Résumé : The slides were taken on collecting trips sponsored by the William L. Bryant Foundation, where books, music and art indigenous to the regions were gathered. The are organized by geographical location.
This image shows a beach with black volcanic sand surrounded by trees near Point Saline, Grenada. Grenada is a volcanic island with two volcanoes: Mount Saint Catherine which is 2,757 feet (840 meters) above sea level and Mount Kick 'em Jenny which is a submarine volcano located 5 miles north of Grenada. Mount Kick 'em Jenny’s summit is about 590.5 feet (180 meters) below the surface of the sea. Slide labeled Black Beach Pt. Saline Grenada.
Grenada -- Caribbean region -- Saint George

Droits : All rights to images are held by the respective holding institution. This image is posted publicly for non-profit educational uses, excluding printed publication. For permission to reproduce images and/or for copyright information contact Special Collections & University Archives, University of Central Florida Libraries, Orlando, FL 32816 phone (407) 823-2576, email: speccoll@mail.ucf.edu
CFM1972_01a
Sheet 44:5
http://ufdc.ufl.edu/AA00029623/00001

Éditeur(s) : HAL CCSD Wiley
Résumé : SUBSURF
International audience
Similarity of form between subaerial and submarine landscapes affected by erosion could suggest similarities in the process of erosion, such as by runoff and sedimentary flows, respectively. On the other hand, if aspects of form vary, its characteristics may be used to identify the environmental origin of erosion. Towards these goals, this contribution addresses the morphology of submarine volcanoes (seamounts) with widely differing histories of erosion. One set from the Pacific Ocean never exposed above sea level includes Cretaceous-age seamounts near Hawai'i (including Apu'upu'u Seamount), two seamounts of < 3 Ma in age near a mid-ocean ridge and the 11-4 Ma Jasper Seamount. These seamounts are all isolated from continents and hence from any erosion associated with mass wasting of unstable terrigenous deposits. In such isolated submarine environments, surfaces erode slowly from in situ weathering, mass wasting and scouring by sedimentary flows initiated by slope failure in pelagic or bedrock materials. The Pacific seamounts are compared with Valencia Seamount in the western Mediterranean, exposed subaerially for 100-400 k.y. during the Messinian Salinity Crisis before 5 Ma. Multibeam and deeply towed sidescan sonar data of Valencia Seamount reveal features typical of subaerial erosion of volcanic islands, such as canyons and relatively uneroded sectors (planezes) between them. Using a simple topographical reconstruction, the apparent erosion depth typically reaches 100 m within canyons and up to 180 m in places. Whereas the younger Pacific seamounts do not show these erosional features, the much older Cretaceous seamounts do have channels, which in one example suggests up to 200 m of incision. Both Valencia and Apu'upu'u seamounts have channel longitudinal profiles that are steep and typically linear to concave upwards. The erosion depth of Apu'upu'u Seamount is significant, despite the seamount's persistent submarine environment, because of its greater age, steeper flanks and greater contributing areas to channels compared with Valencia Seamount. These results illustrate that the channel morphology resulting from submarine erosion can become similar to that produced by subaerial erosion given sufficient time.
ISSN: 0950-091X

hal-00411425
https://hal.archives-ouvertes.fr/hal-00411425
DOI : 10.1111/j.1365-2117.2008.00355.x

Éditeur(s) : HAL CCSD
Résumé : The Neogene geodynamics evolution of the south-Alboran realm in western Mediterranean has been clarified, based on sedimentological and chronostratigraphical studies. This work focuses on three main themes of research, the first is to establish the moments for the opening and closing of the North Rifian Corridor by studying two Neogene basins of the southern edge of the Alboran sea. The second, aims to understand the behavior of these two basins face a major event in the history of the Mediterranean: The Messinian Salinity Crisis. Finally, the third theme aims to understand the modalities Post-MSC reflooding in the southern part of the Alboran realm.The late Miocene evolution of the North Rifian Corridor is clarified on the basis of chronostratigraphic studies of the Neogene Boudinar and Arbaa Taourirt basins (northeastern Morocco). The marine sediments deposited in the Boudinar basin between the early Tortonian and the late early Messinian (10 Ma to 6.1 Ma) and in the late Tortonian-earliest Messinian interval in the Arbaa Taourirt basin. Palaeoenvironmental data record a major drowning in association with extensive tectonics in the Boudinar basin during the early Messinian at ~7.2 Ma. At the same time, prograding conglomerates and sandstones developed over the late Tortonian marls in the Arbaa Taourirt basin. During the late-early Messinian, a shallowing trend occurred in the Boudinar basin. Thus, the North Rifian Corridor opened at ~7.2 Ma ensuring Atlantic-Mediterranean connections, then was progressively restricted during the late-early Messinian and totally closed at ~6.1 Ma. New sedimentological and paleontological studies of the late Messinian-early Pliocene deposits in the Boudinar basin provide new information on the Messinian Salinity Crisis (« MSC ») and the Zanclean reflooding in the Alboran sea. The Messinian erosional surface « MES » is of late Messinian age and was emplaced in subaerial settings. It is polygenic, its original geometry is locally preserved and was re-shaped by the Pliocene transgressive