Éditeur(s) : AIHP-GEODE : Archéologie Industrielle, Histoire, Patrimoine/Géographie- Développement Environnement de la Caraïbe AIHP-GEODE : Archéologie Industrielle, Histoire, Patrimoine/Géographie- Développement Environnement de la Caraïbe
Extrait de : Seconde séminaire du laboratoire AIHP Géode, le 23 octobre 2015. Université des Antilles
Description : Jean-Pierre DEDIEU, directeur de recherche au CNRS, propose une réflexion sur la notion de réseau importée en histoire dans le courant des années 1990 dans un contexte d'effondrement du paradigme de classe sociale. Cette notion mise au point par les sociologues une quarantaine d'années auparavant. Il s'agit d'appréhender des phénomènes fondés sur les relations entre acteurs, quels que soient ces acteurs, d'identifier les flux d'information et des ressources que s'échangent les acteurs. Toutes ces informations sont traitées dans une base de données qui permet de modéliser les réseaux et d'analyser les dynamiques, les rapports de forces et leurs évolutions comme illustré avec l'exemple de la monarchie espagnole au XVIIIe siècle.
Siècle(s) traité(s) : 20
Droits : CC-BY-NC-ND - Attribution - Pas d'utilisation commerciale - Pas de modification
Permalien : http://www.manioc.org/fichiers/V15435
V15435
V15435

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Abstract View references (38)Silicalite-1 (S-1) and ZSM-5 membranes prepared by secondary growth on tubular ceramic supports were tested using a pervaporation set up for the desalination of aqueous solutions containing NaCl in concentrations corresponding to brackish (0.3-1wt%), sea (3.5wt%) and brine (7.5-15wt%) water. ZSM-5 membranes delivered higher water fluxes when compared with S-1 membranes due to enhanced hydrophilicity of the Al-rich zeolite structure leading to fluxes as high as 11.5kgm -2h -1 for 0.3wt% NaCl feed solutions at 75°C. At higher salt concentration the water flux decreased alongside with the salt rejection rate, however the hydrophilic ZMS-5 membrane became more susceptible to performance loss, particularly at high temperatures. Detailed stability experiments carried out for up to 560h showed the dissolution of both S-1 and ZSM-5 top layers. This was attributed to the combined effects of ion exchange and water dissolution mechanisms. Interesting though, the MFI structure zeolite was still observed on the XRD patterns whilst EDX depth profile showed the presence of silica up to 30μm depth into the support. These results suggest the formation/infiltration of a compact amorphous phase in the substrate, derived from the aggregation of the dissolved silicate species and possibly together with the arrangement of MFI nano-slabs during the desalination tests. Despite generating lower water fluxes, the S-1 membrane exhibited relatively high robustness under the long term testing conditions which included temperature cycling, delivering salt rejections from initial >99% to <80% at the end of the testing period (560h). © 2012 Elsevier B.V.
ISSN: 0376-7388

hal-01683201
https://hal.univ-antilles.fr/hal-01683201
DOI : 10.1016/j.memsci.2012.05.074

Éditeur(s) : HAL CCSD Geological Society of America
Résumé : If the net flux to the island arc crust is primitive arc basalt, the evolved composition of most arc magmas entails the formation of complementary thick ultramafic keels at the root of the island arc crust. Dunite, wehrlite, and Cr-rich pyroxenite from the Jijal complex, constituting the Moho transition zone of the Kohistan paleo–island arc (northern Pakistan), are often mentioned as an example of high-pressure cumulates formed by intracrustal fractionation of mantle-derived melts, which were later extracted to form the overlying mafic crust. Here we show that calculated liquids for Jijal pyroxenites-wehrlites are strongly rare earth element (REE) depleted and display flat or convex-upward REE patterns. These patterns are typical of boninites and are therefore unlike those of the overlying mafic crust that have higher REE concentrations and are derived from light rare earth element (LREE)–enriched melts similar to island arc basalt. This observation, along with the lower 208Pb/204Pb and 206Pb/204Pb ratios of Jijal pyroxenites-wehrlites relative to gabbros, rejects the hypothesis that gabbros and ultramafic rocks derive from a common melt via crystal fractionation. In the 208Pb/204Pb versus 206Pb/204Pb diagram, ultramafic rocks and gabbros lie on the same positive correlation, suggesting that their sources share a common enriched mantle 2 (EM2) signature but with a major depleted component contribution for the ultramafic rocks. These data are consistent with a scenario whereby the Jijal ultramafic section represents a Moho transition zone formed via melt-rock reaction between subarc mantle and incoming melt isotopically akin to Jijal gabbroic rocks. The lack in the Kohistan arc of cogenetic ultramafic cumulates complementary to the evolved mafic plutonic rocks implies either (1) that a substantial volume of such ultramafic cumulates was delaminated or torn out by subcrustal mantle flow from the base of the arc crust in extraordinarily short time scales (0.10–0.35 cm/yr), or (2) that the net flux to the Kohistan arc crust was more evolved than primitive arc basalt.
ISSN: 0091-7613

hal-00406688
https://hal.archives-ouvertes.fr/hal-00406688
DOI : 10.1130/G23675A.1

