Éditeur(s) : HAL CCSD Société Géologique de France
Résumé : The Udachnaya-East pipe in Yakutia in Siberia hosts a unique dry (serpentine-free) body of hypabyssal kimberlite (<0.64wt% H2O), associated with a less dry type of kimberlite and a serpentinized kimberlitic breccia. The dry kimberlite is anomalously rich in salts (Na2O and Cl both up to 6wt%) whereas the slightly less dry and the breccia kimberlite are salt free. Yet the Udachnaya kimberlite is a group-I kimberlite, as is the archetypical kimberlite from Kimberley, South Africa. Samples were studied from the three different types of kimberlite (dry-salty, n=8, non-salty, n=5 and breccia, n=3) regarding their mineralogy, geochemistry, and more specifically their sulfur content. Our results show the salty kimberlite is unprecedentedly rich in sulfur (0.13-0.57wt%) compared to the non-salty kimberlite (0.04-0.12wt%) and the breccia (0.29-0.33wt%). In the salty kimberlite, most of the sulfur is present as sulfates (up to 97% of Stotal) and is disseminated throughout the groundmass in close association with Na-K-bearing carbonates. Sulfates occur within the crystal structure of these Na-K-bearing carbonates as the replacement of (CO3) by (SO3) groups, or as Na- and K-rich sulfates (e.g. aphtitalite, (K,Na)3Na(SO4)2). The associated sulfides are djerfisherite; also Na- and K-rich species. The close association of sulfates and carbonates in these S-rich alkaline rocks suggests that the sulfates crystallized from a mantle-derived magma, a case that has strong implication for the oxygen fugacity of kimberlite magmatism and more generally for the global S budget of the mantle.
ISSN: 0037-9409

hal-01622633
https://hal.archives-ouvertes.fr/hal-01622633
DOI : 10.1051/bsgf/2017007

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Ocean island basalts (OIB) from the Comores archipelago (Indian Ocean) display mineralogical and geochemical features different from the other Indian OIB. We present here new geochronological data (40Ar/39Ar), major and trace element compositions and isotopic (Sr, Nd, Pb) ratios of silica-undersaturated alkaline rocks from Mayotte, the oldest island of the Comores. Two trends are defined using major element composition: (1) a highly silica-undersaturated trend which includes basanites, (melilite-bearing) nephelinites, intermediate lavas and phonolites from the southern part of the island and (2) a moderately silica-undersaturated trend which is mainly represented by alkali basalts, basanites, intermediate lavas and phonolites from the northern part of the island. Both trends could be explained, to some extent, by variable degrees of partial melting. Normative larnite-bearing olivine melilitites and nephelinites exhibit, in addition to their high silica-undersaturation, elevated concentrations in CaO (>12wt.%) and P2O5 (up to 1.35wt.%). These exceptional rocks would result from low degree deep partial melting of a CO2-metasomatized source in the presence of carbonate (probably dolomite) and apatite. Igneous rocks from southern and northwestern shield volcanoes are characterized by a radiogenic Pb composition, revealing the existence of a HIMU (high μ=238U/204Pb) component in their source. Its influence decreases from the main building stage (>10.6-~3.0Ma) to the post-shield stage for the benefit of a depleted MORB-mantle (DMM) component, especially in the north central rocks. This feature would reflect increasing melting degrees of the depleted dominant source, bearing small-scale HIMU heterogeneities progressively consumed with time. The HIMU signature might have been introduced in the Comorian lithospheric mantle by thermal erosion or delamination of a continental lithosphere during the Gondwana break-up. The other islands of the Comores archipelago (Moheli, Anjouan and "La Grille" type lavas from Grande Comore) display also a DMM-HIMU mixing trend. Only a few lavas from Grande Comore ("Karthala" type) and one sample from Mayotte show the clear EM1 contribution (87Sr/86Sr>0.7035) of the Comorian plume.
ISSN: 0024-4937

insu-01089376
https://hal-insu.archives-ouvertes.fr/insu-01089376
https://hal-insu.archives-ouvertes.fr/insu-01089376/document
https://hal-insu.archives-ouvertes.fr/insu-01089376/file/Pelleter%20et%20al%201.pdf
DOI : 10.1016/j.lithos.2014.09.012

