Éditeur(s) : HAL CCSD Elsevier
Résumé : To contribute to the understanding of how opening-mode fractures (joints) form and open or close at depth in layered rocks, we present a 2D numerical study aiming to determine whether tensile stress can develop in pre-fractured elastic multilayers submitted to biaxial compressive strain conditions. First, we investigate the role of the elastic and geometrical properties of the layers on the development of tensile stress in models with five bonded layers and containing one open fracture in the central layer. Our results indicate that, in absence of elastic contrast (in Young's modulus) between the layers, no tensile stress develops in the models. However, when the fractured layer is stiffer than the two adjacent layers directly above and below, a lobe of horizontal tensile stress develops centered on the pre-existing fracture. The creation of this tensile stress is contingent upon the partial closing of the fracture. The levels of tensile stress and the thickness of the lobe of tensile stress increase logarithmically with an increase in the elastic contrast and are systematically larger for a larger Soft/Stiff ratio (ratio of the total thickness of the soft layers with the total thickness of the stiff layers). Second, we investigate the role of fracture interaction in the development of tensile stress in models containing a pair of open fractures. We observe that the levels of tensile stress in the region between the fractures are systematically higher than those observed in identical models containing a single fracture. This increase in tensile stress is very large for small elastic contrasts between the layers but diminishes when the elastic contrast increases. Furthermore, the spacing between the pre-existing fractures plays an important role in the stress distribution in the region between them. When the fracture spacing is equal to or lower than 1.15 times the height of the fractured layer for the experimental conditions chosen, the lobes of tensile stress centered on the fractures coalesce. This results in the formation of vast areas of tensile stress in models under remote compressive loading conditions. Such tensile areas are likely to allow the initiation and propagation of subsequent opening-mode fractures. The results obtained provide new insights into the formation of joints in layered rocks in compressive environments, with important consequences on fluid flow.
ISSN: 0040-1951

hal-00407576
https://hal.archives-ouvertes.fr/hal-00407576
DOI : 10.1016/j.tecto.2006.12.003

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
During the early years of the Iceland Deep Drilling Project (IDDP), development of three distinctive technological and scientific approaches were formalised and then carried out until 2010 within a European funded project called HiTI (high temperature instruments for supercritical geothermal reservoir characterisation and exploitation). These approaches were: (1) development of several downhole instruments allowing them to function up to 300 ◦C and 400 ◦C, (2) identification of two new Na/Li cation ratio geothermometric relationships valid at very high temperature, (3) tracer testing with high temperature tolerant organic isomers and finally and (4) basalt rock deformation and petrophysical properties laboratory investigations at high temperature and pressure conditions.
ISSN: 0375-6505

hal-00921127
https://hal-brgm.archives-ouvertes.fr/hal-00921127
DOI : 10.1016/j.geothermics.2013.07.008

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Hydrogen can be stored in the structure of nominally anhydrous minerals as point defects, and these impurities substantially modify many physical properties of Earth's mantle minerals. However, mantle rocks are composed of mineral grains separated by grain boundaries and interphase grains boundaries. Therefore, as a potential hydrogen reservoir, grain boundaries should be given proper attention. Here, I report an experimental investigation into hydrogen diffusion through grain boundaries in polycrystalline aggregates Sintering and diffusion experiments were performed using a gas-medium high-pressure vessel at under pressure of 300 MPa and over a temperature range of 900-1,250 degrees C. The diffusion assembly consisted of a polycrystalline cylinder of aluminous spinel + olivine crystals with a talc cylinder as the main hydrogen source. A Ni capsule was used to buffer the oxygen fugacity at Ni-NiO Experimental durations varied from 5 min to 5 h. The presence of hydrogen in the crystals was measured by Fourier-transform infrared spectroscopy. The calculation of the diffusion coefficients was based on the estimation of the characteristic distance. The absence or presence of hydrogen recorded by the 'hydrogen sensor' olivines embedded in the aggregate allows the estimation of bounds on this characteristic distance. Results presented here suggest that hydrogen effective diffusion coefficients are only one order of magnitude faster (similar to 10(-9) m(2)s(-1) at 1,000 degrees C) than in an olivine single crystal along the [100] axis. Resulting diffusion coefficients for hydrogen in grain boundary are four orders of magnitude faster than in a single crystal, but this diffusivity is not fast enough to affect hydrogen mobility in mantle rocks with grain sizes greater than similar to 1 mm. Thus, very limited chemical homogenization would occur using grain boundaries diffusion in mantle hydrous peridotite for incompatible and volatile element, such as hydrogen.
ISSN: 0010-7999

hal-00564353
https://hal.archives-ouvertes.fr/hal-00564353
DOI : 10.1007/s00410-010-0512-4