Éditeur(s) : HAL CCSD
Résumé : Diffusion du document : INRA Documentation de Centre, Domaine de Duclos, 97170 Petitt-Bourg (Guadeloupe, France) Diplôme : DEA
il s'agit d'un type de produit dont les métadonnées ne correspondent pas aux métadonnées attendues dans les autres types de produit : DISSERTATION
Because soil respiration representes 80% of ecosystem respiration, it is a major flux between biosphere and atmosphere. We examined the effects of root and litter exclusion on soil CO! efflux (Rsu1) using trenching and litter exclusion in a tropical plantation constituted of trees seedlings installed in 16 mono-specific stands 20 years ago near Kourou, French Guyana. Soil CO2 efflux was measured using an infra red gas analyser (PP System,EGM4 ) at 16 randomly distributed plot in each treatment: control, root exclusion, litter exclusion and both root and litter exclusion. in the plantation. We measured R'1l1during four periods, and we have collected soil samples, litter biomass and measured moisture at 5 cm depth in the soil. Soil CO, efflux varied significantly among species from 2,8±O,7f1mo l. m''. s' (mean ± standard deviation) to 7.4± 1.7fLmol. n'-' . s ' for Qualea rosea and Vochys ia tomentosa, respectively. 1'0 significant correlation was found between RSIlI variability and soil moisture, which is mostly related to soil texture in the experimental site. Soil CO2 efflux was significantly reduced in litter exclusion treatment and root exclusion plots (6 months litter and/or root exclusion) during ail measurements period and for ail species, compared to control plots. The reduction of soil CO, efflux was higher in plot without root than in plot without litter of control plot (42% and 25%, respectively). There was an import ant specific diversity in these reductions . We estimated the contribution of roof respiration (Rr) to total Rso1 by calculating the difference between Rso1 control and Rsn l root exclusion plot corrected for the decomposition of root that were killed following t re n e h in ~. Thus the heterotrophic component of soil carbon efflux accounts for 46% of total carbon efflux (1,9f1 mol. rn" . s•') while root respiration accounts for 54% of soil carbon release (2,3 ~t mo l. m-2 S-I) . Because there was a negative and significant correlation between microbial respiration (Rrn) and C/N of mature leaves it seemed to be possible to predict Rm if we known the mature leaves quality. In addition a good estimate theorical R ~, values from R~, measured in different treatments.
La respiration du sol en représentant une part de 80% de la respiration de l'écosystème apparaît être un flux majeur entre la biosphère et l'atmosphère. Nous avons étudié les effets de l'exclusion racinaire et de la litière sur le flux de CO, du sol (R ~ , ) en utilisant la méthode de " Trench-plots" et de suppression de litière dans une plantation d'arbres tropicaux. Ces arbres, âgés de 20 ans ont été plantés sur un sol uniforme, près de Kourou en Guyane française, en 16 placeaux mono-spécifiques. Pour mesurer les flux de CO2 provenant du sol, nous avons utilisé un analyseur différentiel de gaz infrarouge portable muni d'une chambre. Les mesures ont été faites sur 4 traitements différents tels que : le contrôle, l'exclusion racinaire, l'exclusion de litière et l'exclusion de litière et de racine et ce, répétés sur chacune des 16 placettes mono-spécifiques. Cette étude comporte 4 campagnes de mesures. Nous avons également effectué des prélèvements de sol de litière et nous avons fait des mesures d’humidité de sol à une profondeur de 5 cm. Les flux de C01 du sol varient fortement entre espèces de 2.8±O.7 ~t m o 1. m-2. sol à 7 A± 1. 7 ~t m o l. m•1 sol pour Qua/ev rosea ct Vochysto tomentasa, respectivement. Il n'existe pas de corrélation significative entre les variations de Rw l ct celles de l'humidité du sol (indication sur la texture du sol de la plantation ). Nous avons observé que Rso1 était significativement plus faible dans les placeaux sans racines et/ou sans litière (6 mois après la mise en place de l'expérimentation) pour toutes les campagnes de mesures et pour toutes les espèces que dans les placeaux contrôlés. Cette réduction du flux de CO2 du sol est plus forte dans les "trench-plots " que dans les traitement s d'exclusion de litière avec 42 et 25% respectivement. Un effet "traitement " et un effet "espèce" important expliquent 3 1"/.. ct 13% de la variabilité totale de R~. Nous avons cherché à connaître la contribution des racines dans les valeurs de R""I. en comparant le flux de CO2 provenant du sol sur des "trench -plot s'' au flux de COl provenant du sol dans les placeaux contrôlés . Cette estimation a été corrigée pour prendre en compte la décomposition des racines tuées par les tranchées. Ainsi, la composante appartenant aux micro -organismes représente 46% du flux total de carbone provenant du sol (1.9Jlmo l. m-2 S•I ) alors que la respiration des racines représente 54% du dégagement de carbone (2 ,3~lmol. m ol . 5-La respiration des micro-organismes pourrait être estimée en mesurant le C/N des feuilles matures puisqu'il existe une corrélation significative et négative entre les deux. Enfin les résultats obtenus sur les différents traitements permettent d'obtenir une bonne estimation de la respiration du sol avec un RSIlI théorique corrélé à 66% avec les valeurs réelles mesurées.
https://hal.archives-ouvertes.fr/hal-01189239

hal-01189239
https://hal.archives-ouvertes.fr/hal-01189239
PRODINRA : 18212

Éditeur(s) : HAL CCSD Wiley
Résumé : The intensification of the hydrological cycle, with an observed and modeled increase in drought incidence and severity, underscores the need to quantify drought effects on carbon cycling and the terrestrial sink. FLUXNET, a global network of eddy covariance towers, provides dense data streams of meteorological data, and through flux partitioning and gap filling algorithms, estimates of net ecosystem productivity (FNEP), gross ecosystem productivity (P), and ecosystem respiration (R). We analyzed the functional relationship of these three carbon fluxes relative to evaporative fraction (EF), an index of drought and site water status, using monthly data records from 238 micrometeorological tower sites distributed globally across 11 biomes. The analysis was based on relative anomalies of both EF and carbon fluxes and focused on drought episodes by biome and climatic season. Globally P was ≈50% more sensitive to a drought event than R. Network-wide drought-induced decreases in carbon flux averaged −16.6 and −9.3 g C m−2 month−1 for P and R, i.e., drought events induced a net decline in the terrestrial sink. However, in evergreen forests and wetlands drought was coincident with an increase in P or R during parts of the growing season. The most robust relationships between carbon flux and EF occurred during climatic spring for FNEP and in climatic summer for P and R. Upscaling flux sensitivities to a global map showed that spatial patterns for all three carbon fluxes were linked to the distribution of croplands. Agricultural areas exhibited the highest sensitivity whereas the tropical region had minimal sensitivity to drought. Combining gridded flux sensitivities with their uncertainties and the spatial grid of FLUXNET revealed that a more robust quantification of carbon flux response to drought requires additional towers in all biomes of Africa and Asia as well as in the cropland, shrubland, savannah, and wetland biomes globally.
ISSN: 1354-1013

hal-01032076
https://hal.archives-ouvertes.fr/hal-01032076
DOI : 10.1111/j.1365-2486.2009.01991.x

