Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
The transition between the small melt lens observed on top of fast spreading ridge magma chambers and the overlying sheeted dike complex marks the interface between magma and the hydrothermal convective system. It is therefore critical to our understanding of fast spreading ridge accretion processes. We present maps of two areas of the Oman ophiolite where this transition zone is observed as continuous outcrops. Our observations, which include the base of the sheeted dike being crosscut by gabbros, are consistent with episodic dike injections in a steady state model but also suggest that the root of these dikes is commonly erased by vertical movements of the top of the melt lens. Dike assimilation is a possible mechanism for incorporating hydrated phases, which result from hydrothermal alteration, to the melt lens during upward migrations of its upper boundary. Upward migrations are also responsible for a granoblastic overprint of the root of the dikes that is also observed in the stoped diabase xenoliths. This granoblastic overprint attests to reheating of previously hydrothermally altered lithologies which can even trigger hydrous partial melting due to the lowering of the solidus of mafic lithologies by the presence of a water activity. Clinopyroxenes present in these granoblastic lithologies are typically low in Ti and Al content, thus strongly contrasting with corresponding magmatic clinopyroxene. This may attest to the recrystallization of clinopyroxenes after amphiboles under the peculiar conditions present at the root zone of the sheeted dike complex. Downward migrations of the top of the melt lens result in the crystallization of the isotropic gabbros at its roof, which represent the partly fossilized melt lens. Melt lens fossilization eventually occurs when magma supply is stopped or at the melt lens margins where the thermal conditions become cooler. Melt lens migration, recrystallization of hydrothermally altered sheeted dikes during reheating stages, and assimilation processes observed in the Oman ophiolite are consistent with the observations made in IODP Hole 1256D. We propose a general dynamic model in which the melt lens at fast spreading ridges undergoes upward and downward movements as a result of either eruption/replenishment stages or variations in the hydrothermal/magmatic fluxes.
ISSN: 1525-2027

hal-00445249
https://hal.archives-ouvertes.fr/hal-00445249
DOI : 10.1029/2009GC002652

Éditeur(s) : HAL CCSD
Résumé : International audience
In the external Western Alps, the collision started with the shortening of the proximal European (Dauphinois) margin. One peculiar feature is the crustal thickening that finally led to the exhumation of the basement External Crystalline Massifs (ECM) during the Neogene. In these massifs, various age of shortening, structural style and sequence of deformation have been proposed leading to different kinematics along the Alpine arc that in turn do not imply the same crustal/lithospheric strength. In this contribution, we present new structural and microstructural data along with Ar/Ar ages from field studies in the Oisans-Grandes Rousses massifs, between Grenoble and Briançon). From balanced cross-sections, we show that about half of the external zone crustal shortening is accommodated within the ECM with similar Ar/Ar ages in all massifs. Furthermore, the shear zones present very large thicknesses (several hundred meters) and do not reactivated either the inherited Liassic normal faults or the Variscan foliation. Finally, the main shortening structures are localized beneath inherited Liassic syn-rift basins. These results suggest that the crust was weak during its shortening. Such behavior is most likely due to the combination of several factors: the crust burial (below the overthrusting internal units) down to about 10km, the presence of weak inherited syn-rift basins, and the strain softening in shear zones that evolve in mica-rich phyllonites. These results are consistent with the studies in the Aar massif and should most likely apply to the Mont Blanc massif, whose relationships with its cover are still debated.
EGU General Assembly
Vienne, Austria

insu-00839426
https://hal-insu.archives-ouvertes.fr/insu-00839426
BIBCODE : 2013EGUGA..15.8837B

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Whole-rock concentrations of Se and Te were determined in 53 peridotite samples collected in orogenic bodies from the Eastern Pyrenees, including the Lherz massif (33 samples), the type-locality of Iherzolite. Orogenic Iherzolites tectonically emplaced into the continental crust escaped devolatilisation that may strongly alter concentrations of those volatile trace elements in basalt-hosted peridotite xenoliths. The Se and Te concentration ranges (<3.5-100.7 ppb; <1-11 ppb) are consistent with the few analyses of mantle samples yet available, yet extending to higher Se concentrations. In-situ analyses performed by LAM-ICPMS on base metal sulfides indicate that the Se budget is controlled by sulfides whereas a large fraction of Te (50 +/- 30%) does not reside in sulfides. The missing fraction is accounted for by fractional crystallization of Pt-Pd tellurides from Cu-Ni sulfide melts. A maximum of one third of the S budget of Eastern Pyrenean peridotites was added by assimilation of crustal sulfides, which crystallized as pyrite. Disregarding those contaminated samples, some features of the Se and Te systematics (e.g. bivariate plots vs. fertility index) cannot be explained by partial melting processes. The best fit for 33 peridotites (mostly from Lherz) yields higher than chondritic S/Se (3.1213 +/- 500; r(2) = 0.96) for near chondritic Se/Te (8.6 +/- 2; r(2) = 0.9). Our study suggest that such superchondritic S/Se ratios are better explained by petrogenetic processes involving refertilization of harzburgitic lithosphere by metal (Cu,Ni)-rich sulfide melts precipitated along with clinopyroxene and Al-spinel from silicate melts en-route to the surface.
ISSN: 0009-2541

