Éditeur(s) : HAL CCSD
Résumé : Le projet METYSS (Messinian Event in the Tyrrhenian from Seismic Study) concerne le bassin tyrrhénien occidental le long de la côte est-sarde et s'intègre dans le cadre d'une étude comparative des marqueurs sismiques de la Crise de Salinité Messinienne (CSM) à l'échelle du bassin méditerranéen. La mer tyrrhénienne est un bassin arrière-arc néogène lié à la subduction calabraise. Le rifting débute sur la marge est-sarde au cours du Tortonien et du Messinien, impliquant au moins localement une contemporanéité des dépôts de la CSM avec les processus de rifting qui segmente la marge en plusieurs sous-bassins. Cette région est donc particulièrement adaptée à la caractérisation et à l'organisation des dépôts messiniens en contexte de tectonique active. L'identification des marqueurs de la CSM et la détermination de leurs caractéristiques spatio-temporelles (faciès, géométrie, distribution et relations) ont été effectuées à partir de l'interprétation de 1200 km de profils sismiques multitraces HR acquis en 2009 lors de la campagne METYSS-1 sur le N/O "Téthys II". L'un des premiers résultats est que l'on retrouve dans cette zone les marqueurs caractéristiques de la CSM, comparables à ceux déjà observés dans le bassin méditerranéen occidental : surfaces d'érosion (MES, TES, BES) et unités messiniennes typiques (UU: Upper Unit; MU: Mobile Unit). La réalisation des cartes de répartition de ces unités sismiques permet d'en déterminer la variabilité spatiale, et notamment d'affiner celle de la couche de sel (MU), par rapport aux données pré-existantes. Ainsi, le long de la partie haute de la marge est-sarde, la rareté de l'unité MU et la présence des UU semblent indiquer que cette zone se situait à une profondeur intermédiaire pendant la crise. Inversement, plus profondément dans le bassin, l'épaisseur importante de la couche de sel sous les UU, témoigne d'une profondeur déjà conséquente de cette zone durant la CSM. On remarque également que dans le secteur nord de la zone d'étude, la répartition de MU est contrainte par les blocs basculés, le sel étant confiné dans les sous-bassins qui segmentent la marge. Dans le secteur sud, la répartition de la couche de sel est plus homogène dans le bassin profond, et est déformée par une tectonique salifère active. A terme, nous souhaitons utiliser les marqueurs de la CSM pour reconstituer les paléo-connexions et paléo-profondeurs des différents bassins de la zone, mais également comprendre les interactions entre tectonique crustale, tectonique salifère, et sédimentation. L'objectif est aussi de restituer l'évolution tectono-sédimentaire de la marge est-sarde depuis 6Ma.
13ème Congrès Français de Sédimentologie
Dijon, France

hal-00657315
https://hal-brgm.archives-ouvertes.fr/hal-00657315

Éditeur(s) : HAL CCSD Electrochemical Society, Inc.
Résumé : International audience
ISSN: 1938-5862

hal-01683130
https://hal.univ-antilles.fr/hal-01683130
DOI : 10.1149/06426.0001ecst