surface. Above the « MES », the Boudinar basin infill is characterized by a wide variety of facies from continental settings to lower offshore conditions. Two major sets are recognized: a latest Messinian-Zanclean set that constitutes a transgressive-regressive megasequence interrupted at the top by a tectonic unconformity, and an Plio-Quaternary regressive set. During the late Messinian Zanclean interval, four successive depositional models were documented. They record major changes in palaeoflow and paleogeography related to base-level fluctuations. No Gilbert-type delta has ben identified at Boudinar. the beginning of base-level rise is marked by normal regressions and by the formation of several lacs and fan-delta complexes on the margins of the basin in the late Messinian and befor the marine reefloding in the early Zanclean. The marine reflooding of the basin appears later, with a transgressive surface of ravinment and a thick package of transgressive deposits. These transgressive deposits onlap over all previous deposits. The major part of the basin infill did not issue from an inner landward position (south of the basin) but from the northwestern side of the basin, i.e. near the Mediterranean. Sediments were subsequently reworked by storms and transported by longshore-drift towards the south. a maximum flooding surface is found several tens of metres above the « MES ». This fiding is consistent with a progressive and not a catastrophic early Zanclean flooding of the westernMediterranean after the Mediterranean base-level fall.
Sur la base d’études sédimentologiques et chronostratigraphiques dans les bassins de Boudinar et d’Arbaa Taourirt (Rif oriental, Maroc), l’évolution géodynamique néogène du domaine sud-Alboran en Méditerranée occidentale a été clarifiée. Ce travail est axé sur trois grandes thématiques de recherche. La première vise à l’établissement d’un cadre chronostratigraphique pour l’ouverture et la fermeture du Couloir Nord Rifain, par l’étude de deux bassins nèogènes de la bordure sud de la mer d’Alboran. La deuxième, vise à comprendre le comportement de ces deux bassins face à un événement majeur de l’histoire de la Mediterranée : la Crise de salinité messinienne. Finalement, la troisième vise à comprendre les modalités de remise en eau de la Méditerranée après la Crise : le reenoiement pliocène. L'évolution du Couloir Nord Rifain au Miocène supérieur est clarifiée sur la base des études chronostratigraphiques des bassins néogènes de Boudinar et d'Arbaa Taourirt (Maroc Nord oriental). Les sédiments marins miocènes se sont déposés entre le Tortonien inférieur et le Messinien inférieur (10 à 6.1 Ma) dans le bassin de Boudinar et entre le Tortonien supérieur et le Messinien inférieur dans le bassin d'Arbaa Taourirt. Les données paléoenvironnementales enregistrent un ennoyage important du bassin de Boudinar en relation avec une tectonique extensive pendant le Messinien inférieur (~7.2 Ma). En même temps, des conglomérats et de grès progradants se sont développés au-dessus des marnes tortoniennes dans le bassin d’Arbaa Taourirt. Le bassin de Boudinar a subi un désapprofondissement au Messinien inférieur. Ces résultats indiquent que le Couloir Nord Rifain s’est ouvert à ~7.2 Ma assurant les communications entre l’Atlantique et la Méditerranée, puis a subi une restriction progressive pendant le Messinien inférieur avant d’être totalement fermé à ~6.1 Ma.De nouvelles études sédimentologiques et paléontologiques des dépôts Messinien supérieur-Pliocène inférieur dans le bassin de Boudinar fournissent des informations sur la Crise de salinité messinienne (« MSC ») et le réennoiement zancléen dans la Mer d'Alboran. L’un des marqueurs majeurs de la Crise est identifié : la surface d’érosion messinienne « MES ». Elle est d'âge Messinien supérieur et a été mise en place dans des conditions subaériennes. Sa géométrie originale n’est préservée que localement et a été remodelée par la surface transgressive du Pliocène inférieur. Au dessus de la « MES » le remplissage sédimentaire du bassin de Boudinar est caractérisé par une grande variété de faciès allant des conditions de dépôts continentales jusqu’à des conditions d’offshore inférieur. Deux ensembles majeurs sont reconnus : un ensemble messinien terminal-zancléen qui constitue une mégaséquence transgressive-regressive, interrompue au sommet par une discordance tectonique, et un ensemble plio-quaternaire regressif. Durant l’intervalle Messinien terminal-Zancléen, quatre modèles de dépôts successifs ont été documentés enregistrant des changements majeurs de paléocourants et de paléogéographies, liés aux fluctuations de niveau de base. Nous n’avons pas identifié de Gilbert delta à Boudinar. La remontée du niveau de base est marquée par une régression normale et par le développement des lacs et de complexes de fan-deltas sur les marges du bassin pendant le Messinien supérieur, avant l’inondation marine au Zancléen basal. Le réennoiement marin du bassin apparait plus tard avec une surface de transgression ravinante et par d’épais dépôts transgressifs, en onlap sur tous les dépôts précédents. La majeure partie du remplissage sédimentaire du bassin n’est pas reçue des reliefs de la bordure sud du bassin, mais du côté Nord-Ouset au bord de la Méditerranée. Les sédiments sont alors remaniés par les tempêtes et transportés vers le sud par la dérive littorale. Une surface d’inondation maximale a été identifiée à plusieurs dizaines de mètres au-dessus de la « MES ». Ceci suggère un ennoiement progressif et non catastrophique, après la chute du niveau de base méditerranéen.
https://tel.archives-ouvertes.fr/tel-01473572