hal-00544577
https://hal.archives-ouvertes.fr/hal-00544577
DOI : 10.1016/j.chemgeo.2010.09.007

Éditeur(s) : HAL CCSD American Society for Biochemistry and Molecular Biology
Résumé : International audience
Neuroglobins, previously thought to be restricted to vertebrate neurons, were detected in the brain of a photosymbiotic acoel, Symsagittifera roscoffensis, and in neurosensory cells of the jellyfish Clytia hemisphaerica. For the neuroglobin of S. roscoffensis, a member of a lineage that originated either at the base of the bilateria or of the deuterostome clade, we report the ligand binding properties, crystal structure at 2.3 Å, and brain immunocytochemical pattern. We also describe in situ hybridizations of two neuroglobins specifically expressed in differentiating nematocytes (neurosensory cells) and in statocytes (ciliated mechanosensory cells) of C. hemisphaerica, a member of the early branching animal phylum cnidaria. In silico searches using these neuroglobins as queries revealed the presence of previously unidentified neuroglobin-like sequences in most metazoan lineages. Because neural systems are almost ubiquitous in metazoa, the constitutive expression of neuroglobin-like proteins strongly supports the notion of an intimate association of neuroglobins with the evolution of animal neural systems and hints at the preservation of a vitally important function. Neuroglobins were probably recruited in the first protoneurons in early metazoans from globin precursors. Neuroglobins were identified in choanoflagellates, sponges, and placozoans and were conserved during nervous system evolution. Because the origin of neuroglobins predates the other metazoan globins, it is likely that neuroglobin gene duplication followed by co-option and subfunctionalization led to the emergence of globin families in protostomes and deuterostomes (i.e. convergent evolution).
ISSN: 0021-9258

hal-01020584
http://hal.upmc.fr/hal-01020584
http://hal.upmc.fr/hal-01020584/document
http://hal.upmc.fr/hal-01020584/file/Rosko_jbc_revised.pdf
DOI : 10.1074/jbc.M112.407601

Éditeur(s) : HAL CCSD IODP
Résumé : The Superfast Spreading Crust campaign, echoing long-standing ocean lithosphere community endeavors, was designed to help us understand the formation, architecture, and evolution of ocean crust formed at fast spreading rates. Integrated Ocean Drilling Program (IODP) Expedition 335, "Superfast Spreading Rate Crust 4" (13 April-3 June 2011), was the fourth scientific drilling cruise of the Superfast Spreading Crust campaign to Ocean Drilling Program (ODP) Hole 1256D. The expedition aimed to deepen this basement reference site several hundred meters into the gabbroic rocks of intact lower oceanic crust to address the following fundamental scientific questions: Does the lower crust form by subsidence of a crystal mush from a high-level magma chamber (gabbro glacier), by intrusion of sills throughout the lower crust, or by some other mechanism? How does melt percolate through the lower crust, and what are the reactions and chemical evolution of magmas during migration? Is the plutonic crust cooled by conduction or hydrothermal circulation? What are the role and extent of deeply penetrating seawater-derived hydrothermal fluids in cooling the lower crust and the chemical exchanges between the ocean crust and the oceans? What are the relationships among the geological, geochemical, and geophysical structure of the crust and, in particular, the nature of the seismic Layer 2-3 transition? What is the magnetic contribution of the lower crust to marine magnetic anomalies?
https://hal.archives-ouvertes.fr/hal-00688990

hal-00688990
https://hal.archives-ouvertes.fr/hal-00688990
DOI : 10.2204/iodp.pr.335.2011

