Éditeur(s) : HAL CCSD
Résumé : Geothermal energy is considered as a green and infinite energy source at human scale. Currently, the yield of geothermal power plants is limited to temperatures of the operating fluid which 350 °C. From tectonic and volcanic activity at mid-ocean ridges, Iceland is a location where supercritical fluid extraction (T> 375 °C) can considered for the near future. Exploiting such fluids could theoretically multiply by a factor of ten the electrical power delivered by geothermal wells. Can such fluids circulate at the base of brittle oceanic crust? This work investigates the petrophysical properties of basalts in order to constrain geophysical observations in Iceland and predict the behavior of very high temperature geo-hydrothermal reservoirs. The first approach consisted in studying the physical properties of rocks that have hosted deep hydrothermal circulations at oceanic ridges. The study of these rocks at ODP Site 1256 shows that the porosity measured both in the field and in the lab is associated with amphibolite facies alteration minerals (T> 500 ° C). The second approach was to recreate in the laboratory the conditions of pressure, temperature and pore fluid pressure of high temperature to supercritical hydrothermal systems to predict the mechanical and electrical properties of basalts under these conditions. The mechanical results indicate that the brittle/ductile transition occurs at a temperature of about 550° C, where a strong permeability decrease is expected. The implementation and calibration of a new cell for measuring electrical conductivity at high temperature provide the first results for the interpretation of geophysical data. When applied to basaltic crustal conditions in Iceland, these results indicate that hydrothermal fluids could circulate, at least temporarily, in a supercritical state up to 5 km depth.
La géothermie est considérée comme une source d'énergie propre et inépuisable à échelle humaine. Actuellement, le rendement des centrales géothermiques est limité à l'exploitation de fluides de températures inférieures à 350 °C. L'association de l'activité tectonique et volcanique aux dorsales océaniques fait de l'Islande un lieu où l'extraction de fluides supercritiques (T> 375 °C) peut être envisagée. Cette exploitation pourrait multiplier par dix la puissance électrique délivrée par le système géothermal. Ces fluides peuvent-ils circuler dans la croûte océanique ? Ce travail propose de contraindre les observations géophysiques et de prédire le fonctionnement des réservoirs géo-hydrothermaux de très haute température par l'étude des propriétés physiques des basaltes. La première approche est focalisée sur l'étude de roches ayant accueilli une circulation hydrothermale par le passé. L'étude de ces roches au site ODP 1256, montre que leur porosité est associée à la présence de minéraux d'altération hydrothermale du facies amphibolite (T> 500 °C). La seconde approche a consisté à recréer, en laboratoire, les conditions des systèmes hydrothermaux, à très haute température, afin de prédire les propriétés mécaniques et électriques des basaltes dans ces conditions. Les résultats mécaniques indiquent que la transition fragile/ductile, souvent associée à une forte décroissance de perméabilité, intervient à une température d'environ 550 °C. La mise en place d'une cellule de mesure de la conductivité électrique de haute température a fourni les premiers résultats utiles à l'analyse des données géophysiques. Appliqués aux conditions de la croûte basaltique Islandaise, ces résultats indiquent que des fluides hydrothermaux pourraient circuler au moins transitoirement à l'état supercritique jusqu'à ~ 5 km de profondeur.
https://tel.archives-ouvertes.fr/tel-00591798

tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798/document
https://tel.archives-ouvertes.fr/tel-00591798/file/THESE_MV_pro.pdf

Éditeur(s) : HAL CCSD Oxford University Press (OUP): Policy B - Oxford Open Option A Oxford University Press (OUP)
Résumé : International audience
Peridotites exhumed in the footwall of axial detachment faults at slow-spreading ridges are highly serpentinized. Most mid-ocean ridge detachment settings are magmatically active and hydrous fluid circulation in and near the fault has been shown to be influenced by the presence of melt or magmatic lithologies. Our working area along the Southwest Indian Ridge (62–65°E) is nearly amagmatic and represents an end-member to study the hydrous alteration of exhumed peridotites without these magmatic influences. We use an integrated petrological approach combining microstructural, mineralogical and chemical observations to unravel the sequence of serpentinization in 272 dredged samples of variably serpentinized peridotites and to document the circulation of serpentinizing fluids in and near the exhumation faults. We find that serpentine recrystallization and veins overprint the initial serpentinite mesh texture in ∼25% of the samples. Oxygen isotope data suggest that this sequence developed at relatively high temperatures (271–336°C) and under increasing fluid–rock ratios, from near stoichiometry for mesh texture formation to >10 during recrystallization. Increasing fluid supersaturation relative to serpentine favors the replacement of mesh texture lizardite by chrysotile and polygonal or polyhedral serpentine. We attribute local recrystallization into antigorite to moderate Si-metasomatism, possibly following pyroxene serpentinization. We do not observe the more pronounced Si-metasomatism leading to talc replacing serpentine that is reported for the more magmatically active Mid-Atlantic Ridge detachment settings and is attributed to prior leaching of magmatic rocks. Scales of preferential fluid pathways in our samples evolved from pervasive and close-spaced (<500 µm) microfractures during the formation of the initial serpentine mesh texture, to centimeter-thick planar domains of enhanced fluid flux, spaced at ∼10 cm intervals and probably grouped in corridors that may be up to ∼100 m across. Serpentine minerals are enriched in some fluid-mobile elements (Cl, B, U) relative to the peridotite protolith, and several elements (Al, Fe, Si, Cu, As, Sb, REE) are redistributed at the millimeter to decimeter scale. Serpentinizing fluids were seawater-derived, probably mildly alkaline (small to no europium anomalies), reducing and H2-enriched (formation of magnetite). These fluids may have been similar to, though warmer than, those venting at the ultramafic-hosted Lost City hydrothermal fluid (30°N, Mid-Atlantic Ridge).
ISSN: 0022-3530

hal-01174047
https://hal.archives-ouvertes.fr/hal-01174047
DOI : 10.1093/petrology/egv014