Droits : http://hal.archives-ouvertes.fr/licences/copyright/
tel-01473572
https://tel.archives-ouvertes.fr/tel-01473572
https://tel.archives-ouvertes.fr/tel-01473572/document
https://tel.archives-ouvertes.fr/tel-01473572/file/Th%C3%A8se-achalhi.pdf

Résumé : Les forêts côtières inondables (FCI) des régions tropicales et subtropicales remplissent des fonctions écologiques nécessaires aux écosystèmes marins côtiers situés en aval et aux populations humaines vivant à proximité Aux Antilles, les mangroves et les forêts marécageuses à Pterocarpus officinalis sont structurés par des espèces ligneuses qui ont développé des adaptations particulières à la salinité, à l’inondation et aux substrats meubles sur lesquels elles reposent. Dans des contextes climatiques à forte saisonnalité, les saisons sèches prolongées entraînent de fortes variations de la salinité et du niveau de la nappe, que le changement climatique devrait amplifier. Les modèles climatiques de la région Caraïbe prévoient des saisons sèches plus sèches liées à une baisse des précipitations de 20 à 50 %. Or, la question des capacités de résistance et d’acclimatation des espèces ligneuses des FCI à des variations saisonnières marquées de leur environnement édaphique a été peu traitée dans la littérature scientifique.L’objectif de ce travail de thèse a été double. Il s’est agi, d'une part, de caractériser la structure et la croissance de faciès de végétation représentatifs des FCI antillaises et de mettre en évidence leurs déterminants. A cet effet, des individus adultes, des espèces ligneuses dominantes des FCI, (Avicennia germinans, Laguncularia racemosa, Pterocarpus officinalis, Rhizophora mangle), dans cinq faciès de végétation sur le gradient terre-mer, ont été suivis sur l'île de Grande-Terre (Guadeloupe). D’autre part, les effets de variations salines extrêmes sur la croissance et l’écophysiologie de ces quatre espèces ont été évalués au stade plantule par une expérience en conditions contrôlées.A travers cette étude, il a été montré que les différences de salinité et de fertilité entre les stationspermettent d’expliquer la composition et la structure des peuplements de FCI. Cette étude a égalementmontré que P. officinalis peut se maintenir dans une gamme de salinité plus large que ne l'indiquait lalittérature.Dans le contexte des Antilles où les marnages sont faibles, la saisonnalité du climat entraine des variations saisonnières importantes d’un ensemble de descripteurs édaphiques tels que le niveau de la nappe, la salinité du sol, le pH et le potentiel RedOx. L’inondation et la salinité des sols sont fortement corrélées aux variations mensuelles des précipitations. Les périodes sèches sont accompagnées de salinités élevées et d’une baisse du niveau de la nappe allant jusqu’à l’exondation des sols dans toutes les stations suivies. Les stress environnementaux liés à la saisonnalité entrainent une baisse de la production primaire. L’accroissement cambial mensuel des individus est fortement corrélé avec les précipitations et l’intensité du vent. Dans les stations de mangrove, la sècheresse édaphique régule la production primaire des palétuviers. En forêt marécageuse, la part de la sècheresse atmosphérique semble plus importante pour expliquer la production de P. officinalis. Aussi, les sècheresses édaphique et atmosphérique doivent être prises en compte toutes deux pour modéliser efficacement la croissance des peuplements des FCI.Lors de la saison sèche, le stress le plus important est le stress hydrique, lié à la diminution de la teneur en eau du sol et à l’augmentation de la salinité, qui entraine des contraintes physiologiques sur les palétuviers (ajustements stomatiques, pertes de surface foliaire et de conductivité hydraulique). Le stress ionique, lié à la toxicité des ions Na+ et Cl-, permet aussi d’expliquer une partie de la contrainte sur l’assimilation en carbone. En saison sèche, l’aération des sols ne se traduit pas par une amélioration des performances de croissance chez toutes les espèces. Aussi, la croissance cambiale maximale de toutes les espèces de FCI est réalisée en saison des pluies lorsque la salinité est faible et les niveaux d’inondation élevés.
In tropical and subtropical regions, flooded coastal forests provide essentials goods and services to local communities. In the Antilles, mangrove forests and the Pterocarpus officinalis swamp forest host tree species that are adapted to salinity, flooding and loose substrates. In areas were climatic seasonality is strong, dry seasons lead to strong fluctuations of soil salinity and water table level ; that climate change is likely to make stronger again. Climate model for the Caribbean project drier dry seasons with a decease of 20 to 50 % in annual rainfall amounts. However, resistance and acclimation ability of flooded coastal forest’s species to strong environmental fluctuations still remain poorly studied.This thesis aims two objectives. On the one hand, it aims to characterize the forest structure and monthly growth of vegetation structures representative of the Antillean flooded coastal forests and to highlight their determinants. In this respect, adult trees of the four dominant species of local flooded coastal forest (Avicennia germinans, Laguncularia racemosa, Pterocarpus officinalis, Rhizophora mangle), in five stations along a sea – land gradient were monitored on the Grande-Terre island (Guadeloupe). On the other hand, the effects of salinity variation patterns and salinity levels on growth performances and physiology of seedlings from the four same species were investigated through a greenhouse experiment.This study shows that differences among average salinity and soil fertility explain the vegetation structure of flooded coastal forest. It also extents, in the literature, the range of salinity in which P. officinalis can stand at the tree stage.In the Antilles were tidal range is small, climate seasonality lead to strong edaphic seasonal variations in water table level, soil salinity, pH and RedOx potential. Flooding and soil salinity are strongly correlated to monthly rainfall amounts: dry periods lead to high salinity and to a decrease in water table level under the soil surface. Seasonal environmental stresses lead to a decrease of primary production. Cambial growth was strongly correlated to monthly precipitation and average wind speed. In mangrove stations, edaphic drought determines primary production of mangrove trees, when, in swamp forest stations, atmospheric drought determines an important part of P. officinalis’ primary production.During the dry season, water stress is the more important environmental stress, both by the decrease in soil humidity and the increase in soil salinity, and leads to physiological strains (stomatal adjustment, loss of leaf area and hydraulic conductivity) for mangrove trees. Ionic toxicity of ions Na+ and Cl- also explains a part of the strain on carbon assimilation. During the dry season, re oxygenation of soils via low water table level does not lead to an increase of physiological traits. Thus, maximum cambial growth of all species is observed during the rainy season, when salinity is low and water table level is high.Flooded coastal forest’s species do not have the same ability to recover after a dry episode. In all the studied stations, A. germinans’ cambial growth rises back as soon as the rainy season starts, when, for one station, cambial growth of L. racemosa and R. mangle stay null during the three first month of the rainy season. This low ability to recover after a dry episode is correlated to a stronger impact of the dry season on the physiological traits of these two species.The greenhouse experiment shows that salinity variation patterns are to be taken into consideration for explaining seedlings’ growth and salinity tolerance. A stronger salinity increase impacts the growth of all the studied species; a punctual drop of salinity highlights that flooded coastal forest’s species differ in ability to take advantage of a low salinity episode. These results are coherent with field observations as cambial growth was fairly explained by monthly precipitation.

http://www.theses.fr/2013AGUY0674/document

Éditeur(s) : IEEE
Résumé : It is now well understood that data on soil moisture and sea surface salinity (SSS) are required to improve meteorological and climate predictions. These two quantities are not yet available globally or with adequate temporal or spatial sampling. It is recognized that a spaceborne L-band radiometer with a suitable antenna is the most promising way of fulfilling this gap. With these scientific objectives and technical solution at the heart of a proposed mission concept the European Space Agency (ESA) selected the Soil Moisture and Ocean Salinity (SMOS) mission as its second Earth Explorer Opportunity Mission. The development of the SMOS mission was led by ESA in collaboration with the Centre National d'Etudes Spatiales (CNES) in France and the Centro para el Desarrollo Tecnologico Industrial (CDTI) in Spain. SMOS carries a single payload, an L-Band 2-D interferometric radiometer operating in the 1400-1427-MHz protected band [1]. The instrument receives the radiation emitted from Earth's surface, which can then be related to the moisture content in the first few centimeters of soil over land, and to salinity in the surface waters of the oceans. SMOS will achieve an unprecedented maximum spatial resolution of 50 km at L-band over land (43 km on average over the field of view), providing multiangular dual polarized (or fully polarized) brightness temperatures over the globe. SMOS has a revisit time of less than 3 days so as to retrieve soil moisture and ocean salinity data, meeting the mission's science objectives. The caveat in relation to its sampling requirements is that SMOS will have a somewhat reduced sensitivity when compared to conventional radiometers. The SMOS satellite was launched successfully on November 2, 2009.
Proceedings of the IEEE (0018-9219) (IEEE), 2010-05 , Vol. 98 , N. 5 , P. 666-687

Droits : 2010 IEEE – All Rights Reserved
http://archimer.ifremer.fr/doc/00004/11483/8065.pdf
DOI:10.1109/JPROC.2010.2043032
http://archimer.ifremer.fr/doc/00004/11483/

Éditeur(s) : Amer Geophysical Union
Résumé : Large rivers are key hydrologic components in oceanography, particularly regarding air-sea and land-sea exchanges and biogeochemistry. We enter now in a new era of Sea Surface Salinity (SSS) observing system from Space with the recent launches of the ESA Soil Moisture and Ocean Salinity (SMOS) and the NASA Aquarius/Sac-D missions. With these new sensors, we are now in an excellent position to revisit SSS and ocean color investigations in the tropical northwest Atlantic using multi-year remote sensing time series and concurrent in situ observations. The Amazon is the world's largest river in terms of discharge. In its plume, SSS and upper water column optical properties such as the absorption coefficient of colored detrital matter (acdm) are strongly negatively correlated (<-0.7). Local quasi-linear relationships between SSS and acdm are derived for these plume waters over the period of 2010-2013 using new spaceborne SSS and ocean color measurements. Results allow unprecedented spatial and temporal resolution of this coupling. These relationships are then used to estimate SSS in the Amazon plume based on ocean color satellite data. This new product is validated against SMOS and in situ data and compared with previously developed SSS retrieval models. We demonstrate the potential to estimate tropical Atlantic SSS for the extended period from 1998 to 2010, prior to spaceborne SSS data collection.
Journal Of Geophysical Research-oceans (0148-0227) (Amer Geophysical Union), 2015-05 , Vol. 120 , N. 5 , P. 3177-3192

