Éditeur(s) : Gauthier-Villars
Résumé : The analysis of humic compounds by elemental analysis, PY-GC-MS and HPLC techniques permitted determination of the origin of organic inputs, essentially terrestrial, and the effects of environmental conditions in the deposits along a north-south transect through the Rhone delta, from the river mouth to the open sea. In the prodelta the sedimentation of fine particles enriches the sediments in organic matter. The humic compound contents were relatively low in sediments, perhaps due to a rapid burying of organic matter which leads to anoxic conditions. In sediments fulvic acids are more abundant than humic acids. Elemental analysis indicated that fulvic acids were enriched in hydrogen and nitrogen as compared to humic acids. Furthermore, H/C and N/C ratios increased in the fulvic and humic acids towards the open sea, related to a more marine character. Pyrolysis analysis showed some differences between the chemical composition of fulvic acids which correspond to low molecular weights enriched in carbohydrates, and that of humic acids, high molecular weight compounds which are enriched in phenols and aromatic hydrocarbons. The pyrolysis-derived phenols were abundant near the river mouth, decreasing towards the open sea as nitrogen-containing-compounds increased. Near the river mouth, the abundance of phenolic aldehydes demonstrated by HPLC emphasized the existence of fresh organic matter. On the other hand, off the mouth, an increase in phenolic acids could indicate a more degraded organic material. The fractionation of humic acids in various classes of molecular weight species using ultrafiltration (Amicon membranes) and their analysis showed that, close to the river mouth, the large proportion of the high molecular weight humic compounds observed was enriched in phenols and carbohydrates, probably inherited from the terrestrial ligno-cellulosic complex. This process seemed to be superimposed on the increase of molecular weights which is usually observed as the environment becomes purely marine. These humic compounds would derived either from organic matter from terrestrial soils swept along by the river flow, after deposition on its bed or, more probably, from high molecular weight compounds which, associated with the mineral phase, flocculated when reaching the fluvio-marine front. Generally, the low molecular weight fractions were enriched in hydrogen and nitrogen. Near the river mouth, nitrogen-containing compounds were concentrated in the low molecular weight classes which correspond to organic molecules regarded as humic precursors. Off the mouth, they were incorporated into the high molecular weight complexes, certainly of marine origin.
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1992 , Vol. 15 , N. 1 , P. 61-74

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00101/21187/18804.pdf
http://archimer.ifremer.fr/doc/00101/21187/

Résumé : Face aux difficultés d’identification des arbres de la famille des Lauracées et dans un but d’établissement d’une production durable et certifiée d’huiles essentielles, l’entreprise KLR a voulu mettre en place un nouvel outil d’identification multi-critères qui consiste à croiser plusieurs types de caractères afin d’obtenir une détermination taxonomique fiable.Trois méthodes d’identification ont été utilisées : la chimie (analyse de l’odeur de l’écorce), le code barre génétique et l’anatomie du bois. Une analyse par positionnement multidimensionnel non-métrique a permis de faire un tri des critères anatomiques du bois pertinents dans l’identification des Lauracées étudiées, au final 14 critères ont été retenus. D’après les données anatomiques dont nous disposons, nous proposons une clé de détermination au genre. En génétique, la technique de code barres de la région chloroplastique intergénique trnH-psbA a été appliquée aux individus récoltés. En comparant les séquences de tous les individus, 40% des individus peuvent être identifiés au genre car ils présentent des haplotypes uniques. Des haplotypes au sein des genres ont été déterminés et permettent d’identifier l’espèce pour 40 à 100 % des individus selon le genre. L’analyse SPME de l’odeur des écorces a permis de définir pour chaque espèce une carte d’identité chimique à partir des molécules majoritaires. Des chémotypes ont été définis au sein des espèces Licaria cannella, Ocotea indirectinervia et Sextonia rubra. Ces trois domaines d’observation ont permis de constituer une base de type Xper2 pour l’identification.Un criblage des essences intéressantes de par leur rendement en huile essentielle a été effectué. En ce qui concerne la partie extraction de l’huile essentielle, trois espèces montrent un rendement en huile essentielle de l’écorce supérieur à 0,3% et 5 espèces montrent un rendement en huile essentielle du bois supérieur à 0,3%. Les évaluations olfactives menées par un expert ont permis de séparer les huiles distillées en 5 différentes notes. Nous avons jugé intéressant de savoir si l’outil d’identification multicritère pouvait prédire les compositions et rendements en huile essentielle de l’espèce identifiée avant l’abattage de l’arbre. Des études complémentaires ont donc été menées. Pour plus de la moitié des arbres, la signature de l’écorce, la composition de l’huile essentielle de l’écorce et la composition de l’huile essentielle du bois sont similaires. La tentative d’établir un lien entre les caractéristiques des cellules à huile et le rendement s’est avérée infructueuse.
In order to develop a sustainable production of certified essential oils extracts, the compangy KLR has struggled with the identification of the trees from the family of Lauraceae. This is the main reason that led to the project of creating an identification tool for this family.This tool would be based on three approaches: chemistry (chemical signature of the dark), wood anatomy and genetic barcoding. By means of a non-metric multidimensional scaling analysis, we selected a list of 14 relevant wood anatomical features that can identify the trees to the genera. For the genetics, the barcoding of trnH-psbA an intergenic region of the DNA has been used. When comparing all the sequences from all the individuals, 40% of the individuals can be identified to the genera because of their specific haplotype. Haplotypes within the genera have also been established. Chemical identity cards have been set with the SPME analysis technique and chemotypes have been defined inside the species Licaria cannella, Ocotea indirectinervia and Sextonia rubra. These three identification approaches allowed us to construct an identification tool on Xper².During the study, we aimed to screen what species would be interesting for its essential oil yield. Three species showed an essential oil bark yield above 0.3%. five species showed an essential oil wood yield above 0.3%. An expert held an olfactory evaluation on the oils and divided the essential oils in five olfactory groups. We found it relevant to improve the identification tool by trying to predict the compositions of the oils before the three was cut down. In the case of the half of trees studied by SPME analyses, the composition of the wood and the bark essential oils were similar. On the other hand, no link was found between the oil cells dimensions and the essential oil yield.

