Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Melt generation in the continental crust is thought to significantly influence seismic bulk velocities and anisotropy, although existing laboratory data provide limited constraints on such seismic attributes. In this study we measured ultrasonic compressional wave speeds (Vp) and anisotropy during sample compaction, mica-breakdown and melt-generation in synthetic, foliated quartz–muscovite aggregates. Measurements were performed at peak conditions of 300 MPa hydrostatic confining pressure and 750 °C, over a six hour time period, for three separate samples where wave propagation directions were aligned at 0°, 45° and 90° with respect to the foliation plane. The experiments are initially marked by sample compaction and rapid reduction in porosity (from 25% to <2 vol%), with a corresponding increase in Vp. During initial stages of the experiment Vp ranges from 4.65 to 5.45 km/s, depending on the direction of the P wave propagation, resulting in up to ∼16% anisotropy, which originates mainly from the preferred orientation of muscovite and possible incipient melt lenses oriented parallel to foliation. As the experiment progresses the bulk Vp decreases gradually and Vp anisotropy drops from ∼16% to ∼2% after five hours into the experiment. The drop in anisotropy is caused by muscovite-breakdown and increasing amount of partial melting of the aggregate. The bulk velocities are considerably lower than predicted for a mixture of muscovite and β-quartz (stable at 300 MPa and 750 °C). Thermodynamic modeling indicates that mica breakdown and production of melt with ∼2 wt% dissolved water in the aggregate can explain the low Vp, even though β-quartz is stable; the modeled Vp is ∼4.75 km/s at 300 MPa and 750 °C. These ultrasonic attributes signify movement of the melt to fill vacant pores and coating grain boundaries, effectively connecting melt films and reducing seismic anisotropy. The results may apply to regions where crustal melting is on-going, in particular regions of elevated temperature that are only weakly deforming, with coupled anomalously low bulk velocities and seismic anisotropy.
ISSN: 0012-821X

hal-01243569
https://hal.archives-ouvertes.fr/hal-01243569
DOI : 10.1016/j.epsl.2015.05.039

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
We analyse the fluid flow regime within sediments on the Eastern levee of the modern Mississippi Canyon using 3D seismic data and downhole logging data acquired at Sites U1322 and U1324 during the 2005 Integrated Ocean Drilling Program (IODP) Expedition 308 in the Gulf of Mexico. Sulphate and methane concentrations in pore water show that sulphate-methane transition zone, at 74 and 94 m below seafloor, are amongst the deepest ever found in a sedimentary basin. This is in part due to a basinward fluid flow in a buried turbiditic channel (Blue Unit, 1000 mbsf), which separates sedimentary compartments located below and above this unit, preventing normal upward methane flux to the seafloor. Overpressure in the lower compartment leads to episodic and focused fluid migration through deep conduits that bypass the upper compartment, forming mud volcanoes at the seabed. This may also favour seawater circulation and we interpret the deep sulphate-methane transition zones as a result of high downward sulphate fluxes coming from seawater that are about 5-10 times above those measured in other basins. The results show that geochemical reactions within shallow sediments are dominated by seawater downwelling in the Mars-Ursa basin, compared to other basins in which the upward fluid flux is controlling methane-related reactions. This has implications for the occurrence of gas hydrates in the subsurface and is evidence of the active connection between buried sediments and the water column.
ISSN: 1468-8115

hal-00590501
https://hal.archives-ouvertes.fr/hal-00590501
DOI : 10.1111/j.1468-8123.2010.00304.x

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Mesoporous cobalt oxide silica matrices and membranes were successfully prepared using a dual acid-base catalysed sol-gel and interlayer-free approach for desalination applications. The effects of cobalt addition (0-35 mol%) on the structure-property relationship of the silica materials and membrane performance were systematically studied as a function of feed salt concentration (0.3-7.5 wt.% NaCl) and temperature (22-60 °C). As cobalt concentration increases beyond 5 mol%, the concentration of tricobalt tetroxide and proportion of silica mesopores were found to increase within the matrices. Silica membranes with high amount of tricobalt tetroxide (35 mol%) were found to be highly mesoporous with water fluxes of 20, 11.3 and 7.7 kg m-2 h-1 for the 0.3, 3.5 and 7.5 wt.% solutions at 60 °C, respectively, with >99.7% salt rejection at all times. This is attributed to the high pore volume (mesopores formation) and structural robustness of the silica network provided by the presence of tricobalt tetroxide. Even higher performance was achieved for low tricobalt tetroxide (mol%) silica membranes with water fluxes of 47.6 (0.3 wt.%) and 31.5 (3.5 wt.%) kg m-2 h-1 at 60 °C, respectively, though with reduced salt rejections of 90%. © 2015 Elsevier B.V.
ISSN: 0011-9164

hal-01683209
https://hal.univ-antilles.fr/hal-01683209
DOI : 10.1016/j.desal.2015.02.034

