Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Mid-ocean ridge basalt (MORB) is the most abundant magma on Earth, and provides a geochemical window into the mantle. Deriving mantle composition and melting processes from the erupted lavas requires correction to be made for their evolution as they pass through and generate the oceanic crust. This is typically done by assuming that modification of melts in crustal magma chambers occurs exclusively by fractional crystallisation. However, extensive mineral major- and trace element data from a full section of fast-spread lower crustal rocks exposed in Hess Deep (equatorial Pacific Ocean) demonstrate that their evolution is instead controlled by reactive porous flow. These reactions lead to a strong enrichment in, and fractionation of, incompatible trace elements in the melt (as recorded by clinopyroxene compositions), leading to melt compositions far outside of the compositional realm of MORB both in terms of trace element abundances and ratios. The reactive signature increases in strength up section, peaking in varitextured gabbros interpreted to represent the fossilised axial melt lens, indicating that reactive porous flow occurred on the scale of the entire lower crust. The enrichment of the melt is coupled with a strong trace element depletion of plagioclase, olivine, and, to a lesser extent, clinopyroxene cores, suggesting that these phases represent the residues of the reactions from which trace elements have been removed. The dominant role of reactive porous flow, and the resulting deviations from fractional crystallisation predictions, suggest that the lower oceanic crust plays a much more complex and significant role in modifying the compositions of MORB than previously expected, with consequent implications for models of mantle processes.
ISSN: 0012-821X

hal-00814075
https://hal.archives-ouvertes.fr/hal-00814075
DOI : 10.1016/j.epsl.2012.11.012

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report new data on the geochemical evolution, metasomatic and deformation processes in the lower layers of cratonic lithospheric mantle based on a detailed study of extraordinarily fresh and large deformed peridotite xenoliths from the Udachnaya kimberlite pipe, Siberia. Based on our T-P estimates, the deformed peridotites are localized in a depth range of 170 to 220 km near the base of cratonic mantle. The degree of deformation is not correlated with the depth and equilibration temperatures of the xenoliths. The deformed peridotites are depleted in magmaphile major elements indicating their residual nature, but are enriched in incompatible trace elements, Fe and K. The deformed peridotites experienced a complex evolution, i.e., they were formed initially as high-degree melt extraction residues and later were subjected to three main stages of metasomatic modification. (1) An old, mostly cryptic metasomatism by melt/fluid of carbonatitic composition, which formed garnets with sinusoidal REE patterns (Smn/Ern > 1). (2) Silicate metasomatism, which led to the most significant changes in mineralogical and chemical composition of the deformed peridotites. (3) Fe and Ti metasomatism just before the entrainment of the deformed rocks into kimberlite magma. Enrichment of the peridotites in large-ion lithophile elements (K, Rb, Ba) is related to the formation of kelyphitic rims around garnet. The nature of the metasomatic agent of silicate metasomatism was evaluated from mass-balance of measured and calculated whole-rock compositions, ratios of highly incompatible elements (D < 0.1) and fractional crystallization modeling. All this evidence indicates that the agent of silicate metasomatism had a composition intermediate between that of kimberlites and HIMU OIB. The metasomatic processes responsible for the formation of deformed peridotites and precipitation of megacryst suites cannot be widespread at the base of the cratonic mantle. Rather, they are local features only existing in the cratonic mantle below kimberlite fields and localized along the metasomatic vein system.
ISSN: 0024-4937

hal-00941010
https://hal.archives-ouvertes.fr/hal-00941010
DOI : 10.1016/j.lithos.2012.11.014