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
The brittle to ductile transition (BDT) in rocks may strongly influence their transport properties (i.e., permeability, porosity topology ...) and the maximum depth and temperature where hydrothermal fluids may circulate. To examine this transition in the context of Icelandic crust, we conducted deformation experiments on a glassy basalt (GB) and a glass-free basalt (GFB) under oceanic crust conditions. Mechanical and micro-structural observations at a constant strain rate of 10(-5) s(-1) and at confining pressure of 100-300 MPa indicate that the rocks are brittle and dilatant up to 700-800 degrees C. At higher temperatures and effective pressures the deformation mode becomes macroscopically ductile, i.e., deformation is distributed throughout the sample and no localized shear rupture plane develops. The presence of glass is a key component reducing the sample strength and lowering the pressure of the BDT. In the brittle field, strength is consistent with a Mohr-Coulomb failure criterion with an internal coefficient of friction of 0.42 for both samples. In the ductile field, strength is strain rate-and temperature-dependent and both samples were characterized by the same stress exponent in the range 3 < n < 4.2 but by very different activation energy Q(GB) = 59 +/- 15 KJ/mol and Q(GFB) = 456 +/- 4 KJ/mol. Extrapolation of these results to the Iceland oceanic crust conditions predicts a BDT at similar to 100 degrees C for a glassy basalt, whereas the BDT might occur in non-glassy basalts at deeper conditions, i.e., temperatures higher than 550 +/- 100 degrees C, in agreement with the Icelandic seismogenic zone.
ISSN: 0148-0227

hal-00760905
https://hal.archives-ouvertes.fr/hal-00760905
DOI : 10.1029/2011JB008884

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
During compressive events, deformation in sedimentary basins is mainly accommodated by thrust faulting and related fold growth. Thrust faults are generally rooted in the basement and may act as conduits or barriers for crustal fluid flow. Most of recent studies suggest that fluid flow through such discontinuities is not apparent and depends on the structural levels of the thrust within the fold-and-thrust belt. In order to constrain the paleofluid flow through the Jaca thrust-sheet-top basin (Paleogene southwest-Pyrenean fold-and-thrust belt) this study compares on different thrust faults located at different structural levels. The microstructures in the different fault zones studied are similar and consist of pervasive cleavage, calcite shear veins (SV1), extension veins (EV1) and late dilatation veins (EV3). In order to constrain the nature and the source of fluids involved in fluid-rock interactions within fault zones, a geochemical approach, based on oxygen and carbon stable isotope and trace element compositions of calcite from different vein generations and host rocks was adopted. The results suggest a high complexity in the paleohydrological behaviors of thrust faults providing evidence for a fluid-flow compartmentalization within the basin. Previous studies in the southern part of the Axial Zone (North of the Jaca basin) indicates a circulation of deep metamorphic water, probably derived from the Paleozoic basement, along fault zones related to the major basement Gavarnie thrust. In contrast, in northern part of the Jaca basin, the Monte Perdido thrust fault is affected by a closed hydrological fluid system involving formation water during its activity. The Jaca and Cotiella thrust faults, in turn, both located more to the south in the basin, are characterized by a composite fluid flow system. Indeed, stable isotope and trace element compositions of the first generations of calcite veins suggest a relatively closed paleohydrological system, whereas the late calcite vein generations, which are probably associated with the late tectonic activity of the basin, support a contribution of both meteoric and marine waters. Based on these results, a schematic fluid-flow model is presented. This model allows visualization of three main fluid flow compartments along a N-S transect.
ISSN: 0264-8172

hal-00963606
https://hal.archives-ouvertes.fr/hal-00963606
DOI : 10.1016/j.marpetgeo.2013.09.005

Éditeur(s) : HAL CCSD Elsevier
Résumé : Understanding chemical element mobility during high-pressure metamorphism is paramount to the knowledge of the transformations occurring during the course of eclogite-facies metamorphism. In particular, the role of deformation and fluid circulation appear essential. In order to better decipher this role, we investigated two eclogite-facies samples from the Lindas Nappe in the Bergen arcs (Norwegian Caledonides), which are related to a fluid/deformation metamorphic event. This study, based on detailed microtextural investigations, coupled with major and trace element analyses, either in situ EMPA and LA-ICP-MS or by conventional ICP-MS nebulisation on mineral fractions, illustrates the complexity of chemical reactions accompanying the eclogite- and amphibolite-facies metamorphism. A single eclogite-facies mineral species two eclogite-facies (i.e. phengite and epidote) depicts various chemical features depending on its textural location at thin-section scale. The correlation with the mineralogical reaction occurring in each textural site demonstrates that the compositional variations are inherited from the precursor minerals. Thus, the composition of eclogite-facies minerals is locally controlled by the composition of few hundred-micron domains. On the contrary, alteration phases of the amphibolite facies (symplectite and calcic amphibole) display clear enrichment in LILE, Pb, Sr and LREE compared to their precursor minerals (omphacite and garnet). This supports that the transport of elements at hand-sample scale was enhanced during the retrogression and elements were efficiently delocalised from one textural site to another. The contrasting behaviour of element mobility between peak eclogite-facies metamorphism and retrogression can be explained in terms of rate processes and fluid/deformation activity. During eclogitisation,deformation allows the formation of textural and mineralogical microdomains. Contemporaneously the fluid circulation favours the development of heterogeneities by transport of elements in excess towards areas protected from deformation where phengite-bearing quartz lenses crystallise. This, together with the very fast recrystallisation of eclogite-facies minerals, results in a heterogeneous redistribution of elements at sample scale and in a chemical disequilibrium between different microdomains of hundred-micron size. During retrogression in the amphibolite facies, coeval with long-term ductile deformation, the fluids act as an efficient vector to redistribute the elements from a given textural site to another and, thus, allow to reach, at hand-sample scale, a new chemical equilibrium between the different crystallising phases.
ISSN: 0024-4937