Éditeur(s) : HAL CCSD
Résumé : International audience
Energy is a critical enabler. In tropical countries, access to modern electricity is vital to reducing poverty and improving health, increasing productivity and promoting economic growth. However, the International Energy Agency reported in 2015 more than 1.2 billion people still did not have access to electricity in 2013, around 80% of them live in developing and tropical countries. Then, the same agency report also in 2016 around 6.5 million premature deaths each year can be attributed to air pollution. Therefore, it is time to support appropriate renewable energy developments, particularly the river hydrokinetic developments seems to be a better solution in tropics because of large and powerful rivers in these areas.In French Guiana, 35% of the inland populations are still not connected to the electrical grid (Région Guyane, 2012). This could be ascribed to the fact that extending grid wires hundreds of kilometers through difficult terrain and thick jungles just to serve a small remote village is economically unviable initiative (Ajan et al., 2003; Anyi et al., 2010). As an alternative, French Guiana and most of the tropical countries resort to diesel-powered generators which requires significant imports of expensive fuel, difficult to bring into remote areas (Région Guyane, 2012).This works proposes guidelines to estimate river hydrokinetic fluxes in the vicinity of remote communities in tropics. The method is applied to identify and characterise potential sites along an important reach of the Maroni river in French Guiana. First, a novel method to carry out river terrain elevation model is presented and some results about the Maroni river are reported. It begins from how to conduct ADCP survey, which corrections on them should be made and ends up by interpolating bathymetry over curvilinear profiles which handle the flow lines. That approach involves how mutli-source data (sparse ADCP-cross profiles, incomplete LiDAR tiles and hydroligic data) are merged and combined to estimate local cross section shape, maximum water depth and carry out cross profile in ungauged sites.This is followed by a deep characterisation about time-evolution of hydrokinetic fluxes field in the areas of interest by implementation of a full 2D hydrodynamic model (TELEMAC2D) over an important reach of the Maroni river. To optimise computational cost, river sections outside the areas of interest are modelled as a porous media where only the flows variables up and down stream must fulfil the field data.
CAS
Deshaies, Guadeloupe

