Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In this study, we propose a theoretical approach to test the validity of the isomechanical analogues for post-perovskite structures. Intrinsic plastic properties are evaluated for three materials exhibiting a post-perovskite phase: MgSiO3, MgGeO3 and CaIrO3. Dislocation properties of each structure are determined using the Peierls-Nabarro model based on first-principles calculations of generalised stacking fault and the plastic properties are extended to crystal-preferred orientations using a visco-plastic self-consistent method. This study provides intrinsic parameters of plastic deformation such as dislocation structures and Peierls stresses that can be directly compared between the three materials. It appears that it is very difficult to draw any simple conclusions on polycrystalline deformation simply by comparing single crystal properties. In particular, contrasting single crystal properties of MgSiO3 and CaIrO3 lead to similar crystal-preferred orientation of the polycrystal aggregates.
ISSN: 0031-9201

hal-00420104
https://hal.archives-ouvertes.fr/hal-00420104
DOI : 10.1016/j.pepi.2008.04.003

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
A set of synthetic aggregates, containing mixtures of calcite and muscovite, were compacted with varying uniaxial loads ranging from 20 MPa up to 400 MPa. Their elastic properties have been measured using compressional and shear waves in confining hydrostatic pressures up to 475 MPa. Measured seismic velocities are shown to depend on 1) the ratio of calcite to muscovite, 2) the uniaxial load used during sample manufacturing, and 3) the porosity amount prior to velocity measurements. The matrix framework may also affect the seismic velocities, but this effect is not easily quantifiable. In general, measured seismic velocities decrease with increasing muscovite content and porosity. Elastic properties have been calculated based on texture measurements, which were obtained by neutron diffraction. The calculated velocities are based on the calcite and muscovite single crystal elastic tensors, their orientation distribution functions, and their modal fractions. A large discrepancy is apparent between calculated and measured velocities, where the former always overestimate the actual velocities. Shear waves display less of a difference between calculated and measured values, than do compressional waves, indicating that waves propagating by shearing are less affected by sample porosity and matrix framework. A better agreement between measured and calculated seismic velocities arises when the initial porosity is taken into account, using a differential effective medium model. Seismic anisotropy is evident from both measured and calculated velocities, and is low for samples containing pure calcite, but becomes prominent as the muscovite concentration increases. The intensity of anisotropy further depends on the uniaxial load used during sample compaction and the initial porosity.
ISSN: 0148-0227

hal-00512666
https://hal.archives-ouvertes.fr/hal-00512666
DOI : 10.1029/2009JB006523

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
In situ mineralization of CO2 in ultramafic rock-hosted aquifers is one of the promising solutions for decreasing CO2 concentrations in the atmosphere. Naturally altered ultramafic rocks suggest that carbonation processes are controlled by local heterogeneities in the structure of the rock and fluid transport at the water-rock interfaces. We studied the role of rock crystallographic anisotropy relative to the global fluid flow direction on the mineralization of CO2 by means of electron microscope analyses from the macro- to the micrometer scale (EBSD-FIB). The sample used for the measurements was a hot pressed olivine core percolated by water enriched in CO2 (pCO2 = 10 MPa) at 180 °C. During the percolation experiment, olivine was dissolved and two types of carbonates, dolomite, and magnesite, were precipitated on olivine surfaces. The results showed that the dissolution of olivine is controlled by its crystallographic properties as shown by the development of etch-pits only on the (010)ol planes and with elongated shapes parallel to the [010]ol axes. In contrast, the precipitation of carbonates is governed by hydrodynamic properties. Carbonates are heterogeneously distributed in the percolated rock. They are mainly located along the moderate (for dolomite) and the minor (for magnesite) flow paths, both oriented parallel to the principal fluid flow direction, which allow carbonates to be supplied with divalent cations (e.g., Ca2+, Mg2+, and Fe2+). In these flow paths, carbonate growth is systematically oriented normal to the flow that facilitates the development of chemical gradients with cationic supersaturation conditions for carbonate precipitation near the walls.In natural systems, the (010)ol planes are parallel to the Moho and the (100)ol planes are vertical; our study suggests that flow of CO2-rich fluids will induce precipitation of carbonates localized along, and preferentially clogging, vertical flow paths while favoring olivine dissolution along horizontal fluid pathways. This dual control of structure and fluid flow on carbonation mechanisms could be an important parameter allowing sustainable CO2 storage in peridotites, while limiting the risks of leakage toward the surface.
ISSN: 0003-004X

hal-01143393
https://hal.archives-ouvertes.fr/hal-01143393
DOI : 10.2138/am-2015-4913

