Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The southwestern Tianshan (China) metamorphic belt records high-pressure (HP) to ultrahigh-pressure (UHP) conditions corresponding to a cold oceanic subduction-zone setting. Serpentinites enclosing retrogressed eclogite and rodingite occur as lenses within metapelites in the UHP unit, which also hosts coesite-bearing eclogites. Based on the petrology and petrography of these serpentinites, five events are recognized: (1) formation of a wehrlite–harzburgite–dunite association in the mantle; (2) retrograde metamorphism and partial hydration during exhumation of the mantle rocks close to the seafloor; (3) oceanic metamorphism leading to the first serpentinization and rodingitization; (4) UHP metamorphism during subduction; (5) retrograde metamorphism during exhumation together with a second serpentinization. The peak metamorphic mineral assemblage of the serpentinized wehrlite comprises Ti-chondrodite + olivine + antigorite + chlorite + magnetite + brucite. A computed pseudosection for this serpentinized wehrlite shows that the Al content in antigorite is mostly sensititive to temperature but can also be used to constrain pressure. The average XAl = 0·204 ± 0·026 of antigorite (XAl = Al (a.p.f.u.)/8, where Al is in atoms per formula unit for a structural formula M48T34O85(OH)62, and M and T are octahedral and tetrahedral sites, respectively) included in Ti-chondrodite and average XAl = 0·203 ± 0·019 of antigorite in the matrix result in a well-constrained peak metamorphic temperature of 510–530°C. Peak pressures are less precisely constrained at 37 ± 7 kbar. The Tianshan serpentinites thus record UHP metamorphic conditions and represent the deepest subducted serpentinites discovered so far. The retrograde evolution occurs within the stability field of brucite + antigorite + olivine + chlorite and formation of Ti-clinohumite at the expense of Ti-chondrodite has been observed, suggesting isothermal decompression. The resulting P–T path is in excellent agreement with the metamorphic evolution of country rocks, indicating that the UHP unit in Tianshan was subducted and exhumed as a coherent block. To refine the metamorphic path of the ultramafic rocks, we have investigated the stability fields of Ti-chondrodite and Ti-clinohumite using piston-cylinder experiments. A total of 11 experiments were conducted at 25–55 kbar and 600–750°C in a F-free natural system. Combined with previous experiments and information from natural rocks we constructed a petrogenetic grid for the stability of Ti-chondrodite and Ti-clinohumite in F-free peridotite compositions. The formation of Ti-chondrodite in serpentinites requires a minimum pressure of about 26 kbar, whereas in Ti-rich systems it can form at considerably lower pressures. A key finding is that at UHP conditions, F-free Ti-chondrodite or Ti-clinohumite breaks down in the presence of orthopyroxene between 700 and 750°C, at temperatures that are significantly lower than those of the terminal breakdown reactions of these humite minerals. These breakdown reactions are an additional source of fluid during prograde subduction of serpentinites.
ISSN: 0022-3530

hal-01243507
https://hal.archives-ouvertes.fr/hal-01243507
DOI : 10.1093/petrology/egv042

Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : Production rates in horizontal shale gas wells display declines that are controlled by the low permeability and the intrinsic heterogeneity of the shale matrix. We present an original multi-continuum approach that yields a physical model able to reproduce the complexity of the decreasing gas rates. The model describes the dynamics of gas rate as function of the physical reservoir parameters and geometry, while the shale matrix heterogeneity is accounted for by a stochastic description of transmissivity field. From the 3D (Dimensional) problem setting, including the heterogeneous shale matrix, the fractures generated by the hydrofracking operations, as well as the production well characteristics, we establish an effective upscaled 1D model for the gas pressures in fracture and matrix as well as the volumetric flux. We analyse the decline curves behaviour, and we identify the time scales that characterize the dynamics of the gas rate decline using explicit analytical Laplace space solutions of the upscaled process model. Asymptotically, the flux curves decrease exponentially, while in an intermediate regime we find a power-law behaviour, in which the flux scales with a power law in time as (t^{-beta }), where (beta ) reflects the medium heterogeneity. We use this solution to fit a set of real data displaying distinctly different decline trends and study the sensitivity of the model to the reservoir parameters in order to identify their respective controls at the different stages of the decline curve dynamics. Results indicate that the initial value of the gas rate is determined by the transmissivity of the fractures and the initial pressure of the gas in the shale matrix. The latter causes mainly a shift in the entire decline curve. The early time of decline curve shape is primarily controlled by the fracture properties (compressibility and transmissivity). During the main part of the economically valuable production times, i.e. before the production rate drops exponentially, the decline curve is strongly controlled by the properties of the shale rocks including their heterogeneity, which is modelled by two parameters describing the non-Fickian pressure diffusion effects in a stochastic framework.
ISSN: 0169-3913

hal-01217247
https://hal.archives-ouvertes.fr/hal-01217247
DOI : 10.1007/s11242-015-0504-y

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The 40Ar/39Ar geochronological technique has significantly contributed to the study of crustal deformation. However, the frequent occurrence of extraneous argon in high-pressure terrains can make the interpretation of 40Ar/39Ar ages problematic. This contribution attempts to: i) characterize the distribution and origin of extraneous argon in the Cycladic Blueschist Unit (CBU, Greece) by applying the 40Ar/39Ar dating technique on three Cycladic islands, Syros, Tinos and Ios, which span a complete transect of the CBU and ii) discuss regional implications for the tectonometamorphic evolution of the CBU. Our results, combined with ages available in the literature, show that periods of peak-burial conditions (55–49 Ma) and syn- (45–38 Ma) to post-orogenic exhumation (37–21 Ma) are well constrained in the CBU by the 40Ar/39Ar method. Moreover, Variscan apparent ages are preserved in the Cycladic basement of Ios, indicating that the 40Ar/39Ar system was not completely reset during the Eocene metamorphic episode. Additionally, our 40Ar/39Ar data show that the occurrence of extraneous argon is heterogeneously distributed in the CBU. While high-pressure rocks of Syros and Tinos are only locally affected, extraneous argon is clearly evidenced in the CBU of Ios, yielding geologically meaningless ages up to 900 Ma. On each island, the most affected ages were obtained in microstructures where fluid circulation is enhanced such as shear bands or strain shadows around garnets. We suggest that the Cycladic Basement, a polymetamorphic continental unit, behaved as an argon reservoir that has been mobilized by fluid circulation at the Eocene. These argon-enriched fluids have then heterogeneously contaminated metamorphic rocks when percolating through the CBU. Finally, we claim that a minimum closure temperature of 550 °C must be accepted for the phengites of the CBU and conclude that volume diffusion is not the main process resetting the argon isotopic system in high-pressure rocks compare to recrystallization enhanced by fluid circulation and deformation.
ISSN: 0024-4937