hal-01514240
https://hal.archives-ouvertes.fr/hal-01514240

Résumé : Le fluide chaud produit par les forages de la centrale géothermique de Bouillante (Guadeloupe) est enrichi en espèces dissoutes telles que la silice qui peuvent précipiter sous forme de dépôts solides lors de son refroidissement et gêner fortement la production électrique. L’un des principaux objectifs de ce travail de thèse a donc été d’améliorer l’état des connaissances sur les conditions physiques, chimiques et cinétiques de la précipitation de la silice amorphe à Bouillante. Après une étude des caractéristiques physico-chimiques des fluides et des dépôts associés au champ de Bouillante, des expériences sur la cinétique de précipitation de la silice, sur site, pour une large gamme de température (25 - 90°C) et de pH (4 - 12) ont été menées et analysées en détail.Pour l’ensemble de ces expériences, seule la polymérisation (réversible) de la silice dissoute, sous forme de suspensions colloïdales très stables en solution, a été observée. La modélisation des données expérimentales de cinétique montre que la vitesse de polymérisation de la silice suit une loi d’ordre 2 vis-à-vis de la silice dissoute jusqu’à l’équilibre en accord avec une dimérisation de la silice. Par contre, durant l’étape initiale de la réaction, une loi d’ordre 4 semble mieux adaptée, suggérant des réactions de polymérisation plus complexes avec formation de tétramères. La température a un effet limité sur la cinétique de polymérisation de la silice comparé à l’effet du pH qui est beaucoup plus important. L’énergie d’activation de la réaction globale est de 41 - 54 kJ pour des pH compris entre 5 et 8.La caractérisation de la silice précipitée a mis en évidence des différences notables entre la structure poreuse de la silice solide prélevée sur les installations de surface et celle de la silice colloïdale obtenue par polymérisation lors des expériences de cinétique, ce qui semble indiquer que des mécanismes différents interviennent dans ces deux contextes de précipitation de la silice dissoute.Le deuxième objectif de cette thèse était d’évaluer la possibilité de valoriser la silice extraite de l’eau géothermale de Bouillante dans un procédé de traitement des eaux naturelles par adsorption. Pour cela, les propriétés d’adsorption de la silice géothermale brute et fonctionnalisée par le poly(ethylèneimine) (ou PEI) ont été étudiées pour deux polluants : un colorant, le bleu de méthylène et un métal lourd, le plomb. Les résultats obtenus montrent que la silice brute possède une grande capacité d’adsorption vis-à-vis du bleu de méthylène. En outre, la fonctionnalisation de la silice par le PEI permet d’améliorer sa capacité d’adsorption vis-à-vis du plomb en solution, en accord avec un modèle cinétique du pseudo-second ordre suggérant une chimisorption. Le modèle d’isotherme de Redlich-Peterson est également en très bon accord avec les données expérimentales.
The hot geothermal fluid produced by the geothermal power plant of Bouillante (Guadeloupe) contains various dissolved components such as silica that can precipitate as solid deposits during their cooling and cause serious problems on the electricity generation. One of the aim of this study is to improve the understanding on the physical, chemical and kinetics conditions of the amorphous silica precipitation in the Bouillante geothermal field. After a study on the physical and chemical characteristics of the Bouillante fluids and deposits which can form during their exploitation, experiments on the kinetics of silica precipitation, on site, under a large range of temperature (25 – 90°C) and pH (4 – 12) have been carried out and analyzed in detail.During on site kinetics experimentations only dissolved silica polymerization (reversible) as colloidal gel, very stable in solution, was observed. Modeling of the experimental data showed that the kinetics polymerization is characterized by a 2-order kinetic law relative to dissolved silica until the equilibrium that is consistent with silica dimerization. On the other side, the initial stage of the reaction is better characterized by a 4-order kinetic law that suggested more complex polymerization reactions with tetramers formation.Temperature has a little effect on the polymerization kinetics compared with the pH which has an effect more important. The activation energy of silica precipitation calculated between 25 and 90°C, is about 41 - 54 kJ for pH ranging to 5 - 8.The characterization of the silica precipitate reveals significant differences in the porous structure of the silica collected on the surface installations and the one obtained from kinetic experiments that suggests different precipitation mechanisms. The second objective of this thesis was to evaluate the possibility to promote geothermal silica for the treatment of natural waters containing contaminants by adsorption. Adsorption properties of the untreated and functionalized by poly(ethylèneimine) (ou PEI) geothermal silica have been investigated for two pollutants: a colorant, the methylene blue and a heavy metal, the lead.Results showed that untreated silica has a great adsorption capacity concerning the methylene blue. Besides, silica functionalization by the PEI allows improving the adsorption capacity for lead in solution. The adsorption kinetics curves followed a pseudo-second order model consistent with a chimisorption. The isotherm model of Redlich-Peterson fitted well the experimental data.