Éditeur(s) : HAL CCSD
Résumé : A section of ancient fast-spreading ocean crust was sampled at Wadi Gideah, located in the Wadi Tayin Massif of the Oman ophiolite. This sample suite was used for generating a coherent data set combining various petro-geochemical and structural investigations, with the aim of building a reference section for advancing our understanding of crustal accretion processes at fast-spreading mid-ocean ridges. Additionally, this study focuses on one outcrop that represents part of the fossil axial melt lens (AML).Major and trace element analyses reveal a trend of chemical evolution up section in the lower crust, with a marked difference between the layered gabbros and the foliated gabbros above. Petrological modeling shows that the chemical evolution up section can be produced by hydrous fractionation crystallization, with melt H2O contents of ~0.8 wt% and 0.8 to 1.2 wt% for the lower and upper crust, respectively. Together with the observed very steep bulk Zr/Hf vs. Zr gradient, high F and Cl content of magmatic amphibole, general Nb-Ta depletion of melts compared with NMORB, and high Sr87/Sr86 ratio compared with modern fast-spread crust, this suggests that Wadi Gideah layered gabbros were accreted by crystallization of ascending melts in sills, in a context of subduction initiation. The distinct changes in chemical trends and average grain size at the layered to foliated gabbro transition are tentatively explained by enhanced hydrothermal cooling deeper than the AML. The gabbro/dike transition displays complex structural and lithological relationships that, together with fractional crystallization modeling, point to episodic vertical movements of the AML. Plagioclase crystallographic preferred orientations (CPO) measured over the whole gabbro section are always consistent with magmatic flow. The CPO strength generally increases downward, with more scattering in the layered gabbro section. From the top to the bottom of the layered gabbros, CPO become progressively more prolate, possibly reflecting increasing shear induced by active mantle flow underneath.Wadi Gideah lower crust recorded a formation history consistent with a hybrid accretion model, combing several processes such as downward magmatic flow and/or upward melt migration in the upper foliated gabbros, sill intrusions in the layered gabbros, and deep hydrothermal circulation. The latter was presumably focused in channels, preserved today as several, up to 100 m wide zones of extensively altered former layered gabbro, cross-cutting the magmatic layering. These metagabbros display significantly higher Sr87/Sr86 ratio, late stage magmatic phases, and evidence for high temperature partial melting.
Une coupe d'ancienne croute océanique rapide a été échantillonnée dans le Wadi Gideah, situé dans le Massif de Wadi Tayin de l'Ophiolite d'Oman. Cette série d'échantillons a permis de générer un jeu de données cohérent, combinant des études pétro-géochimiques et structurales, dans le but de construire une coupe de référence pour mieux contraindre notre compréhension des processus d'accrétion crustale aux dorsales océaniques rapides. Ce travail intègre aussi l'étude détaillée d'un affleurement représentant en partie la lentille magmatique axiale (LMA) fossile.Les analyses d'éléments majeurs et traces révèlent une évolution chimique dans la croûte inférieure, avec une nette différence entre les gabbros lités et les gabbros foliés sus-jacents. La modélisation pétrologique montre que l'évolution chimique vers le haut peut être produite par cristallisation fractionnée hydratée, avec des teneurs en H2O des magmas de ~0.8 wt% dans la croute inférieure et 0.8 to 1.2 wt% dans la croute supérieure. Combiné aux forts gradients de Zr/Hf vs. Zr, aux teneurs élevées de F et Cl dans les amphiboles magmatiques, à l'appauvrissement général en Nb-Ta des magmas comparé aux NMORB, et aux rapports Sr87/Sr86 élevés comparés à la croûte rapide moderne, ceci suggère que les gabbros lités du Wadi Gideah ont été formés par la cristallisation des magmas ascendants dans des sills, dans un contexte d'initiation de subduction. Les changements de signature géochimique et de taille de grain à la transition entre gabbros lités et gabbros foliés témoignent possiblement d'un fort refroidissement hydrothermal plus profond que la LMA. La transition complexe filonien/gabbro montre des relations structurale et lithologiques complexes, qui, combinées o la modélisation de la cristallisation fractionnée, traduisent les mouvements verticaux épisodiques de la LMA. Les orientations préférentielles cristallographiques (OPC) des plagioclases mesurées sur l'ensemble de la coupe dans les gabbros témoignent toujours d'une déformation magmatique. L'intensité des OPC a tendance à augmenter vers le bas, avec une plus forte variabilité dans les gabbros lités. Dans les gabbros lités, les OPC sont de plus en plus linéaires vers le bas, résultant possiblement d'un cisaillement plus fort induit par l'écoulement actif du manteau sous-jacent.La croûte inférieure dans le Wadi Gideah a enregistré une histoire compatible avec un modèle d'accrétion hydride, combinant plusieurs processus tels que l'écoulement magmatique vers le bas et/ou la migration de liquides magmatiques vers le haut dans les gabbros foliés supérieurs, l'intrusion de sills dans les gabbros lités, et une circulation hydrothermale profonde. Cette dernière était probablement concentrée dans des chenaux, préservés aujourd'hui sous la forme de plusieurs zones, dont l'épaisseur atteint 100 m, de gabbros lités fortement altérés, recoupant le litage magmatique. Ces métagabbros ont des rapports Sr87/Sr86 élevés, comportent des phases magmatiques tardives et montrent des évidences de fusion partielle.
https://hal.archives-ouvertes.fr/tel-01302675

tel-01302675
https://hal.archives-ouvertes.fr/tel-01302675
https://hal.archives-ouvertes.fr/tel-01302675/document
https://hal.archives-ouvertes.fr/tel-01302675/file/Th%C3%A8se_Tim-Mueller_2015.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Serpentinites are one of the major components of the oceanic lithosphere and are stable in the slab and the mantle wedge up to 100-150 km depth in subduction zones. During oceanic mantle hydration and alteration, they trap trace and fluid mobile (FME: B, Li, As, Sb, Rb, Ba, Cs, Sr, U and Pb) elements that participate to elemental transfer occurring between the dehydrating slab and the mantle wedge in subduction context. The Lanzo massif is an eclogitized oceanic lithosphere that preserved its oceanic structure and recorded different steps of serpentinization/de-serpentinization from oceanic lizardite to prograde antigorite in subduction context, up to its dehydration and secondary olivine crystallization, and finally retrograde antigorite during massif exhumation. It constitutes a suitable place to study trace element behavior during serpentinization/de-serpentinization processes and associated chemical transfers between the different envelopes of the oceanic lithosphere and the mantle wedge. Geochemical analyses of serpentine and associated minerals show that the serpentinization/de-serpentinization of the Lanzo massif took place in a relatively closed system without significant trace element transfer between the different parts of the oceanic lithosphere. In the deeper part of the lithosphere, from the slightly serpentinized mantle peridotites (SSP, < 20% serpentinization) to the paleo-Moho, composed of massive serpentinites (MS, 80% serpentinization), the trace elements mobility is reduced. The chemical composition of lizardite and antigorite is homogenized with the local degree of serpentinization: in SSP, serpentine veins composition is inherited from the host mineral while, in MS, their composition is homogenous between destabilized phases at the scale of the outcrop (~ 5 m). In the shallowest part of the oceanic lithosphere, from the paleo-Moho to the oceanic paleo-seafloor, the serpentinites are foliated (FS, > 90% serpentinization). In that zone, the alpine deformation enhances the mobility of trace elements and permits their redistribution and the homogenization of antigorite composition at massif scale. Locally, in the SSP and MS, the crystallization of metamorphic veins of ~ 1-2 m corresponds to channelized fluid flows that allowed fluid transfers - and thereby trace elements - to longer distance. The successive crystallizations of antigorite and then olivine are accompanied by a diminution of some FME (B, Li, As, Sb, Ba, Rb) and Eu contents attesting that these elements are removed from slab to mantle wedge during subduction.
ISSN: 0009-2541

hal-00937661
https://hal.archives-ouvertes.fr/hal-00937661
DOI : 10.1016/j.chemgeo.2013.08.025

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Serpentinites from subduction environments represent an important sink for fluid-mobile elements. In order to constrain geochemical behavior of fluid-mobile elements hosted by serpentine phases during subduction processes, we carried out a geochemical study (trace elements and Pb isotopes) of a series of serpentinites and cumulates from the accretionary wedge of Greater Caribbean (Cuba and Dominican Republic). The trace element compositions of the primary and alteration-related phases were analyzed in situ using LA-HR-ICP-MS techniques. The studied samples represent parts of the subducted proto-Atlantic oceanic lithosphere, which has experienced low to high grade metamorphism (greenschist to eclogite facies), before being exhumed; a subset of these samples were derived from the mantle wedge. This sampling provides the opportunity to trace the chemical mobility of fluid-mobile elements during prograde metamorphism along a cold geotherm in an oceanic subduction setting.
ISSN: 0009-2541

hal-00720895
https://hal.archives-ouvertes.fr/hal-00720895
DOI : 10.1016/j.chemgeo.2012.04.009