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We have analyzed the microstructures and crystal preferred orientations (CPO), and calculated the seismic properties of 53 mantle xenoliths from four localities within the North Tanzanian Divergence of the East African rift: two within the rift axis and two in the transverse volcanic belt. Olivine OH concentrations were measured in 15 xenoliths.Most samples have harzburgitic to dunitic compositions and high olivine Mg#. Microstructures and olivine CPO patterns vary strongly depending on the location. In-axis peridotites display mylonitic to porphyroclastic microstructures, which record recent deformation by dislocation creep. Highly stretched orthopyroxenes in mylonites indicate that the deformation was initiated under high stress and probably low temperature. Orthopyroxene replacement by olivine in mylonitic and porphyroclastic peridotites suggest syn-kinematic melt–rock reactions and further deformation under near-solidus conditions. Exsolutions in orthopyroxene imply significant cooling between melt-assisted deformation and xenolith extraction. Late metasomatism is evidenced by the occurrence of veins crosscutting the microstructure and interstitial clinopyroxene and phlogopite. Axial-[100] olivine CPOs predominate, suggesting activation of the high temperature, low pressure [100] {0kl} slip systems and, probably, transtensional deformation. In the volcanic belt, Lashaine peridotites display very coarse-granular textures, indicating deformation by dislocation creep under low deviatoric stress conditions followed by annealing. Axial-[010] olivine CPOs are consistent with transpressional deformation or simultaneous activation of the [100](010) and [001](010) slip systems. Intermediate microstructures and CPOs in Olmani suggests heterogeneous deformation within the volcanic belt. Olivine OH concentrations range between 2 and 12 ppm wt. H2O. No systematic variations are observed between in- and off-axis samples. Maximum P wave azimuthal anisotropy (AVp) ranges between 3.3 and 18.4%, and the maximum S wave polarization anisotropy (AVs) between 2.3 and 13.2%. Comparison between seismic properties of in-axis peridotites and SKS splitting data suggests transtensional deformation in the lithospheric mantle beneath the rift.
ISSN: 0040-1951

hal-01121552
https://hal.archives-ouvertes.fr/hal-01121552
DOI : 10.1016/j.tecto.2014.11.011

Éditeur(s) : HAL CCSD European Geosciences Union
Résumé : The properties of the subduction interplate domain are likely to affect not only the seismogenic potential of the subduction area but also the overall subduction process, as it influences its viability. Numerical simulations are performed to model the long-term equilibrium state of the subduction interplate when the diving lithosphere interacts with both the overriding plate and the surrounding convective mantle. The thermomechanical model combines a non-Newtonian viscous rheology and a pseudo-brittle rheology. Rock strength here depends on depth, temperature and stress, for both oceanic crust and mantle rocks. I study the evolution through time of, on one hand, the brittle-ductile transition (BDT) depth, zBDT, and, on the other hand, of the kinematic decoupling depth, zdec, simulated along the subduction interplate. The results show that both a high friction and a low ductile strength at the asthenospheric wedge tip shallow zBDT. The influence of the weak material activation energy is of second order but not negligible. zBDT becomes dependent on the ductile strength increase with depth (activation volume) if the BDT occurs at the interplate decoupling depth. Regarding the interplate decoupling depth, it is shallowed (1) significantly if mantle viscosity at asthenospheric wedge tip is low, (2) if the difference in mantle and interplate activation energy is weak, and (3) if the activation volume is increased. Very low friction coefficients and/or low asthenospheric viscosities promote zBDT = zdec. I then present how the subducting lithosphere age affects the brittle-ductile transition depth and the kinematic decoupling depth in this model. Simulations show that a rheological model in which the respective activation energies of mantle and interplate material are too close hinders the mechanical decoupling at the down-dip extent of the interplate, and eventually jams the subduction process during incipient subduction of a young (20-Myr-old) and soft lithosphere under a thick upper plate. Finally, both the BDT depth and the decoupling depth are a function of the subducting plate age, but are not influenced in the same fashion: cool and old subducting plates deepen the BDT but shallow the interplate decoupling depth. Even if BDT and kinematic decoupling are intrinsically related to different mechanisms of deformation, this work shows that they are able to interact closely. Comparison between modelling results and observations suggests a minimum friction coefficient of 0.045 for the interplate plane, even 0.069 in some cases, to model realistic BDT depths. The modelled zdec is a bit deeper than suggested by geophysical observations. Eventually, the better way to improve the adjustment to observations may rely on a moderate to strong asthenosphere viscosity reduction in the metasomatised mantle wedge.
ISSN: 1869-9510

hal-00795559
https://hal.archives-ouvertes.fr/hal-00795559
DOI : 10.5194/se-3-467-2012, 2012