http://www.theses.fr/2014AGUY0698/document

Éditeur(s) : HAL CCSD
Résumé : Manque : organisateur de la manifestation - éléments/proceedings
With the new data on bathymetry, currentology, in this ecosystem and the abiotic variables studied from February to May 2007, a review of the Manche-à-Eau’s biological zonation recently stated from the fishassemblage is proposed. The water volume turnover at each tide (14,8%) twice a day combined with an active and various hydrodynamism contribute to vivify the lagoon andprovide information for a better interpretation of the Well-Being Index values and the populational parameters gradients of the fish assemblage. During the studied period, no gradient is observed with the abiotic variables. The water characteristics are homogene-ous verywhere in the lagoon, in the water column and whatever the period studied (temperature: 30,02°C; salinity: 36,16 ‰; pH:8,29; turbidity: 6,10 mg/L; conductivity: 5,51S/m; dissolved oxygen: 7,18mg/L; dissolved solids: 32,78g/Ll; osmolarity:1021,7milliosmoles). A revised biological zonation of the Manche-à-Eau lagoon is pro-posed. According to the quality observed, it is made of three zones, instead four, from II to IV: the zone II is more spread at South and narrow along the island, the zone III occupies the geater part of the ecosystem and the zone IV centered on the two main depressions at South and West, on the shallows and its North-West border and the end of the sector enclaved at South-West.
Con los nuevos datos sobre batimetría y la corrientología en este ecosistema y las variables abióticas estudiadas de febrero a mayo del 2007, se propone una revisión de la zonación biológica recientemente establecida en cuanto a la agrupación de peces del Manche-à-Eau. El volumen de agua renovada dos veces al día en cada marea (14.8%) combinado a un hidrodinamismo activo y variado contribuyen a verificar la laguna, y aportan elementos para una mejor interpretación de los valores de los índices de buen estado y de los diferentes parámetros poblacionales de la ictiofáuna presente. Durante el período estudiado no se observó ningúngradiente con los parámetros abióticos. Las características del agua son homogéneas a lo largo de toda la laguna. En la columna de agua en cualquiera de los períodos considerados (temperatura: 30,02°C; salinidad: 36,16 ‰; pH: 8,29; turbidez: 6,10 mg/L;conductividad: 5,51 S/m; oxígeno disuelto: 7,18 mg/L; sólidos disueltos: 32,78g/L; osmolaridad: 1021,7miliosmoles). Se propone una zonación biológica rectificada. De acuerdo a la calidad observada, esta, está compuesta por tres zonas en lugar de cuatro: de II a IV, la zona II está mas dispersa al sur y es mas estrecha a lo largo de la isla, la zona III domina la mayor parte del ecosistema y lazona IV está centrada en las dos principales depresiones al sur y al oeste, las zonas someras y en su borde al noroeste al igual que del sector enclavado al suroeste.
Avec les nouvelles données sur la bathymétrie et la courantologie de cet écosystème et les paramètres physicochimiques étudiés entre février et mai 2007, c’est une actualisation de la zonation biologique établie récemment à partir de l’assemblage de poissons y séjournant qui est proposée dans cette étude. En effet, le volume d’eau renouvelé deux fois par jour à chaque marée (14,8%) combiné à un hydrodynamisme actif et varié contribuent à vivifier la lagune, et apportent des éléments pour une meilleure interprétation des valeurs des indices de bien-être et des gradients des paramètres populationnels de l’ichtyofaune présente. Durant la période étudiée, aucun gradient n’est observé avec les paramètres abiotiques. La caractéristique des eaux est homogène partout dans la lagune, sa colonne d’eau et aux différentes périodes considérées (température : 30,02°C ; salinité : 36,16 ‰ ; pH : 8,29 ; turbidité : 6,10 mg/L ; conductivité : 5,51 S/m ; oxygène dissous : 7,18 mg/L ; solides dissous : 32,78g/L ; osmolarité : 1021,7milliosmoles). Une zonation biologique rectifiée est proposée. Plus conforme à la qualité observée, elle est composée de trois zones, au lieu de quatre, allant de II à IV: la zone II un peu plus étendue au Sud et plus étroite le long de l’île, une zone III dominante sur l’ensemble de la lagune, et une zone IV centrée sur les deux principales dépressions au Sud et à l’Ouest, le haut-fond et sa bordure au Nord-Ouest ainsi que le fond du secteur enclavé au Sud-Ouest.
Proceedings of the 61st Gulf and Caribbean Fisheries Institute
Le Gosier, Guadeloupe, France

hal-01600920
https://hal.archives-ouvertes.fr/hal-01600920
PRODINRA : 384820

Éditeur(s) : Elsevier
Résumé : Shrimp farming is a small but growing industry in New Caledonia. Since 1993, "Syndrome 93" has been affecting New Caledonian shrimp farming industry every cold season, causing severe epizootic mortalities in grow-out ponds and significant losses. Highly pathogenic strains of Vibrio penaeicida are considered the etiological agent of the disease in Litopenaeus stylirostris. On one hand, studies demonstrated that healthy shrimp may carry V penaeicida for weeks with a high overall prevalence, regardless of any seasonal pattern or temperature conditions. On the other hand, larvae are free of V penaeicida and are also resistant to experimental infection. V penaeicida is frequently detected in incoming water pumped from the bays, which was shown, by a molecular typing study, to be the infectious source. This particular epidemiological pattern highlights the major role of the factors that trigger and aggravate the disease in grow-out ponds, where shrimp populations carry the pathogen all year round. In order to gain a better understanding of "Syndrome 93" epidemiology, quantification of V penaeicida both in shrimp and the shrimp farm ecosystem is necessary. This article describes the steps in the successful development of a real-time PCR quantification assay of V penaeicida in shrimp haemolymph, seawater (from ponds or bays) and sediment pore water, including the choice of an accurate extraction technique. The entire detection method; including sample processing, DNA extraction and real-time PCR amplification, can be completed within 4 h. (c) 2006 Elsevier B.V All rights reserved.
Journal of Microbiological Methods (0167-7012) (Elsevier), 2006-10 , Vol. 67 , N. 1 , P. 27-35

