Éditeur(s) : University of the Virgin Islands University of the Virgin Islands ( Gallows Bay, St. Croix V.I )
Résumé : Cover title.
"September 1996."
"UVI Cooperative Extension Service, VI Resource Conservation and Development Council, Inc., USDA Natural Resources Conservation Service"--P. 1 of each section.
(Statement of Responsibility) Virgin Islands Resource Conservation & Development Council, Inc.
United States Virgin Islands
Virgin Islands of the United States
Virgin Islands of the United States
Virgin Islands of the United States
Virgin Islands of the United States

49936692

Éditeur(s) : Water Resources Research Center, Caribbean Research Institute, College of the Virgin Islands Water Resources Research Center, Caribbean Research Institute, College of the Virgin Islands ( St. Thomas, USVI )
Résumé : (Bibliography) Includes bibliographical references.
Supported in part by funds provided by the United States Department of the Interior, as authorized by the Water Research and Development Act of 1978.
"December 1976."
Partial completion report, project No. A-003-VI, agreement No. A-31-0001-5053.
(Statement of Responsibility) by Dr. Jerome L. McElroy.
United States Virgin Islands
Virgin Islands of the United States
Virgin Islands of the United States

10093782

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The interplay between fault zone cataclasis and cementation is important since both processes can drastically reduce the permeability of faults in porous sandstones. Yet the prediction of fault cementation in high-porosity sandstone reservoirs remains elusive. Nevertheless, this process has rarely been investigated in shallowly buried faults (<2 km; T°<80 °C) where its sealing capacity could be acquired early in the geological history of a reservoir. In this paper, the macro- and microscopic analysis of a fault zone in the porous Cenomanian quartz arenite sands of Provence (France) shows that silica diagenesis occurs in the most intensely-deformed cataclastic parts of the fault zone. This fault zone shows 19–48% of its total thickness occupied by low-porosity quartz-cemented cataclastic shear bands whose porosities range from 0 – ca. 5%. The analysis of the weathering profile around the fault zone reveals the presence of groundwater silcretes in the form of tabular, tightly silicified concretions cross-cut by the fault. Detailed transmitted light, cold-cathodoluminescence and scanning electron microscopy analyses of the silica cements (from the fault and the silcrete) reveal that all the silica cements originate from groundwater diagenetic processes. This study therefore shows that silica cementation can occur specifically in fault zones and as groundwater silcrete in the shallow context of a groundwater system, generated at the vicinity of an erosional unconformity.
ISSN: 0191-8141

hal-01278286
https://hal.archives-ouvertes.fr/hal-01278286
DOI : 10.1016/j.jsg.2015.10.001

Éditeur(s) : HAL CCSD
Résumé : International audience
This communication reports on a field experiment carried out on a microtidal beach in Camargue, France. The analysis is built on the initial work presented by Sous et al. (2016) on swash-groundwater dynamics. The analysis of a cross-shore network of buried pressure sensors allows to monitor the watertable dynamics over the full 2013-2014 winter season. The pressure head gradients are observed to be primarily seaward, forced by a higher level at the landward boundary. The groundwater flux is driven by the relative fluctuations of Still Water Level and inland elevations. Rain and tides have a little effect. A nearly isolated groundwater circulation is driven by wave activity below the swash zone whatever the overall watertable gradient. Estimations of beach groundwater discharge over the Gulf of Beauduc reveal the importance of beach groundwater in the exchanges between coastal aquifer and open sea.
Coastal Dynamics 2017
Helsingor, Denmark

hal-01562908
https://hal.archives-ouvertes.fr/hal-01562908

Éditeur(s) : HAL CCSD
Résumé : 1 p.
For groundwater issues (potential leakages in waste repository, aquifer management ...), the development of modeling techniques is far ahead of the actual knowledge of aquifers. This raises two fundamental issues: 1) which and how much data are necessary to make predictions accurate enough for aquifer management issues; 2) which models remain relevant to describe the heterogeneity and complexity of geological systems. The French observatory H+ was created in 2002 with the twofold motivation of acquiring a large database for validating models of heterogeneous aquifers, and of surveying groundwater quality evolution in the context of environmental changes. H+ is a network of 4 sites (Ploemeur, Brittany, France; HES Poitiers, France; Cadarache, France; Campos, Mallorca, Spain) with different geological, climatic, and economic contexts. All of them are characterized by a highly heterogeneous structure (fractured crystalline basement for Ploemeur, karstified and fractured limestone for Poitiers, Cadarache and Mallorca), which is far to be taken into account by basic models. Ploemeur is exploited as a tap-water plant for a medium-size coastal city (15,000 inhabitants) for 20 years. Each site is developed for long term investigation and monitoring. They involves a dense network of boreholes, detailed geological and geophysical surveys, periodic campaigns and/or permanent measurements of groundwater flow, water chemistry, geophysical signals (including ground motions), climatic parameter, etc. Several large-scale flow experiments are scheduled per year to investigate the aquifer structure with combined geophysical, hydrogeological, and geochemical instruments. All this information is recorded in a database that has been developed to improve the sustainability and quality of data, and to be used as a collaborative tool for both site researchers and modelers. This project lasts now for 5 years. It is a short time to collect the amount of information necessary to apprehend the complexity of aquifers; but it is already enough to obtain a few important scientific results about the very nature of the flow heterogeneity, the origin and residence time of water elements, the kinetic of geochemical processes, etc. We have also developed new methods to investigate aquifers (in-situ flow measurements, flow experiment designs, groundwater dating, versatile in-situ probes, etc.). This experience aiming at building up long term knowledge appears extremely useful to address critical issues related to groundwater aquifers: the structure and occurrence of productive aquifer in crystalline basement, the assessment of aquifer protection area in the context of highly heterogeneous flow, the biochemical reactivity processes, the long term evolution of both water quantity and quality in the context of significant environmental changes, for instance.
AGU, Fall Meeting 2008
San Francisco, United States

