Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : Solidus phase relations of carbon dioxide-saturated (CO2 vapor) model peridotite in the system CaO-MgO-Al2O3-SiO2-CO2 in the 1.1-2.1 GPa pressure range are reported. The solidus has a positive slope in pressure-temperature (PT) space from 1.1 to 2 GPa. Between 2 and 2.1 GPa, the melting curve changes to a negative slope. From 1.1 to 1.9 GPa, the liquid, best described as CO2-bearing silicate liquid, is in equilibrium with forsterite, orthopyroxene, clinopyroxene, spinel, and vapor. At 2 GPa, the same crystalline phase assemblage plus vapor is in equilibrium with two liquids, which are silicate and carbonatitic in composition, making the solidus at 2 GPa PT invariant. The presence of two liquids is interpreted as being due to liquid immiscibility. Melting reactions written over 1.1-1.9 GPa are peritectic, with forsterite being produced upon melting, and the liquid is silicate in composition. Upon melting at 2.1 GPa, orthopyroxene is produced, and the liquid is carbonatitic in composition. Hence, the invariance between 1.9 and 2.1 GPa is not only the reason for the dramatic change in the liquid composition over an interval of 0.2 GPa, but the carbonated peridotite solidus ledge itself most likely appears because of this PT invariance. It is suggested that because carbonatitic liquid is produced at the highest solidus temperature at 2 GPa in PT space in the system studied, such liquids, in principle, can erupt through liquid immiscibility, as near-primary magmas from depths of approximately 60 km.
ISSN: 0148-0227

hal-00939406
https://hal.archives-ouvertes.fr/hal-00939406
DOI : 10.1002/jgrb.50249

Éditeur(s) : HAL CCSD
Résumé : International audience
The Jaca basin is a thrust-sheet top basin transported southward andunderlain by basement and cover thrusts separated by a Triassic décollement.Basin-fill upper Cretaceous to lower Oligocene synorogenic sequencesrecord a southward depocenter migration, while growth stratadate a shift of deformation from the mid-Eocene in the N to the earlyMiocene in the S (S-Pyrenean front). However, the deep geometry andkinematic relationships between the cover and basement thrusts remainnon-consensual. We present a new structural and kinematic interpretationfor the eastern Jaca basin, based on subsurface structural maps andcross-sections constructed using industrial seismic reflection profiles.Raman Spectroscopy of Carbonaceous Material (RSCM), vitrinite reflectanceand apatite fission track (AFT) thermochronology data givefurther constraints for the restoration of the deformation and burialexhumationsequence. We define 3 main basement thrusts under thenorthern part of the basin, from N to S the Broto, Fiscal and Guargathrusts. The study also clarifies the deep structure of the cover thrustsand their links with these basement thrusts and those located more tothe north in the Axial Zone (AZ), which altogether define the timing ofthe basement thrust sequence as follows : the Lakoura-Eaux Chaudesthrust system (northern AZ) active up to the end Bartonian, the Gavarnie(central AZ) and Broto thrusts during the Priabonian-Rupelian andthe Fiscal and Guarga thrusts during the late Oligocene-early Miocene.AFT results in the basin fill and AZ date the exhumation of the basinto the late Oligocene-early Miocene, in relation to the Fiscal-Guargathrusting. AFT partial reset argues for a maximum burial < 6 km forthe base of the Eocene detrital sequence (Hecho Group turbidites). Bycontrast, RSCM and vitrinite thermometry at the same level indicatesTmax around 180°C, locally up to 240°C, attesting to a temperature anomalypossibly related to transient fluid circulation.
24 ème Réunion des sciences de la Terre 2014
Pau, France