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The present study aims to apply the AMS method (Anisotropy of Magnetic Susceptibility) at a regional scale to track the fluid circulation direction that has produced an iron metasomatism within pre-existing dolomite host rock. The Urgonian formations hosting the Zn-Pb mineralizations in La Florida (Cantabria, northern Spain) have been taken as target for this purpose. Sampling was carried out, in addition to ferroan dolomite host rock enclosing the Zn-Pb mineralizations, in dolomite host rock and limestone to make the comparison possible between magnetic signals from mineralized rocks, where fluid circulation occurred, and their surrounding formations. AMS study was coupled with petrofabric analysis carried out by texture goniometry, Scanning Electron Microscopy (SEM) observations and also Shape Preferred Orientation (SPO) statistics. SEM observations of ferroan dolomite host rock illustrate both bright and dark grey ribbons corresponding respectively to Fe enriched and pure dolomites. SPO statistics applied on four images from ferroan dolomite host rock give a well defined orientation of ribbons related to the intermediate axis of magnetic susceptibility K2. For AMS data, two magnetic fabrics are observed. The first one is observed in ferroan dolomite host rock and characterised by a prolate ellipsoid of magnetic susceptibility with a vertical magnetic lineation. The magnetic susceptibility carrier is Fe-rich dolomite. These features are probably acquired during metasomatic fluid circulations. In Fe-rich dolomite host rock, ‹c› axes are vertical. As a rule, (0001) planes (i.e. planes perpendicular to ‹c› axes) are isotropic with respect to crystallographic properties. So, the magnetic anisotropy measured in this plane should reflect crystallographic modification due to fluid circulation. This is confirmed by the texture observed using the SEM. Consequently, AMS results show a dominant NE-SW elongation interpreted as the global circulation direction and a NW-SE secondary elongation that we have considered as sinuosities of the fluid trajectory. The second type of magnetic fabric is essentially observed in the limestone and characterised by an oblate form of the ellipsoid of magnetic susceptibility, a horizontal magnetic foliation and mixed magnetic susceptibility carriers. It is interpreted as a sedimentary fabric.
ISSN: 0012-821X

insu-00342499
https://hal-insu.archives-ouvertes.fr/insu-00342499
https://hal-insu.archives-ouvertes.fr/insu-00342499/document
https://hal-insu.archives-ouvertes.fr/insu-00342499/file/Essalhi-EPSL-2008.pdf
DOI : 10.1016/j.epsl.2008.11.011

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : International audience
We report here U-series and trace element data for an olivine-melilitite lava flow, erupted in 1957 in the Virunga volcanic field and known as the Mugogo eruption. Petrological and geochemical data show that the Mugogo magma represents a primary mantle melt, derived from a low degree of melting of a metasomatised mantle source. It is highly enriched in very incompatible trace elements (e.g. more than 300-fold compared to primitive mantle for Th), with a distinctly lower enrichment in Rb, Ba and Sr. The high Th/U and low (230Th/232Th) ratios (4.4 and 0.750, respectively, with a (230Th/238U) ratio of 1.09) are close to the values found for the Nyamuragira basanites. But the most striking feature is the very low (226Ra/230Th) ratio of 0.48, the lowest ever measured in a mafic volcanic rock. The most probable origin of this Ra deficit is the presence of phlogopite (having a high Ra partition coefficient) in the lithospheric mantle, either as a residual phase during low-degree isobaric melting (in batch-melting or a diffusion-controlled melting models), or in a phlogopite-bearing upper mantle through which the melt migrates and equilibrates (in an equilibrium porous flow model commonly used to describe adiabatic melting). The disequilibrium pattern (230Th) > (238U) > (210Pb) ≫ (226Ra), reversed compared to the pattern observed in the Oldoinyo Lengai natrocarbonatite, suggests that a carbonatite melt might have been involved to explain the Ra deficit. We thus discuss the possibility of an early separation of a Ra-enriched carbonate melt either from the olivine-melilitite melt or from a carbonated mantle source, followed by the production of a low-degree melt of olivine-melilitite composition, but the lack of available experimental, petrological and geochemical evidences makes this process somewhat speculative at present. Further studies of recent (<5 ky) olivine-melilitites are needed to check whether the large Ra deficit is a general characteristic of this type of magma that can be used to constrain models of its formation.
ISSN: 0010-7999

hal-01174173
https://hal.archives-ouvertes.fr/hal-01174173
DOI : 10.1007/s00410-015-1124-9

Éditeur(s) : HAL CCSD Geological Society of America
Résumé : International audience
Fluid-rock interactions can control earthquake nucleation and the evolution of earthquake sequences. Experimental studies of fault frictional properties in the presence of fluid can provide unique insights into these interactions. We report the first results from experiments performed on cohesive silicate-bearing rocks (microgabbro) in the presence of pressurized pore fluids (H2O, drained conditions) at realistic seismic deformation conditions. The experimental data are compared with those recently obtained from carbonate-bearing rocks (Carrara marble). Contrary to theoretical arguments, and consistent with the interpretation of some field observations, we show that frictional melting of a microgabbro develops in the presence of water. In microgabbro, the initial weakening mechanism (flash melting of the asperities) is delayed in the presence of water; conversely, in calcite marble the weakening mechanism (brittle failure of the asperities) is favored. This opposite behavior highlights the importance of host-rock composition in controlling dynamic (frictional) weakening in the presence of water: cohesive carbonate-bearing rocks are more prone to slip in the presence of water, whereas the presence of water might delay or inhibit the rupture nucleation and propagation in cohesive silicate-bearing rocks.
ISSN: 0091-7613

hal-01054327
https://hal.archives-ouvertes.fr/hal-01054327
DOI : 10.1130/G34916.1

