Éditeur(s) : HAL CCSD
Résumé : This work focus on the characterization of the source and dynamic of compactional fluids during sedimentary burial, through two complementary examples of late orogenic oil‐field half‐grabens: The exhumed Lodève Permian Basin and a deep buried Jurassic basin in the North Viking Graben (North Sea).Constituting the main part of the thesis, a multi‐disciplinary approach was conducted in the Lodève Basin where Ba‐F‐Cu‐Pb polymetallic mineralized systems are trapped into synrift faults and paleokarsts in the carbonate basement at the hinge point of the rollover. The source, timing and P/T conditions of fluid migration were deduced from the analysis of the microfabric, the fluid inclusions microthermometry, and the isotopic (Sr, S, O, H) and Rare Earth Element (REE) signature. Results are then crossed with a structural and thermal modeling that consolidates the sequence and dynamics of fluid during burial.A similar approach was conducted in the North Viking Graben where fluid markers are restricted to 3D seismic and well core data. Comparable Ba‐Pb‐Zn veins are reported in basin margin, plugging one of the most important siliciclastic hydrocarbon reservoir in the substratum. This analysis provides additional constraints on basinal fluid behavior and allows us to propose a global dynamic model for various compositions of fluids and reservoirs.We conclude to a polyphase fluid sequence history including:(a) In the carbonate basement of the Lodève Basin, karstic paleocanyon incisions and associated cavities coupled to synrift fault, act as major drain for fluids. These structures are early affected by hypogen‐sulfuric karstification in response to the interaction between bacterial oxidation of sulfides entrapped within Lower Permian blackshales and the basement oxidizing aquifer.(b) Disequilibrium compaction initiates overpressure‐driven basinal fluid migration towards basin margins, characterized by temperatures around 150‐180°C and salinities between 9 et 18wt%eq.NaCl. Isotopic (Sr, S, O) and REE analyses reveal that Ba‐M+‐rich mineralizing fluids derived mainly from buried blackshales diagenesis. External fluids coming from the lower crust are also identified that play a key role in fluorite precipitation by the leaching of late hercynian granites (mean temperature of 250°C and salinity > 20wt%eq.NaCl).(c) During the synrift period, fluid overpressure is responsible for the periodic reactivation of fault plane according to seismic‐valve process, bedded‐control shearing and hydraulic brecciation at the basement‐seal interface. These mechanisms induce cyclic polymetallic mineralization by the mixing between in‐situ formation water and deep ascending basinal fluids.(d) Thermogenic fluids expulsion starts with last basinal fluids during late burial stage. Hydrocarbons thus migrate along the same regional pathways up to the rollover crest, where they are partly rerouted by the previous mineralized baffle.(e) In the Lodève basin, post‐rift exhumation of the margins led to the remobilization of synrift deposits by subaerial biochemical processes at the sulfate‐methane transition. The latter results from the interaction between the still active hydrocarbon dysmigration with a playa lake sulfate‐rich aquifer. Secondary low‐temperature barite fronts precipitate then within basement meteoric karsts.In addition to the « source to sink » model of basinal fluids, this work provides new insights on the early plugging of hydrocarbon reservoirs and for the metallogenesis of Mississippi Valley‐Type deposits.
Ce travail porte sur la caractérisation de la source et de la dynamique des fluides de bassin au cours de leur chargement à travers deux exemples complémentaires de demi‐grabens tardi‐orogéniques pétroliers : Le Bassin Permien de Lodève, aujourd’hui à l’affleurement et un bassin jurassique enfouis dans le North Viking Graben (Mer du Nord).Le coeur de la thèse concerne le Bassin de Lodève où, à partir d’une approche pluridisciplinaire intégrée, nous avons caractérisé l’architecture des minéralisations (Ba, F, Cu, Pb) piégées dans un réseau paléokarstique alimenté par les failles syn‐rift, dans le substratum carbonaté à l’apex du roll‐over. La source, le calendrier et les conditions de migration des fluides ont été approchés à partir de l’analyse de la micro‐fabrique, la microthermométrie sur inclusions fluides, les analyses isotopiques (Sr, S, O, H) et de Terres Rares. Les résultats analytiques ont été enfin croisés avec un modèle thermique et structural du bassin qui conforte la séquence et la dynamique du système fluide en cours d’enfouissement.Une démarche similaire, mais plus limitée, a été conduite dans le bassin du North Viking Graben où l’accès aux marqueurs fluides est restreint aux données de sismique 3D et de carottes. Comme à Lodève, les minéralisations Ba‐Pb‐Zn colmatent un réservoir dans le substratum à l’apex du roll‐over. Elles se présentent sous forme de ciments dans des grès ou des fractures. Cette analyse apporte des contraintes complémentaires et permet de proposer un modèle dynamique général avec des variantes en fonction de la nature des fluides et des réservoirs.On retiendra donc la séquence fluide suivante :(a) Dans le cas du bassin de Lodève sur substratum carbonaté, les chemins préférentiels de drainage se développent dans des paléocanyons N‐S couplés à un réseau de fractures et d’endokarsts météoriques. Ces derniers sont élargis en début de rifting par la dissolution hypogène sulfurique produite par l’oxydation bactérienne des sulfates et des pyrites des blackshales, au contact de l’aquifère oxydant du Cambrien.(b) Le déséquilibre de compaction initie la migration des fluides interstitiels en surpression vers les marges avec des températures autour de 150‐180°C et des salinités entre 9 et 18wt%eq.NaCl. Les analyses isotopiques (Sr, S, O) révèlent que la majorité des fluides provient de l’altération diagénétique des blackshales riches en métaux. Des interactions sont également mises en évidence avec des fluides profonds (entre 240°C et 260°C ; salinités > à 20wt%eq.NaCl), qui lessivent les granites tardi‐hercyniens.(c) Pendant le syn‐rift, les conditions de surpression de fluide permettent la réactivation cyclique des failles, les décollements stratigraphiques et la formation de brèches hydrauliques, favorisant la mise en connexion avec les réservoirs superficiels à l’apex du rollover. Le modèle de Sibson ajusté aux fluides de bassins est alors le moteur de la migration verticale.(d) Les fluides thermogéniques commencent à être expulsés avec les derniers fluides de compaction au cours d’un stade plus évolué de l’enfouissement en empruntant les mêmes chemins jusqu’à l’apex du roll over. Ils sont alors partiellement freinés et déviés par les colmatages minéralisés antérieurs.(e) A Lodève, la continentalisation des minéralisations antérieures au cours de l’exhumation post‐rift conduit à leur remaniement partiel au niveau de la transition sulfate‐méthane induite par l’interaction entre une playa évaporitique et la dysmigration des hydrocarbures. Des barytines secondaires de basse température, déprimées en Sr sont alors précipitées de manière synsédimentaire dans des karsts météoriques du socle.Outre l’illustration d’un modèle complet (source to sink) de dynamique des fluides dans un bassin, ce travail apporte de nouvelles contraintes dans l’approche du colmatage des réservoirs à hydrocarbures sur les têtes de blocs basculés et sur la genèse des gîtes miniers de type Mississippi Valley‐Type.
https://hal.archives-ouvertes.fr/tel-01457583

tel-01457583
https://hal.archives-ouvertes.fr/tel-01457583
https://hal.archives-ouvertes.fr/tel-01457583/document
https://hal.archives-ouvertes.fr/tel-01457583/file/th%C3%A8seLaurent2015V2.pdf