insu-01080836
https://hal-insu.archives-ouvertes.fr/insu-01080836

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Chromatin modification enzymes are important regulators of gene expression and some are evolutionarily conserved from yeast to human. Saccharomyces cerevisiae is a major model organism for genome-wide studies that aim at the identification of target genes under the control of conserved epigenetic regulators. Ume6 interacts with the upstream repressor site 1 (URS1) and represses transcription by recruiting both the conserved histone deacetylase Rpd3 (through the co-repressor Sin3) and the chromatin-remodeling factor Isw2. Cells lacking Ume6 are defective in growth, stress response, and meiotic development. RNA profiling studies and in vivo protein-DNA binding assays identified mRNAs or transcript isoforms that are directly repressed by Ume6 in mitosis. However, a comprehensive understanding of the transcriptional alterations, which underlie the complex ume6Δ mutant phenotype during fermentation, respiration, or sporulation, is lacking. We report the protein-coding transcriptome of a diploid MAT a/α wild-type and ume6/ume6 mutant strains cultured in rich media with glucose or acetate as a carbon source, or sporulation-inducing medium. We distinguished direct from indirect effects on mRNA levels by combining GeneChip data with URS1 motif predictions and published high-throughput in vivo Ume6-DNA binding data. To gain insight into the molecular interactions between successive waves of Ume6-dependent meiotic genes, we integrated expression data with information on protein networks. Our work identifies novel Ume6 repressed genes during growth and development and reveals a strong effect of the carbon source on the derepression pattern of transcripts in growing and developmentally arrested ume6/ume6 mutant cells. Since yeast is a useful model organism for chromatin-mediated effects on gene expression, our results provide a rich source for further genetic and molecular biological work on the regulation of cell growth and cell differentiation in eukaryotes.
ISSN: 1617-4615

hal-01151619
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01151619
DOI : 10.1007/s00438-015-1051-5
PUBMED : 25957495

Éditeur(s) : Elsevier France-editions Scientifiques Medicales Elsevier
Résumé : The essential characteristics of the vegetation dynamics of tropical Africa remain only partially known. This study assesses the succession of vegetation-types over Central Africa during the last two glacial/interglacial cycles. Analysis of core KZai 02, which contains pollen from the Zaire River watershed (latitudes 9°N-13°S), allows the investigation of long-term patterns of plant ecosystem development and their climatic causes. Core KZai 02 (18.20 m long) was recovered from 6°24.20′S/9°54.10′E in the uppermost axial edifice of the Zaire deep sea fan. The chronology of this sedimentary archive was established using nannofossils and correlations of pollen and total organic carbon signals with the nearby core GeoB1008. The pollen record indicates that: (i) glacials (MIS 6, 4, 2) are marked by the development of afromontane (Podocarpus) forest at high altitudes when central basin lowlands were occupied by Cyperaceae marshes and savannah; (ii) during interglacials (MIS 1, 5) lowland forests were developed, marked by the successive expansion of pioneer, warm-temperate, rain forests, and mangrove indicating sea-level rise; (iii) glacial-interglacial transitions (MIS 6/5, 2/1) display similar vegetation dynamics. The strong evidence of afromontane forest and the opening of the vegetation during glacials suggest a reduced latitudinal distribution of rainfall by the strengthening of the trade wind system. West African monsoon systems were enhanced during interglacials, allowing the progressive development of lowland forests. The development of rain and pioneer forests during glacial Heinrich stadials suggests an enhancement of water availability in tropical Africa associated with these high latitude events. However, no augmentation of wind activity, described by previous studies, is evidenced by our pollen record. Similar vegetation successions during glacial/interglacial transitions suggest the diachronous and stepped intervention of CO2 (emphasizing the influence of temperature on plant ecosystems) and water availability.
Geobios (0016-6995) (Elsevier France-editions Scientifiques Medicales Elsevier), 2014-07 , Vol. 47 , N. 4 , P. 183-198

Droits : 2014 Elsevier Masson SAS. All rights reserved.
http://archimer.ifremer.fr/doc/00199/31031/29436.pdf
DOI:10.1016/j.geobios.2014.06.002
http://archimer.ifremer.fr/doc/00199/31031/

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : The present study aims to review palaeoecological evidence for environmental changes induced by human activities over the last few millennia in the montane landscapes of Morocco. The study is based on well-dated pollen and geochemical records from the Rif and the Middle Atlas mountains, to show spatial and temporal variation in the onset and intensity of exploitation of forest, soil and mineral resources. Before ca. 2000 BP, anthropogenic impact was minimal. At about that time, abrupt changes of the arboreal pollen proportions, with a decline in all tree taxa, indicate a reduction of the forest cover interpreted as being anthropogenic. In the Rif Mountains, increased influx of carbonates (Ca) in the sedimentary records indicates enhanced soil erosion coincident with the reduction in tree cover. In the Middle Atlas, reduced forest cover is linked to geochemical evidence for mining and metallurgy of lead (Pb), copper (Cu) and zinc (Zn). These industrial activities correspond to the expansion of the Roman Empire into Morocco at around AD 40 and show a decline when the Romans were displaced by the Vandals about five centuries later.
ISSN: 0263-0338

hal-01217206
https://hal.archives-ouvertes.fr/hal-01217206
DOI : 10.1007/s10437-015-9186-7