Éditeur(s) : HAL CCSD
Résumé : International audience
The carbon capture and storage is considered as one of the solutions of reducing the effects of global warming. It consists in injecting large quantities of CO 2 in supercritical form directly into deeply located geological formations. One of the methods involves sequestration in the carbonate sedimentary rocks (sandstones and limestones) which are considered as a promising solution. The morphology of the pore network and solid skeleton defines important macroscopic prop-erties of the rock (permeability, stiffness). Modelling at micro scale of random heterogeneous materials (porous media) should be based on morphological and statistical characterisation 1,2 of the investigated microstructure. The work is focused on a reconstruction method by grains deposit 3 , for various range of pa-rameters, to obtain equivalent model of natural rock samples (oolitic limestone and fontainebleau sandstone). Generated samples satisfy morphological and statistical informations 4 which were obtained by 3D image analysis of X-ray tomography of the natural rock samples. For validation of the modelling numerical computations of mechanical and transfer properties are also provided.
14th European Mechanics of Materials Conference - EMMC14
Gothembourg, Sweden

hal-01103163
https://hal.archives-ouvertes.fr/hal-01103163

Éditeur(s) : HAL CCSD Elsevier
Résumé : Nominally anhydrous minerals (NAMs) of Earth's mantle can contain hydrogen as atomic impurity in their crystal structures. This hydrogen substantially modifies many physical properties of Earth's mantle rocks. Also, the Earth's deep interior is made of rocks where minerals are separated by nanometer-scale interfaces call grain boundaries and interphase boundaries. These grain boundaries should carefully be considered as a potential hydrogen reservoir as well. I report here an experimental investigation of hydrogen diffusion through grain boundaries in olivine polycrystalline aggregates. Hot-press and diffusion experiments were performed using a gas-medium high-pressure vessel at a confining pressure of 300 MPa, over a temperature range of 1000-1200 degrees C. The diffusion assembly consisted of a dense polycrystalline cylinder of natural olivine from San Carlos (Arizona) mixed with olivine singles crystals of millimeter size. This mixture was couple with a talc cylinder. Ni capsule were used to buffer the oxygen fugacity at Ni-NiO level. Experiment durations varied from 3 min to 4 h. The presence of hydrogen in the sample was quantified using Fourier transform infrared spectroscopy. The calculation of the diffusion coefficients was based on the estimation of the length of polycrystalline solid affected by the diffusion of hydrogen. The absence or presence of hydrogen was recorded by the large olivines behaving here as "hydrogen sensor", which are implanted in the aggregate. The results indicate that effective hydrogen diffusivity which includes grain boundaries effect in olivine aggregate is barely one order of magnitude faster than hydrogen diffusion in an olivine single crystal with a diffusivity similar to 8.5x 10(-10) m(2) s(-1) 1000 degrees C and only twice faster similar to 2.1 x10(-9) m(2) s(-1) 1200 degrees C. Calculations of the diffusion data in relation to the Arrhenius Law, yield an activation energy of similar to 70 +/- 10 kJ mol(-l) . From these effective diffusivities and combined with published diffusion data for olivine single crystals, hydrogen diffusion in grain boundaries is extracted and yield diffusivities almost three order of magnitude faster (similar to 5 x 10(-6) m(2) s(-1) at 1200 degrees C) than in an olivine single crystal at the equivalent high temperature. On geological scales and for coarse-grain rocks, hydrogen diffusivity in grain boundaries is not fast enough to compete with lattice diffusion. The relative large grain size of mantle rocks will ensure a very limited hydrogen transport by effective diffusion, and a good conservation of water-rich zones in the Earth's mantle.
ISSN: 0012-821X

hal-00512821
https://hal.archives-ouvertes.fr/hal-00512821
DOI : 10.1016/j.epsl.2010.04.019

Éditeur(s) : HAL CCSD Geological society of London
Résumé : International audience
We present a synthesis of the tectonic and thermochronological evolution of the Eastern Tibet since the Triassic. The long-term cooling histories obtained on magmatic and metamorphic rocks of the South Songpan-Garze--, Kunlun and Yidun blocks are similar showing a very slow and regular cooling during Late Jurassic and Cretaceous, confirming the suspected lack of major tectonic events between c. 150 and 30 Ma. The exhumation linked to the Tertiary growth of the Tibetan Plateau initiated around 30 Ma and concentrates at the vicinity of the major tectonic structures. Exhumation rates increased again from about 7 Ma in the Longmen Shan. To interpret this very slow cooling rate between Late Jurassic and Early Cenozoic from granites of this area, we use a simple 1D thermal model that takes into account the thermal properties of both sediments and crust. The results suggest that: (1) high temperature (500 8C) can be kept over a long period of time; (2) during Cretaceous, cooling is mostly controlled by the thermal properties of sediments of continental origin; and (3) the initial Late Triassic rapid cooling rate was caused by the large thermal contrast between the granite body and the sedimentary rocks rather than by a high exhumation rate.
Growth and Collapse of the Tibetan Plateau

insu-00610491
https://hal-insu.archives-ouvertes.fr/insu-00610491
DOI : 10.1144/SP353.2