Éditeur(s) : HAL CCSD
Résumé : National audience
Lorsque le volume des données est trop important pour qu'elles soient stockées dans une base de données, ou lorsque leur taux d'arrivée est rapide, les Systèmes de Gestion de Flux de Données (SGFD) permettent de capturer des flux d'enregistrements structurés et de les interroger à la volée par des requêtes permanentes (exécutées de façon continue). Mais les SGFD ne conservent pas l'historique des flux qui est perdu à jamais. Cette communica- tion propose une définition formelle de ce que devrait être un résumé généraliste de flux de données. La notion de résumé généraliste est liée à la capacité de répondre à des requêtes variées et de réaliser des tâches variées de fouille de données, en utilisant le résumé à la place du flux d'origine. Une revue de plusieurs approches de résumés est ensuite réalisée dans le cadre de cette définition. Enfin, l'intégration de telles approches de résumés dans un SGFD est discutée, à la fois en termes de construction et d'utilisation.
EGC: Extraction et Gestion des Connaissances
Hammamet, Tunisia

hal-00502017
https://hal.archives-ouvertes.fr/hal-00502017
https://hal.archives-ouvertes.fr/hal-00502017/document
https://hal.archives-ouvertes.fr/hal-00502017/file/resume_generaliste.pdf

Éditeur(s) : HAL CCSD MDPI AG, Basel, Switzerland
Résumé : International audience
Abstract View references (46)This work shows the preparation of silica membranes by a two-step sol-gel method using tetraethyl orthosilicate in ethanolic solution by employing nitric acid and ammonia as co-catalysts. The sols prepared in pH 6 resulted in the lowest concentration of silanol (Si-OH) species to improve hydrostability and the optimized conditions for film coating. The membrane was tested to desalinate 0.3-15 wt % synthetic sodium chloride (NaCl) solutions at a feed temperature of 22 °C followed by long term membrane performance of up to 250 h in 3.5 wt % NaCl solution. Results show that the water flux (and salt rejection) decrease with increasing salt concentration delivering an average value of 9.5 kg m-2 h-1 (99.6%) and 1.55 kg m-2 h-1 (89.2%) from the 0.3 and 15 wt % saline feed solutions, respectively. Furthermore, the permeate salt concentration was measured to be less than 600 ppm for testing conditions up to 5 wt % saline feed solutions, achieving below the recommended standard for potable water. Long term stability shows that the membrane performance in water flux was stable for up to 150 h, and slightly reduced from thereon, possibly due to the blockage of large hydrated ions in the micropore constrictions of the silica matrix. However, the integrity of the silica matrix was not affected by the long term testing as excellent salt rejection of >99% was maintained for over 250 h. © 2013 by the authors; licensee MDPI, Basel, Switzerland.
ISSN: 2077-0375

hal-01683203
https://hal.univ-antilles.fr/hal-01683203
DOI : 10.3390/membranes3030136

Éditeur(s) : Elsevier
Résumé : The Okinawa Trough is a natural laboratory for the study of later Quaternary land-ocean interaction and paleoenvironmental changes. In this study we reconstruct the evolution of clay mineral assemblages in Core DGKS9604 retrieved from the central Okinawa Trough. Illite dominates the clay mineral compositions, with average contents above 60%. Clay mineral evolution since 28 ka is closely related to changes in sediment provenance and paleoenvironment. Sea level rise and the strength of the Kuroshio Current control the dispersal and deposition of clays on the East China Sea shelf and in the Okinawa Trough, and thus, determine the clay mineral compositions in the core sediments. During the late last glacial period (28.0-14.0 ka), the paleo-Changjiang River mouth was situated at the shelf edge close to the central Okinawa Trough and thus, together with the outer shelf, supplied large volumes of terrigenous sediments directly into the trough. From 14.0 to 8.4 ka influence from the Changjiang decreased while the mid-outer shelf of the East China Sea became the dominant sediment source to the central Okinawa Trough as sea level rose and the Changjiang river mouth migrated west. Strong sediment reworking and erosion at the shelf edge at 15-13 ka significantly increased the lateral transport of fine-grained shelf sediments to the central Okinawa Trough. Since ca. 8.4 ka clays from Taiwan have dominated the sediment flux to the site, coinciding with the re-entry of the Kuroshio Current into the trough. The increasing influence of the Changjiang-sourced sediments since 1.5 ka was probably related to the weakening of the Kuroshio Current and/or a higher river flux. (C) 2010 Elsevier B.V. All rights reserved.
Palaeogeography, Palaeoclimatology, Palaeoecology (0031-0182) (Elsevier), 2010-03 , Vol. 288 , N. 1-4 , P. 108-117

Droits : 2010 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/00002/11367/7977.pdf
DOI:10.1016/j.palaeo.2010.01.040
http://archimer.ifremer.fr/doc/00002/11367/

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : Production rates in horizontal shale gas wells display declines that are controlled by the low permeability and the intrinsic heterogeneity of the shale matrix. We present an original multi-continuum approach that yields a physical model able to reproduce the complexity of the decreasing gas rates. The model describes the dynamics of gas rate as function of the physical reservoir parameters and geometry, while the shale matrix heterogeneity is accounted for by a stochastic description of transmissivity field. From the 3D (Dimensional) problem setting, including the heterogeneous shale matrix, the fractures generated by the hydrofracking operations, as well as the production well characteristics, we establish an effective upscaled 1D model for the gas pressures in fracture and matrix as well as the volumetric flux. We analyse the decline curves behaviour, and we identify the time scales that characterize the dynamics of the gas rate decline using explicit analytical Laplace space solutions of the upscaled process model. Asymptotically, the flux curves decrease exponentially, while in an intermediate regime we find a power-law behaviour, in which the flux scales with a power law in time as (t^{-beta }), where (beta ) reflects the medium heterogeneity. We use this solution to fit a set of real data displaying distinctly different decline trends and study the sensitivity of the model to the reservoir parameters in order to identify their respective controls at the different stages of the decline curve dynamics. Results indicate that the initial value of the gas rate is determined by the transmissivity of the fractures and the initial pressure of the gas in the shale matrix. The latter causes mainly a shift in the entire decline curve. The early time of decline curve shape is primarily controlled by the fracture properties (compressibility and transmissivity). During the main part of the economically valuable production times, i.e. before the production rate drops exponentially, the decline curve is strongly controlled by the properties of the shale rocks including their heterogeneity, which is modelled by two parameters describing the non-Fickian pressure diffusion effects in a stochastic framework.
ISSN: 0169-3913

hal-01217247
https://hal.archives-ouvertes.fr/hal-01217247
DOI : 10.1007/s11242-015-0504-y