Droits : 2015. American Geophysical Union. All Rights Reserved.
http://archimer.ifremer.fr/doc/00255/36610/35742.pdf
DOI:10.1002/2014JC010109
http://archimer.ifremer.fr/doc/00255/36610/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
During the last decade, the interaction of deep processes in the lithosphere and mantle with surface processes (erosion, climate, sea-level, subsidence, glacio-isostatic readjustment) has been the subject of heated discussion. The use of a multidisciplinary approach linking geology, geophysics, geodesy, modelling, and geotechnology has led to the awareness of coupled deep and surface processes. Deep earth dynamics (topography, erosion, tectonics) are strongly connected to natural hazards such as earthquakes, landslides, and tsunamis; sedimentary mass transfers have important consequences on isostatic movements and on georesources, geothermal energy repartitions. The ability to read and understand the link between deep Earth dynamics and surface processes has therefore important societal impacts. Ground-truthing at carefully-selected sites of investigation is imperative to better understand these connections.Due to its youth (<30 Ma) and its subsidence history, the almost land-locked Gulf of Lion–Sardinia continental margins system provides a unique record of sedimentary deposition from the Miocene to present. Due to its high subsidence rate, palaeoclimatic variations, tectonic events and vertical evolution are all recorded here at very high resolution. The late Miocene isolation and desiccation of the Mediterranean, the youngest and most catastrophic event, the Messinian Salinity Crisis (MSC), induced drastic changes in marine environments: widespread deposition of evaporite (gypsum, anhydrite and halite) in the central basin, and intense subaerial erosion along its periphery. These extraordinary mass transfers from land to sea induced strong isostatic re-adjustments that are archived in the sedimentary record and represent a window to the lithospheric rheology and the deep processes.The GOLD (Gulf of Lion Drilling) project, proposes to explore this unique sedimentary record as well as the nature of the deep crustal structure, providing valuable information about the mechanisms underlying vertical motions in basins and their margins.
ISSN: 0264-8172

insu-01197393
https://hal-insu.archives-ouvertes.fr/insu-01197393
https://hal-insu.archives-ouvertes.fr/insu-01197393/document
https://hal-insu.archives-ouvertes.fr/insu-01197393/file/Rabineau%20et%20al.-final-MPG2014_REVISED-FINAL-No-Marked_FINAL%2BFigures.pdf
DOI : 10.1016/j.marpetgeo.2015.03.018

Éditeur(s) : IEEE
Résumé : This paper aims at studying the quality of the sea surface salinity (SSS) retrieved from soil moisture and ocean salinity (SMOS) data in coastal areas. These areas are characterized by strong and variable SSS gradients [several practical salinity units (psu) on relatively small scales: the extent of river plumes is highly variable, typically at kilometric and daily scales. Monitoring this variability from SMOS measurements is particularly challenging because of their resolution (typically 30-100 km) and because of the contamination by the nearby land. A set of academic tests was conducted with a linear coastline and constant geophysical parameters, and more realistic tests were conducted over the Bay of Biscay. The bias of the retrieved SSS has been analyzed, as well as the root mean square (rms) of the bias, and the retrieved SSS compared to a numerical hydrodynamic model in the semirealistic case. The academic study showed that the Blackman apodization window provides the best compromise in terms of magnitude and fluctuations of the bias of the retrieved SSS. Whatever the type of vegetation cover, a strong negative bias, greater than 1 psu, was found when nearer than 36 km from the coast. Between 44 and 80 km, the type of vegetation cover has an impact of less than a factor 2 on the bias, and no influence further than 80 km from the coast. The semirealistic study conducted in the Bay of Biscay showed a bias over ten days lower than 0.2 psu for distances greater than 47 km, due to an averaging over various geometries (coastline orientation, swath orientation, etc.). The bias showed a weak dependence on the location of the grid point within the swath. Despite the noise on the retrieved SSS, contrasts due to the plume of the Loire River and the Gironde estuary remained detectable on ten-day averaged maps with an rms of 0.57 psu. Finally, imposing thresholds on the major axis of the measurements brought little improvement to the bias, whereas it increased the rms and- could lead to strong swath restriction: a 49-km threshold on the major axis resulted in an effective swath of 800-900 km instead of 1200 km. NOT CONTROLLED OCR
Transactions on geoscience an remote sensing IEEE (0196-2892) (IEEE), 2007-07 , Vol. 45 , N. 7 , P. 2061-2072

Droits : 2007 IEEE
http://archimer.ifremer.fr/doc/2007/publication-3643.pdf
DOI:10.1109/TGRS.2007.894934
http://archimer.ifremer.fr/doc/00000/3643/

Éditeur(s) : American Geophysical Union
Résumé : Lagrangian analyses of a global ocean circulation model quantify the salinity changes experienced by the warm limb of the thermohaline circulation during the northward flow to the Atlantic deep convection regions. 6 Sv out of the estimated 10-Sv transfer from 45 degrees S to 47 degrees N flow through regions of prevailing surface evaporation: the southern and northern formation regions of Salinity Maximum Water and the Gulf of Cadiz/Mediterranean Sea domain. The remaining transport gains salinity through mixing with adjacent waters. As much as 6 Sv flow through the low-salinity surface mixed layer at the latitudes of the ITCZ whose effect annihilates that of the southern region of Salinity Maximum Water. Most of the salinity increase corresponds to the transformation of South to North Atlantic Central Water, with strong diapycnal transfers for the water that intersects the high and low salinity regions, and nearly isopycnal modifications for the water that avoids these regions.
Geophysical Research Letters ( GRL ) (0094-8276) (American Geophysical Union), 2006-03 , Vol. 33 , N. 6 , P. NIL_44-NIL_47

Droits : 2006 by the American Geophysical Union
http://archimer.ifremer.fr/doc/2006/publication-1213.pdf
DOI:10.1029/2005GL024938
http://archimer.ifremer.fr/doc/00000/1213/

Éditeur(s) : Amer Geophysical Union
Résumé : The temporal evolution and spatial distribution of surface salinity and colored detrital matter (cdm) were evaluated within and adjacent to the Amazon River Plume. Study objectives were as follows: first, to document the spatial coherence between Amazon discharge, salinity, cdm, and the nature of the salinity-cdm relationship; second, to document the temporal and spatial variability of cdm along the trajectory of the low-salinity Amazon Plume, and third, to explore the departure of cdm from conservative mixing behavior along the plume trajectory into the open ocean. Time series (2003-2007) of surface salinity estimated using the Advanced Microwave Scanning Radiometer-Earth Observing System and corresponding satellite cdm absorption (acdm) data documented a plume of freshened, colored water emanating from the Amazon. Salinity and acdm were generally coherent, but there were regions in which spatial patterns of salinity and acdm did not coincide. Salinity was oppositely phased with discharge, whereas acdm was in phase but lagged discharge and typically remained high after maximum discharge. Along the river plume trajectory, acdm was inversely correlated with salinity, yet there was considerable deviation from conservative mixing behavior during all seasons. Positive anomalies in a linear relationship between salinity and acdm corresponded to areas of enhanced satellite-retrieved net primary productivity, suggesting the importance of phytoplankton biomass or its subsequent remineralization as a source of cdm. Negative anomalies tended to predominate at the distal sections of the plume trajectories, an observation consistent with the process of photo-oxidation of cdm over observed time scales of days to weeks.
Journal Of Geophysical Research-oceans (0148-0227) (Amer Geophysical Union), 2011-07 , Vol. 116 , N. C00H02 , P. 14 p.