Droits : http://creativecommons.org/licenses/by-nc-nd/
insu-01424268
https://hal-insu.archives-ouvertes.fr/insu-01424268
https://hal-insu.archives-ouvertes.fr/insu-01424268/document
https://hal-insu.archives-ouvertes.fr/insu-01424268/file/Valentin-Lithos-Accepted-2016.pdf
DOI : 10.1016/j.lithos.2016.12.013

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
The El Oro metamorphic province of SW Ecuador is a composite massif made of juxtaposed terranes of both continental and oceanic affinity that has been located in a fore-arc position since Late Paleozoic times. Various geochemical, geochronological, and metamorphic studies have been undertaken on the El Oro metamorphic province, providing an understanding of the origin and age of the distinct units. However, the internal structures and geodynamic evolution of this area remain poorly understood. Our structural analysis and thermal modeling in the El Oro metamorphic province show that this fore-arc zone underwent four main geological events. (1) During Triassic times (230–225 Ma), the emplacement of the Piedras gabbroic unit at crustal-root level (~9 kbar) triggered partial melting of the metasedimentary sequence under an E-W extensional regime at pressure-temperature conditions ranging from 4.5 to 8.5 kbar and from 650 to 900°C for the migmatitic unit. (2) At 226 Ma, the tectonic underplating of the Arenillas-Panupalí oceanic unit (9 kbar and 300°C) thermally sealed the fore-arc region. (3) Around the Jurassic-Cretaceous boundary, the shift from trench-normal to trench-parallel subduction triggered the exhumation and underplating of the high-pressure, oceanic Raspas Ophiolitic Complex (18 kbar and 600°C) beneath the El Oro Group (130–120 Ma). This was followed by the opening of a NE-SW pull-apart basin, which tilted the massif along an E-W subhorizontal axis (110 Ma). (4) In Late Cretaceous times, an N-S compressional event generated heterogeneous deformation due to the presence of the Cretaceous Celica volcanic arc, which acted as a buttress and predominantly affected the central and eastern part of the massif.
ISSN: 0278-7407

hal-01115714
https://hal.archives-ouvertes.fr/hal-01115714
DOI : 10.1002/2014TC003618

Résumé : Une étude de faisabilité de poutres en bois lamellé-collé a été menée en Guyane Française en utilisant les essences locales. Le but est de déterminer les paramètres de collage assurant la bonne résistance mécanique des assemblages par lamellation et par aboutage, nécessaires à la fabrication de poutres en bois lamellé-collé en climat tropical. Trois essences de bois abondantes de différentes densités ont été sélectionnées. Les adhésifs de types Mélamine-Urée-Formol et Résorcinol-Phénol-Formol ont été utilisées. Les paramètres de collage considérés sont : le grammage, le temps d’assemblage fermé et la pression.En utilisant les normes Européennes, plusieurs campagnes de tests ont été conduites sur des échantillons normalisés. Concernant le collage par lamellation, des tests élémentaires de délamination et de cisaillement des joints de colle ont été réalisés. Le test de délamination consiste en deux cycles d’immersion dans l’eau sous pression et de séchage, il induit de sévères variations d’humidité du bois susceptibles de créer des ouvertures des joints de colles. Le collage par aboutage est réalisé sur des poutres normalisées aboutées. Les entures sont obtenues grâce à un outillage standard communément utilisé pour les résineux. Les résultats ont mis en évidence l’influence des propriétés du bois et des paramètres de collage sur la résistance du joint et la résistance mécanique du produit. En effet, les paramètres du bois, tels que la densité, la rétractibilité et l’imprégnation, ont une forte influence sur le collage, en particulier sur la pression et le grammage nécessaires à la production d’un produit commercialisable. Il apparait qu’un bois de densité moyenne et poreux nécessite un grammage et une pression élevés comparé à un bois de densité élevée qui nécessite des valeurs moindres. Aussi, l’influence d’autres paramètres de fabrication, tels que le rabotage, l’encollage double face et simple face ainsi que l’épaisseur des lamelles, a été établie. Par contre il semblerait que le matériel communément utilisé pour l’aboutage des résineux n’est pas adapté aux feuillus tropicaux. En final, des paramètres de collage ont été validés pour la fabrication de lamellé-collé endémique en Guyane Française et une étude du coût de production d’une poutre lamellé-collé standard a identifié les conditions économiques d’une fabrication en Guyane Française.
A feasibility study of glued-laminated timber beams was carried out in French Guiana using local wood species. The aim of the study was to evaluate the gluing parameters that could ensure good mechanical properties for the manufactured glued-laminated beams in tropical climates. Three abundant wood species with different specific gravity were selected for the study. Melamine-Urea-Formaldehyde and Resorcinol-Phenol-Formaldehyde resins were used for gluing. The three gluing parameters considered are: adhesive spread rate, closing assembly time and gluing pressure.Using European standards, several laboratory tests were performed on normalized samples. The evaluation of a successful lamella’s gluing was done by using elementary tests of delamination and shearing. A delamination test consists of two cycles of water immersion at high pressure and drying which induces severe hygroscopic variation in wood thus causing joints opening. The finger-joints are made using a standard tool usually used for cutting softwoods. The performed tests revealed the influence of wood properties and the gluing parameters on the joint resistance and the mechanical properties of the product. Results show that wood properties such as specific gravity, shrinkage coefficient, and permeation, have a high degree of influence on the gluing step especially on the gluing pressure and on the adhesive spread rate needed to produce a commercial product. Furthermore, wood with medium specific gravity needs more adhesive and more pressure than the one with high specific gravity. Additionally, the effects of other manufacturing parameters, such as planning, double or simple side glue spreading and lamellae thicknesses, on the glue joint resistance were demonstrated. Finally, the common tools used for softwoods are not adapted to making the finger joints with tropical hardwoods.In conclusion, optimal gluing parameters for manufacturing glued-laminated timber beams in French Guiana were established and an economical study using standard glued-laminated timber beams revealed the economic conditions under which a successful manufacturing of these local beams can be implemented in French Guiana.

