Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Here we show that copper substitution in perovskite-type barium strontium cobalt copper oxide (BSCC) membranes confers extremely high oxygen fluxes well beyond the state of art, reaching 27.5 ml cm−2 min−1at 950 °C. A key feature of BSCC is the formation of a mixed matrix catalyst-perovskite membrane caused by the segregation of copper, leading to the formation of an intergranular network of copper-rich oxide between perovskite grains. BSCC membranes delivered pressure normalised oxygen flux (i.e. permeance) of up to 86 times higher, above pressure difference of 18 kPa, as compared to best perovskite membrane, BBSC, due to the catalytic effect of segregated copper oxide. Unlike conventional dual-phase membranes which contain ion and electron conducting phases, this work shows for the first time perovskite-type membranes consisting of a mixed matrix of oxygen ion/electron conducting (perovskite) and catalytic (copper oxide) phases, thus paving the way to the development of high performance membranes for oxygen separation from air for clean energy applications. © 2016 Elsevier B.V.
ISSN: 0376-7388

hal-01683219
https://hal.univ-antilles.fr/hal-01683219
DOI : 10.1016/j.memsci.2016.12.035

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
The easy-to-use in vivo model, zebrafish larva, is being increasingly used to screen chemical-induced hepatotoxicity, with a good predictivity for various mechanisms of liver injury. However, nothing is known about its applicability in exploring the mechanism called membrane remodeling, depicted as changes in membrane fluidity or lipid raft properties. The aim of this study was, therefore, to substantiate the zebrafish larva as a suitable in vivo model in this context. Ethanol was chosen as a prototype toxicant because it is largely described, both in hepatocyte cultures and in rodents, as capable of inducing a membrane remodeling leading to hepatocyte death and liver injury. The zebrafish larva model was demonstrated to be fully relevant as membrane remodeling was maintained even after a 1-week exposure without any adaptation as usually reported in rodents and hepatocyte cultures. It was also proven to exhibit a high sensitivity as it discriminated various levels of cytotoxicity depending on the extent of changes in membrane remodeling. In this context, its sensitivity appeared higher than that of WIF-B9 hepatic cells, which is suited for analyzing this kind of hepatotoxicity. Finally, the protection afforded by a membrane stabilizer, ursodeoxycholic acid (UDCA), or by a lipid raft disrupter, pravastatin, definitely validated zebrafish larva as a reliable model to quickly assess membrane remodeling involvement in chemical-induced hepatotoxicity. In conclusion, this model, compatible with a high throughput screening, might be adapted to seek hepatotoxicants via membrane remodeling, and also drugs targeting membrane features to propose new preventive or therapeutic strategies in chemical-induced liver diseases.
ISSN: 0260-437X

hal-01526425
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01526425
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01526425/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01526425/file/Zebrafish%20larva%20as%20a%20reliable%20model-Podechard%20JAT%202016%20revised.pdf
DOI : 10.1002/jat.3421

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Increasingly, health risk assessment is addressing multiple pathway exposures to multiple contaminants. We reviewed aggregated exposure and cumulative risk approaches for contemporary and ubiquitous semivolatile organic compounds (SVOC). We identified 22 studies aggregating exposure pathways, and 31 cumulating risk. Exposure aggregation is based on the addition of pathway-specific doses, using kinetic modeling where it exists, and classic external dose equations otherwise. In most cases, exposure is dominated by a single route or source of exposure - mainly the oral pathway - via dietary or non-dietary exposure. Preferential routes and sources of exposure are influenced by SVOC physical-chemical properties such as vapor pressure. The cumulative risk approach for contaminants is based on dose addition. Simple sum of hazard quotient (Hazard Index: HI) is the most commonly used cumulative risk assessment approach, while Relative Potency Factor (RPF) appeared to the best suited – although this calls for a level of toxicological information that limits the number of compounds that can be studied simultaneously. Where both were performed, moving from HI to more refined approach produced similar results. In conclusion, both approaches - exposure aggregation and cumulative risk - rely on simple assumptions. Nevertheless, they allow uncertainty to be reduced, in comparison with source-by-source or chemical-by-chemical approaches.
ISSN: 0013-9351

hal-01635759
https://hal.archives-ouvertes.fr/hal-01635759
https://hal.archives-ouvertes.fr/hal-01635759/document
https://hal.archives-ouvertes.fr/hal-01635759/file/Pelletier%202017%20Review%20%20rev2.pdf
DOI : 10.1016/j.envres.2017.06.022