Éditeur(s) : HAL CCSD Springer-Verlag
Résumé : International audience
High-resolution borehole strainmeters are usually installed in tectonically active regions in order to detect slow-slip events, and to estimate slow transients related to earthquake swarms. However, they are also sensitive to other numerous influences, internal or external. Furthermore, the quality of their coupling to the rock through cementation, and the mechanical properties of the rock mass around them, have a critical influence on their records. Many of the existing strainmeters present such problems, and the correction for these effects often remains a challenge. In this paper, we present the analysis of the records of a high-resolution borehole dilatometer (Sacks–Evertson), located in the seismically active rift of Corinth (Greece) (station TRZ in the Trizonia island). We show that the instrument suffers from an only partial-solid coupling, and that the nearby sea tides have a direct (through elastic response) and indirect (through pore-pressure diffusion) effect on the dilatation signal, which adds up to the solid tidal strain source. We propose a methodology that allows, in a first step, to better separate the internal (solid tide) from the external (air pressure, sea level) influences, by calculating a frequency-dependent transfer function outside the range of the tidal periods. We then extrapolate this function, in particular at the tidal periods. In a second step, the resulting variation with frequency of the coupling coefficients with sea level led us to estimate the proportion of instrument not solidly cemented to rock (thus in contact with water pore pressure), which is about 90 % of the total height. Despite the small proportion of solid coupling, the sensor resolution remains very good up to a few tens of hours of a time period, thanks to the confining effects of the rocks on the local pore pressure. These results allow us to correct for the external effects, and reduce the associated variance by 80–90 % (in the period range of minutes to days). The empirical correction of the sea level effect could be explained using a simple Boussinesq’s approximation and 1D pore-pressure diffusion model, which contributed to better constraint of some of the poro-elastic parameters in the vicinity of the instrument. After correction, the solid tidal signal at the 24-h period is almost anti-correlated with those of the theoretical solid tide. This surprising result is consistent with a similar anti-correlation observed for the longest period surface waves (200 s) comparing the TRZ dilatometer signals to the strain measured by a nearby borehole strainmeter (MOK, 15 km). This could be related to the presence of a shallow fault close to the instrument, which would creep in response to seismic wave-related stress.
ISSN: 0033-4533

hal-01122853
https://hal.archives-ouvertes.fr/hal-01122853
DOI : 10.1007/s00024-013-0742-2

Éditeur(s) : HAL CCSD
Résumé : The Restefond fault, located in the Late Eocene-Early Oligocene Alpine foreland basin, affects the well lithified and low porosity Grès d'Annot. The fault core zone is characterized by the occurrence of highly deformed sandstone lenses. Deformation inside the lenses corresponds to mm to sub-mm-spaced cleavage planes rich in phyllosilicates and up to cm-thick and dm-long quartz-calcite pure extensional veins. The cleavages are mostly composed of newly-formed synkinematic white mica and chlorite. By using thermodynamic thermometers based on the chemical composition of chlorite, a temperature of 200 ± 20 °C of fault activity was computed. This temperature shows that the Restefond fault was active at burial conditions comprised between 6.5 and 8 km, assuming a mean geothermal gradient between 25 and 30 °Ckm−1. The petrophysic properties of sandstones from the core zone and in the hanging and foot wall of the fault were determined on drilled plugs following three spacial directions. The permeability of the highly deformed sandstone from the core zone is about one order of magnitude higher than in the host rock. This increase in permeability occurs in the direction parallel to the S-C structures and is explained by the occurrence of well-connected micropores localized between platy phyllosilicates. This study shows that the fault petrophysic properties are mostly controlled by the precipitation of synkinematic phyllosilicates under deep burial conditions.
Swiss Journal of Geosciences

hal-00795551
https://hal.archives-ouvertes.fr/hal-00795551
DOI : 10.1007/s00015-012-0099-z