http://www.theses.fr/2011AGUY0484/document

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
Pressure-temperature divariant melting phase relations of model carbonated peridotite in the system CaO-MgO-Al2O3-SiO2-CO2 from 8 to 12 GPa are reported. From 8 to 12 GPa, melting temperatures on the studied pressure-temperature divariant surface rise quite rapidly. Liquids, in equilibrium with forsterite, orthopyroxene, clinopyroxene, and garnet, on the low-temperature side of the divariant surface are magnesiocarbonatitic in composition. With increasing temperature along an isobar on the pressure-temperature divariant surface, and with the same crystalline phase assemblage, liquids gradually become kimberlitic in their composition. Given the model system data reported here, Group IB kimberlites and perhaps some kimberlites from Greenland, Canada, and South Africa could be generated from direct melting of carbonated peridotite in the pressure range of approximately 6-8 GPa. Some kimberlites from Canada and Russia could have formed by partial melting of carbonated mantle peridotite at pressures of about 10-12 GPa. From 8 to 12 GPa, liquid compositions on the studied divariant surface show a limited compositional range, which implies that the divariant surface is essentially flat. The implied flatness of the divariant surface, and so long as the liquid is in equilibrium with the crystalline assemblage of forsterite + orthopyroxene + clinopyroxene + garnet on the divariant surface, indicate that kimberlites belonging to Group IA and those more magnesian than Group IA cannot have their origin in only being a melting product of carbonated mantle peridotite. The absence of topography of the studied pressure-temperature divariant surface in all likelihood limits the generation of kimberlites in the Earth's upper mantle only.
ISSN: 0003-004X

hal-01053915
https://hal.archives-ouvertes.fr/hal-01053915
DOI : 10.2138/am.2014.4826

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Here we show that copper substitution in perovskite-type barium strontium cobalt copper oxide (BSCC) membranes confers extremely high oxygen fluxes well beyond the state of art, reaching 27.5 ml cm−2 min−1at 950 °C. A key feature of BSCC is the formation of a mixed matrix catalyst-perovskite membrane caused by the segregation of copper, leading to the formation of an intergranular network of copper-rich oxide between perovskite grains. BSCC membranes delivered pressure normalised oxygen flux (i.e. permeance) of up to 86 times higher, above pressure difference of 18 kPa, as compared to best perovskite membrane, BBSC, due to the catalytic effect of segregated copper oxide. Unlike conventional dual-phase membranes which contain ion and electron conducting phases, this work shows for the first time perovskite-type membranes consisting of a mixed matrix of oxygen ion/electron conducting (perovskite) and catalytic (copper oxide) phases, thus paving the way to the development of high performance membranes for oxygen separation from air for clean energy applications. © 2016 Elsevier B.V.
ISSN: 0376-7388

hal-01683219
https://hal.univ-antilles.fr/hal-01683219
DOI : 10.1016/j.memsci.2016.12.035

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
eoproterozoic eclogite and garnet amphibolites, representing retrogressed eclogites, from the Tassendjanet-Tidéridjaouine terrane in the Pan-African Western Hoggar (Tuareg shield, Southern Algeria) form lenses enclosed in 1.8 Ga subalkaline Paleoproterozoic orthogneisses. They lie along a major sinistral shear zone marking the boundary with the Archean/Paleoproterozoic granulitic In Ouzzal terrane and are associated with high-pressure metasediments. According to thermodynamic calculations, peak condition of the eclogitic stage is 650 °C, 20-22 kbar followed by post-peak heating and exhumation at 730 °C, 10-14 kbar and cooling to 610 °C, 7-10 kbar. Their major, trace-element and isotopic compositions are consistent with emplacement of former basalts in the shoulder of a 700-800 Ma continental rift that evolved to an oceanic basin. The eclogite and garnet amphibolites were thus part of the continental portion of a subducting slab that was pulled down by a denser oceanic lithosphere. Sheath and recumbent folds associated with the exhumation of HP units are verging toward the west, meaning that the former slab was dipping to the east. U-Pb zircon dating on metamorphic zircons bordering ilmenite and rutile in the eclogite gave an age of 623 ± 2 Ma, interpreted as the syn-collisional exhumation stage of the high-pressure unit. This event was rapidly followed by transpressional tectonics and abundant magmatism linked to the northward motion of the adjacent In Ouzzal terrane.
ISSN: 0301-9268

hal-01054338
https://hal.archives-ouvertes.fr/hal-01054338
DOI : 10.1016/j.precamres.2014.04.002

Éditeur(s) : Université des Antilles Études caribéennes
Résumé : Cette étude permet une approche distincte de la réflexion sur les ressources marines dans le cadre d’une aire protégée. En effet, les écosystèmes marins sont essentiels d’autant plus, qu’ils présentent en Nouvelle-Calédonie une grande richesse, notamment en termes de patrimoine culturel. Ce sont majoritairement les Kanak qui habitent sur la Côte Est de la Province nord, où la Collectivité et le WWF collaborent à la mise en place de plusieurs aires marines protégées (AMP). Jusqu’à présent, la gestion coutumière Kanak a permis une relative préservation de ces écosystèmes dans un secteur littoral non soumis aux pressions de l’urbanisation, du tourisme ou de la navigation. L’étude s’attache à souligner les enjeux autour de la mise en place des AMP et des perspectives de développement local, sur le milieu marin et les populations locales. Il s’agit de voir comment cette expérimentation est envisagée par les différents acteurs (État, Province Nord, associations, coutumiers, etc.) et de s’interroger sur les mécanismes de gouvernance.
This study allows a distinct approach to thinking about the marine resources in a protected area. Indeed, marine ecosystems are essential, especially as they are in New Caledonia, particularly in terms of cultural heritage. It is mainly Kanak who live on the East Coast of the North Province, where the Community and WWF collaborate on the installation of several marine protected areas (MPAs). So far, the Kanak customary management allowed a relative preservation of these ecosystems in a coastal area not subject to the pressures of urbanization, tourism and navigation. The study aims to highlight the issues surrounding the establishment of MPAs and opportunities for local development on the marine environment and local populations. This is to see how this experiment is considered by the various actors (State, Northern Province, associations, etc. customary). And to consider the mechanisms of governance.
Nouvelle-Calédonie

Droits : info:eu-repo/semantics/openAccess
urn:doi:10.4000/etudescaribeennes.7883
http://journals.openedition.org/etudescaribeennes/7883