Éditeur(s) : HAL CCSD
Résumé : The Tyrrhenian Sea is usually interpreted to be a Neogene back-arc basin that opened by continental rifting and oceanic spreading caused by the eastward migration of the Apennine subduction system from Tortonian to Pliocene times. Rifting of the Tyrrhenian Sea started first along the Eastern Sardinian margin during the Tortonian-Messinian times. The " METYSS " project aims at better constraining the relations between crustal tectonics, salt tectonics and sedimentation from Messinian times to present-day. The " METYSS 1 " cruise (2009, R/V "Téthys II"-INSU) allowed us to obtain about 1200 km of high-resolution seismic reflection profiles along the SE Corsican margin, and along the upper and middle parts of the Eastern Sardinian margin, Western Tyrrhenian. This new dataset clearly illustrates that this area has been highly dissected during the rifting stage by N-S trending normal faults delineating ridges and basins, as previously described. The Messinian seismic markers (UU and MU) locally display fan-shaped stratal geometries, but the mechanism responsible for such geometries, i.e., salt tectonics or rifting, has yet to be carefully deciphered. We also mapped the spatial distribution of the mobile salt (MU). The highly variable thickness of the confined salt basins may be related to the initial pre-Messinian basin geometry or to the fact that sediment deposition was syn-rift. Southeastward, salt tectonics appears highly vigorous. More surprisingly, our data demonstrate that some of the major faults have been significantly reactivated during the post-rift period, up to late Quaternary time. Such recent fault activity has been recorded by bathymetric scarps and associated footwall debris flows. Moreover, some of this post-rift deformation can be evidenced within the Plio-Quaternary sequence by a regional unconformity. The post-Miocene deformation style varies greatly between different areas of the margin, and can also be strongly influenced by the presence or absence of mobile Messinian evaporites (MU).
13ème Congrès Français de Sédimentologie
Dijon, France

hal-00657310
https://hal-brgm.archives-ouvertes.fr/hal-00657310

Éditeur(s) : HAL CCSD Berlin: A. Asher & Co.
Résumé : International audience
In this work, we compare IASI-retrieved vertical water vapour profiles and related precipitable water over a complex region, namely the Rhine Valley area, during the pre-operational period of IASI exploitation (June?August 2007). Both IASI water vapour mixing ratio profiles and integrated water vapour content are retrieved from L1C radiances spectra using two techniques and compared with water vapour related observations acquired during the Convective and Orographically-induced Precipitation Study (COPS) field campaign that took place in this area at that time (i.e. lidars, radiosoundings and a global positioning system - GPS - station network). This work addresses the issue of IASI vertical spatial resolution and its capability to detect two-layer water vapour structures such as those observed in a mountainous area and which play an important role in convective initiation or inhibition. We found that this capability mostly relies on the type of a-priori background vector (climatology or space-time colocated ECMWF analysis), which is used within the retrieval scheme. Systematic comparison of water vapour products derived from 71 IASI spectra confirms that IASI can retrieve water vapour amounts in 2 km width layers, in the lower troposphere, with an accuracy of approximately 10%.
ISSN: 0369-1845

hal-00923710
https://hal.archives-ouvertes.fr/hal-00923710
https://hal.archives-ouvertes.fr/hal-00923710/document
https://hal.archives-ouvertes.fr/hal-00923710/file/masiello.pdf
DOI : 10.1127/0941-2948/2013/0430

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The biogeochemistry of sulfur and carbon during early-diagenetic processes within organic-rich marine mangrove sediments was studied in the “Manche à Eau” lagoon, Guadeloupe, West Indies. These sediments are characterized by a total organic carbon content (TOC) mostly above 11 wt%, δ13CTOC below − 25‰ VPDB and C/Nmolar ratios exceeding 15. Rates of mangrove-derived organic carbon accumulation vary between ~ 200 and 400 gOC·m− 2·yr− 1, with highest rates at the shore of the lagoon. On the lagoon border, where colorless filamentous sulfur-oxidizing bacteria colonize the sediments, active sulfate reduction within the upper 20 cm, with a net removal rate of ~ 0.5 μmol·cm− 3·d− 1, is assumed to be essentially driven by organic carbon oxidation. This is expressed by relatively low apparent sulfur isotope fractionation (34εnet = − 33‰) and a gentle δ18O/δ34Ssulfate apparent slope of 0.36 ± 0.03 (2s). Further inside the lagoon, in the absence of sulfur-oxidizing bacteria, higher apparent sulfur isotope fractionation and a steeper δ18O/δ34Ssulfate slope (0.67 ± 0.20) suggest an overall lower sulfate removal rate that may be coupled to minor sulfur disproportionation. Spatial and vertical variation in sulfur cycling, reflected by oxygen and sulfur isotopic characteristics, seem to be mainly controlled by unsteady to relatively steady organic matter deposition and its reactivity. In all sediments, δ34S values of pyrite are positively correlated with the TOC/TS ratio and negatively correlated with δ13CTOC; suggesting a primary control of the quantity and quality of organic matter on the pyrite isotope records, despite potential iron-limiting conditions for the most active sites. Our results provide insights into the role of organic carbon input on sulfur cycling; stimulating sulfate reduction and in turn the presence of sulfur-oxidizing microbial mats, resulting in an intense cycling of both carbon and sulfur in these marine mangrove sediments.
ISSN: 0009-2541