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Anisotropy of low-field magnetic susceptibility (AMS) of basaltic lava flows can give some clues about post-emplacement tilting occurring in volcanic sequences. Such a study has been carried out on a sequence of 19 successive lava flows from Kerguelen Archipelago. Surprisingly, two different patterns were observed. The first one - herein called normal fabric - is consistent with the lava-flow direction inferred from geological observations, whereas the second one observed for about 70 per cent of the analysed samples - herein called abnormal fabric - appears to be unrelated to the shear history of the lava flows during their emplacements. These abnormal fabrics are not strictly inverse fabric but seem to have a more complex origin. The unusual nature of these abnormal fabrics has been confirmed by lattice preferred orientation of plagioclases obtained from high-resolution electron backscattered diffraction measurements. The aim of this study is to propose a physical interpretation of these fabrics. A first step in our understanding was to clearly identify the nature and the magnetic properties of the Fe-Ti oxides assemblage. Thus, we present a comprehensive rock magnetic analysis relying on low- and high-temperature thermomagnetic curves (K-T), crossover diagrams, first-order reversal curves, ore-microscopy, Mössbauer measurements and electron backscattered images. We found that in the present case the abnormal fabrics are probably linked to a mixture of prevailing single domain (SD) strongly interacting grains population and a subsidiary multidomain grains population. SD grains are identified as small magnetite crystallized within the interstitial glass in globular aggregates along the silicate framework. Then a question arises: to what extent such SD interacting grains in globular aggregates can affect the magnetic susceptibility and its anisotropy? To answer this question, we developed a physical model in which the total energy density of an SD grain with an uniaxial anisotropy is minimized. In this model, the distribution function of the direction of the magnetic interaction field is comprised between two boundary states. It is either isotropic, which formally corresponds to the thermal demagnetized state, or it is ordered, which formally corresponds to the Alternative Field demagnetized state. We show that in both cases the degree of anisotropy decreases as the interaction field increases. Thus, we conclude that the abnormal fabric encountered in this study can be simply explained by strong magnetostatic interactions that would explain the large scattering of AMS often observed in basaltic lava flows.
ISSN: 0956-540X

hal-00716449
https://hal.archives-ouvertes.fr/hal-00716449
https://hal.archives-ouvertes.fr/hal-00716449/document
https://hal.archives-ouvertes.fr/hal-00716449/file/gji-S-12-HAL.pdf
DOI : 10.1111/J.1365-246X.2012.05421.X

Éditeur(s) : HAL CCSD European Geosciences Union
Résumé : International audience
We calculated the seismic properties of 47 mantle xenoliths from 9 kimberlitic pipes in the Kaapvaal craton based on their modal composition, the crystal-preferred orientations (CPO) of olivine, ortho- and clinopyroxene, and garnet, the Fe content of olivine, and the pressures and temperatures at which the rocks were equilibrated. These data allow constraining the variation of seismic anisotropy and velocities within the cratonic mantle. The fastest P and S2 wave propagation directions and the polarization of fast split shear waves (S1) are always subparallel to olivine [100] axes of maximum concentration, which marks the lineation (fossil flow direction). Seismic anisotropy is higher for high olivine contents and stronger CPO. Maximum P wave azimuthal anisotropy (AVp) ranges between 2.5 and 10.2% and the maximum S wave polarization anisotropy (AVs), between 2.7 and 8%. Changes in olivine CPO symmetry result in minor variations in the seismic anisotropy patterns, mainly in the apparent isotropy directions for shear wave splitting. Seismic properties averaged over 20 km-thick depth sections are, therefore, very homogeneous. Based on these data, we predict the anisotropy that would be measured by SKS, Rayleigh (SV) and Love (SH) waves for five endmember orientations of the foliation and lineation. Comparison to seismic anisotropy data from the Kaapvaal shows that the coherent fast directions, but low delay times imaged by SKS studies, and the low azimuthal anisotropy with with the horizontally polarized S waves (SH) faster than the vertically polarized S wave (SV) measured using surface waves are best explained by homogeneously dipping (45°) foliations and lineations in the cratonic mantle lithosphere. Laterally or vertically varying foliation and lineation orientations with a dominantly NW-SE trend might also explain the low measured anisotropies, but this model should also result in backazimuthal variability of the SKS splitting data, not reported in the seismological data. The strong compositional heterogeneity of the Kaapvaal peridotite xenoliths results in up to 3% variation in density and in up to 2.3% variation of Vp, Vs, and Vp / Vs ratio. Fe depletion by melt extraction increases Vp and Vs, but decreases the Vp / Vs ratio and density. Orthopyroxene enrichment due to metasomatism decreases the density and Vp, strongly reducing the Vp / Vs ratio. Garnet enrichment, which was also attributed to metasomatism, increases the density, and in a lesser extent Vp and the Vp / Vs ratio. Comparison of density and seismic velocity profiles calculated using the xenoliths' compositions and equilibration conditions to seismological data in the Kaapvaal highlights that (i) the thickness of the craton is underestimated in some seismic studies and reaches at least 180 km, (ii) the deep sheared peridotites represent very local modifications caused and oversampled by kimberlites, and (iii) seismological models probably underestimate the compositional heterogeneity in the Kaapvaal mantle root, which occurs at a scale much smaller than the one that may be sampled seismologically.
ISSN: 1869-9510

hal-01053516
https://hal.archives-ouvertes.fr/hal-01053516
DOI : 10.5194/se-5-45-2014