insu-00375980
https://hal-insu.archives-ouvertes.fr/insu-00375980

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This manuscript reports on a novel field experiment carried out on a microtidal beach in Camargue, France. For the first time in the field, a comprehensive description of the groundwater dynamics under sandy beach swash zone is presented. A cross-shore network of 15 buried pressure sensors is combined with terrestrial LiDAR measurements to study the swash-groundwater dynamics. The presented data focus on the decay of a moderate storm which allows to monitor the evolution of the groundwater pressure field in response to the retreat of the swash zone. Both horizontal and vertical head gradients are measured within the porous sand soil to estimate the groundwater flow field using Darcy’s law. Time-averaged analysis demonstrates the presence of a rather consistent groundwater circulation pattern under the swash zone, shifting offshore with the swash zone. The main tendency is an offshore directed flow, with infiltration/exfiltration in the upper/lower parts of the swash zone. Time-resolved analysis highlights the typical groundwater response to swash events which consists mainly of an overall infiltration flow during the bed inundation by the swash tongue, a seaward flow during the swash retreat and, for long backwash events, a localized exfiltration flow under the next incoming uprush.
ISSN: 0309-1708

hal-01412450
https://hal.archives-ouvertes.fr/hal-01412450
DOI : 10.1016/j.advwatres.2016.09.009

Éditeur(s) : HAL CCSD
Résumé : International audience
Characterizing the hydraulic properties of heterogeneous and complex aquifers often requires field scale investigations at multiple space and time scales to better constrain hydraulic property estimates. Here, we present and discuss results from the site of Ploemeur (Brittany, France) where complementary hydrological and geophysical approaches have been combined to characterize the hydrogeological functioning of this highly fractured crystalline rock aquifer. In particular, we show how cross-borehole flowmeter tests, pumping tests and frequency domain analysis of groundwater levels allow quantifying the hydraulic properties of the aquifer at different scales. In complement, we used groundwater temperature as an excellent tracer for characterizing groundwater flow. At the site scale, measurements of ground surface deformation through long-base tiltmeters provide robust estimates of aquifer storage and allow identifying the active structures where groundwater pressure changes occur, including those acting during recharge process. Finally, a numerical model of the site that combines hydraulic data and groundwater ages confirms the geometry of this complex aquifer and the consistency of the different datasets. The Ploemeur site, which has been used for water supply at a rate of about 106 m3 per year since 1991, belongs to the French network of hydrogeological sites H+ and is currently used for monitoring groundwater changes and testing innovative field methods.
AGU Fall Meeting 2014
San Francisco, United States

insu-01088596
https://hal-insu.archives-ouvertes.fr/insu-01088596

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : A detailed and integrated geologic–hydraulic–geophysical–geochemical study of groundwater flow in the near-vicinity of a borehole drilled into fractured and karstified limestone demonstrates the power of such an integrated approach in localising and characterising preferential groundwater flow pathways and ambient borehole flow. The study, conducted in the vicinity of a 100-m-deep research borehole on the island of Mallorca, achieves such characterisation on a scale from millimetres to tens of metres in scale. More specifically, it adds single packer and open-hole pumping test interpretations to the results obtained during fluid logging, impeller flowmeter testing, borehole imaging, core descriptions and an innovative fracture analysis. This approach allows the delineation of the main flowing features and showed that such features are directly or indirectly linked to karst phenomena. Understanding this complex flow system is critical for an appropriate assessment of groundwater resources and the design of sustainable groundwater production schemes.
ISSN: 1431-2174

hal-00404921
https://hal.archives-ouvertes.fr/hal-00404921
DOI : 10.1007/s10040-006-0086-4

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
Most of the Mediterranean coastal porous aquifers are intensively exploited. Because of climatic and anthropogenic effects, understanding the physical and geological controls on groundwater distribution and flow dynamics in such aquifers is crucial. This study presents the results of a structural investigation of a system located along the coastline of the Gulf of Lions (NW Mediterranean). A key aspect of this study relies on an onshore-offshore integrated approach combining outcrops, seismic profiles, and borehole data analysis. This multidisciplinary approach provides constraints on pore-fluid salinity distribution and stratigraphic organization, which are crucial in assessing the modes of groundwater/seawater exchanges. Onshore, Lower Pliocene deposits dip gently seaward. They are unconformably overlain by Holocene clays in the lagoons. Offshore the Pliocene deposits either outcrop at the seabed or are buried below nonconsolidated sands infilling paleo-valleys. Beneath the lido, the groundwater salinity distribution consists of salty pore water, overlying fresher pore water. Active circulation of groundwater masses is inferred from the geophysical results. In particular, offshore outcrops and paleo-valleys may play an important role in salt water intrusion.
ISSN: 0017-467X

halsde-00866825
https://hal.archives-ouvertes.fr/halsde-00866825
DOI : 10.1111/j.1745-6584.2012.01011.x