hal-01507696
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01507696
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01507696/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01507696/file/Cr%C3%A9mi%C3%A8re%20et%20al.%20-%20Sulfur%20diagenesis%20under%20rapid%20accumulation%20of%20orga.pdf
DOI : 10.1016/j.chemgeo.2017.02.017

Éditeur(s) : HAL CCSD Elsevier
Résumé : The current interpretation of the Messinian Salinity Crisis (MSC) involves the deposition of the so-called “peripheral or marginal” evaporites in onshore basins, as well as the erosion of the margins and the formation of thick evaporites in the deep parts of the basins. The present study focuses on intermediate depth basins, i.e. located between the onshore outcrops and the deep basins. Indeed, the Balearic Promontory shows small stepped basins filled with MSC deposits between its western extremity on the Alicante shelf and its eastern end around the Menorca block. New and already available seismic reflection profiles and onshore data allow us to investigate the nature and geometrical relationships of these deposits in the area between the islands of Ibiza and Mallorca.Our observations suggest the existence of three MSC-related units in this area. The lowermost transparent seismic unit can be interpreted as a 100 to 200-m-thick salt layer deposited in the deepest part of the Central Mallorca Depression. These evaporites pass laterally and upward into a thin-bedded seismic unit, which could be lithologically equivalent to the Upper Evaporites of the deep basins. All around the borders of the Central Mallorca Depression, this bedded seismic unit onlaps a Slope Unit which shows bedded to chaotic and rafted facies. The Messinian continental shelf is eroded and incised by a valley extending from the Palma onshore area to the Mallorca downslope domain.Our results suggest the presence offshore of at least two generations of diachronous MSC deposits. The observation of salt on a continental high and the widespread MSC deposits on the margins of the Central Mallorca Depression call into question the location of halite preferentially in the deep abyssal basins and the significance of the deep basin MSC units that onlap onto the Margin Erosional Surface (MES), as observed all around the passive margins of the Northwest-Mediterranean Basin. The dual terminology used for peripheral/deep MSC evaporites cannot be applied to any of the MSC units found in the study area.
ISSN: 0025-3227

hal-01115656
https://hal.archives-ouvertes.fr/hal-01115656
DOI : 10.1016/j.margeo.2014.10.001