Éditeur(s) : HAL CCSD E Schweizerbart Science Publishers
Résumé : The occurrence and preservation of aragonite in eclogite-facies rocks of north-eastern Corsica is linked to an uncommon microtexture. Aragonite exclusively occurs as oriented fibres in garnet crystals of a graphitic, more or less siliceous marble that immediately overlies a serpentinite body of the meta-ophiolitic unit. The arrangement of the fibres is grossly radial, but more clearly sectoral in subhedral garnet, the fibres growing perpendicular to the garnet/matrix interface. Raman mapping reveals that the carbonate is calcite in the matrix and in poikiloblastic garnet cores, and that the fibres in the garnet mantle are aragonite alone in the case of a carbonate matrix, and both aragonite and quartz (in distinct fibres) in a quartz–carbonate matrix. These features are interpreted as prograde intergrowths, the result of garnet nucleation and growth in a calcite and then aragonite matrix (±quartz). Upon further heating and/or decompression, the aragonite matrix transformed back to calcite while the carbonates included in garnet retained their original structure, in spite of the relatively high temperature attained (ca. 500 °C). These aragonite relics are one more example of the preservation of a high-pressure polymorph through mechanical shielding of inclusions in a rigid host. The aragonite–garnet intergrowths are similar to quartz–garnet intergrowths described in amphibolite-facies graphitic schists. They are evidence that oriented inclusions in garnet are not necessarily precipitates (‘exsolutions'). Unlike precipitates, their orientation is controlled more by the shape of the garnet growth front than by symmetry constraints.
ISSN: 0935-1221

hal-00411136
https://hal.archives-ouvertes.fr/hal-00411136
DOI : 10.1127/0935-1221/2008/0020-1892

Éditeur(s) : HAL CCSD Elsevier
Résumé : Une approche par datations multiples a été menée sur les dépôts de sédiments de crue retrouvés dans les gorges du Gardon (Languedoc). Le plomb-210, le césium-137 et l’analyse géochimique des sédiments contaminés par les mines ont été utilisés pour reconstruire l’histoire des dépôts de crue. Cette approche a été combinée avec l’historique des crues du Gardon depuis 1890 pour affiner l’approche géochronologique. Au niveau de la cavité GG et de la terrasse GE les analyses ont permis d’illustrer les mécanismes d’érosion-redéposition pouvant perturber les séquences de sédiments. Les enregistrements des dépôts de sédiments de crue sont complets sur la terrasse GE située à 10 m au-dessus du lit mineur à partir de 1958, et incomplets auparavant. Sur la période 1880-1958, 25 crues ont eu un débit suffisant (>1450 m3/s) pour recouvrir la terrasse, alors que l’on recense seulement 5 à 6 crues depuis 1958 (pour un débit de submersion supérieur à 1700 m3/s). L’augmentation progressive du débit de submersion et la fréquence moindre d’inondation de la terrasse ont pu permettre sur la période récente la stabilisation de la couche de surface par la végétation et limiter l’érosion lors de crues importantes. Les enregistrements semblent complets dans la cavité GG située à 15 m au-dessus du lit mineur. La fréquence moindre de submersion à ce niveau plus élevé peut expliquer une meilleure stabilisation des dépôts de crue, rendus moins vulnérables à l’érosion. La datation au radiocarbone a été testée même si elle ne permet pas de dater avec précision les dépôts de crue des derniers siècles. Sur la terrasse GE, 80% des dates au carbone 14 sur charbon de bois sont beaucoup trop vieilles par rapport aux autres techniques de datation, ce qui peut s’expliquer par une remobilisation/déstockage de charbons de bois anciens. Les datations radiocarbone sur graines donnent de meilleurs résultats, car issues d’une production annuelle, plus facilement décomposable et moins sujette à des dépôts intermédiaires. Au final, il apparaît que la technique de datation par radiocarbone sur des charbons de bois retrouvés dans les séquences sédimentaires n’est pas fiable, alors qu’elle est la plus pratiquée en paléo-hydrologie. L’utilisation combinée du plomb-210, du césium-137, de l’analyse géochimique des sédiments et des informations sur les crues historiques a permis de discriminer et de dater les différents dépôts de crue de ce dernier siècle dans la cavité GG et la terrasse GE. / A multidating approach was carried out on slackwater flood deposits, preserved in valley side rock cave and terrace, of the Gardon River in Languedoc, southeast France. Lead-210, caesium-137, and geochemical analysis of mining-contaminated slackwater flood sediments have been used to reconstruct the history of these flood deposits. These age controls were combined with the continuous record of Gardon flow since 1890, and the combined records were then used to assign ages to slackwater deposits. The stratigraphic records of terrace GE and cave GG were excellent examples to illustrate the effects of erosion/preservation in a context of a progressively self-censoring, vertically accreting sequence. The sedimentary flood record of the terrace GE located at 10 m above the channel bed is complete for years post-1958 but incomplete before. During the 78-year period 1880-1958, 25 floods of a sufficient magnitude (> 1450 m3/s) have covered the terrace. Since 1958, however, the frequency of inundation of the deposits has been lower:only 5 or 6 floods in 52 years have been large enough to exceed the necessary threshold discharge (> 1700 m3/s). The progressive increase of threshold discharge and the reduced frequency of inundation at the terrace could allow stabilisation of the vegetation cover and improved protection against erosion from subsequent large magnitude flood events. The sedimentary flood record seems complete for cave GG located at 15 m above the channel bed. Here, the low frequency of events would have enabled a high degree of stabilisation of the sedimentary flood record, rendering the deposits less susceptible to erosion. Radiocarbon dating are used in this study and compared to the other dating techniques.Eighty percent of radiocarbon dates on charcoals were considerably older than those obtained by the other techniques in the terrace. On the other hand, radiocarbon dating on seeds provided better results. This discrepancy between radiocarbon dates on charcoal and seeds is explained by the nature of the dated material (permanent wood vs. annual production and resistance to degradation process). Finally, we showed in this study that although the most common dating technique used in paleoflood hydrology is radiocarbon dating, usually on charcoal preserved within slackwater flood sediments, this method did not permitus to define a coherent age model. Only the combined use of lead-210, caesium-137, and geochemical analysis of mining-contaminated sediments with the instrumental flood record can be applied to discriminate and date the recent slackwater deposits of the terrace GE and cave GG.
ISSN: 0169-555X