Éditeur(s) : HAL CCSD
Résumé : International audience
The purpose of our study is to model a geothermal reservoir. When geothermal reservoir are assumed to be composed of pure water, the transfer of mass and energy is classically described by two balance equations: mass balance equation and the energy balance equation. In addition to those equations, fluid velocity ist classically given by the Darcy law while thermodynamic properties, inferred from theoretical or empirical equations of state, are used to close the mathematical system. Once this system is closed, there exist different solutions. The first one is to solve for pressure and temperature with a variable switch to saturation in the two-phase region (e.g. TOUGH2). The second one is to solve for pressure and enthalpy to increase stability of phase transition between single and two-phase states (e.g. Hydrotherm). We adopted the second option and chose te use a splitting method to get rid of the complexity of coupling equations and a finite volume method for the spatial discretization. Selecting object-oriented languages, we developed a multi-language framework, combining Python, Fortran and a C++ implementation of IAPWS (from the freesteam project) including the supercritical equations, in porous media velocity is given by Darcy law and to close the system physical properties are determined by the IAPWS-IF97 thermodynamic formulation. We resolve the equations in pressure and enthalpy instead of pressure and temperature in order to increase stability and to handle easier the passage from a single-phase to a two-phase system. We solve the system by using a splitting method - to get rid of the complexity of coupling equations - and a finite volume method. We offer some freedom to users thanks to the implementation of several methods like explicit or implicit Euler, Runge-Kutta or BDF2 for time solvers or GMRES and BICGSTAB for the linear solver. We can handle several boundary conditions like no-flow - describing a boundary which can not exchange matter with the exterior - or like a mixed-therm condition - a Dirichlet condition to the pressure and a Dirichlet or an outflow condition to the temperature in order to describe a recharge or a discharge zone - ... We're developing a multi-language framework, combining Python, Fortran and the C++ implementation of IAPWS (from the freesteam project). All these languages are object-oriented. We've applied this simulation model to the dogger in Paris, France, to several one-dimensional systems and a two-dimensional one made by Coumou with the CSMP++ platform. The dogger is a reservoir exploited to produce heat by pumping water at 70 and reinjecting it in the reservoir at 40. In the one-dimensional systems we wanted to observe the process of heat transfer from a higher temperature boundary to a smaller one in a high-energy domain. The last simulation shows the natural convection of water in a fault. For every simulation we compared the solutions we found with an other code (TOUGH2 or CSMP++) and they agreed. The next step will be to model the geothermal plant in Guadeloupe, West Indies. It's the only place in France - and in the West Indies so far - producing electricity with the earth power. The temperature can reach up to 1000 and the pressure range is around a few hundreds MPa. In some surface zones we can see two-phase water at atmospheric pressure. In the 1980s Bouillante was a laboratory for France. Since 1995 Bouillante has given 30GWh electricity a year to the Guadeloupeans.
PROCEEDINGS, Thirty-Ninth Workshop on Geothermal Reservoir Engineering
Stanford, United States

Droits : info:eu-repo/semantics/OpenAccess
hal-00944133
https://hal-brgm.archives-ouvertes.fr/hal-00944133
https://hal-brgm.archives-ouvertes.fr/hal-00944133/document
https://hal-brgm.archives-ouvertes.fr/hal-00944133/file/Copol.pdf

Éditeur(s) : HAL CCSD Springer-Verlag
Résumé : The seismology is the most effective method to explore the Structure of subduction zones to great depth. The distinguishing feature of the mantle in the subduction regions is the presence of hydrated phases, which transport water into the Earth's interior and release it with dramatic local consequences, triggering earthquakes and melting. The seismological detection of these hydrous phases and geo-dynamic interpretation of flow in the hydrous mantle depend on knowledge of the anisotropic elastic properties and the characteristics of the wave propagation in anisotropic media. In this paper we briefly recall the distinguishing features of anisotropic wave propagation and the observable parameters. We suggest the Vp/Vs ratio is a physically sound parameter than can be observed by seismology in anisotropic regions of the Earth, whereas the Poisson's ratio, which is often quoted, is not directly observable and does not correspond to the characteristics of wave propagation in an anisotropic or isotropic medium. We report for the first time the ratios of Vp/Vs1 and Vp/Vs2, where Vs1 is the fastest and Vs2 slowest S-wave velocities of an anisotropic media. We present the current knowledge of the anisotropic seismic properties of hydrous minerals in the upper mantle, transition zone, and lower mantle that are stable along low temperature geotherms associated with subduction, and identify which minerals are likely to influence seismological observations because they have very high volume fractions, or very high anisotropies, or both of these.;In the upper mantle antigorite and talc are exceptionally anisotropic (Vp 71% Vs 68% and Vp 65%, Vs 68%, respectively) and chlorite is also very anisotropic for S-waves (Vp 35%, Vs 76%). Comparatively less anisotropic are hornblende (Vp 27%, Vs 31%), used as proxy for tremolite in subduction zones, and clinohumite (21.8%, Vs 15.9%). Brucite at 4 GPa (Vp 26.5%, Vs 30.9%) and the dense hydrogen magnesium silicate (DHMS) phase A at 9GPa (Vp 9.3%, Vs 17.6%) are the only hydrous minerals stable in the upper mantle that have had their elastic properties measured at in situ mantle pressures. Except for the phase A, all these minerals are more anisotropic than olivine for at least one parameter (Vp, Vs, Vp/Vs1, or Vp/Vs2). In the transition zone the major phases hydrous wadsleyite and ringwoodite C have moderate to weak anisotropies (Vp 16.3%, Vs 16.5%, and Vp 1.9%, Vs 4.4%, respectively). The DHMS Superhydrous B has a moderate anisotropy (Vp 6.9%, Vs 11.6%). At greater depth the DHMS phase D Lit 24 GPa (Vp 10.8%, Vs 18.0%) is the only hydrous phase that can transport hydrogen from the transition zone into the lower mantle. The phase D is more anisotropic for S than P waves like many of the hydrous phases. From these data it is clear that hydrous phases are in general very anisotropic. However, pressure can play a strong role in reducing anisotropy. It is the case for brucite and talc, in which increasing pressure from ambient to 4 GPa reduces the anisotropy by about 50% for both P and S waves. In contrast, the anisotropy of the DHMS phase A does not change significantly with pressure.;Our picture of the seismic anisotropy of hydrated minerals remains incomplete; the elastic properties of many have not been measured even at ambient conditions (e.g., 10 angstrom phase and phase E) or not measured in their true elastic symmetry (e.g., clinochlore). The majority of hydrous minerals have not been measured at high pressure. and none related to hydrated mantle have been measured at elevated temperature. We have shown in the few cases where hydrous minerals have been measured as a function of pressure, that this variable has an important effect oil the velocity distribution and in most cases reduces the degree of anisotropy, hence we Would expect seismic anisotropy to play a key role in the determination of the shallow structure of subduction zones in the upper mantle.
Subduction zone geodynamics