Éditeur(s) : HAL CCSD Société Géologique de France
Résumé : Based on a High-Resolution 3D seismic block acquired in the Gulf of Lion in 2004–2005 we investigated fluid pipes and pockmarks on the top of the interfluve between the Hérault canyon and the Bourcart canyon both created by turbidity currents and gravity flows from the shelf to the deep basin in the north-western Mediterranean Sea. Combining the geometry of the potential fluid pipes with the induced deformation of surrounding sediments leads then to the ability to differentiate between potential fluid sources (root vs source) and to better estimate the triggering mechanisms (allochtonous vs. autochtonous cause). We linked together a set of derived attributes, such as Chaos and RMS amplitude, to a 3D description of pipes along which fluids may migrate. As previously shown in other basins, the induced deformation, creating cone in cone or V-shaped structures, may develop in response to the fluid pipe propagation in unconsolidated sediments in the near surface. The level at the top of a cone structure is diachronous. It means that stratigraphic levels over this surface are deformed at the end of the migration. They collapse forming a depression called a pockmark. These pipes are the result of repeated cycles of fluid expulsion that might be correlated with rapid sea-level rise instead of sediment loading. The most recent event (MIS 2.2 stage) has led to the formation of a pockmark on the modern seafloor. It has been used as a reference for calculating the effect of a rapid sea-level rise on fluid expulsion. As all physical and geometrical parameters are constrained, we were able to define that a + 34 m of sea level rise may account for triggering fluid expulsion from a very shallow silty-sandy layer at 9 m below seafloor since the last glacial stage. This value is consistent with a sea level rise of about 102 m during this period. This study shows that the episodic nature of fluid release resulted from hydromechanical processes during sea-level rise due to the interactivity between high pressure regimes and principal in situ stresses.
ISSN: 0037-9409

hal-01667241
https://hal.archives-ouvertes.fr/hal-01667241
DOI : 10.1051/bsgf/2017190

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study analyses the interactions between deformation and reactive fluid and melt percolation, and their effects on sub-arc mantle seismic properties based on microstructural observations on mantle xenoliths extracted by the Tubaf and Edison seamounts close to the Lihir Island, in the Papua New Guinea archipelago. These xenoliths sample an oceanic lithosphere, which has experienced high-temperature deformation in the presence of fluids or melts. This was followed by metasomatism under static conditions. Syn-kinematic percolation of reactive Si-rich melts or fluids in peridotites has produced pyroxene-enrichment, grain size reduction, and dispersion of olivine crystal preferred orientation (CPO). Fourier transform infrared spectroscopy analyses show that olivine has very low water contents (1-4 wt. ppm H2O), similar to spinel peridotites from other subduction zones. These low values may record both low water solubility in olivine at low pressure and dehydration during transport and exhumation. Water contents in pyroxenes are highly variable and likely result from spatially heterogeneous melt or fluid percolation. Analysis of olivine CPO indicates dominant activation of both (010)[100] and (001)[100] slip systems, which are characteristic of deformation under high temperature, low stress, low pressure and low to moderate hydrous conditions. Fast S-wave polarization and P- and Rayleigh propagation directions are thus parallel to the mantle flow direction. The pyroxene enrichment by melt-rock reactions is accompanied by dispersion of olivine CPO and induces a significant decrease of the maximum S-wave and P-wave anisotropy in the peridotites. The calculated seismic properties also show that the lowest Vp/Vs ratios (< 1.7) mapped in fore-arc mantle may only be explained by taking in consideration the CPO-induced elastic anisotropy of the peridotites.
ISSN: 0040-1951

hal-00950058
https://hal.archives-ouvertes.fr/hal-00950058
DOI : 10.1016/j.tecto.2013.09.024

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The mantle above a subducting slab is the site of complex interactions between deformation, partial melting, fluid migration and magma transport. To constrain these interactions and their effects on olivine deformation, we analyze microstructures, crystal preferred orientations, and water contents of peridotite xenoliths entrained by andesites of the Avacha volcano, southern Kamchatka arc. These xenoliths are refractory spinel harzburgites that have coarse-grained microstructures with widely spaced subgrain boundaries and sinuous grain boundaries in olivine, consistent with deformation by dislocation creep under low deviatoric stress (< 13 MPa) and with a significant contribution from diffusional processes. Analysis of crystal preferred orientations (CPO) indicates dominant activation of high-temperature, low-stress {0kl}[100] slip systems in olivine and of(100)[001] in orthopyroxene. In most samples, coarse opx crystals, elongated parallel to the lineation, enclose small olivine grains in crystallographic continuity with neighbouring crystals, indicating crystallization of orthopyroxene at the expense of olivine as a result of reactive percolation of Si-rich fluids coeval with the high-temperature deformation. Secondary crystallization of interstitial orthopyroxene led locally to development of opx-rich lenses parallel to the foliation, characterized by a decrease in olivine grain size and dispersion of the olivine CPO without changing the dominant slip systems. Half of the samples also show acicular orthopyroxene aggregates with which is associated a fine-grained matrix composed of rounded strain-free olivine, orthopyroxene, spinel, and rare amphibole crystals. This matrix occurs pervasively along grain boundaries or forms millimeter-scale irregular lenses and anastomosing veinlets that crosscut the coarse crystals and their ductile deformation structures. Both acicular orthopyroxene and the fine-grained matrix are interpreted as resulting from reactive transport of H2O-rich fluids under static conditions, probably in the lithospheric mantle. Infrared analyses show that olivine contains 1-8 center dot 6 ppm by weight of water. These low water contents are similar to those observed in spinel peridotites from other subduction zones and probably record both the low solubility of water in olivine at low pressure and dehydration during exhumation of the xenoliths. Water contents in orthopyroxene are highly variable (25-506 ppm H2O), probably recording spatially heterogeneous interaction with fluids or melts and compositional disequilibrium in the studied samples. Change in the dominant percolation mechanism from porous flow to fracturing suggests cooling, consistent with the low temperatures estimated from pyroxene thermometry (< 800-900 degrees C). The Avacha xenoliths therefore record pervasive deformation of a region of the mantle under asthenospheric conditions, followed by its accretion to the base of the lithosphere, probably as a result of cooling of the mantle wedge. Percolation of Si-rich fluids or hydrous melts is recorded at all stages; this probably enhanced diffusion and lowered deviatoric stresses during ductile deformation, but did not change the dominant slip direction in olivine from [100] to [001].
ISSN: 0022-3530

hal-00456053
https://hal.archives-ouvertes.fr/hal-00456053
DOI : 10.1093/petrology/egp085