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : Late Jurassic platform carbonates of Languedoc (southern France) are deeply incised by Late Miocene canyons, allowing the observation of karst systems filled with sediments containing evidences of marine origin. Field and structural relationships as well as new biostratigraphic data (planktonic foraminifera and calcareous nannofossils) provide a Latest Cretaceous-Earliest Paleocene age for the major karstification and a Paleocene (Danian-Selandian) age for the sedimentary filling. The ≥ 350 m vertical extent of this karst system and its subsequent marine filling gives a minimum amplitude for the base-level variation responsible for the karstification and then the marine flooding events. The observations suggest that at least, two marine successive events occurred in the Late Danian then in Selandian time. The large amplitude of base level is not in agreement with eustatic sea-level change, and the rate of base-level change is too fast for tectonic uplift and subsidence within the tabular, poorly deformed studied area. We propose a model of a silled endoreic basin, which was dessiccated and karstified over hundreds of meters, when it was disconnected from the World Ocean, and later suddently transgressed by the Paleocene sea and the karst flooded, when the bounding sill was submerged. Such a model is similar, although with significant differences, with the later Messinian-Zanclean event that affected the Mediterranean realm.
EISSN: 1777-5817

hal-00767556
https://hal.archives-ouvertes.fr/hal-00767556
DOI : 10.2113/gssgfbull.183.5.425

Éditeur(s) : HAL CCSD Elsevier
Résumé : High-precision Ni isotopic variations are reported for the metal phase of equilibrated and unequilibrated ordinary chondrites, carbonaceous chondrites, iron meteorites, mesosiderites, and pallasites. We also report new Zn and Cu isotopic data for some of these samples and combine them with literature Fe, Cu, and Zn isotope data to constrain the fractionation history of metals during nebular (vapor/solid) and planetary (metal/sulfide/silicate) phase changes. The observed variations of the Ni-62/Ni-58, Ni-61/Ni-58, and Ni-60/Ni-58 ratios vary linearly with mass difference and define isotope fractionation lines in common with terrestrial samples. This implies that Ni was derived from a single homogeneous reservoir. While no Ni-60 anomaly is detected within the analytical uncertainties, Ni isotopic fractionation up to 0.45 parts per thousand per mass-difference unit is observed. The isotope compositions of Ni and Zn in chondrites are positively correlated. We suggest that, in ordinary chondrites, exchange between solid phases, in particular metal and silicates, and vapor followed by mineral sorting during accretion are the main processes controlling these isotopic variations. The positive correlation between Ni and Zn isotope compositions contrasts with a negative correlation between Ni (and Zn) and Cu isotope compositions, which, when taken together, do not favor a simple kinetic interpretation. The observed transition element similarities between different groups of chondrites and iron meteorites are consistent with the genetic relationships inferred from oxygen isotopes (IIIA/pallasites and IVA/L chondrites). Copper is an exception, which we suggest may be related to separate processing of sulfides either in the vapor or during core formation. (C) 2007 Elsevier Ltd. All rights reserved.
ISSN: 0016-7037

hal-00408304
https://hal.archives-ouvertes.fr/hal-00408304
DOI : 10.1016/j.gca.2007.06.049

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
Melting phase relations of model carbonated peridotite in the system CaO-MgO-Al2O3-SiO2-CO2 from 2 to 3 GPa are reported. Experimentally produced melts, which are model carbonatites, with approximately 36-40 wt % CaO, 12-17 wt % MgO, 0.2-1.5 wt % Al2O3, 1-4 wt % SiO2, and 40-42 wt % CO2 (carbon dioxide) are present at all pressures investigated. At 2.8 and 3 GPa, carbonatitic melts are seen experimentally at temperatures that are very close to the vapor-free (CO2) peridotite solidus and are found in equilibrium with forsterite, orthopyroxene, clinopyroxene, and garnet. Solidus phase relations with isobaric and pressure-temperature invariant points, defining the so-called carbonated peridotite solidus ledge, are also reported from 2.1 to 3 GPa. A divariant region exists from 2 to 2.6 GPa wherein two, compositionally different melts are present. In this region, these two melts, carbonatitic and silicate in composition, coexist with crystalline phase assemblage and free vapor. The silicate liquid has approximately 30-48 wt % SiO2 and approximately 6 to 20 wt % of dissolved CO2. The presence of carbonatitic and silicate liquids is interpreted to be due to liquid immiscibility. On the basis of melting phase relations reported here, we conclude that (a) the ledge is a feature along which model carbonatitic liquids are produced by reaction of silicates and CO2 vapor and (b) alkali-free carbonatites and silicate melts can form through melt unmixing at depths of ~60-80 km in the Earth's mantle.
ISSN: 0148-0227