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The analysis of field relationships between allochthonous crystalline slivers, ultramafic units and associated sedimentary cover in the high-pressure Schistes Lustrés units of northern Corsica allows reconstruction of the pre-orogenic architecture of a fossil Mesozoic Ocean-Continent Transition (OCT) of the Tethys basin. The studied area, encompassing the Serra di Pigno and Col de Téghime areas (Cap Corse) is composed of an assemblage of prealpine basement sheets made up of serpentinized mantle rocks, Permian gabbros and gneisses, locally associated with Paleozoic metabasites and micaschists. The sedimentary cover includes numerous intervals of calc-schists, marbles, quartzites, micaschists and dolomitic metabreccias yielding a great variety of lithostratigraphical successions. The metasedimentary sequences do not show affinities with the typical cover series of the Prépiémontais margin domains. This implies an origin from a more internal domain (oceanward) for the studied units. In addition, the sedimentary cover of the ultramafic basement units do not display the characters of the classical Alpine ophiolites but bear lithological features showing affinities with both continental and oceanic environments. We assume that the high variability of the sedimentary successions as well as the presence of a basement composed of continental and upper-mantle rocks is consistent with an origin at an OCT. The acidic basement slivers are regarded as former extensional allochthons of continental crust abandoned during breakup on a newly exhumed seafloor of peridotite composition. Such extensional allochthons, will then logically constitute the most internal continental slices buried at great depth during Alpine subduction. This work shows that a lot has to be expected from a revision of the Schistes Lustrés lithostratigraphy in the light of the new concepts of the evolution of the OCT domains.
ISSN: 0040-1951

hal-00795578
https://hal.archives-ouvertes.fr/hal-00795578
DOI : 10.1016/j.tecto.2012.06.013

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Longmen Shan (Sichuan, China) is characterised by an unusual morphology which results from a Triassic prism tectonics and a more recent Neogene thick-skin thrusting. Among its specific features is the high elevation of the internal zones in continuity with the Songpan Garze fold-and-thrust belt (SG), which is associated with an abrupt 20 km Moho offset between the Sichuan Basin and the Tibetan plateau as revealed by the analysis of teleseismic data acquired by a dense seismic network. The jump in crustal thickness is located at the apex of the Wenchuan shear zone (WSZ) and marks the western boundary of the metamorphosed units of SG characterized by temperatures varying from 590 degrees C down to 300 degrees C as commonly observed in mature accretionary wedges. Both the structural style marked by intense shortening in tight kink folds and geophysical data suggest the presence of an horizontal discontinuity at similar to 15 km depth over a thick crust (similar to 63 km).;The Longmen Shan east of the WSZ is characterized by thick-skin detachment which thrusts the internal sedimentary units and the Proterozoic basement over the series of the Sichuan Basin deposited on a thinner crust of similar to 44 km thick. The major front is the Beichuan Fault Zone (BFZ) which brought the internal zones onto Triassic and Jurassic series with lower temperatures (less than 400 degrees C). Locally, temperatures of similar to 425 degrees C are found just below the klippes.;These results are in agreement with an original contact of the SG zone represented by an accretionary wedge of sediments thrusted over the margin of the continental crust of the Yangtze craton in the early stage (Indosinian) of the evolution. The present-day slow E-W component of the convergence, added to the difference in crustal thickness caused the Yangtze crust to indent the Songpan Tibetan crust which was softened by a high thermal regime. As a response the edge of the Tibet crust was inflated to the bottom (up to 70 km), whereas to the top, the crystalline massif were exhumed and pushed the deformation eastward as emerging and blind thrusts. This configuration reflects a moderate shortening of the crust which behaves as a soft thick material abutting the resistant and cold Yangtze crust.
ISSN: 0040-1951

hal-00534849
https://hal.archives-ouvertes.fr/hal-00534849
DOI : 10.1016/j.tecto.2010.03.018

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A new portable sampling system was developed to extract Radium isotopes from large volumes (up to 300 L) of fresh surface- and ground-waters of low Ra-activities (<5 mBq/L). Ra is quantitatively adsorbed on a small amount (6.5 g) of MnO2-coated acrylic fibers, which are then dried and burned at 600 °C in the laboratory. The resulting Mn-oxide powder (about 2 cm3 when compacted) is then analyzed through gamma-ray spectrometry which allows measurement of the whole Ra quartet (226Ra, 228Ra, 224Ra and 223Ra) in a single counting of a few days. The usual relative standard combined uncertainties (1σ) are 2–3% for 226Ra, 228Ra and 224Ra; and less than 10% for 223Ra. This method was applied to the analysis of Ra in karstic waters of the Lez aquifer, and surface- and ground-waters of the upper and middle Vidourle watershed (South of France). The analyzed waters have relatively low 226Ra activities (1–4 mBq/L) in both cases, regardless of the contrasted geology (Mesozoic limestone vs crystalline Variscan basement), but clearly distinct (228Ra/226Ra) ratios in agreement with the differences in Th/U ratios of the two drained areas. Short-lived Ra isotopes (224Ra and 223Ra) appear to be mainly influenced by near-surface desorption/recoil processes for most of the sampling sites.
ISSN: 0969-8043

hal-01491281
https://hal.archives-ouvertes.fr/hal-01491281
DOI : 10.1016/j.apradiso.2016.12.010