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Despite a relatively 'uniform' fertile composition (Al2O3 = 2 center dot 19-4 center dot 47 wt %; Fo% = 89 center dot 2 +/- 0 center dot 3%; Cr#(Spl) = 8 center dot 9 +/- 1 center dot 5%), the Montferrier peridotite xenoliths show a wide range of S contents (22-590 ppm). Most sulphides are interstitial and show peculiar pyrrhotite-pentlandite intergrowths and low abundances of Cu-rich phases. Sulphide-rich samples are characterized by strong enrichment in the light rare earth elements and large ion lithophile elements without concomitant enrichment of the high field strength elements. Such trace-element fractionation is commonly ascribed to metasomatism by volatile-rich melts and/or carbonatitic melts. S and Se (11-67 ppb), as well as S/Se (up to approximate to 12 000), are correlated with La/Sm. Cu, however, remains broadly constant (30 +/- 5 ppm). These features strongly suggest that the percolation-reaction of such volatile-rich fluids has led to sulphide enrichment with an atypical signature marked by strong fractionation of the chalcophile elements (i.e. S vs Se and Cu). S-rich xenoliths are also characterized by high (Pd/Ir)(N) (1 center dot 2-1 center dot 9; where subscript N indicates normalized to chondrite), (Pd/Pt)(N) between 1 center dot 5 and 2 center dot 2, and (Os/Ir)(N) up to 1 center dot 85. Despite the relative uniform fertile composition of the xenoliths, Re/Os ranges between 0 center dot 02 and 0 center dot 18. Os-187/Os-188 is extremely variable even within a single sample and can be as high as 0 center dot 1756 for the most S-rich samples. Sulphides show highly fractionated and variable abundances of the highly siderophile elements (HSE) [0 center dot 03 (Pd/Ir)(N) < 1283] and Re-Os isotopic composition (0 center dot 115 < Os-187/Os-188 < 0 center dot 172). Such variation can be observed at the thin-section scale. Whole-rock and in situ sulphide data demonstrate that chalcophile and HSE systematics and the Os isotopic composition of the upper mantle could be significantly modified through metasomatism, even with volatile-rich fluids. These features highlight the complex behaviour of the HSE in fluid-rock percolation-reaction models and suggest a complex interplay between sulphide addition (crystallization or sulphidation) and partial equilibration of pre-existing sulphide. The specific fractionations observed in chemical proxies such as S and Se, Os and Ir, and Pd and Pt, as well as the low abundance of Cu-rich sulphides, suggest that sulphide addition may not have occurred via sulphide melts. Rather, we infer that S was present as a dissolved species in a (supercritical) oxidizing, volatile-rich fluid (C-O-H-S +/- Cl) along with other chalcophile and siderophile elements such as Os, Pd, Re and Au. The highly radiogenic Os composition of this fluid ( Os-187/ Os-188 > 0 center dot 17) would imply that such fluids are derived from an uncommon type of mantle source possibly related to carbonatite melts.
ISSN: 0022-3530

hal-00644524
https://hal.archives-ouvertes.fr/hal-00644524
DOI : 10.1093/petrology/egr038

Éditeur(s) : HAL CCSD Ecological Society of America
Résumé : Reliable assessment of fish origin is of critical importance for exploited species, since nursery areas must be identified and protected to maintain recruitment to the adult stock. During the last two decades, otolith chemical signatures (or "fingerprints") have been increasingly used as tools to discriminate between coastal habitats. However, correct assessment of fish origin from otolith fingerprints depends on various environmental and methodological parameters, including the choice of the statistical method used to assign fish to unknown origin. Among the available methods of classification, Linear Discriminant Analysis (LDA) is the most frequently used, although it assumes data are multivariate normal with homogeneous within-group dispersions, conditions that are not always met by otolith chemical data, even after transformation. Other less constrained classification methods are available, but there is a current lack of comparative analysis in applications to otolith microchemistry. Here, we assessed stock identification accuracy for four classification methods (LDA, Quadratic Discriminant Analysis [QDA], Random Forests [RF], and Artificial Neural Networks [ANN]), through the use of three distinct data sets. In each case, all possible combinations of chemical elements were examined to identify the elements to be used for optimal accuracy in fish assignment to their actual origin. Our study shows that accuracy differs according to the model and the number of elements considered. Best combinations did not include all the elements measured, and it was not possible to define an ad hoc multielement combination for accurate site discrimination. Among all the models tested, RF and ANN performed best, especially for complex data sets (e. g., with numerous fish species and/or chemical elements involved). However, for these data, RF was less time-consuming and more interpretable than ANN, and far more efficient and less demanding in terms of assumptions than LDA or QDA. Therefore, when LDA and QDA assumptions cannot be reached, the use of machine learning methods, such as RF, should be preferred for stock assessment and nursery identification based on otolith microchemistry, especially when data set include multispecific otolith signatures and/or many chemical elements.
ISSN: 1051-0761

hal-00644549
https://hal.archives-ouvertes.fr/hal-00644549
DOI : 10.1890/09-1887.1