hal-01053913
https://hal.archives-ouvertes.fr/hal-01053913
DOI : 10.1002/2013JB010913

Éditeur(s) : Society for General Microbiology
Résumé : A novel piezotolerant, mesophilic, facultatively anaerobic, organotrophic, polarly flagellated bacterium (strain LT13a(T)) was isolated from a deep sediment layer in the Nankai Trough (Leg 190, Ocean Drilling Program) off the coast of Japan. This organism used a wide range of organic substrates as sole carbon and energy sources: pyruvate, glutamate, succinate, fumarate, lactate, citrate, peptone and tryptone. Oxygen, nitrate, fumarate, ferric iron and cystine were used as electron acceptors. Maximal growth rates were observed at a hydrostatic pressure of 10 MPa. Hydrostatic pressure for growth was in the range 0.1-50 MPa. Predominant cellular fatty acids were 16:1 omega7c, 15: 0 iso, 16: 0 and 13: 0 iso. The G + C content of the DNA was 44.9 mol%. On the basis of 16S rRNA gene sequences, strain LT13a(T) was shown to belong to the gamma-Proteobacteria, being closely related to Shewanella putrefaciens (98%), Shewanella oneidensis (97%) and Shewanella baltica (96 %). Levels of DNA homology between strain LT13a(T) and S. putrefaciens, S. oneidensis and S. baltica were < 20 %, indicating that strain LT13a(T) represents a novel species. Genetic evidence and phenotypic characteristics showed that isolate LT13a(T) constitutes a novel species of the genus Shewanella, Because of the deep origin of the strain, the name Shewanella profunda sp. nov. is proposed, with LT13a(T) (= DSM 15900(T)-JCM 12080(T)) as the type strain.
International journal of systematic and evolutionary microbiology (1466-5026) (Society for General Microbiology), 2004-11 , Vol. 54 , N. 6 , P. 1943-1949

Droits : 2004 International Union of Microbiological Societies
http://archimer.ifremer.fr/doc/2004/publication-590.pdf
DOI:10.1099/ijs.0.03007-0
http://archimer.ifremer.fr/doc/00000/590/

Éditeur(s) : HAL CCSD Springer Verlag/EDP Sciences
Résumé : We characterised the among species variability in leaf gas exchange and morphological traits under controlled conditions of seedlings of 22 tropical rainforest canopy species to understand the origin of the variability in leaf carbon isotope discrimination (Delta) among species with different growth and dynamic characteristics (successional gradient). Our results first suggest that these species pursue a consistent strategy in terms of (Delta) throughout their ontogeny (juveniles grown here versus canopy adult trees from the natural forest). Second, leaf (Delta) was negatively correlated with WUE and N, and positively correlated with gs, but among species differences in (Delta) were mainly explained by differences in WUE. Finally, species belonging to different successional groups display distinct leaf functional and morphological traits. We confirmed that fast growing early successional species maximise carbon assimilation with high stomatal conductance. In contrast, fast and slow growing late successional species are both characterised by low carbon assimilation values, but by distinct stomatal conductance and leaf morphological features. Along the successional gradient, these differences result in much lower (Delta) for the intermediate species (i.e. fast growing late successional) as compared to the two other groups.
ISSN: 1286-4560

hal-01032038
https://hal.archives-ouvertes.fr/hal-01032038
DOI : 10.1051/forest:2006101