Droits : 2011 American Geophysical Union. All Rights Reserved.
http://archimer.ifremer.fr/doc/00041/15218/12593.pdf
DOI:10.1029/2011JC006989
http://archimer.ifremer.fr/doc/00041/15218/

Éditeur(s) : Amer Meteorological Soc
Résumé : Salinity measurements from 119 surface drifters in 2007-12 were assessed; 80% [Surface Velocity Program with a barometer with a salinity sensor (SVP-BS)] and 75% [SVP with salinity (SVP-S)] of the salinity data were found to be usable, after editing out some spikes. Sudden salinity jumps are found in drifter salinity records that are not always associated with temperature jumps, in particular in the wet tropics. A method is proposed to decide whether and how to correct those jumps, and the uncertainty in the correction applied. Northeast of South America, in a region influenced by the Amazon plume and fresh coastal water, drifter salinity is very variable, but a comparison with data from the Soil Moisture and Ocean Salinity satellite suggests that this variability is usually reasonable. The drifter salinity accuracy is then explored based on comparisons with data from Argo floats and from thermosalinographs (TSGs) of ships of opportunity. SVP-S/SVP-BS drifter records do not usually present significant biases within the first 6 months, but afterward biases sometimes need to be corrected (altogether, 16% of the SVP-BS records). Biases start earlier after 3 months for drifters not protected by antifouling paint. For the few drifters for which large corrections were applied to portions of the record, the accuracy cannot be proven to be better than 0.1 psu, and it cannot be proven to be better than 0.5 psu for data in the largest variability area off northeast South America. Elsewhere, after excluding portions of the records with suspicious salinity jumps or when large corrections were applied, the comparisons rule out average biases in individual drifter salinity record larger than 0.02 psu (midlatitudes) and 0.05 psu (tropics).
Journal Of Atmospheric And Oceanic Technology (0739-0572) (Amer Meteorological Soc), 2014-04 , Vol. 31 , N. 4 , P. 967-983

Droits : 2014 American Meteorological Society
http://archimer.ifremer.fr/doc/00190/30095/28748.pdf
DOI:10.1175/JTECH-D-13-00158.1
http://archimer.ifremer.fr/doc/00190/30095/

Résumé : Preliminary analysis of the impact of an environmental change on ichtyologic fauna marinates and fishing in Guyanese water enter within the framework of the program CHALOUPE (dynamic Change of the exploited marine biodiversity and the viability of the Fisheries) coordinated by Ifremer Cayenne and financed by the ANR (National Agency of Research). The study focuses on: -analysis temporal variations of various environmental parameters (sea surface temperature and salinity, the phenomenon El Niño) -fish physical characteristics (tolerances of temperature and salinity, maximum height, distribution…) - analysis of the unloadings per unit of effort of the inshore fishing and an economic analysis of the selling price of fish Data are found on data bases and are given by scientists. The statistical studies and the cartographic representations show that there is an increase in temperature of water in Guiana since the end of the Nineties. The model AquaMaps® simulates the potential consequences of this reheating on the fish distribution. Certain stocks of fishing are weakened. For the moment, if the composition of the captures of inshore fishing changes, that seems more due to a change of fishing strategy than due to an impact of the climatic change. In addition, the average value of the capture increased for reason commercial.
Les analyses de l’impact d’un changement environnemental sur la faune ichtyologique marine et la pêche dans les eaux guyanaises entrent dans le cadre du programme CHALOUPE (CHAngement gLObal, dynamiqUe de la biodiversité marine exploitée et de la viabilité des Pêcheries) coordonné par l’Ifremer Cayenne et financé par l’ANR (Agence Nationale de la Recherche). L’étude porte sur : -l’analyse des variations temporelles de différents paramètres environnementaux (température et salinité de surface des eaux, le phénomène El Niño) à l’échelle de quelques décennies -les caractéristiques physiques des poissons (tolérances de températures et de salinité (taille maximum, répartition…) ; -l’analyse des débarquements par unité d’effort de la pêche côtière depuis les années 70 ; -une analyse économique de la pêche ; Les données sont récoltées à partir de bases de données et au près de différents chercheurs. Les études statistiques et les représentations cartographiques démontrent qu’il y a bien une augmentation de température des eaux en Guyane depuis la fin des années 90. Le modèle statistique sous AquaMaps® permet de simuler les conséquences potentielles de ce réchauffement sur la répartition des poissons. Dans un tel contexte, certains stocks de pêche sont fragilisés. Pour le moment, si la composition des captures de la pêche côtière se modifie dans le même temps, cela semble plus du fait de changement de stratégie de pêche que du fait de l’impact du changement climatique. Par ailleurs, la valeur moyenne de la capture a augmenté pour des raisons commerciales.

Droits : 2006 Ifremer
http://archimer.ifremer.fr/doc/00077/18855/16429.pdf
http://archimer.ifremer.fr/doc/00077/18855/