hal-00404602
https://hal.archives-ouvertes.fr/hal-00404602
DOI : 10.1016/j.lithos.2006.10.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A reactive percolation experiment was conducted by injecting seawater into a permeable olivine aggregate at 190 °C and 19 MPa to explore the relationships between hydration reactions and hydrodynamic properties during the onset of serpentinization in the ultramafic lithosphere exposed at mid-ocean ridges. The experiment was stopped after 23 days when the sample became impermeable. The initial flow rate was 0.2 mL/h and then was decreased down to 0.06 mL/h after 8 days. Permeability decreased continuously throughout the experiment. The analyses of fluid chemistry time series and of the mineralogy and structure of the reacted sample showed olivine dissolution and precipitation of proto-serpentine, brucite and Fe-oxides. These reactions are controlled by coupled hydrodynamic and chemical processes interacting at different time and spatial scales. Their first characteristic is the production of silica rich outlet fluids in disequilibrium with the observed reacted mineral assemblages. These compositions are interpreted as resulting from a suite of coupled dissolution-precipitation reactions, controlled at the pore scale by surface kinetic processes, that rapidly reaches steady-state (constant fluid composition independent of fluid flux). Hence, the effective rate of serpentinization was controlled, to the first order, by the transport of reactants during the experiment. Mass balance calculations show that the rate of olivine conversion was fast (0.2-0.5 wt%/day), yet only ∼8 wt% of the olivine sample reacted, because the permeability drop limited fluid circulation. Porosity varied little during the experiment compared to permeability changes: the decrease of permeability was explained by the structure of the newly formed serpentine favouring the clogging of fluid paths. The rate at which permeability decreased was the fastest at low flux conditions. This suggests that permeability changes were not controlled simply by the kinetics of the serpentinization reactions, but mainly reflected the development of low Peclet pore scale zones forming micro-environments that control the serpentinization reaction-paths. These results outline the need to take into account the coupling of hydrodynamic and chemical processes when modelling the effects of reactive transport within the hydrating oceanic lithosphere.
ISSN: 0012-821X

hal-00855043
https://hal.archives-ouvertes.fr/hal-00855043
DOI : 10.1016/j.epsl.2013.03.052

Éditeur(s) : Gauthier-villars
Résumé : 69 new hydrothermal sites were discovered during the Naudur diving cruise. Dives were conducted between 17 degrees 5 and 18 degrees 40'5 on four segments showing marked contrast in morphology, volcanic, tectonic and hydrothermal activity. At 17 degrees 10'5, 17 degrees 25'5 and 18 degrees 37'5 the ridge has a dome shaped cross-section and is dominated by very active volcanic activity. Early widespread low temperature (<50 degrees C) diffuse hydrothermal discharge is followed by focused high temperature black smokers. At 18 degrees 15'S tectonic activity is dominant, no recent lava was observed, and only two of the 20 hydrothermal sites are active. At 18 degrees 32'5 recent lava representing a new volcanic episode partly covers the bottom of the graben. Deep hydrothermal convection is reactivated with new black smokers along the graben wall. Also, there is low temperature shimmering water from cooling lava flows. These three segments can be considered as successive volcanic/tectonic episodes typical of a fast spreading ridge. Further, the observations support a new model for the temporal evolution of episodic hydrothermal activity. Hydrothermal convection is unstable and superficial during the volcanic stage (dykes injection). At the beginning of the teaonic stage (graben formation) faults allow deep circulation and hot fluid to reach the surface. As the graben widens hydrothermal activity is less important and may cease. The heat of a new volcanic episode reactivates the deep hot water circulation along the graben faults completing a cycle.
69 nouveaux sites hydrothermaux ont été découverts entre 17'5 et 18'40'5 sur quatre segments présentant des activités volcaniques et tectoniques contrastées. A 17°10'S,17025'S et 18'37'5, la ride forme un dôme et l'activité volcanique est dominante. Les émissions hydrothermales sont d'abord diffuses et de basse température, puis focalisées et de haute température. A 18°15'S la majorité des sites hydrothermaux sont inactifs dans un graben axial dépourvu de laves récentes. A 18'32'5, des laves récentes s'épanchent au fond du graben. Les circuits hydrothermaux réactivés par le nouvel épisode volcanique se traduisent par des diffusions sur les laves récentes et par une reprise des émissions de haute température le long des murs du graben. Ces quatre segments traduisent des épisodes volcanoltectoniques successifs, caractéristiques de I'évolution temporelle des dorsales rapides. Les observations permettent de proposer un nouveau modèle de l'activité hydrothermale. Les circuits hydrothermaux sont diffus, peu structurés, instables et superficiels durant les épisodes volcaniques. Au début des épisodes tectoniques, les failles du graben drainent les fluides chauds en profondeur, puis lorsque le graben s'élargit, l'activité s'interrompt. La reprise de l'activité volcanique réamorce les circulations profondes le long des failles du graben.
Comptes Rendus de l'Academie des Sciences Serie II (1251-8069) (Gauthier-villars), 1994-12 , Vol. 319 , N. 11 , P. 1399-1406

Droits : Académie des Sciences
http://archimer.ifremer.fr/doc/00183/29455/27889.pdf
http://archimer.ifremer.fr/doc/00183/29455/