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
During compressive events, deformation in sedimentary basins is mainly accommodated by thrust faulting and related fold growth. Thrust faults are generally rooted in the basement and may act as conduits or barriers for crustal fluid flow. Most of recent studies suggest that fluid flow through such discontinuities is not apparent and depends on the structural levels of the thrust within the fold-and-thrust belt. In order to constrain the paleofluid flow through the Jaca thrust-sheet-top basin (Paleogene southwest-Pyrenean fold-and-thrust belt) this study compares on different thrust faults located at different structural levels. The microstructures in the different fault zones studied are similar and consist of pervasive cleavage, calcite shear veins (SV1), extension veins (EV1) and late dilatation veins (EV3). In order to constrain the nature and the source of fluids involved in fluid-rock interactions within fault zones, a geochemical approach, based on oxygen and carbon stable isotope and trace element compositions of calcite from different vein generations and host rocks was adopted. The results suggest a high complexity in the paleohydrological behaviors of thrust faults providing evidence for a fluid-flow compartmentalization within the basin. Previous studies in the southern part of the Axial Zone (North of the Jaca basin) indicates a circulation of deep metamorphic water, probably derived from the Paleozoic basement, along fault zones related to the major basement Gavarnie thrust. In contrast, in northern part of the Jaca basin, the Monte Perdido thrust fault is affected by a closed hydrological fluid system involving formation water during its activity. The Jaca and Cotiella thrust faults, in turn, both located more to the south in the basin, are characterized by a composite fluid flow system. Indeed, stable isotope and trace element compositions of the first generations of calcite veins suggest a relatively closed paleohydrological system, whereas the late calcite vein generations, which are probably associated with the late tectonic activity of the basin, support a contribution of both meteoric and marine waters. Based on these results, a schematic fluid-flow model is presented. This model allows visualization of three main fluid flow compartments along a N-S transect.
ISSN: 0264-8172

hal-00963606
https://hal.archives-ouvertes.fr/hal-00963606
DOI : 10.1016/j.marpetgeo.2013.09.005

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Orogenic lherzolites exhibit a specific (although reproducible) platinum-group element signature characterized by slight positive deviations of Pd/Ir, Rh/Ir and Ru/Ir ratios from the canonical chondritic model. Such a signature was alternatively considered to be a compositional feature of the primitive upper mantle or resulting from sulfide melt addition by refertilisation reactions in the continental lithosphere. To shed additional light on this conundrum, the distribution of PGE in FON B 93, an unserpentinized, fertile (3.24% Al2O3) orogenic lherzolite (French Pyrenees) used as in-house standard by our group, has been studied to different scales, from the bulk rock to trace minerals. In addition to new ICPMS analyses after separation into Nis and Te coprecipitation, its whole-rock PGE concentrations were redetermined by three different laboratories using very precise ID-ICP-MS methods after digestion of the sample in Carius tube at T=250 degrees C and 320 degrees C or in high-pressure asher (HPA-S). The four methods produce reproducible Ru, Rh and Pd contents (7.1 +/- 0.18 ppb; 1.43 +/- 0.05 ppb; 7.1 +/- 0.30 ppb) whereas the non-ID NiS-fire assay method underestimates the Os and Ir concentrations by c.a. 10 and 15% compared to ID-ICP-MS analyses (4.40 +/- 0.07 and 4.00 +/- 0.17 ppb, respectively). Platinum was the most difficult to analyse. If performed on powder aliquots smaller than 3 g, the ID-ICP-MS analyses generate strong nugget effects while the non-ID NiS-fire assay method yields statistically lower (but highly reproducible) Pt concentrations (6.92 +/- 0.26 ppb). These features reflect the strong partitioning of Pt into trace phases that SEM and laser ablation-ICP-MS analyses on thin sections identify as both high-temperature Pt-Ir-Os alloys and Pt-(Pd) tellurides of likely subsolidus origin; ten to fifteen grains ranging in maximum dimension from a few micrometres to a few hundreds of nanometers, were identified by standard polished thin section. LA-ICP-MS data on base metal sulfides (25 grains analysed), coupled with the whole-rock S concentration (277 +/- 10 ppm) and modal composition of the BMS (90% pentlandite+accessory pyrite and secondary pyrrhotite + 10% chalcopyrite) allowed the contribution of the BMS phase to the PGE budget of FON B 93 to be estimated. Except Pt that exhibits a 95% deficit in the BMS phase, the PGE concentrations measured by ID-ICP-MS can be balanced by BMS while Al-spinel is a negligible contributor, accounting for less than 0.5% of the Ru budget. The occurrence of Pt in trace phases may bias the whole-rock Pt concentrations because 1) mechanical collection of Pt-rich trace phases remains problematic with the Nis button, and 2) Pt-Ir-Os alloys may be prone to digestion problems in conventional Carius tube procedures. Since they could be stable at mantle depth, such refractory alloys that contain Os and Ir may also have enhanced the heavy PGEs/light PGEs fractionation. Our observations likely pertain to orogenic lherzolites as a whole because BMS assemblages in these mantle rocks record evolution at low sulfur fugacity, which prevents Pt-Ir-Os alloy from entering the Mss in the mantle; moreover, at subsolidus temperature, pentlandite, the major BMS, cannot accommodate 0 valence state Pt.
ISSN: 0009-2541

hal-00411486
https://hal.archives-ouvertes.fr/hal-00411486
DOI : 10.1016/j.chemgeo.2007.06.030

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Correlations between major and minor transition elements in tectonically emplaced orogenic peridotites have been ascribed to variable degrees of melt extraction and melt–rock reaction processes, leading to depletion or refertilization. To elucidate how such processes are recorded in the subcontinental lithospheric mantle, we processed a large geochemical dataset for peridotites from the four tectono-metamorphic domains of the Beni Bousera orogenic massif (Rif Belt, northern Morocco). Our study reveals that variations in bulk-rock major and minor elements, Mg-number and modal mineralogy of lherzolites, as well as their clinopyroxene trace element compositions, are inconsistent with simple partial melting and mainly resulted from different reactions between melts and depleted peridotites. Up to 30% melting at < 3 GPa and cryptic metasomatism can account for the geochemical variations of most harzburgites. In Grt–Sp mylonites, melting and melt–rock reactions are masked by tectonic mixing with garnet pyroxenites and subsolidus re-equilibration. In the rest of the massif, lherzolites were mostly produced by refertilization of a refractory protolith (Mg-number ∼ 91, Ol ∼ 70%, Cpx/Opx = 0·4) via two distinct near-solidus, melt–rock reactions: (1) clinopyroxene and orthopyroxene precipitation and olivine consumption at melt/rock ratios <0·75 and variable mass ratio between crystallized minerals and infiltrated melt (R), which are recorded fairly homogeneously throughout the massif; (2) dissolution of orthopyroxene and precipitation of clinopyroxene and olivine at melt/rock ratios ≤1 and R = 0·2–0·3, which affected mainly the Ariègite–Seiland and Seiland domains. The distribution of secondary lherzolites in the massif suggests that the first refertilization reaction occurred prior to the differentiation of the Beni Bousera mantle section into petro-structural zones, whereas the second reaction was associated with the development of the tectono-metamorphic domains. Our data support a secondary, refertilization-related origin for most lherzolites in orogenic peridotite massifs.
ISSN: 0022-3530

hal-01526901
https://hal.archives-ouvertes.fr/hal-01526901
DOI : 10.1093/petrology/egx003