Éditeur(s) : HAL CCSD Société Géologique de France
Résumé : International audience
The seaward extension of onshore formations and structures were previously almost unknown in Provence. The interpretation of 2D high-resolution marine seismic profiles together with the integration of sea-bottom rock samples provides new insights into the stratigraphic, structural and paleogeographic framework of pre-Messinian Salinity Crisis (MSC) deposits of the Provence continental shelf. Seven post-Jurassic seismic units have been identified on seismic profiles, mapped throughout the offshore Provence area and correlated with the onshore series. The studied marine surface and sub-surface database provided new insights into the mid and late Cretaceous paleogeography and structural framework as well as into the syn-and post-rift deformation in Provence. Thick (up to 2000 m) Aptian-Albian series whose deposition is controlled by E-W-trending faults are evidenced offshore. The occurrence and location of the Upper Cretaceous South-Provence basin is confirmed by the thick (up to 1500 m) basinal series downlaping the Aptian-Albian unit. This basin was fed in terrigenous sediments by a southern massif (" Massif Méridional ") whose present-day relict is the Paleozoic basement and its sedimentary cover from the Sicié imbricate. In the bay of Marseille, thick syn-rift (Rupelian to Aquitanian) deposition occurred (>1000 m). During the rifting phase, syn-sedimentary deformations consist of dominant N040 to N060 sub-vertical faults with a normal component and N050 drag-synclines and anticlines. The syn-rift and early post-rift units (Rupelian to early Burdigalian) are deformed and form a set of E-W-trending en echelon folds that may result from sinistral strike-slip reactivation of N040 to N060 normal faults during a N-S com-pressive phase of early-to-mid Burdigalian age (18-20 Ma). Finally, minor fault reactivation and local folding affect post-rift deposits within a N160-trending corridor localized south of La Couronne, and could result from a later, post-Burdigalian and pre-Pliocene compressive phase.
Cadre tectonostratigraphique des formations anté-pliocènes du plateau continental de Provence (golfe du Lion oriental, SE France) Mots-clés. – Géologie marine, Tectonostratigraphie, Stratigraphie sismique, Paléogéographie crétacée, Rifting oligo-miocène, Compression post-rift Résumé. – Le prolongement en mer des formations et des structures provençales était jusqu'alors largement inconnu.L'interprétation de profils de sismique-réflexion marine 2D et l'intégration de dragages et carottages du fond-marin ont permis d'apporter des éléments nouveaux concernant le cadre stratigraphique, structural et paléogéographique des dé-pôts anté-Messiniens du plateau continental de Provence. Sept unités sismiques post-jurassiques ont été identifiées sur les profils sismiques, cartographiées à travers le plateau continental et corrélées avec les séries affleurant à terre. Une épaisse unité apto-albienne (jusqu'à 2000 m) dont le dépôt est contrôlé par des failles E-W a été mise en évidence en mer. L'existence d'un bassin subsident au Crétacé supérieur sur le plateau continental de Provence a été confirmée par le développement d'une épaisse série de bassin (jusqu'à 1500 m) reposant en downlap sur l'Apto-Albien. Le socle mé-tamorphique de l'écaille de Sicié et sa couverture sédimentaire peut être considéré comme une relique allochtone du « Massif Méridional » ayant alimenté le Bassin sud-provençal en éléments terrigènes au Crétacé supérieur. Dans la rade de Marseille, une épaisse unité syn-rift (Rupélien à Aquitanien) a été mise en évidence (>1000 m), structurée en une série de synformes en échelon d'axe E-W et affectée par des failles d'orientation dominante N040 à N060. Sur le flanc sud des synformes, la formation de plis d'axe N050 est associée à une déformation syn-sédimentaire. La formation des synformes en échelon d'axe E-W résulterait d'une réactivation en décrochement des failles N040 à N060 pendant une phase de compression N-S dont l'âge est compris entre le Burdigalien inférieur et moyen (18-20 Ma). Enfin, les dépôts post-rift sont affectés par des déformations mineures (réactivation de failles et plis associés), le long d'un couloir d'orientation N160 à l'ouest de la baie de Marseille, attribuables à une phase de compression post-burdigalienne et anté-pliocène.
ISSN: 0037-9409

hal-01463727
https://hal-amu.archives-ouvertes.fr/hal-01463727
https://hal-amu.archives-ouvertes.fr/hal-01463727/document
https://hal-amu.archives-ouvertes.fr/hal-01463727/file/Fournier_et_al_Provence_2016.pdf
DOI : 10.2113/gssgfbull.187.4-5.187

Éditeur(s) : OMICS Publishing Group
Résumé : Coastal tropical shrimp farming may impact the adjacent ecosystems through the release of large quantities of effluents rich in nutrients. In New Caledonia, mangroves are considered as a natural biofilter to reduce impacts on the surrounding World Heritage listed lagoon. Our main objective was to understand the influence of effluent discharge on the biogeochemistry of mangrove sediments. A monitoring of the physico-chemical parameters of mangrove sediments was carried out during a whole year, including active and non active periods of the farm. The parameters studied were: i) benthic primary production (Chl-a concentrations), ii) physico-chemical parameters of sediments (redox potential, pH, salinity, TOC, TN, TS, δ13C and δ15N), iii) concentrations of dissolved nitrogen, iron and phosphorus. A mangrove developing in the same physiographic conditions, presenting the same zonation, and free of anthropogenic input was used as reference. The concentration of benthic Chl-a measured at sediment surface in the effluent receiving mangrove was twice to three times that measured in the control zone whatever the season. We thus suggest that nutrients inputs significantly increased the phytobenthic production in the effluent receiving mangrove during the whole year, even after the cessation of discharges and because of natural seasonal dynamic of phytobenthos. Although the flow of surface OM was increased, the OM content at depth was not higher than in the control mangrove. However, the contribution of mangrove detritus to the sedimentary organic pool was higher probably as a result of higher density and much greater individual size of the mangrove trees. Unlike the control mangrove sediment, the effluent receiving mangrove sediment was not stratified, redox potential values were high and presence of Fe3+ was detected down to 50 cm depth, probably as a result of a larger root system, allowing a better sediment oxygenation and accentuated OM decomposition processes, and thus limiting ecosystem saturation.
Journal of Aquaculture Research & Development (21559546) (OMICS Publishing Group), 2014-07-03 , Vol. 5 , N. 5 , P. 1-13

Droits : 2014 Marchand C, et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
http://archimer.ifremer.fr/doc/00251/36253/34801.pdf
DOI:10.4172/2155-9546.1000262
http://archimer.ifremer.fr/doc/00251/36253/