http://www.theses.fr/2012AGUY0516/document

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Roussillon sedimentary Basin (South France) is a complex multi-layered aquifer, close to the Mediterranean Sea facing seasonally increases of water abstraction and salinization issues. We report geochemical and isotopic vertical variability in this aquifer using groundwater sampled with a Westbay System® at two coastal monitoring sites: Barcarès and Canet. The Westbay sampling allows pointing out and explaining the variation of water quality along vertical profiles, both in productive layers and in the less permeable ones where most of the chemical processes are susceptible to take place.The aquifer layers are not equally impacted by salinization, with electrical conductivity ranging from 460 to 43,000 μS·cm− 1. The δ2H–δ18O signatures show mixing between seawater and freshwater components with long water residence time as evidenced by the lack of contribution from modern water using 3H, 14C and CFCs/SF6. S(SO4) isotopes also evidence seawater contribution but some signatures can be related to oxidation of pyrite and/or organically bounded S. In the upper layers 87Sr/86Sr ratios are close to that of seawater and then increase with depth, reflecting water–rock interaction with argillaceous formations while punctual low values reflect interaction with carbonate. Boron isotopes highlight secondary processes such as adsorption/desorption onto clays in addition to mixings. At the Barcarès site (120 m deep), the high salinity in some layers appear to be related neither to present day seawater intrusion, nor to Salses-Leucate lagoonwater intrusion. Groundwater chemical composition thus highlights binary mixing between fresh groundwater and inherited salty water together with cation exchange processes, water–rock interactions and, locally, sedimentary organic matter mineralisation probably enhanced by pyrite oxidation.Finally, combining the results of this study and those of Caballero and Ladouche (2015), we discuss the possible future evolution of this aquifer system under global change, as well as the potential management strategies needed to preserve quantitatively and qualitatively this water resource.
ISSN: 0048-9697

hal-01685219
https://hal-brgm.archives-ouvertes.fr/hal-01685219
DOI : 10.1016/j.scitotenv.2016.05.016

Éditeur(s) : HAL CCSD
Résumé : Diffusion du document : INRA Antilles-Guyane, UMR ECOFOG, 97387 Kourou, Guyane (France)Diplôme : Maîtrise
il s'agit d'un type de produit dont les métadonnées ne correspondent pas aux métadonnées attendues dans les autres types de produit : DISSERTATION
Nous avons analysé la composition chimique de feuilles matures et sénescentes de 21 espèces d'arbres de forêt tropicale humide. Ces arbres ont été plantés il y a 20 ans, sur un sol uniforme pour tous, sous forme de jeunes plants. Cette plantation est organisée sous forme de placeaux mono-spécifiques et estsituée près de Kourou, en Guyane française. Les mesures de concentration d’azote, de phosphore, de carbone et des polyphénols ont été réalisées et ont permis de calculer le rapport C/N et la résorption desnutriments. Les compositions chimiques varient radicalement entre les espèces à la fois pour les feuilles matures et sénescentes : dans les feuilles matures les concen- trations en N et P varient de 1.03% à 2.69% et de 0,037% à 0,115%, respectivement. La concentration d'N dans les feuilles sénescentes varie de 0,72% à 2.03% et pour le P de 0,0 13% à 0.074%. La vitesse de croissance est positivement corrélée avec laconcentration d'N dans les feuilles. La résorption est le phénomène suivant lequel les plantes réabsorbent les nutriments des feuilles avant la période d'abscission pour les redistribuer à travers ses tissus.L'efficience de résorption varie fortement en fonction des espèces et est plus élevée pour le P que pour l'N. La résorption de l'N varie de -9,84% à 57.22% (moyenne ~30.7%) et celle du P varie de -15,75% à 79,56% (moyenne ~47.64%). Une analyse par corrélation montre que les résorptions de N et P sont signifi- cativement et positivement corrélés. Il y a aussi une corrélation significative et positive entre l'efficience de résorption et i) les concentrations en nutriment dans les feuilles vertes et ii) le coût de construction des feuilles et la vitesse de croissance.Parmi les espèces, une forte relation positive est trouvée entre le C/N de la litière et la résorption de l’N,suggérant que celle-ci est un élément déterminant de la qualité de la litière. Une forte résorption entraîne une faible qualité de litière et par conséquent une mauvaise décomposition. La résorption et la décomposition sont liés dans le recyclage des nutriments dans les écosystèmes, et sont négativement corrélés. Il semble que la connaissance de la résorption seule ou de la décomposition seule peut fausser la compréhension du fonctionnement de l’écosystème ou des espèces.
https://hal.archives-ouvertes.fr/hal-01189262