Éditeur(s) : HAL CCSD
Résumé : Sand intrusions (or injectites) are most often the product of post-depositional remobilization of sand leading to its injection into the surrounding rocks. While injectites were recognized for the first time nearly 200 years ago, their emplacement process has been studied for a couple of decades only, since the concepts of deep sea depositional environments have allowed us to better understand their emplacement processes. However, these processes are still relatively poorly understood. Our approach is based on the study of injectites in the Lower Congo Basin from seismic and well data, which we compare to a fossil system in the SE France basin. We have shown that: (1) In buried turbidite channel systems draping deposits on the channel flanks and terraces of channels have the same geophysical signature as 'wing-like' injectites. Finally, the only criterion for identifying seismic injectites is the presence of bedding-discordant seismic reflections, and in the best case the associated uplift of the overlying seismic reflectors. (2) Seismic-scale conical and saucer-shaped sand injectites have been identified in the Lower Congo Basin. The remobilization is likely due to overpressuring induced by the buoyancy effect of hydrocarbons trapped in the margins of a lobe buried underneath 160 m of sediment, followed by the sudden injection of fluidized sand associated with fault reactivation of faults (with a possible role of nearby salt diapirs). (3) A network of injectites (dykes, sills/wings and laccoliths) was formed in the Vocontian basin during the late Albian and/or early Cenomanian, from a lower-middle Albian turbidite channel. The emplacement is probably due to the early compartmentalization of the channel during its burial and the increase of the sedimentation rate generating overpressure; and the subsequent large influx of deep fluids triggering injection. The injection of sand was polyphased: a first episode formed the sills and another emplaced the dykes. Sills/wings and dykes propagated about 2 km laterally away from the parent sand body and about 200 m up to the surface, revealing a much more extended lateral than vertical reach, contrary to the classically accepted idea from the interpretation of seismic data. (4) The emplacement of this large network of injectites was governed by hydrofracturing. Therefore, its morphology is dependent on the host rock heterogeneity (isotropy, fractures), the paleo-stress orientation (ó3 = NW-SE) and the burial depth of the source (300-600 m) at the time of injection. The study of this fossil network allows us to define the relationship between morphology of the injected network and stress state at the time of injection. This relationship can be extrapolated to constrain the morphology of subsurface networks beyond seismicvisibility. (5) Sands injected into low permeability lithologies bear evidence to a major event of fluid escape in the studied basin, but also channeled fluids long after their formation. In this way, injectites both attest to specific episodes of fluid migration in sedimentary basins and contribute to long-lived re-routing of migrating fluids once emplaced. The injection of sand is associated with the sudden escape of fluids, probably resulting from a significant tectonic and/or sedimentary event; in addition, the architecture of injectite networks is governed by the local paleo-stress and heterogeneity in the host rock. Consequently, characterizing injectite networks is an important step in understanding the plumbing systems of continental margins, i.e. the post-depositional evolution of sedimentary basins.
Les intrusions sableuses (ou injectites) sont le plus souvent le produit de la remobilisation post-dépositionnelle des sédiments et de l'injection du sable dans les roches environnantes. Bien que reconnues pour la première fois il y a près de 200 ans, elles ne sont réellement étudiées que depuis quelques dizaines d'années, depuis que les concepts sur les environnements de dépôt dans les domaines marins profonds nous permettent de mieux comprendre les processus de mise en place. Cependant, ces processus restent encore aujourd'hui relativement mal compris. Notre approche repose sur l'étude d'injectites dans le bassin du Bas-Congo a partir de données de sismique et de puits que nous comparerons a un système fossile dans le bassin du SE de la France. Nous avons montre que : (1) Dans des systèmes de chenaux turbiditiques enfouis, les dépôts de drapage sur les marges et terrasses de chenaux présentent la même signature géophysique que les injectites de type "wing". Finalement, le seul critère sismique d'identification des injectites est la présence de réflexions sismiques sécantes vis-a-vis de la stratigraphie associée dans le meilleur des cas au soulèvement des réflecteurs sismiques sus-jacents. (2) Des injectites d'échelle sismique en forme de cône et d'assiette ont été identifiées dans le bassin du Bas-Congo. La remobilisation résulte probablement des pressions anormales induites par l'effet de flottabilité des hydrocarbures piégés dans les marges d'un lobe enfoui sous 160 m de sédiment, puis de l'injection soudaine du sable fluidise associée a la réactivation de failles (possible rôle des diapirs de sel a proximité). (3) Un réseau d'injectites (dykes, sills/wings et laccolites) s'est formé dans le bassin Vocontien entre la fin de l'Albien supérieur et/ou le début du Cénomanien, depuis un chenal turbiditique de l'Albien inférieur-moyen. La mise en place résulte probablement de la compartimentalisation précoce du chenal au cours de son enfouissement et de l'augmentation du taux de sédimentation générant la surpression et de l'apport ulterieur d'importante quantité de fluides profonds déclenchant l'injection. L'injection du sable a été polyphasée : une première injection a formé des sills et une suivante des dykes. Les sills/wings et les dykes se sont propagés latéralement au chenal source sur environ 2 km et vers la surface sur environ 200 m, mettant en évidence une forte remobilisation latérale plutôt que verticale, contrairement a l'idée classiquement admise a partir de l'interprétation des données sismiques. (4) La formation de ce large réseau d'injectites a été gouvernée par des mécanismes d'hydrofracturation. Par conséquent, sa morphologie a été dépendante des hétérogenéités de la roche hôte (milieu isotrope, fracture), des directions de paléo-contraintes (ƒÐ3 = NWSE) et de la profondeur d'enfouissement de la source (300-600 m) au moment de l'injection. L'étude de ce réseau fossile permet de définir les relations entre morphologie du réseau injecté et état de contraintes au moment de l'injection. Cette relation peut être extrapolée de façon à contraindre la morphologie des réseaux de subsurface au-delà de la visibilité sismique. (5) Les sables injectés dans des lithologies de faible perméabilité témoignent d'un épisode d'échappement de fluide important dans les bassins étudiés mais ont aussi guide les fluides longtemps après leur formation. Les injectites contribuent ainsi a l'initiation épisodique et la pérennisation de migrations de fluides dans les bassins sedimentaires. Le processus d'injection est associé a l'échappement brutal de fluides, résultant vraisemblablement d'un évènement tectonique et/ou sédimentaire important, et l'architecture des réseaux d'injectites est gouverné par les paléo-contraintes locales et les hétérogénéités de la roche hôte. Par conséquent, la caractérisation des réseaux d'injectites est une étape importante dans la compréhension de la plomberie des marges, c'est-a-dire l'évolution post-dépôt des bassins sédimentaires.
https://tel.archives-ouvertes.fr/tel-01011486

tel-01011486
https://tel.archives-ouvertes.fr/tel-01011486
https://tel.archives-ouvertes.fr/tel-01011486/document
https://tel.archives-ouvertes.fr/tel-01011486/file/These_Monnier_2013_banalisee.pdf