Éditeur(s) : Université Paris 7 – Denis Diderot
Résumé : Sea surface salinity (SSS) influences numerous oceanic phenomena, for instance surface water ventilation, deep water formation and thermohaline circulation. SSS also controls some ocean-atmosphere coupled processes, such as the intensity of freshwater flux and the penetration of heat flux and turbulence. Salinity is more difficult to measure than temperature from in situ surveys, which results in 20 times less data being currently available. Moreover, sea surface temperature (SST) is routinely estimated from satellites, which is not possible yet for SSS. Two space missions will fill this gap soon: SMOS from the European Space Agency and Aquarius/SAC-D from NASA and CONAE. To contribute to the SMOS project, we propose a method for estimating SSS from current satellite observations and for studying the mechanisms governing its variability. We developed a simplified model of the ocean mixed layer, based on the "slab mixed layer" formulation (Frankignoul et Hasselmann, 1977). This 2D horizontal model is implemented over the global ocean, using a near 100 km resolution, and integrated during a climatological year. Air-sea fluxes are taken from the ECMWF meteorological model (ERA40 reanalysis) and the surface currents are provided by altimeter data (SSALTO-DUACS analysis). The mixed layer depth (MLD) is derived from SST observations, using an original inversion technique. The MLD fields obtained from this inversion are well correlated to in situ estimates. This effective depth represents the air-sea fluxes penetration and ensures consistency between fluxes, les currents and SST. We first validate the simulation through examination of the heat balance in north-eastern Atlantic, by comparing to measurements and models from the POMME experiment. Then we study the salinity balance in the global domain, in terms of its geographical distribution and seasonal evolution. Equilibrium between the various processes appears generally more complex than for temperature. Noteworthy, the role of atmospheric flux is less predominant (22%), while geostrophic advection (33%) and diapycnal mixing (22%) contribute more strongly. Our results indicate this model succeeds in reconstructing SSS variability over most of the oceans. Daily SSS variations are also simulated, whereas they are not represented in current observed data at a global scale. Owing to its simplicity and fast computation, the model will be useful to the SMOS mission. It can help for the measurement calibration/validation and provide a first guess estimate to the sophisticated algorithm required for SSS restitution.
La salinité de surface des océans (SSS) influence de nombreux phénomènes océaniques, parmi lesquels la ventilation des eaux de surface, la formation d'eaux profondes et la circulation thermohaline. Elle détermine aussi certains processus couplés océan-atmosphère, notamment l'intensité du flux d'eau douce, la pénétration du flux de chaleur et de la turbulence. La mesure in situ de salinité est plus compliquée que celle de température, si bien qu'on dispose actuellement de 20 fois moins de données pour cette propriété. De plus, la température de surface (SST) est couramment estimée par satellite, ce qui n'est pas encore le cas de la SSS. Deux missions spatiales vont prochainement combler cette lacune : le satellite SMOS de l'Agence Spatiale Européenne et le satellite Aquarius/SAC-D de la NASA et de la CONAE. En préparation du projet SMOS, nous proposons une méthode pour estimer la SSS à partir des observations satellitaires actuelles et étudier les mécanismes de sa variabilité. Nous avons développé un modèle simplifié de couche mélangée océanique, basé sur la formulation "slab mixed layer" (Frankignoul et Hasselmann, 1977). Ce modèle 2D horizontal est implémenté sur l'océan global, avec une résolution proche de 100 km, et intégré au cours d'une année climatologique. Les flux air-mer proviennent du modèle météorologique ECMWF (réanalyse ERA40) et les courants de surface sont issus de l'altimétrie (analyse SSALTO-DUACS). La profondeur de la couche mélangée (MLD) est dérivée des observations de SST, grâce à une technique d'inversion originale. La MLD obtenue par inversion est bien corrélée aux estimations basées sur des données in situ. Cette profondeur effective représente la pénétration des flux air-mer et assure la cohérence entre les flux, les courants et la SST. La simulation est d'abord validée en examinant le bilan de chaleur dans l'Atlantique Nord-Est, par comparaison aux mesures et aux modèles de l'expérience POMME. Puis le bilan de salinité est étudié dans le domaine global, en termes de distribution géographique et d'évolution saisonnière. L'équilibre entre les différents processus est généralement plus complexe que pour la température. Notamment, le rôle du flux atmosphérique est moins prépondérant (22%), tandis que l'advection géostrophique (33%) et le mélange diapycnal (22%) contribuent fortement. Nos résultats montrent que ce modèle parvient à restituer la variabilité de la SSS sur la majeure partie des océans. Le modèle simule aussi les variations journalières de SSS, qui ne sont pas représentées à l'échelle globale dans les observations actuelles. Grâce à sa simplicité et à sa rapidité, le modèle pourra être utile dans le cadre de SMOS. Il pourra aider à la calibration/validation de la mesure et fournir une estimation a priori pour l'algorithme complexe nécessaire à la restitution de la SSS.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/2006/these-2302.pdf
http://archimer.ifremer.fr/doc/00000/2302/

Éditeur(s) : Springer
Résumé : While it is well known that the ocean is one of the most important component of the climate system, with a heat capacity 1,100 times greater than the atmosphere, the ocean is also the primary reservoir for freshwater transport to the atmosphere and largest component of the global water cycle. Two new satellite sensors, the ESA Soil Moisture and Ocean Salinity (SMOS) and the NASA Aquarius SAC-D missions, are now providing the first space-borne measurements of the sea surface salinity (SSS). In this paper, we present examples demonstrating how SMOS-derived SSS data are being used to better characterize key land–ocean and atmosphere–ocean interaction processes that occur within the marine hydrological cycle. In particular, SMOS with its ocean mapping capability provides observations across the world’s largest tropical ocean fresh pool regions, and we discuss from intraseasonal to interannual precipitation impacts as well as large-scale river runoff from the Amazon–Orinoco and Congo rivers and its offshore advection. Synergistic multi-satellite analyses of these new surface salinity data sets combined with sea surface temperature, dynamical height and currents from altimetry, surface wind, ocean color, rainfall estimates, and in situ observations are shown to yield new freshwater budget insight. Finally, SSS observations from the SMOS and Aquarius/SAC-D sensors are combined to examine the response of the upper ocean to tropical cyclone passage including the potential role that a freshwater-induced upper ocean barrier layer may play in modulating surface cooling and enthalpy flux in tropical cyclone track regions.
Surveys In Geophysics (0169-3298) (Springer), 2014-05 , Vol. 35 , N. 3 , P. 681-722

Droits : Springer Science+Business Media Dordrecht 2013
http://archimer.ifremer.fr/doc/00152/26334/24430.pdf
DOI:10.1007/s10712-013-9244-0
http://archimer.ifremer.fr/doc/00152/26334/

Éditeur(s) : Springer Berlin / Heidelberg
Résumé : The role of particles in the fate and speciation of trace metals in macrotidal estuaries was studied using a surface complexation model (MOCO). Cadmium was selected as the target metal contaminant due to its reactivity in estuaries: cadmium behavior is mainly controlled by heterogeneous processes (sorption/desorption) related to salinity and suspended matter gradients. Various scenarios of suspended matter distribution according to salinity were simulated. The impact of surface properties (specific surface area, density of surface sites, acido-basic properties, and complexation constant) was evaluated using data collected on particles from the Gironde, Loire, and Seine estuaries. Our results show that particle surface properties, evaluated on the basis of various parameters, are instrumental in "non-conservative" contaminant speciation in the estuarine environment. Their evaluation enables us to understand and simulate, to a large extent, the fate of "Cd-type" contaminants (whose behavior is controlled by competition between sorption and desorption processes). The natural variations of these properties can be responsible for significant modifications of the Cd speciation in the macrotidal estuaries where salinity and SM gradients are very strong.
The Handbook of Environmental Chemistry (1433-6839) (Springer Berlin / Heidelberg), 2006 , Vol. 5H , P. 265-301

Droits : 2006 Springer
http://archimer.ifremer.fr/doc/2006/publication-2005.pdf
DOI:10.1007/b89479
http://archimer.ifremer.fr/doc/00000/2005/