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Roussillon sedimentary Basin (South France) is a complex multi-layered aquifer, close to the Mediterranean Sea facing seasonally increases of water abstraction and salinization issues. We report geochemical and isotopic vertical variability in this aquifer using groundwater sampled with a Westbay System® at two coastal monitoring sites: Barcarès and Canet. The Westbay sampling allows pointing out and explaining the variation of water quality along vertical profiles, both in productive layers and in the less permeable ones where most of the chemical processes are susceptible to take place.The aquifer layers are not equally impacted by salinization, with electrical conductivity ranging from 460 to 43,000 μS·cm− 1. The δ2H–δ18O signatures show mixing between seawater and freshwater components with long water residence time as evidenced by the lack of contribution from modern water using 3H, 14C and CFCs/SF6. S(SO4) isotopes also evidence seawater contribution but some signatures can be related to oxidation of pyrite and/or organically bounded S. In the upper layers 87Sr/86Sr ratios are close to that of seawater and then increase with depth, reflecting water–rock interaction with argillaceous formations while punctual low values reflect interaction with carbonate. Boron isotopes highlight secondary processes such as adsorption/desorption onto clays in addition to mixings. At the Barcarès site (120 m deep), the high salinity in some layers appear to be related neither to present day seawater intrusion, nor to Salses-Leucate lagoonwater intrusion. Groundwater chemical composition thus highlights binary mixing between fresh groundwater and inherited salty water together with cation exchange processes, water–rock interactions and, locally, sedimentary organic matter mineralisation probably enhanced by pyrite oxidation.Finally, combining the results of this study and those of Caballero and Ladouche (2015), we discuss the possible future evolution of this aquifer system under global change, as well as the potential management strategies needed to preserve quantitatively and qualitatively this water resource.
ISSN: 0048-9697

hal-01685219
https://hal-brgm.archives-ouvertes.fr/hal-01685219
DOI : 10.1016/j.scitotenv.2016.05.016

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
This paper presents a multicontinuum approach to model fractal temporal scaling of catchment response in hydrological systems. The temporal scaling of discharge is quantified in frequency domain by the transfer function HðxÞ, which is defined as the ratio between the spectra of catchment response and recharge time series. The transfer function may scale with frequency x as HðxÞ x2b. While the classical linear and Dupuit models predict exponents of b52 and b51, observations indicate scalings with noninteger exponents b. Such behaviors have been described by multifractal models, which, however, often lack a relation to the medium characteristics. We revisit and extend the classical linear Dupuit aquifer models and discuss their physical meanings in the light of the resulting aquifer dynamics. On the basis of these classical models, we derive a multicontinuum approach that provides physical recharge models which are able to explain fractal behaviors with exponents 1=2 < b < 2. Furthermore, this approach allows to link the fractal dynamics of the discharge process to the physical aquifer characteristics as reflected in the distribution of storage time scales. We systematically analyze the catchment responses in the proposed multicontinuum models, and identify and quantify the time scales which characterize the dynamics of the catchment response to recharge.
ISSN: 0043-1397

insu-00952537
https://hal-insu.archives-ouvertes.fr/insu-00952537
https://hal-insu.archives-ouvertes.fr/insu-00952537/document
https://hal-insu.archives-ouvertes.fr/insu-00952537/file/russian.pdf
DOI : 10.1002/2013WR014255

Éditeur(s) : Elsevier
Résumé : In situ microbialites occurring in reef rocks dredged between 80 and 130 in water depth on the modern fore-reef slopes of Tahiti and the Marquesas islands yield ages ranging from 17,100 2900 to 4410 2250 years BP, suggesting that they played a prominent role during the last deglacial sea level rise. Microbialites developed in both shallow and deep water depositional environments where they characterize various zones of the reef tracts (reef crests, upper reef slopes, deep fore-reef slopes), reflecting contrasting scenarios of microbialite development involving ''reefal microbialites'' in shallow-water settings and ''slope microbialites'' that formed in environments deeper than 1020 in and extending down to more than 100 m. Reefal microbialites correspond to a late stage of encrustation of the dead parts of coral colonies, or more commonly, of related encrusting organisms (red algae and foraminifers), thus forming surface crusts. Slope microbialites generally form the ultimate stage of a biological succession indicating a deepening sequence, whereby shallow water corals and associated encrusting organisms are replaced by deeper water assemblages of red algae and foraminifers before microbialite growth. The precipitation of phosphatic-iron-manganese crusts and the deposition of planktonic micritic limestones on the microbialites characterize a deepening-upward sequence. The widespread development of microbialites in reef sequences from the Last Deglaciation characterizes a period of environmental degradation consequential oil the rapid sea-level rise and abrupt climatic changes of that time. The reported biological succession reflects changes in water quality, and especially an increase in nutrients. In shallow-water settings, increased alkalinity and nutrient availability in interstitial waters were related to surface fluxes and terrestrial groundwater seepage while slope environments were exposed to continuous upwelling of nutrient-rich deeper waters during the last deglacial sea level rise. The age differences between corals and overlying slope microbialites range from 1600 to 8400 years, based on high-precision U-series age measurements of both corals and microbialites, and indicates that a significant time (several thousand years) elapsed between the development of the coralgal frameworks and the growth of slope microbialite crusts. Microbialites cannot be considered as part of the drowning event some 14,000 years ago that resulted in the demise of reef frameworks in the 90-110 m present depth range, but are Substantially younger. (c) 2006 Elsevier B.V. All rights reserved.
Sedimentary Geology (0037-0738) (Elsevier), 2006-03 , Vol. 185 , N. 3-4 , P. 277-295

