Éditeur(s) : HAL CCSD Taylor & Francis
Résumé : International audience
The Jurassic Mirdita ophiolite crops out in the western branch of the Hellenide-Dinaride ophiolite belt in the Balkan Peninsula; it represents a remnant of the Tethyan oceanic lithosphere developed between the Apulian and Pelagonian microcontinents. Emplaced during the Cretaceous on the western margin of Pelagonia, the Mirdita ophiolite was involved in southwestward thrusting of the Hellenide-Dinaride tectonic units during the Eocene alpine tectonics. It was little affected, however, by these alpine events as marked by nearly horizontal Cretaceous limestone deposits overlying the ophiolite. A continuous section of Middle Jurassic oceanic crust, including thin gabbros, a N-S-trending sheeted dike complex, and extrusive rocks, is exposed in the central part of the ophiolite and thickens eastward within a regional, N-S-trending synform. Peridotite massifs exposed along the western and eastern edges of this synform show major structural and petrological differences. The eastern ultramafic domain has a harzburgitic mantle exhibiting a high-temperature asthenospheric foliation dipping steeply to moderately to the west. Major chromite deposits are restricted to these eastern ultramafic massifs. The western ultramafic domain has a zoned mantle, with asthenospheric harzburgite exposed at its western margin, progressively replaced eastward by plagioclase-peridotites that were highly strained at low temperatures, and that are bounded by amphibole-peridotites along with crustal rocks. The occurrence of plagioclase is ascribed to melt impregnation processes that occurred immediately before or during intense lithospheric deformation. The gabbros in the eastern massifs are thicker (1-2 km and layered, whereas they are highly thin and discontinuous in the western massifs. Mantle peridotites of the western massifs locally are in direct contact with the overlying diabase and volcanic rocks along ductile shear zones. Development of epidote-amphibolite facies metamorphism in upper-crustal rocks was produced by hydrothermal alteration in the oceanic realm, and was intense and widespread in the western domain. The Mirdita ophiolite likely originated in a short-lived, narrow ocean basin, which was closed during the Middle Jurassic by eastward overthrusting of the western domain, and westward subduction of the eastern domain. This constrictional phase was followed by dextral oblique convergence between the Pelagonian and Apulian microcontinents. This model implies a parautochtonous origin of the Mirdita ophiolite between these two microcontinents.
ISSN: 0020-6814

hal-00456063
https://hal.archives-ouvertes.fr/hal-00456063
DOI : 10.1080/00206810902823982

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
To quantify the seismic properties of lower crustal rocks and to better constrain the origin of the lower crustal seismic reflectivity, we determined the complete 3-D seismic properties of a lower crustal section. Eight representative samples of the main lithologic and structural units outcropping in the Val Sesia (Ivrea zone) were studied in detail. The seismic velocities were calculated using the single crystal stiffness coefficients and the lattice preferred orientation (LPO) of each mineral in all samples. The 21 stiffness coefficients characterizing the elastic behaviour of each rock are determined. Mafic and ultramafic rocks such as pyroxenite and pyroxene-bearing gabbros display complex shear wave properties. These rocks are weakly birefringent (maximum 0.1 kms-1) and it is difficult to find consistent relationships between the seismic properties and the rock structure. On the other hand, seismic properties of deformed felsic rocks are essentially controlled by mica. They display strong S-wave birefringence (0.3 km s-1) and relatively high Vp anisotropy (7.6 per cent). Amphibole also strongly influences the rock birefringence patterns. For both kind of rocks, the foliation is highly birefringent and the fast polarized shear wave is systematically oriented parallel to the foliation. We show that the number of mineral phases in the rock strongly controls the anisotropy. The seismic anisotropy has a complex role in the P-wave reflectivity. Compared to the isotropic case, anisotropy enhances the reflection coefficient for about 60 per cent of the possible lithological interfaces. For 40 per cent of the interfaces, the reflection coefficient is much lower when one considers the medium as anisotropic.
ISSN: 0956-540X

hal-01389122
http://hal.univ-reunion.fr/hal-01389122
http://hal.univ-reunion.fr/hal-01389122/document
http://hal.univ-reunion.fr/hal-01389122/file/Barruol_3D_velocities_GJI1993.pdf
DOI : 10.1111/j.1365-246X.1993.tb01519.x

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : International audience
Separated olivine grains from a deeply subducted serpentinized wehrlite (Changawuzi in the western Tianshan ultrahigh-pressure belt, China) were analysed with unpolarized transmission FTIR and the Ti contents were determined using LA-ICP-MS. The major bands in the olivine spectra display striking similarities to Ti-clinohumite and are interpreted as OH in lamellae. The quantification of the water content in lamellae requires calibration of the IR-absorption for such bands. We have obtained a new absorption coefficient for Ti-clinohumite of 0.125+/−0.017 ppm cm2 based on polarized FTIR measurements on three orthogonal sections through a large single crystal of Ti-clinohumite from Val Malenco, which has a known water content of 1.53 wt%. The resulting water content in olivine using this calibration factor ranges from 440 to 2,600 ppm and correlates positively with the Ti content that ranges from 130 to 1,400 ppm. For the quantification of the water content in Ti-chondrodite and Ti-clinohumite that are associated with olivine, we developed a new method using attenuated total reflectance FTIR spectroscopy. Ti-chondrodite and Ti-clinohumite display similar IR bands at ~3,562, 3,525 and ~3,583–3,586 cm−1. As in olivine, the water content and Ti content correlate in both Ti-clinohumite and Ti-chondrodite, indicating an intergrowth of these minerals, which has been confirmed by TEM analyses. Our results confirm previous suggestions that there is a strong correlation between the Ti content of ultramafic rocks and their capacity to transport water to the deeper mantle in subduction zones beyond conditions where hydrous phases are stable.
ISSN: 0010-7999

hal-01172237
https://hal.archives-ouvertes.fr/hal-01172237
DOI : 10.1007/s00410-014-0992-8