Éditeur(s) : HAL CCSD
Résumé : Sand intrusions (or injectites) are most often the product of post-depositional remobilization of sand leading to its injection into the surrounding rocks. While injectites were recognized for the first time nearly 200 years ago, their emplacement process has been studied for a couple of decades only, since the concepts of deep sea depositional environments have allowed us to better understand their emplacement processes. However, these processes are still relatively poorly understood. Our approach is based on the study of injectites in the Lower Congo Basin from seismic and well data, which we compare to a fossil system in the SE France basin. We have shown that: (1) In buried turbidite channel systems draping deposits on the channel flanks and terraces of channels have the same geophysical signature as 'wing-like' injectites. Finally, the only criterion for identifying seismic injectites is the presence of bedding-discordant seismic reflections, and in the best case the associated uplift of the overlying seismic reflectors. (2) Seismic-scale conical and saucer-shaped sand injectites have been identified in the Lower Congo Basin. The remobilization is likely due to overpressuring induced by the buoyancy effect of hydrocarbons trapped in the margins of a lobe buried underneath 160 m of sediment, followed by the sudden injection of fluidized sand associated with fault reactivation of faults (with a possible role of nearby salt diapirs). (3) A network of injectites (dykes, sills/wings and laccoliths) was formed in the Vocontian basin during the late Albian and/or early Cenomanian, from a lower-middle Albian turbidite channel. The emplacement is probably due to the early compartmentalization of the channel during its burial and the increase of the sedimentation rate generating overpressure; and the subsequent large influx of deep fluids triggering injection. The injection of sand was polyphased: a first episode formed the sills and another emplaced the dykes. Sills/wings and dykes propagated about 2 km laterally away from the parent sand body and about 200 m up to the surface, revealing a much more extended lateral than vertical reach, contrary to the classically accepted idea from the interpretation of seismic data. (4) The emplacement of this large network of injectites was governed by hydrofracturing. Therefore, its morphology is dependent on the host rock heterogeneity (isotropy, fractures), the paleo-stress orientation (ó3 = NW-SE) and the burial depth of the source (300-600 m) at the time of injection. The study of this fossil network allows us to define the relationship between morphology of the injected network and stress state at the time of injection. This relationship can be extrapolated to constrain the morphology of subsurface networks beyond seismicvisibility. (5) Sands injected into low permeability lithologies bear evidence to a major event of fluid escape in the studied basin, but also channeled fluids long after their formation. In this way, injectites both attest to specific episodes of fluid migration in sedimentary basins and contribute to long-lived re-routing of migrating fluids once emplaced. The injection of sand is associated with the sudden escape of fluids, probably resulting from a significant tectonic and/or sedimentary event; in addition, the architecture of injectite networks is governed by the local paleo-stress and heterogeneity in the host rock. Consequently, characterizing injectite networks is an important step in understanding the plumbing systems of continental margins, i.e. the post-depositional evolution of sedimentary basins.
Les intrusions sableuses (ou injectites) sont le plus souvent le produit de la remobilisation post-dépositionnelle des sédiments et de l'injection du sable dans les roches environnantes. Bien que reconnues pour la première fois il y a près de 200 ans, elles ne sont réellement étudiées que depuis quelques dizaines d'années, depuis que les concepts sur les environnements de dépôt dans les domaines marins profonds nous permettent de mieux comprendre les processus de mise en place. Cependant, ces processus restent encore aujourd'hui relativement mal compris. Notre approche repose sur l'étude d'injectites dans le bassin du Bas-Congo a partir de données de sismique et de puits que nous comparerons a un système fossile dans le bassin du SE de la France. Nous avons montre que : (1) Dans des systèmes de chenaux turbiditiques enfouis, les dépôts de drapage sur les marges et terrasses de chenaux présentent la même signature géophysique que les injectites de type "wing". Finalement, le seul critère sismique d'identification des injectites est la présence de réflexions sismiques sécantes vis-a-vis de la stratigraphie associée dans le meilleur des cas au soulèvement des réflecteurs sismiques sus-jacents. (2) Des injectites d'échelle sismique en forme de cône et d'assiette ont été identifiées dans le bassin du Bas-Congo. La remobilisation résulte probablement des pressions anormales induites par l'effet de flottabilité des hydrocarbures piégés dans les marges d'un lobe enfoui sous 160 m de sédiment, puis de l'injection soudaine du sable fluidise associée a la réactivation de failles (possible rôle des diapirs de sel a proximité). (3) Un réseau d'injectites (dykes, sills/wings et laccolites) s'est formé dans le bassin Vocontien entre la fin de l'Albien supérieur et/ou le début du Cénomanien, depuis un chenal turbiditique de l'Albien inférieur-moyen. La mise en place résulte probablement de la compartimentalisation précoce du chenal au cours de son enfouissement et de l'augmentation du taux de sédimentation générant la surpression et de l'apport ulterieur d'importante quantité de fluides profonds déclenchant l'injection. L'injection du sable a été polyphasée : une première injection a formé des sills et une suivante des dykes. Les sills/wings et les dykes se sont propagés latéralement au chenal source sur environ 2 km et vers la surface sur environ 200 m, mettant en évidence une forte remobilisation latérale plutôt que verticale, contrairement a l'idée classiquement admise a partir de l'interprétation des données sismiques. (4) La formation de ce large réseau d'injectites a été gouvernée par des mécanismes d'hydrofracturation. Par conséquent, sa morphologie a été dépendante des hétérogenéités de la roche hôte (milieu isotrope, fracture), des directions de paléo-contraintes (ƒÐ3 = NWSE) et de la profondeur d'enfouissement de la source (300-600 m) au moment de l'injection. L'étude de ce réseau fossile permet de définir les relations entre morphologie du réseau injecté et état de contraintes au moment de l'injection. Cette relation peut être extrapolée de façon à contraindre la morphologie des réseaux de subsurface au-delà de la visibilité sismique. (5) Les sables injectés dans des lithologies de faible perméabilité témoignent d'un épisode d'échappement de fluide important dans les bassins étudiés mais ont aussi guide les fluides longtemps après leur formation. Les injectites contribuent ainsi a l'initiation épisodique et la pérennisation de migrations de fluides dans les bassins sedimentaires. Le processus d'injection est associé a l'échappement brutal de fluides, résultant vraisemblablement d'un évènement tectonique et/ou sédimentaire important, et l'architecture des réseaux d'injectites est gouverné par les paléo-contraintes locales et les hétérogénéités de la roche hôte. Par conséquent, la caractérisation des réseaux d'injectites est une étape importante dans la compréhension de la plomberie des marges, c'est-a-dire l'évolution post-dépôt des bassins sédimentaires.
https://tel.archives-ouvertes.fr/tel-01011486