hal-00420893
https://hal.archives-ouvertes.fr/hal-00420893

Résumé : Marine capture fisheries in Jamaica is primarily artisanal in nature ansd is conducted maiinly by fishermen operating from canoes. Approximately 95% of these fishermen operate on the coastal shelf and its associated banks. The commercial species harvested comprise bottom-dwelling, coral reef species and free swimming species of finfish. Other fishery resources of commercial value include marine shrimp, conch and lobsters. Catch statistics are not available for all species, but the Department of Fisheries reports a slight decline in fishery production with production decreasing from 16 milion lbs in 1990, despite the fact that fishing efforts have doubled. Over this period the number of registered fishermen has grown from 12 000 to 16 000, al of whom are engaged in full-time fishing. There arealso part-time fishermen who are not registered. The decline in fish catch is accompanied by a decrease in fish size and quality, suggesting that the fisheries are under pressure and have already exceeded optimum production in relation to vailable resources. As a result the economic returns to fishermen are declining. There are also other problems, such as high incidence of conflicts among fishermen at sea, the high cost of purchasing boats, outboard engine fuel, and equipment, with together with the dangers involved in fishing offshore (piracy, and praedial larceny) create serious social ans economic difficulties for fishermen. Notwithstanding, there is an apparent move on the part of the fishermen to leave the industryor to seek alternative forms of employment. In fact, the Department ofFisheries reports that it is still reciving applications for new licences to operate fishing boats. This is probably due to the fact that where the basis of a community is fishing, it becomes difficult to introduce alternative forms of employment, such as cottage industries, village crafts and other trades. In 1987 the Jamaica Department of Fisheries prepared a Management plan which proposed several conservation measures to promote the efficient use of fisheries resources and to control the development of the Fishery in such a way that the country would receive highest benefits. Adequate attention was given to limitations on fishing gear, institution of closed seasons and related legislation. Strategies to diversify the marine fishing were also proposed. The 1990 five year Devlopment Plan for marine fisheries also focuses on proper resource management in order to reverse trends associated with the overexploitation of marine resources. According to the plan, emphasis will be placed on inland fisheries and mariculture in order to reduce pressure on the fisheries. Inland fisheries in the form of freshwater fish fanning has expanded significantly over the past 10 years with production increasing from less than 0,5 million lbs. in 1980 to in excess of 6.0 million lbs. in 1989. However, some freshwater fish farmers are already experiencing serious competition for water usage and, to a lesser extent for land from crop-producing farmers. The Ministry of Agriculture is of the view that marine cage culture technologically has the potential for introduction in Jamaica . This technologyhas been successfully developed in Norway and the technology is currentlty being experimentally utilized in several countries in the area. The technology, if widely utilized in Jamaica, couls significantly reduce pressure on fisheries, making fishing more cost effective and improve the economic returns to fishermen. Already there exist some technical and institutional capabilities in Jamaica to support commercial development of marine cage culture. The Department of Fisheries has highly trained personnel in aquaculture and marine fisherie, some of whom are directly responsible for the success of freshwater fish fanning. In adition, the Marine Laboratory at the Univesity of the West Indies (UWI) is caarying research on hatchery facilities for marine cage farming. The Department of Fisheries will seek the collaboration ofg the marine unit at UWI which could provide fingerlings of selected marine species for cage 1
Les pêcheries de captage marin en Jamaïque sont principalement de nature artisanale et elles sont dirigées principalement par les pêcheurs qui travaillent depuis des canoës. Environ 95 % de ces pêcheurs travaillent sur la plaine côtière et ses bancs associés. Les espèces commerciales récoltées comprennent les espèces benthiques, les espèces de corail et les espèces de poisson marin de nage libre. D'autres ressources de pêcheries de valeur commerciale comprennent la crevette, la conque et le homard. Les statistiques des pêches ne sont pas disponibles pour toutes les espèces, mais le Département des Pêcheries fait état d'une légère réduction de production de pêcheries, la production se réduisant de 16 millions de livres en 1990, en dépit du fait que les efforts de la pêche ont doublé. Sur cette période le nombre de pêcheurs inscrits a augmenté de 12 000 à 16 000, dont tous sont occupés à plein temps à la pêche. Il y a aussi des pêcheurs à mi-temps qui ne sont pas inscrits. La réduction des pêches est accompagnée d'une réduction de la taille et la qualité des poissons, ce qui implique que les pêcheries sont sous pression et qu'elles ont déjà dépassé la production optimum par rapport aux ressources disponibles. En conséquence, les rendements pour les pêcheurs sont en baisse. Il y a aussi d'autres problèmes, tels qu'un taux élevé de conflits entre les pêcheurs en mer, le coût élevé pour acheter les bateaux, le combustible pour les moteurs hors-bord, et le matériel, ainsi que les dangers impliqués dans la pêche offshore (le piratage, et le vol prédial) ont créé de graves problèmes sociaux et économiques pour les pêcheurs. Néanmoins, il y a une tendance évidente chez les pêcheurs de quitter l'industrie ou de chercher du travail dans d'autres domaines. En fait, le Département des Pêcheries signale qu'il continue de recevoir des demandes de nouveaux permis pour opérer les bateaux de pêche. Ceci est probablement attribuable au fait que là où la base d'une communauté est la pêche, il est difficile d'y introduire des formes alternatives de travail, telles que l'industrie artisanale, l'artisanat de village ou d'autres métiers. Le Département des Pêcheries de la Jamaïque a préparé en 1987 un Projet de gestion qui proposait plusieurs mesures de conservation afin d'encourager l'utilisation efficace des ressources des pêcheries et de contrôler le développement de la Pêcherie de manière que le pays touche le plus de bénéfices. Une attention adéquate a été prêtée aux limitations sur les engins de la pêche, l'établissement de saisons de clôture et les législations associées. Des stratégies pour diversifier la pêche marine ont aussi été proposées. Le Plan de développement quinquennal de 1990 pour les pêcheries marines met l'accent aussi sur la gestion de ressources appropriée afin de faire reculer les tendances associées à la surexploitation des ressources marines. Selon le plan, l'accent sera mis sur les pêcheries intérieures et la mariculture afin de réduire la pression sur les pêcheries. Les pêcheries intérieures, sous la forme de l'élevage de poissons en eau douce, ont pris leur essor sur les 10 dernières années avec une production qui s'est élevée de moins de 0,5 millions de livres en 1980 pour atteindre en 1989 plus de 6.0 millions de livres. Cependant, certains pisciculteurs en eau douce expérimentent déjà une concurrence sérieuse avec les agriculteurs pour l'usage de l'eau et, dans une moindre mesure, de la terre. Le Ministère de l'Agriculture est de l'avis que l'élevage en cage marine a technologiquement le potentiel d'être introduit en Jamaïque. La technologie a été développée avec réussite en Norvège et plusieurs pays dans la région utilisent actuellement la technologie expérimentalement. La technologie, si elle était utilisée en Jamaïque, pourrait réduire de façon significative la pression sur les pêcheries, ce qui rendrait la pêche plus économique et améliorerait les rendements aux pêcheurs. Certaines capacités techniques et institutionnelles existent déjà en Jamaïque qui pourraient soutenir le développement de l'élevage en cage marine. Le Département des Pêcheries a un personnel bien formé en aquaculture et pêcherie marine, dont certains qui sont directement responsables du succès de la pisciculture en eau douce. Par ailleurs, le Laboratoire Marin à l'Université des Antilles (UWI) mène des recherches sur les installations d'écloseries pour l'élevage en cage marine. Le Département des Pêcheries demandera la collaboration de l'unité marine à l'UWI qui pourra fournir des saumoneaux d'espèces marines sélectionnées pour la cage 1.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/1993/rapport-1918.pdf
http://archimer.ifremer.fr/doc/00000/1918/