Éditeur(s) : HAL CCSD Oxford University Press (OUP): Policy B - Oxford Open Option A Oxford University Press (OUP)
Résumé : International audience
Peridotites exhumed in the footwall of axial detachment faults at slow-spreading ridges are highly serpentinized. Most mid-ocean ridge detachment settings are magmatically active and hydrous fluid circulation in and near the fault has been shown to be influenced by the presence of melt or magmatic lithologies. Our working area along the Southwest Indian Ridge (62–65°E) is nearly amagmatic and represents an end-member to study the hydrous alteration of exhumed peridotites without these magmatic influences. We use an integrated petrological approach combining microstructural, mineralogical and chemical observations to unravel the sequence of serpentinization in 272 dredged samples of variably serpentinized peridotites and to document the circulation of serpentinizing fluids in and near the exhumation faults. We find that serpentine recrystallization and veins overprint the initial serpentinite mesh texture in ∼25% of the samples. Oxygen isotope data suggest that this sequence developed at relatively high temperatures (271–336°C) and under increasing fluid–rock ratios, from near stoichiometry for mesh texture formation to >10 during recrystallization. Increasing fluid supersaturation relative to serpentine favors the replacement of mesh texture lizardite by chrysotile and polygonal or polyhedral serpentine. We attribute local recrystallization into antigorite to moderate Si-metasomatism, possibly following pyroxene serpentinization. We do not observe the more pronounced Si-metasomatism leading to talc replacing serpentine that is reported for the more magmatically active Mid-Atlantic Ridge detachment settings and is attributed to prior leaching of magmatic rocks. Scales of preferential fluid pathways in our samples evolved from pervasive and close-spaced (<500 µm) microfractures during the formation of the initial serpentine mesh texture, to centimeter-thick planar domains of enhanced fluid flux, spaced at ∼10 cm intervals and probably grouped in corridors that may be up to ∼100 m across. Serpentine minerals are enriched in some fluid-mobile elements (Cl, B, U) relative to the peridotite protolith, and several elements (Al, Fe, Si, Cu, As, Sb, REE) are redistributed at the millimeter to decimeter scale. Serpentinizing fluids were seawater-derived, probably mildly alkaline (small to no europium anomalies), reducing and H2-enriched (formation of magnetite). These fluids may have been similar to, though warmer than, those venting at the ultramafic-hosted Lost City hydrothermal fluid (30°N, Mid-Atlantic Ridge).
ISSN: 0022-3530

hal-01174047
https://hal.archives-ouvertes.fr/hal-01174047
DOI : 10.1093/petrology/egv014

Éditeur(s) : HAL CCSD Elsevier Masson
Résumé : International audience
Although they are famous among Earth scientists, the Lherz peridotites are exposed within geological formations of the North Pyrenean Zone (NPZ) still lacking detailed investigations. Our study focuses on the metasediments of the Aulus basin hosting the Lherz peridotite body and associated ultramafic fragments of smaller size. The new data set comprises of structural analysis and detailed geological mapping of the massive Mesozoic marbles that form the prerift sequence typical of the NPZ and of the ultramafic-rich clastic breccia formations surrounding the peridotite bodies. The massive marbles display an evolution from hot and ductile to cold and brittle deformation, indicative of an exhumation process ending with the sedimentary reworking of both the deformed Mesozoic metasediments and the exhumed ultramafic rocks. Crystal Preferred Orientations (CPO) measured in the marbles support a deformation mechanism by dislocation creep of calcite, which is dominant between 400 8C and 600 8C; these deformation temperatures are within the range determined earlier by Clerc et al. (2015), using RSCM (Raman Spectroscopy of Carbonaceous Material) geothermometry. As a consequence, we better describe the transition from ductile to brittle deformation in the prerift marbles and clarify the origin of the syn-rift breccias. Due to continuous exhumation along detachments' faults, the brecciated metamorphic carbonates of the prerift NPZ sedimentary cover were passively uplifted towards shallower levels and progressively unroofed, while transported passively on the back of the exhumed ultramafic footwall. These results are consistent with the recent interpretations of the North Pyrenean peridotites as remnants of subcontinental mantle rocks exhumed within the pre-Pyrenean rift system. We emphasize the importance of tectonic decoupling between the Mesozoic sedimentary cover and the Palaeozoic basement, which leads to the juxtaposition of metamorphosed and deformed Mesozoic Please cite this article in press as: Lagabrielle Y, et al. Very high geothermal gradient during mantle exhumation recorded in mylonitic marbles and carbonate breccias from a Mesozoic Pyrenean palaeomargin (Lherz area, North Pyrenean Zone, France). C. R. Geoscience (2016), http://dx.
ISSN: 1631-0713

Droits : http://creativecommons.org/licenses/by-nc-nd/
insu-01285079
https://hal-insu.archives-ouvertes.fr/insu-01285079
https://hal-insu.archives-ouvertes.fr/insu-01285079/document
https://hal-insu.archives-ouvertes.fr/insu-01285079/file/1-s2.0-S1631071315002060-main.pdf
DOI : 10.1016/j.crte.2015.11.004