Éditeur(s) : HAL CCSD
Résumé : 1 p.
International audience
The 12th May 2008 Wenchuan earthquake in the Longmen Shan occurred on a large thrust fault largely inherited from an Indosinian structure itself probably controlled by an older structural heritage of the South China block continental margin. Within the whole northeast Tibet region, such a structural inheritance has had a major impact on the Tertiary deformation. It appears of primary importance to assess the pre-Tertiary tectonic evolution of the main blocks involved to understand the actual deformation in the eastern edge of Tibet. Over the past decades, the Proterozoic to Cenozoic tectonic, metamorphic and geochronologic history of the Longmen Shan and Songpan Garzê area have been largely studied. We present a synthesis of the tectonic evolution of the Songpan Garzê fold and thrust belt from Triassic to present. The Songpan-Garzê belt was formed during closure of a wide oceanic basin ?lled with a thick (5 to 15 km) sequence of Triassic ?yschoid sediments. Closure of the basin due to Triassic subduction involved strong shortening, intense folding and faulting of the Triassic series. A large-scale décollement, that presently outcrops along the eastern boundary of the belt (Danba area), allowed the growth of a wide and thick accretionary wedge. It develops in the Paleozoic and Triassic series and separates the accretionary prism from an autochthonous crystalline basement which shares many similarities with the basement of the Yangtze Craton (0.7-0.9 Ga). To the north and northwest, below the thickened Triassic series of the belt, the composition (oceanic or continental) of the basement remains unknown. During the Indosinian orogeny the emplacement of orogenic granites (220 - 150 Ma) was associated to crustal thickening. The isotopic composition of granitoids shows that their magma source were predominantly derived from melting of the proterozoic basement with varying degrees of sedimentary material and negligible mantle source contribution. In the Danba area, the décollement outcrops in a large tertiary antiform with a NNW-SSE axis. It has been exhumed too in the hanging wall of the NE-SW faults of the Tertiary Longmen-Shan belt that marks the present day transition from the Tibetan plateau to the Sichuan basin. These faults have episodically absorbed signi?cant shortening since the Late Triassic. The amount and precise timing of post-triassic deformation are dif?cult to constrain especially because of the dif?culty to isolate the tertiary thermochronological signal from the protracted late Triassic - Cretaceous thermal history. Nonetheless it is generally accepted that Jurassic - Cretaceous tectonism did not modi?ed the general Triassic architecture of eastern Tibet contrarily to the Tertiary deformation. The long-term cooling histories obtained on Mesozoic granites and on the metamorphic series of the Danba dome are very similar showing a very slow and regular cooling during Jurassic andCretaceous, con?rming the absence of major tectonic event between c.a. 150 and 30 Ma. Low temperature thermochronology data indicate that ?nal exhumation and cooling occurred in theTertiary with an acceleration between 10 and 5 Ma along the major tectonic structures. Within the Longmen Shan range, a total denudation of 7 to 10 km is estimated for the late Cenozoic period. Similar amounts of late Tertiary denudation have been estimated along an east-west section across the Xianshuihe fault
Asian climate and tectonics seminar
Utrecht, Netherlands

insu-00610298
https://hal-insu.archives-ouvertes.fr/insu-00610298
DOI : 10.1016/j.jseaes.2010.03.008