Éditeur(s) : HAL CCSD
Résumé : International audience
High Pressure - Low Temperature (HP-LT) rocks testify for burying and exhumation of crustal material in subduction zones. The question of their exhumation is nevertheless still unclear. The Aegean domain offers several HP-LT belts. Especially, the Attic-Cycladic Blueschist unit (ACBU) is an example of a HP-LT unit exhumed in a convergent and then in a divergent context. It actually appears in metamorphic core complexes (MCCs) formed in the back-arc of the subduction. The syn-convergence "message" is however difficult to read because of the post-convergence structural and thermal overprint that accompanied the formation of the MCCs. Particularly, the geometry, the timing and the amount of the syn-orogenic exhumation remain unclear. We investigate theses questions with metamorphic petrology (Andros and Ios islands) and phengite population, single grain and in situ 40Ar-39Ar geochronology (Andros, Tinos, Syros and Ios islands). Based on these new constraints and a synthesis of published data, we are able to refine the geometry, the timing and the modes of the exhumation of the ACBU. Data from the whole Cyclades exhibit little differences in the age and P-T conditions at the successive stages of syn-orogenic exhumation. The peak of pressure (500±50 °C-18±1 kbar) has been reached at 50-55 Ma. The onset of the exhumation occurred at 40-45 Ma in blueschist facies conditions, between a basal thrust and a summital detachment. The following decompression was accompanied by cooling until 30-35 Ma (400±50 °C-8±1 kbar). At that time, the boundary conditions switched to extension. The change in boundary conditions is recorded by slowing of the exhumation and isobare heating. The conditions of post-orogenic exhumation differ from an island to another. The onset of post-orogenic exhumation is dated around 30 Ma in the northern Cyclades and 25 Ma in the southern Cyclades. It is related to top-to-the-North deformation in all the studied domain. The end of ductile deformation below the detachments is also diachronous (21 Ma in the North and 18 Ma in the South). Finally, we propose a model for the final steps of the exhumation related to the intrusion of granitic bodies around 14 Ma.
American Geophysical Union, Fall Meeting
San Francisco, United States

insu-00860510
https://hal-insu.archives-ouvertes.fr/insu-00860510
BIBCODE : 2010AGUFM.T23C2301L

Éditeur(s) : HAL CCSD
Résumé : Geothermal energy is considered as a green and infinite energy source at human scale. Currently, the yield of geothermal power plants is limited to temperatures of the operating fluid which 350 °C. From tectonic and volcanic activity at mid-ocean ridges, Iceland is a location where supercritical fluid extraction (T> 375 °C) can considered for the near future. Exploiting such fluids could theoretically multiply by a factor of ten the electrical power delivered by geothermal wells. Can such fluids circulate at the base of brittle oceanic crust? This work investigates the petrophysical properties of basalts in order to constrain geophysical observations in Iceland and predict the behavior of very high temperature geo-hydrothermal reservoirs. The first approach consisted in studying the physical properties of rocks that have hosted deep hydrothermal circulations at oceanic ridges. The study of these rocks at ODP Site 1256 shows that the porosity measured both in the field and in the lab is associated with amphibolite facies alteration minerals (T> 500 ° C). The second approach was to recreate in the laboratory the conditions of pressure, temperature and pore fluid pressure of high temperature to supercritical hydrothermal systems to predict the mechanical and electrical properties of basalts under these conditions. The mechanical results indicate that the brittle/ductile transition occurs at a temperature of about 550° C, where a strong permeability decrease is expected. The implementation and calibration of a new cell for measuring electrical conductivity at high temperature provide the first results for the interpretation of geophysical data. When applied to basaltic crustal conditions in Iceland, these results indicate that hydrothermal fluids could circulate, at least temporarily, in a supercritical state up to 5 km depth.
La géothermie est considérée comme une source d'énergie propre et inépuisable à échelle humaine. Actuellement, le rendement des centrales géothermiques est limité à l'exploitation de fluides de températures inférieures à 350 °C. L'association de l'activité tectonique et volcanique aux dorsales océaniques fait de l'Islande un lieu où l'extraction de fluides supercritiques (T> 375 °C) peut être envisagée. Cette exploitation pourrait multiplier par dix la puissance électrique délivrée par le système géothermal. Ces fluides peuvent-ils circuler dans la croûte océanique ? Ce travail propose de contraindre les observations géophysiques et de prédire le fonctionnement des réservoirs géo-hydrothermaux de très haute température par l'étude des propriétés physiques des basaltes. La première approche est focalisée sur l'étude de roches ayant accueilli une circulation hydrothermale par le passé. L'étude de ces roches au site ODP 1256, montre que leur porosité est associée à la présence de minéraux d'altération hydrothermale du facies amphibolite (T> 500 °C). La seconde approche a consisté à recréer, en laboratoire, les conditions des systèmes hydrothermaux, à très haute température, afin de prédire les propriétés mécaniques et électriques des basaltes dans ces conditions. Les résultats mécaniques indiquent que la transition fragile/ductile, souvent associée à une forte décroissance de perméabilité, intervient à une température d'environ 550 °C. La mise en place d'une cellule de mesure de la conductivité électrique de haute température a fourni les premiers résultats utiles à l'analyse des données géophysiques. Appliqués aux conditions de la croûte basaltique Islandaise, ces résultats indiquent que des fluides hydrothermaux pourraient circuler au moins transitoirement à l'état supercritique jusqu'à ~ 5 km de profondeur.
https://tel.archives-ouvertes.fr/tel-00591798

tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798/document
https://tel.archives-ouvertes.fr/tel-00591798/file/THESE_MV_pro.pdf