Droits : 2006 Elsevier
http://archimer.ifremer.fr/doc/2006/publication-1903.pdf
DOI:10.1016/j.mimet.2006.02.013
http://archimer.ifremer.fr/doc/00000/1903/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This work shows the preparation and separation performance assessment of carbon membranes derived from phenolic resin by a vacuum-assisted method and carbonisation in an inert atmosphere. The vacuum time played an important role in tailoring the structure of the membranes. For instance, pore volumes and surface areas increased from 0.81 and 834 to 2.2 cm3g−1and 1910 m2g−1, respectively, as the vacuum time exposure increased from 0 to 1200 s. The significant structural changes correlated very well with water permeation, as fluxes increased by 91% as the vacuum time increased from 0 to 1200 s reaching up to 169 L m−2h−1at 5 bar. Molecular weight cut-off tests showed no rejection for the smaller glucose and sucrose molecules, though this increased to ~ 80% and full rejection for 36 kDa and 400 kDa polyvinyl pyrrolidine. Interestingly, FTIR spectra showed that the peaks of C–H stretching vibration (2800–3200 cm−1) and C–O stretching (1030 cm−1) became more pronounced as a function of increasing vacuum time, strongly suggesting that the use of vacuum further assisted in the polycondensation of phenolic oligomers. Based on these outcomes, a cluster to cluster model is proposed, whereby vacuum application promoted crosslinking reactions of the phenolic resin, creating microporous regions within the clusters, and mesoporous regions between the clusters. © 2016 Elsevier B.V
ISSN: 0376-7388

hal-01683220
https://hal.univ-antilles.fr/hal-01683220
DOI : 10.1016/j.memsci.2016.11.002

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Abstract This work shows the preparation, characterisation and testing of TiO2 membranes dip-coated on commercial α-Al2O3 tubes for desalination. TiO2 thin films (∼400 nm) were synthesised from titanium propoxide and exposed to a gentle thermal treatment to control particle and pore sizes (dp ∼ 4 nm). The TiO2 membranes were tested for brackish (0.3 wt%), sea water (3.5 wt%) and brine concentrations (7.5 and 10 wt%) up to 75°C in a pervaporation setup. Water fluxes as high as 10.5 kg m-2 h-1 were achieved for brackish concentrations, whilst values of up to 4.0 and 6.0 kg m-2 h-1 were measured for the highest brine concentration (10 wt%). Concentration and temperature polarisation both affected the water fluxes, particularly for brine solutions, though the latter was more dominant. Salt rejection remained very high at ∼99% for all tested conditions, thus demonstrating the feasibility of mesoporous inorganic TiO2 structures for desalination and brine processing. The TiO2 membranes proved to be stable for long term (>350 h) testing even under thermal cycling conditions. © 2015 Elsevier B.V. All rights reserved.
ISSN: 1383-5866

hal-01683212
https://hal.univ-antilles.fr/hal-01683212
DOI : 10.1016/j.seppur.2015.04.028

Éditeur(s) : HAL CCSD Elsevier
Résumé : Among the radionuclides that can migrate from radioactive wastes buried within consolidated argillaceous rocks, I-129 poses a particular problem due to its high mobility in geomedia and its very long half-life of 1.6 10(7) years. Previous studies carried out on such rocks showed the existence of a low iodide retardation regarding the other anion species. The purpose of the present study was two-fold. It was hoped (1) to confirm this retardation by means of radial diffusion experiments and (2) to estimate the influence of the initial iodide concentrations towards the iodide uptake. The results obtained from in-diffusion stage show that (1) no iodide uptake occurs at high initial concentrations and (2) an uptake at low initial concentrations cannot be clearly evidenced. Finally. the most singular behaviour of iodide was highlighted for all the initial iodide concentrations, from the out-diffusion stage. during which some amount of iodide, available for out-diffusion, were not involved in the diffusion process. Although the origin of such phenomenon remains unclear, a kinetic effect for the iodide uptake was proposed, assuming that the period of 55days (corresponding to the in-diffusion stage duration) would be necessary for inducing the iodide uptake. This kinetic effect, already shown elsewhere by (Descostes. M., Blin, V., Bazer-Bachi, F., Meier, P., Grenut, B., Radwan. J., Schlegel, M.L., Buschaert, S.. Coelho, D, Tevissen, E. Diffusion of anionic species in Callovo-Oxfordian argillites and Oxfordian limestones. In press for Appl. Geochem.) on similar materials, needs to be deepened.
ISSN: 0079-1946

hal-00412393
https://hal.archives-ouvertes.fr/hal-00412393
DOI : 10.1016/j.pce.2008.05.020