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Seismic anisotropy originating within the continental crust is used to determine kinematic flow lines within active mountain belts and is widely attributed to regionally aligned mica. However, naturally deformed micaceous rocks commonly show composite (e.g. S-C) fabrics. It is necessary therefore to understand how both varying mica content and differing intensities of multiple foliations impact on seismic interpretations in terms of deformation fields. An outcrop analogue for granitic mid-crustal deformed zones is used here to calibrate the seismic response against both parameters. Seismic responses are modelled using crystallographic preferred orientations for polymineralic, micaceous granitic gneisses, measured using Electron Back-Scatter Diffraction. The sample results are generalised by modelling the effects of variations in modal composition and the relative importance of deformation fabrics of variable orientation, so-called rock and fabric recipes. The maximum P- and S-anisotropy are calculated at 16.6% and 23.9% for single-foliation gneisses but for mixed (i.e. S-C) foliation gneisses these values reduce to 5.8% and 7.5% respectively. Furthermore, mixtures of multiple foliations generate significant variations in the geometry of the seismic anisotropy. This effect, coupled with the geographical orientation of fabrics in nature. can generate substantial variations in the orientation and magnitude of seismic anisotropy (especially for shear waves) as measured for the continental crust using existing receiver function and teleseismic near-vertical incidence methods. Thus, maps of seismic anisotropy varying with depth in deforming continents need not imply necessarily depth-varying deformation kinematics and tectonic decoupling.
ISSN: 0012-821X

hal-00445247
https://hal.archives-ouvertes.fr/hal-00445247
DOI : 10.1016/j.epsl.2009.09.035

Éditeur(s) : HAL CCSD Geological Society of London
Résumé : We have applied transmission electron microscopy (TEM) analyses coupled with viscoplastic self-consistent (VPSC) numerical modelling to identify the active slip systems and to better understand the crystal preferred orientation (CPO) development of the Torridon quartz mylonite (NW Scotland). TEM analyses showed evidence of activation of 1/3〈a〉{π′}, 1/3〈a〉{z} and possible 〈a〉(c) slip systems, as well as dislocation climb and dynamic recrystallization. All the CPOs generated by VPSC models share common characteristics with the Torridon quartz mylonite, but only Models 2 and 3 reproduce the [c]-axes maxima at low angle (<20°) to the foliation pole along the YZ plane, as observed in the mylonite. In Model 2, this concentration only occurs at γ≥2.6, whereas in Model 3 this maxima occurs at lower shear strains. The models that start with a previous preferred orientation acquire very strong CPOs after small-imposed strains, followed by the rapid rotation of the fabric in relation to the new imposed finite strain axes. The combined activation of 〈a〉{π′}, 〈a〉{z} and possibly 〈a〉(c) slip systems, as demonstrated by TEM analyses, suggests that the VPSC model that best predicts CPO development in the Torridon quartz mylonite is Model 2, where the critical resolved shear stress (CRSS) of 〈a〉{π/π′} is assumed to be slightly stronger than 〈a〉(c).
Deformation Mechanisms, Rheology and Tectonics: Microstructures, Mechanics and Anisotropy

hal-00688840
https://hal.archives-ouvertes.fr/hal-00688840

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Melt generation in the continental crust is thought to significantly influence seismic bulk velocities and anisotropy, although existing laboratory data provide limited constraints on such seismic attributes. In this study we measured ultrasonic compressional wave speeds (Vp) and anisotropy during sample compaction, mica-breakdown and melt-generation in synthetic, foliated quartz–muscovite aggregates. Measurements were performed at peak conditions of 300 MPa hydrostatic confining pressure and 750 °C, over a six hour time period, for three separate samples where wave propagation directions were aligned at 0°, 45° and 90° with respect to the foliation plane. The experiments are initially marked by sample compaction and rapid reduction in porosity (from 25% to <2 vol%), with a corresponding increase in Vp. During initial stages of the experiment Vp ranges from 4.65 to 5.45 km/s, depending on the direction of the P wave propagation, resulting in up to ∼16% anisotropy, which originates mainly from the preferred orientation of muscovite and possible incipient melt lenses oriented parallel to foliation. As the experiment progresses the bulk Vp decreases gradually and Vp anisotropy drops from ∼16% to ∼2% after five hours into the experiment. The drop in anisotropy is caused by muscovite-breakdown and increasing amount of partial melting of the aggregate. The bulk velocities are considerably lower than predicted for a mixture of muscovite and β-quartz (stable at 300 MPa and 750 °C). Thermodynamic modeling indicates that mica breakdown and production of melt with ∼2 wt% dissolved water in the aggregate can explain the low Vp, even though β-quartz is stable; the modeled Vp is ∼4.75 km/s at 300 MPa and 750 °C. These ultrasonic attributes signify movement of the melt to fill vacant pores and coating grain boundaries, effectively connecting melt films and reducing seismic anisotropy. The results may apply to regions where crustal melting is on-going, in particular regions of elevated temperature that are only weakly deforming, with coupled anomalously low bulk velocities and seismic anisotropy.
ISSN: 0012-821X