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The minerals constituting the Earth's upper mantle are nominally anhydrous silicates (NAMs). However they do contain hydrogen as a trace element, decorating point defects in their crystalline structure. Experimental petrology and mineralogy have quantified the maximum concentration under several compositional and thermodynamic conditions, but systematic studies on the hydrogen concentration in minerals from mantle-derived rocks have only recently been carried out. Here, we have compiled the distribution of hydrogen in upper mantle peridotite xenoliths, from which several conclusions can be drawn. NAMs from peridotite xenoliths contain a few ppm wt. H2O in their structure. From the current database, the hydrogen concentrations in olivine regularly increase with increasing depth. The amount of hydrogen in NAMs from peridotite xenoliths from subduction contexts is not higher than in other geological context for similar temperature and pressure conditions. The highest hydrogen concentrations is found in peridotitic olivines from cratonic mantle, and are likely due to the depth of origin. The increasing hydrogen concentration in olivine with increasing depth is likely controlled by the increase of H partitioning into olivine at the expense of orthopyroxene as imposed by a decrease in Al content in opx with depth. However, the sparse data could also indicate that the bulk hydrogen concentration slightly increases with depth > 150 km. In this case, it would suggest, locally (Udachnaya for example), a possible increase in water fugacity due to fluid saturation. Even if the most abundant mineral in mantle rocks is olivine, the bulk hydrogen concentration in peridotites is controlled by the amount of hydrogen stored in pyroxenes. However, hydrogen concentration in olivine remains crucial for consequences on physical properties such as rheology and electrical conductivity. Kinetics of hydrogen transport is reviewed and hydrous melt/fluid percolation appears necessary to homogenize the hydrogen distribution at km-scale. Sampling of natural rock specimens is currently biased (e.g., in favor of optically attractive samples) and needs improvement, which will be achieved by increasing sample diversity (all type of grain sizes, lithologies, geological settings) and size of rock samples, as well as advances in analytical techniques. Acquisition of high quality data will be achieved by studying the co-existing minerals in mantle specimens, exploring each sample by linear and mapping measurements, and using appropriate FTIR calibrations for polarized and unpolarized radiation.
ISSN: 0024-4937

hal-01306676
https://hal.archives-ouvertes.fr/hal-01306676
DOI : 10.1016/j.lithos.2015.11.012

Éditeur(s) : HAL CCSD
Résumé : In coastal carbonate aquifers submitted to a saline intrusion, water - rock interactions processes at the interface between freshwater and saltwater are a cause for heterogeneities development within the porous media. The dissolutions and precipitations induced by the mixing zone play a major role in the transport properties of the reservoir and so in the long term evolution of the saltwater intrusion. The characterization and the in situ observation of a current saline intrusion in the Llucmajor carbonate platform at the experimental site of Ses Sitjoles (South-Easth of Mallorca Island, Spain), allowed to study the temporal evolution of the saltwater intrusion and the biogeochemical processes active in the mixing zone. The influence of microstructure, characterized using X-Ray microtomography, on the petrophysical and flow properties was investigated in laboratory and flow-through experiments were also conducted to study the modifications of the microstructures when submitted to water - rock interactions processes. The mixing zone at the Ses Sitjoles site appears as quite thick and not very sensitive to climate and anthropic stress and is proved to be the locus of active microbiological activity. Laboratory studies highlight a strong control of the microporosity on transport processes and of pCO2 on water - rock interactions. The percolation experiments of slightly reactive waters reveal calcite dissolution together with a decrease in permeability due to a rearrangement of micro-grains within the microporous network.
Les processus d'interactions fluide-roche à l'interface eau douce-eau salée, dans les aquifères carbonatés côtiers soumis à une intrusion saline, sont une des causes du développement d'hétérogénéités dans la structure du milieu poreux. Les dissolutions et/ou précipitations engendrées par la présence de cette zone de mélange jouent un rôle déterminant pour les propriétés de transport du réservoir et donc l'évolution à long terme de l'intrusion d'eau salée. En prenant l'exemple de la plateforme carbonatée de Llucmajor au niveau du site expérimental de Ses Sitjoles (Sud-Est de Majorque, Espagne), un travail de caractérisation et d'observation in situ à moyen terme de l'intrusion saline actuelle de ce réservoir permet de décrire son évolution temporelle et les processus biogéochimiques actifs dans la zone de mélange. L'influence de la microstructure du milieu poreux, caractérisée par microtomographie RX, sur les propriétés pétrophysiques et hydrodynamiques est étudiée en laboratoire et des expériences de percolations d'eaux réactives (mélanges eau douce - eau salée et eau pure chargée en CO2) sont réalisées afin d'étudier les modifications de ces microstructures lorsqu'elles sont soumises à des interactions eau - roche. La zone de mélange eau douce - eau salée rencontrée au niveau du site de Ses Sitjoles est large et peu sensible aux contraintes extérieures (climatologiques et anthropiques) et constitue un lieu d'activité microbiologique particulièrement actif. En laboratoire, on observe un fort contrôle des phénomènes de transport par la microporosité et des processus d'interactions eau - roche par la pCO2. Dans le cas d'une percolation de fluides moyennement réactifs, les expériences mettent en évidence une dissolution de calcite accompagnée par une diminution de la perméabilité, liée à un réarrangement des micro-grains à l'intérieur du réseau microporeux.
https://tel.archives-ouvertes.fr/tel-00767152