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
Benthic microbial fuel cells (BMFCs) are continuous electricity generators using electroactive microorganisms and organic matter from aquatic environment, respectively, as catalysts and substrate. In this paper, first a low-cost PVC-made structure is constructed to harvest electricity from mangrove environment located in French Guiana. An in situ BMFC has given power density of 30 mW/m2 of the anodic surface area. This performance has been confirmed by experience in laboratory where inter-electrode distance and electrode surface area appeared to be power increasing factors. However, the output power of one BMFC is not used to supply real devices such as autonomous sensors. Second, to meet this expectation, in parallel and in series associations were considered. These associations were made in order to increase the output voltage and consequently the power, to reach levels that can supply small sensors (about 3 V). Finally, to improve the performance of the series association and to avoid the voltage reversal phenomenon, a voltage balancing circuit was simulated and added to the series connections. With balancing method, the cell voltage of BMFCs can be equalized, and the performances can be improved. This allows an optimal energy harvesting and a better global efficiency of the set.
ISSN: 0363-907X

hal-01683128
https://hal.univ-antilles.fr/hal-01683128
DOI : 10.1002/er.3270

Éditeur(s) : HAL CCSD
Résumé : The geological storage of CO 2 is considered as one of the solutions to the problem of global warming. The most possible scenarios of geological behavior of soil in the long term conditions has to be precisely defined to avoid catastrophic damages in the future. Chemical properties of saline water in the aquifer after the CO 2 injection becomes more acidic with time. Therefore, chemical degradation of rock occurs, which leads to modifications of its mechanical properties (chemo-mechanical coupling) [1]. In this paper an incremental model of chemo-mechanical coupling using homogenization approach (asymptotic expansion method [2,3]) is proposed. The paper is focused on the numerical computations for the X-ray tomography image of carbonate rock microstructure [4]. The chemical degradation of the microstructure is obtained as a homogeneous dissolution in each direction (Fig.1. – Fig.2.) For every porosity state numerical computations to obtain full, orthotropic elasticity tensor are performed. Therefore, the degradations functions for all components of the rigidity tensor were defined (Fig.3.). Moreover, results of numerical calculations of diffusion, tortuosity and permeability tensors are presented [5,6]. The link between geometrical properties and mechanical and transport parameters are discussed. The numerical analysis of the carbonate rock sample in long term conditions shows the increase of porosity and associated mechanical weakening of the rock. Moreover, the increase of diffusion, tortuosity and permeability tensors elements with time were observed. Finally, the solution of the one-dimensional macroscopic problem of soil settlement due to chemical dissolution of rock at constant load is presented. The method is universal, in the sense that the non-dimensional time scale is used.
ALERT Workshop 2013
Aussois, France

hal-01103175
https://hal.archives-ouvertes.fr/hal-01103175

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
Abstract View references (60)Here we show the long term performance at high temperatures of a multi-tube module containing 8 membranes in 4 parallel lines with a total of 545 cm 2 area. The membranes were prepared via thin film dip coating of cobalt oxide silica (CoO xSi) sol-gel on tubular alumina supports. A preliminary study found that the sol-gel containing 20 mol% cobalt oxide formed the best microporous structure with the highest surface area and pore volume. All resulting membranes delivered permeances of ∼1 × 10 -7 mol m -2 s -1 Pa -1 at 500 °C, indicating a high repeatability for the membrane fabrication process. The permselectivities of helium (He) and hydrogen (H 2) over carbon dioxide (CO 2) and nitrogen (N 2) increased from 10-20 at 100 °C to values close to 1000 at 500 °C. Additionally, the apparent energies of activation (E act) for the smaller kinetic diameter gases He and H 2 at 12.2 and 19.5 kJ mol -1 were high and contrary to the negative values for larger gases N 2 and CO 2 at -1.8 and -7.4 kJ mol -1. These remarkable results were attributed to the molecular sieving mechanism of the microporous silica which was enhanced by the embedding of cobalt oxide into the matrix, delivering structural control with an average pore size of 3 Å. The E act for H 2 permeance was higher than that of He, indicating that the cobalt oxide played an important role in H 2 transport. Two membrane lines performed exceptionally well for binary gas mixture processing with H 2 purity reaching values close to 100% in the permeate stream for argon (Ar) concentrations of up to 80% in the retentate stream. A major finding here is that the binary gas selectivity was independent of temperature, contrary to the permselectivity observed for single gas permeance. Further, the H 2 flow rate was greatly affected by the concentration of Ar in the mixture, while the temperature dependency played only a marginal role. In particular, competitive adsorption in the percolative pathways containing pore constrictions or bottlenecks of the anisotropic CoO xSi matrix allowed Ar to impede H 2 diffusion. Finally, the CoO xSi membranes proved thermally stable and robust for 2000 h of testing for various thermal cycles up to 500 °C. © The Royal Society of Chemistry 2012.
Energy & Environmental Science