Éditeur(s) : Copernicus Gesellschaft Mbh
Résumé : From 10 to 8 ka BP (thousand years before present), paleoclimate records show an atmospheric and oceanic cooling in the high latitudes of the Southern Hemisphere. During this interval, temperatures estimated from proxy data decrease by 0.8 degrees C over Antarctica and 1.2 degrees C over the Southern Ocean. In order to study the causes of this cooling, simulations covering the early Holocene have been performed with the climate model of intermediate complexity LOVECLIM constrained to follow the signal recorded in climate proxies using a data assimilation method based on a particle filtering approach. The selected proxies represent oceanic and atmospheric surface temperature in the Southern Hemisphere derived from terrestrial, marine and glaciological records. Two mechanisms previously suggested to explain the 10-8 ka BP cooling pattern are investigated using the data assimilation approach in our model. The first hypothesis is a change in atmospheric circulation, and the second one is a cooling of the sea surface temperature in the Southern Ocean, driven in our experimental setup by the impact of an increased West Antarctic melting rate on ocean circulation. For the atmosphere hypothesis, the climate state obtained by data assimilation produces a modification of the meridional atmospheric circulation leading to a 0.5 degrees C Antarctic cooling from 10 to 8 ka BP compared to the simulation without data assimilation, without congruent cooling of the atmospheric and sea surface temperature in the Southern Ocean. For the ocean hypothesis, the increased West Antarctic freshwater flux constrainted by data assimilation (+100 mSv from 10 to 8 ka BP) leads to an oceanic cooling of 0.7 degrees C and a strengthening of Southern Hemisphere westerlies (+6 %). Thus, according to our experiments, the observed cooling in Antarctic and the Southern Ocean proxy records can only be reconciled with the reconstructions by the combination of a modified atmospheric circulation and an enhanced freshwater flux.
Climate Of The Past (1814-9324) (Copernicus Gesellschaft Mbh), 2013 , Vol. 9 , N. 2 , P. 887-901

Droits : Author(s) 2013. CC Attribution 3.0 License.
http://archimer.ifremer.fr/doc/00181/29203/27584.pdf
DOI:10.5194/cp-9-887-2013
http://archimer.ifremer.fr/doc/00181/29203/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Here we show that copper substitution in perovskite-type barium strontium cobalt copper oxide (BSCC) membranes confers extremely high oxygen fluxes well beyond the state of art, reaching 27.5 ml cm−2 min−1at 950 °C. A key feature of BSCC is the formation of a mixed matrix catalyst-perovskite membrane caused by the segregation of copper, leading to the formation of an intergranular network of copper-rich oxide between perovskite grains. BSCC membranes delivered pressure normalised oxygen flux (i.e. permeance) of up to 86 times higher, above pressure difference of 18 kPa, as compared to best perovskite membrane, BBSC, due to the catalytic effect of segregated copper oxide. Unlike conventional dual-phase membranes which contain ion and electron conducting phases, this work shows for the first time perovskite-type membranes consisting of a mixed matrix of oxygen ion/electron conducting (perovskite) and catalytic (copper oxide) phases, thus paving the way to the development of high performance membranes for oxygen separation from air for clean energy applications. © 2016 Elsevier B.V.
ISSN: 0376-7388

hal-01683219
https://hal.univ-antilles.fr/hal-01683219
DOI : 10.1016/j.memsci.2016.12.035

Éditeur(s) : HAL CCSD
Résumé : Karst systems are the most important groundwater reservoirs in Mediterranean area. Beyond saturated zone, unsaturated zone constitute an entity where water storage and transfer play a major role in a global behavior of spring water. This structure and functioning are complex and not well known because of the high heterogeneity created and organized by groundwater flow. In this study, we used gravimetric and hydrogeologic method to directly observe and quantify water storage and transfer processes in unsaturated zone of karst system. Surface to depth gravity measurements on several karst system allow quantifying seasonal water storage changes in unsaturated zone. We show that these variations occur in the first tens meters of unsaturated zone. Furthermore, water storage capacity of unsaturated zone seems to be influenced by lithology (limestone or dolomite). Finally, direct observations of water flow in unsaturated zone are done using caves access. We show that some characteristics of unsaturated water flow such as bipolar slow-fast flow can be widespread for whatever depth of measurement and recharge area. Model of this flow, using a simple modeling scheme, show the complexity of water transfer processes in unsaturated zone of karst system.
Les aquifères karstiques constituent l'essentiel des ressources en eau du pourtour Méditerranéen. Au-delà de la zone saturée de ces systèmes, la zone non saturée constitue une entité importante quant au transfert et au stockage temporaire de l'eau. La structure et le fonctionnement de cette entité du karst sont complexes et mal connus à cause du processus de karstification qui hiérarchise la circulation hydrodynamique en son sein. Dans cette étude nous utilisons des méthodes géodésiques et hydrogéologiques afin d'observer de façon directe et de quantifier les processus de transfert et de stockage de la zone non saturée. Les mesures gravimétriques en surface et profondeur sur différents systèmes karstiques ont permis de quantifier les variations du stockage en eau saisonnier dans la zone non saturée. La gravimétrie différentielle montre que ces variations sont réparties dans les quelques premiers mètres de la zone non saturée. Il semble, de plus, que la capacité de stockage de la zone non saturée soit fonction de la lithologie de l'encaissant (calcaire et dolomie). Enfin, des observations directes du flux d'eau en zone non saturée ont été effectuées par le biais de mesures dans différentes cavités. Nous montrons que certaines caractéristiques du flux d'eau en zone non saturée, comme la présence d'un flux bipolaire lent-rapide, peuvent être généralisées quelque soit la profondeur de mesure et la surface d'impluvium. La modélisation de ce flux, à partir d'un schéma simple, a montré la complexité des processus de transfert engendrés au sein de la zone non saturée.
https://tel.archives-ouvertes.fr/tel-00829346

tel-00829346
https://tel.archives-ouvertes.fr/tel-00829346
https://tel.archives-ouvertes.fr/tel-00829346/document
https://tel.archives-ouvertes.fr/tel-00829346/file/manuscrit_deville_finish.pdf