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Peridotite xenoliths brought up to the surface by the volcanism of the Kerguelen Islands represent a mantle that has been affected by a high degree of partial melting followed by intense melt percolation above the Kerguelen plume. These xenoliths are therefore particularly suitable to investigate effects of melt-rock interaction on crystallographic fabrics (lattice-preferred orientation (LPO)) of peridotite minerals and on the LPO-induced seismic properties of peridotites above a mantle plume. We have studied a suite of 16 ultramafic samples representative of different degrees of partial melting and magma-rock interaction among which the protogranular harzburgites are the least metasomatised xenoliths and dunites are the ultimate stage of metasomatism. Olivine LPO is characterized by high concentration of [010] axes perpendicular to the foliation and [100] axes close to the lineation or distributed in the foliation plane in harzburgites, whereas the high concentration of [100] axes is parallel to the lineation and [010] axes is perpendicular to the assumed foliation in dunites. Olivine LPO in harzburgites is interpreted as being due to a deformation regime in axial compression or transpression. The fabric strength of olivine decreases progressively from protogranular to poikilitic harzburgites and finally to dunites, for which it remains nevertheless significant (J index 3.8). Seismic properties calculated from LPO of minerals indicate that metasomatism at higher melt/rock ratio lowers the P wave velocities. The most significant difference between harzburgites and dunites corresponds to the distribution of S wave anisotropy. Harzburgites display the maximum of anisotropy within the foliation plane and the minimum of anisotropy perpendicular to the foliation plane, whereas the lowest anisotropy is parallel to the lineation for dunites. These modifications of seismic properties as a result of metasomatic processes may induce seismic heterogeneities in the mantle above the Kerguelen plume. In addition, assuming a lithospheric mantle primarily harzburgitic and structured with a horizontal foliation, the seismic properties calculated for the Kerguelen xenoliths reconcile the rather high anisotropy evidenced by the horizontally propagating surface waves with the apparent isotropy revealed by the absence of splitting of vertically propagating teleseismic SKS waves recorded by the GEOSCOPE Kerguelen station.
ISSN: 1525-2027

hal-00366222
https://hal.archives-ouvertes.fr/hal-00366222
https://hal.archives-ouvertes.fr/hal-00366222/document
https://hal.archives-ouvertes.fr/hal-00366222/file/bascou_Kerguelen_2007GC001879_hal.pdf
DOI : 10.1029/2007GC001879

Éditeur(s) : HAL CCSD American Chemical Society
Résumé : International audience
Carbonation of ultramafic rocks in geological reservoirs is, in theory, the most efficient way to trap CO2 irreversibly; however, possible feedback effects between carbonation reactions and changes in the reservoir permeability must be considered to realistically assess the efficiency and sustainability of this process. We investigated changes in the hydrodynamic properties of sintered dunite samples by means of percolation experiments, under conditions analogous to that of in situ carbonation. Our results show that carbonation efficiency is controlled by the local renewal of the reactants and the heterogeneity of the pore structure. Preferential flow zones are characterized by the formation of magnetite and of a silica-rich layer at the olivine surfaces, which eventually inhibits olivine dissolution. Conversely, sustainable olivine dissolution together with coprecipitation of magnesite, siderite, and minor Mg-TOT-phyllosilicates, occur in reduced-flow zones. Thus carbonate precipitation only decreases porosity in zones where diffusion-controlled transport is dominant. Consequently, while high flow rates will decrease the carbonation efficiency of the reservoir and low flow rates may reduce the permeability irreversibly close to the injection point, moderate injection rates will ensure a partial carbonation of the rock and maintain the reservoir permeability.
ISSN: 0013-936X

hal-00424540
https://hal.archives-ouvertes.fr/hal-00424540
DOI : 10.1021/es8018429

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Brecciated and fractured peridotites with a carbonate matrix, referred to as ophicalcites, are common features of mantle rocks exhumed in passive margins and mid-oceanic ridges. Ophicalcites have been found in close association with massive peridotites, which form the numerous ultramafic bodies scattered along the North Pyrenean Zone (NPZ), on the northern flank of the Pyrenean belt. We present the first field, textural and stable isotopic characterization of these rocks. Our observations show that Pyrenean ophicalcites belong to three main types: (1) a wide variety of breccias composed of sorted or unsorted millimeter- to meter-sized clasts of fresh or oxidized ultramafic material, in a fine-grained calcitic matrix; (2) calcitic veins penetrating into fractured serpentine and fresh peridotite; and (3) pervasive substitution of serpentine minerals by calcite. Stable isotopic analyses (O, C) have been conducted on the carbonate matrix, veins and clasts of samples from 12 Pyrenean ultramafic bodies. We show that the Pyrenean ophicalcites are the product of three distinct genetic processes: (1) pervasive ophicalcite resulting from relatively deep and hot hydrothermal activity; (2) ophicalcites in veins resulting from tectonic fracturing and cooler hydrothermal activity; and (3) polymictic breccias resulting from sedimentary processes occurring after the exposure of subcontinental mantle as portions of the floor of basins which opened during the mid-Cretaceous. We highlight a major difference between the eastern and western Pyrenean ophicalcites belonging, respectively, to the sedimentary and to the hydrothermal types. Our data set points to a possible origin of the sedimentary ophicalcites in continental endorheic basins, but a post-depositional evolution by circulation of metamorphic fluids or an origin from relatively warm marine waters cannot be ruled out. Finally, we discuss the significance of such discrepancy in the characteristics of the NPZ ophicalcites in the frame of the variable exhumation history of the peridotites all along the Pyrenean realm.
ISSN: 1437-3254

insu-00944405
https://hal-insu.archives-ouvertes.fr/insu-00944405
https://hal-insu.archives-ouvertes.fr/insu-00944405/document
https://hal-insu.archives-ouvertes.fr/insu-00944405/file/clerc-etal-IJES-Review.pdf
DOI : 10.1007/s00531-013-0927-z

Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
In the Pyrenees, the lherzolites nowhere occur as continuous units. Rather, they always outcrop as restricted bodies, never more than 3 km wide, scattered across Mesozoic sedimentary units along the North Pyrenean Fault. We report the results of a detailed analysis of the geological setting of the Lherz massif (central Pyrenees), the type-locality of lherzolites and one of the most studied occurrences of mantle rocks worldwide. The Lherz body is only 1.5 km long and belongs to a series of ultramafic bodies of restricted size (a few metres to some hundreds of metres), occurring within sedimentary formations composed mostly of carbonate breccias originating from the reworking of Mesozoic platform limestones and dolomites. The clastic formations also include numerous layers of polymictic breccias reworking lherzolitic clasts. These layers are found far from any lherzolitic body, implying that lherzolitic clasts cannot derive from the in situ fragmentation of an ultramafic body alone, but might also have been transported far away from their sources by sedimentary processes. A detailed analysis of the contacts between the Lherz ultramafic body and the surrounding limestones confirms that there is no fault contact and that sediments composed of ultramafic material have been emplaced into fissures within the brecciated carapace of the peridotites. These observations bear important constraints for the mode of emplacement of the lherzolite bodies. We infer that mantle exhumation may have occurred during Albian strike-slip deformation linked to the rotation of Iberia along the proto-North Pyrenean Fault.
ISSN: 0954-4879

hal-00412602
https://hal.archives-ouvertes.fr/hal-00412602

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Sapat peridotite in Kohistan (NW Pakistan) is a 12x1 km sized body of meta-harzburgites, dunites, pyroxenites and meta-gabbros in the hanging wall of the Indus Suture Zone. Field relations, micro-textures, bulk and mineral chemistry document melt-rock reactions producing dunites at the expense of meta-harzburgites, and a consecutive olivine-clinopyroxenite formation from the same melt type. The association of mesa-gabbros, dunites, and pyroxenites is interpreted as a crust-mantle transition zone produced by the percolation of highly depleted primitive arc melt. The meta-harzburgites represent large portions of refractoty mantle that have suffered melt extraction and metasomatism prior to their interaction with the dunite-forming primitive arc melt and the establishment of the crust-mantle transition zone. Uncommon vein assemblages in the dunites that include Cr-clinochlore, calcite and olivine document a late percolation of slab-related, volatile-rich fluids. Taking into account the highly refractory composition of the Sapat mantle, its structural position, the evidence for interaction with highly depleted arc melts and the sub-solidus interaction with volatile-rich arc fluids, the Sapat ultramafic rocks are interpreted as being derived from the frontal Kohistan arc, representing a crust-mantle transition formed by arc magmatism.
ISSN: 0024-4937

hal-00424515
https://hal.archives-ouvertes.fr/hal-00424515
DOI : 10.1016/j.lithos.2008.07.004

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Timétrine massif exposed west of the Pan-African suture zone in northeastern Mali belongs to the passive margin of the West African craton facing to the east intra-oceanic arc assemblages and 730 Ma old pre-collisional calc-alkaline plutons. The Timétrine lithologic succession includes from the base to the top Mesoproterozoic cratonic to passive margin formations overlain by deep-sea Fe-Mg schists. Submarine metabasalts and two ultramafic massifs of serpentinized mantle peridotites are inserted as olistoliths towards the top whereas turbidites of continental origin represent the younger unit. Field and petrological data have revealed a distinct metasedimentary sequence attached to the serpentinized peridotites. It essentially consists of impure carbonates, Fe jaspers and polymictic breccias containing altered blocks of mantle peridotites, most rocks being enriched in detrital chromite. This association is interpreted as reworked chemical and detrital sediments derived from the alteration of mafic-ultramafic rocks. It is argued that mantle exhumation above sea floor took place during the Neoproterozoic rifting and crustal thinning period under possible tropical conditions, as suggested by the large volume of silicified serpentinites. In spite of greenschist facies metamorphic overprint characterized by widespread Fe-rich blue amphiboles that are not diagnostic of high-pressure conditions, it is possible to reconstruct a former ocean-continent transition similar to that evidenced for the Mesozoic period, followed by the deposition of syn-to post rift terrigeneous turbidites roughly coeval with ocean spreading some time before 800 Ma. It is concluded that the serpentinite massifs were tectonically emplaced first in an extensional setting, then incorporated within deep-sea sediments as olistoliths and finally transported westward during late Neoproterozoic collisional tectonics onto the West African craton.
ISSN: 0899-5362

hal-00985586
https://hal.archives-ouvertes.fr/hal-00985586
DOI : 10.1016/j.jafrearsci.2013.11.004