Éditeur(s) : Ofioliti
Résumé : Serpentinisation of mantle rocks, leading to natural venting of hydrogen and methane, has been reported to occur at the global scale, wherever fluids percolate in ultramafic formations. Here we compare gas composition from two on-land, low-temperature, and hyper-alkaline springs hosted on ultramafic rocks in the ophiolite massifs of the Sultanate of Oman and the Ligurian Alps (Voltri Group, Genoa region, Northern Italy). These two settings exhibit similar chemical and mineralogical features but show diverse styles of gas venting. Commonly to all hyper-alkaline springs, gases are characterised by relatively high N-2, very low O-2 and CO2 concentrations, and a strong enrichment in H-2 and CH4. The comparison between Oman and Liguria highlights a high variability of the H-2/CH4 ratios whereby the gas phase of the Oman Ophiolite is enriched in H-2 whereas being CH4 enriched in the Voltri Ophiolite. These results combined with literature data define three groups that may reflect different stages of serpentinisation producing fluids from hydrogen-dominated to methane-dominated. The origin of these distinct groups might lie in the difference of the mineralogical composition of the rocks within which the fluids circulate, on the degree of alteration of the rocks and finally on the geological/metamorphic history of the ophiolite.
Ofioliti (0391-2612) (Ofioliti), 2013-12 , Vol. 38 , N. 2 , P. 143-156

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00175/28634/27059.pdf
DOI:10.4454/ofioliti.v38i2.423
http://archimer.ifremer.fr/doc/00175/28634/

Éditeur(s) : Gauthier-Villars
Résumé : We report here our findings on the chemistry of methane, manganese and chloride dissolved in the interstitial water of the Barbados accretionary complex. The decollement separating the subduction plate from the accretionary wedge is geochemically characterized by high methane and manganese and low chloride concentrations relative to buried seawater. Sandstone layers occurring below the decollement and the compressive structures recording some of the earliest effects of offscraping are also characterized by similar anomalies. A fluid with the same characteristics is also found six kilometres to the east of the deformation front within the oceanic plate. High manganese concentration and low chlorinity also occur in the pore water of the offscraped sediment packages, but without associated anomalous methane concentrations. These results suggest that: Dewatering processes occur below the decollement in association with thermogenic methane production; Fluid with low chlorinity and high methane concentrations circulates mainly along the decollement, its propagation in the oceanic domain and along the main fracture zones being associated with these detachment surfaces; Diagenetic processes essentially control the dissolved manganese concentration and probably affect the methane content of the interstitial waters; The observations made in this paper illustrate advective processes in the front of an accretionary prism.
Oceanologica Acta (0399-1784) (Gauthier-Villars), 1991 , Vol. 14 , N. 1 , P. 33-49

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00101/21262/18873.pdf
http://archimer.ifremer.fr/doc/00101/21262/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The present study aims to apply the AMS method (Anisotropy of Magnetic Susceptibility) at a regional scale to track the fluid circulation direction that has produced an iron metasomatism within pre-existing dolomite host rock. The Urgonian formations hosting the Zn-Pb mineralizations in La Florida (Cantabria, northern Spain) have been taken as target for this purpose. Sampling was carried out, in addition to ferroan dolomite host rock enclosing the Zn-Pb mineralizations, in dolomite host rock and limestone to make the comparison possible between magnetic signals from mineralized rocks, where fluid circulation occurred, and their surrounding formations. AMS study was coupled with petrofabric analysis carried out by texture goniometry, Scanning Electron Microscopy (SEM) observations and also Shape Preferred Orientation (SPO) statistics. SEM observations of ferroan dolomite host rock illustrate both bright and dark grey ribbons corresponding respectively to Fe enriched and pure dolomites. SPO statistics applied on four images from ferroan dolomite host rock give a well defined orientation of ribbons related to the intermediate axis of magnetic susceptibility K2. For AMS data, two magnetic fabrics are observed. The first one is observed in ferroan dolomite host rock and characterised by a prolate ellipsoid of magnetic susceptibility with a vertical magnetic lineation. The magnetic susceptibility carrier is Fe-rich dolomite. These features are probably acquired during metasomatic fluid circulations. In Fe-rich dolomite host rock, ‹c› axes are vertical. As a rule, (0001) planes (i.e. planes perpendicular to ‹c› axes) are isotropic with respect to crystallographic properties. So, the magnetic anisotropy measured in this plane should reflect crystallographic modification due to fluid circulation. This is confirmed by the texture observed using the SEM. Consequently, AMS results show a dominant NE-SW elongation interpreted as the global circulation direction and a NW-SE secondary elongation that we have considered as sinuosities of the fluid trajectory. The second type of magnetic fabric is essentially observed in the limestone and characterised by an oblate form of the ellipsoid of magnetic susceptibility, a horizontal magnetic foliation and mixed magnetic susceptibility carriers. It is interpreted as a sedimentary fabric.
ISSN: 0012-821X

insu-00342499
https://hal-insu.archives-ouvertes.fr/insu-00342499
https://hal-insu.archives-ouvertes.fr/insu-00342499/document
https://hal-insu.archives-ouvertes.fr/insu-00342499/file/Essalhi-EPSL-2008.pdf
DOI : 10.1016/j.epsl.2008.11.011