Éditeur(s) : HAL CCSD
Résumé : Le projet terre-mer METYSS a pour objectif de comprendre les effets immédiats et différés de la Crise de Salinité Messinienne (CSM) ainsi que les relations tectonique et sédimentation sur la marge est-sarde. Cette marge résulte de l'ouverture de la Mer Tyrrhénienne à partir du Tortonien et jusqu'au Messinien (c. 9 à 5 Ma). Des bassins profonds existaient déjà au Messinien dans le domaine tyrrhénien, comme l'atteste l'identification, à partir des données sismiques, d'épaisses séries évaporitiques messiniennes (Gaullier et al., 2009). Le principal canyon creusé dans la marge est connecté en amont avec le golfe d'Orosei, où affleurent à terre les seuls dépôts pliocènes connus. Dans la région d'Orosei, ces dépôts correspondraient donc potentiellement au remplissage de la partie amont des incisions liées à la CSM, lors de la remise en eau de la Méditerranée, comme c'est le cas en de nombreux endroits du pourtour méditerranéen (Clauzon, 1982). Les investigations de terrain MeTySar-2010 montrent que le principal fleuve actuel, le Cedrino, suit le cours d'une paléovallée qui incise le soubassement granitique et ses altérites. Ces dépôts ont été érodés (au Messinien ?) puis remaniés lors d'une transgression marine. Les microfaunes, présentes dans les faciès marins fins, indiquent un âge Pliocène supérieur (Giresse et al., ce congrès). Cette série marine présente des pendages de l'ordre de 20 à 30 ° qui s'organisent selon une direction NNE-SSW, subparallèle aux structures tectoniques majeures associées au rifting de la marge est-sarde. Le basculement des séries pliocènes est scellé par un ensemble de coulées volcaniques dont les plus anciennes sont datées du Quaternaire ancien. La cartographie et la caractérisation des dépôts mettent en évidence un paléo-relief orienté NNE-SSW qui contrôle la répartition des unités sédimentaires. Ces résultats suggèrent que l'activité tectonique post-messinienne participe au contrôle de l'architecture et de la paléogéographie des séries pliocènes dans ce secteur. Aucune trace de dépôts marins du Pliocène Inférieur, ni de Gilbert deltas s.s. n'a été relevée à terre. La transgression observée au Pliocène supérieur sur cette bordure du bassin implique 1) une position haute de la marge au Pliocène inférieur, et 2) une forte subsidence de ce secteur de la marge au Pliocène moyen. Cette subsidence serait la conséquence de l'activité tectonique post-rift, par ailleurs mise en évidence en mer grâce à deux campagnes récentes (METYSS 1 et 3, Gaullier et al., ce congrès).
13ème Congrès Français de Sédimentologie
Dijon, France

hal-00657307
https://hal-brgm.archives-ouvertes.fr/hal-00657307

Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : This study describes normal fault zones formed in foreland arkosic turbidites (the Grès d'Annot Formation, SW French Alps) under deep diagenesis conditions (~200 °C) and highlights the occurrence of two markedly different fault-rock types: (1) the foliated fault rocks of the Moutière-Restefond area; and (2) the dilatant fault rocks of the Estrop area. The deformation of (1) is dominated by intra- and transgranular fracturing, pressure solution of quartz and feldspar grains and syn-kinematic phyllosilicate precipitation resulting from feldspar alteration. The combination of these mechanisms results in a strongly anisotropic strain with intense shortening normal to the foliation (pressure solution) and extension parallel to the foliation (quartz- and calcite-sealed extension veins). This deformation implies local mass transfer that may be achieved without (or with limited) volume change. The deformation of (2) is expressed as dilatant quartz-sealed veins and breccia textures in which the main mechanisms are transgranular fracturing and quartz precipitation. Type (2) implies fault volume increase, isotropy of deformation and mass transfer at distances larger than in type (1). This study discusses the origins of (1) and (2) and shows that the permeability of (1) is anisotropic, with higher values than the host rocks parallel to the Y main deformation axis (i.e. perpendicular to the slip vector), whereas the permeability of (2) is isotropic and equivalent to that of the host rocks.
ISSN: 0954-4879

hal-01115177
https://hal.archives-ouvertes.fr/hal-01115177
DOI : 10.1111/ter.12100