Éditeur(s) : HAL CCSD
Résumé : Karstic aquifers represent the most important fresh water reservoirs in many regions of the world like the Mediterranean Basin. However, because of complex processes of karstification, those aquifers are highly heterogeneous at all spatial scales and vulnerable to contamination. In this dissertation, we studied the potential of gravimetry and ambient seismic noise for hydrological modeling in karstic areas.The dolomitic area surrounding the “GEK” observatory in the Durzon catchment on the Larzac plateau, in France, is the preferred site for these studies. Inside the observatory, a superconducting gravimeter dedicated to hydrology has continuously measured gravity changes since 2011 with high precision, undertaken for the first time on a karst. From this gravity monitoring, we made conceptual hydrological models which laid the foundation of 1-D flow physical models. Indeed, gravimetry is an integrative hydro-geophysical method which allows 1) to consider the epikarst, locally heterogeneous as an equivalent tabular medium and 2) to define the types of transfer (fast & slow) occurring at the site. Especially, the lack of fast transfer through the GEK epikarst was precisely quantified for the first time at the field scale (~100m). Gravity-driven water mass balance with local meteorological data (evapotranspiration from a flux tower and precipitation) allowed setting the bottom outlet of the model to 1 mm.day-1. This flow has proved to be representative of the low-flow discharge at the only spring which represents all groundwater outflows from the catchment. This result supposes the homogeneity of the dolomitic epikarst almost at the basin scale. Model parameters were next calibrated using one year of ambient seismic noise monitored at two stations. Phase velocity changes obtained by cross-correlating the noise between 6 and 8 Hz were used as a ”timer” to follow the water infiltration between a depth of 30 and 60 meters. Thus, monitoring seismic velocity changes using ambient seismic noise demonstrates great potential for the study of deep and complex critical zones and could fill the instrumental gap currently existing in hydrology.Time-lapse gravity measurements with a spring-based portable gravimeter have also demonstrated the different behavior of two epikarsts and their variability at the scale of a few hundred meters. Monthly measurements around the observatory revealed the spatial homogeneity of this dolomitic epikarst: all the stations showed the same water storage changes. On the contrary, seasonal surface to depth gravity measurements along the underground passage of the Saint-Ferréol sinkhole, in limestone, have shown fast transfer and strong spatial variability of water storage. Lithology is then expected to play a part in the epikarst capacity to retain water. The precision needed to measure the weak hydrological induced signals during those surveys required robust methodology and an ambient temperature effect on measurements with spring-based gravimeter was observed in the field and quantified in the laboratory.
Les aquifères karstiques représentent des ressources en eau essentielles dans de nombreuses régions du monde comme le bassin Méditerranéen. Cependant, de par les processus complexes de karstification, ces aquifères sont hétérogènes à de nombreuses échelles et vulnérables. Dans cette thèse, nous étudions le potentiel de la gravimétrie et du bruit sismique ambiant pour la modélisation hydrologique en milieu karstique.Le site dolomitique de l’observatoire « GEK », sur le bassin du Durzon dans le Larzac, est le site d’étude privilégié de ces travaux. Dans l’observatoire, un gravimètre supraconducteur dédié à l’hydrologie mesure depuis 2011 les variations de gravité en continu et à une très haute précision, pour la première fois sur un karst. Des modèles hydrologiques conceptuels ont été réalisés à partir de cette surveillance gravimétrique et ont permis de poser les bases de modèles physiques d’écoulements 1-D. En effet la gravimétrie, intégratrice, permet 1) de considérer l’épikarst localement hétérogène comme un milieu tabulaire équivalent et 2) de définir les types de transfert à l’œuvre sur le site. En particulier, l’absence de transfert rapide dans l’épikarst a été quantifiée avec précision pour la première fois à l’échelle du terrain (~100m). A l’aide de données météorologiques locales, un bilan de masse précis a permis de définir le flux en limite inférieure du modèle à 1 mm.jour-1. Ce flux s’est montré représentatif du débit de basses-eaux de la source drainant l’ensemble du bassin. Ce résultat suppose une homogénéité de l’épikarst dolomitique quasiment à l’échelle du bassin. Les paramètres des modèles physiques ont ensuite pu être calibrés à l’aide d’un an d’intercorrélation du bruit sismique ambiant entre deux stations. Les variations de vitesses de phase obtenues entre 6 et 8Hz nous ont servi de « chronomètre » pour suivre l’infiltration entre 30 et 60m de profondeur. La surveillance passive des variations de vitesses sismiques par intercorrélation du bruit sismique ambiant montre ainsi un fort potentiel pour l’étude des zones critiques profondes et complexes à l’échelle du terrain et peut combler la lacune instrumentale qui existe actuellement en hydrologie.Des campagnes répétées de mesures avec un gravimètre portable à ressort ont également mis en évidence le fonctionnement différent de deux épikarsts et leur variabilité à l’échelle de la centaine de mètres. Des mesures mensuelles autour de l’observatoire ont mis en évidence l’homogénéité spatiale de cet épikarst dolomitique : toutes les stations ont les mêmes variations temporelles de stock d’eau. Au contraire, des mesures saisonnières en surface et en profondeur le long de la galerie souterraine calcaire de l’abîme de Saint-Ferréol ont montré une variabilité spatiale forte du stockage ainsi que du transfert rapide. La lithologie de l’épikarst est donc suspectée de jouer un rôle dans sa capacité de stockage. Lors de ces campagnes, la faiblesse du signal recherché a nécessité une méthodologie précautionneuse et un effet de température sur les mesures des gravimètres relatifs à ressort a été observé sur le terrain et quantifié en laboratoire.
https://tel.archives-ouvertes.fr/tel-01649606