tel-00767152
https://tel.archives-ouvertes.fr/tel-00767152
https://tel.archives-ouvertes.fr/tel-00767152/document
https://tel.archives-ouvertes.fr/tel-00767152/file/thesegaring.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In this paper we solve the Navier Stokes’ equation using finite difference method, on a simulated porous rock structure in 2-D, to study the velocity distribution of fluid flowing through it under a constant pressure gradient. A reactive solute carried through the fluid is allowed to interact with the minerals in the rock. Depending on the rock composition, both dissolution and precipitation reactions may occur. However precipitation occurs only through the cations that are released in the solution due to dissolution. These combined dissolution–precipitation reactions change the porosity, permeability and pore geometry of the sedimentary rock. We study the temporal changes of these properties as functions of Peclet number, concentration of the reactive solute and ratio of Damkholer numbers of dissolution to precipitation. The final flow property is decided by a combination of these parameters.
ISSN: 0022-1694

hal-01115291
https://hal.archives-ouvertes.fr/hal-01115291
DOI : 10.1016/j.jhydrol.2014.10.019

Éditeur(s) : HAL CCSD Geological Society of London
Résumé : This paper presents the background for the calculation of physical properties of an aggregate from constituent crystal properties and the texture of the aggregate in a coherent manner. Emphasis is placed on the important tensor properties of 2nd and 4th rank with applications in rock deformation, structural geology, geodynamics and geophysics. We cover texture information that comes from pole figure diffraction and single orientation measurements (electron backscattered diffraction or EBSD, electron channelling pattern, Laue pattern, optical microscope universal-stage). In particular, we provide explicit formulae for the calculation of the averaged tensor from individual orientations or from an orientation distribution function (ODF). For the latter we consider numerical integration and an approach based on the expansion into spherical harmonics. This paper also serves as a reference paper for the mathematical tensor capabilities of the texture analysis software MTEX, which is a comprehensive, freely available MatLab toolbox that covers a wide range of problems in quantitative texture analysis, for example, ODF modelling, pole figure to ODF inversion, EBSD data analysis and grain detection. MTEX offers a programming interface which allows the processing of involved research problems as well as highly customizable visualization capabilities; MTEX is therefore ideal for presentations, publications and teaching demonstrations.
Deformation Mechanisms, Rheology and Tectonics: Microstructures, Mechanics and Anisotropy

hal-00688833
https://hal.archives-ouvertes.fr/hal-00688833

Éditeur(s) : HAL CCSD Springer
Résumé : International audience
This contribution is an attempt to present a self-contained and comprehensive survey of the mathematics and physics of material behavior of rocks in terms of texture and anisotropy. Being generally multi-phase and poly-crystalline, where each single crystallite is anisotropic with respect to its physical properties, texture, i.e., the statistical and spatial distribution of crystallographic orientations becomes a constitutive characteristic and determines the material behavior except for grain boundary effects, i.e., in first order approximation. This chapter is in particular an account of modern mathematical texture analysis, explicitly clarifying terms, providing definitions and justifying their application, and emphasizing its major insights. Thus, mathematical texture analysis is brought back to the realm of spherical Radon and Fourier transforms, spherical approximation, spherical probability, i.e., to themathematics of spherical tomography
Handbook of Geomathematics

hal-00564939
https://hal.archives-ouvertes.fr/hal-00564939

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We conducted triaxial compression experiments to investigate the effects of pressure, temperature and strain rate on the rheology of talc rocks. The tests were carried out at T from 25 to 860 degrees C, P from 0.1 to 300 MPa, and <(epsilon) over dot> from 0.3 to 30 x 10-5 s(-1). In addition to being very weak, there are other important differences between the mechanical behavior of talc and that of most other silicates. Deformation at all temperatures up to dehydration was accommodated by a combination of crystal plasticity, frictional sliding, and cataclasis. A transition from localized to distributed deformation occurred at P = 300 MPa and T = 400 degrees C, but this transition is ill-defined as both distributed and localized deformation were observed at P = 300 MPa and T = 600 degrees C. Unlike most silicates, both the coefficient of internal friction and the coefficient of (sliding) friction are very low and nearly equal to each other. Temperature enhances plastic deformation (kinking), and inter- and intra-granular microcracks are observed parallel to the (001) planes at all conditions. Voids are created by delamination along (001) planes at kink-band boundaries. Full crystal plasticity was not achieved under any of the conditions tested, i.e., the von Mises criterion was never satisfied. However, the strength of the aggregates remained much less than the confining pressure. These unusual properties are likely a manifestation of the pronounced mechanical anisotropy of talc at the grain scale. At T >= 750 degrees C dehydration is observed, but only along shear zones. These results suggest that feedbacks between deformation and reaction kinetics could control fluid flow in fault zones. The presence of talc can promote significant weakening and strain localization in the oceanic lithosphere, the subducting plate and the overlying mantle wedge. (c) 2008 Elsevier B.V. All rights reserved.
ISSN: 0012-821X

hal-00492706
https://hal.archives-ouvertes.fr/hal-00492706
DOI : 10.1016/j.epsl.2008.02.004