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
We aim at testing and validating a mobile-immobile mass transfer model from a set of single-well injection withdrawal tracer tests in a heterogeneous porous aquifer. By varying the duration of the injection phase, different volumes of aquifer are investigated by the tracer. Hence, we focus the transport model validation not only on reproducing a single breakthrough curve (BTC) but also on the model's capacity to predict the amount of mixing as a function of the volume visited by the tracer. All the BTCs are strongly asymmetric, as expected when dispersion is controlled by diffusive mass transfers between the mobile water and the immobile water part of the porosity. However, the BTC cannot be modeled by a conventional mobile-immobile mass transfer model with a simple power law memory function. To account for that, we implement a continuous time random walk model in which the transition time distribution y (t), which is related to the excursion time probability of the tracer in the immobile domain, is a dual-slope power law distribution. The model best fits the BTC data set with a transitional regime controlled by y(t) t2 and an asymptotic regime characteristic of the conventional double-porosity model with y(t) t1.5 . This work emphasizes that high-resolution concentration measurement and multiple-scale tracer tests are required for assessing solute dispersion models in heterogeneous reservoirs and for subsequently obtaining reliable predictions.
ISSN: 0043-1397

insu-00373698
https://hal-insu.archives-ouvertes.fr/insu-00373698
https://hal-insu.archives-ouvertes.fr/insu-00373698/document
https://hal-insu.archives-ouvertes.fr/insu-00373698/file/Borgne_et_al-2008-Water_Resources_Research.pdf
DOI : 10.1029/2007WR006279

Éditeur(s) : Université des Antilles Études caribéennes
Résumé : El Caribe colombiano ha experimentado un acelerado proceso de urbanización y desarrollo turístico en los últimos 50 años. Solo en una ciudad como Cartagena de Indias (la ciudad turística por excelencia de Colombia), datos referidos al periodo noviembre 2009 – enero 2015, mostraron un incremento en la llegada de turistas cercano al 20%. Después de un gran número de encuestas realizadas alrededor del mundo, se encontró que los parámetros en que se basan los turistas a la hora de preferir una playa son: i) la seguridad, ii) el paisaje, iii) calidad del agua, iv) basuras, v) instalaciones. El paisaje es uno de los recursos costeros y por lo tanto su evaluación es una herramienta importante para los gestores y planificadores del litoral a la hora de la realización de planes de conservación, protección, desarrollo y manejo. Este trabajo se basa en la evaluación del valor paisajístico de las playas que constituyen la base de la economía de muchas ciudades costeras en el mundo y en especial de la zona central de litoral Caribe colombiano. Un problema importante en la evaluación del paisaje es la incapacidad de algunas metodologías de reflejar correctamente las percepciones de la gente, debido al alto peso que tienen algunos aspectos subjetivos (p. ej. altura de una geoforma).En este trabajo se presenta la evaluación del paisaje realizada para la zona central de Caribe colombiano (37 playas de los departamentos de Sucre, Bolívar y Atlántico) utilizando la lógica matemática y matrices ponderadas (fuzzy logic mathematics - parameter weighting matrices) las cuales permiten disminuir la subjetividad y cuantificar con exactitud la incertidumbre. Para la evaluación se utilizó una lista de chequeo que está conformada por 26 parámetros, 18 físicos (acantilados, playas, plataformas rocosas, dunas, características de los valles, forma del relieve, mareas, paisaje costero, color del agua y restos de vegetación), y 8 antropogénicos (ruido, basura, descarga de aguas residuales, grado de modificación y de construcción del medio, tipos de acceso, línea del horizonte y estructuras antrópicas). Los parámetros fueron calificados en una escala de 1 a 5 (presencia/ausencia o poca/alta calidad) y, con el fin de cuantificar la incertidumbre y excesos derivados de la subjetividad que pudo haber tenido la evaluación de los parámetros, se utilizó la lógica difusa (fuzzy logic). A la par, un sistema de matrices, se empleó para asignar valores de peso de acuerdo a las preferencias y prioridades de los usuarios. Como resultado de estos análisis lógico-estadísticos se obtuvo un valor (D) el cual resume la evaluación del paisaje en 5 clases que van desde la CLASE 1 (zona litoral sumamente atractiva) hasta la CLASE 5 (playas urbanas muy poco atractivas). De los 37 sectores estudiados, ninguno puede ser considerado como una zona litoral sumamente atractiva, mientras que 15 corresponden a zonas litorales urbanas poco atractivas, el resto de las playas (22) se ubicó entre las clases 2, 3 y 4. Los resultados obtenidos son útiles para los gestores costeros en la medida que, aunque no es posible mejorar los aspectos naturales de la clasificación, si es posible mejorar muchos de los parámetros antropogenicos y, de esta forma, hacer que una playa mejore su clasificación y sea paisajísticamente más atractiva.
In the past few years, the Colombian Caribbean coast has experienced rapid tourism development which has not been accompanied with a similar increase in urbanization facilities. For example, the city of Cartagena de Indias (the most famous tourist destination of Colombia), data related to November 2009 – January 2015 period, showed an increase of 20% in tourist arrivals. A large number of surveys developed in Europe found that the most critical parameters for tourists, when they choose a beach, are: i) security, ii) scenery, iii) water quality, iv) litter, v) facilities. Scenery is one of the most significant coastal resources. Therefore, its evaluation is a valuable tool for coastal managers when developing conservation and protection plans. This proposal provides coastal scenery assessment of 37 beaches along the North Colombian Caribbean littoral by analysing 26 physical and human factors. Results were weighted (not all parameters have equal weight) and subjected to fuzzy logic mathematics in order to reduce recorder judgment subjectivity. The sites were categorised into five classes; Class 1 locations had top grade scenery; Class 5 poor scenery. Of the 37 sectors studied, currently none can be considered as an extremely attractive coastal area (class1), while 15 were unattractive urban coastal areas (class 5), the rest of the beaches (22) placed in classes 2, 3 and 4. Classification of analysed sites depends on the geological setting and degree of human occupation. The technique opens new perspectives for analysis of the potential for coastal tourism development in natural areas and scenic quality improvement of current tourist developed areas. Concerning coastal management issues, emphasis should be given to the upgrading of human parameters eliminating litter and sewage evidence, vegetation debris and enhancing beach nourishment works. This proposal can help in moving some locations from their present status to a higher one.
Caraïbes
Colombie