NNT : 2016MONTT128
tel-01649606
https://tel.archives-ouvertes.fr/tel-01649606
https://tel.archives-ouvertes.fr/tel-01649606/document
https://tel.archives-ouvertes.fr/tel-01649606/file/2016_FORES_archivage.pdf

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
Le but de cette étude est de relier les variations des descripteurs de structure (densité du peuplement, surface terrière, biomasse aérienne) et de dynamique (croissance des arbres, taux de mortalité et de recrutement, flux de biomasse) de la forêt tropicale à la surface des parcelles forestières et à l'intervalle de temps entre les inventaires forestiers. Un jeu de données provenant d'un large réseau de parcelles recensé tous les 2 ans sur une période de 16 ans a été utilisé pour développer et paramétrer un nouveau modèle statistique de prédictions des coefficients de variations pour chacun des descripteurs étudiés. Plus de 90 % de la variabilité de ces coefficients de variation est prédit par un modèle statistique qui inclut la taille de la parcelle et l'intervalle de temps entre les inventaires. Tous les descripteurs de structure de la forêt varient de moins de 10% pour des parcelles de taille supérieure à 2 ha. Parmi les descripteurs de la dynamique forestière, le flux sortant de biomasse aérienne est le plus variable. Cinq parcelles de 6.25 ha sont nécessaires pour estimer sa moyenne, sur une période 16 ans, avec une erreur de 20 % sur la moyenne. Ceci contraste avec un flux entrant de biomasse aérienne, via la croissance et le recrutement, relativement constant. La croissance des arbres est remarquablement bien estimée avec moins de 15 % de variabilité pour une parcelle de 2 ha recensée tous les 2 ans. Ce travail fournit une méthode facile de quantification des limitations des jeux de données utilisés pour estimer les descripteurs de structure et de dynamique forestière. Ceci est un prérequis indispensable à l'analyse des effets du changement global sur les forêts tropicales.
ISSN: 0006-3606

hal-01093212
https://hal-agroparistech.archives-ouvertes.fr/hal-01093212
DOI : 10.1111/j.1744-7429.2010.00644.x

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A reactive percolation experiment was conducted by injecting seawater into a permeable olivine aggregate at 190 °C and 19 MPa to explore the relationships between hydration reactions and hydrodynamic properties during the onset of serpentinization in the ultramafic lithosphere exposed at mid-ocean ridges. The experiment was stopped after 23 days when the sample became impermeable. The initial flow rate was 0.2 mL/h and then was decreased down to 0.06 mL/h after 8 days. Permeability decreased continuously throughout the experiment. The analyses of fluid chemistry time series and of the mineralogy and structure of the reacted sample showed olivine dissolution and precipitation of proto-serpentine, brucite and Fe-oxides. These reactions are controlled by coupled hydrodynamic and chemical processes interacting at different time and spatial scales. Their first characteristic is the production of silica rich outlet fluids in disequilibrium with the observed reacted mineral assemblages. These compositions are interpreted as resulting from a suite of coupled dissolution-precipitation reactions, controlled at the pore scale by surface kinetic processes, that rapidly reaches steady-state (constant fluid composition independent of fluid flux). Hence, the effective rate of serpentinization was controlled, to the first order, by the transport of reactants during the experiment. Mass balance calculations show that the rate of olivine conversion was fast (0.2-0.5 wt%/day), yet only ∼8 wt% of the olivine sample reacted, because the permeability drop limited fluid circulation. Porosity varied little during the experiment compared to permeability changes: the decrease of permeability was explained by the structure of the newly formed serpentine favouring the clogging of fluid paths. The rate at which permeability decreased was the fastest at low flux conditions. This suggests that permeability changes were not controlled simply by the kinetics of the serpentinization reactions, but mainly reflected the development of low Peclet pore scale zones forming micro-environments that control the serpentinization reaction-paths. These results outline the need to take into account the coupling of hydrodynamic and chemical processes when modelling the effects of reactive transport within the hydrating oceanic lithosphere.
ISSN: 0012-821X

hal-00855043
https://hal.archives-ouvertes.fr/hal-00855043
DOI : 10.1016/j.epsl.2013.03.052

Éditeur(s) : HAL CCSD Elsevier
Résumé : This study analyzes the records of several trace metals sensitive to redox conditions in continental shelf sediments off Concepcion, Chile (36 degrees S). The continental margin off Concepcion (36 S; 73 W) lies beneath an important upwelling center characterized by high primary production rates and, consequently, high fluxes of organic matter. In spring and summer, this material settles to the seafloor where it decays, producing periods of very low oxygen content in bottom waters (<1 mL L-1). In addition, an oxygen minimum zone develops at similar to 100-400 m water depth, where dissolved oxygen levels are <0.5 mL L-1. This situation changes during strong El Nino events, when dissolved oxygen at the bottom increases drastically (>1 mL L-1).;The goals of this study were to determine the input of trace metals to the sediment and to decipher how this information can be used to reveal variations in primary productivity or bottom oxygenation. Gravity cores collected at two stations - VG06-2 over the mid-shelf station (88 m water depth, upper boundary of the oxygen minimum zone) and VG06-3 over the outer shelf (120 m water depth, within the oxygen minimum zone) - were sampled for high resolution profiles (1 cm) of trace metals, biogenic opal, stable isotopes, and total organic carbon. The results suggest that the variability in the trace metal distribution on the continental shelf off Concepcion is determined by redox conditions and the organic carbon flux to the bottom. Some sections of the sediment cores from the outer shelf showed appreciable authigenic enrichment of U, Cd, and Mo (EF: 5-10, 2-5, and 10-16 respectively) along with heavier values of delta N-15, suggesting periods of suboxic conditions. During these periods, fluxes of organic material to the bottom were higher, as indicated by elevated TOC and opal contents. Alternating periods of higher and lower trace metal contents were not observed mid-shelf as they were on the outer shelf. Rather, the mid-shelf samples showed authigenic enrichment of U, Cd, and Mo (EF: 1-6, 4-5, and 10-20, respectively) throughout the core except in a 10-cm-thick gray layer. In general, authigenic enrichment of U. Mo, and Cd occurred at both sites, coincident with olive green layers in the cores. These layers were associated with periods of elevated primary productivity and suboxic conditions. Such periods did not seem to last as long as the oxygenated periods, which had higher inputs of refractive detrital material, coincident with the occurrence of distinct gray sediment layers.
ISSN: 0079-6611