Éditeur(s) : HAL CCSD
Résumé : Subduction is one of the major geodynamical process active during the Earth evolution. The characterization of arc magmas, their evolution through space and time, and the relationship between arc magmatism and continental crust forming processes, constitute the main research topics in petrology and geochemistry since the last three decades. This study focuses on an exhumed portion of the Kohistan Arc (N Pakistan), which is an exceptional ‘in situ' laboratory to study and follow through time the processes active on subduction zones. Based on a pluri-geochemical approach, this study allows unraveling two major issues : 1/ The lack of a cogenetic relationship between the arc root (i.e. ultramafic rocks) and the overlying gabbroic crustal section. The Jijal ultramafic section does not bear a crustal origin and was emplaced at ~117 Ma via a magma-rock reaction between REE-depleted ‘boninite-like' melts and the pre-existing lithospheric mantle with Indian-MORB affinities; 2/ A three-stage geodynamical model covering the arc evolution through ~30 Ma. This model starts with the onset of the subduction followed by the building of the volcanic arc (1st stage). The 2nd stage corresponds to a major thermal event, characterized by abundant magma underplating and by granulitisation of the arc base. Recycling of the residual/cumulative lower crust into the convective asthenospheric mantle was efficient during this stage, and probably related to thermo-mechanical erosion processes. The last stage, between ~95 and 85 Ma, seals the end of the intra-oceanic subduction and corresponds to an “amagmatic” period. This step is followed by a voluminous, but short, magmatic pulse at ~85 Ma, occurring just before the arc-continent collision. At last, this study emphasizes the more mafic composition of the investigated crustal arc section when compared to the bulk continental crust. Nevertheless the arc section composition nicely fits with the lower continental crust average.
Les zones de subduction représentent des zones d'évolution clés dans la compréhension des processus géologiques majeurs actifs sur notre planète. En particulier, la caractérisation et l'évolution des magmas générés dans les zones d'arcs océaniques et la relation entre leur genèse et les processus de croissance crustale sont des axes primordiaux. Cette étude est focalisée sur la portion d'arc océanique exhumée du Kohistan (Nord Pakistan) qui constitue un laboratoire exceptionnel pour appréhender cette problématique. Basée sur une approche géochimique multi-méthodes (éléments majeurs et en trace, isotopes), cette étude a permis d'établir : 1/ l'absence de relation génétique directe entre les roches ultrabasiques de la racine de l'arc et la section crustale sus-jacente. La formation de la séquence ultrabasique de Jijal se produit à ~117 Ma via une réaction de type magma-roche entre des liquides de type boninitique (appauvris en terres rares), et le manteau lithosphérique de type MORB-Indien ; 2/ un modèle géodynamique en trois stades majeurs résumant l'évolution de l'arc océanique et de la subduction sur une période d'environ 30 Ma. Ce modèle débute par l'initiation de la subduction et la formation de l'arc volcanique s.s. (1er stade) ; le 2ème stade correspond à un évènement thermique majeur. Il est représenté par un sous-placage important de magmas et une granulitisation intense de la base de l'arc. Le recyclage de la croûte inférieure cumulative et résiduelle, dans le manteau sous-jacent, se produit durant cette étape vraisemblablement suite à des processus d'érosion thermo-mécanique. Le dernier stade, entre 95 Ma et 85 Ma, scelle la fin du fonctionnement de la zone de subduction et correspond à une période amagmatique suivie par une brève reprise du magmatisme avant la collision de l'arc après 85 Ma. Enfin, une modélisation numérique comparative avec la croûte continentale globale met en évidence la composition significativement plus basique de la croûte de l'arc insulaire du Kohistan. De fortes similitudes sont en revanche observées entre la section d'arc étudiée et la croûte continentale inférieure.
https://tel.archives-ouvertes.fr/tel-00437770

tel-00437770
https://tel.archives-ouvertes.fr/tel-00437770
https://tel.archives-ouvertes.fr/tel-00437770/document
https://tel.archives-ouvertes.fr/tel-00437770/file/thesedhuime.pdf

Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
The Lanzo peridotite massif is a fragment of oceanic lithosphere generated in an ocean-continent transition context and eclogitized during alpine collision. Despite the subduction history, the massif has preserved its sedimentary oceanic cover, suggesting that it may have preserved its oceanic structure. It is an exceptional case for studying the evolution of a fragment of the lithosphere from its oceanization to its subduction and then exhumation. We present a field and petrological study retracing the different serpentinization episodes and their impact on the massif structure. The Lanzo massif is composed of slightly serpentinized peridotites (<20% serpentinization) surrounded by an envelope of foliated serpentinites (100% serpentinization) bordered by oceanic metabasalts and metasedimentary rocks. The limit between peridotites and serpentinites defines the front of serpentinization. This limit is sharp: it is marked by the presence of massive serpentinites (80% serpentinization) and, locally, by dykes of metagabbros and mylonitic gabbros. The deformation of these gabbros is contemporaneous with the emplacement of the magma. The presence of early lizardite in the peridotites testifies that serpentinization began during the oceanization, which is confirmed by the presence of meta-ophicarbonates bordering the foliated serpentinite envelope. Two additional generations of serpentine occur in the ultramafic rocks. The first is a prograde antigorite that partially replaced the lizardite and the relict primary minerals of the peridotite during subduction, indicating that serpentinization is an active process at the ridge and in the subduction zone. Locally, this episode is followed by the deserpentinization of antigorite at peak P-T (estimated in eclogitized metagabbros at 2-2.5 GPa and 550-620 °C): it is marked by the crystallization of secondary olivine associated with chlorite and/or antigorite and of clinopyroxene, amphibole and chlorite assemblages. A second antigorite formed during exhumation partially to completely obliterating previous textures in the massive and foliated serpentinites. Serpentinites are an important component of the oceanic lithosphere generated in slow to ultraslow spreading settings, and in these settings, there is a serpentinization gradient with depth in the upper mantle. The seismic Moho limit could correspond to a serpentinization front affecting the mantle. This partially serpentinized zone constitutes a less competent level where, during subduction and exhumation, deformation and fluid circulation are localized. In this zone, the reaction kinetics are increased and the later steps of serpentinization obliterate the evidence of this progressive zone of serpentinization. In the Lanzo massif, this zone fully recrystallized into serpentinite during alpine subduction and collision. Thus, the serpentinite envelope represents the oceanic crust as defined by geophysicists, and the sharp front of serpentinization corresponds to an eclogitized seismic palaeo-Moho.
ISSN: 0263-4929

hal-00823051
https://hal.archives-ouvertes.fr/hal-00823051
DOI : 10.1111/jmg.12008