Éditeur(s) : HAL CCSD Montpellier : CIRAD
Résumé : Les aménagements futurs nécessaires au développement rapide de la Guyane vont entraîner la conversion de terres forestières, participant ainsi au changement global. Les décideurs guyanais devront conjuguer ces aménagements avec la préservation des services écosystémiques forestiers. Le projet GuyaSim avait comme objectif l’approfondissement des connaissances sur ces services (stock de carbone, biodiversité et qualité du sol)et le transfert d’un logiciel aux décideurs pour faciliter l’intégration de ces connaissances dans les politiques d’aménagement du territoire. L’article présente les caractéristiques et les fonctionnalités de ce logiciel GuyaSim. Il s’agit d’un logiciel libre de type Sig, destiné a priori aux services d’aménagement des collectivités et du domaine forestier de Guyane. Le logiciel offre deux grands types de fonctionnalité : la mise à disposition d’informationset l’aide à l’aménagement. Les informations mises à disposition sont les scénarios de développement socio-économique, les scénarios climatiques et les valeurs des services écosystémiques. L’aide à l’aménagement consiste en des outils de construction des scénarios d’aménagement du territoire (changement d’usage des terres) et d’aménagement forestier (exploitation forestière), fournissant des informations sur l’impact environnemental. Les fonctionnalités du logiciel sont limitées par les connaissances sur les écosystèmes guyanais. Les avancées des projets de recherche en cours permettront de mettre à jour le logiciel à moyen terme
ISSN: 0006-579X

hal-01535354
https://hal.archives-ouvertes.fr/hal-01535354
PRODINRA : 351684

Éditeur(s) : HAL CCSD Thieme Publishing
Résumé : International audience
To determine the effect of triathlete performance level on the cardiorespiratory responses elicited by the cycle-run succession, eight regionally and nationally-ranked (Competitive) and five internationally-ranked (Elite) male triathletes underwent four successive laboratory trials: 1) an incremental treadmill test, 2) an incremental cycle test, 3) 30 min of cycling followed by 20 min of running (C-R), and 4) a 20-min control run (R) at the same speed as the run in C-R. Before and 10 min after the third and fourth trials the triathletes underwent lung function testing: spirometry and diffusing capacity testing for carbon monoxide (DL(CO)). During the C-R trial blood samples were drawn to measure venous lactate concentration. During all trials ventilatory data were collected every minute using an automated breath-by-breath system. The results showed that 1) the oxygen uptake (VO2) of post-cycling running versus running alone was similar for both groups; 2) the ventilatory responses (VE, VE/VO2, VE/VC02 and f) of C-R running versus R were significantly higher (P < 0.005) for the Competitive group; and 3) a significant decrease (P< 0.05) in DL(CO) was also noted after the C-R trial in the Competitive group but not in the Elite group. We concluded that 1) the ventilatory responses during a run subsequent to cycling may be related to the triathlete performance level, and 2) the C-R trial induced specific alterations in pulmonary function that may be associated with respiratory muscle alteration and exercise-induced hypoxemia in the Competitive triathletes.
ISSN: 0172-4622

hal-00720719
https://hal.univ-antilles.fr/hal-00720719

Éditeur(s) : HAL CCSD
Résumé : International audience
In the context of climate change, this study presents the ability of major/trace elements together with strontiumisotopes to trace back water paths at small scale and to deconvolve the geochemical signal of a small watershedsubject to intense flash floods episodes (Peyne, Hérault, France). Two small sub-basins draining distinct lithologiesin their heads (Plio-Villafranchian conglomerate versus Triassic gypsum-rich marls and dolomites) and the sameMiocene lithology downstream are investigated.Major elements and Ca/Na vs. Mg/Na ratios classically applied at large scale to distinguish carbonate from silicateweathering, allow here discriminating the three main lithologies from the two sub-basins. Trace elements Rband Sr coupled to calcium, also allow this lithological discrimination but in addition the Ca/Rb vs. Sr/Rb tracersappear to be much more discriminant for the various hydrological conditions. Thus, in combination with detailedlithological descriptions, they allow identifying the different facies that imprint the water signature through water-rock interaction according to the hydrological conditions.Strontium isotopes and Rb/Sr ratio, discriminate more precisely the drained lithologies of the 2 sub-basins. Firstly,the 87Sr/86Sr ratios allow identifying the nature of the lithologies and their main component(s) contributing to theSr budget in water and thus imprint the isotopic signature. Secondly, Sr isotopes evidenced two distinct Miocenefacies: the detritric faction (sandy marls), and the marine carbonates.The geochemical signatures of the brook samples draining both compartments were compared to the signatureof the Peyne River outlet just before the confluence into the Hérault River. It appears that the signature of thePeyne River, integrating all the water draining the basin, is relatively stable whatever the hydrological conditionsand mainly marked by the Miocene formations. Sr isotopes further highlight that this signature seems to resultfrom the mixing of both Miocene facies present in the lower part of the Peyne watershed, i.e. the sandy marls andthe carbonates. The typical signatures of the Plio-Villafanchian conglomerates and Triassic gypsiferous marls anddolomites of the headwaters of each sub-basin are completely hidden by the Miocene signatures. This should berelated to the large drainage area of the Miocene compared to other lithologies, despite the high solubility of thegypsum formations releasing large quantities of dissolved elements in solution.Understanding water paths at small scale is even more efficient when the geochemical approach is coupled with adetailed geological description. Indeed, the geochemical tracers are extremely dependent on the facies sequences(morphology) and of the soil nature (mineralogical composition), this is particularly sensitive at small scale.In the context of climate change increasing the intensity of rain events in the Mediterranean region, and resultingin catastrophic floods events (flash floods), tracing the origin of water contributing to the runoff is of primaryimportance and this must be investigated at small scale. Geochemical and isotopic fingerprinting thus constituteexcellent tools which can help to define the area of interest to be monitored in the framework of flood forecast andwarning networks
EGU General Assembly 2015
Vienne, Austria