tel-01011486
https://tel.archives-ouvertes.fr/tel-01011486
https://tel.archives-ouvertes.fr/tel-01011486/document
https://tel.archives-ouvertes.fr/tel-01011486/file/These_Monnier_2013_banalisee.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : A synthesis of backscatter imagery coupled with a large 3D seismic dataset in the Lower Congo Basin (LCB) reveals a patchy distribution of features interpreted to be associated with fluid seepage from 300 m to 2500 m water depth. With the exception of one region of anomalous backscatter positive-relief mounds, all inferred seep sites occur in negative-relief pockmarks. The extensive 3D seismic dataset in the LCB offers a unique opportunity to study the plumbing system that is feeding surface cold seep systems, and in general, to reconstruct the relationship between tectonics and fluid flow in continental margins. The fluid seeps in the LCB are associated with morphologically, stratigraphically or tectonically controlled focused fluid flow. The integration of the geophysical datasets, backscatter imagery coupled to 3D seismic, clearly indicates that fluid seeps are not randomly distributed, but their seabed organization reflects 1) the location of the underlying structure (reservoir or trap) where the fluids are coming from, 2) the geometry and morphology of the reservoir/trap, and 3) the discontinuities in the sedimentary column along which fluids have migrated. In the LCB seafloor pockmarks are always associated with underlying tectonic structures (fault zones, salt diapirs, polygonal faults) or buried sedimentary bodies (turbiditic channels, erosional surfaces), whereas they never occur above sub-horizontal parallel-stratified fine-grained sediments. Even if triggering processes can not be clearly defined here, we propose a model of seafloor fluid seep organization, which represents a new tool for identifying the geometry of flow pathways and the underlying buried bodies where the fluids are originating from. This qualitative 3D model provides insight into the geohydrologic processes of continental margins.
ISSN: 0025-3227

hal-00406640
https://hal.archives-ouvertes.fr/hal-00406640
DOI : 10.1016/j.margeo.2007.06.003

Éditeur(s) : HAL CCSD
Résumé : Both short-term and long-term morphodynamics of sand barrier systems forced by moderate storm conditions have been studied significantly in the literature. However, the dynamics of the emerged beach -- from a seaside water depth of ~ 1.5 metres below the lowest tide to the back-barrier -- impacted by typhoons remain scarcely documented. This study focuses on the analysis and a better understanding of the morphologic changes of such an emerged beach, when it is forced by one typhoon, several typhoons or the combination of a summer season of typhoons and a winter season of Monsoon wave/ wind conditions. The monitoring of near-shore hydrodynamics and beach morphodynamics was performed in the Wan-Tzu-Liao sand barrier from November 2011 to August 2012. Waves, currents and water level were measured at an offshore buoy (Cigu buoy; 18 m of water depth; 1.5 km seaward the studied zone), a current profiler (4 m of water depth), and a serie of pressure sensors deployed along a cross-shore section from the lower intertidal zone up to the eolian dune. Tide was obtained from a tide gauge inside the lagoon and wind conditions were obtained respectively from an inland station and the offshore Cigu buoy. Morphodynamic changes were monitoring thanks to DGDPS surveys performed on a grid including a 300 meters long portion of sand barrier extending from the subtidal zone to the back-barrier, as well as along two cross-shore and two long-shore profiles located within the grid. Surveys were performed each week during winter and just before and after each storm during the typhoons summer season. This field methodology provided a new and very robust dataset in order to quantify sand barrier dynamics exposed to high-energy events at various time scales. Amongst the eight typhoons recorded, TALIM is the most significant and representative. Offshore wave height reached 10.34 m (Tp = 14.6 s) at Cigu buoy and 2.3 m in 4 m of water depth. Morphological changes recorded 6 m of retreat for the dune front, a 20 m large dune breaching and the occurence of a wash-over fan in the lagoon. These changes form a well-known morphodynamic responses to moderate storms. More surprisingly, TALIM drove a significant nourishment of the supratidal zone, as well as a positive sand balance on the whole sand barrier. Five other typhoons resulted in the same type of morphological responses while two typhoons resulted in a strong erosion of the whole emerged beach. During winter and spring (moderate wave conditions and strong Monsoon winds), sand moved from the beach front to the back-barrier. For the whole year, the sand barrier recorded a 12 m landward migration concomitantly with a 12 m widening without abrasion of the dune elevation.
American Geophysical Union, Fall Meeting 2013

hal-01012312
https://hal.archives-ouvertes.fr/hal-01012312

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Secondary migration is defined as the movement of hydrocarbons through relatively permeable rocks from source to trap: a two-phase flow within a porous medium. Depending on the geometry and capillary pressure distributions of carrier beds, secondary migration has both vertical and lateral components. The present paper focuses on that part of the migration where the movement is mainly vertical. Its objective is to propose a description of the dynamics governing the vertical part of secondary migration based on the main physical aspects of two-phase flow in a homogeneous porous medium. The study is illustrated by laboratory observations performed in a vertical, 2-D Hele-Shaw cell filled with a transparent porous medium where the flow of dyed oil invading a wetting fluid is visually observed. These observations help us to understand the effect of buoyant, capillary and viscous forces on the resulting flow, the relative importance of which is characterized by non-dimensional numbers. Extrapolating these observations to natural media, it is proposed that vertical secondary migration can be described as a percolation of disconnected and vertically-elongated stringers. These stringers do not move continuously but as a succession of snap-off and re-feeding events which result in a jerky upward movement. Using parameters characterizing the physical properties of the fluid and of the porous medium, the geometry and the dynamic behavior of the stringers are estimated. The width of stringers occurring during secondary migration in geological media is centimetric and their vertical size ranges from several centimeters to a few meters. An upper limit of the mean upward velocity of stringers is proposed, as well as an estimate of their spatial density and of the minimum, average horizontal distance (decametric) between two stringers. The stringers are sparsely distributed, resulting in a low average oil loss and a high efficiency of the vertical migration process.
ISSN: 0264-8172

hal-00831370
https://hal.archives-ouvertes.fr/hal-00831370
https://hal.archives-ouvertes.fr/hal-00831370/document
https://hal.archives-ouvertes.fr/hal-00831370/file/pekins-V-edited.pdf
DOI : 10.1016/j.marpetgeo.2013.04.020