Éditeur(s) : Amer Geophysical Union
Résumé : The freshest surface waters in the tropical Pacific are found at its eastern boundary. Using in situ observations, we depict the quasi-permanent presence of a far eastern Pacific fresh pool with Sea Surface Salinity (SSS) lower than 33, which is confined between Panama's west coast and 85W in December and extends westward to 95W in April. Strong SSS fronts are found at the outer edge of this fresh pool. We investigate the seasonal dynamics of the fresh pool using complementary satellite wind, rain, sea level and in situ oceanic current data at the surface, along with hydrographic profiles. The fresh pool appears off Panama due to the strong summer rains associated with the northward migration of the ITCZ over Central America in June. During the second half of the year, the eastward-flowing North Equatorial Counter Current keeps it trapped to the coast and strengthens the SSS front on its western edge. During winter, as the ITCZ moves southward, the north-easterly Panama gap wind creates a south-westward jet-like current in its path with a dipole of Ekman pumping/eddies on its flanks. As a result, upwelling in the Panama Bight brings to the surface cold and salty waters which erode the fresh pool on its eastern side while both the jet current and the enhanced South Equatorial Current stretch the fresh pool westward until it nearly disappears in May. New SMOS satellite SSS data proves able to capture the main seasonal features of the fresh pool and monitor its spatial extent.
Journal Of Geophysical Research-oceans (0148-0227) (Amer Geophysical Union), 2012-04 , Vol. 117 , P. -

Droits : 2012 AGU
http://archimer.ifremer.fr/doc/00072/18311/16581.pdf
DOI:10.1029/2011JC007802
http://archimer.ifremer.fr/doc/00072/18311/

Éditeur(s) : American Geophysical Union
Résumé : Microwave Sea Surface Salinity (SSS) measurements can be performed by isolating the emissivity response to salinity changes from numerous geophysical effects, including surface temperature and wind waves. At L-band frequencies (1 to 2 GHz), the sensitivity to SSS is sufficient but it falls off quickly as frequency is increased. Nevertheless, methods using higher microwave frequencies with much lower SSS sensitivity than at L band, can already be tested. In particular, combining 6 and 10 GHz data in vertical polarization efficiently minimizes sea surface roughness and thermal impacts. Using AMSR-E data, the retrieved bi-monthly maps of SSS at 0.5 degrees resolution over the region of the Amazon plume show relative accuracy in-line with the future L-band dedicated mission objectives. Citation: Reul, N., S. Saux-Picart, B. Chapron, D. Vandemark, J. Tournadre, and J. Salisbury (2009), Demonstration of ocean surface salinity microwave measurements from space using AMSR-E data over the Amazon plume, Geophys. Res. Lett., 36, L13607, doi:10.1029/2009GL038860.
Geophysical Research Letters ( GRL ) (0094-8276) (American Geophysical Union), 2009-07 , Vol. 36 , P. 1-5

Droits : 2009. American Geophysical Union. All Rights Reserved
http://archimer.ifremer.fr/doc/2009/publication-6620.pdf
DOI:10.1029/2009GL038860
http://archimer.ifremer.fr/doc/00000/6620/

Éditeur(s) : Université Bordeaux 1
Résumé : The mercury cycle was explored in the Petit-Saut reservoir / Sinnamary Estuary continuum in French Guiana. Main processes involve (i) photo-induced reduction, (ii) adsorption and desorption at the particle surfaces, (iii) methylating bacterial activity, (iv) precipitation and dissolution of iron oxyhydroxides and sulfides. Sources of mercury to the Petit-Saut reservoir consist of the partly impacted river-tributaries, the atmospheric deposition and the flooded soils or vegetation. Once into the reservoir, divalent mercury undergoes a large spectrum of transformations including speciation and phase changes. We, here, probe these processes and demonstrate that the Petit-Saut reservoir behaves as a privileged site for atmospheric recycling and in situ methylation. At the air / water interface, the mercury evasion exceeds by 50 % the direct atmospheric deposition. The in situ monomethylmercury (MMHg) production mostly occurs at the water-column chemocline and near the benthic interface. It reaches, for the whole reservoir, 8.1 moles yr-1 which corresponds to a 0.06 % d-1 methylation rate. We calculated that the 2003/04 period MMHg outputs from the reservoir to the Sinnamary Estuary averaged 13.5 moles yr-1 while the inputs were 5.4 moles yr-1. The dynamic Sinnamary Estuary is the genuine geochemical reactor of the continuum. There, the divalent mercury undergoes rapid yet profound partitioning among phases, recycling to the atmosphere and methylation processes. Those mostly originate from the long-scale oxygen paucity of the dam discharged waters. The expression of marked redox gradients and the intense organic matter turnover enhance the production of methylable inorganic mercurial species and tend to favor the sulfate reducing bacteria (methylating agents) activity. As a result, the dynamic Sinnamary Estuary exports 60 % more MMHg than it does import: 27 versus 17 moles yr-1. Further at large, in the saline estuary, we determined: (i) a non conservative behavior of dissolved (< 0.2 µm) mercury, (ii) a lowering of the mercury level of particles during mixing with the Amazon plume and (iii) a gradual dilution of the estuarine mercury concentrations by oceanic waters.
La retenue de Petit-Saut et, à l'aval, l'estuaire du Sinnamary sont deux centres d'altération du cycle naturel du mercure. Les processus sont, entre autres, (i) la photoréduction, (ii) la sorption / désorption en surface des particules, (iii) l'activité méthylante des bactéries, (iv) la dissolution / précipitation des oxyhydroxydes et des sulfures de fer. Les sources de mercure vers la retenue sont variées. Elles regroupent, en premier lieu, les affluents (partiellement orpaillés), l'atmosphère, les sols et la végétation ennoyés. Dans la colonne d'eau, les formes divalentes du mercure subissent un train complet de transformations couplant changements de phase et de spéciation. Nos résultats illustrent ces processus et démontrent que la retenue constitue un site privilégié de recyclage vers l'atmosphère et de méthylation. A l'interface air / eau, les exports en mercure de la retenue excèdent de 50 % le dépôt atmosphérique. La production endogène de monométhylmercure (MMHg) a lieu dans des sites particuliers : la chemocline et l'interface benthique. Elle atteint pour l'ensemble de la retenue 8,1 moles a-1 soit un taux de méthylation de 0,06 % j-1. On estime que la retenue exporte vers l'estuaire du Sinnamary 13,5 moles a-1 de MMHg alors qu'elle n'importe que 5,4 moles a-1. L'estuaire dynamique du Sinnamary constitue le véritable réacteur chimique du système fonctionnant en liaison avec celui de la retenue. Le mercure y décrit un cycle rapide aux processus de partition, de recyclage et de méthylation marqués. Ces processus résultent de l'oxygénation incomplète et durable des masses d'eau anoxiques exportées par la retenue de Petit-Saut. L'expression de gradients rédox prononcés conjuguée à un intense recyclage de la matière organique y favorise la production de formes méthylables de mercure ainsi que l'activité des bactéries sulfatoréductrices (agents de la méthylation). C'est pourquoi, l'estuaire dynamique du Sinnamary exporte 60 % plus de MMHg qu'il n'importe : 27 contre 17 moles a-1. Plus en aval, dans l'estuaire salin, nous avons mis en évidence : (i) un comportement non conservatif du mercure dissous, (ii) un appauvrissement du mercure des particules suite au mélange avec le panache de l'Amazone et (iii) une dilution des concentrations par les masses d'eau océaniques.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/2006/these-1508.pdf
http://archimer.ifremer.fr/doc/00000/1508/