hal-01059669
https://hal.archives-ouvertes.fr/hal-01059669
https://hal.archives-ouvertes.fr/hal-01059669/document
https://hal.archives-ouvertes.fr/hal-01059669/file/ly2014-pub00040953.pdf
IRSTEA : PUB00040953

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Kimberlites of the Udachnaya-East pipe (Siberia) include a uniquely dry and serpentine-free rock type with anomalously high contents of chlorine (Cl ≤ 6.1 wt%), alkalies (Na2O + K2O ≤ 10 wt%) and sulfur (S ≤ 0.50 wt%), referred to as a “salty” kimberlite. The straightforward interpretation is that the Na-, K-, Cl- and S-rich components originate directly from a carbonate-chloride kimberlitic magma that is anhydrous and alkali-rich. However, because brines and evaporites are present on the Siberian craton, previous studies proposed that the kimberlitic magma was contaminated by the assimilation of salt-rich crustal rocks. To clarify the origin of high Cl, alkalies and S in this unusual kimberlite, here we determine its sulfur speciation and isotopic composition and compare it to that of non-salty kimberlites and kimberlitic breccia from the same pipe, as well as potential contamination sources (hydrothermal sulfides and sulfates, country-rock sediment and brine collected in the area). The average δ34S of sulfides is − 1.4 ± 2.2‰ in the salty kimberlite, 2.1 ± 2.7‰ in the non-salty kimberlites and 14.2 ± 5.8‰ in the breccia. The average δ34S of sulfates in the salty kimberlites is 11.1 ± 1.8‰ and 27.3 ± 1.6‰ in the breccia. In contrast, the δ34S of potential contaminants range from 20 to 42‰ for hydrothermal sulfides, from 16 to 34‰ for hydrothermal sulfates, 34‰ for a country-rock sediment (Chukuck suite) and the regional brine aquifer. Our isotope analyses show that (1) in the salty kimberlites, neither sulfates nor sulfides can be simply explained by brine infiltration, hydrothermal alteration or the assimilation of known salt-rich country rocks and instead, we propose that they are late magmatic phases; (2) in the non-salty kimberlite and breccia, brine infiltration lead to sulfate reduction and the formation of secondary sulfides – this explains the removal of salts, alkali-carbonates and sulfates, as well as the minor olivine serpentinization; (3) hydrothermal sulfur was added to the kimberlitic breccia, but not to the massive kimberlites. In situ measurements of sulfides confirm this scenario, clearly showing the addition of two sulfide populations in the breccia (pyrite-pyrrhotites with average δ34S of 7.9 ± 3.4‰ and chalcopyrites with average δ34S of 38.0 ± 0.4‰) whereas the salty and non-salty kimberlites preserve a unique population of djerfisherites (Cl- and K-rich sulfides) with δ34S values within the mantle range. This study provides the first direct evidence of alkaline igneous rocks in which magmatic sulfate is more abundant than sulfide. Although sulfates have been rarely reported in mantle materials, sulfate-rich melts may be more common in the mantle than previously thought and could balance the sulfur isotope budget of Earth's mantle.
ISSN: 0009-2541

hal-01571982
https://hal.archives-ouvertes.fr/hal-01571982
DOI : 10.1016/j.chemgeo.2016.10.037

Éditeur(s) : HAL CCSD
Résumé : The geological storage of CO 2 is considered as one of the solutions to the problem of global warming. The most possible scenarios of geological behavior of soil in the long term conditions has to be precisely defined to avoid catastrophic damages in the future. Chemical properties of saline water in the aquifer after the CO 2 injection becomes more acidic with time. Therefore, chemical degradation of rock occurs, which leads to modifications of its mechanical properties (chemo-mechanical coupling) [1]. In this paper an incremental model of chemo-mechanical coupling using homogenization approach (asymptotic expansion method [2,3]) is proposed. The paper is focused on the numerical computations for the X-ray tomography image of carbonate rock microstructure [4]. The chemical degradation of the microstructure is obtained as a homogeneous dissolution in each direction (Fig.1. – Fig.2.) For every porosity state numerical computations to obtain full, orthotropic elasticity tensor are performed. Therefore, the degradations functions for all components of the rigidity tensor were defined (Fig.3.). Moreover, results of numerical calculations of diffusion, tortuosity and permeability tensors are presented [5,6]. The link between geometrical properties and mechanical and transport parameters are discussed. The numerical analysis of the carbonate rock sample in long term conditions shows the increase of porosity and associated mechanical weakening of the rock. Moreover, the increase of diffusion, tortuosity and permeability tensors elements with time were observed. Finally, the solution of the one-dimensional macroscopic problem of soil settlement due to chemical dissolution of rock at constant load is presented. The method is universal, in the sense that the non-dimensional time scale is used.
ALERT Workshop 2013
Aussois, France