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
The anisotropic single crystal seismic properties are reviewed in the light of recent experimental and theoretical determinations. Although considerable progress has been made on the determination of single crystal properties, data are still lacking, particularly for the temperature derivatives of transition zone and lower mantle phases. The common types of LPO of olivine, opx and cpx are presented together with their associated seismic properties. It is emphasized that simple seismic symmetry pattern of upper mantle rocks are a direct result of the interaction of olivine, opx and cpx. Using the standard structural frame (X lineation, Z pole to foliation) for typical LPOs of olivine, opx and cpx have the maximum Vp parallel to X, in the XZ plane and parallel to Y respectively. Destructive interference occurs between these minerals and hence P-wave anisotropy should be sensitive to the aggregate composition. For shear wave splitting (dVs) typical olivine and opx LPOs result in similar patterns with the maximum dVs in the YZ plane and the fast split shear wave (Vs1) polarized parallel to the foliation. A typical cpx LPO on the other hand produces destructive interference as the max dVs is close to X. By comparison with experiments and numerical simulations, it is estimated that upper mantle samples have an olivine LPO strength which recorded shear strain gamma of between 0.25 and 2.0. Pyrolite and piclogite models are compared with global transverse isotropic models. The slowly reducing P-wave anisotropy in the first 200 km can be explained by a model with constant composition and LPO strength. The sharp decrease in the observed anisotropy in the global models cannot be explained by the transformation of opx to cpx at 300 km, it is proposed that this decrease is due to a reduction in LPO strength from 200 to 350 km at the base of the lithosphere.
Earth's Deep Interior: Mineral Physics and Tomography From the Atomic Scale to the Global Scale

ISBN : 9780875909752
hal-01391524
http://hal.univ-reunion.fr/hal-01391524
http://hal.univ-reunion.fr/hal-01391524/document
http://hal.univ-reunion.fr/hal-01391524/file/Mainprice_AGUmonog_DM_GB_WBI_2000.pdf

Éditeur(s) : HAL CCSD Geological Society of London
Résumé : International audience
This paper presents the background for the calculation of various numbers that can be used to characterize crystal-preferred orientation (CPO), also known as texture in materials science, for large datasets using the combined scripting possibilities of MTEX and MatLab®. The paper is focused on three aspects in particular: the strength of CPO represented by orientation and misorientation distribution functions (ODFs, MDFs) or pole figures (PFs); symmetry of PFs and components of ODFs; and elastic tensors. The traditional measurements of texture strength of ODFs, MDFs and PFs are integral measurements of the distribution squared. The M-index is a partial measure of the MDF as the difference between uniform and measured misorientation angles. In addition there other parameters based on eigen analysis, but there are restrictions on their use. Eigen analysis does provide some shape factors for the distributions. The maxima of an ODF provides information on the modes. MTEX provides an estimate of the lower bound uniform fraction of an ODF. Finally, we illustrate the decomposition of arbitrary elastic tensor into symmetry components as an example of components in anisotropic physical properties. Ten examples scripts and their output are provided in the appendix.
Geological Society Special Publication

hal-01277689
https://hal.archives-ouvertes.fr/hal-01277689
DOI : 10.1144/SP409.8

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study explores the dynamics of porosity and reactive surface area changes during porous limestone dissolution by CO2-rich water. The Sr and Ca concentrations in both the rock and the outlet solution are used to evaluate the reactive surface area changes of the two rock-forming calcites, i.e. micrite grains and sparite crystals, which have different trace element signatures. The geometric surface area measured with X-ray microtomography decreases slightly whereas the reactive surface area increases continuously with increasing porosity from 20.3 to 30.2%. Surprisingly, changes in reactive surface areas are very different between the two calcites. The reactive surface area changes in the micrite are parabolic while the reactive surface area of sparite increases greatly. The numerical model HYTEC is used to model the change in reactive surface areas during the experiment. Different geometrical models are tested. The model based on spherical-grain dissolution and spherical-pore growth fails to reproduce the experimental results, while the sugar-lump model provides reasonable agreement with the experiment.
ISSN: 0009-2541

hal-00445274
https://hal.archives-ouvertes.fr/hal-00445274
DOI : 10.1016/j.chemgeo.2009.01.032

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
One of the main difficulties encountered when characterizing the hydrodynamic properties of a fractured aquifer is to identify the preferential flow paths within it. Different methods may be applied to determine the variability of the permeability at the borehole scale and to image the structure of the main flow zones between boreholes. In this paper, we compare the information obtained from different measurement techniques performed in a set of three 100 m depth wells (well-to-well spacing: 5­10 m) in a fractured crystalline rock setting. Geophysical logging and borehole-wall imaging are used to identify open and closed fractures intersecting the boreholes and their orientation. The comparison with flowmeter and single packer tests shows that few of the fractures interpreted as open from geophysical logs are significantly transmissive. Cross-borehole connectivity is first investigated from single packer tests with pressure monitoring in adjacent boreholes. To determine fracture zone connectivity, we propose a methodology simply based on the variation with packer depth of the ratio of the drawdown in the observation well and the drawdown in the pumping well. The results are compared to the analysis of cross-borehole flowmeter tests. We show that both methods provide consistent results with a similar level of information on connectivity.
ISSN: 0022-1694

insu-00221380
https://hal-insu.archives-ouvertes.fr/insu-00221380
DOI : 10.1016/j.jhydrol.2007.07.007