hal-01683199
https://hal.univ-antilles.fr/hal-01683199
DOI : 10.1039/c2ee03247c

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Various bagasse fibre/cement composites have been prepared, the fibres having a random distribution in the composites. The influence of different parameters on the setting of the composite material has been studied: (1) botanical components of the fibre, (2) thermal or chemical treatment of the fibre, (3) bagasse fibre content and (4) added water percentage. This study shows a retarding effect of lignin on the setting of the composite, for small amount of heat-treated bagasse (200 °C) the behaviour of the composite is closely the same as the classical cement or cellulose/cement composite.
ISSN: 0958-9465

hal-00809715
https://hal.univ-antilles.fr/hal-00809715
DOI : 10.1016/S0958-9465(02)00003-3

Éditeur(s) : EDP Sciences
Résumé : The WFD monitoring requirements for surface waters were adapted to the coastal area with the selection of the relevant parameters to qualify the maritime ecosystems, with appropriate strategies of sampling. Ifremer and Cemagref for the fish indicator in the estuarine waters, are in charge of the elaboration of the monitoring programme in coastal waters (surveillance monitoring and operational monitoring). Ifremer has elaborated technical recommendations for the monitoring of the biological (benthic and phytoplanctonic) and chemical elements, according to many years of observations by the french monitoring networks (RNO, Rephy, Rinbio, RSL, Rebent). These recommendations were established within experts groups They clarify the parameters, the analytical methods, and the strategies of sampling for the classification of the water bodies in five ecological classes and two chemical classes. The work on the relevant indicators of the ecological status still goes on, in relation with the 2006 european intercalibration exercise. Available data and future data will be used in order to set the borders between the classes of high, good, and moderate status, before the monitoring programme starts. Data sets have to be completed to set the borders and to assess the ecological status of water bodies.
Houille Blanche - Revue internationale de l'eau (0018-6368) (EDP Sciences), 2006-07 , N. 4 , P. 68-74

Droits : © Société Hydrotechnique de France 2006
http://archimer.ifremer.fr/doc/2006/publication-3530.pdf
DOI:10.1051/lhb:200604011
http://archimer.ifremer.fr/doc/00000/3530/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Well-dispersed iron oxide nanoparticles supported onto graphene oxide sheets (i.e. GO-Fe3O4 nanocomposite) were synthesised and used as heterogeneous Fenton-like catalyst for the degradation of Acid Orange 7 dye (AO7). The reaction was systematically investigated under various experimental conditions such as nanocomposite dosage, pH, temperature, oxidant and dye concentrations. Best results showed a fast 80% degradation in ∼20 min, whilst ∼98% of AO7 was successfully removed after 180 min of reaction time. The degradation kinetics of AO7 was most influenced by pH and temperature, and can be described by a pseudo-first-order reaction following the Langmuir-Hinshelwood mechanism. Analysis of the spent nanocomposite suggested that the phase of iron oxide nanoparticles remained unchanged whilst minor pore volume losses occurred via carbon deposition and/or re-stacking of GO sheets. © 2014 Elsevier Ltd.
ISSN: 2213-3437

hal-01683206
https://hal.univ-antilles.fr/hal-01683206
DOI : 10.1016/j.jece.2014.08.001