hal-01189262
https://hal.archives-ouvertes.fr/hal-01189262
PRODINRA : 21212

Éditeur(s) : HAL CCSD
Résumé : International audience
In the southern part of the Armorican Massif, a Carboniferous continental sedimentation is preserved in two basins located along a dextral fault (the Nort-sur-Erdre Fault). The first one called the Ancenis Basin is Early Carboniferous in age. The second, Namurian in age (i.e. Early to Late Carboniferous), consists of coal-bearing basins (Basse-Loire Unit) and is supposed to be synchronous with the dextral displacement along the North-sur-Erdre Fault. The Carboniferous series of the Ancenis Basin presents intrusive rocks (granite, microgranites) and volcanic rocks (rhyolites). Chemical analyses indicate that they all belong to the same magmatic high-K calc-alkaline association of peraluminous composition. For the first time, this magmatic event has been dated using the LA-ICPMS U-Pb method on zircons. The obtained age is of 319.3 3.1 Ma and constrains both the maximum age of end of the sedimentation and the northward tilting of the sediments in the Ancenis Basin. This magmatic event is coeval with the sedimentation of the coal-bearing Namurian basins. These intrusions are interpreted as the feeding conduits of the volcano-sedimentary layers encountered in these basins. The present-day distance between the intrusive rocks in the Ancenis basin and their extrusive products would imply a minimal dextral displacement of nearly 20-25 km along the Nort-sur-Erdre Fault.
Geophysical Research Abstracts
Vienne, Austria

insu-00673907
https://hal-insu.archives-ouvertes.fr/insu-00673907

Éditeur(s) : HAL CCSD Taylor & Francis
Résumé : International audience
This work evaluates the influence of three different intensities of refinement of sisal pulp and the effect of accelerated aging cycles on the behavior of composites. Fiber-cements were prepared by the slurry de-watering method and pressing as a crude simulation of the Hatschek process. Mechanical behavior of composites was evaluated by four-point bending test at 28 days, and after 50 and 100 wet/dry cycles. Refinement of pulp and aging have increased the strength and bulk density of composites and decreased the toughness and porosity. The best mechanical performance after aging was achieved for samples with highly refined fibers.
ISSN: 1042-6914

hal-00809817
https://hal.univ-antilles.fr/hal-00809817
DOI : 10.1080/10426910601062065

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In fold-and-thrust belts, shortening is mainly accommodated by thrust faults which are preferential zones for recrystallisation and mass transfer. This study focuses on a detachment fault related to the emplacement of the Monte Perdido thrust unit in the southern Pyrenees. The studied fault zone consists of a 10 m thick intensively foliated phyllonite developed within the Millaris marls, of Eocene age. The lithological homogeneity of the hanging wall and footwall allows us to compare the Millaris marls outside the fault zone with the highly deformed marls located in the fault zone and to quantify the chemical, mineralogical and volumetric changes related to deformation processes along the fault. The Millaris marls are composed of detrital quartz, illite, chlorite, minor albite and pyrite, in a micritic calcite matrix. In the fault zone, the cleavage planes are marked by clay minerals and calcite ± chlorite veins attest to fluid-mineral interactions during deformation. The mineral proportions in all samples from both the fault zone and Millaris marls have been quantified by two methods: (1) X-ray diffraction and Rietveld refinement, and (2) bulk chemical analyses as well as microprobe analyses to calculate modal composition. The excellent agreement between the results of these two methods allows us to estimate mineralogical variations using a modification of the Gresens' equation. During fault activation, up to 45 wt% of calcite was lost while the amounts of quartz and chlorite remained unchanged. Illite content remained constant to slightly enriched. The mineralogical variations were coupled with a significant volume loss (up to 45%) mostly due to the dissolution of micritic calcite grains. Deformation was accompanied by pressure solution and phyllosilicates recrystallisation. These processes accommodated slip along the fault. They required fluids as catalyst, but they did not necessitate major chemical transfers.
ISSN: 0264-8172

hal-00976361
https://hal.archives-ouvertes.fr/hal-00976361
DOI : 10.1016/j.marpetgeo.2013.12.016