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Electrical resistivity soundings are used by geophysicists to determine the structure and composition of the Earth's crust and mantle and to explore natural resources (ore, oil, gas, water). Their interpretations in terms of composition and in-situ physical conditions depend mainly on laboratory measurements of electrical conductivity of rocks at simulated crustal conditions of temperature, pressure, saturation and pore pressures. These measurements present a numbers of limitations, in particular, in the case where conductive pore fluids are present, as in the case of deep reservoir conditions, where temperature exceeds 250 A degrees C. Here, we present a new cell capable of measuring electrical conductivity of large saturated samples at confining pressure up to 200 MPa, pore pressure up to 50 MPa, and temperature up to 500 A degrees C. The measurement cell has been developed in a commercial, internally heated, gas pressure apparatus (Paterson press). It is based on the concept of "guard ring" electrode, which is adapted to samples that are jacketed by a very conductive, metallic material. Numerical modeling of the current flow in the electrical cell allowed defining the optimal cell geometry. Calibration tests have been performed on Fontainebleau sandstones saturated with electrolytes of different conductivities, up to 350 A degrees C. The resulting electrical formation factor and temperature dependence of electrical conductivity are in very good agreement with previous studies. This new cell will improve the exploration and exploitation of deep fluid reservoirs, as in unconventional, high enthalpy geothermal fields. In particular, the investigations address possible effects of fluid-rock interactions on electrical resistivity of a reservoir host rock.
ISSN: 0169-3913

hal-00681997
https://hal.archives-ouvertes.fr/hal-00681997
DOI : 10.1007/s11242-011-9846-2

Éditeur(s) : HAL CCSD Nature Publishing Group
Résumé : International audience
Different marine habitats are characterised by different soundscapes. How or which differences may be representative of the habitat characteristics and/or community structure remains however to be explored. A growing project in passive acoustics is to find a way to use soundscapes to have information on the habitat and on its changes. In this study we have successfully tested the potential of two acoustic indices, i.e. the average sound pressure level and the acoustic complexity index based on the frequency spectrum. Inside and outside marine protected areas of Moorea Island (French Polynesia), sound pressure level was positively correlated with the characteristics of the substratum and acoustic complexity was positively correlated with fish diversity. It clearly shows soundscape can be used to evaluate the acoustic features of marine protected areas, which presented a significantly higher ambient sound pressure level and were more acoustically complex than non-protected areas. This study further emphasizes the importance of acoustics as a tool in the monitoring of marine environments and in the elaboration and management of future conservation plans. Coral reef ecosystems are among the most biologically diverse and complex marine ecosystems worldwide. In addition to their biological and ecological importance, coral reefs support major economic and physical functions (e.g. food production, tourism, biotechnology development and coastal protection) that are essential for many countries 1. Unfortunately, coral reefs are severely threatened: 20% of coral reefs can no longer be defined as such, another 25% are currently endangered and another 25% will be endangered by 2050 2. The frequency and severity of natural perturbations (e.g. cyclone, outbreaks of predators, particularly the crown-of-thorns starfish [COTS] Acanthaster planci) and anthropogenic perturbations (e.g. ocean acidification, pesticides, rising seawater temperatures) on coral reefs have greatly increased worldwide in the last three decades, and, as a consequence, reef communities (fish, coral and benthic invertebrates) have suffered unprecedented levels of decline 3,4
ISSN: 2045-2322

hal-01370610
https://hal-uvsq.archives-ouvertes.fr/hal-01370610
https://hal-uvsq.archives-ouvertes.fr/hal-01370610/document
https://hal-uvsq.archives-ouvertes.fr/hal-01370610/file/2016%20Sci.Rep.pdf
DOI : 10.1038/srep33326

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We present an integrated study of geochemistry, petrofabrics and seismic properties of strongly sheared eclogites from the Chinese Continental Scientific Drilling (CCSD) project in the Sulu ultrahigh-pressure (UHP) metamorphic terrane, eastern China. First, geochemical data characterize diverse protoliths of the studied eclogites. The positive Eu- and Sr-anomalies, negative Nb anomaly and flat portion of heavy rare earth elements in coarse-grained rutile eclogites (samples B270 and B295) suggest a cumulate origin in the continental crust, whereas the negative Nb anomaly and enrichment of light rare earth elements in retrograde eclogites (samples B504, B15 and B19) imply an origin of continental basalts or island arc basalts. Second, P-wave velocities (V-p) of three typical eclogite samples were measured under confining pressures up to 500 MPa and temperatures to 700 degrees C. At 500 MPa and room temperature, the mean V-p reaches 8.50-8.53 km/s in samples B270 and B295 but drops to 7.86 km/s in sample B504, and the P-wave anisotropy changes from 1.7-2.7% to 5.5%, respectively. The pressure and temperature derivatives of V-p are larger in the retrograde eclogite than in fresh ones. Third, the electron backscatter diffraction (EBSD) measurements of the eclogites reveal random crystal preferred orientation (CPO) of garnet and pronounced CPO of omphacite, which is characterized by a strong concentration of [001]-axes sub-parallel to the lineation and of (010)-poles perpendicular to the foliation. The asymmetric CPO of omphacite in sample B270 recorded a top-to-the-south shear event during subduction of the Yangtze plate. The calculated fastest V-p is generally sub-parallel to the lineation, but a different deformation environment during exhumation could form second-order variations in omphacite CPO and affect the V-p distribution in eclogites (e.g., the fastest V-p is at similar to 35 degrees from the foliation in sample 13295). Comparison between measured and calculated seismic properties indicates that the CPO of omphacite controls the seismic anisotropy of eclogites at high pressure, and compositional layering and retrograde minerals will increase the anisotropy. Calculated P-wave velocities agree well with velocities measured at 500 MPa and room temperature for fresh eclogites, but much higher than those of retrograde eclogite. As a case study, the laboratory-derived V-p-P and V-p-T relationships were used to estimate P-wave velocities of eclogites and peridotites beneath the Western Superior Province, Canada. The results indicate that besides the fabric-induced anisotropy, the direction dependence of pressure and temperature derivatives of V-p can significantly increase seismic anisotropy of eclogites with depth, which results in eclogites being an important candidate for the seismic anisotropy in the upper mantle. Due to their very high density and velocity, garnet-rich eclogites within peridotite could be detected in seismic reflections in subduction zones.
ISSN: 0040-1951

hal-00463512
https://hal.archives-ouvertes.fr/hal-00463512
DOI : 10.1016/j.tecto.2008.09.027