Éditeur(s) : HAL CCSD American Chemical Society
Résumé : Ants have evolved venoms rich in peptides and proteins used for predation, defense, and communication. However, they remain extremely understudied due to the minimal amount of venom secreted by each ant. The present study investigated the differences in the proteome and peptidome of the venom from the bullet ant, Paraponera clavata. Venom samples were collected from a single colony either by manual venom gland dissection or by electrical stimulation and were compared using proteomic methods. Venom proteins were separated by 2D-PAGE and identified by nanoLC-ESI-QTOF MS/MS. Venom peptides were initially separated using C18 reversed-phase high-performance liquid chromatography, then analyzed by MALDI-TOF MS. The proteomic analysis revealed numerous proteins that could be assigned a biological function (total 94), mainly as toxins, or roles in cell regulation and transport. This investigation found that ca. 73% of the proteins were common to venoms collected by the two methods. The peptidomic analysis revealed a large number of peptides (total 309) but with <20% shared by the two collection methods. There was also a marked difference between venoms obtained by venom gland dissection from different ant colonies. These findings demonstrate the rich composition and variability of P. clavata venom.
ISSN: 1535-3893

hal-01603415
https://hal.archives-ouvertes.fr/hal-01603415
DOI : 10.1021/acs.jproteome.6b00948
PRODINRA : 406775
PUBMED : 28118015

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
Chemical mediation regulates behavioral interactions between species and thus affects population structure,community organization and ecosystem function. Among marine taxa that have developed chemicalmediation strategies, gastropods belong to a diverse group of molluscs found worldwide, including specieswith a coiled, reduced or absent shell. Most gastropods use natural products to mediate a wide range ofbehaviors such as defense, prey location or interactions with con- and hetero-geners. Their chemicallydefended diet, such as cyanobacteria, algae, sponges, bryozoans and tunicates, provides them witha considerable opportunity either as shelter from predators, or as a means to enhance their own chemicaldefense. In addition to improving their defenses, molluscs also use prey secondary metabolites in complexchemical communication including settlement induction, prey detection and feeding preferences. Theassimilation of prey secondary metabolites further provides the opportunity for interactions withconspecifics via diet-derived chemical cues or signals. This review intends to provide an overview on thesequestration, detoxification, and biotransformation of diet-derived natural products, as well as the role ofthese compounds as chemical mediators in gastropod-prey interactions.
ISSN: 0265-0568

hal-01563402
https://hal-univ-perp.archives-ouvertes.fr/hal-01563402
DOI : 10.1039/c6np00097e

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Humans are exposed to a large number of contaminants, many of which may have similar health effects. This paper presents a framework for identifying pollutants to be included in a cumulative risk assessment approach. To account for the possibility of simultaneous exposure to chemicals with common toxic modes of action, the first step of the traditional risk assessment process, i.e. hazard identification, is structured in three sub-steps: (1a) Identification of pollutants people are exposed to, (1b) identification of effects and mechanisms of action of these pollutants, (1c) grouping of pollutants according to similarity of their mechanism of action and health effects. Based on this exposure-based grouping we can derive "multi-pollutant" toxicity reference values, in the "dose-response assessment" step. The approach proposed in this work is original in that it is based on real exposures instead of a limited number of pollutants from a unique chemical family, as traditionally performed. This framework is illustrated by the case study of semi-volatile organic compounds in French dwellings, providing insights into practical considerations regarding the accuracy of the available toxicological information. This case study illustrates the value of the exposure-based approach as opposed to the traditional cumulative framework, in which chemicals with similar health effects were not always included in the same chemical class.
ISSN: 0013-9351

hal-00982315
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00982315
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00982315/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00982315/file/An_exposure-based_framework_for_grouping_pollutants_accepted.pdf
DOI : 10.1016/j.envres.2014.01.007