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
We report new textural and chemical data for 10 garnet peridotite xenoliths from the Udachnaya kimberlite and examine them together with recent data on another 21 xenoliths from the 80-220 km depth range. The samples are very fresh (LOI near zero), modally homogeneous and large (>100 g). Some coarse-grained peridotites show incipient stages of deformation with <10 % neoblasts at grain boundaries of coarse olivine. Such microstructures can only be recognized in very fresh rocks, because fine-grained interstitial olivine is strongly affected by alteration, and may have been overlooked in previous studies of altered peridotite xenoliths in the Siberian and other cratons. Some of the garnet peridotites are similar in composition to low-opx Udachnaya spinel harzburgites (previously interpreted as pristine melt extraction residues), but the majority show post-melting enrichments in Fe and Ti. The least metasomatized coarse peridotites were formed by 30-38 % of polybaric fractional melting between 7 and 4 GPa and ≤1-3 GPa. Our data together with experimental results suggest that garnet in these rocks, as well as in some other cratonic peridotites elsewhere, may be a residual mineral, which has survived partial melting together with olivine and opx. Many coarse and all deformed garnet peridotites from Udachnaya underwent modal metasomatism through interaction of the melting residues with Fe-, Al-, Si-, Ti-, REE-rich melts, which precipitated cpx, less commonly additional garnet. The xenoliths define a complex geotherm probably affected by thermal perturbations shortly before the intrusion of the host kimberlite magmas. The deformation in the lower lithosphere may be linked to metasomatism.
ISSN: 0010-7999

hal-00941252
https://hal.archives-ouvertes.fr/hal-00941252
DOI : 10.1007/s00410-013-0855-8

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
ISSN: 0098-0331

hal-01083748
https://hal-agroparistech.archives-ouvertes.fr/hal-01083748
DOI : 10.1007/s10886-009-9673-x

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
To test the impact of fluid flow on the reactivity of porous (ultra-)mafic rocks, reactive percolation experiments were realized during which CO2-enriched water was injected at two different injection rates (Q = 0.1 and 1 mL h−1) through sintered analogues of olivine-accumulation zones in basaltic flows at temperature and fluid composition conditions (T = 180 °C; NaHCO3 buffered solution) favorable for CO2-mineralization (carbonation).All experiments resulted in silicate dissolution, carbonate precipitation upstream and (proto-)serpentine formation downstream indicating a decrease in the fluid reactivity along flow paths. The measured bulk carbonation rates ranged from 4 to 7 × 10−8 s−1; these values were significantly lower than previously published values of olivine carbonation rate obtained on powders in closed batch and flow-through reactors. Our study show complex couplings, at pore scale, between fluid flow, localization of reaction zones, and chemical reaction kinetics which in turn control hydrodynamic properties, carbonation rate and efficiency and fluid reactivity. This results in carbonation rates being higher when injection rates are high and permeability ultimately controlling carbonation reactions by limiting fluid input. During experiments, notable changes in permeability occurred for only minor changes in porosity indicating a control by the geometry of the porous network: heterogeneities in the distribution of flow paths favored the localization of precipitated minerals which in turn resulted in the closure of flow paths. This mechanism was particularly efficient at low injection rates. These results imply that controlling the injection rate could allow enhancing/limiting the efficiency of in situ carbonation.
ISSN: 0883-2927

hal-01115284
https://hal.archives-ouvertes.fr/hal-01115284
DOI : 10.1016/j.apgeochem.2014.11.024