Éditeur(s) : HAL CCSD
Résumé : International audience
The hierarchical architecture of biopolymers induces remarkable behaviour. Wood mechanical properties mainly originate from the organization of wood tissue and interactions of cellwall components. The respective contribution on components inside those networks occurs at nanometric scale and still challenging to investigate in-situ. X-ray scattering techniques are now used as a routine technique to investigate internal organization of material components. For that purpose large-scale synchrotron facilities like ESRF offer leading X-ray sources capabilities (large energy range, high brilliance, high intensity, dedicated setups). ESRF's ID13 beamline serves high spacial resolution scanning setups to expertise in elastic scattering of monochromatic X-rays. Since analytical description of the scattering signal of cellulose have been well describe wood material benefit wide range of exposure conditions and sample environment. During this conference, we will present our achievements based on transverse sections of poplar specimens exposed to micrometric beam (1.2 μm side, 12.6 keV energy) to reveal crystalline cellulose distribution within wood tissue and to nanometric beam (100 nm side, 12 6 keV energy) to map the evolution of cellulose orientation within double cell wall over combined Wide-Angle (WAXS) and Small-Angle (SAXS) X-ray Scattering configuration. Within those setups hygrometric sample environment and stretching solicitations will be approached based on-going developments.
COST FP0802 Workshop 'Micro Characterisation of Wood Material'
Edimbourg, United Kingdom

hal-01113298
https://hal.archives-ouvertes.fr/hal-01113298

Éditeur(s) : HAL CCSD National Research Council Canada
Résumé : International audience
The spadix of Arum italicum Miller consists of two main parts: a clavate sterile portion (appendix) and a cylindroid fertile portion. In the fertile portion with both male and female zones, there are two zones of sterile flowers (bristles). The basal portion of bristles is surrounded by a verrucose structure consisting of a mass of tissular excrescences. During early stages of development, there is no free space between the different zones of the inflorescence. The elongation of the inflorescence axis is what eventually separates the different zones from each other. There are no atypical flowers that are morphologically intermediate between male and female flowers as is the case in other genera of Aroideae (e.g., Cercestis, Philodendron, Schismatoglottis). The structure of the bristles in the inflorescences of Arum does not correspond to any type of atypical flower (unisexual or bisexual) that has been analysed previously in the Araceae. From a developmental point of view, it is not possible to determine if the bristles correspond to aborted or modified female or male flowers. In the early stages of development, the stamens, staminodes, and appendix are covered by globular masses of extracellular calcium oxalate crystals.
Le spadice de l’Arum italicum comporte deux parties principales : une portion claviforme stérile (appendice) et une portion cylindroïde fertile. Dans la portion fertile avec zones mâles et femelles, il y a deux zones de fleurs stériles (soies). La portion basales des soies est entourée par une structure verruqueuse, constituée d’une masse d’excroissances tissulaires. Aux premiers stades du développement, il n’y a pas d’espace libre entre les différentes zones de l’inflorescence. L’élongation de l’axe de l’inflorescence est ce qui sépare éventuellement les différentes zones l’une de l’autre. Il n’y pas de fleurs atypiques intermédiaires entre des fleurs mâles et des fleurs femelles, comme c’est le cas dans d’autres genres d’Aroideae (p. ex. Cercestis, Philodendron, Schismataglottis). La structure des soies chez les inflorescences de l’Arum ne correspond à aucune des fleurs atypiques (unisexuées ou bisexuées) qui ont précédemment été analysées chez les Araceae. Considérant le développement, il n’est pas possible de déterminer si les soies correspondent à des modifications de fleurs femelles ou mâles avortées. Aux premiers stades du développement, les étamines, les staminodes et les appendices sont couverts de masses globuleuses constituées de cristaux extracellulaires d’oxalate de calcium.
ISSN: 0008-4026