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : International audience
We report here U-series and trace element data for an olivine-melilitite lava flow, erupted in 1957 in the Virunga volcanic field and known as the Mugogo eruption. Petrological and geochemical data show that the Mugogo magma represents a primary mantle melt, derived from a low degree of melting of a metasomatised mantle source. It is highly enriched in very incompatible trace elements (e.g. more than 300-fold compared to primitive mantle for Th), with a distinctly lower enrichment in Rb, Ba and Sr. The high Th/U and low (230Th/232Th) ratios (4.4 and 0.750, respectively, with a (230Th/238U) ratio of 1.09) are close to the values found for the Nyamuragira basanites. But the most striking feature is the very low (226Ra/230Th) ratio of 0.48, the lowest ever measured in a mafic volcanic rock. The most probable origin of this Ra deficit is the presence of phlogopite (having a high Ra partition coefficient) in the lithospheric mantle, either as a residual phase during low-degree isobaric melting (in batch-melting or a diffusion-controlled melting models), or in a phlogopite-bearing upper mantle through which the melt migrates and equilibrates (in an equilibrium porous flow model commonly used to describe adiabatic melting). The disequilibrium pattern (230Th) > (238U) > (210Pb) ≫ (226Ra), reversed compared to the pattern observed in the Oldoinyo Lengai natrocarbonatite, suggests that a carbonatite melt might have been involved to explain the Ra deficit. We thus discuss the possibility of an early separation of a Ra-enriched carbonate melt either from the olivine-melilitite melt or from a carbonated mantle source, followed by the production of a low-degree melt of olivine-melilitite composition, but the lack of available experimental, petrological and geochemical evidences makes this process somewhat speculative at present. Further studies of recent (<5 ky) olivine-melilitites are needed to check whether the large Ra deficit is a general characteristic of this type of magma that can be used to constrain models of its formation.
ISSN: 0010-7999

hal-01174173
https://hal.archives-ouvertes.fr/hal-01174173
DOI : 10.1007/s00410-015-1124-9

Éditeur(s) : Elsevier Science Bv
Résumé : Here we present a new geochemical study of Lopevi volcano, one the most active volcanoes in the Vanuatu island arc. We focus on the temporally well-defined sequence of lava flows emitted since 1960, and for the first time, on pre-1960 volcanic products, including high-MgO basalts and felsic andesites, the most evolved lavas sampled so far on this island. This work reports the first Pb and Hf isotopic study of lavas from Lopevi island. These lavas display correlations between differentiation indexes such as SiO2 content and isotopic ratios. The felsic andesites extend the known correlations with both the least (Sr-Pb) and the most (Nd-Hf) radiogenic isotopic compositions on the island. Our results confirm that the rising magma interacted with the sub-arc crust. Assimilation-Fractional Crystallization (AFC) quantitative modeling of trace element ratios and isotopic compositions requires 1% and 10% of assimilated partial melts of a mafic oceanic crust to account for the pre- and post-1960 lavas, respectively. The post-1960 lavas differ from the former lavas emitted similar to 20 years earlier by enrichments in fluid mobile elements (K, Ba, Rb ... ), Th, and Light Rare Earth Elements (LREE). We ascribe these features to slight variations in the metasomatic agent added to the sub-arc mantle and ultimately derived from the subducted lithosphere. However, the contrasting time scales involved in subducted lithosphere dehydration and magma genesis, relative to the time elapsed between eruptions of the two lava series, suggest that two different portions of mantle which have undergone slightly different metasomatism, gave birth to the Lopevi lavas. These distinct magmas are still present beneath the volcano.
Journal Of Volcanology And Geothermal Research (0377-0273) (Elsevier Science Bv), 2013-08 , Vol. 264 , P. 72-84

Droits : 2013 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/00167/27801/26223.pdf
DOI:10.1016/j.jvolgeores.2013.07.005
http://archimer.ifremer.fr/doc/00167/27801/

Éditeur(s) : HAL CCSD Elsevier
Résumé : Differentiation of the Earth's mantle and formation of continental and oceanic crust occur principally through partial melting and extraction of basaltic melt. Among the mantle rocks occurring at the Earth's surface, as tectonically-emplaced massifs, abyssal peridotites or xenoliths, the harzburgites (< 5% clinopyroxene) are widely considered as refractory mantle residues left after extraction of a basaltic component. In contrast, the most fertile lherzolites (15% clinopyroxene) are generally regarded as pristine mantle, only weakly affected by partial melting. In this paper we present new convergent structural and geochemical data from the Lherz massif, the type-locality of lherzolite, indicating that the lherzolites from Lherz do not represent pristine mantle. Detailed structural mapping clearly shows that the lherzolites are secondary rocks formed at the expense of the harzburgites. Variations of major, minor and trace elements through the harzburgite–lherzolite contacts indicate that the lherzolites were formed through a refertilization process involving interaction of refractory, lithospheric mantle with upwelling asthenospheric partial melts. Combined with previously published indications of refertilization in orogenic peridotites, our new observations in Lherz suggest that most lherzolite massifs represent secondary (refertilized) rather than pristine mantle. Together with geochemical data on mantle xenoliths, this indicates that melt transport and melt-rock reaction play a key role on the rejuvenation and erosion of the lithospheric mantle.
ISSN: 0012-821X

hal-00406433
https://hal.archives-ouvertes.fr/hal-00406433
DOI : 10.1016/j.epsl.2007.05.026