hal-01103175
https://hal.archives-ouvertes.fr/hal-01103175

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : In the eastern Pyrenees, the lherzolites always outcrop as restricted bodies scattered across Mesozoic sedimentary units along the North Pyrenean fault. In this article, we focus on the sedimentary processes associated with the tectonic exhumation of the mantle rocks during the Lower Cretaceous and we provide a new detailed analysis of the ultramafic-bearing sedimentary sequences associated with the Lherz body. The Lherz body, 1.5 km long only, belongs to a series of ultramafic bodies of restricted size (a few m to some hundred of m), occurring within sedimentary formations composed mostly of carbonate breccias originating from the reworking of Mesozoic platform limestones and dolomites. The carbonate clasts include marbles displaying different evolutions in relation with the Cretaceous thermal metamorphic event. The clastic formations also include numerous layers of polymictic breccias reworking ultramafic clasts. These layers are found far from any peridotitic body, implying that ultramafic clasts have been transported far away from their sources by sedimentary processes after their disaggregation on the seafloor. In addition, clasts of ultramafic-rich breccias and sandstones are also observed which indicates rapid sedimentation and diagenesis within a tectonically active environment. We discuss the significance of these deposits and their bearing on our understanding of the tectono-sedimentary processes associated with mantle exhumation in a context of development of narrow intracontinental basins suffering extreme crustal thinning.
EISSN: 1777-5817

hal-00766884
https://hal.archives-ouvertes.fr/hal-00766884
DOI : 10.2113/gssgfbull.183.5.443

Éditeur(s) : HAL CCSD Elsevier
Résumé : Integrated field, LA-MC-ICP-MS geochronology and geochemical data from the Novo Oriente Group have been investigated in order to determine their provenance and possible tectonic setting. This group in the southwestern portion of the Ceara Central Domain, is a well-preserved metavolcanosedimentary sequence, in part exhalative, composed of two distinct formations. The proximal coastal Bonsucesso Formation comprises mainly quartzite and minor basic metavolcanic rocks and is in gradational contact with the distal Caranbas Formation which constitutes a metapelitic-volcanic-carbonate sequence, including metabasic rocks with pillow structure and sheared serpentinized ultrabasic rocks. The youngest detrital zircon found in the quartzite of the Bonsucesso Formation yielded an age of ca. 2.1 Ga and well-defined peaks around 2.2.2.3-2.4 and 2.5 Ga. In addition, zircons from a related metabasalt yielded an upper intercept age of 2083 +/- 28 Ma. We interpret the zircons found in this metabasalt as inherited from the host quartzite. This fact is supported by depleted-mantle Nd model ages (T-DM age) from correlated metabasic and metaultrabasic rocks from other places in the Novo Oriente sequence, which have yielded ages between 1.36 and 1.69 Ga, that is younger than the zircon age obtained in the metabasalt extruded over the Bonsucesso quartzite. Geochemical data of the metasedimentary rocks from the Caraubas Formation indicates a provenance composed of a mixture of felsic and intermediate sources typical of old stable cratons and older continental roots of active tectonic settings. The rocks of the Crania (Medio Coreau Domain) and Bacaja Complexes (southeastern Amazonian Craton) exposed to the west of the Novo Oriente Group, and largely covered by the Phanerozoic Parnaiba intracratonic basin, are the most likely source rocks. Since the precise age of the Novo Oriente Group is not yet well constrained, two distinct settings may be proposed: (1) it may represent a more evolved basin developed from extensional processes during the Mesoproterozoic (ca. 1.5-1.3 Ga); and (2) it could constitute part of the passive margin systems developed during the break-up of the Rodinia crown copyright supercontinent (ca. 0.95-0.8 Ga), associated with a pre-Brasiliano/Pan-African ocean (e.g. Pharusian Ocean). Crown.
ISSN: 1342-937X

hal-00512825
https://hal.archives-ouvertes.fr/hal-00512825
DOI : 10.1016/j.gr.2010.02.001

Éditeur(s) : HAL CCSD
Résumé : International audience
The porosity (from values of <1% up to more than 50%, with a mean value of 36.5%) and permeability (from very low values to 20.4 D, with a mean value around 800 mD) of 38 plugs, with a diameter 40 mm, have been measured. These plugs were taken approximately every 1.5 m along a 100 m-long core, sampling a series of reefal carbonate platform lithofacies. A non-unique relationship between porosity and permeability is obtained. In addition, the porosity was measured from processing X-ray micro-tomography images with resolutions ranging from 0.42 to 190.0 µm and sampling volumes ranging from less than 1 µm3 to few cm3. Depending on the structure of the pore network, the computed porosity is, in some cases, controlled by the X-ray image resolution and the sampled volume. While high resolution is required to image micro-porous material, large samples with lower resolution images are necessary for identifying distributed vugs and millimetre-scale structures. This study shows that multi-resolution X-ray micro-tomography is an effective tool for characterizing the multi-scale pore structure of carbonate rocks and understanding how it may control key petrophysical parameters such as porosity and permeability.
Geological Society Special Publication

hal-01174157
https://hal.archives-ouvertes.fr/hal-01174157
DOI : 10.1144/SP406.12