hal-01206194
https://hal.archives-ouvertes.fr/hal-01206194

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The oxygen fugacity and therefore the iron redox state of a melt is known to have a strong influence on the liquid line of descent of magmas and thus on the composition of the coexisting melts and crystals. We present a new method to estimate this critical parameter from electron probe microanalyses of two of the most common minerals of basaltic series, plagioclase and clinopyroxene. This method is not based on stoichiometric calculations, but on the different partitioning behaviour of Fe3+ and Fe2+ between both minerals and a melt phase: plagioclase can incorporate more Fe3+ than Fe2+, while clinopyroxene can incorporate more Fe2+ than Fe3+. For example, the effect of oxidizing a partly molten basaltic system (Fe3+ is stabilized with respect to Fe2+) results in an increase of FeOtotal in plagioclase, but a decrease in the associated clinopyroxene. We propose an equation, based on published partition coefficients, that allows estimating the redox state of a melt from these considerations. An application to a set of experimental and natural data attests the validity of the proposed model. The associated error can be calculated and is on average <1 log unit of the prevailing oxygen fugacity.;In order to reduce the number of different variables influencing the Fe2+/Fe3+ mineral/melt equilibrium, our model is restricted to basaltic series with SiO2<60% that have crystallized at intermediate to low pressure (<0.5 GPa) and under relatively oxidizing conditions (Delta FMQ>0; where FMQ is the fayalite-magnetite-quartz oxygen buffer equilibrium), but it may be parameterized for other conditions. A spreadsheet is provided to assist the use of equations, and to perform the error propagation analysis.
ISSN: 0377-0273

hal-00475550
https://hal.archives-ouvertes.fr/hal-00475550
DOI : 10.1016/j.jvolgeores.2009.11.023

Éditeur(s) : HAL CCSD Elsevier
Résumé : The relationship between deformation and so-called fluid paleotransfers in minor faults has been analysed in an argillaceous formation located in the Causses Basin in France. The fluid paleotransfers are related to the fault activity to a large extent. We attempt to estimate the intensity of paleo-deviatoric stress magnitudes under which the fault activity may have occurred and consequently, the change in the structural fault permeability. The paleo-deviatoric stress magnitudes were calculated with the inverse method of Etchecopar applied to calcite twinning. The measured crystals are contained within the core zone of minor faults and this study is based on a previous complete microtectonic and microstructural analysis of the faults. In this paper, analysis of calcite twinning has been applied for the first time to vein fillings associated small faults in a context of relatively weak deformation, a condition ensured by the tectonic and structural analysis. Calculation and discussion of the paleo-deviatoric stress tensors in relation to the evolution of the structural fault permeability and to the hydraulic behaviour of the faults are the aim of this paper. The analysed faults, created and active during the same tectonic event, were permeable under a (;σ;1;–;σ;3;) mean value of 40–50 MPa. On the other hand, the reactivation of faults during a second tectonic event implies mean (;σ;1;–;σ;3;) value higher than 40–50 MPa, especially for the faults that are poorly oriented with respect to the principal tectonic stress directions. The core zone of these faults remained sealed and impermeable or became permeable by development of microcracks inside the pre-existing fillings.
ISSN: 0040-1951

hal-00407577
https://hal.archives-ouvertes.fr/hal-00407577
DOI : 10.1016/j.tecto.2006.09.014

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The present study is based on a set of lavas and crosscutting dikes collected by dives along detailed vertical transects on the northern flank of the western part of the Blanco Transform Fault, Northeast Pacific. The studied area consists of a small basin, the Western Blanco Depression (WBD), extending from the southern end of the Juan de Fuca ridge to a pseudofault trace 60 km eastward. The Northern Scarp of the WBD comprises a volcanic unit overlying a sheeted-dike complex. Major and trace element data, coupled with Sr–Nd isotope ratios, reveal a two-component mantle source, composed by an isotopically depleted matrix variably veined by more enriched material. One chemical group (NS2), indistinguishable from the other Northern Scarp samples on the basis of trace element data, has an unusually depleted isotopic composition typical of a nearly pure mantle end-member. Some cogenetic samples of the Northern Scarp have been used to constrain the differentiation modalities. Anorthite and MgO content profiles in plagioclase xenocrysts and phenocrysts reveal (i) the existence of H2O-bearing evolved melts in the mushy zones and (ii) the occurrence of mixing process between these melts and anhydrous mafic liquids. The hydration is supported by other petrographic features such as high magmatic fO2 values, calculated from Fe–Ti oxide pairs, and the presence of pyroxene inclusions in plagioclase phenocrysts. Mixing, consistent with the existence of Ni-rich ferrobasalts, is interpreted to be the consequence of the reservoir refilling by mafic liquids (Mg# = 70). These petrological and geochemical evidences are combined with the evolution of Mg# with depth to suggest a periodic open-system magma chamber evolution beneath the southern end of the Juan de Fuca ridge.
ISSN: 0024-4937

insu-00213426
https://hal-insu.archives-ouvertes.fr/insu-00213426
DOI : 10.1016/j.lithos.2007.06.009