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : Geochemistry, Geophysics, Geosystems, v. 9, p. Q12001, 2008. http://dx.doi.org/10.1029/2008GC002098
International audience
Rb/Sr, 40Ar/39Ar, and Sm/Nd isotopic data are reported in Caledonian eclogites from the Lindås Nappe, Bergen Arcs, Norway, in order to investigate processes controlling isotopic equilibrium at mineral scale in polymetamorphic rocks. The Bergen Arcs exposes Sveconorwegian ∼950–930 Ma granulites, partially overprinted by Caledonian eclogite-facies metamorphism at ∼425 Ma and amphibolite-facies metamorphism at ∼410 Ma. Geochemical and Rb-Sr data from more than 10 phengite fractions separated from one sample reflect the composition of the microdomain (a few hundred microns in size) in which phengite crystallized. Phengite crystallized after garnet or plagioclase by dissolution-precipitation processes yield apparent age between 700 and 600 Ma. At the time of their crystallization, these phengites inherited the isotopic composition of their precursor minerals, at a microdomain scale. Phengite from quartz veins, which crystallized from elements mobilized by the circulating fluid, yield an age closer to the eclogite-facies metamorphic age. The closed system evolution of the eclogitizing fluid, the segregation of textural and reactional microdomains, the high Sr content of the studied phengite, and the short duration of the recrystallization processes (<1Ma) are interpreted as the main factors responsible for the lack of a Rb/Sr isotopic equilibrium, at the scale of hand samples. Such equilibrium is nevertheless reached in quartz veins where the crystallization of minerals implies that the fluid circulation acted as a factor of isotopic homogenization. The in situ single mineral Ar/Ar datings revealed that both eclogite- and amphibolite-facies minerals are characterized by an excess of radiogenic argon (ages between 425 and 520 Ma). The excess of argon has been inherited from the previous granulite and has been only partially evacuated from the system by the circulating fluid. The apparent Sm/Nd ages from garnets inherited from the granulite-facies metamorphism (c. 930 Ma) are in agreement with previous estimates. This result confirms that the diffusion of Nd in garnet does not occur at temperatures lower than 700°C. This study highlights the complexity of radiochronometer behavior during HP metamorphism and demonstrates that coupling different radiochronometers, such as Ar/Ar and Rb/Sr, does not always guarantee the validity of the geochronological results.
ISSN: 1525-2027

hal-00407885
https://hal.archives-ouvertes.fr/hal-00407885
DOI : 10.1029/2008GC002098

Éditeur(s) : HAL CCSD
Résumé : International audience
Les plages sableuses constituent une frontière mobile et poreuse entre l'océan ouvert et la terre. La compréhension de la circulation dans les nappes de plage est importante pour une variété de processus physiques, biologiques et chimiques. On cherche à caractériser in-situ la dynamique souterraine sous la zone de swash. Le site atelier est la plage microtidale de Rousty (Camargue, France). L'étude, réalisée sur 48h les 13 et 14 décembre 2014, fait partie d'une plus grande campagne de mesure visant à caractériser la réponse hydro-morphologique de la plage de Rousty à une saison hivernale. La période présentée ici correspond à la phase de déclin d'une tempête modérée. La stratégie retenue dans le cadre de ce projet a été de déployer un réseau de15 capteurs de pression enterrés sous la zone de swash. Les caractéristiques des vagues incidentes, à la fois au large et dans la zone de surf interne, ont été mesurées conjointement à l'utilisation d'un LiDAR terrestre haute fréquence permettant de suivre la surface libre et l'évolution du lit sableux à haute fréquence sur la zone de swash. L'analyse des données moyennées dans le temps a mis en évidence la présence d'un schéma de circulation relativement robuste sous la zone de swash, qui se décale vers le large en suivant la descente du niveau moyen et la diminution de l'activité des vagues. La tendancedominante est un écoulement vers le large, avec une intensité maximale de l'ordre de 0.1mm/s modulé par des infiltrations et exfiltrations dans les parties hautes et basses de la zone de swash, respectivement. L'analyse haute fréquence à des événements de swash sélectionnés ont mis en évidence uncycle souterrain caractéristique.
XIV èmes Journées Nationales Génie Côtier – Génie Civil
toulon, France

hal-01357778
https://hal.archives-ouvertes.fr/hal-01357778

Éditeur(s) : Elsevier Sci Ltd
Résumé : The eastern Demerara Plateau offshore French Guiana was surveyed in 2003 during the GUYAPLAC cruise (multibeam bathymetry and acoustic imagery, 6-channel seismic reflection and 3.5 kHz echo-sounding). The data show the "post-transform" Cenozoic that the series located on the outer part of the plateau (below c. 2000 m) contain at least twelve stacked mass transport deposits (MTDs) that have recorded a history of large-scale slope failure, as well as two main normal fault sets that provide possible pathways for upward fluid migration through the series, reaching at high as the uppermost MTDs. Seabed data show that the area above the failures is characterized by circular-to-elongate (slope-parallel) depressions interpreted as fluid seeps (pockmarks), some of them have been modified by along slope currents. We suggest that the development of the MTDs to results from the combinaiton of the presence of fluid overpressure at depth the geometry of the margin's deep structure, in particular the existence of a 'free borderlateral border' on the outermost plateau. Our results also emphasise the role of stratigraphic decollements within the Cenozoic series.
Marine And Petroleum Geology (0264-8172) (Elsevier Sci Ltd), 2013-09 , Vol. 46 , P. 287-303

Droits : 2013 Elsevier Ltd. All rights reserved.
http://archimer.ifremer.fr/doc/00157/26850/25316.pdf
DOI:10.1016/j.marpetgeo.2013.06.010
http://archimer.ifremer.fr/doc/00157/26850/