Résumé : Les résultats de cette étude de la composition du fruit à pain récolté sur un territoire contrasté du point de vue agropédoclimatique, et de son amidon, montrent que la teneur en amidon du fruit à pain apparaît comme étant influencée par la saison, mais pas par la zone de récolte. La teneur en amidon beaucoup plus élevée pour les fruits à pain développés durant la saison la plus sèche est un résultat très original. La connaissance du cycle de développement des fruits à pain à la Martinique a été décrite pour une première fois, permettant de déterminer une période de récolte optimisée par rapport à la floraison : la 16ème semaine pour une croissance maximale, ou la 17ème semaine pour une plus haute teneur en amidon. L’étude de Worrell et al., (1998), la seule publiée actuellement, menée à la Barbade, a montré un cycle plus long de 2 semaines environ.Du point de vue de la diversité génétique, les fruits à pain récoltés en Martinique constituent un seul groupe, à l’opposé de ceux récoltés en Guadeloupe qui constituent 2 sous-groupes proches.En ce qui concerne l’amidon, nos résultats montrent que les dimensions des grains d’amidon de fruits matures sont comprises entre 9 et 12 µm. Leur taille augmente avec la croissance du fruit puisque dans un fruit immature leur diamètre moyen était de 7,5 µm. Il s’agit d’amidons de type B à très haute cristallinité, dont les températures d'empesage sont autour de 75 °C. Parmi les facteurs agropédoclimatiques, l’humidité a eu un rôle actif sur la qualité de l’amidon puisque à la fois la quantité d’amylose et la masse molaire de l’amylopectine diminuent. L’amidon a une solubilité et un gonflement faible du même ordre de grandeur que les amidons classiques et une forte viscosité à la gélatinisation et à la rétrogradation, lui conférant une aptitude à l’utilisation comme gélifiant.Des essais d’applications alimentaires ont été effectués en panification et en extrusion. Des transformations en produits de type crackers ont donné des résultats moyennement satisfaisant avec 100 % de farine de fruit à pain. En panification l’incorporation de farine de fruit à pain a des actions délétères sur la valeur boulangère. L’acceptabilité d’un goût « nature, vert » conféré par la farine de fruit à pain devra notamment être évaluée lors de travaux ultérieurs.Le développement de produits à base de fruit à pain permettra
The results of this study the composition of breadfruit harvested in an area of agro climatic soil contrasting views, and its starch, show that the starch content of breadfruit appears to be influenced by season, but not by collection area. The starch content is much higher for breadfruit developed during the driest season is a very original result. Knowledge of the development cycle of breadfruit in Martinique has been described for the first time, to determine an optimal harvest period compared to flower: the 16th week for maximum growth, or the 17th week for a higher starch content. The study by Worrell et al., (1998), the only currently published, conducted in Barbados, showed a longer cycle of about 2 weeks.From the perspective of genetic diversity, breadfruit harvested in Martinique as a single group, in contrast to those collected in Guadeloupe that are close to two subgroups.With regard to starch, our results show that the size of starch granules of mature fruits are between 9 and 12 microns. Their size increases with the growth of the fruit as an immature fruit in their mean diameter was 7.5 microns. This is B-type starches with very high crystallinity, with temperatures of gelatinization are around 75 °C. Agro climatic soil factors, humidity took an active role on the quality of starch, since both the amount of amylose and amylopectin molecular weight of the decline. The starch has a solubility and low swelling of the same order of magnitude as the conventional starches and high viscosity to gelatinization and retrogradation, giving it a suitability for use as a gelling agent.Testing of food applications were made in bakery and extrusion. Changes in products like crackers gave moderately satisfactory results with 100 % breadfruit flour. Incorporation into bread flour breadfruit has deleterious actions on the baking. The acceptability of a taste "nature green" conferred by the breadfruit flour will be particularly assessed in future work.Product development based breadfruit allow several things, which meet the growing demand for food diversification.

http://www.theses.fr/2012AGUY0517/document

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Fault affecting silicoclastic sediments are commonly enriched in clay minerals. Clays are sensitive to fluid–rock interactions and deformation mechanisms; in this paper, they are used as proxy for fault activity and behavior. The present study focuses on clay mineral assemblages from the Point Vert normal fault zone located in the Annot sandstones, a Priabonian-Rupelian turbidite succession of the Alpine foredeep in SE France. In this area, the Annot sandstones were buried around 6–8 km below the front of Alpine nappes soon after their deposition and exhumed during the middle-late Miocene. The fault affects arkosic sandstone beds alternating with pelitic layers, and displays throw of about thirty meters. The fault core zone comprises intensely foliated sandstones bounding a corridor of gouge about 20 cm thick. The foliated sandstones display clay concentration along S–C structures characterized by dissolution of K-feldspar and their replacement by mica, associated with quartz pressure solution, intense microfracturation and quartz vein precipitation. The gouge is formed by a clayey matrix containing fragments of foliated sandstones and pelites. However, a detailed petrographical investigation suggests complex polyphase deformation processes. Optical and SEM observations show that the clay minerals fraction of all studied rocks (pelites and sandstones from the damage and core zones of the fault) is dominated by white micas and chlorite. These minerals have two different origins: detrital and newly-formed. Detrital micas are identified by their larger shape and their chemical composition with a lower Fe–Mg content than the newly-formed white micas. In the foliated sandstones, newly-formed white micas are concentrated along S–C structures or replace K-feldspar. Both types of newly formed micas display the same chemical composition confirmed microstructural observations suggesting that they formed in the same conditions. They have the following structural formulas: Na0.05 K0.86 (Al 1.77 Fe0.08 Mg0.15) (Si3.22 Al0.78) O10 (OH)2. They are enriched in Fe and Mg compared to the detrital micas. Newly-formed chlorites are associated with micas along the shear planes. According to microprobe analyses, they present the following structural formula: (Al1,48 Fe2,50 Mg1,84) (Si2,82 Al1,18) O10 (OH)8. All these data suggest that these clay minerals are synkinematic and registered the fault activity. In the gouge samples, illite and chlorite are the major clay minerals; smectite is locally present in some samples.In the foliated sandstones, Kubler Index (KI) ((001) XRD peak width at half height) data and thermodynamic calculations from synkinematic chlorite chemistry suggest that the main fault deformation occurred under temperatures around 220 °C (diagenesis to anchizone boundary). KI measured on pelites and sandstones from the hanging and footwall, display similar values coherent with the maximal burial temperature of the Annot sandstones in this area. The gouge samples have a higher KI index, which could be explained by a reactivation of the fault at lower temperatures during the exhumation of the Annot sandstones formation
ISSN: 0191-8141