Éditeur(s) : HAL CCSD
Résumé : soutenue le 09 juin 2008
Intrinsic tribological properties of lamellar compounds are usually attributed to the presence of van der Waals gap in their structure. The controled variation of the graphite's crystal and electronic structure by intercalation processes of different species (electrophile, nucleophile ...) give a possibility to study in a more deeply way the friction reduction processes for low dimensional compounds. Three groups of intercalant are studied and tribological properties are correlated to structural and chemical evolutions.
Les propriétés tribologiques intrinsèques des composés lamellaires sont généralement attribuées à la présence de gap de van der Waals dans leur structure. La possibilité de faire varier de manière contrôlée la structure cristalline et la structure électronique du graphite par processus d'intercalation de différentes espèces chimiques (électrophile, nucléophile ...) sont utilisées pour étudier de façon plus approfondie les processus de réduction du frottement par les composés de basse dimensionnalité. Trois familles d'intercalants sont étudiées et les propriétés tribologiques sont corrélées aux évolutions structurales et chimiques.
https://tel.archives-ouvertes.fr/tel-00431713

Droits : info:eu-repo/semantics/OpenAccess
tel-00431713
https://tel.archives-ouvertes.fr/tel-00431713
https://tel.archives-ouvertes.fr/tel-00431713/document
https://tel.archives-ouvertes.fr/tel-00431713/file/These-DELBE_Karl.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The eastern part of the Cordillera Occidental of Ecuador comprises thick buoyant oceanic plateaus associated with island-arc tholeiites and subduction-related calc-alkaline series, accreted to the Ecuadorian Continental Margin from Late Cretaceous to Eocene times. One of these plateau sequences, the Guaranda Oceanic Plateau is considered as remnant of the Caribbean–Colombian Oceanic Province (CCOP) accreted to the Ecuadorian Margin in the Maastrichtien. Samples studied in this paper were taken from four cross-sections through two arc-sequences in the northern part of the Cordillera Occidental of Ecuador, dated as (Río Cala) or ascribed to (Macuchi) the Late Cretaceous and one arc-like sequence in the Chogòn-Colonche Cordillera (Las Orquídeas). These three island-arcs can clearly be identified and rest conformably on the CCOP. In all four localities, basalts with abundant large clinopyroxene phenocrysts can be found, mimicking a picritic or ankaramitic facies. This mineralogical particularity, although not uncommon in island arc lavas, hints at a contribution of the CCOP in the genesis of these island arc rocks. The complete petrological and geochemical study of these rocks reveals that some have a primitive island-arc nature (MgO values range from 6 to 11 wt.%). Studied samples display marked Nb, Ta and Ti negative anomalies relative to the adjacent elements in the spidergrams characteristic of subduction-related magmatism. These rocks are LREE-enriched and their clinopyroxenes show a tholeiitic affinity (FeOT–TiO2 enrichment and CaO depletion from core to rim within a single crystal). The four sampled cross-sections through the island-arc sequences display homogeneous initial Nd, and Pb isotope ratios that suggest a unique mantellic source for these rocks resulting from the mixing of three components: an East-Pacific MORB end-member, an enriched pelagic sediment component, and a HIMU component carried by the CCOP. Indeed, the ankaramite and Mg-basalt sequences that form part of the Caribbean-Colombian Oceanic Plateau are radiogenically enriched in 206Pb/204Pb and 207Pb/204Pb and contain a HIMU component similar to that observed in the Gorgona basalts and Galápagos lavas. The subduction zone that generated the Late Cretaceous arcs occurred far from the continental margin, in an oceanic environment. This implies that no terrigenous detrital sediments interacted with the source at this period. Thus, the enriched component can only result from the melting of subducted pelagic sediments. We have thus defined the East-Pacific MORB, enriched (cherts, pelagic sediments) and HIMU components in an attempt to constrain and model the genesis of the studied island-arc magmatism, using a compilation of carefully selected isotopic data from literature according to rock age and paleogeographic location at the time of arc edification. Tripolar mixing models reveal that proportions of 12–15 wt.% of the HIMU component, 7–15 wt.% of the pelagic sediment end-member and 70–75 wt.% of an East-pacific MORB end-member are needed to explain the measured isotope ratios. These surprisingly high proportions of the HIMU/CCOP component could be explained by the young age of the oceanic plateau (5–15 Ma) during the Late Cretaceous arc emplacement. The CCOP, basement of these arc sequences, was probably still hot and easily assimilated at the island-arc lava source.
ISSN: 0895-9811

insu-00353692
https://hal-insu.archives-ouvertes.fr/insu-00353692
DOI : 10.1016/j.jsames.2008.06.003