Éditeur(s) : HAL CCSD
Résumé : National audience
La Zone Nord-Pyrénéenne (ZNP) résulte de l’inversion debassins albo-cénomaniens ouverts entre les plaques Europe etIbérie. Le manteau subcontinental a été exhumé dans le fond decertains de ces bassins et la couverture sédimentaire mésozoïquepré-rift, désolidarisée du soubassement paléozoïque, est venue localementen contact tectonique avec les péridotites. Ceci faitde la ZNP un analogue pour l’étude des marges continentalespassives à manteau exhumé. L’extension crustale s’est produiteen régime thermique chaud comme le montre le métamorphismecrétacé des sédiments pré-rift. Les Chaînons Béarnais (PyrénéesOccidentales) représentent un témoin peu inversé de ce type demarge chaude et sont donc propices à l’étude des modalités del’amincissement crustal dans un tel système. Les analyses detempératures par spectrométrie Raman réalisées sur la couverturesédimentaire aux abords du manteau (Saraillé, Urdach, Turon dela Técouère), montrent que la totalité du système a été soumis àdes températures maximales variant de 253C à 482C. Le contacttectonique majeur entre les sédiments pré-rift décollés et lemanteau est une zone d’intense circulation de fluides avec formationde roches métasomatiques à talc+chlorite+pyrite dans lesconditions du faciès schistes verts. La géochimie isotopique (O, C,Sr) et les inclusions fluides triphasées montrent une circulation desaumures chaudes (~200C), à travers toute la couverture sédimentairedans les derniers stades de l’exhumation du manteau.Nous montrons pour la première fois que pendant l’exhumationdes péridotites : (1) les sédiments pré-rift ont subi un amincissementsyn-métamorphique avec génèse d’une foliation S0/S1 et,(2) le socle paléozoïque a été réduit à de fines lentilles tectoniquesdéformées ductilement et restées adhérentes au manteau. Ainsi, larhéologie de la croûte supérieure durant l’amincissement est contrôléeen grande partie par la présence d’une couverture sédimentairepré- et syn-rift épaisse décollée jouant le rôle d’un couverclethermique efficace. Ces nouvelles données mettent en avant le caractèrede marge passive distale chaude de la ZNP. Cela constitueun élément important pour la compréhension des mécanismes del’amincissement crustal en contexte d’exhumation du manteau etses conséquences comme héritage structural lors de l’inversion tectoniquedes bassins.
RST 2016, livre des résumés
Caen, France

insu-01387892
https://hal-insu.archives-ouvertes.fr/insu-01387892

Éditeur(s) : HAL CCSD Springer
Résumé : The analysis of three different regions of the South- Pyrenean fold-and-thrust belt reveals that during the Tertiary compression the hydrological system was compartmentalised in time and space. During the early-middle Eocene, when the thrust front affected marine soft-sediments in the Ainsa basin, the thrust fault zones were dominated by formation fluids derived from Eocene marine waters trapped in the underlying Eocene marls, although influences of meteoric waters were also present. During the middle-late Eocene, when the thrust front emplaced marine rocks over continental redbeds in the eastern Catalan basin (L'Escala thrust), the thrust fault zones were dominated by meteoric fluids. These fluids flowed preferentially along these faults, draining laterally the meteoric fluids and acting as barriers hindering their flowing towards more external parts of the belt. During the Oligocene, the most external part of the fold-and-thrust belt in the eastern Catalan basin developed on top of a salt detachment horizon. The thrust front affected continental materials of late Eocene-Oligocene age. At this moment, the thrusts were conduits for meteoric fluids arriving from the surface and also for evolved meteoric fluids migrating over short distance upwards after being in contact with the underlying evaporitic beds. Most of the fractures show a similar sequence of microfractures. Microfractures of stage 1 formed when the sediment was poorly lithified. Microfractures of stage 2 represent the main episode of vein formation which developed when a progressive induration of the host sediment occurred. During microfracture stage 3, formed in an extensional regime, the host sediment was more indurated. The repetition of this sequence of microfractures in different fracture generations of the same outcrop indicates that the sediment induration was restricted to the vicinity of the vein. Away from the veins, the sediment remained poorly lithified during the entire deformation cycle. Calcite cement within the host rock precipitated later than the syn-compressive veins, when the sediment was more indurated. Elemental geochemistry and stable isotopes of the calcite veins indicates that early generation of microfractures is infilled by local fluids (either marine or meteoric), whereas external fluids (meteoric or evolved meteoric) infilled the main compressive stage of microfractures. The hot temperature of these fluids (157°C to 183°C in the Atiart-Arro example) indicates their circulation through deep parts of the thrust belt. The progressive increase of the 87Sr/86Sr ratio through time is due to the progressive uplift, exposure and erosion of the internal Pyrenean Axial Zone.
Thrust belts and foreland basins, from fold kinematics to hydrocarbon systems

hal-00408001
https://hal.archives-ouvertes.fr/hal-00408001
DOI : 10.1007/978-3-540-69426-7_5

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
We analyse the fluid flow regime within sediments on the Eastern levee of the modern Mississippi Canyon using 3D seismic data and downhole logging data acquired at Sites U1322 and U1324 during the 2005 Integrated Ocean Drilling Program (IODP) Expedition 308 in the Gulf of Mexico. Sulphate and methane concentrations in pore water show that sulphate-methane transition zone, at 74 and 94 m below seafloor, are amongst the deepest ever found in a sedimentary basin. This is in part due to a basinward fluid flow in a buried turbiditic channel (Blue Unit, 1000 mbsf), which separates sedimentary compartments located below and above this unit, preventing normal upward methane flux to the seafloor. Overpressure in the lower compartment leads to episodic and focused fluid migration through deep conduits that bypass the upper compartment, forming mud volcanoes at the seabed. This may also favour seawater circulation and we interpret the deep sulphate-methane transition zones as a result of high downward sulphate fluxes coming from seawater that are about 5-10 times above those measured in other basins. The results show that geochemical reactions within shallow sediments are dominated by seawater downwelling in the Mars-Ursa basin, compared to other basins in which the upward fluid flux is controlling methane-related reactions. This has implications for the occurrence of gas hydrates in the subsurface and is evidence of the active connection between buried sediments and the water column.
ISSN: 1468-8115

hal-00590501
https://hal.archives-ouvertes.fr/hal-00590501
DOI : 10.1111/j.1468-8123.2010.00304.x