hal-01172423
https://hal.archives-ouvertes.fr/hal-01172423
DOI : 10.1016/j.jsg.2015.03.012

Éditeur(s) : HAL CCSD
Résumé : The Restefond fault, located in the Late Eocene-Early Oligocene Alpine foreland basin, affects the well lithified and low porosity Grès d'Annot. The fault core zone is characterized by the occurrence of highly deformed sandstone lenses. Deformation inside the lenses corresponds to mm to sub-mm-spaced cleavage planes rich in phyllosilicates and up to cm-thick and dm-long quartz-calcite pure extensional veins. The cleavages are mostly composed of newly-formed synkinematic white mica and chlorite. By using thermodynamic thermometers based on the chemical composition of chlorite, a temperature of 200 ± 20 °C of fault activity was computed. This temperature shows that the Restefond fault was active at burial conditions comprised between 6.5 and 8 km, assuming a mean geothermal gradient between 25 and 30 °Ckm−1. The petrophysic properties of sandstones from the core zone and in the hanging and foot wall of the fault were determined on drilled plugs following three spacial directions. The permeability of the highly deformed sandstone from the core zone is about one order of magnitude higher than in the host rock. This increase in permeability occurs in the direction parallel to the S-C structures and is explained by the occurrence of well-connected micropores localized between platy phyllosilicates. This study shows that the fault petrophysic properties are mostly controlled by the precipitation of synkinematic phyllosilicates under deep burial conditions.
Swiss Journal of Geosciences

hal-00795551
https://hal.archives-ouvertes.fr/hal-00795551
DOI : 10.1007/s00015-012-0099-z

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The Ronda peridotite massif in Southern Spain shows a well-defined 'recrystallization' front that separates a large-scale partial melting domain formed at the expense of the continental lithospheric mantle from a 'preserved' lithospheric domain. To investigate the processes allowing a transient lithosphere-asthenosphere boundary to propagate in the lithospheric mantle, we performed a joint petrostructural and geochemical study of an similar to 2.5 km(2) zone extending from the melting front to the mylonites that mark the western limit of the massif. This study emphasizes a feedback between heat transfer, melt percolation, and deformation in the lithospheric mantle. Petrographical observations and geochemical data show that heterogeneous reactive percolation of melts produced in the underlying partial melting domain led to refertilization of lithospheric peridotites up to 1.5 km ahead from the melting front, producing metre-scale layering of fertile and refractory mantle rocks. Within 800 m from the front, pre-existing garnet pyroxenite layers were partially molten and the resulting melts probably contributed to the refertilization process. Detailed structural mapping and analysis of the microstructures and crystal preferred orientations highlight the relations between reactive melt transport and deformation, and the control of the temperature gradient on both processes. Parallelism between the recrystallization front, compositional boundaries, and deformation structures, as well as variations in the deformation intensity of pyroxenes and spinels, suggest syn- to late-tectonic melt transport controlled by both the deformation and the thermal gradient. Variations in the strength of olivine crystal preferred orientations as a function of the modal and chemical composition of the spinel tectonites point to a higher contribution of diffusion to deformation in the most fertile rocks, corroborating the hypothesis that deformation occurred in presence of melt. Finally, the systematic dispersion of olivine [100] and orthopyroxene [001] axes in the foliation plane suggests a dominantly transpressive deformation regime.
ISSN: 0022-3530

hal-00420904
https://hal.archives-ouvertes.fr/hal-00420904
DOI : 10.1093/petrology/egp032

Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
In Alpine Corsica (France), deeply subducted metabasalts are well preserved as lawsonite-bearing eclogite (Law-Ecl), occurrence of which is restricted to similar to 10 localities worldwide. The Corsican Law-Ecl, consisting of omphacite + lawsonite + garnet + phengite + titanite, occurs as both single undeformed metabasaltic pillows surrounded by lawsonite blueschist (Law-Bs), and carbonate-bearing eclogitic veins. Law-Bs are found as variably deformed metabasaltic pillows locally cross-cut by eclogitic veins and consist of glaucophane + actinolite + lawsonite + garnet + phengite + titanite. Field evidence and microstructures reveal that both Law-Ecl and Law-Bs are stable at the metamorphic peak in the lawsonite-eclogite stability field. Isochemical phase diagrams (pseudosections) calculated for representative Law-Ecl and Law-Bs samples indicate that both lithologies equilibrated at the same conditions of similar to 520 +/- 20 degrees C and 2.3 +/- 0.1 GPa. Therefore, the coexistence at the same peak metamorphic conditions of Law-Ecl and Law-Bs implies that different portions of deeply subducted oceanic crust may store significantly different H2O contents, depending on bulk-rock chemical composition. In addition, thermodynamic modelling of phase equilibria indicates that the occurring progressive dehydration reactions, which are significantly depending on bulk-rock chemical composition, strongly influence rock densification and eclogite formation in subducting slabs.
ISSN: 0263-4929

hal-00617768
https://hal.archives-ouvertes.fr/hal-00617768
DOI : 10.1111/j.1525-1314.2011.00931.x

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study presents the geochemical composition of superficial sediment under oxic and suboxic bottom water conditions along the Chilean continental margin (SE Pacific), where evidence for benthic chemosynthetic activity associated with diffuse seeping of chemically reduced fluids has been reported. The exploration was carried out at: (1) the Chilean Triple Junction (CTJ), at a water depth of ∼2900 m, with the additional indication of hydrothermal activity near a methane-rich cold-seep area (46°S) (German et al., 2010); and (2) the El Quisco methane seep site (EQSS), at ∼340 m water depth (33°S) (Melo et al., 2007; Krylova et al., 2014). While the deeper CTJ is located within an oxic environment (dissolved oxygen in the bottom waters: 164 μM), the shallower EQSS lies within a suboxic environment (dissolved oxygen in bottom water: 23 μM), located within the lower limit of the SE Pacific oxygen minimum zone (OMZ).Pore water from short cores was analyzed for dissolved major, minor, and trace elements (Cl, Na, Mg, K, Ca, Sr, Si, B, P, Ba, Pb, Mn, Fe, Cd, U, and Mo), δ13DIC, sulfide, sulfate, and methane. The solid sediment fraction was likewise analyzed for total organic carbon (TOC), metals, and redox potential. Elevated sediment temperatures were found in superficial sediments (5–13 °C) at the CTJ site, which could be due to warm fluids associated with the proximity of the ridge, where hydrothermal vents may occur. Reduced fluids were also present here, indicated by higher Mn fluxes toward the water column even in oxidized sediments (RPD > 8 cm), which contrasted with the lower fluxes in reduced sediments of the EQSS site (RPD ∼ 2 cm). 13C-depleted DIC, anomalously low pore water Cl (∼15 ppb), and low concentrations of other major elements may be the result of dilution by fluid seeping and precipitation of major elements, producing authigenic enrichment (Ca, Mg, Sr). The fluid could also: (a) be diluted by pure water produced during methane hydrate dissociation, as observed in other cold-seep areas; and (b) correspond to clay mineral dehydration, as reported in plate subduction systems. The reducing conditions established at the CTJ conduct the Cd enrichment at a similar magnitude of that seen at the shallower suboxic site (EQSS). Evidence of chimney or vent fauna was not observed. At the EQSS, higher TOC and total sulfide contents were consistent with enhanced deposition of organic matter and reducing conditions developed in the OMZ, favoring the authigenic enrichment of Cd, U and Pb. The geochemical evidence, based only on methane concentrations and δ13DIC, is insufficient to establish the presence of methane seeps, as previously reported.
ISSN: 0079-6611

hal-01412700
https://hal.archives-ouvertes.fr/hal-01412700
DOI : 10.1016/j.pocean.2016.09.002

Éditeur(s) : Gauthier-Villars
Résumé : The mangroves of Senegal are limited to the inlet of the Casamance - a river with very low discharge - and to the Sine-Saloum. The mineralogical and geochemical analysis of sediments (derived from 30 deep bore-holes) shows the thickness of the mangrove substrate, which overlies the continental terminal formation. Kaolinite and smectite account for over 90% of the clay fraction. The former is derived from the continental terminal whereas the latter is of marine origin. The chemical composition of the mangrove sediments is remarkably stable and clays play an overwhelming role in the preservation of organic matter and pyrite. Since 1968, a drought in Senegal has caused an important increase in the salinity levels of streams and water-tables; a considerable modification of vegetation zones in the Casamance, especially manifest in the extension of bare flats locally known as "tannes" at the expense of mangroves and marked changes in the morphology and geochemistry of mangrove soils. Compared to most mangrove areas in the humid tropics, mangroves in Senegal are characterized by a very fragile equilibrium.
Oceanologica Acta, Special issue (0399-1784) (Gauthier-Villars), 1982