hal-01118622
https://hal-brgm.archives-ouvertes.fr/hal-01118622

Éditeur(s) : Amer Geophysical Union
Résumé : Since Last Glacial Maximum (23-19 ka), Earth climate warming and deglaciation occurred in two major steps (Bolling-Allerod and Preboreal), interrupted by a short cooling interval referred to as the Younger Dryas (12.5-11.5 ka B. P.). In this study, three cores (MV-33, MV-66, and MD-40) collected in the central part of Pandora Trough (Gulf of Papua) have been analyzed, and they reveal a detailed sedimentary pattern at millennial timescale. Siliciclastic turbidites disappeared during the Bolling-Allerod and Preboreal intervals to systematically reoccur during the Younger Dryas interval. Subsequent to the final disappearance of the siliciclastic turbidites a calciturbidite occurred during meltwater pulse 1B. The Holocene interval was characterized by a lack of siliciclastic turbidites, relatively high carbonate content, and fine bank-derived aragonitic sediment. The observed millennial timescale sedimentary variability can be explained by sea level fluctuations. During the Last Glacial Maximum, siliciclastic turbidites were numerous when the lowstand coastal system was located along the modern shelf edge. Although they did not occur during the intervals of maximum flooding of the shelf (during meltwater pulses 1A and 1B), siliciclastic turbidites reappear briefly during the Younger Dryas, an interval when sea level rise slowed, stopped, or perhaps even fell. The timing of the calciturbidite coincides with the first reflooding of Eastern Fields Reef, an atoll that remained exposed for most of the glacial stages.
Journal Of Geophysical Research-earth Surface (0148-0227) (Amer Geophysical Union), 2008-03-29 , Vol. 113 , N. F01S19 , P. 1-15

Droits : Copyright 2008 by the American Geophysical Union.
http://archimer.ifremer.fr/doc/00079/19014/16592.pdf
DOI:10.1029/2006JF000649
http://archimer.ifremer.fr/doc/00079/19014/

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Brecciated and fractured peridotites with a carbonate matrix, referred to as ophicalcites, are common features of mantle rocks exhumed in passive margins and mid-oceanic ridges. Ophicalcites have been found in close association with massive peridotites, which form the numerous ultramafic bodies scattered along the North Pyrenean Zone (NPZ), on the northern flank of the Pyrenean belt. We present the first field, textural and stable isotopic characterization of these rocks. Our observations show that Pyrenean ophicalcites belong to three main types: (1) a wide variety of breccias composed of sorted or unsorted millimeter- to meter-sized clasts of fresh or oxidized ultramafic material, in a fine-grained calcitic matrix; (2) calcitic veins penetrating into fractured serpentine and fresh peridotite; and (3) pervasive substitution of serpentine minerals by calcite. Stable isotopic analyses (O, C) have been conducted on the carbonate matrix, veins and clasts of samples from 12 Pyrenean ultramafic bodies. We show that the Pyrenean ophicalcites are the product of three distinct genetic processes: (1) pervasive ophicalcite resulting from relatively deep and hot hydrothermal activity; (2) ophicalcites in veins resulting from tectonic fracturing and cooler hydrothermal activity; and (3) polymictic breccias resulting from sedimentary processes occurring after the exposure of subcontinental mantle as portions of the floor of basins which opened during the mid-Cretaceous. We highlight a major difference between the eastern and western Pyrenean ophicalcites belonging, respectively, to the sedimentary and to the hydrothermal types. Our data set points to a possible origin of the sedimentary ophicalcites in continental endorheic basins, but a post-depositional evolution by circulation of metamorphic fluids or an origin from relatively warm marine waters cannot be ruled out. Finally, we discuss the significance of such discrepancy in the characteristics of the NPZ ophicalcites in the frame of the variable exhumation history of the peridotites all along the Pyrenean realm.
ISSN: 1437-3254

