides. We focus on the Indian western passive margin where theWestern Ghats Escarpment (WGE) – a ~1000 m high topographic barrier resulting from thecontinental break up of Greater India – exposes exceptionally preserved weathering profilesfrom the western coastal lowlands to the eastern highland plateaus above the WGE. Four mainlateritic paleosurfaces have been identified: Three in the highland; a high landsurface (Al-Femostly bauxite) at elevation 1200-1000 m asl, an intermediate landsurface covered by a Feduricrustat 1000-900 m asl and a lower pediment landsurface at 850-600 m asl; and one inthe coastal lowland underneath a pediment landsurface at 150-50 m asl. The 40Ar/39Ar agesdocument three major weathering periods over the Cenozoic. The oldest weathering period(W1) is recorded between 53 Ma to 45 Ma both in the highland and the lowland. This correlatesto the Global Eocene climatic Optimum, and allows defining a bauxitic paleolandsurface acrossthe escarpment. Intense bauxitic weathering between ~ 45 and 47 Ma in the lowland indicatethat the WGE was stabilized before ~ 47 Ma on its margin and also implies low denudation rateat the foot of the WGE (<5 m Ma-1) since that time. The second weathering period between37 Ma to 19 Ma (W2) occurred in two distinctive stages (W2a and W2b). From 37 to 26 (W2a),weathering is only recorded in the highland and affect intermediate surfaces. The intensityof chemical weathering decreased sensibly between 32 and 29 Ma – potentially linked to theEarly Oligocene cooling – and resulted in the formation of the lower pediment surface. From~26 Ma to 19 Ma (W2b), only the western coastal lowland weathered while the highland surfacesare mostly dissected. This change and the highland/lowland weathering mitigation after~26 Ma documents a change in climatic patterns over peninsular India that signs the onset ofmodern-like monsoon regime. These results are being interpolated to the Deccan Traps basaltsto quantify their weathering and ultimately estimate of the contribution to CO2 fluxes of thesethree weathering periods and their potential link to Asian Monsoons and global cooling.
Source to Sink: a long term perspective of sediment budgets and sources characterization, Abstracts
Rennes, France

insu-01406455
https://hal-insu.archives-ouvertes.fr/insu-01406455

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The kinetics of hydrogenation of dry iron-bearing olivine single crystals was determined by performing hydration experiments under hydrothermal conditions at high pressure. The experiments were performed in a multi-anvil press at 3 GPa, for a temperature range between 900 and 1200 °C and for various durations. The oxygen fugacity was buffered along Ni-NiO joint. Polarized Fourier transform infrared spectroscopy and recent empirical calibration were used to quantify the hydroxyl distributions in the samples along crystallographic axes after the experiments. The chemical diffusion coefficients are similar (barely slower) than in olivine hydrated at lower pressure (0.2 and 0.3 GPa) for the same diffusion mechanism. Under the given experimental conditions, the anisotropy of diffusion is the same as for proton-vacancy mechanism, with diffusion along the [0 0 1] axis faster than along the [1 0 0]. However, the anisotropy at 3 GPa is weaker compared to measurements at lower pressures and the analysis of concentration profiles using 3D models shows that an isotropic solution could also be relevant. Fits of the diffusion data to an Arrhenius law yield activation energies for the slightly faster [0 0 1] axis of the crystallographic axes around 198 ± 5 kJ mol−1, a value only slightly lower than the results from previous experimental studies for natural iron-bearing olivine hydrogenated at lower confining pressure. At 3 GPa, hydrogenation can be well approximated by a single mechanism controlled by coupled diffusion of protons and octahedral vacancies (di- and tri-valent ions). The diffusion rates are fast enough to alter hydrogen concentration within olivine in xenoliths ascending from the mantle or experiencing hydrogen-rich metasomatism events, but too slow to permit complete homogenization of hydrogen in olivine-rich rocks at kilometer scale in less than one My.
ISSN: 0031-9201

hal-01412663
https://hal.archives-ouvertes.fr/hal-01412663
DOI : 10.1016/j.pepi.2016.08.005

Éditeur(s) : HAL CCSD MDPI
Résumé : International audience
This work investigates the structural formation and analyses of titania membranes (TM) prepared using different vacuum exposure times for molecular weight (MW) cut-off performance and oil/water separation. Titania membranes were synthesized via a sol-gel method and coated on macroporous alumina tubes followed by exposure to a vacuum between 30 and 1200 s and then calcined at 400 °C. X-ray diffraction and nitrogen adsorption analyses showed that the crystallite size and particle size of titania increased as a function of vacuum time. All the TM membranes were mesoporous with an average pore diameter of ~3.6 nm with an anatase crystal morphology. Water, glucose, sucrose, and polyvinylpyrrolidone with 40 and 360 kDa (PVP-40 kDa and PVP-360 kDa) were used as feed solutions for MW cut-off and hexadecane solution for oil filtration investigation. The TM membranes were not able to separate glucose and sucrose, thus indicating the membrane pore sizes are larger than the kinetic diameter of sucrose of 0.9 nm, irrespective of vacuum exposure time. They also showed only moderate rejection (20%) of the smaller PVP-40 kDa, however, all the membranes were able to obtain an excellent rejection of near 100% for the larger PVP-360 kDa molecule. Furthermore, the TM membranes were tested for the separation of oil emulsions with a high concentration of oil (3000 ppm), reaching high oil rejections of more than 90% of oil. In general, the water fluxes increased with the vacuum exposure time indicating a pore structural tailoring effect. It is therefore proposed that a mechanism of pore size tailoring was formed by an interconnected network of Ti-O-Ti nanoparticles with inter-particle voids, which increased as TiO2 nanoparticle size increased as a function of vacuum exposure time, and thus reduced the water transport resistance through the TM membranes. © 2016 by the authors.
ISSN: 1996-1944