Éditeur(s) : HAL CCSD Taylor & Francis (Routledge)
Résumé : International audience
This article presents the institutional implications and ideologies in the organisation of a Sports Movement for the disabled, whether a physical or sensory handicap, and focusing particular attention on its development in France, linked with international structures. The emergence and development in France of sports organisations for the disabled is based on a different model from that introduced in England by Guttmann through the Stoke Mandeville Games. From the 1960s, both trends, one supported by physicians and the other by individuals concerned with disabilities, structured the International Movement as a contest of negotiations and competition. The objective of rehabilitating paraplegics put in place at Stoke Mandeville gradually gave way to a sport rational and the integration of all types of disability within the Movement. The desire to unite in a single organisation was the driving force of the Movement in its search for dual recognition, on the one hand, as the representative of all physical and sensory deficiencies and, on the other, by the able-bodied sports councils and, in particular, the International Olympic Committee. However, this raised a number of issues inherent to any deficiency when taking into account its specific peculiarities.
ISSN: 0952-3367

hal-01681857
https://hal.archives-ouvertes.fr/hal-01681857
DOI : 10.1080/09523367.2014.931842

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Mantle noble gases record important and ancient isotopic heterogeneities, which fundamentally influence our understanding of mantle geodynamics, yet these heterogeneities are difficult to fully interpret without understanding the basic mechanisms of noble gas storage and transport in mantle minerals. A series of annealing experiments that mimic mantle conditions (i.e. sub-solidus with natural, polycrystalline, texturally equilibrated olivines at low noble gas partial pressures) show that intergranular interfaces (grain boundaries) are major hosts for noble gases in the mantle, and that interfaces can dramatically fractionate noble gases from their radio-parents (U + Th and K). Therefore, noble gas isotopic heterogeneities in the mantle could result from grain size variations. Fine-grained lithologies (mylonites and ultramylonites, for example) with more grain boundaries will have lower U/3He ratios (compared to a coarse grained equivalent), which, over time, will preserve higher 3He/4He ratios. As predicted by theory of points defect diffusivity, these results show that noble gas diffusion along interfaces is different from those in the grain lattice itself at low temperatures. However, for grain size relevant of the Earth's mantle, the resulting effective correlated activation energies (Ea)(Ea) and pre-exponential factors (Do/a2)(Do/a2) produce similar diffusivities at mantle temperatures for interface- and lattice-hosted helium. Therefore, grain boundaries do not significantly affect helium transport at mantle conditions and length scales.
ISSN: 0012-821X

hal-01236013
https://hal.archives-ouvertes.fr/hal-01236013
DOI : 10.1016/j.epsl.2015.08.024

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We propose a new geometric approach to describe the qualitative dynamics of chemical reactions networks. By this method we identify metastable regimes, defined as low dimensional regions of the phase space close to which the dynamics is much slower compared to the rest of the phase space. These metastable regimes depend on the network topology and on the orders of magnitude of the kinetic parameters. Benchmarking of the method on a computational biology model repository suggests that the number of metastable regimes is sub-exponential in the number of variables and equations. The dynamics of the network can be described as a sequence of jumps from one metastable regime to another. We show that a geometrically computed con-nectivity graph restricts the set of possible jumps. We also provide finite state machine (Markov chain) models for such dynamic changes. Applied to signal transduction models, our approach unravels dynamical and functional * corresponding author capacities of signalling pathways, as well as parameters responsible for speci-ficity of the pathway response. In particular, for a model of TGFβ signalling, we find that the ratio of TGFBR2 to TGFBR1 receptors concentrations can be used to discriminate between metastable regimes. Using expression data from the NCI60 panel of human tumor cell lines, we show that aggressive and non-aggressive tumour cell lines function in different metastable regimes and can be distinguished by measuring the relative concentrations of receptors of the two types.
ISSN: 0303-2647

hal-01379033
https://hal.inria.fr/hal-01379033
https://hal.inria.fr/hal-01379033/document
https://hal.inria.fr/hal-01379033/file/Samal_et_al_Biosystems_final.pdf
DOI : 10.1016/j.biosystems.2016.07.004

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
ISSN: 0013-4686

hal-01683184
https://hal.univ-antilles.fr/hal-01683184
DOI : 10.1016/j.electacta.2013.12.023

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
ISSN: 0013-4686

hal-01683183
https://hal.univ-antilles.fr/hal-01683183
DOI : 10.1016/j.electacta.2013.12.070