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Talc is a hydrous magnesium rich layered silicate that is widely disseminated in the Earth from the seafloor to over 100 km depth, in ultra-high pressure metamorphism of oceanic crust. In this paper we determine the single crystal elastic constants at pressures from 0 to 12 GPa of talc triclinic (C 1¯) and monoclinic (C2/c) polytypes using ab initio methods. We find that talc has an extraordinarily high elastic anisotropy at zero pressure that reduces with increasing pressure. The exceptional anisotropy is complemented by a negative Poisson's ratio for many directions in crystal space. Calculations show that talc is not only one of very few common minerals to exhibit auxetic behaviour, but the magnitude of this effect may be the largest reported so far for a mineral. The compression (Vp) and shear (Vs) wave velocity anisotropy is 80% and 85% for the triclinic polytype. At pressures where talc is known be stable in the Earth (up to 5 GPa) the Vp and Vs anisotropy is reduced to about 40% for both velocities, which is still a very high value. Vp is slow parallel to the c-axis and fast perpendicular to it. This remains unchanged with increasing pressure and is observed in both polytypes. The shear wave splitting (difference between fast and slow S-wave velocities) at low pressure has high values in the plane normal to the c-axis, with a maximum near the alow asterisk-axis in the triclinic and the b-axis in the monoclinic polytype. The c-axis is the direction of minimum splitting. The pattern of shear wave splitting does not change significantly with pressure. The volume fraction of talc varies between 11 and 41% for hydrated mantle rocks, but the lack of data on the crystallographic preferred orientation (CPO) precludes a detailed analysis of the impact of talc on seismic anisotropy in subduction zones. However, it is highly likely that CPO can easily develop in zones of deformation due to the platy habit of talc crystals. For random aggregates of talc, the isotropic Vp, Vs and Vp/Vs ratio have significantly lower values than those of antigorite and may explain low-velocity regions in the mantle wedge. Vp/Vs ratios are more complex in anisotropic media because there are fast and slow S-waves, resulting in Vp/Vs1 and Vp/Vs2 ratios for every propagation direction, making interpretation difficult in deformed polycrystalline talc with a CPO. Talc on the subduction plate boundary can strongly influence guided wave velocity as CPO would develop in this region of intense shearing. The very low coefficient of friction (< 0.1) of talc above 100 °C could also explain silent earthquakes at shallow depths (ca 30 km) along the subduction plate boundaries, frequently responsible for tsunami.
ISSN: 0012-821X

hal-00411481
https://hal.archives-ouvertes.fr/hal-00411481
DOI : 10.1016/j.epsl.2008.07.047

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Abstract View references (38)Silicalite-1 (S-1) and ZSM-5 membranes prepared by secondary growth on tubular ceramic supports were tested using a pervaporation set up for the desalination of aqueous solutions containing NaCl in concentrations corresponding to brackish (0.3-1wt%), sea (3.5wt%) and brine (7.5-15wt%) water. ZSM-5 membranes delivered higher water fluxes when compared with S-1 membranes due to enhanced hydrophilicity of the Al-rich zeolite structure leading to fluxes as high as 11.5kgm -2h -1 for 0.3wt% NaCl feed solutions at 75°C. At higher salt concentration the water flux decreased alongside with the salt rejection rate, however the hydrophilic ZMS-5 membrane became more susceptible to performance loss, particularly at high temperatures. Detailed stability experiments carried out for up to 560h showed the dissolution of both S-1 and ZSM-5 top layers. This was attributed to the combined effects of ion exchange and water dissolution mechanisms. Interesting though, the MFI structure zeolite was still observed on the XRD patterns whilst EDX depth profile showed the presence of silica up to 30μm depth into the support. These results suggest the formation/infiltration of a compact amorphous phase in the substrate, derived from the aggregation of the dissolved silicate species and possibly together with the arrangement of MFI nano-slabs during the desalination tests. Despite generating lower water fluxes, the S-1 membrane exhibited relatively high robustness under the long term testing conditions which included temperature cycling, delivering salt rejections from initial >99% to <80% at the end of the testing period (560h). © 2012 Elsevier B.V.
ISSN: 0376-7388

hal-01683201
https://hal.univ-antilles.fr/hal-01683201
DOI : 10.1016/j.memsci.2012.05.074

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
A full equilibrium treatment of molecular aggregation is presented for prototypes of 1D and 3D aggregates, with and without nucleation. By skipping complex kinetic parameters like aggregate size-dependent diffusion, the equilibrium treatment allows to predict directly time-independent quantities such as critical concentrations. The relationships between the macroscopic equilibrium constants for the different paths are first established by statistical corrections and so as to comply with the detailed balance constraints imposed by nucleation, and the composition of the mixture resulting from homogeneous aggregation is then analyzed using the polylogarithm function. Several critical concentrations are distinguished: the residual monomer concentation in equilibrium (RMC) and the critical nucleation concentration (CNC), that is the threshold concentration of total subunits necessary for initiating aggregation. When increasing the concentration of total subunits, the RMC converges more strongly to its asymptotic value, the equilibrium constant of depolymerization, for 3D aggregates and in case of nucleation. The CNC moderately depends on the number of subunits in the nucleus, but sharply increases with the difference between the equilibrium constants of polymerization and nucleation. As the RMC and CNC can be numerically but not analytically determined, ansatz equations connecting them to thermodynamic parameters are proposed
PCCP : Physical chemistry chemical physics