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Before attaining the mantle wedge, where they trigger partial melting, volatiles released from dehydration reactions in the slab have to migrate across a relatively cold (<750 degrees C), peridotite-layer above the incoming slab. In order to unravel the mechanisms allowing for this initial stage of fluid transport, we performed a detailed field and microstructural study of metamorphic prograde peridotites in the Cerro del Almirez ultramafic massif (Betic Cordillera, Spain), where evidences of one of the most important dehydration reactions in subduction zones, the high-pressure antigorite breakdown (P = 1.6-1.9 GPa and T approximate to 680 degrees C), can be mapped in the field. This reaction led to arborescent growth of centimeter-size olivine and orthopyroxene, producing a chlorite-harzburgite with a spinifex-like texture. Microstructural observations and crystal preferred (CPO) mapping show no evidences of solid-state deformation during the prograde growth of olivine and orthopyroxene at the expenses of antigorite. However, a few tens to a hundred meters away from the reaction front, the metamorphic texture is partially obliterated by grain-size reduction in roughly planar conjugate zones, a few mm to meters wide. Grain size reduction zones (GSRZ) are characterized by (1) sharp contacts with undeformed spinifex-like texture domains, (2) important reduction of the olivine grain size (60-250 mu m), (3) olivine color change from brownish to colorless, (4) decrease in the modal amount of orthopyroxene, and (5) at the mm- to cm-scale, irregular shapes and abrupt terminations. Field and microstructural observations exclude that relative displacement took place across these GSRZ. Changes in modal composition imply reactions with fluids undersaturated in silica. Analysis of olivine crystal-preferred orientations (CPO) in GSRZ shows patterns similar, but more dispersed, than those in neighboring spinifex-like domains. It also reveals mm- to cm-scale discrete domains with rather homogeneous crystallographic orientations suggesting inheritance from the preexisting spinifex-like olivines in the host peridotite. Misorientation angles between neighboring grains in the GSRZ show peaks at similar to 5-10 degrees and similar to 20 degrees, but rotations are not crystallographically controlled. Based on these observations, we rule out the formation of the GSRZ by dynamic recrystallization during dislocation creep and propose that they record brittle deformation (microcraking) of the spinifex-like chlorite-harzburgite, probably induced by hydrofracturing at high pressure and relative low temperature conditions (680-710 degrees C). High-pressure hydrofracturing can, thus, be invoked as an efficient mechanism for fluid flow across the cold top-slab mantle layer, hence allowing the slab-derived fluids to ingress in the wedge.
ISSN: 0012-821X

hal-00534035
https://hal.archives-ouvertes.fr/hal-00534035
DOI : 10.1016/j.epsl.2010.06.029

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
An exploration 3D seismic data set from the Gjallar Ridge off mid-Norway images a giant fluid seep structure 3 × 5 km wide, which connects to late Palaeocene magmatic sills at depth. Two of the pipes that have developed as hydrothermal vents reach all the way to the modern seafloor implying that they either were active much longer than the original hydrothermal activity or have been reactivated. We combine detailed seismic analysis of the northern pipe and sandbox modeling to constrain pipe initiation and propagation. Although both the seismic data and the sandbox models suggest that fluids at depth are focused through a vertical conduit, sandbox models show that fluids ascend and reach a critical depth migration where focused migration abruptly transforms into distributed fluid flow through unconsolidated sediments. This indicates that at this level the sediments are intensely deformed during pipe propagation, creating a V-shaped structure, i.e. an inverted cone at depth and a positive relief anomaly, 5 to 10 m high, at the seafloor, which is clearly identified on 3D seismic data. Comparison of the geometries observed in sandbox modeling with the seismically observed geometries of the Giant Gjallar Vent suggests that the Giant Gjallar Vent may be a proto-fluid seep at an early stage of its development, preceding the future collapse of the structure forming a seafloor depression. Our results imply that the Gjallar Giant Vent can be used as a window into the geological processes active in the deep parts of the Vøring Basin.
ISSN: 0025-3227

hal-00772465
https://hal.archives-ouvertes.fr/hal-00772465
DOI : 10.1016/j.margeo.2012.08.010

Éditeur(s) : Elsevier Sci Ltd
Résumé : The eastern Demerara Plateau offshore French Guiana was surveyed in 2003 during the GUYAPLAC cruise (multibeam bathymetry and acoustic imagery, 6-channel seismic reflection and 3.5 kHz echo-sounding). The data show the "post-transform" Cenozoic that the series located on the outer part of the plateau (below c. 2000 m) contain at least twelve stacked mass transport deposits (MTDs) that have recorded a history of large-scale slope failure, as well as two main normal fault sets that provide possible pathways for upward fluid migration through the series, reaching at high as the uppermost MTDs. Seabed data show that the area above the failures is characterized by circular-to-elongate (slope-parallel) depressions interpreted as fluid seeps (pockmarks), some of them have been modified by along slope currents. We suggest that the development of the MTDs to results from the combinaiton of the presence of fluid overpressure at depth the geometry of the margin's deep structure, in particular the existence of a 'free borderlateral border' on the outermost plateau. Our results also emphasise the role of stratigraphic decollements within the Cenozoic series.
Marine And Petroleum Geology (0264-8172) (Elsevier Sci Ltd), 2013-09 , Vol. 46 , P. 287-303

Droits : 2013 Elsevier Ltd. All rights reserved.
http://archimer.ifremer.fr/doc/00157/26850/25316.pdf
DOI:10.1016/j.marpetgeo.2013.06.010
http://archimer.ifremer.fr/doc/00157/26850/

Éditeur(s) : HAL CCSD Springer
Résumé : The analysis of three different regions of the South- Pyrenean fold-and-thrust belt reveals that during the Tertiary compression the hydrological system was compartmentalised in time and space. During the early-middle Eocene, when the thrust front affected marine soft-sediments in the Ainsa basin, the thrust fault zones were dominated by formation fluids derived from Eocene marine waters trapped in the underlying Eocene marls, although influences of meteoric waters were also present. During the middle-late Eocene, when the thrust front emplaced marine rocks over continental redbeds in the eastern Catalan basin (L'Escala thrust), the thrust fault zones were dominated by meteoric fluids. These fluids flowed preferentially along these faults, draining laterally the meteoric fluids and acting as barriers hindering their flowing towards more external parts of the belt. During the Oligocene, the most external part of the fold-and-thrust belt in the eastern Catalan basin developed on top of a salt detachment horizon. The thrust front affected continental materials of late Eocene-Oligocene age. At this moment, the thrusts were conduits for meteoric fluids arriving from the surface and also for evolved meteoric fluids migrating over short distance upwards after being in contact with the underlying evaporitic beds. Most of the fractures show a similar sequence of microfractures. Microfractures of stage 1 formed when the sediment was poorly lithified. Microfractures of stage 2 represent the main episode of vein formation which developed when a progressive induration of the host sediment occurred. During microfracture stage 3, formed in an extensional regime, the host sediment was more indurated. The repetition of this sequence of microfractures in different fracture generations of the same outcrop indicates that the sediment induration was restricted to the vicinity of the vein. Away from the veins, the sediment remained poorly lithified during the entire deformation cycle. Calcite cement within the host rock precipitated later than the syn-compressive veins, when the sediment was more indurated. Elemental geochemistry and stable isotopes of the calcite veins indicates that early generation of microfractures is infilled by local fluids (either marine or meteoric), whereas external fluids (meteoric or evolved meteoric) infilled the main compressive stage of microfractures. The hot temperature of these fluids (157°C to 183°C in the Atiart-Arro example) indicates their circulation through deep parts of the thrust belt. The progressive increase of the 87Sr/86Sr ratio through time is due to the progressive uplift, exposure and erosion of the internal Pyrenean Axial Zone.
Thrust belts and foreland basins, from fold kinematics to hydrocarbon systems