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In this study, we propose a theoretical approach to test the validity of the isomechanical analogues for post-perovskite structures. Intrinsic plastic properties are evaluated for three materials exhibiting a post-perovskite phase: MgSiO3, MgGeO3 and CaIrO3. Dislocation properties of each structure are determined using the Peierls-Nabarro model based on first-principles calculations of generalised stacking fault and the plastic properties are extended to crystal-preferred orientations using a visco-plastic self-consistent method. This study provides intrinsic parameters of plastic deformation such as dislocation structures and Peierls stresses that can be directly compared between the three materials. It appears that it is very difficult to draw any simple conclusions on polycrystalline deformation simply by comparing single crystal properties. In particular, contrasting single crystal properties of MgSiO3 and CaIrO3 lead to similar crystal-preferred orientation of the polycrystal aggregates.
ISSN: 0031-9201

hal-00420104
https://hal.archives-ouvertes.fr/hal-00420104
DOI : 10.1016/j.pepi.2008.04.003

Éditeur(s) : HAL CCSD Institut Henri Poincaré-Nonlinéaire Publications
Résumé : International audience
Depuis quelques décennies, l'énergie éolienne connaît une croissance considérable. Cependant cette énergie est dépendante de la vitesse du vent variant en intensité sur des échelles de temps qui incluent l'année, la journée à quelques secondes. Il est donc fondamental de bien parvenir à comprendre et décrire le caractère non-linéaire et stochastique de ces fluctuations dans la production électrique issue des éoliennes. L'objectif de ce travail est de caract'eriser les fluctuations d'une série temporelle de production éolienne. Dans un premier temps, nous vérifions l'utilisation de la loi de Taylor, relation de puissance entre l'écart-type et la moyenne. Cette relation fut observée en écologie, en finance, dans les sciences du vivant et pour des données de traffic internet. De récents travaux fournissent des hypothèses d'explication quant à l'origine de cette loi cite{Agata2010,Kendall2011}. L'exposant alpha caractérise le type de dynamique du processus considéré et varie entre 1/2 et 1. Dans notre cas d'étude, l'estimation de l'exposant alpha est proche de 1. Quand alpha=1, les processus considérés sont à invariance d'échelle cite{eisler2008}. Pour mettre en évidence les propriétés d'invariance d'échelle de notre série temporelle, nous effectuons une analyse multifractale pour estimer la fonction exposant d' échelle l'aide des moments d'ordre $q$ de l'incrément temporel des données de production éolienne $Delta P=P(t+ au)-P(t)$, telle que $<(Delta P_ au)^q>simeq au^{zeta(q)}$ cite{Schertzer1997}. La fonction $zeta(q)$ est concave et non-linéaire: plus elle est concave, plus la série analysée sera intermittente. Nous montrons que la série temporelle de la production éolienne considérée est intermittente et possède des propriiétés multifractales. De plus le modèle de cascades aléatoires log-normal se révèle pertinent pour décrire ces fluctuations.
Compte-rendus de la 15ème Rencontre du non-linéaire

hal-01527884
https://hal.archives-ouvertes.fr/hal-01527884

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
ISSN: 2046-2069

hal-01116129
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01116129
DOI : 10.1039/C3RA47255H