hal-00682159
https://hal.archives-ouvertes.fr/hal-00682159
DOI : 10.1016/j.pocean.2011.07.010

Éditeur(s) : Université de la Rochelle
Résumé : In order to better understand the functioning of the Brouage intertidal mudflat (Marennes- Oléron Basin, France), its carbon-based trophic web has been modelled and analyzed. The foodweb building is based on the 4 step method of Inverse Analysis: 1) conceive an a priori model as the graph of compartments (nodes) between which exist fluxes of material (vertices). These vertices are the unknowns for the problem; 2) gather all the existing knowledge about the ecosystem and translate it into linear equations and inequalities involving the fluxes; 3) complete this set of data by common knowledge on the behaviour of the compartments and translate it into inequalities, 4) solve the obtained linear system under the parsimony principle to find a unique solution vector. The food-web analysis is based on. The first purpose of this work was a methodological one: inverse analysis method has been adapted to consider the seasonal and spatial variability of the temperate ecosystem: two seasons have been coupled in the computation and the area has been divided into three geographical zones along a cross-shore gradient. Hence, two types of physical exchanges are involved: the benthicpelagic ones and the advection ones. Statistical results can also be obtained by coupling Monte Carlo methods to Inverse Analysis. To study the obtained networks, new indices based on Markov Chains take delay into account in describing integrative transfers of material between compartments. This lets emerge the systems' properties that are not obvious at first sight and emphasizes the role of peculiar components. The second purpose was to apply such methods to the Brouage mudflat ecosystem in order to better understand its functioning. As the knowledge and methods evolve, various food webs were computed and analyzed with the help such indices and existing ones. Sensitivity analyses allow to point at the most crucial lacks of knowledge, which can orientate future field research. New data would improve the quality of the model in two ways: one the one hand, they would validate or invalidate the outcomes and on the other hand, they would give useful information to better constrain some of the black boxes and most uncertain fluxes, especially the advection and vertical flows. The main results of the study show a strongly seasonal system in which benthic and pelagic components are linked with intensity. The system is driven by its high local benthic primary production, but also depends on imports from the basin. Each of the 3 geographic zones has a peculiar functioning. The central zone corresponds to the classical description of European intertidal mudflats: very productive, it can feed the other regions. It is a production zone. The upper part is less productive but is fed by the middle one via the water column and can be exploited by shorebirds. It is a degradation zone (material is transformed for less qualitative). The lower part strongly depends on the basin imports for its functioning, as the cultivated bivalves act as a pump for pelagic material of which a great part is deposited under the cultivation structures (oyster racks or mussels "bouchots"). It is a transformation zone.
Un double objectif (méthodologique et appliqué) a été visé par une modélisation du réseau trophique de la vasière de Brouage (Bassin de Marennes Oléron, France) à l'aide de l'analyse inverse, et son étude à l'aide de l'analyse des réseaux. L'Analyse Inverse permet en effet de reconstruire l'ensemble du réseau à partir de données éparses, le problème du manque de données étant récurrent en Ecologie. Au plan méthodologique, l'analyse inverse a été adaptée à la prise en compte des caractères saisonnier et spatialement hétérogène d'un écosystème tempéré de zone intertidale : deux saisons ont ainsi été couplées et la vasière a été considérée le long d'un transect perpendiculaire au rivage et divisé en trois zones spatiales. Deux types de flux physiques interviennent donc : les flux verticaux de dépôt et remise en suspension, et les flux d'advection via la colonne d'eau. Des pistes d'amélioration et de nouvelles méthodes sont proposées. Un résultat sous forme statistique peut être obtenu en couplant l'utilisation de méthodes de Monte Carlo à l'analyse inverse pour la construction des réseaux trophiques. Les moyens d'étude des modèles ont été enrichis par la mise au point d'indices issus de la construction de chaînes de Markov et prenant en compte le caractère temporel des transferts de matière entre compartiments. Enfin, la transformation mathématique du modèle statique pour une étude dynamique de la stabilité de l'équilibre décrit est abordée. Plusieurs modèles ont été construits au cours de l'évolution des méthodes et de l'acquisition de connaissances sur le site. Des méthodes d'analyses existantes et d'autres mises au point dans le cadre de cet ouvrage ont été appliquées aux réseaux obtenus afin de faire émerger les propriétés du fonctionnement de la vasière et de souligner le rôle de certains compartiments. Des analyses de sensibilité permettent d'évaluer la robustesse des résultats et d'orienter les recherches futures en mettant en évidence les manques les plus cruciaux. Des données supplémentaires, notamment concernant les foraminifères benthiques, le zooplancton ou les mouvements verticaux du microphytobenthos permettront de fournir de meilleures contraintes et de valider (ou non) les résultats obtenus. Les principaux résultats montrent un système au fort caractère saisonnier dont les compartiments benthiques et pélagiques sont très liés. La production primaire benthique locale est un moteur important, mais qui ne suffirait pas à suppléer l'indispensable importation de matériel détritique. Le découpage de la vasière en trois zones fait apparaître les particularités de chacune. La zone centrale correspond à la description classique des « vasières intertidales européennes » : très productive, elle peut alimenter les autres régions. C'est une zone de production et d'exportation. La partie supérieure est moins productive et reçoit de la matière de la zone de milieu d'estran via la colonne d'eau. Sa production secondaire peut alors être exploitée par les limicoles, nombreux en hiver. C'est une zone de dégradation et d'exportation. Le bas d'estran dépend fortement des importations extérieures, « pompées » par les bivalves cultivés qui sont ainsi directement responsables d'une forte sédimentation sous les structures mytilicoles et ostréicoles. C'est une zone de transformation.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/2005/these-2260.pdf
http://archimer.ifremer.fr/doc/00000/2260/