Droits : 2006 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/2006/publication-4204.pdf
DOI:10.1016/j.sedgeo.2005.12.018
http://archimer.ifremer.fr/doc/00000/4204/

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : In this paper we present the potential of a new compact superconducting gravimeter (GWR iGrav) designed for groundwater monitoring. At first, 3 yr of continuous gravity data are evaluated and the performance of the instrument is investigated. With repeated absolute gravity measurements using a Micro-g Lacoste FG5, the calibration factor (−894.8 nm s−2 V−1) and the long-term drift of this instrument (45 nm s−2 yr−1) are estimated for the first time with a high precision and found to be respectively constant and linear for this particular iGrav. The low noise level performance is found similar to those of previous superconducting gravimeters and leads to gravity residuals coherent with local hydrology. The iGrav is located in a fully instrumented hydrogeophysical observatory on the Durzon karstic basin (Larzac plateau, south of France). Rain gauges and a flux tower (evapo-transpiration measurements) are used to evaluate the groundwater mass balance at the local scale. Water mass balance demonstrates that the karst is only capacitive: all the rainwater is temporarily stored in the matrix and fast transfers to the spring through fractures are insignificant in this area. Moreover, the upper part of the karst around the observatory appears to be representative of slow transfer of the whole catchment. Indeed, slow transfer estimated on the site fully supports the low-flow discharge at the only spring which represents all groundwater outflows from the catchment. In the last part of the paper, reservoir models are used to characterize the water transfer and storage processes. Particular highlights are done on the advantages of continuous gravity data (compared to repeated campaigns) and on the importance of local accurate meteorological data to limit misinterpretation of the gravity observations. The results are complementary with previous studies at the basin scale and show a clear potential for continuous gravity time-series assimilation in hydrological simulations, even on heterogeneous karstic systems.
ISSN: 0956-540X

hal-01526965
https://hal.archives-ouvertes.fr/hal-01526965
https://hal.archives-ouvertes.fr/hal-01526965/document
https://hal.archives-ouvertes.fr/hal-01526965/file/fores2016.pdf
DOI : 10.1093/gji/ggw396

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Advances in groundwater storage monitoring are crucial for water resource management and hydrological processes understanding. The evaluation of water storage changes (WSC) often involve point measurements (observation wells, moisture probes, etc.), which may be inappropriate in heterogeneous media. Over the past few years, there has been an increasing interest in the use of gravimetry for hydrological studies. In the framework of the GHYRAF (Gravity and Hydrology inAfrica) project, 3 yr of repeated absolute gravity measurements using a FG5-type gravimeter have been undertaken at Nalohou, a Sudanian site in northern Benin. Hydrological data are collected within the long-term observing system AMMA-Catch. Once corrected for solid earth tides, ocean loading, air pressure effects, polar motion contribution and non-local hydrology, seasonal gravity variations reach up to 11 μGal, equivalent to a WSC of 260-mm thick infinite layer of water. Absolute temporal gravity data are compared to WSC deduced from neutron probe and water-table variations through a direct modelling approach. First, we use neutronic measurements available for the whole vertical profile where WSC occur (the vadose zone and a shallow unconfined aquifer). The RMSD between observed and modelled gravity variations is 1.61 μGal, which falls within the error bars of the absolute gravity data. Second, to acknowledge for the spatial variability of aquifer properties, we use a 2-D model for specific yield (Sy) derived from resistivity mapping and Magnetic Resonance Soundings (MRS). The latter provides a water content (θMRS) known to be higher than the specific yield. Hence, we scaled the 2-D model of θMRS with a single factor (α). WSC are calculated from water-table monitoring in the aquifer layer and neutronic measurements in the vadose layer. The value of α is obtained with aMonte-Carlo sampling approach, minimizing the RMSD between modelled and observed gravity variations. This leads to α = Sy/θMRS = 0.63 ± 0.15, close to what is found in the literature on the basis of pumping tests experiments, with a RMSD value of 0.94 μGal. This hydrogeophysical experiment is a first step towards the use of time-lapse gravity data as an integrative tool to monitor interannual WSC even in complicated subsurface distribution.
ISSN: 0956-540X

hal-00821181
https://hal.archives-ouvertes.fr/hal-00821181
DOI : 10.1093/gji/ggt146