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Demerara plateau, located offshore French Guiana and Suriname, is part of a passive transform continental margin particularly prone to develop slope instabilities, probably in relation to the presence of a free distal border along its steep continental slope. Slope failure occurred at different periods (Cretaceous to Neogene) and shows an overall retrogressive evolution through time. Upslope these failure headscarp, an enigmatic regional Mio-Pliocene unconformity has been discovered through the interpretation of new academic and industrial datasets. The aim of this work is to describe and understand the origin of this surface. Our analysis shows that this unconformity is made of a series of valleys that cross-cut sedimentary strata. Each one of these valleys has a short lateral extent and is closed along two perpendicular directions, which suggests that it could correspond to a highly meandering system, or to some sub-circular depressions. The infill of these features is equivalent to the regional stratigraphic strata found outside the structures, but in a subdued position. This seems to imply that the structures have originated by a local loss of sediments at their base or by sliding processes. Furthermore, these depressions intersect each other through time, while migrating progressively downslope.We discuss a series of hypotheses that try to explain the onset and evolution of these depressions forming the Mio-Pliocene unconformity (Canyons? Slope failures? Contourite moats? Hydrate pockmarks?). Having established that these structures are depressions formed by collapse, and have many similarities with structures recently described in the literature as pockmarks associated with gas hydrate dissolution, we favor this hypothesis.We propose that these hydrate pockmarks form with a mass failure that was triggered by fluid-overpressure development at the base of the hydrate stability zone.
ISSN: 0025-3227

hal-01365920
https://hal.archives-ouvertes.fr/hal-01365920
DOI : 10.1016/j.margeo.2015.04.001

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
To test if hydrogen incorporation by ionic diffusion can occur between a volatile-rich kimberlitic liquid and forsterite, results of high-pressure and high-temperature experiments using a piston-cylinder apparatus at 1200–1300 °C and 1 GPa for durations of 1 min, 5 h, and 23 h, are reported here. Kimberlitic liquid in the system CaO-MgO-Al2O3-SiO2-CO2-H2O and synthetic forsterite single crystals were chosen as a first simplification of the complex natural kimberlite composition. Unpolarized Fourier transform infrared spectroscopy was used to quantify the concentrations of OH in the crystallographically oriented forsterite. Scanning electron microscopy, electron backscattered diffraction, electron microprobe analyses, and transmission electron microscopy were performed to identify the run products. After 5 and 23 h, a forsterite overgrowth crystallized with the same orientation as the initial forsterite single crystal. The kimberlitic liquid has crystallized as micrometer-scale euhedral forsterite neocrystals with random crystallographic orientations, as well as a nanoscale aluminous phase and a calcic phase. Despite theoretical water-saturation of the system and long duration, none of the initial forsterite single crystals display signs of hydration such as hydrogen diffusion profile from the border toward the center of the crystal. Most likely, the presence of CO2 in the system has lowered the H2O fugacity to such an extent that there is no significant hydration of the starting forsterite single crystal or its overgrowth. Also, the presence of CO2 enhances rapid forsterite crystal growth. Forsterite growth rate is around 2 × 108 μm3/h at 1250 °C. These experimental results suggest a deep mantle origin of the high OH content found in natural mantle-derived xenoliths transported in kimberlites, as reported from the Kaapvaal craton. In agreement with previous studies, it also points out to the fact that significant hydration must take place in a CO2-poor environment.
ISSN: 0003-004X

hal-01217157
https://hal.archives-ouvertes.fr/hal-01217157
DOI : 10.2138/am-2015-5200