Droits : info:eu-repo/semantics/openAccess
urn:doi:10.4000/etudescaribeennes.9326
http://journals.openedition.org/etudescaribeennes/9326

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Two in situ concrete/claystone interfaces were sampled at the laboratory level in the Andra Meuse/Haute Marne (France) Underground Research Laboratory (URL) in order to study five years of interactions between Callovian-Oxfordian (COx) claystone and two cementitious materials (concrete bottom slab and shotcrete on the walls of the main gallery), with a specific focus on sulfur. Combined mineralogical, chemical and sulfur isotopic investigations were carried out to define the degree of the perturbation of the sulfur system in the claystone and in both the cementitious materials. At both interfaces, results show that the main perturbation on the claystone side is the formation of scarce μm-sized gypsum, the sulfur content of which is essentially derived from pyrite oxidation. The distribution of gypsum is highly correlated with the fissure network of the damaged zone due to excavation of the gallery. Its presence is also often associated with a loss of cohesion of the concrete/claystone interface. Due to the small amounts of gypsum and its μm-size, measurements were performed by ion microprobe. Adaptations were needed on account of the reactivity of gypsum and sulfates in general under the beam. The use of ion microprobe analysis provided evidence of high local isotopic heterogeneity that could be attributed to kinetic fractionation effects. Some analyses suggest a minor contribution of dissolved sulfates in pore water of claystone and possibly of concrete. The perturbation on the concrete side is marked by a significant increase in the bulk sulfur content within three millimeters of the interface with the claystone, showing a sulfur gradient from claystone to concrete. The main objective of this work was to define the extent of the chemical and mineralogical perturbations, taking into account in situ URL conditions, i.e. hydrodynamic conditions (shotcrete sprayed on the gallery walls and subjected to ventilation of the galleries), damaged zone of claystone induced by excavation and multi-scale heterogeneity. This identifies the relevant parameters to better constrain predictive reactive transport models of concrete/claystone interactions at a realistic scale.
ISSN: 0079-1946

hal-01055790
https://hal-brgm.archives-ouvertes.fr/hal-01055790
DOI : 10.1016/j.pce.2014.01.003

Éditeur(s) : Geological Soc Amer, Inc
Résumé : Pockmarks are seafloor depressions commonly associated with fluid escape from the seabed and are believed to contribute noticeably to the transfer of methane into the ocean and ultimately into the atmosphere. They occur in many different areas and geological contexts, and vary greatly in size and shape. Nevertheless, the mechanisms of pockmark growth are still largely unclear. Still, seabed methane emissions contribute to the global carbon budget, and understanding such processes is critical to constrain future quantifications of seabed methane release at local and global scales. The giant Regab pockmark (9 degrees 42.6' E, 5 degrees 47.8' S), located at 3160 m water depth near the Congo deep-sea channel (offshore southwestern Africa), was investigated with state-of-the-art mapping devices mounted on IFREMER's (French Research Institute for Exploitation of the Sea) remotely operated vehicle (ROV) Victor 6000. ROV-borne micro-bathymetry and backscatter data of the entire structure, a high-resolution photo-mosaic covering 105,000 m(2) of the most active area, sidescan mapping of gas emissions, and maps of faunal distribution as well as of carbonate crust occurrence are combined to provide an unprecedented detailed view of a giant pockmark. All data sets suggest that the pockmark is composed of two very distinctive zones in terms of seepage intensity. We postulate that these zones are the surface expression of two fluid flow regimes in the subsurface: focused flow through a fractured medium and diffuse flow through a porous medium. We conclude that the growth of giant pockmarks is controlled by self-sealing processes and lateral spreading of rising fluids. In particular, partial redirection of fluids through fractures in the sediments can drive the pockmark growth in preferential directions.
Geology (0091-7613) (Geological Soc Amer, Inc), 2014-01 , Vol. 42 , N. 1 , P. 63-66