hal-01243569
https://hal.archives-ouvertes.fr/hal-01243569
DOI : 10.1016/j.epsl.2015.05.039

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : The core structures of dislocations in diopside have been calculated within the Peierls model, which assumes a planar core. 1/2 < 110 > dislocations can dissociate into two collinear partial dislocations. We show that [001] glide is very difficult in (010) and that a non-collinear dissociation of [001](100) (modelled within a Peierls-Nabarro-Galerkin approach) makes glide equally easy in (100) and {110}. A widely spread core structure corresponding to a low lattice friction has been found for [100](010) and [010](100) dislocations which is not supported by mechanical data and, together with TEM observations, suggests that another, probably non-planar core structure is possible for these dislocations.
ISSN: 0342-1791

hal-00558238
https://hal.archives-ouvertes.fr/hal-00558238
DOI : 10.1007/s00269-010-0370-7

Éditeur(s) : HAL CCSD European Geosciences Union
Résumé : No abstract available
ISSN: 1869-9510

hal-01115507
https://hal.archives-ouvertes.fr/hal-01115507
DOI : 10.5194/se-5-509-2014

Éditeur(s) : HAL CCSD Royal Society, The
Résumé : International audience
Nucleation mechanisms occurring during dynamic recrystallization play a crucial role in the evolution of microstructures and textures during high temperature deformation. In polycrystalline ice, the strong viscoplastic anisotropy induces high strain heterogeneities between grains which control the recrystallization mechanisms. Here, we study the nucleation mechanisms occurring during creep tests performed on polycrystalline columnar ice at high temperature and stress (T=−5°C;σ=0.5 MPa) by post-mortem analyses of deformation microstructures using cryogenic electron backscatter diffraction. The columnar geometry of the samples enables discrimination of the nuclei from the initial grains. Various nucleation mechanisms are deduced from the analysis of the nuclei relations with the dislocation sub-structures within grains and at grain boundaries. Tilt sub-grain boundaries and kink bands are the main structures responsible for development of polygonization and mosaic sub-structures. Nucleation by bulging at serrated grain boundaries is also an efficient nucleation mechanism near the grain boundaries where strain incompatibilities are high. Observation of nuclei with orientations not related to the ‘parent’ ones suggests the possibility of ‘spontaneous’ nucleation driven by the relaxation of the dislocation-related internal stress field. The complexity of the nucleation mechanisms observed here emphasizes the impact of stress and strain heterogeneities on dynamic recrystallization mechanisms.This article is part of the themed issue ‘Microdynamics of ice’.
ISSN: 1364-503X

hal-01467152
https://hal.archives-ouvertes.fr/hal-01467152
DOI : 10.1098/rsta.2015.0345

Éditeur(s) : HAL CCSD Geological Society of London
Résumé : International audience
This paper presents the background for the calculation of various numbers that can be used to characterize crystal-preferred orientation (CPO), also known as texture in materials science, for large datasets using the combined scripting possibilities of MTEX and MatLab®. The paper is focused on three aspects in particular: the strength of CPO represented by orientation and misorientation distribution functions (ODFs, MDFs) or pole figures (PFs); symmetry of PFs and components of ODFs; and elastic tensors. The traditional measurements of texture strength of ODFs, MDFs and PFs are integral measurements of the distribution squared. The M-index is a partial measure of the MDF as the difference between uniform and measured misorientation angles. In addition there other parameters based on eigen analysis, but there are restrictions on their use. Eigen analysis does provide some shape factors for the distributions. The maxima of an ODF provides information on the modes. MTEX provides an estimate of the lower bound uniform fraction of an ODF. Finally, we illustrate the decomposition of arbitrary elastic tensor into symmetry components as an example of components in anisotropic physical properties. Ten examples scripts and their output are provided in the appendix.
Geological Society Special Publication