Éditeur(s) : HAL CCSD Elsevier Masson
Résumé : National audience
Contexte La qualité de l’air ambiant dans les enceintes de transports ferroviaires souterrains (EFS) est caractérisée par des particules en suspension riches en métaux, majoritairement du fer, et en carbone, dont la concentration massique est très supérieure à celle mesurée dans l’air ambiant extérieur aux EFS. Cependant, les risques sanitaires chez les travailleurs des EFS liés aux polluants chimiques de l’air présents dans ces enceintes ferroviaires ont été peu étudiés. Dans ce contexte, l’Anses a été saisie afin de dresser un état des connaissances et réaliser une évaluation des risques sanitaires (ERS) chez les travailleurs des EFS. Méthodes Un groupe de travail pluridisciplinaire a analysé les études publiées jusqu’en décembre 2014 et des données communiquées par les exploitants de transport. L’ERS a porté sur les travailleurs de l’exploitation, l’organisation du transport et des services, et des commerces qui exercent une activité durant les horaires de trafic des rames de voyageurs. L’exposition chronique des travailleurs a été estimée à partir des données de concentration inhalée en particules (PM2,5 et PM10), en éléments métalliques, en carbone, en hydrocarbures aromatiques polycycliques particulaires et en hydrocarbures aromatiques monocycliques, issues d’une campagne transversale de métrologie individuelle de la RATP. Cette exposition estimée a ensuite été comparée à une valeur toxicologique de référence (VTR ajustée, VLEP, NOAECHEC) pour calculer un indicateur de risque. Résultats Les risques sanitaires en lien avec les éléments métalliques évalués individuellement semblent négligeables. Concernant l’exposition chronique aux particules, une inflammation des voies respiratoires et des effets consécutifs à cette inflammation sont probables, sur la base d’un effet démontré par une étude de toxicité aiguë chez l’animal. Par analogie avec les particules de l’air ambiant extérieur, des effets délétères sont attendus sur la santé cardiovasculaire et respiratoire en lien avec l’exposition chronique de ces travailleurs aux particules des EFS. L’ERS présente néanmoins des incertitudes notables compte tenu notamment du corpus d’études épidémiologiques assez peu informatif et de l’absence d’étude toxicologique d’exposition chronique. Conclusion Des effets sanitaires sont attendus en relation avec l’exposition chronique des travailleurs à la pollution de l’air des EFS. Des travaux sont recommandés pour combler les lacunes des connaissances sur la toxicité à long terme des particules de l’air de ces enceintes ferroviaires, mais également sur l’exposition de certaines catégories de travailleurs de la maintenance vraisemblablement plus exposés
ISSN: 1775-8785

hal-01331986
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01331986
DOI : 10.1016/j.admp.2016.03.448
PUBMED : 26334607

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In order to better constrain the relationship between tectonics and sedimentation of the Eastern Sardinian Margin, from the Messinian to the present day (METYSS project), a lithostratigraphic study was carried out on the Late Neogene deposits along the Cedrino Valley (eastern Sardinia). The late Neogene evolution is documented from sedimentological and tectonic analysis, biostratigraphic dating, and by mapping and logging stratigraphic sections. Previous authors have differentiated an early Pliocene marine formation from an older continental formation, possibly Miocene, the entire system being covered by late Pliocene to Quaternary lava flows. Preliminary biostratigraphic data suggest the absence of the lowermost Pliocene, based on the absence of Globorotalia margaritae and the presence of Globorotalia puncticulata, implying a sediment age between 3.81 and 2.41 Ma. At the foot of the Fiuli cliff, some mud clasts include a coccolith microflora, Tortonian in age, suggesting reworking. The Pliocene marine deposits consist of a single filling sequence instead of a succession of superimposed sequences as we would expect during this period of time; the occurrences of terms rarely respect the usual transgressive-regressive succession. Contrasting bathymetric environments (fore-shore, pro-delta, shelf or upper slope) can be abruptly superimposed on top of the other, along few meter thick intervals. A rapidly flooded term is observed in several sites and indicates a spatial variability over only a few kilometers distance. Some deep water deposits are in the middle of the infilling Pliocene sequence, whereas shallower water deposits can be repeated along a vertical section, or even interrupted by emersion. These marked differences can express syn-, or possibly post-sedimentation tectonic uplifts. The 10–25° bed dips originated through local tectonic uplift. At Fiuli, the geometry of the bedding planes is indicative of tilting toward the west, in a direction opposite to the one observed at Onifai. These Pliocene series form a wide syncline with an approximately NNE–SSW axis. This morpho-structural behavior appears to be largely atypical of this East-Sardinian coastal area.
ISSN: 1040-6182

hal-01134707
https://hal.archives-ouvertes.fr/hal-01134707
DOI : 10.1016/j.quaint.2014.11.022