Éditeur(s) : HAL CCSD IWA Publishing
Résumé : International audience
The widely occurring degradation product aminomethylphosphonic acid (AMPA) is a result of glyphosate and amino-polyphosphonate degradation. Massive use of the parent compounds leads to the ubiquity of AMPA in the environment, and particularly in water. The purpose of this review is to summarize and discuss current insights into AMPA formation, transport, persistence and toxicity. In agricultural soils, AMPA is concentrated in the topsoil, and degrades slowly in most soils. It can reach shallow groundwater, but rarely managed to enter deep groundwater. AMPA is strongly adsorbed to soil particles and moves with the particles towards the stream in rainfall runoff. In urban areas, AMPA comes from phosphonates and glyphosate in wastewater. It is commonly found at the outlets of Wastewater Treatment Plants (WWTP). Sediments tend to accumulate AMPA, where it may be biodegraded. Airborne AMPA is not negligible, but does wash-out with heavy rainfall. AMPA is reported to be persistent and can be biologically degraded in soils and sediments. Limited photodegradation in waters exists. AMPA mainly has its sources in agricultural leachates, and urban wastewater effluents. The domestic contribution to urban loads is negligible. There is a critical lack of epidemiological data - especially on water exposure - to understand the toxicological effects, if any, of AMPA on humans. Fortunately, well operated water treatment plants remove a significant proportion of the AMPA from water, even though there are not sufficient regulatory limits for metabolites.
ISSN: 0043-1354

hal-01516026
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01516026
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01516026/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01516026/file/Grandcoin%20et%20al.%20-%20AminoMethylPhosphonic%20acid%20%28AMPA%29%20in%20natural%20water.pdf
DOI : 10.1016/j.watres.2017.03.055

Éditeur(s) : HAL CCSD
Résumé : The presence of biological matter (biofilms) in deep geological sites for storage of, for instance, toxic elements or groundwater in aquifers was clearly proved. That biomass triggers physical and chemical processes which greatly modify the durability and the sustainability of the sites. These processes, mainly from oxidative/reductive reactions, are poorly understood. This is mainly due to the fact that former studies were done at the macroscopic level far away from the micrometric scale where relevant processes induced by bacteria take place. Investigations at microscopic level are needed. Thus, we developed an experimental set-up based on the combined use of optical microscopy (transmission), atomic force microscopy (AFM) and electrical and electro-chemical AFM microscopy (EC_AFM) in order to get simultaneous information on topographic and electro-chemical processes. The first highly sensitive step was to use AFM with biological samples in liquid environment: wepresent here a study about AFM imaging of living, moving or self-immobilized bacteria, in their genuine physiological liquid medium and in true in vivo conditions. No external immobilization protocol, neither chemical nor mechanical was needed. For the first time, the native gliding movements of Gram negative Nostoc cyanobacteria upon the surface were studied by AFM. AFM height and mechanical stiffness data were simultaneously acquired. From these, mechanical parameters, inner turgor pressure and Young modulus, were derived for different bacterial species (Anabaenopsis circularis, Rhodococcus wratislaviensis). Our study revealed that AFM imaging is thus possible on moving living species. These results open a large window on new studies of both dynamical phenomena of practical and fundamental interests such as the formation of biofilms and dynamic properties of bacteria in real physiological conditions. The second delicate step was to combine AFM and optical measurements with electrical ones. We mounted a new experimental set-up coupling real-time (i) monitoring of optical properties as the optical density (OD) evolution related to bulk bacterial growth in liquid or as the counting of number of bacteria adhering on the surface of the sample as well and (ii) electrical and electrochemical measurements. Furthermore, these results will shortly be applied to the optimized monitoring of the in-situ activity of bacteria consuming oil pollutants, following this way, in real-time, the bioremediation of an oilcontaminated soil (ANR ECOTECH_BIOPHY program).
La présence de matière biologique (biofilms) dans les sites de stockage géologique profond, d'éléments toxiques ou encore de l'eau potable des aquifères est maintenant clairement démontrée. Cette biomasse est à l'origine de processus physiques et chimiques qui modifient considérablement la durabilité et la pérennité des sites concernés. Ces processus, principalement de type oxydo-réductif, sont encore mal compris. Ceci est principalement dû aux méthodes d'investigation, principalement macroscopiques, loin de l'échelle micrométrique caractéristique des bactéries. Seules des études, basées sur des méthodes d'investigation locale, peuvent apporter les informations requises. Ainsi, nous avons développé un dispositif expérimental basé sur l'utilisation combinée de la microscopie optique (en transmission), la microscopie à force atomique (AFM) et la microscopie AFM en mode électrique et électrochimique (EC_AFM) afin d'obtenir des informations simultanées sur la topographie de l'échantillon et sur les processus électrochimiques à l'échelle des bactéries. La première étape sensible consistait à utiliser l'AFM sur des échantillons biologiques en milieu liquide: nous présentons ici les résultats de l'imagerie AFM en milieu liquide de plusieurs types de bactéries dans leurs conditions physiologiques naturelles (conditions in vivo). Aucun protocole d'immobilisation, ni chimique ni mécanique, n'a été nécessaire; et pour la première fois, les mouvements de reptation de cyanobactéries Nostoc ont été étudiés par l'AFM. Les études AFM ont permis d'acquérir des données topographiques mais aussi mécaniques : nous avons pu ainsi mesurer le module d'Young, la pression de turgescence de différentes souches bactériennes (Anabaenopsis circularis, Rhodococcus wratislaviensis). Cette étude complète, a révélé que l'imagerie AFM est donc possible sur des espèces vivantes en mouvement. Ces résultats ouvrent une grande fenêtre sur de nouvelles études d'intérêts tels que la formation de biofilms et les propriétés dynamiques de bactéries dans des conditions physiologiques réelles. La deuxième étape délicate était de combiner l'AFM aux mesures optiques et électriques. Nous avons développé un nouveau dispositif expérimental permettant (i) le suivi de l'évolution de la croissance bactérienne par la mesure des propriétés optiques comme la densité optique DO (pour le développement bactérien en volume - milieu planctonique) , ou l'analyse de l'image du substrat par comptage du nombre de bactéries sur la surface de l'échantillon (biofilm), et (ii) les mesures électriques et électrochimiques. L'ensemble de ces résultats sera prochainement appliqué au développement de nouveaux outils de surveillance d'une biodépollution de terrain contaminé par les hydrocarbures, par le suivi in situ et en temps réel de l'activité de bactéries dépolluantes (ECOTECH_BIOPHY ANR).
https://tel.archives-ouvertes.fr/tel-01044714