Éditeur(s) : Elsevier Science Bv
Résumé : Although Ni isotopes have been shown to be significantly fractionated in terrestrial samples, their use in continental environmental studies has not yet been evaluated. The present study focuses on an ultramafic (UM) massif (Barro Alto, Goias, Brazil) because such areas are naturally rich in Ni. We present developed lateritic weathering profiles. The goal of the study is to evaluate the potential of using Ni isotopes in environmental continental studies by combining its isotopic signature with mineralogy, in order to better understand the geochemical cycling of Ni in UM settings during weathering. As such, Ni isotope values were measured in samples from the Barro Alto UM complex in the main stages of the lateritic weathering profile of UM rocks, including bedrock, ores (saprolitic and lateritic samples) and soil. The mineralogical composition of the samples, with a focus on the different Ni-bearing minerals, was also determined to decipher the potential links between isotopic fractionation and weathering dynamics. Isotopic signatures (δ60Ni) from the natural Ni geochemical cycle include: bedrock samples (δ60Ni = 0.28 ± 0.08‰), ore samples (saprolitic and lateritic, δ60Ni from -0.60 to 0.30‰) and soil samples (δ60Ni from -0.19 to -0.02‰). An overall trend of heavier isotope depletion was observed in the solid phase during weathering (Δ60NiSoil-Bedrock = -0.47‰). The mineralogical results were consistent with the literature and showed that the mineralogy of the lateritic part and soil was dominated by Fe-oxides, whereas clay minerals were the primary Ni phase scavengers in the saprolitic part of the profile. Thus, the formation of Ni-bearing clay minerals and Fe-oxides appeared to lead to depletion in heavier isotopes, which indicates preferential export of heavy isotopes in the dissolved phase. This result is consistent with isotopic signatures measured in the exchangeable pool of the solid phase (Δ60Niexch-total up to 0.47‰), and Ni isotopes appear to be a promising tracer to better understand the biogeochemical Ni cycling on the Earth’s surface.
Chemical Geology (0009-2541) (Elsevier Science Bv), 2015-05 , Vol. 402 , P. 68-76

Droits : 2015 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/00254/36553/35098.pdf
DOI:10.1016/j.chemgeo.2015.02.039
http://archimer.ifremer.fr/doc/00254/36553/

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The southwestern Tianshan (China) metamorphic belt records high-pressure (HP) to ultrahigh-pressure (UHP) conditions corresponding to a cold oceanic subduction-zone setting. Serpentinites enclosing retrogressed eclogite and rodingite occur as lenses within metapelites in the UHP unit, which also hosts coesite-bearing eclogites. Based on the petrology and petrography of these serpentinites, five events are recognized: (1) formation of a wehrlite–harzburgite–dunite association in the mantle; (2) retrograde metamorphism and partial hydration during exhumation of the mantle rocks close to the seafloor; (3) oceanic metamorphism leading to the first serpentinization and rodingitization; (4) UHP metamorphism during subduction; (5) retrograde metamorphism during exhumation together with a second serpentinization. The peak metamorphic mineral assemblage of the serpentinized wehrlite comprises Ti-chondrodite + olivine + antigorite + chlorite + magnetite + brucite. A computed pseudosection for this serpentinized wehrlite shows that the Al content in antigorite is mostly sensititive to temperature but can also be used to constrain pressure. The average XAl = 0·204 ± 0·026 of antigorite (XAl = Al (a.p.f.u.)/8, where Al is in atoms per formula unit for a structural formula M48T34O85(OH)62, and M and T are octahedral and tetrahedral sites, respectively) included in Ti-chondrodite and average XAl = 0·203 ± 0·019 of antigorite in the matrix result in a well-constrained peak metamorphic temperature of 510–530°C. Peak pressures are less precisely constrained at 37 ± 7 kbar. The Tianshan serpentinites thus record UHP metamorphic conditions and represent the deepest subducted serpentinites discovered so far. The retrograde evolution occurs within the stability field of brucite + antigorite + olivine + chlorite and formation of Ti-clinohumite at the expense of Ti-chondrodite has been observed, suggesting isothermal decompression. The resulting P–T path is in excellent agreement with the metamorphic evolution of country rocks, indicating that the UHP unit in Tianshan was subducted and exhumed as a coherent block. To refine the metamorphic path of the ultramafic rocks, we have investigated the stability fields of Ti-chondrodite and Ti-clinohumite using piston-cylinder experiments. A total of 11 experiments were conducted at 25–55 kbar and 600–750°C in a F-free natural system. Combined with previous experiments and information from natural rocks we constructed a petrogenetic grid for the stability of Ti-chondrodite and Ti-clinohumite in F-free peridotite compositions. The formation of Ti-chondrodite in serpentinites requires a minimum pressure of about 26 kbar, whereas in Ti-rich systems it can form at considerably lower pressures. A key finding is that at UHP conditions, F-free Ti-chondrodite or Ti-clinohumite breaks down in the presence of orthopyroxene between 700 and 750°C, at temperatures that are significantly lower than those of the terminal breakdown reactions of these humite minerals. These breakdown reactions are an additional source of fluid during prograde subduction of serpentinites.
ISSN: 0022-3530

hal-01243507
https://hal.archives-ouvertes.fr/hal-01243507
DOI : 10.1093/petrology/egv042