hal-00408001
https://hal.archives-ouvertes.fr/hal-00408001
DOI : 10.1007/978-3-540-69426-7_5

Éditeur(s) : HAL CCSD Elsevier
Résumé : The seismic characteristics of focused fluid-related features such as pockmarks and carbonate build-ups on the Nigerian continental slope have been investigated using complementary seismic data sets (reprocessed 3D exploration data and 2D Very High Resolution hull-mounted and near-bottom seismic data) coupled with the results of previous studies (sedimentological, geotechnical and geochemical analyses).The results show different types of fluid-related features within the hemipelagic phase of long duration (∼1 Myr) Turbidite/Hemipelagic cycles. They are the product of the disturbance of the hosting sediments following two main distinct processes: (1) no or low sediment deposition caused by fluid escape associated with seafloor settlement (benthic fauna, carbonate precipitation, gas hydrate formation) and (2) post-depositional erosion, caused either by fluid release (dewatering from underlying features such as channels and upward migration from a deep source) or by collapse (destabilisation of gas hydrates). The temporal evolution reveals a decrease in fluid flow during the hemipelagic deposition as witnessed by the decrease in methanogenic activity and by gas hydrate destabilisation. The spatial distribution of fluid-related features seems to be controlled by the type of fault (small fault or structural lineament).
ISSN: 0264-8172

hal-01685513
https://hal.archives-ouvertes.fr/hal-01685513
DOI : 10.1016/j.marpetgeo.2017.10.004

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
Large-scale conical and saucer-shaped sand injectites have been identified in the Upper Miocene sediments of the Lower Congo Basin. These structures are evidenced on the 3D high-resolution seismic data at about 600 ms TWT (two-way traveltime) beneath the seabed. The conical and saucer-shaped anomalies range from 20 to 80 m in height, 50 to 300 m in diameter, and 10 to 20 ms TWT in thickness. They are located within a sedimentary interval of about 100 m in thickness and are aligned over 20 km in dip direction (NE-SW), above the NW margin of an underlying Upper Miocene submarine fan. We have interpreted the conical and saucer-shaped anomalies as upward-emplaced sand injectites sourced from the Upper Miocene fan because of their discordant character, the postsedimentary uplifting of the sediments overlying the cones and saucer-shaped bodies, the alignment with the lateral fringe of the Upper Miocene submarine fan, and the geological context. Sand injection dates from the Miocene-Pliocene transition (approximately 5.3 Ma). The prerequisite overpressure to the sand injection process may be due to the buoyancy effect of hydrocarbons accumulated in the margins of the fan. Additionally, overpressure could have been enhanced by the lateral transfer of fluids operating in the inclined margins of the lobe. The short duration of sand injection and the presence of many sandstone intrusions suggested that the process of injection was triggered by an event, likely due to a nearby fault displacement related to diapiric movements. This is the first time that sand injectites of seismic scale have been described from the Lower Congo Basin. The localized nature of these injectites has led to a change in the migration path of fluids through the sedimentary cover. Consequently, the sand intrusions are both evidence and vectors of fluid migration within the basin fill.
ISSN: 1468-8115

hal-00963594
https://hal.archives-ouvertes.fr/hal-00963594
DOI : 10.1111/gfl.12057

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
The upward oil migration in a transparent and rough fracture containing a liquid of higher density is studied experimentally using a light transmission technique. The aperture heterogeneity is also measured by light transmission. The injection of oil in a fracture containing a heavier fluid produces a gravitational fingering instability. Depending on the injection velocity (capillary number, Ca) and the density difference between the two fluids (Bond number, Bo), different patterns are observed during the oil displacements. The width of the finger and its velocity are measured as a function of Bo and Ca. A stability analysis of the interface, based on a generalised Darcy equation in a two-dimensional fracture, allows an accurate description of the experimental results. The order of magnitude of the finger width and its velocity are in good agreement with the calculations, with small disparities due to various unknown fluid flow parameters: capillary pressure, finger thickness in the gap of the fracture, finger tortuosity and oil velocity field into the finger. The theoretical approach allows constructing a (Ca, Bo) phase diagram of stability of the interface.
ISSN: 0169-3913

hal-00429329
https://hal.archives-ouvertes.fr/hal-00429329
DOI : 10.1007/s11242-009-9340-2

Éditeur(s) : HAL CCSD Elsevier
Résumé : The uppermost mantle in back arc regions is the site of complex interactions between partial melting, melt percolation, and fluid migration. To constrain these interactions and evaluate their consequences on geochemical cycles, we carried out an in situ trace element and water study of a suite of spinel peridotite xenoliths from two regions of the Japan back arc system, Ichinomegata (NE Japan) and Oki-Dogo (SW Japan), using LA-ICPMS and FTIR spectrometry, respectively. This study provides the first full dataset of trace element and hydrogen compositions in peridotites including analyses of all their main constitutive silicate minerals: olivine, orthopyroxene and clinopyroxene. The Ichinomegata peridotites sample a LREE-depleted refractory mantle (Mg# olivine = 0.90; Cr# spinel = 0.07–0.23; Yb clinopyroxene = 7.8–13.3 × C1-chondrite, and La/Yb clinopyroxene = 0.003–0.086 × C1-chondrite), characterized by Th-U positive anomalies and constant values of Nb/Ta. The composition of the studied Ichinomegata samples is consistent with that of an oceanic mantle lithosphere affected by cryptic metasomatic interactions with hydrous/aqueous fluids (crypto-hydrous metasomatism). In contrast, the Oki-Dogo peridotites have low Mg# olivine (0.86–0.93) and a broad range of compositions with clinopyroxene showing “spoon-shaped” to flat, and LREE-enriched patterns. They are also characterized by their homogeneous compositions in the most incompatible LILE (e.g., Rb clinopyroxene = 0.01–0.05 × primitive mantle) and HFSE (e.g., Nb clinopyroxene = 0.01–2.16 × primitive mantle). This characteristic is interpreted as resulting from various degrees of melting and extensive melt-rock interactions. FTIR spectroscopy shows that olivine in both Ichinomegata and Oki-Dogo samples has low water contents ranging from 2 to 7 ppm wt. H2O. In contrast, the water contents of pyroxenes from Ichinomegata peridotites (113–271 ppm wt. H2O for orthopyroxene, and 292–347 ppm wt. H2O for clinopyroxene) are significantly higher than in Oki-Dogo peridotites (9–35 ppm wt. H2O for orthopyroxene, and 15–98 ppm wt. H2O for clinopyroxene). This indicates a relationship between melt-rock interaction and water concentrations in pyroxenes. Our study suggests that the water content of the Japan mantle wedge is controlled by the late melt/fluid/rock interactions evidenced by trace element geochemistry: a mechanism triggered by magma-rock interactions may have acted as an efficient dehydrating process in the Oki-Dogo region while the Ichinomegata mantle water content is controlled by slab-derived crypto-hydrous metasomatism.
ISSN: 0016-7037