tel-01044714
https://tel.archives-ouvertes.fr/tel-01044714
https://tel.archives-ouvertes.fr/tel-01044714/document
https://tel.archives-ouvertes.fr/tel-01044714/file/theseDhahri2013.pdf

Éditeur(s) : HAL CCSD
Résumé : Karst systems are the most important groundwater reservoirs in Mediterranean areas. Their structure and functioning are complex and not well known because of the high heterogeneity created and organised by groundwater flow. Water storage entities and water storage changes within remain difficult to assess by direct measurement and modelling. Geodetic monitoring is here used to constrain and bring original insights on karst system functioning. The Durzon karst system (Larzac plateau, Southern France) is monitored by several geodetic techniques: - Monthly absolute gravity measurements at three sites - Time-lapse surface to depth gravity measurements - Time-lapse microgravity surveying - Continuous long base hydrostatic tiltmeter monitoring at two sites Absolute gravity monitoring complemented with relative gravity surveys allows quantification of water storage changes on the studied karst system. Interannual water storage changes as detected by gravity are ~400 mm in amplitude. These storage changes are shown to occur in the epikarst and infiltration zone in certain areas. Water storage variations spatial heterogeneity is also demonstrated on the karst system. Tilt measurements monitor fast and slow infiltration processes within the karst fractured media. Karst system geodetic monitoring brings both quantitative and integrated hydrologic knowledge. Such methods could be applied to other karst aquifer studies.
Les aquifères karstiques constituent l'essentiel des ressources en eau souterraine sur le pourtour de la Méditerranée. Leur structure et leur fonctionnement sont complexes et mal connus à cause du processus de karstification qui hiérarchise la circulation hydrodynamique en leur sein. La localisation du stockage de l'eau et de ses variations au sein de tels aquifères est difficile à mesurer et à modéliser. Nous utilisons les outils de la géodésie pour apporter de nouvelles contraintes sur le fonctionnement hydrologique et les variations de stock d'eau en milieu karstique. Ainsi, le système karstique du Durzon, (Causse du Larzac, France) fait l'objet d'un suivi par plusieurs méthodes géodésiques incluant: - Des mesures de gravimétrie absolue en trois sites répétées de manière mensuelle ; - Des mesures répétées de gravimétrie relative entre la surface et la profondeur du karst ; - Des mesures répétées de microgravimétrie ; - Des mesures inclinométriques longue base en deux sites. Nous démontrons que le couplage entre la gravimétrie absolue et relative permet d'appréhender les variations de stock d'eau sur le bassin d'alimentation étudié. Les variations inter-anuelles observées sont de l'ordre de 400 mm, et nous montrons que celles-ci s'opèrent dans certaines zones au sein des horizons supérieurs du karst : épikarst et zone d'infiltration. Une forte hétérogénéité spatiale des variations de stockage est aussi mise en évidence à l'échelle du bassin d'alimentation. Les mesures inclinométriques permettent de suivre les phénomènes d'infiltration rapide et lente dans la masse karstique fracturée. Le suivi géodésique de ce système karstique permet d'apprécier quantitativement et de façon intégrée son fonctionnement hydrologique et pourra être transposé pour l'étude d'autres aquifère karstiques.
https://tel.archives-ouvertes.fr/tel-00404851

tel-00404851
https://tel.archives-ouvertes.fr/tel-00404851
https://tel.archives-ouvertes.fr/tel-00404851/document
https://tel.archives-ouvertes.fr/tel-00404851/file/THESE_jacob.pdf