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
The chemical and isotopic compositions of clay minerals such as illite and chlorite are commonly used to quantify diagenetic and low-grade metamorphic conditions, an approach that is also used in the present study of the Monte Perdido thrust fault from the South Pyrenean fold-and-thrust belt. The Monte Perdido thrust fault is a shallow thrust juxtaposing upper Cretaceous-Paleocene platform carbonates and Lower Eocene marls and turbidites from the Jaca basin. The core zone of the fault, about 6 m thick, consists of intensely deformed clay-bearing rocks bounded by major shear surfaces. Illite and chlorite are the main hydrous minerals in the fault zone. Illite is oriented along cleavage planes while chlorite formed along shear veins (<50 μm in thickness). Authigenic chlorite provides essential information about the origin of fluids and their temperature. δ18O and δD values of newly formed chlorite support equilibration with sedimentary interstitial water, directly derived from the local hanging wall and footwall during deformation. Given the absence of large-scale fluid flow, the mineralization observed in the thrust faults records the P-T conditions of thrust activity. Temperatures of chlorite formation of about 240°C are obtained via two independent methods: chlorite compositional thermometers and oxygen isotope fractionation between cogenetic chlorite and quartz. Burial depth conditions of 7 km are determined for the Monte Perdido thrust reactivation, coupling calculated temperature and fluid inclusion isochores. The present study demonstrates that both isotopic and thermodynamic methods applied to clay minerals formed in thrust fault are useful to help constrain diagenetic and low-grade metamorphic conditions.
ISSN: 0010-7999

hal-00757736
https://hal.archives-ouvertes.fr/hal-00757736
DOI : 10.1007/s00410-011-0718-0

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : Results are reported for an acidic water flow-through experiment conducted in a fractured argillaceous limestone sample (73% carbonates). The change in fracture geometry and related parameters is reported for six data sets obtained from synchrotron X-ray microtomography experiments. High-resolution three-dimensional images of the sample allowed quantification of the changes in fracture morphology at a spatial resolution of 6 ;μm. Mineral mass loss and permeability changes in the sample were also determined. Several physico-chemical phenomena were identified during the experiment. Initial smooth fracture surfaces evolved rapidly toward rough surfaces with uneven clay coverage due to the preferential dissolution of carbonate minerals compared to clay minerals whose dissolution rate is about 106 slower. A microporous clay coating progressively developed at the fluid-rock interface during heterogeneous dissolution of the fracture, while the global dissolution rate of the fracture walls exponentially decreased. The increase in surface roughness and the presumed reorganization of clays caused a progressive reduction in permeability. During the last flow-through stage, a large decrease in sample permeability was attributed to the large removal of clay particles; this process was responsible for a dramatic collapse of the fracture walls near the sample inlet and led to the development of preferential flow pathways. The development of the clay coating also acted as a barrier to flow and mass transfer between calcite grains and bulk solution and affected transport processes within the fracture
ISSN: 0043-1397

hal-00405333
https://hal.archives-ouvertes.fr/hal-00405333
DOI : 10.1029/2006WR005379

Éditeur(s) : HAL CCSD
Résumé : In coastal carbonate aquifers submitted to a saline intrusion, water - rock interactions processes at the interface between freshwater and saltwater are a cause for heterogeneities development within the porous media. The dissolutions and precipitations induced by the mixing zone play a major role in the transport properties of the reservoir and so in the long term evolution of the saltwater intrusion. The characterization and the in situ observation of a current saline intrusion in the Llucmajor carbonate platform at the experimental site of Ses Sitjoles (South-Easth of Mallorca Island, Spain), allowed to study the temporal evolution of the saltwater intrusion and the biogeochemical processes active in the mixing zone. The influence of microstructure, characterized using X-Ray microtomography, on the petrophysical and flow properties was investigated in laboratory and flow-through experiments were also conducted to study the modifications of the microstructures when submitted to water - rock interactions processes. The mixing zone at the Ses Sitjoles site appears as quite thick and not very sensitive to climate and anthropic stress and is proved to be the locus of active microbiological activity. Laboratory studies highlight a strong control of the microporosity on transport processes and of pCO2 on water - rock interactions. The percolation experiments of slightly reactive waters reveal calcite dissolution together with a decrease in permeability due to a rearrangement of micro-grains within the microporous network.
Les processus d'interactions fluide-roche à l'interface eau douce-eau salée, dans les aquifères carbonatés côtiers soumis à une intrusion saline, sont une des causes du développement d'hétérogénéités dans la structure du milieu poreux. Les dissolutions et/ou précipitations engendrées par la présence de cette zone de mélange jouent un rôle déterminant pour les propriétés de transport du réservoir et donc l'évolution à long terme de l'intrusion d'eau salée. En prenant l'exemple de la plateforme carbonatée de Llucmajor au niveau du site expérimental de Ses Sitjoles (Sud-Est de Majorque, Espagne), un travail de caractérisation et d'observation in situ à moyen terme de l'intrusion saline actuelle de ce réservoir permet de décrire son évolution temporelle et les processus biogéochimiques actifs dans la zone de mélange. L'influence de la microstructure du milieu poreux, caractérisée par microtomographie RX, sur les propriétés pétrophysiques et hydrodynamiques est étudiée en laboratoire et des expériences de percolations d'eaux réactives (mélanges eau douce - eau salée et eau pure chargée en CO2) sont réalisées afin d'étudier les modifications de ces microstructures lorsqu'elles sont soumises à des interactions eau - roche. La zone de mélange eau douce - eau salée rencontrée au niveau du site de Ses Sitjoles est large et peu sensible aux contraintes extérieures (climatologiques et anthropiques) et constitue un lieu d'activité microbiologique particulièrement actif. En laboratoire, on observe un fort contrôle des phénomènes de transport par la microporosité et des processus d'interactions eau - roche par la pCO2. Dans le cas d'une percolation de fluides moyennement réactifs, les expériences mettent en évidence une dissolution de calcite accompagnée par une diminution de la perméabilité, liée à un réarrangement des micro-grains à l'intérieur du réseau microporeux.
https://tel.archives-ouvertes.fr/tel-00767152