Droits : info:eu-repo/semantics/OpenAccess
hal-01565995
https://hal.archives-ouvertes.fr/hal-01565995
https://hal.archives-ouvertes.fr/hal-01565995/document
https://hal.archives-ouvertes.fr/hal-01565995/file/Aggregates_in_equilibrium.pdf
DOI : 10.1039/c6cp08369b

Éditeur(s) : Adac-cryptogamie
Résumé : Very few attempts have been made in order to investigate the role of nutrients on cellular growth and toxin production in dinoflagellates associated with DSP (Diarrhetic Shellfish Poison). Some preliminary results are presented here, aiming at a better knowledge of inorganic nitrogen and organic phosphorus effects upon division rate and toxin content of Prorocentrum lima (PL2V spanish strain). Nitrogen have a positive effect on growth rate, up to a threshold value of 880muM.l-1. Above this threshold the rate decreases. There is no effect on toxin content since okadaic acid and DTX1 cell contents remain low (4.8 +/- 0.5 pg.cell.-1) and steady. Phosphorus effect upon division rate follows a non-linear relationship, whereas cellular toxic content is inversely proportional to growth rate.
Peu d'études ont été réalisées sur l'influence des nutriments sur la croissance et la toxicité de dinoflagellés producteurs de poisons diarrhéiques (Diarrhetic Shellfish Poison = DSP). Des résultats préliminaires sont présentés ici en ce qui concerne l'effef de concentrations croissantes d'azote inorganique et de phosphore organique sur le taux de division et la production toxinique de Prorocentrum lima (souche espagnole PL2V). L'azote a une influence positive sur la croissance de cette microalgue jusqu'à une valeur seuil de 880 μM.l#-1. Au-delà de ce seuil, le taux de division diminue. Par contre, l'effet sur la toxicité n'est pas significatif, les concentrations en acide okadaïque et DTXI restant relativement faibles (4.8 ± 0.5 pg.cell.· l ) et stables. Le phosphore agit intégralement sur le taux de division et il y a une relation inverse entre ce dernier et le contenu toxinique cellulaire.
Cryptogamie Algologie (0181-1568) (Adac-cryptogamie), 1992-08 , Vol. 13 , N. 3 , P. 187-195

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00133/24469/22483.pdf
http://archimer.ifremer.fr/doc/00133/24469/

Éditeur(s) : HAL CCSD Wiley
Résumé : We report new measurements of the surface ionization Phi(0) for Ge K alpha and L alpha X-rays on an Fe substrate, Ga K alpha and L alpha X-rays on an Ni substrate, and Au M alpha X-rays on Si, W and Ta substrates. The measurements were performed using the tracer technique for electron incident energies ranging from the ionization threshold up to about 40 keV. Improvements in sample preparation and in the X-ray measurement technique enabled surface ionization values to be obtained with uncertainties less than 2%. Simulations of Phi(0) for the studied cases were performed using the general-purpose Monte Carlo (MC) code PENELOPE. Experimental measurements are compared with simulation results and with the results of several predictive formulae widely used in electron probe microanalysis and Auger electron spectroscopy (AES). The accuracy of the reported measurements makes it possible to assess the reliability of the different calculations for incident electron energies below 10 keV.
ISSN: 0049-8246

hal-00617775
https://hal.archives-ouvertes.fr/hal-00617775
DOI : 10.1002/xrs.1294

Éditeur(s) : HAL CCSD Ecological Society of America
Résumé : Reliable assessment of fish origin is of critical importance for exploited species, since nursery areas must be identified and protected to maintain recruitment to the adult stock. During the last two decades, otolith chemical signatures (or "fingerprints") have been increasingly used as tools to discriminate between coastal habitats. However, correct assessment of fish origin from otolith fingerprints depends on various environmental and methodological parameters, including the choice of the statistical method used to assign fish to unknown origin. Among the available methods of classification, Linear Discriminant Analysis (LDA) is the most frequently used, although it assumes data are multivariate normal with homogeneous within-group dispersions, conditions that are not always met by otolith chemical data, even after transformation. Other less constrained classification methods are available, but there is a current lack of comparative analysis in applications to otolith microchemistry. Here, we assessed stock identification accuracy for four classification methods (LDA, Quadratic Discriminant Analysis [QDA], Random Forests [RF], and Artificial Neural Networks [ANN]), through the use of three distinct data sets. In each case, all possible combinations of chemical elements were examined to identify the elements to be used for optimal accuracy in fish assignment to their actual origin. Our study shows that accuracy differs according to the model and the number of elements considered. Best combinations did not include all the elements measured, and it was not possible to define an ad hoc multielement combination for accurate site discrimination. Among all the models tested, RF and ANN performed best, especially for complex data sets (e. g., with numerous fish species and/or chemical elements involved). However, for these data, RF was less time-consuming and more interpretable than ANN, and far more efficient and less demanding in terms of assumptions than LDA or QDA. Therefore, when LDA and QDA assumptions cannot be reached, the use of machine learning methods, such as RF, should be preferred for stock assessment and nursery identification based on otolith microchemistry, especially when data set include multispecific otolith signatures and/or many chemical elements.
ISSN: 1051-0761