Éditeur(s) : HAL CCSD
Résumé : Karst systems are the most important groundwater reservoirs in Mediterranean area. Beyond saturated zone, unsaturated zone constitute an entity where water storage and transfer play a major role in a global behavior of spring water. This structure and functioning are complex and not well known because of the high heterogeneity created and organized by groundwater flow. In this study, we used gravimetric and hydrogeologic method to directly observe and quantify water storage and transfer processes in unsaturated zone of karst system. Surface to depth gravity measurements on several karst system allow quantifying seasonal water storage changes in unsaturated zone. We show that these variations occur in the first tens meters of unsaturated zone. Furthermore, water storage capacity of unsaturated zone seems to be influenced by lithology (limestone or dolomite). Finally, direct observations of water flow in unsaturated zone are done using caves access. We show that some characteristics of unsaturated water flow such as bipolar slow-fast flow can be widespread for whatever depth of measurement and recharge area. Model of this flow, using a simple modeling scheme, show the complexity of water transfer processes in unsaturated zone of karst system.
Les aquifères karstiques constituent l'essentiel des ressources en eau du pourtour Méditerranéen. Au-delà de la zone saturée de ces systèmes, la zone non saturée constitue une entité importante quant au transfert et au stockage temporaire de l'eau. La structure et le fonctionnement de cette entité du karst sont complexes et mal connus à cause du processus de karstification qui hiérarchise la circulation hydrodynamique en son sein. Dans cette étude nous utilisons des méthodes géodésiques et hydrogéologiques afin d'observer de façon directe et de quantifier les processus de transfert et de stockage de la zone non saturée. Les mesures gravimétriques en surface et profondeur sur différents systèmes karstiques ont permis de quantifier les variations du stockage en eau saisonnier dans la zone non saturée. La gravimétrie différentielle montre que ces variations sont réparties dans les quelques premiers mètres de la zone non saturée. Il semble, de plus, que la capacité de stockage de la zone non saturée soit fonction de la lithologie de l'encaissant (calcaire et dolomie). Enfin, des observations directes du flux d'eau en zone non saturée ont été effectuées par le biais de mesures dans différentes cavités. Nous montrons que certaines caractéristiques du flux d'eau en zone non saturée, comme la présence d'un flux bipolaire lent-rapide, peuvent être généralisées quelque soit la profondeur de mesure et la surface d'impluvium. La modélisation de ce flux, à partir d'un schéma simple, a montré la complexité des processus de transfert engendrés au sein de la zone non saturée.
https://tel.archives-ouvertes.fr/tel-00829346

tel-00829346
https://tel.archives-ouvertes.fr/tel-00829346
https://tel.archives-ouvertes.fr/tel-00829346/document
https://tel.archives-ouvertes.fr/tel-00829346/file/manuscrit_deville_finish.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In order to perform a human and ecological risk assessment of pharmaceutical products (PPs) in natural waters, it is necessary to accurately quantify a broad variety of PPs at low concentrations. Although numerous currently implemented analytical methodologies, less is known about the preservation of PPs in natural water samples within the period before analysis (holding time, storage conditions). This paper is the first literature review about the stability of PPs in natural waters (surface and groundwaters) during sample storage. The current work focuses on a comparison of the performances of the available preservation techniques (filtration, container materials, storage temperature, preservative agents, etc.) for PPs in samples. All 58 reviewed PPs may be successfully stabilized during 7 days in surface waters by at least one appropriate methodology regarding temperature, acidic and non-acidic preservatives. When temperature is not a sufficient preservation parameter f! or some PPs (hormones and fluoxetine) its combination with the addition of chemical agents into the samples may prolong the integrity of the PPs during storage in surface water. There is a strong need to use standard protocols to assess and compare the stability of PPs in environmental water matrices during storage as well as during analytical preparation or analysis (European criteria 2002/657/EC). Since the stability of PPs during sample storage is a critical parameter that could call into question the quality of the data provided for the concentrations, the design of stability studies should rigorously take into account all critical parameters that could impact the concentrations of the PPs with time.
Talanta

insu-00839186
https://hal-insu.archives-ouvertes.fr/insu-00839186
DOI : 10.1016/j.talanta.2013.01.042