Droits : 2013 Geological Society of America
http://archimer.ifremer.fr/doc/00186/29731/28293.pdf
DOI:10.1130/G34801.1
http://archimer.ifremer.fr/doc/00186/29731/

Éditeur(s) : MDPI AG
Résumé : In mangrove ecosystems, strong reciprocal interactions exist between plant and substrate. Under semi-arid climate, Rhizophora spp. are usually predominant, colonizing the seashore, and Avicennia marina develops at the edge of salt-flats, which is the highest zone in the intertidal range. Along this zonation, distribution and speciation of C, Fe, S, N, and P in sediments and pore-waters were investigated. From the land-side to the sea-side of the mangrove, sediments were characterized by I/ increase in: (i) water content; (ii) TOC; (iii) mangrove-derived OM; II/ and decrease in: (i) salinity; (ii) redox; (iii) pH; (iv) solid Fe and solid P. Beneath Avicennia and Rhizophora, TS accumulated at depth, probably as a result of reduction of iron oxides and sulfate. The loss of total Fe observed towards the sea-side may be related to sulfur oxidation and to more intense tidal flushing of dissolved components. Except the organic forms, dissolved N and P concentrations were very low beneath Avicennia and Rhizophora stands, probably as a result of their uptake by the root systems. However, in the unvegetated salt-flat, NH4+ can accumulate in organic rich and anoxic layers. This study shows: (i) the evolution of mangrove sediment biogeochemistry along the intertidal zone as a result of the different duration of tidal inundation and organic enrichment; and (ii) the strong links between the distribution and speciation of the different elements.
Journal of Marine Science and Engineering (2077-1312) (MDPI AG), 2015-02-10 , Vol. 3 , N. 1 , P. 52-72

Droits : 2015 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution license (http://creativecommons.org/licenses/by/4.0/).
http://archimer.ifremer.fr/doc/00251/36252/34802.pdf
DOI:10.3390/jmse3010052
http://archimer.ifremer.fr/doc/00251/36252/

Éditeur(s) : Université des Antilles Études caribéennes
Résumé : La grande plaisance qui regroupe les navires de plus de 25 mètres connaît une belle croissance malgré la crise. Elle constitue une forme de matérialisation de la grande richesse d’une minorité de milliardaires dont le nombre ne cesse cependant d’augmenter. Ce monde qui se donne à voir reste cependant relativement secret. Cette ambivalence génère de larges retombées économiques et nécessité des aménagements portuaires parfois très importants. Une véritable compétition s’opère entre certaines villes portuaires afin de capter cette clientèle de luxe et les touristes moins aisés, mais plus nombreux, qui sont attirés par la présence de ces yachts prestigieux.
The big sailing which includes the ships of more than 25 metres knows a beautiful growth in spite of the crisis. It establishes a form of realization of the great wealth of billionaires' minority by which the number does not, however, stop increasing. This world is just showing, but it remains relatively secret. This ambivalence generates wide economic fallout, and it sometimes requires very important harbour arrangements. A real competition takes place between some harbour cities which want to attract this luxury clientele and the other tourists, less easy, but more numerous, who are attracted by the presence of these prestigious yachts.
La gran navegación de recreo que reagrupa los buques de más de 25 metros conoce un fuerte crecimiento a pesar de la crisis. Constituye una forma de materialización de la gran riqueza de una minoría de multimillonarios cuyo número sigue crecimiento. Este mundo que se deja contemplar, queda sin embargo relativamente secreto. Esta ambivalencia genera beneficios económicos significativos e instalaciones portuarias a veces muy importantes. Una verdadera competencia opera entre algunas ciudades portuarias con el fin de captar a esta clientela de lujo y los turistas menos adinerados pero más numerosos que son atraídos por la presencia de estos yates prestigiosos.

Droits : info:eu-repo/semantics/openAccess
urn:doi:10.4000/etudescaribeennes.10562
http://journals.openedition.org/etudescaribeennes/10562