Éditeur(s) : Elsevier Science Bv
Résumé : Mechanisms controlling the transfer and retention of silicon (Si) along continental margins are poorly understood, but play a major role in the functioning of coastal ecosystems and the oceanic biological pump of carbon. Deep-sea fans are well recognized as carbon sink spots, but we lack knowledge about the importance of the fans in the global Si cycle. Here, we provide a first estimate of the role played by the Congo deep-sea fan, one of the biggest in the world, in the Si cycle. Sediment cores sampled in the deep-sea fan were analyzed to build a Si mass balance. An exceptionally high accumulation rate of amorphous silica aSiO(2) (2.29 +/- 0.58 mol Si m(-2) y(-1)) was found, due to a high sedimentation rate and the presence of aluminum in the sediments. Although favored by bioirrigation, recycling fluxes remained low (0.3 mol Si m(-2) y(-1)) and reconstructed input fluxes could only be explained by lateral inputs coming from the canyon. Preliminary calculations show that the rapid transport of aSiO(2) through the canyon and the excellent preservation efficiency in the sediments imply that 50% of aSiO(2) river inputs from the Congo River accumulate annually in the deep-sea fan. Si:C ratios in deep-sea fan sediments were very low (0.2) and only three times as high as those measured in the river itself, which suggests that material from the river and the continental shelf was delivered directly through the canyon, with very little time for Si and C cycle decoupling to take place.
Journal Of Marine Systems (0924-7963) (Elsevier Science Bv), 2015-01 , Vol. 141 , P. 71-79

Droits : 2014 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/00251/36242/35797.pdf
DOI:10.1016/j.jmarsys.2014.07.010
http://archimer.ifremer.fr/doc/00251/36242/

Éditeur(s) : HAL CCSD
Résumé : International audience
A long standing debate in biochemistry is to determine whether the conformational changes observed during biomolecular interactions proceed through conformational selection (of preexisting isoforms) or induced fit (ligand-induced 3D reshaping). The latter mechanism had been invoked in certain circumstances, for example to explain the non-Michaelian activity of monomeric enzymes like glucokinase. But the relative importance of induced fit has been recently depreciated in favor of conformational selection, assumed to be always sufficient, predominant in general and in particular for glucokinase. The relative contributions of conformational selection and induced fit are reconsidered here in and out of equilibrium, in the light of earlier concepts such as the cyclic equilibrium rule and the turning wheel of Wyman, using single molecule state probability, one-way fluxes and net fluxes. The conditions for a switch from conformational selection to induced fit at a given ligand concentration are explicitly determined. Out of equilibrium, the inspection of the enzyme states circuit shows that conformational selection alone would give a Michaelian reaction rate but not the established nonlinear behaviour of glucokinase. Moreover, when induced fit and conformational selection coexist and allow kinetic cooperativity, the net flux emerging in the linkage cycle necessarily corresponds to the induced fit path. © 2016 Elsevier B.V. and Société Française de Biochimie et Biologie Molé
Biochimie

hal-01367150
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01367150
DOI : 10.1016/j.biochi.2016.06.012

Éditeur(s) : Taylor & Francis Ltd
Résumé : A new method is developed to estimate daily turbulent airsea fluxes over the global ocean on a 0.25 degrees grid. The required surface wind speed (w(10)) and specific air humidity (q(10)) at 10m height are both estimated from remotely sensed measurements. w(10) is obtained from the SeaWinds scatterometer on board the QuikSCAT satellite. A new empirical model relating brightness temperatures (T-b) from the Special Sensor Microwave Imager (SSM/I) and q(10) is developed. It is an extension of the author's previous q(10) model. In addition to T-b, the empirical model includes sea surface temperature (SST) and airsea temperature difference data. The calibration of the new empirical q(10) model utilizes q(10) from the latest version of the National Oceanography Centre airsea interaction gridded data set (NOCS2.0). Compared with mooring data, the new satellite q(10) exhibits better statistical results than previous estimates. For instance, the bias, the root mean square (RMS), and the correlation coefficient values estimated from comparisons between satellite and moorings in the northeast Atlantic and the Mediterranean Sea are 0.04gkg(1), 0.87gkg(1), and 0.95, respectively. The new satellite q(10) is used in combination with the newly reprocessed QuikSCAT V3, the latest version of SST analyses provided by the National Climatic Data Center (NCDC), and 10m air temperature estimated from the European Centre for Medium-Range Weather Forecasts (ECMWF) reanalyses (ERA-Interim), to determine three daily gridded turbulent quantities at 0.25 degrees spatial resolution: surface wind stress, latent heat flux (LHF), and sensible heat flux (SHF). Validation of the resulting fields is performed through a comprehensive comparison with daily, in situ values of LHF and SHF from buoys. In the northeast Atlantic basin, the satellite-derived daily LHF has bias, RMS, and correlation of 5Wm(2), 27Wm(2), and 0.89, respectively. For SHF, the statistical parameters are 2Wm(2), 10Wm(2), and 0.94, respectively. At global scale, the new satellite LHF and SHF are compared to NOCS2.0 daily estimates. Both daily fluxes exhibit similar spatial and seasonal variability. The main departures are found at latitudes south of 40 degrees S, where satellite latent and sensible heat fluxes are generally larger.
International Journal Of Remote Sensing (0143-1161) (Taylor & Francis Ltd), 2013-07 , Vol. 34 , N. 14 , P. 5243-5261

Droits : 2013 Taylor & Francis
http://archimer.ifremer.fr/doc/00137/24825/23575.pdf
DOI:10.1080/01431161.2013.787502
http://archimer.ifremer.fr/doc/00137/24825/