Éditeur(s) : HAL CCSD
Résumé : Karstic aquifers represent the most important fresh water reservoirs in many regions of the world like the Mediterranean Basin. However, because of complex processes of karstification, those aquifers are highly heterogeneous at all spatial scales and vulnerable to contamination. In this dissertation, we studied the potential of gravimetry and ambient seismic noise for hydrological modeling in karstic areas.The dolomitic area surrounding the “GEK” observatory in the Durzon catchment on the Larzac plateau, in France, is the preferred site for these studies. Inside the observatory, a superconducting gravimeter dedicated to hydrology has continuously measured gravity changes since 2011 with high precision, undertaken for the first time on a karst. From this gravity monitoring, we made conceptual hydrological models which laid the foundation of 1-D flow physical models. Indeed, gravimetry is an integrative hydro-geophysical method which allows 1) to consider the epikarst, locally heterogeneous as an equivalent tabular medium and 2) to define the types of transfer (fast & slow) occurring at the site. Especially, the lack of fast transfer through the GEK epikarst was precisely quantified for the first time at the field scale (~100m). Gravity-driven water mass balance with local meteorological data (evapotranspiration from a flux tower and precipitation) allowed setting the bottom outlet of the model to 1 mm.day-1. This flow has proved to be representative of the low-flow discharge at the only spring which represents all groundwater outflows from the catchment. This result supposes the homogeneity of the dolomitic epikarst almost at the basin scale. Model parameters were next calibrated using one year of ambient seismic noise monitored at two stations. Phase velocity changes obtained by cross-correlating the noise between 6 and 8 Hz were used as a ”timer” to follow the water infiltration between a depth of 30 and 60 meters. Thus, monitoring seismic velocity changes using ambient seismic noise demonstrates great potential for the study of deep and complex critical zones and could fill the instrumental gap currently existing in hydrology.Time-lapse gravity measurements with a spring-based portable gravimeter have also demonstrated the different behavior of two epikarsts and their variability at the scale of a few hundred meters. Monthly measurements around the observatory revealed the spatial homogeneity of this dolomitic epikarst: all the stations showed the same water storage changes. On the contrary, seasonal surface to depth gravity measurements along the underground passage of the Saint-Ferréol sinkhole, in limestone, have shown fast transfer and strong spatial variability of water storage. Lithology is then expected to play a part in the epikarst capacity to retain water. The precision needed to measure the weak hydrological induced signals during those surveys required robust methodology and an ambient temperature effect on measurements with spring-based gravimeter was observed in the field and quantified in the laboratory.
Les aquifères karstiques représentent des ressources en eau essentielles dans de nombreuses régions du monde comme le bassin Méditerranéen. Cependant, de par les processus complexes de karstification, ces aquifères sont hétérogènes à de nombreuses échelles et vulnérables. Dans cette thèse, nous étudions le potentiel de la gravimétrie et du bruit sismique ambiant pour la modélisation hydrologique en milieu karstique.Le site dolomitique de l’observatoire « GEK », sur le bassin du Durzon dans le Larzac, est le site d’étude privilégié de ces travaux. Dans l’observatoire, un gravimètre supraconducteur dédié à l’hydrologie mesure depuis 2011 les variations de gravité en continu et à une très haute précision, pour la première fois sur un karst. Des modèles hydrologiques conceptuels ont été réalisés à partir de cette surveillance gravimétrique et ont permis de poser les bases de modèles physiques d’écoulements 1-D. En effet la gravimétrie, intégratrice, permet 1) de considérer l’épikarst localement hétérogène comme un milieu tabulaire équivalent et 2) de définir les types de transfert à l’œuvre sur le site. En particulier, l’absence de transfert rapide dans l’épikarst a été quantifiée avec précision pour la première fois à l’échelle du terrain (~100m). A l’aide de données météorologiques locales, un bilan de masse précis a permis de définir le flux en limite inférieure du modèle à 1 mm.jour-1. Ce flux s’est montré représentatif du débit de basses-eaux de la source drainant l’ensemble du bassin. Ce résultat suppose une homogénéité de l’épikarst dolomitique quasiment à l’échelle du bassin. Les paramètres des modèles physiques ont ensuite pu être calibrés à l’aide d’un an d’intercorrélation du bruit sismique ambiant entre deux stations. Les variations de vitesses de phase obtenues entre 6 et 8Hz nous ont servi de « chronomètre » pour suivre l’infiltration entre 30 et 60m de profondeur. La surveillance passive des variations de vitesses sismiques par intercorrélation du bruit sismique ambiant montre ainsi un fort potentiel pour l’étude des zones critiques profondes et complexes à l’échelle du terrain et peut combler la lacune instrumentale qui existe actuellement en hydrologie.Des campagnes répétées de mesures avec un gravimètre portable à ressort ont également mis en évidence le fonctionnement différent de deux épikarsts et leur variabilité à l’échelle de la centaine de mètres. Des mesures mensuelles autour de l’observatoire ont mis en évidence l’homogénéité spatiale de cet épikarst dolomitique : toutes les stations ont les mêmes variations temporelles de stock d’eau. Au contraire, des mesures saisonnières en surface et en profondeur le long de la galerie souterraine calcaire de l’abîme de Saint-Ferréol ont montré une variabilité spatiale forte du stockage ainsi que du transfert rapide. La lithologie de l’épikarst est donc suspectée de jouer un rôle dans sa capacité de stockage. Lors de ces campagnes, la faiblesse du signal recherché a nécessité une méthodologie précautionneuse et un effet de température sur les mesures des gravimètres relatifs à ressort a été observé sur le terrain et quantifié en laboratoire.
https://tel.archives-ouvertes.fr/tel-01649606

NNT : 2016MONTT128
tel-01649606
https://tel.archives-ouvertes.fr/tel-01649606
https://tel.archives-ouvertes.fr/tel-01649606/document
https://tel.archives-ouvertes.fr/tel-01649606/file/2016_FORES_archivage.pdf