Éditeur(s) : HAL CCSD
Résumé : International audience
The Jaca basin is a thrust-sheet top basin transported southward andunderlain by basement and cover thrusts separated by a Triassic décollement.Basin-fill upper Cretaceous to lower Oligocene synorogenic sequencesrecord a southward depocenter migration, while growth stratadate a shift of deformation from the mid-Eocene in the N to the earlyMiocene in the S (S-Pyrenean front). However, the deep geometry andkinematic relationships between the cover and basement thrusts remainnon-consensual. We present a new structural and kinematic interpretationfor the eastern Jaca basin, based on subsurface structural maps andcross-sections constructed using industrial seismic reflection profiles.Raman Spectroscopy of Carbonaceous Material (RSCM), vitrinite reflectanceand apatite fission track (AFT) thermochronology data givefurther constraints for the restoration of the deformation and burialexhumationsequence. We define 3 main basement thrusts under thenorthern part of the basin, from N to S the Broto, Fiscal and Guargathrusts. The study also clarifies the deep structure of the cover thrustsand their links with these basement thrusts and those located more tothe north in the Axial Zone (AZ), which altogether define the timing ofthe basement thrust sequence as follows : the Lakoura-Eaux Chaudesthrust system (northern AZ) active up to the end Bartonian, the Gavarnie(central AZ) and Broto thrusts during the Priabonian-Rupelian andthe Fiscal and Guarga thrusts during the late Oligocene-early Miocene.AFT results in the basin fill and AZ date the exhumation of the basinto the late Oligocene-early Miocene, in relation to the Fiscal-Guargathrusting. AFT partial reset argues for a maximum burial < 6 km forthe base of the Eocene detrital sequence (Hecho Group turbidites). Bycontrast, RSCM and vitrinite thermometry at the same level indicatesTmax around 180°C, locally up to 240°C, attesting to a temperature anomalypossibly related to transient fluid circulation.
24 ème Réunion des sciences de la Terre 2014
Pau, France

insu-01080836
https://hal-insu.archives-ouvertes.fr/insu-01080836

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Rainbow is a dome-shaped massif at the 36°14′N nontransform offset along the Mid-Atlantic Ridge. It hosts three ultramafic-hosted hydrothermal sites: Rainbow is active and high temperature; Clamstone and Ghost City are fossil and low temperature. The MoMARDREAM cruises (2007, 2008) presented here provided extensive rock sampling throughout the massif that constrains the geological setting of hydrothermal activity. The lithology is heterogeneous with abundant serpentinites surrounding gabbros, troctolites, chromitites, plagiogranites, and basalts. We propose that a W dipping detachment fault, now inactive, uplifted the massif and exhumed these deep-seated rocks. Present-day deformation is accommodated by SSW-NNE faults and fissures, consistent with oblique teleseismic focal mechanisms and stress rotation across the discontinuity. Faults localize fluid flow and control the location of fossil and active hydrothermal fields that appear to be ephemeral and lacking in spatiotemporal progression. Markers of high-temperature hydrothermal activity (∼350°C) are restricted to some samples from the active field while a more diffuse, lower temperature hydrothermal activity (<220°C) is inferred at various locations through anomalously high As, Sb, and Pb contents, attributed to element incorporation in serpentines or microscale-sulfide precipitation. Petrographic and geochemical analyses show that the dominant basement alteration is pervasive peridotite serpentinization at ∼160–260°C, attributed to fluids chemically similar to those venting at Rainbow, and controlled by concomitant alteration of mafic-ultramafic units at depth. Rainbow provides a model for fluid circulation, possibly applicable to hydrothermalism at oceanic detachments elsewhere, where both low-temperature serpentinization and magmatic-driven high-temperature outflow develop contemporaneously, channeled by faults in the footwall and not along the detachment fault.
ISSN: 1525-2027

hal-01115281
https://hal.archives-ouvertes.fr/hal-01115281
https://hal.archives-ouvertes.fr/hal-01115281/document
https://hal.archives-ouvertes.fr/hal-01115281/file/Andreani_et_al-2014-Geochemistry%2C_Geophysics%2C_Geosystems.pdf
DOI : 10.1002/2014GC005269

Éditeur(s) : HAL CCSD Society of Economic Geologists
Résumé : International audience
The ~8-Moz Sadiola Hill gold deposit is located in the Kédougou-Kénieba inlier, a window of deformed ca. 2200 to 2050 Ma rocks that crop out in eastern Senegal and western Mali. The geology of the inlier differs from other Paleoproterozoic granite-greenstone belts and sedimentary basins by the abundance of carbonate rocks. The Sadiola Hill gold deposit occurs within 3 km of the Senegal-Mali shear zone, and country rocks in the region have undergone polycyclic deformation. The lithostratigraphy of the open pit consists of impure limestones overlain by younger sequences of detrital sedimentary rocks, which include arenite, wacke, and siltstone. The sedimentary rocks have been subjected to regional greenschist-facies metamorphism and have been intruded by multiple generations of synkinematic, calc-alkaline stocks and dikes. The bulk of the ore is hosted within a N-S- to NNW-trending, 10- to 50-m-wide, brittle-ductile dilational shear zone defined as the Sadiola shear zone. Gold lodes also occur along an array of steep NNE-trending shear zones. Geometric and kinematic analyses indicate that the ore-hosting structures were undergoing sinistral displacement at the time of mineralization, locally defined as the D3s NNW-SSE-shortening event. Hydrothermal alteration is polyphase and includes an early high-temperature calc-silicate phase (i.e., porphyroblastic growth of actinolite-tremolite) followed by a potassic phase (i.e., biotite-calcite-quartz ± K-feldspar-tourmaline-actinolite) that was synchronous with ore mineral deposition. Paragenetic studies reveal a multistage ore development that includes an As-rich sulfide stage, followed by an Au-Sb stage. The ore is associated with a metal enrichment suite of Au-As-Sb ± Cu-Fe-W-Mo-Ag-Bi-Zn-Pb-Te. The Sadiola Hill deposit shares a similar relative timing and structural setting to that of other world-class orogenic gold systems in the West African craton (e.g., Ashanti, Loulo), with gold deposition occurring during a period of transcurrent tectonics, after the cessation of region-wide compressional deformation. The high-temperature paragenesis at Sadiola Hill is atypical of gold mineralization in the craton and indicates that the late Eburnean tectono-magmatic activity between ca. 2080 and 2060 Ma played an important role in the dynamics of hydrothermal fluid circulation along the Senegal-Mali shear zone.
ISSN: 0361-0128

hal-01583358
https://hal.archives-ouvertes.fr/hal-01583358
DOI : 10.2113/econgeo.112.1.23