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00246/35744/34252.pdf
http://archimer.ifremer.fr/doc/00246/35744/

Éditeur(s) : HAL CCSD European Geosciences Union
Résumé : During the Neoproterozoic orogeny, the middle crust of the Araçuaí belt underwent widespread partial melting. At the regional scale, this anatectic domain is characterized by a progressive rotation of the flow direction from south to north, suggesting a 3-D deformation of the anatectic middle crust. To better determine whether melt volumes present in the anatectic middle crust of the Araçuaí orogen were large enough to allow a combination of gravity-driven and convergence-driven deformation, we used the titanium-in-quartz (TitaniQ) geothermometer to estimate the crystallization temperatures of quartz grains in the anatectic rocks. When possible, we compared these estimates with thermobarometric estimates from traditional exchange geothermobarometers applied to neighboring migmatitic kinzigites. TitaniQ temperatures range from 750 to 900 °C, suggesting that quartz starts crystallizing at minimum temperatures of ≥ 800 °C. These results, combined with the bulk-rock chemical composition of diatexites, allows the estimation of a minimum of ~ 30% melt and a corresponding viscosity of ~ 109–1010 Pa s. Such a minimum melt content and low viscosity are in agreement with interconnected melt networks observed in the field. Considering that these characteristics are homogeneous over a wide area, this supports the finding that the strength of the middle crust was severely weakened by extensive partial melting, making it prone to gravity-driven flow and lateral extrusion.
ISSN: 1869-9510

hal-01116434
https://hal.archives-ouvertes.fr/hal-01116434
DOI : 10.5194/se-5-1223-2014

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
The New Jersey continental shelf extends 150 km off the shoreline. During IODP Expedition 313, siliciclastic deposits of late Eocene to late Pleistocene age were drilled down to 631, 669 and 755 m below seafloor at sites 27A, 28A and 29A respectively in very shallow waters (33.5 to 36 m depth). Pore water salinities display multilayered brackish-salty-brine units 10 to 170 m thick, where low-salinity water is preferentially stored in fine-grained sediments. The sharp boundaries of these buried aquifers are often marked by cemented layers a few centimetres thick. The mineralogy and scanning electron microscope observations of these layers show two phases of cementation by authigenic minerals: (1) the early carbonate cement is frequently associated with pyrite, and (2) the late silicate cement infills the residual porosity. The isotopic compositions of the carbonate cements vary widely: −2.4 < δ¹⁸O ‰ VPDB < +2.8; −15.1 < δ¹³C ‰ VPDB < +15.6. The δ¹⁸O values indicate that the carbonate cements precipitated with pore waters comprising variable mixtures of seawater and ¹⁸O-depleted fresh water originating from submarine groundwater discharge. The δ¹³C values of the carbonate cements are related to organic matter diagenesis, providing ¹³C-depleted dissolved inorganic carbon during bacterial sulphate reduction and anaerobic oxidation of methane, and ¹³C-rich dissolved inorganic carbon during methanogenesis. The diagenetic cementation processes included chemical weathering of reactive silicate minerals by the CO²-rich pore waters issued from organic matter diagenesis that released bicarbonate, cations and dissolved silica, which were further precipitated as carbonate and silicate cements. The estimated range of temperature (18±4 °C) during carbonate precipitation is consistent with carbonate cementation at moderate burial depths; however, silicate cementation occurred later during diagenesis at deeper burial depths.
ISSN: 0276-0460

hal-01559985
https://hal.archives-ouvertes.fr/hal-01559985
DOI : 10.1007/s00367-017-0506-6

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
For the first time, an albite orthogneiss has been recognised and dated within the HP-LT blueschist facies metabasites and metapelites of the Ile de Groix. It is characterised by a peraluminous composition, high LILE, Th and U contents, MORB-like HREE abundances and moderate Nb and Y values. A U-Pb age of 480.8 ± 4.8 Ma was obtained by LA-ICP-MS dating of zircon and titanite. It is interpreted as the age of the magmatic emplacement during the Early Ordovician. Morphologically different zircon grains yield late Neoproterozoic ages of 546.6-647.4 Ma. Zircon and titanite U-Pb ages indicate that the felsic magmatism from the Ile de Groix is contemporaneous with the acid, pre-orogenic magmatism widely recognised in the internal zones of the Variscan belt, related to the Cambro-Ordovician continental rifting. The magmatic protolith probably inherited a specific chemical composition from a combination of orogenic, back-arc and anorogenic signatures because of partial melting of the Cadomian basement during magma emplacement. Besides, the late Devonian U-Pb age of 366 ± 33 Ma obtained for titanite from a blueschist facies metapelite corresponds to the age of the HP-LT peak metamorphism.
ISSN: 1437-3254

insu-00714570
https://hal-insu.archives-ouvertes.fr/insu-00714570
DOI : 10.1007/s00531-011-0732-5