hal-00644549
https://hal.archives-ouvertes.fr/hal-00644549
DOI : 10.1890/09-1887.1

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
BACKGROUND: The insecticide chlordecone was extensively used in the French West Indies to control banana root borer. Its persistence in soils has led to the widespread pollution of the environment, and human beings are still exposed to this chemical. Chlordecone has been shown to impair neurological and behavioural functions in rodents when exposed gestationally or neonatally. OBJECTIVES: The aim of the study was to evaluate the impact of prenatal and postnatal exposure to chlordecone on the cognitive, visual, and motor development of 7-month-old infants from Guadeloupe. METHODS: Infants were tested at 7 months (n=153). Visual recognition memory and processing speed were assessed with the Fagan Tests of Infant Intelligence (FTII), visual acuity with the Teller Acuity Card, and fine motor development with the Brunet-Lezine. Samples of cord blood and breast milk at 3 months (n=88) were analyzed for chlordecone concentrations. Postnatal exposure was determined through breast feeding and frequency of contaminated food consumption by the infants. RESULTS: Cord chlordecone concentrations in tertiles were associated with reduced novelty preference on the FTII in the highly exposed group (β=-0.19, p=0.02). Postnatal exposure through contaminated food consumption was marginally related to reduced novelty preference (β=-0.14, p=0.07), and longer processing speed (β=0.16, p=0.07). Detectable levels of chlordecone in cord blood were associated with higher risk of obtaining low scores on the fine motor development scale (OR=1.25, p<0.01). CONCLUSION: These results suggest that pre- and postnatal low chronic exposure to chlordecone is associated with negative effects on cognitive and motor development during infancy.
ISSN: 0013-9351

hal-00875939
https://hal.archives-ouvertes.fr/hal-00875939
DOI : 10.1016/j.envres.2012.07.006
PUBMED : 22910562

Éditeur(s) : Elsevier
Résumé : Phosphorus forms with respect to sediment characteristics, such as grain-size, and major chemical elements, were studied in French coastal marine areas (the Bay of Seine and the Loire and Gironde Estuaries).In the three areas, Fe/Al-bound phosphate (Fe/Al-P) and exchangeable phosphate (exch-P) were significantly related to the proportion of fine fraction (< 63 mum). The special association of these forms with fine particles, as well as the relationships between exch-P, Fe/Al-P and Fe showed that adsorption processes on Fe oxides had taken place. However, for similar Fe concentrations, Bay of Seine sediments showed Fe/Al-P concentrations which were four to five times higher than those found in the Loire and Gironde Estuaries. This was attributed to differences in sediment nature and processes in these two types of areas. Indeed, the Loire and Gironde Estuaries frequently show hypoxia.Calcium-bound phosphate (Ca-P) was found in all grain size classes with comparable concentrations in the Bay of Seine where there was no correlation between Ca-P and Ca. This corresponded to the calcium's marine origin (shells) in the Bay of Seine. In contrast, the correlation of Ca-P with Ca and the fine fraction of the sediment in the Loire and Gironde Estuaries was characteristic of the predominant metamorphic origin of Ca-P in these areas.Useful information for interpretation of P-forms can be obtained from major sediment characteristics. Thus, for areas where specific relationships have previously been established good estimates of P-forms could be predicted from sediment properties.
Estuarine, Coastal and Shelf Science (0272-7714) (Elsevier), 2001-05 , Vol. 52 , N. 5 , P. 617-629

Droits : 2001 Academic Press. All rights reserved
http://archimer.ifremer.fr/doc/2001/publication-469.pdf
DOI:10.1006/ecss.2001.0766
http://archimer.ifremer.fr/doc/00000/469/