hal-01553105
https://hal.archives-ouvertes.fr/hal-01553105
DOI : 10.1016/j.gca.2017.03.042

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
We analyse the fluid flow regime within sediments on the Eastern levee of the modern Mississippi Canyon using 3D seismic data and downhole logging data acquired at Sites U1322 and U1324 during the 2005 Integrated Ocean Drilling Program (IODP) Expedition 308 in the Gulf of Mexico. Sulphate and methane concentrations in pore water show that sulphate-methane transition zone, at 74 and 94 m below seafloor, are amongst the deepest ever found in a sedimentary basin. This is in part due to a basinward fluid flow in a buried turbiditic channel (Blue Unit, 1000 mbsf), which separates sedimentary compartments located below and above this unit, preventing normal upward methane flux to the seafloor. Overpressure in the lower compartment leads to episodic and focused fluid migration through deep conduits that bypass the upper compartment, forming mud volcanoes at the seabed. This may also favour seawater circulation and we interpret the deep sulphate-methane transition zones as a result of high downward sulphate fluxes coming from seawater that are about 5-10 times above those measured in other basins. The results show that geochemical reactions within shallow sediments are dominated by seawater downwelling in the Mars-Ursa basin, compared to other basins in which the upward fluid flux is controlling methane-related reactions. This has implications for the occurrence of gas hydrates in the subsurface and is evidence of the active connection between buried sediments and the water column.
ISSN: 1468-8115

hal-00590501
https://hal.archives-ouvertes.fr/hal-00590501
DOI : 10.1111/j.1468-8123.2010.00304.x

Éditeur(s) : HAL CCSD
Résumé : Fault zones are major discontinuities in sedimentary basins. Understanding their role on fluid migrations is an essential issue to (i) characterize the mechanisms and kinematics of deformation and (ii) to determine the parameters which control the distribution of energetic or mineral resources. This work applies to faulting under a temperature range of 200-250°C, corresponding to that of deeply buried reservoirs as well as potentially seismogenic fault zones. The studied faults are normal faults affecting the “Grès d’Annot” Formation, a Priabonian-Rupelian siliclastic turbidite succession of the Alpine foreland basin. They are located in two distinct areas: the Moutière-Restefond area in the eastern part of the basin and the Estrop area in the western part. Vitrinite reflectance outside fault zones indicates maximal temperatures of 240-260°C at Moutière-Restefond and 170-200°C at Estrop, i.e. burial depths around 8 km and 6 km, respectively, assuming a mean geothermal gradient of 30°C/km. Burial was due to underthrusting below the Embrunais-Ubaye Alpine nappes, the difference in burial between the two areas traducing the westward taper of the nappe front.The studied faults affect alternating arkosic sandstone beds and pelite layers with offsets from centimeters to decameters. Two types of core zones are recognized: (1) the foliated core zones of the Moutière-Restefond area, where deformation dominated by pressure solution and synkinematic phyllosilicate neoformation resulted in a foliated fabric, and (2) the core zones of the Estrop area, characterized by dilatant quartz-mineralized veins and breccia. Fault and host rock petrophysical properties were measured on drill plugs, using the water porosity technique and nitrogen permeability technique under 2 Mpa of confining pressure. In the Moutière-Restefond fault zones, plug axes were oriented in three orthogonal directions corresponding to the main deformation axes (X, Y, Z) of the foliated arkose to characterize the effect of structural anisotropy. In the Estrop fault zones, where deformation does not show equivalent anisotropy, the plug axes were oriented according to the main fault plane orientation (i.e., parallel to azimuth, parallel to dip and normal). In each fault zone, the porosity of fault rocks is equivalent to that of host rocks. In the Moutière-Restefond fault zones, the plugs parallel to the X and Z axes of deformation have a permeability similar to that of the host rocks, whereas permeability parallel to the Y axis (i.e. parallel to the foliation and the main fault plane) is one order of magnitude higher. By contrast, the permeability values in the Estrop fault zones are isotropic and equivalent to the host rock values. This study highlights the importance of various types of deformation mechanisms and related fluid-rock interactions in determining different fault rock types within a similar protolith, ultimately controlling distinct petrophysical properties of fault zones.
Les zones de failles constituent des discontinuités majeures dans la croûte supérieure. Ce mémoire s’intéresse aux failles actives à des profondeurs de 5-8 km, i.e. dans des conditions pouvant jouer un rôle important (i) sur le comportement mécanique de de la croûte, en particulier sur son potentiel sismogénique et (ii) sur la compartimentation des réservoirs géologiques profondément enfouis.Les failles étudiées sont des failles normales (rejet jusqu’à 50 mètres) affectant des alternances de bancs de grès arkosiques et de pélites dans les Grès d’Annot, une formation turbiditique d’âge priabonien-rupélien du bassin d’avant-chaine alpin. Les Grès d’Annot ont été enfouis sous les nappes de l’Embrunais-Ubaye peu de temps après leur dépôt et exhumés au Miocène moyen-supérieur. L’étude a été réalisée dans deux secteurs des Alpes de Haute-Provence, (1) le secteur de l’Estrop (chaine des Trois Evéchés, dans la partie occidentale du bassin) et (2) le secteur de Point Vert-Restefond (alentours du col de la Bonette, dans la partie orientale du bassin). La réflectance de la vitrinite dans les Grès d’Annot indique des températures maximales de 160-190°C dans le secteur (1) et de 240-260 °C dans le secteur (2) , soit des profondeurs d’enfouissement de 5-6 km et 8-10 km, respectivement, dans l’hypothèse d’un gradient géothermique moyen de 25-30°C/km. A partir des observations microstructurales, de données d’inclusions de fluides, de modélisations thermodynamiques sur chlorites syncinématiques et des indices de cristallinité de l’illite, on a établi que les failles du secteur (1) ont fonctionné à une température d’environ 200°C pour une pression de 0.6Kbar et celles du secteur (2) dans une gamme de température de 200-220°C et de pression comprise entre 0.6 et 1.1 Kba. L’activité de la faille de Point-Vert a été datée par la méthode 40Ar/39Ar au Miocène inférieur (21 Ma). Ces failles sont interprétées comme associées aux premiers stades du soulèvement résultant de l’activité des chevauchements dans le socle sous-jacent.Deux types principaux de roches de failles caractérisent les failles étudiées. Les brèches dilatantes sont majoritaires dans les zones de failles du secteur (1) alors que les arkoses foliées sont majoritaires dans les zones de failles du secteur (2). Les brèches dilatantes témoignent de mécanismes de déformation dominés par la fracturation transgranulaire et la pression-solution des silicates. Ce dernier mécanisme se manifeste principalement par d’abondantes précipitations cycliques de quartz, les stylolites restant peu développés. Les géométries structurales sont associées à l’activation de plans T de Riedel déterminant l’ouverture de relais extensifs et un régime localement dilatant. Nous associons ce type de roche de faille à une faible pression effective au cours de la déformation.La déformation cisaillante exprimée dans les arkoses foliées témoigne de mécanismes de déformation dominés par (i) la fracturation intragranulaire et transgranulaire, (ii) la pressionsolution/ précipitation des silicates, principalement le quartz, (iii) la néoformation de micas blancs liée à l’altération des feldspaths et (iv) la précipitation de chlorite. Ce travail montre également que les transformations minéralogiques liées aux interactions fluide-roche dans la zone de faille (forte augmentation de la proportion des phyllosilicates au dépend des feldspaths) changent radicalementla composition minéralogique de la roche. Nous associons ce type de roche de faille à une forte pression effective au cours de la déformation.La pétrophysique montre que les brèches de failles (secteur 1) ont une perméabilité isotrope et équivalente à celle du protolithe (10-3mD sous 2 MPa de confinement) tandis que les roches foliées (secteur 2) montrent une augmentation de perméabilité (10-2mD) selon l’axe Y de la déformation, d’un ordre de grandeur supérieure aux perméabilités suivant les axes X et Z et dans la roche hôte (10-3mD). Ce drain préférentiel potentiel est associé à l’orientation des phyllosilicates dans la foliation.
https://hal.archives-ouvertes.fr/tel-01310382