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The analysis of field relationships between allochthonous crystalline slivers, ultramafic units and associated sedimentary cover in the high-pressure Schistes Lustrés units of northern Corsica allows reconstruction of the pre-orogenic architecture of a fossil Mesozoic Ocean-Continent Transition (OCT) of the Tethys basin. The studied area, encompassing the Serra di Pigno and Col de Téghime areas (Cap Corse) is composed of an assemblage of prealpine basement sheets made up of serpentinized mantle rocks, Permian gabbros and gneisses, locally associated with Paleozoic metabasites and micaschists. The sedimentary cover includes numerous intervals of calc-schists, marbles, quartzites, micaschists and dolomitic metabreccias yielding a great variety of lithostratigraphical successions. The metasedimentary sequences do not show affinities with the typical cover series of the Prépiémontais margin domains. This implies an origin from a more internal domain (oceanward) for the studied units. In addition, the sedimentary cover of the ultramafic basement units do not display the characters of the classical Alpine ophiolites but bear lithological features showing affinities with both continental and oceanic environments. We assume that the high variability of the sedimentary successions as well as the presence of a basement composed of continental and upper-mantle rocks is consistent with an origin at an OCT. The acidic basement slivers are regarded as former extensional allochthons of continental crust abandoned during breakup on a newly exhumed seafloor of peridotite composition. Such extensional allochthons, will then logically constitute the most internal continental slices buried at great depth during Alpine subduction. This work shows that a lot has to be expected from a revision of the Schistes Lustrés lithostratigraphy in the light of the new concepts of the evolution of the OCT domains.
ISSN: 0040-1951

hal-00795578
https://hal.archives-ouvertes.fr/hal-00795578
DOI : 10.1016/j.tecto.2012.06.013

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Massif du Sud is a large ophiolitic complex that crops out in the southern region of New Caledonia (SW Pacific). It is dominated by harzburgite tectonite that locally shows a transitional gradation to massive dunite up section. Clinopyroxene, orthopyroxene and plagioclase progressively appear in dunite up to the transition to layered wehrlite and orthopyroxene-gabbro. The dunite-wehrlite and wehrlite-gabbro contacts are parallel and the latter defines the paleo-Moho.;Highly depleted modal, mineral and bulk rock compositions indicate that harzburgites are residues after high degrees (20-30%) of partial melting mainly in the spinet-stability field. Their relative enrichment in HFSE, LREE and MREE is due to re-equilibration of melting residues with percolating melts. Dunite formed in the Moho transition zone by reaction between residual mantle harzburgite and olivine-saturated melts that led to pyroxene dissolution and olivine precipitation. Rare clinopyroxene and plagioclase crystallized in interstitial melt pores of dunite from primitive, low-TiO2, ultra-depleted liquids with a geochemical signature transitional between those of island arc tholeiites and boninites.;Ascending batches of relatively high-SiO2, ultra-depleted melts migrated through the Moho transition zone and generated wehrlite by olivine dissolution and crystallization of clinopyroxene, orthopyroxene and plagioclase in variable amounts. These liquids were more evolved and were produced by higher degrees of melting or from a more depleted source compared with melts that locally crystallized clinopyroxene in dunite. Ultra-depleted magmas, non-cogenetic with those that formed the Moho transition zone, ascended to the lower crust and generated gabbroic cumulates with subduction-related affinity. Thus, the ultramafic and mafic rocks in the Moho transition zone and lower crust of the Massif du Sud ophiolite are not products of fractional crystallization from a single magma-type but are the result of migration and accumulation of different melts in a multi-stage evolution. The record of high partial melting in the mantle section, and migration and accumulation of ultra-depleted subduction-related melts in the Moho transition zone and lower crust support that the Massif du Sud ophiolite is a portion of forearc lithosphere generated in an extensional regime during the early phases of the subduction zone evolution. Our results show the existence of different types of ultra-depleted melt compositions arriving at the Moho transition zone and lower crust of an infant intraoceanic paleo-arc. Ultra-depleted melts may thus be a significant component of the melt budget generated in oceanic spreading forearcs prior to aggregation and mixing of a large range of melt compositions in the crust.
ISSN: 0009-2541

hal-00429333
https://hal.archives-ouvertes.fr/hal-00429333
DOI : 10.1016/j.chemgeo.2009.06.004

Éditeur(s) : HAL CCSD Integrated Ocean Drilling Program
Résumé : This contribution is a compilation of electron microprobe analyses of primary minerals in mafic and ultramafic oceanic crustal rocks from Atlantis Massif. The samples were recovered during Integrated Ocean Drilling Program Expedition 304/305, which was designed to investigate the formation and evolution of oceanic core complexes. The analyses were performed at five different institutions, and while common standard reference materials were not utilized at all institutions, internal standards and routine operational protocols were undertaken to assure analysis quality. More than 5000 analyses of plagioclase, pyroxene, olivine, and spinel are compiled here as a collaborative effort to provide mineral analyses to the expedition shipboard science party and other interested researchers.
ISSN: 1930-1014

hal-00464225
https://hal.archives-ouvertes.fr/hal-00464225
DOI : 10.2204/iodp.proc.304305.202.2009

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Analysis of the microstructures in the km-scale mantle shear zone that separates the northern and the central parts of the Lanzo peridotite massif provides evidence of an evolution in time and space of deformation processes accommodating shearing in the shallow mantle within an extensional setting. This shear zone displays an asymmetric distribution of deformation facies. From south to north, gradual reorientation of the foliation of coarse porphyroclastic plagioclase-bearing peridotites is followed by development of protomylonites, mylonites, and mm-scale ultramylonite bands. A sharp grain size gradient marks the northern boundary. Early deformation under near-solidus conditions in the south is recorded by preservation of weakly deformed interstitial plagioclase and almost random clinopyroxene and plagioclase crystal orientations. Feedback between deformation and melt transport probably led to melt focusing and strain weakening in the shear zone. Overprint of melt-rock reaction microstructures by solid-state deformation and decrease in recrystallized grain size in the protomylonites and mylonites indicate continued deformation under decreasing temperature. Less enriched peridotite compositions and absence of ultramafic dykes or widespread melt-impregnation microstructures north of the shear zone and clinopyroxene and amphibole enrichment in the mylonites and ultramylonites suggest that the shear zone acted as both a thermal barrier and a high-permeability channel for late crystallizing fluids. These observations, together with chemical data indicating faster cooling of central Lanzo relative to the northern body, corroborate that this shear zone is a mantle detachment fault. All deformation facies have crystal preferred orientations consistent with deformation by dislocation creep with dominant activation of the (010)[100] and (100)[001] systems in olivine and orthopyroxene, respectively. Dynamic recrystallization produces dispersion of olivine CPO but not a change of dominant deformation mechanism. Evidence for activation of grain boundary sliding is limited to mm-scale ultramylonite bands, where solid-state reactions produced very fine grained polymineralic aggregates. Except for these latest stages of deformation, strain localization does not result from the microstructural evolution; the grain size decrease is a consequence of the need to deform a rock volume whose strength continuously increases because of decreasing temperature conditions. Strain localization in the intermediate levels thus essentially results from the more localizing behavior of both the deep, partially molten, and shallow parts of this extensional shear zone distribution.
ISSN: 1525-2027