insu-00944405
https://hal-insu.archives-ouvertes.fr/insu-00944405
https://hal-insu.archives-ouvertes.fr/insu-00944405/document
https://hal-insu.archives-ouvertes.fr/insu-00944405/file/clerc-etal-IJES-Review.pdf
DOI : 10.1007/s00531-013-0927-z

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
Abstract View references (60)Here we show the long term performance at high temperatures of a multi-tube module containing 8 membranes in 4 parallel lines with a total of 545 cm 2 area. The membranes were prepared via thin film dip coating of cobalt oxide silica (CoO xSi) sol-gel on tubular alumina supports. A preliminary study found that the sol-gel containing 20 mol% cobalt oxide formed the best microporous structure with the highest surface area and pore volume. All resulting membranes delivered permeances of ∼1 × 10 -7 mol m -2 s -1 Pa -1 at 500 °C, indicating a high repeatability for the membrane fabrication process. The permselectivities of helium (He) and hydrogen (H 2) over carbon dioxide (CO 2) and nitrogen (N 2) increased from 10-20 at 100 °C to values close to 1000 at 500 °C. Additionally, the apparent energies of activation (E act) for the smaller kinetic diameter gases He and H 2 at 12.2 and 19.5 kJ mol -1 were high and contrary to the negative values for larger gases N 2 and CO 2 at -1.8 and -7.4 kJ mol -1. These remarkable results were attributed to the molecular sieving mechanism of the microporous silica which was enhanced by the embedding of cobalt oxide into the matrix, delivering structural control with an average pore size of 3 Å. The E act for H 2 permeance was higher than that of He, indicating that the cobalt oxide played an important role in H 2 transport. Two membrane lines performed exceptionally well for binary gas mixture processing with H 2 purity reaching values close to 100% in the permeate stream for argon (Ar) concentrations of up to 80% in the retentate stream. A major finding here is that the binary gas selectivity was independent of temperature, contrary to the permselectivity observed for single gas permeance. Further, the H 2 flow rate was greatly affected by the concentration of Ar in the mixture, while the temperature dependency played only a marginal role. In particular, competitive adsorption in the percolative pathways containing pore constrictions or bottlenecks of the anisotropic CoO xSi matrix allowed Ar to impede H 2 diffusion. Finally, the CoO xSi membranes proved thermally stable and robust for 2000 h of testing for various thermal cycles up to 500 °C. © The Royal Society of Chemistry 2012.
Energy & Environmental Science

hal-01683199
https://hal.univ-antilles.fr/hal-01683199
DOI : 10.1039/c2ee03247c

Éditeur(s) : Springer
Résumé : Large benthic foraminifers are considered to be good indicators of shallow marine carbonate environments in fossil series. Over the last 50 years, the palaeoenvironment of Tertiary Nummulites accumulations has been a matter of debate, particularly because of difficulties in interpreting these deposits, and in this way, the absence of analogues in present-day seas does not help. The aim of this paper is to insight the different ways Nummulites tests and clasts may accumulate according to their hydrodynamic behaviour. Based on experimental measurements and on SEM observations, it appears that the high primary skeletal porosity of Nummulites made them easily transportable. The calculated threshold shear velocities confirm that large-sized Nummulites can be moved by weak wave-driven currents. This peculiar hydrodynamic behaviour of Nummulites could explain the diversity of depositional models. Depending on local hydrodynamic conditions, autochthonous Nummulites deposits can be preserved as in situ winnowed bioaccumulations or be accumulated offshore, onshore or alongshore, away from the original biotope.
Facies (0172-9179) (Springer), 2006-05 , Vol. 52 , N. 2 , P. 221-235