Éditeur(s) : Université des Antilles Études caribéennes
Résumé : Las Islas Canarias, situadas en la región macaronésica, acogen ecosistemas terrestres y marinos de valiosa riqueza ecológica y paisajística, representativos de las áreas culturales y biogeográficas de su entorno; hasta el punto de albergar tres Reservas de la Biosfera reconocidas por la UNESCO. La diversidad y riqueza de este marco insular ya fue elogiada por grandes científicos como Alexander von Humboldt o Charles Darwin. Sin embargo, actualmente la presión ejercida sobre el medio por parte del desarrollo urbanístico y la industria turística, motor económico del archipiélago, pone en peligro estos frágiles ecosistemas; lo que ha generado un profundo debate entre crecimiento económico y turístico, y desarrollo sostenible y conservación. El presente artículo trata, desde una óptica divulgativa, de acercar al lector al medio que caracteriza las Islas Canarias e introducirlo en el marco donde se desarrolla parte importante de la actividad turística en España, uno de los países que más turistas recibe año a año.
Les îles Canaries, situées dans la région de la ‘Macaronésica’ (l’Est de l’Océan Atlantique), abritent des écosystèmes marins et terrestres très précieux, tant du point de vue écologique que paysager. Ils sont représentatifs de les zones biogéographiques de sa région et comptent trois Réserves da Biosphère reconnues par l’UNESCO. De grands scientifiques comme Alexander Von Humboldt et Charles Darwin ont fait l’éloge de la richesse de la biodiversité de cet archipel. Cependant, actuellement, la pression anthropique, notamment en liaison avec le développement touristique et tous les enjeux économiques qui l’accompagnent, mettent en danger les écosystèmes des Canaries ; ce constat a ouvert un large débat sur les enjeux autour des développements économique et touristiques et leurs dérives. Notre article propose de mettre l’accent sur les caractéristiques des îles Canaries et de replacer les processus de développements touristiques dans leur contexte pour ouvrir la réflexion sur les conditions nécessaires pour d’un développement durable.
The Canary Islands, located in the region of 'Macaronésica' (Este of Atlantic Ocean), are home to marine and terrestrial ecosystems very valuable, both ecological and landscape. They are representative of the bio-geographic zones of the region and there are three Biosphere Reserves da recognized by UNESCO. Great scientists such as Alexander Von Humboldt and Charles Darwin have praised the richness of the biodiversity of this archipelago. However, at present, anthropogenic pressure, including in relation to tourism development and all economic issues that accompany it, endanger ecosystems Canary Islands. This has opened a broad debate on the issues surrounding economic development and tourism and their excesses. Our article proposes to focus on the characteristics of the Canary Islands and put the process of tourist developments in their context to open reflection on the necessary conditions for sustainable development.
Canaries

Droits : info:eu-repo/semantics/openAccess
urn:doi:10.4000/etudescaribeennes.1302
http://journals.openedition.org/etudescaribeennes/1302

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Hydrogen can be stored in the structure of nominally anhydrous minerals as point defects, and these impurities substantially modify many physical properties of Earth's mantle minerals. However, mantle rocks are composed of mineral grains separated by grain boundaries and interphase grains boundaries. Therefore, as a potential hydrogen reservoir, grain boundaries should be given proper attention. Here, I report an experimental investigation into hydrogen diffusion through grain boundaries in polycrystalline aggregates Sintering and diffusion experiments were performed using a gas-medium high-pressure vessel at under pressure of 300 MPa and over a temperature range of 900-1,250 degrees C. The diffusion assembly consisted of a polycrystalline cylinder of aluminous spinel + olivine crystals with a talc cylinder as the main hydrogen source. A Ni capsule was used to buffer the oxygen fugacity at Ni-NiO Experimental durations varied from 5 min to 5 h. The presence of hydrogen in the crystals was measured by Fourier-transform infrared spectroscopy. The calculation of the diffusion coefficients was based on the estimation of the characteristic distance. The absence or presence of hydrogen recorded by the 'hydrogen sensor' olivines embedded in the aggregate allows the estimation of bounds on this characteristic distance. Results presented here suggest that hydrogen effective diffusion coefficients are only one order of magnitude faster (similar to 10(-9) m(2)s(-1) at 1,000 degrees C) than in an olivine single crystal along the [100] axis. Resulting diffusion coefficients for hydrogen in grain boundary are four orders of magnitude faster than in a single crystal, but this diffusivity is not fast enough to affect hydrogen mobility in mantle rocks with grain sizes greater than similar to 1 mm. Thus, very limited chemical homogenization would occur using grain boundaries diffusion in mantle hydrous peridotite for incompatible and volatile element, such as hydrogen.
ISSN: 0010-7999

hal-00564353
https://hal.archives-ouvertes.fr/hal-00564353
DOI : 10.1007/s00410-010-0512-4

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Convergent plate margins typically experience a transition from subduction to collision dynamics as massive continental blocks enter the subduction channel. Studies of high-pressure rocks indicate that tectonic fragments are rapidly exhumed from eclogite facies to mid-crustal levels, but the details of such dynamics are controversial. To understand the dynamics of a subduction channel we report the results of a petrochronological study from the central Sesia Zone, a key element of the internal Western Alps. This comprises two polymetamorphic basement complexes (Eclogitic Micaschist Complex and Gneiss Minuti Complex) and a thin, dismembered cover sequence (Scalaro Unit) associated with pre-Alpine metagabbros and metasediments (Bonze Unit). Structurally controlled samples from three of these units (Eclogitic Micaschist Complex and Scalaro-Bonze Units) yield unequivocal petrological and geochronological evidence of two distinct high-pressure stages. Ages (U-Th-Pb) of growth zones in accessory allanite and zircon, combined with inclusion and textural relationships, can be tied to the multi-stage evolution of single samples. Two independent tectono-metamorphic 'slices' showing a coherent metamorphic evolution during a given time interval have been recognized: the Fondo slice (which includes Scalaro and Bonze rocks) and the Druer slice (belonging to the Eclogitic Micaschist Complex). The new data indicate separate stages of deformation at eclogite-facies conditions for each recognized independent kilometer-sized tectono-metamorphic slice, between ∼85 and 60 Ma, with evidence of intermittent decompression (ΔP ∼ 0*5 GPa) within only the Fondo slice. The evolution path of the Druer slice indicates a different P-T-time evolution with prolonged eclogite-facies metamorphism between ∼85 and 75 Ma. Our approach, combining structural, petrological and geochronological techniques, yields field-based constraints on the duration and rates of dynamics within a subduction channel.
ISSN: 0022-3530

hal-01054335
https://hal.archives-ouvertes.fr/hal-01054335
DOI : 10.1093/petrology/egu029