tel-00767152
https://tel.archives-ouvertes.fr/tel-00767152
https://tel.archives-ouvertes.fr/tel-00767152/document
https://tel.archives-ouvertes.fr/tel-00767152/file/thesegaring.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
During compressive events, deformation in sedimentary basins is mainly accommodated by thrust faulting and related fold growth. Thrust faults are generally rooted in the basement and may act as conduits or barriers for crustal fluid flow. Most of recent studies suggest that fluid flow through such discontinuities is not apparent and depends on the structural levels of the thrust within the fold-and-thrust belt. In order to constrain the paleofluid flow through the Jaca thrust-sheet-top basin (Paleogene southwest-Pyrenean fold-and-thrust belt) this study compares on different thrust faults located at different structural levels. The microstructures in the different fault zones studied are similar and consist of pervasive cleavage, calcite shear veins (SV1), extension veins (EV1) and late dilatation veins (EV3). In order to constrain the nature and the source of fluids involved in fluid-rock interactions within fault zones, a geochemical approach, based on oxygen and carbon stable isotope and trace element compositions of calcite from different vein generations and host rocks was adopted. The results suggest a high complexity in the paleohydrological behaviors of thrust faults providing evidence for a fluid-flow compartmentalization within the basin. Previous studies in the southern part of the Axial Zone (North of the Jaca basin) indicates a circulation of deep metamorphic water, probably derived from the Paleozoic basement, along fault zones related to the major basement Gavarnie thrust. In contrast, in northern part of the Jaca basin, the Monte Perdido thrust fault is affected by a closed hydrological fluid system involving formation water during its activity. The Jaca and Cotiella thrust faults, in turn, both located more to the south in the basin, are characterized by a composite fluid flow system. Indeed, stable isotope and trace element compositions of the first generations of calcite veins suggest a relatively closed paleohydrological system, whereas the late calcite vein generations, which are probably associated with the late tectonic activity of the basin, support a contribution of both meteoric and marine waters. Based on these results, a schematic fluid-flow model is presented. This model allows visualization of three main fluid flow compartments along a N-S transect.
ISSN: 0264-8172

hal-00963606
https://hal.archives-ouvertes.fr/hal-00963606
DOI : 10.1016/j.marpetgeo.2013.09.005

Éditeur(s) : HAL CCSD
Résumé : International audience
Sub-continental lithospheric mantle rocks are exhumed at the foot of magma-poor distal passive margins as aresponse to extreme stretching of the continental crust during plate separation. Remnants of the Northern Iberianpaleo-passive margin are now exposed in the North-Pyrenean Zone (NPZ) and represent field analogues to studythe processes of continental crust thinning and subcontinental mantle exhumation. The NPZ results from theinversion of basins opened between the Iberia and Europa plates during Albo-Cenomanian times. In the westernNPZ, the ‘Chaînons Béarnais’ ranges display a fold-and-thrust structure involving the Mesozoic sedimentarycover, decoupled from its continental basement and associated with peridotite bodies in tectonic contact withPalaeozoic basement lenses of small size. Continental extension developed under hot thermal conditions, asdemonstrated by the syn-metamorphic Cretaceous ductile deformation affecting both the crustal basement and theallochthonous Mesozoic cover.In this study, we present structural and geochemical data providing constraints to reconstruct the evolution ofthe northern Iberia paleo-margin. Field work confirms that the pre-rift Mesozoic cover is intimately associatedto mantle rocks and to thin tectonic lenses of crustal basement. It also shows that the pre-rift cover was detachedfrom its bedrock at the Keuper evaporites level and was welded to mantle rocks during their exhumation atthe foot of the hyper-extended margin. The crust/mantle detachment fault is a major shear zone characterizedby anastomosed shear bands defining a plurimetric phacoidal fabric at the top of the serpentinized mantle. Thedetachment is marked by a layer of metasomatic rocks, locally 20 meters thick, made of talc-chlorite-pyrite-richrocks that developped under greenschist facies conditions. Raman Spectroscopy on Carbonaceous Materials(RSCM), performed on the Mesozoic cover reveal that the entire sedimentary pile underwent temperatures rangingbetween 200C and 480C.We show that: (i) at the site of mantle rocks exhumation, the boudinaged pre-rift sediments have undergone drasticsyn-metamorphic thinning with the genesis of a S0/S1 foliation and, (ii) the Paleozoic basement has been ductilelydeformed, into thin tectonic lenses that remained welded to the exhumed mantle rocks. Therefore the overallcrustal rheology appears dominated by shallow levels having a ductile behavior. This rheology is related to thepresence of a thick pre- and syn-rift decoupled cover acting as an efficient thermal blanket. This new geologicaldata set highlights important characteristics of ductile-type hyper-extended passive margin that cannot be obtainedfrom the study of seismic lines. Finally, we stress that studying field analogues represents a major tool to betterunderstand the mechanisms of extreme crustal thinning associated with mantle exhumation and their structuralinheritance during tectonic inversion.
Geophysical Research Abstracts
Vienne, Austria