Droits : Springer-Verlag 2005
http://archimer.ifremer.fr/doc/00085/19597/17234.pdf
DOI:10.1007/s10347-005-0035-z
http://archimer.ifremer.fr/doc/00085/19597/

Éditeur(s) : HAL CCSD
Résumé : Annual report
We present here the results of CRS reprocessing of a 3D real dataset acquired in 2001 on the Tournemire site in France, which is an experimental site for the Institut de Radioprotection et de Sûreté Nucléaire (IRSN) to test geophysical imaging process in the context of geological nuclear waste storage. The main objective was to evaluate the ability of the methodology to recognize, in the carbonate cover of the experimental site clay layer, the prolongation of weak vertical-displacement faults seen in a tunnel within that clay layer. Previous seismic processing using the conventional common midpoint (CMP) approach did not provide satisfactory results in this cover, although the fault has beenrecognized in the carbonates underlying the clay layer. An original strategy was elaborated to define the best-possible parameters of the 3D Common-Reflection-Surface (CRS) stack. The procedure in- cluded refining the velocity search along a velocity guide, using a first CRS stack as the base of a subsequent curvature-parameter search, or a parameter smoothing before stacking. An optimal ap- proach was elaborated on a subset of the data, and furthermore applied to the whole dataset. The resulting image shows improved event continuity in the carbonate cover, which allowed for horizon picking after depth migration, as well as the estimation of post-stack geometrical attributes, such as coherency. The processing indicates a zone of degraded quality of reflection events lying in the N-S direction, above the known fault zone within the underlying formations. Such feature corresponds to an alteration zone at the earth surface. Further investigation at a higher resolution scale is planned to confirm whether this zone could be a spot of possible leakage
https://hal.archives-ouvertes.fr/hal-00857376

hal-00857376
https://hal.archives-ouvertes.fr/hal-00857376

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This work shows the preparation and separation performance assessment of carbon membranes derived from phenolic resin by a vacuum-assisted method and carbonisation in an inert atmosphere. The vacuum time played an important role in tailoring the structure of the membranes. For instance, pore volumes and surface areas increased from 0.81 and 834 to 2.2 cm3g−1and 1910 m2g−1, respectively, as the vacuum time exposure increased from 0 to 1200 s. The significant structural changes correlated very well with water permeation, as fluxes increased by 91% as the vacuum time increased from 0 to 1200 s reaching up to 169 L m−2h−1at 5 bar. Molecular weight cut-off tests showed no rejection for the smaller glucose and sucrose molecules, though this increased to ~ 80% and full rejection for 36 kDa and 400 kDa polyvinyl pyrrolidine. Interestingly, FTIR spectra showed that the peaks of C–H stretching vibration (2800–3200 cm−1) and C–O stretching (1030 cm−1) became more pronounced as a function of increasing vacuum time, strongly suggesting that the use of vacuum further assisted in the polycondensation of phenolic oligomers. Based on these outcomes, a cluster to cluster model is proposed, whereby vacuum application promoted crosslinking reactions of the phenolic resin, creating microporous regions within the clusters, and mesoporous regions between the clusters. © 2016 Elsevier B.V
ISSN: 0376-7388

hal-01683220
https://hal.univ-antilles.fr/hal-01683220
DOI : 10.1016/j.memsci.2016.11.002

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Factors controlling ocean acidification and its temporal variations were studied over the 1995–2011 period at the Dyfamed site at 10 m depth, in the North Mediterranean Sea. The results indicated a mean annual decrease of 0.003 ± 0.001 pH units on the seawater scale. The seasonal variability was characterized by a pH decrease during springtime and a strong pH increase in late fall. Anthropogenic CO2 (CANT) absorption by the ocean was the key driver of seawater acidification in this region, accounting for about 70% of the observed drop in pH, followed by water temperature (about 30%). The total inorganic carbon (CT) data showed a CT increase of 30.0 ± 1.0 μmol kg−1 per decade. This decadal increase is mainly due to the CANT penetration (43.2 μmol kg−1 per decade) in surface waters, which is mitigated for by relatively small opposing changes in CT due to physical and biological processes.
ISSN: 0141-1136

hal-01286093
https://hal-univ-perp.archives-ouvertes.fr/hal-01286093
DOI : 10.1016/j.marenvres.2016.02.016