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Energy dissipation is observed on seismic data when a wave propagates through a porous medium, involving different frequency regimes depending on the nature of rock and fluid types. We focus here on the role of partial fluid saturation in unconsolidated porous media, looking in particular at P-wave phase velocity and attenuation. The study consists in running an experiment in a sand-filled tank partially saturated with water. Seismic propagation in the tank is generated in the kHz range by hitting a steel ball on a granite plate. Seismic data are recorded by buried accelerometers and injecting or extracting water controls the partial saturation. Several imbibition/drainage cycles were performed between the water and gas residual saturations. A Continuous Wavelet Transform applied on seismic records allowed us to extract the direct P-wave at each receiver.We observe an hysteresis in phase velocities and inverse quality factors between imbibition and drainage. Phase velocities and inverse quality factors are then jointly inverted to get a final poro-visco-elastic model of the partially saturated sand that satisfactorily reproduces the data. The model formulation consists in generalizing the Biot theory to effective properties of the fluid and medium (permeability and bulk modulus) in order to properly explain the phase velocity variation as a function of the saturation. The strong level of attenuation measured experimentally is further explained by an anelastic effect due to grain to grain sliding, adding to Biot's losses. This study shows that fluid distribution at microscopic scale has strong influence on the attenuation of direct P-waves at macroscopic scale and confirms that seismic prospection may be a powerful tool for the characterization of transport phenomena in porous media.
ISSN: 0956-540X

hal-00779920
https://hal.archives-ouvertes.fr/hal-00779920
https://hal.archives-ouvertes.fr/hal-00779920/document
https://hal.archives-ouvertes.fr/hal-00779920/file/Barriere_et_al_HAL.pdf
DOI : 10.1111/j.1365-246X.2012.05691.x

Éditeur(s) : HAL CCSD European Geosciences Union
Résumé : This study presents a unique database of 172 plagioclase Crystallographic Preferred Orientations (CPO) of variously deformed gabbroic rocks. The CPO characteristics as a function of the deformation regime (magmatic or crystal-plastic) are outlined and discussed. The studied samples are dominantly from slow- and fast-spread present-day ocean crust, as well as from the Oman ophiolite. Plagioclase is the dominant mineral phase in the studied samples. Plagioclase CPOs are grouped into three main categories: Axial-B, a strong point alignment of (010) with a girdle distribution of [100]; Axial-A, a strong point maximum concentration of [100] with parallel girdle distributions of (010) and (001); and P-type, point maxima of [100], (010), and (001). A majority of CPO patterns are Axial-B and P-type, in samples showing either magmatic or crystal-plastic deformation textures. Axial-A CPOs are less common; they represent 21% of the samples deformed by crystal-plastic flow. Although fabric strength (ODF J index) does not show any consistent variation as a function of the CPO patterns, there is a significant difference in the relationship between the ODF and pole figures J indices; the magmatic type microstructures have high (010) pole figures J indices, which increase linearly with ODF J index, whereas the high [100] pole figures J indices of plastically deformed samples vary in a more scattered manner with ODF J index. The multistage nature of plastic deformation superposed on a magmatic structure compared with magmatic flow, and the large number of possible slip-systems in plagioclase probably account for these differences. Calculated seismic properties (P wave and S wave velocities and anisotropies) of plagioclase aggregates show that anisotropy (up to 12% for P wave and 14% for S wave) tends to increase as a function of ODF J index. In comparison with the olivine 1998 CPO database, the magnitude of P wave anisotropy for a given J index is much less than olivine, whereas it is similar for S wave anisotropy. Despite a large variation of fabric patterns and geodynamic setting, seismic properties of plagioclase-rich rocks have similar magnitudes of anisotropy. There is a small difference in the aggregate elastic symmetry, with magmatic microstructures having higher orthorhombic and hexagonal components, whereas plastic deformation microstructures have a slightly higher monoclinic component, possibly correlated with predominant monoclinic simple shear flow in plastically deformed samples. Overall, plots for CPO strength (ODF J index), pole figure strength, CPO symmetry and seismic anisotropy show significant scattering. This could be related to sampling statistics, although our database is a factor of ten higher than the olivine database of 1998, or it could be related to the low symmetry (triclinic) structure of plagioclase resulting in the addition of degrees of freedom in the processes creating the CPOs.
ISSN: 1869-9510

hal-00963439
https://hal.archives-ouvertes.fr/hal-00963439
DOI : 10.5194/se-4-511-2013