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
High-grade migmatitic and mylonitic gneisses from the Day Nui Con Voi massif in northern Vietnam record temperatures of 760-810 °C at pressures of 6-10 kbars. High temperature conditions have resulted in the development of major element diffusional profiles in garnet. Laser ablation ICP-MS analyses of trace elements indicate that REE and Hf closely followed Rayleigh-like fractionation trends but underwent significant post-crystallization modification. Light REE and to a lesser extent, HREE rim-to-rim zonation profiles show progressive flattening with the decreasing garnet size. Nd and Sm are completely homogenized in the crystals smaller than 1.5 mm, while Lu always preserves variable degrees of core-to-rim concentration gradient. The observed REE patterns are interpreted as resulting from the combination of protracted garnet growth of progressively smaller crystals and intracrystalline diffusion. This had profound influence on Sm-Nd geochronology and resulted in isochron ages ranging from 50 to 32 Ma. The youngest age was obtained for a sample, where all garnet crystals are smaller than 2 mm in which light REE profiles are completely or nearly completely homogenized. Thus, only the youngest age represents geologically meaningful event, and 31.7 ± 0.9 Ma age is interpreted as the best estimate of the resetting episode due to high temperature diffusional homogenization of light REE during early Oligocene metamorphism. Older Sm-Nd ages reflect mixed analyses of variably reset individual garnet crystals. Lu-Hf isotopic analyses of bulk garnet fractions, despite yielding high parent/daughter isotopic ratios appeared very scattered and did not allow defining isochron ages. Instead, apparent ages defined by whole rock and individual garnet fractions range from c. 80 to 160 Ma. Very old apparent ages are interpreted as being the consequence of intracrystalline Lu diffusion and preservation of the original Hf distribution, which leads to lower 176Lu/177Hf ratios, and thus steeper (older) isochrons. Back diffusion of Lu during commonly observed resorption played a subordinate role in modifying isotope systematics.
ISSN: 0009-2541

hal-00813949
https://hal.archives-ouvertes.fr/hal-00813949
DOI : 10.1016/j.chemgeo.2012.04.024

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The processes active in the deep crust above an oceanic subduction zone during its evolution have been constrained through a detailed geochemical study (major and trace elements and Sr, Nd and Pb isotopes) of representative samples through an 30 km thick exhumed crustal section of the Cretaceous Kohistan oceanic island arc (Northern Pakistan). The use of both trace elements and radiogenic isotopes reveals two distinct geochemical suites (suites A and B) within the JijalPatanKiruKamila (JPKK) complex. Suite A is characterized by a progressive enrichment in Pb-207 and a decrease in Nd-143/Nd-144 with increasing La-N/Sm-N. Suite B has higher Pb-207/Pb-204 and lower Nd-143/Nd-144 ratios with approximately constant La-N/Sm-N. By combining trace elements with different partitioning behaviour it is demonstrated that there is an increasing contribution of the subduction component in the magmas with time. It is also possible to distinguish a slab component imprint carried by aqueous fluids from one corresponding to sediment melts. Intrusive granites are abundant in the upper levels of the JPKK section. All were generated at the arc root level (Jijal crustal section) during dehydration-melting of hornblende-rich plutonic rocks. A three-stage geodynamic model is proposed for the evolution of the arc over a period of 30 Myr. The first stage (117105 Ma) starts with the onset of subduction, which was followed by the building of the volcanic arc. The second stage (10599 Ma to 9691 Ma) corresponds to a major igneous event, which was characterized by abundant magma underplating and granulite-facies metamorphism at the arc base. Recycling of the residualcumulative lower crust into the convective asthenospheric mantle was efficient during this stage, and was probably related to thermo-mechanical erosion of the base of the crust. The last stage (9585 Ma) corresponds to a period of low magmatic activity, which marked the end of the intra-oceanic subduction. This is related to the formation of a cold blanket above the slab surface as a result of thermo-mechanical erosion of the cold walls of the subduction zone (i.e. the upper part of the slab and the base of the overriding plate), and corner flow dragging the cold material into the zone of melt generation. Ultimately, a voluminous magmatic pulse occurred around 85 Ma (forming the Chilas complex), before arccontinent collision.
ISSN: 0022-3530

hal-00420068
https://hal.archives-ouvertes.fr/hal-00420068
DOI : 10.1093/petrology/egp010

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : The Oman ophiolite consists of several massifs cropping out along a 500 km long band trending NW-SE along the coast of Oman; it is one of the best exposed sections of oceanic crust and mantle in the world. There is a gradient in igneous processes and composition in the ophiolite, with the northern massifs recording a polygenetic igneous history involving an increasingly important subduction component, whereas the southern massifs were formed primarily via a mid-ocean ridge basalt (MORB)-like, single-stage process at a submarine spreading ridge. In this study we use geochemical data from Wadi Tayin, which is one of the southern massifs of the Oman ophiolite, to constrain the composition and genesis of oceanic crust and upper mantle. The Wadi Tayin harzburgites are residues of partial melting that are as depleted as the most depleted mid-ocean ridge peridotites. They have low middle- to heavy rare earth element ratios, most probably reflecting melting close to and beyond the exhaustion of clinopyroxene. Like many abyssal peridotites, the Wadi Tayin samples show enrichment in highly incompatible elements, giving rise to U-shaped MORB-normalized trace element patterns. We favor the idea that this is caused by enrichment of highly incompatible elements along grain boundaries in peridotite, which may be the result of near-equilibrium partitioning between grain boundaries and grain interiors, rather than disequilibrium processes. Equilibrium partitioning between crystals and grain boundaries during melting and melt extraction is also our preferred explanation for ubiquitous high Pb contents relative to Ce and La in our samples as well as in most abyssal peridotites. The Wadi Tayin samples record substantial variability in terms of osmium isotopic composition and platinum group element (PGE) concentrations. The more radiogenic nature of the dunites and impregnated peridotites compared with the residual harzburgites may be due to relatively high Os-187/Os-188 in melt transported through the dunites. The presence of residual peridotites with whole-rock osmium isotopic compositions less radiogenic than MORB may be explained by melting of a veined (upwelling) mantle forming mixed melts in which much of the Os derives from veins with high Re/Os in a matrix of previously depleted peridotite. An important result of this study is that the shallowest samples are refertilized (i.e. anomalously enriched in incompatible elements), and record relatively high metamorphic closure temperatures. These observations suggest that migrating melt underwent crystallization during rapid cooling in the uppermost mantle during and immediately after ridge magmatism. A variety of geothermometers all yield the result that the stratigraphically highest harzburgites equilibrated at higher temperature than the deeper ones. The systematic decrease in closure temperature with increasing depth below the Moho transition zone probably reflects systematic variation in cooling rate as a function of depth in the mantle section. We hypothesize that the refertilization and higher closure temperatures recorded by the uppermost mantle samples are linked. More rapid cooling led to higher closure temperatures, and to partial crystallization of migrating melts in the shallowest part of the mantle section, yielding slightly elevated abundances of elements such as Ca and Na, and incompatible trace elements.
ISSN: 0022-3530