tel-01310382
https://hal.archives-ouvertes.fr/tel-01310382
https://hal.archives-ouvertes.fr/tel-01310382/document
https://hal.archives-ouvertes.fr/tel-01310382/file/Th%C3%A8seCAVAILHES2012.pdf

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Most kimberlites contain abundant dunitic nodules. These are centimetre-sized, rounded and multi-grained assemblages of xenocrystic olivine with a wide range of compositions (Fo83 to Fo94). The absence of orthopyroxene and other mantle minerals and the range of olivine compositions have been attributed to reaction between mantle peridotite and (proto)kimberlitic fluid or melt, but the timing of the reaction is a subject of debate. In a kimberlite from the Kangamiut region of Greenland, nodule cores are surrounded by fine-grained outer margins with near-constant Fo contents (∼Fo88) but highly variable minor element contents (e.g. 500–2500 ppm Ni). These margins crystallized from the kimberlite melt and we show that their compositions can be explained by crystallization of olivine alone, if a high partition coefficient for Ni between melt and olivine (DNi > 20) is assumed. Orthopyroxene assimilation is not required, removing the constraint that its dissolution occurred during ascent of the kimberlite magma. Within some nodules, in addition to the usual core-to-margin gradients, we observe asymmetric compositional changes (variable Fo but near-constant minor element contents) across mobile grain boundaries. These changes document fluid percolation at the grain scale that occurred during dynamic recrystallization in the deforming lithospheric mantle. We note that chemical gradients associated with mobile grain boundaries are observed in olivines that cover the entire compositional range of the nodules, and propose that fluid-assisted dynamic recrystallization took place in dunite that was already compositionally heterogeneous. Reaction between peridotite and protokimberlitic melt or fluid and dissolution of orthopyroxene thus occurred within the lithospheric mantle, immediately (a few days) prior to the ascent of the kimberlite melt and the entrainment of the dunite nodules. We propose that the grain boundary zones probably mimic, at a fine scale, the fluid–peridotite interaction that caused, at a larger scale, orthopyroxene dissolution and formation of compositionally diverse olivine in kimberlites.
ISSN: 0022-3530

hal-01277963
https://hal.archives-ouvertes.fr/hal-01277963
DOI : 10.1093/petrology/egv054

Éditeur(s) : HAL CCSD
Résumé : International audience
The Jaca basin is a thrust-sheet top basin transported southward andunderlain by basement and cover thrusts separated by a Triassic décollement.Basin-fill upper Cretaceous to lower Oligocene synorogenic sequencesrecord a southward depocenter migration, while growth stratadate a shift of deformation from the mid-Eocene in the N to the earlyMiocene in the S (S-Pyrenean front). However, the deep geometry andkinematic relationships between the cover and basement thrusts remainnon-consensual. We present a new structural and kinematic interpretationfor the eastern Jaca basin, based on subsurface structural maps andcross-sections constructed using industrial seismic reflection profiles.Raman Spectroscopy of Carbonaceous Material (RSCM), vitrinite reflectanceand apatite fission track (AFT) thermochronology data givefurther constraints for the restoration of the deformation and burialexhumationsequence. We define 3 main basement thrusts under thenorthern part of the basin, from N to S the Broto, Fiscal and Guargathrusts. The study also clarifies the deep structure of the cover thrustsand their links with these basement thrusts and those located more tothe north in the Axial Zone (AZ), which altogether define the timing ofthe basement thrust sequence as follows : the Lakoura-Eaux Chaudesthrust system (northern AZ) active up to the end Bartonian, the Gavarnie(central AZ) and Broto thrusts during the Priabonian-Rupelian andthe Fiscal and Guarga thrusts during the late Oligocene-early Miocene.AFT results in the basin fill and AZ date the exhumation of the basinto the late Oligocene-early Miocene, in relation to the Fiscal-Guargathrusting. AFT partial reset argues for a maximum burial < 6 km forthe base of the Eocene detrital sequence (Hecho Group turbidites). Bycontrast, RSCM and vitrinite thermometry at the same level indicatesTmax around 180°C, locally up to 240°C, attesting to a temperature anomalypossibly related to transient fluid circulation.
24 ème Réunion des sciences de la Terre 2014
Pau, France

insu-01080836
https://hal-insu.archives-ouvertes.fr/insu-01080836