hal-00644844
https://hal.archives-ouvertes.fr/hal-00644844
DOI : 10.1029/2011GC003627

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : International audience
– The 300 km long allochthonous sheet of oceanic mantle forming the New Caledonia ophiolite displays three specific characters: 1) the ophiolite pile lacks concordant sheeted dykes and pillow basalt layers; 2) the ophiolite, refered to as the Peridotite nappe, is thrusted over the basaltic formations of the Poya terrane which are classicaly thought to originate from a different oceanic environment; 3) The basal contact of the ultramafic sheet is remarkably flat all along New-Caledonia and the Peridotite nappe has not been thickened during obduction, rather it experienced significant extension. This suggests that the peridotites have not been emplaced by a tectonic force applied to the rear. New petrological and geochemical results obtained from mantle rocks finally show that the Poya terrane may originate from the same oceanic basin as the peridotites. In this article, we consider such possible cogenetic links and we propose a simple model for the obduction of the New Caledonia ophiolite in which the Poya basalts represent the original cover of the Peridotite nappe. We infer that continuous uplift of the subducted units buried beneath the oceanic lithosphere in the northern part of New Caledonia drove passive uplift of the ophiolite and led to erosion and to initiation of sliding of the basaltic layer. During the Priabonian (latest Eocene), products of the erosion of the basaltic layer were deposited together with sediments derived from the Norfolk passive oceanic margin. These sediments are involved as tectonic slices into an accretionary wedge formed in response to plate convergence. The volcaniclastic sedimentation ends up with the emplacement of large slided blocks of basalts and rafted mafic units that progressively filled up the basin. Obduction process ended with the gravity sliding of the oceanic mantle sheet, previously scalped from its mafic cover. This process is contemporaneous with the exhumation of the HP-LT units of Pouebo and Diahot. Gravity sliding was facilitated by the occurrence of a continuous serpentine sole resulting from metasomatic hydratation of mantle rocks, which developed during the uplift of the Norfolk basement and overlying Diahot and Pouébo units. Progressive emersion of the obducted lithosphere allowed subsequent weathering under subaerial, tropical conditions. Obduction passive et mise en place gravitaire des grandes nappes ophiolitiques : les ophiolites de Nouvelle-Calédonie (SW Pacifique) sont-elles un cas d'école ? Résumé. – La nappe de manteau de Nouvelle-Calédonie, s'étendant sur 300 km de long montre trois caractéristiques im-portantes: 1) La succession ophiolitique ne contient ni dykes, ni basaltes en coussin, 2) l'ophiolite est charriée sur des formations basaltiques (nappe de Poya) que l'on considère classiquement comme originaires d'un bassin océanique dif-férent de celui d'où est issu le manteau, et 3) le contact basal de la nappe ultrabasique est remarquablement plat tout le long de l'île et celle-ci n'a pas été épaissie durant l'obduction. Cela suggère que les péridotites n'ont pas été mises en place en réponse à une poussée tectonique arrière. De nouveaux résultats pétrologiques et géochimiques obtenus sur l'ophiolite montrent en réalité que les basaltes de Poya peuvent être extraits de la fusion du manteau de l'ophiolite. Nous proposons donc un nouveau modèle pour l'obduction, dans lequel les basaltes de Poya forment la couver-ture initiale primitive du manteau de la nappe des péridotites. La surrection progressive des unités profondes enfouies lors de la subduction de la lithosphère du bassin sud-Loyauté à l'Eocène, a permis le soulèvement passif de l'ophiolite et l'érosion puis le glissement des unités basaltiques. Durant le Priabonien, l'accumulation des produits de l'érosion de la couche des basaltes et de la marge passive de Norfolk ont formé les séquences de flysch comprenant localement des débris basaltiques grossiers. Ces sédiments font partie d'un prisme d'accrétion tectonique construit en réponse à la convergence au front de la subduction. La sédimentation détritique se termine par la mise en place de grandes unités ba-saltiques glissées qui comblent le bassin. Le processus de l'obduction se termine par le glissement gravitaire de l'écaille de manteau océanique sur les basaltes. Cet événement est contemporain de l'exhumation des unités HP-BT de Pouébo et du Diahot. Le glissement gravitaire a été facilité par la présence sous l'ophiolite, d'une semelle continue de serpentines résultant de l'interaction du manteau avec des fluides métasomatiques remontant durant l'exhumation des unités en-fouies pendant la subduction continentale. L'émersion progressive de la lithosphère obduite a placé le manteau dans des conditions d'altération supergène tropicale.
EISSN: 1777-5817

hal-01257702
https://hal.archives-ouvertes.fr/hal-01257702
https://hal.archives-ouvertes.fr/hal-01257702/document
https://hal.archives-ouvertes.fr/hal-01257702/file/Lagabrielleetal-BSGF-2012-revised-light.pdf
DOI : 10.2113/gssgfbull.184.6.545