insu-01510103
https://hal-insu.archives-ouvertes.fr/insu-01510103

Éditeur(s) : HAL CCSD
Résumé : International audience
The carbon capture and storage is considered as one of the solutions of reducing the effects of global warming. It consists in injecting large quantities of CO 2 in supercritical form directly into deeply located geological formations. One of the methods involves sequestration in the carbonate sedimentary rocks (sandstones and limestones) which are considered as a promising solution. The morphology of the pore network and solid skeleton defines important macroscopic prop-erties of the rock (permeability, stiffness). Modelling at micro scale of random heterogeneous materials (porous media) should be based on morphological and statistical characterisation 1,2 of the investigated microstructure. The work is focused on a reconstruction method by grains deposit 3 , for various range of pa-rameters, to obtain equivalent model of natural rock samples (oolitic limestone and fontainebleau sandstone). Generated samples satisfy morphological and statistical informations 4 which were obtained by 3D image analysis of X-ray tomography of the natural rock samples. For validation of the modelling numerical computations of mechanical and transfer properties are also provided.
14th European Mechanics of Materials Conference - EMMC14
Gothembourg, Sweden

hal-01103163
https://hal.archives-ouvertes.fr/hal-01103163

Éditeur(s) : HAL CCSD Copernicus Publications
Résumé : International audience
During Ocean Drilling Program Leg 134, a mixed sequence of volcaniclastic and carbonate sediments was cored together with basaltic breccias and a single basalt sill in Hole 833B. In this study, data from Schlumberger's Geochemical Logging Tool, together with physical property logs, characterise part of the section and establish a complete log-derived lithostratigraphy. The major transition between the sedimentary rocks and a basaltic sill at 830 mbsf (metres below sea floor) is clearly seen as well as the distinction between the silicate-rich sediments and the carbonate-rich part of the section. The transition between the volcanic sandstone interbedded with basaltic and sed-lithic breccia of Unit III, and the volcanic sandstone of Unit IV is clearly marked by the physical property logs. The accuracy of the logging data was evaluated and discussed with an improved log versus core correlation. The cluster analysis of the complete data set shows a correlation with the data provided by the mechanical caliper device, which in turn indicates the quality of the borehole.
ISSN: 1816-8957

hal-00642165
http://hal.upmc.fr/hal-00642165
http://hal.upmc.fr/hal-00642165/document
http://hal.upmc.fr/hal-00642165/file/Rabaute_et_al-SciDrilling-1997.pdf

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
This paper presents a new balanced structural cross-section of the Jaca thrust-sheet-top basin of the southern Pyrenees combined with paleo-thermometry and apatite fission track (AFT) thermochronology data. The cross-section, based on field data and interpretation of industrial seismic reflection profiles, allows refinement of previous interpretations of the south-directed thrust system, involving the identification of new thrust faults, and of the kinematic relationships between basement and cover thrusts from the middle Eocene to the early Miocene. AFT analysis shows a southward decrease in the level of fission track resetting, from totally reset Paleozoic rocks and lower Eocene turbidites (indicative of heating to Tmax > ~120 °C), to partially reset middle Eocene turbidites and no/very weak resetting in the upper Eocene-lower Oligocene molasse (Tmax < ~60 °C). AFT results indicate a late Oligocene-early Miocene cooling event throughout the Axial Zone and Jaca Basin. Paleo-maximum temperatures determined by vitrinite reflectance measurements and Raman spectroscopy of carbonaceous material reach up to ~240 °C at the base of the turbidite succession. Inverse modelling of AFT and vitrinite reflectance data with the QTQt software for key samples show compatibility between vitrinite-derived Tmax and the AFT reset level for most of the samples. However, they also suggest that the highest temperatures determined in the lowermost turbidites correspond to a thermal anomaly rather than burial heating, possibly due to fluid circulation during thrust activity. From these results, we propose a new sequential restoration of the south Pyrenean thrust system propagation and related basin evolution.
ISSN: 0278-7407

insu-01312746
https://hal-insu.archives-ouvertes.fr/insu-01312746
https://hal-insu.archives-ouvertes.fr/insu-01312746/document
https://hal-insu.archives-ouvertes.fr/insu-01312746/file/Labaume_et_al-2016-Tectonics.pdf
DOI : 10.1002/2016TC004192