hal-00456056
https://hal.archives-ouvertes.fr/hal-00456056
DOI : 10.1093/petrology/egp077

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
IODP Hole U1309D (Atlantis Massif, Mid-Atlantic Ridge 30 degrees N) is the second deepest hole drilled into slow spread gabbroic lithosphere. It comprises 5.4% of olivine-rich troctolites (->70% olivine), possibly the most primitive gabbroic rocks ever drilled at mid-ocean ridges. We present the result of an in situ trace element study carried out on a series of olivine-rich troctolites, and neighbouring troctolites and gabbros, from olivine-rich intervals in Hole U1309D. Olivine-rich troctolites display poilkilitic textures; coarse-grained subhedral to medium-grained rounded olivine crystals are included into large undeformed clinopyroxene and plagioclase poikiloblasts. In contrast, gabbros and troctolites have irregularly seriate textures, with highly variable grain sizes, and locally poikilitic clinopyroxene oikocrysts in troctolites. Clinopyroxene is high Mg# augite (Mg# 87 in olivine-rich troctolites to 82 in gabbros), and plagioclase has anorthite contents ranging from 77 in olivine-rich troctolites to 68 in gabbros. Olivine has high forsterite contents (82-88 in olivine-rich troctolites, to 78-83 in gabbros) and is in Mg-Fe equilibrium with clinopyroxene. Clinopyroxene cores and plagioclase are depleted in trace elements (e.g., Yb-cpx similar to 5-11 x Chondrite), they are in equilibrium with the same MORB-type melt in all studied rock-types. These compositions are not consistent with the progressively more trace element enriched (evolved) compositions expected from olivine rich primitive products to gabbros in a MORB cumulate sequence. They indicate that clinopyroxene and plagioclase crystallized concurrently, after melts having the same trace element composition, consistent with crystallization in an open system with a buffered magma composition. The slight trace element enrichments and lower Cr contents observed in clinopyroxene rims and interstitial grains results from crystallization of late-stage differentiated melts, probably indicating the closure of the magmatic system. In contrast to clinopyroxene and plagioclase, olivine is not in equilibrium with MORB, but with a highly fractionated depleted melt, similar to that in equilibrium with refractory oceanic peridotites, thus possibly indicating a mantle origin. In addition, textural relationships suggest that olivine was in part assimilated by the basaltic melts after which clinopyroxene and plagioclase crystallized (impregnation). These observations suggest a complex crystallization history in an open system involving impregnation by MORB-type melt(s) of an olivine-rich rock or mush. The documented magmatic processes suggest that olivine-rich troctolites were formed in a zone with large magmatic transfer and accumulation, similar to the mantle-crust transition zone documented in ophiolites and at fast spreading ridges.
ISSN: 0009-2541

hal-00420916
https://hal.archives-ouvertes.fr/hal-00420916
DOI : 10.1016/j.chemgeo.2009.02.013

Éditeur(s) : HAL CCSD
Résumé : National audience
Le standard d’eau de rivière naturelle SLRS-5 (NRC-CNRC) est uneréférence de contrôle qualité en analyse d’eau de routine pour la communautéinternationale. Dix laboratoires français étudiant les élémentsmajeurs et en trace dans les solutions naturelles (groupe de travail del’atelier du CNRS « Isotrace ») valident leurs mesures avec les 19 élémentscertifiés par le producteur. Or, d’autres éléments non certifiés sontrégulièrement analysés par ces laboratoires qui ont comparé et compilé2 années de leurs mesures sur ce standard d’eau. La plupart desmesures sont réalisées par ICP-MS (Inductively Coupled Plasma Mass-Spectrometry).Dans un premier temps, il a été vérifié que les résultats obtenus étaientcohérents pour les éléments certifiés par le producteur. Ainsi Ba présenteune valeur compilée de 14,2 1,4 g/l (330 mesures issues de 9laboratoires participants) en accord avec la valeur certifiée de 14 0,5g/l.Ensuite, des valeurs moyennes et leurs incertitudes associées sont proposéespour des éléments non certifiés par NRC-CNRC tels que le siliciumet 35 éléments en trace (terres rares, Ag, B, Bi, Cs, Ga, Ge, Li, Nb,P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl,W, Y et Zr). Le rapport isotopique deSr est aussi proposé à partir de mesures par TIMS (Thermo IonisationMass Spectrometry).Il apparaît que les mesures individuelles et compilées varient dequelques ng/l à 2400 g/l avec des incertitudes associées comprisesentre 2 et 240%. Les fortes incertitudes associées ne sont pas proportionnellesaux concentrations puisque certaines mesures s’accordent mêmeà de faibles teneurs tels que Bi (0,9 0,3 ng/l valeur compilée). Danscertains cas, un ou deux laboratoires ont caractérisé l’élément impliquantmoins de mesures et une incertitude associée plus élevée quelleque soit la concentration en l’élément. C’est le cas, par exemple, de Ge(0,015 0,014 g/l valeur compilée) caracterisé par seulement 2 laboratoires(34 mesures) et de P (8,19 3,40 g/l) issu de 8 mesuresd’un seul laboratoire. Les terres rares et onze autres éléments (B, Bi,Cs, Li, Rb, Si, Th, Ti, Tl, Y et Zr) ont été déterminés par au moins 3laboratoires différents et apportent des informations complémentairesessentielles à l’utilisation
24 ème Réunion des sciences de la Terre 2014
Pau, France