hal-01683214
https://hal.univ-antilles.fr/hal-01683214
DOI : 10.3390/ma9110938

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
In the Tifnoute Valley, three plutonic units have been defined: the Askaoun intrusion, the Imourkhssen intrusion and the Ougougane group of small intrusions. They are made of quartz diorite, granodiorite and granite and all contain abundant mafic microgranular enclaves (MME). The Askaoun granodiorite and the Imourkhssen granite have been dated by LA-ICP-MS on zircon at 558 ± 2 Ma and 561 ± 3 Ma, respectively. These granitic intrusions are subcontemporaneous to the widespread volcanic and volcano-detrital rocks from the Ouarzazate Group (580-545 Ma), marking the post-collisional transtensional period in the Anti-Atlas and which evolved towards alkaline and tholeiitic lavas in minor volume at the beginning of the Cambrian anorogenic intraplate extensional period. Geochemically, the Tifnoute Valley granitoids belong to an alkali-calcic series (high-K calc-alkaline) with typical Nb-Ta negative anomalies and no alkaline affinities. Granitoids and enclaves display positive εNd-560Ma (+0.8 to +3.5) with young Nd-TDM between 800 and 1200 Ma and relatively low 87Sr/86Sr initial ratios (Sri: 0.7034 and 0.7065). These values indicate a mainly juvenile source corresponding to a Pan-African metasomatized lithospheric mantle partly mixed with an old crustal component from the underlying West African Craton (WAC). Preservation in the Anti-Atlas of pre-Pan-African lithologies (c. 2.03 Ga basement, c. 800 Ma passive margin greenschist-facies sediments, allochthonous 750-700 Ma ophiolitic sequences) indicates that the Anti-Atlas lithosphere has not been thickened and was never an active margin during the Neoproterozoic. After a transpressive period, the late Ediacaran period (580-545 Ma) is marked by movement on near vertical transtensional faults, synchronous with the emplacement of the huge Ouarzazate Group and the Tifnoute Valley granitoids. We propose here a geodynamical model where the Tifnoute Valley granitoids as well as the Ouarzazate Group were generated during the post-collisional metacratonic evolution of the northern boundary of the West African craton. The convergence with the peri-Gondwanan active margin produced brittle fracturing of the cratonic boundary without thickening, allowing rising of magmas. The Tifnoute Valley granitoids display a metasomatized lithospheric mantle source mixed with a minor ancient (2 Ga) continental crust component from the underlying WAC.
ISSN: 0930-0708

halsde-00782152
https://hal.archives-ouvertes.fr/halsde-00782152
DOI : 10.1007/s00710-012-0245-3

Éditeur(s) : HAL CCSD Elsevier
Résumé : In situ analysis of major elements, platinum-group elements and Os isotope composition data for 170 grains of Ru–Os–Ir alloys from podiform chromitites in the Luobusa and Dongqiao ophiolites, Tibet, provide new constraints on the sources of the alloy grains, the Os-isotope composition of the Neo-Tethyan oceanic upper mantle, and the timing of melt–rock reactions in the ultramafic peridotites of the host ophiolites. Most alloy grains are osmiridium and iridosmine. Based on elemental and isotopic compositions, two populations can be identified. Group I, found in both ophiolite bodies, has fractionated PGE patterns typical of alloys and homogeneous 187Os/188Os 0.12645 ± 4 (2s; n = 145). Group II alloys from the Dongqiao ophiolites show smooth PGE patterns and 187Os/188Os ranges from 0.12003 to 0.12194 (yielding Re-depletion ages ≥ 1.1 Ga). Both the PGE patterns and the Os isotopic compositions of Group II resemble those of sulfides residual after melting. Group I alloys represent an early cumulate phase during the crystallization of magmas and are interpreted as derived from an asthenospheric melt. In contrast, Group II alloys are inferred to derive from the breakdown of residual sulfides from the mantle section of the ophiolite, which may represent relics of a sub-continental lithospheric mantle. The coexistence of the two groups of alloys in Dongqiao samples reflects interaction between asthenosphere-derived melts and old depleted lithospheric mantle and suggests that the chromitites originated through melt–rock reactions. The data on the Group I alloys support the hypothesis that the Re–Os evolution of the convective oceanic mantle resembles that of enstatite chondrites.
ISSN: 0012-821X

hal-00404967
https://hal.archives-ouvertes.fr/hal-00404967
DOI : 10.1016/j.epsl.2007.05.044