insu-01080879
https://hal-insu.archives-ouvertes.fr/insu-01080879

Éditeur(s) : HAL CCSD
Résumé : International audience
In the context of climate change, this study presents the ability of major/trace elements together with strontiumisotopes to trace back water paths at small scale and to deconvolve the geochemical signal of a small watershedsubject to intense flash floods episodes (Peyne, Hérault, France). Two small sub-basins draining distinct lithologiesin their heads (Plio-Villafranchian conglomerate versus Triassic gypsum-rich marls and dolomites) and the sameMiocene lithology downstream are investigated.Major elements and Ca/Na vs. Mg/Na ratios classically applied at large scale to distinguish carbonate from silicateweathering, allow here discriminating the three main lithologies from the two sub-basins. Trace elements Rband Sr coupled to calcium, also allow this lithological discrimination but in addition the Ca/Rb vs. Sr/Rb tracersappear to be much more discriminant for the various hydrological conditions. Thus, in combination with detailedlithological descriptions, they allow identifying the different facies that imprint the water signature through water-rock interaction according to the hydrological conditions.Strontium isotopes and Rb/Sr ratio, discriminate more precisely the drained lithologies of the 2 sub-basins. Firstly,the 87Sr/86Sr ratios allow identifying the nature of the lithologies and their main component(s) contributing to theSr budget in water and thus imprint the isotopic signature. Secondly, Sr isotopes evidenced two distinct Miocenefacies: the detritric faction (sandy marls), and the marine carbonates.The geochemical signatures of the brook samples draining both compartments were compared to the signatureof the Peyne River outlet just before the confluence into the Hérault River. It appears that the signature of thePeyne River, integrating all the water draining the basin, is relatively stable whatever the hydrological conditionsand mainly marked by the Miocene formations. Sr isotopes further highlight that this signature seems to resultfrom the mixing of both Miocene facies present in the lower part of the Peyne watershed, i.e. the sandy marls andthe carbonates. The typical signatures of the Plio-Villafanchian conglomerates and Triassic gypsiferous marls anddolomites of the headwaters of each sub-basin are completely hidden by the Miocene signatures. This should berelated to the large drainage area of the Miocene compared to other lithologies, despite the high solubility of thegypsum formations releasing large quantities of dissolved elements in solution.Understanding water paths at small scale is even more efficient when the geochemical approach is coupled with adetailed geological description. Indeed, the geochemical tracers are extremely dependent on the facies sequences(morphology) and of the soil nature (mineralogical composition), this is particularly sensitive at small scale.In the context of climate change increasing the intensity of rain events in the Mediterranean region, and resultingin catastrophic floods events (flash floods), tracing the origin of water contributing to the runoff is of primaryimportance and this must be investigated at small scale. Geochemical and isotopic fingerprinting thus constituteexcellent tools which can help to define the area of interest to be monitored in the framework of flood forecast andwarning networks
EGU General Assembly 2015
Vienne, Austria

hal-01118622
https://hal-brgm.archives-ouvertes.fr/hal-01118622

Éditeur(s) : Elsevier Science Bv
Résumé : For many trace elements, continental margins are the location of intense exchange processes between sediment and seawater, which control their distribution in the water column, but have yet to be fully understood. In this study, we have investigated the impact of fluid seepage at cold seeps on the marine cycle of neodymium. We determined dissolved and total dissolvable (TD) concentrations for REE and well-established tracers of fluid seepage (CH4, TDFe, TDMn), and Nd isotopic compositions in seawater samples collected above cold seeps and a reference site (i.e. away from any fluid venting area) from the Niger Delta margin. We also analyzed cold seep authigenic phases and various core-top sediment fractions (pore water, detrital component, easily leachable phases, uncleaned foraminifera) recovered near the hydrocast stations. Methane, TDFe and TDMn concentrations clearly indicate active fluid venting at the studied seeps, with plumes rising up to about 100 m above the seafloor. Depth profiles show pronounced REE enrichments in the non-filtered samples (TD concentrations) within plumes, whereas filtered samples (dissolved concentrations) exhibit slight REE depletion in plumes relative to the overlying water column and display typical seawater REE patterns. These results suggest that the net flux of REE emitted into seawater at cold seeps is controlled by the presence of particulate phases, most probably Fe-Mn oxyhydroxides associated to resuspended sediments. At the reference site, however, our data reveal significant enrichment for dissolved REE in bottom waters, that clearly relates to diffusive benthic fluxes from surface sediments. Neodymium isotopic ratios measured in the water column range from epsilon(Nd) similar to-15.7 to -10.4. Evidence that the epsilon(Nd) values for Antarctic Intermediate waters (AAIW) differed from those reported for the same water mass at open ocean settings shows that sediment/water interactions take place in the Gulf of Guinea. At each site, however, the bottom water epsilon(Nd) signature generally differs from that for cold seep minerals, easily leachable sediment phases, and detrital fractions from local sediments, ruling out the possibility that seepage of methane-rich fluids and sediment dissolution act as a substantial source of dissolved Nd to seawater in the Gulf of Guinea. Taken together, our data hence suggest that co-precipitation of Fe-Mn oxyhydroxide phases in sub-surface sediments leads to quantitative scavenging of dissolved REE at cold seeps, preventing their emission into bottom waters. Most probably, it is likely that diffusion from suboxic surface sediments dominates the exchange processes affecting the marine Nd cycle at the Niger Delta margin. (C) 2011 Elsevier B.V. All rights reserved.
Earth And Planetary Science Letters (0012-821X) (Elsevier Science Bv), 2011-12 , Vol. 312 , N. 3-4 , P. 443-452

Droits : 2011 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/00066/17754/15571.pdf
DOI:10.1016/j.epsl.2011.10.008
http://archimer.ifremer.fr/doc/00066/17754/