hal-01277689
https://hal.archives-ouvertes.fr/hal-01277689
DOI : 10.1144/SP409.8

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We performed torsional deformation experiments on pre-hydrated fine-grained olivine aggregates using an innovative experimental assembly to investigate water weakening in mantle rocks at high shear strains. San Carlos olivine powder was cold-pressed and then hot-pressed under hydrous conditions, producing aggregates with average grain sizes of 7 or 15 μm. Deformation experiments were performed in a high-resolution gas-medium apparatus equipped with a torsional actuator, under a confining pressure of 300 MPa, a temperature of 1200 °C, and constant shear strain rates ranging from 8 × 10−5 to 1.4 × 10−4 s−1. Maximum shear stresses range from 150 to 195 MPa. These values are 30% lower relative to those determined in previous torsion experiments on dry, fined-grained dunites under similar conditions. Textures and microstructures of the starting and deformed specimens were characterized by scanning and transmission electron microscopy. All deformed aggregates exhibit a shape-preferred orientation marking a foliation and lineation, as well as a reduction in mean grain size from 15 μm down to 3-4 μm due to dynamic recrystallization. Olivine crystallographic fabrics developed rapidly (γ < 0.1), but their strength, characterized by the J-index, is low compared to naturally deformed peridotites or to polycrystalline olivine deformed at similar finite shear strains under dry conditions. The crystallographic fabrics are consistent with deformation by a dislocation accommodated creep mechanism with activation of multiple {0 k l}[1 0 0] systems, among which the (0 1 0)[1 0 0] slip system is dominant, and minor participation of the (0 1 0)[0 0 1] slip system. Transmission electron microscopy confirmed the occurrence of dislocations with [1 0 0] and [0 0 1] Burgers vectors in most grains. Analysis of unpolarized infrared spectra indicates that hydrogen concentration in the olivine lattice is below the saturation level of 18 ppm wt H2O, which is similar to those typically observed in spinel-bearing peridotite xenoliths, and also provide evidence for water-rich inter-granular material trapped in pores and grain boundaries. Seismic properties computed from the CPO observations correspond to those most commonly observed in naturally deformed mantle peridotites with fast P-wave propagation and S-wave polarization subparallel to the shear direction. These torsion experiments on fine-grained olivine polycrystals under hydrous conditions indicate that water weakening under lithospheric conditions is linked to various defects with hydrogen in the olivine structure, as well as with water-derived species in grain boundaries or pores.
ISSN: 0031-9201

hal-00745170
https://hal.archives-ouvertes.fr/hal-00745170
DOI : 10.1016/j.pepi.2012.05.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : We have studied the phase transformation of forsterite to wadsleyite under shear stress at the Earth's transition zone pressure and temperature conditions. Two-step experiments were performed using a multi-anvil press. First, we hot pressed iron-free forsterite at 6 or 11 GPa and 1100 degrees C. Then we deformed a slab of this starting material using a direct simple shear assembly at 16 GPa and 1400 degrees C for 1, 15, 35, 40, or 60 min. Both the starting material and the deformed samples were characterized using optical and scanning electron microscopy including measurements of crystal preferred orientations (CPO) by electron back scattered diffraction (EBSD), transmission electron microscopy (TEM), and Fourier transform infrared spectroscopy (FTIR). The phase transformation occurs very rapidly, in less than 1 min, and metastable forsterite relics are not observed after deformation. The grain size of wadsleyite is slightly smaller than the forsterite starting material. The water contents obtained from FTIR analyses in forsterite and wadsleyite are 65-124 wt ppm H2O and 114-736 wt ppm H2O, respectively, which are well below water solubility at similar conditions in the presence of free water. Wadsleyite aggregates display weak CPO patterns with [1 0 0] axes concentrated at low angle to the shear direction, [0 1 0] axes perpendicular to the shear plane and nearly random [0 0 1] axes. Only a few dislocations were observed in wadsleyite with TEM. This observation is consistent with the assumption that most dislocations formed during the initial high-stress stages of these stress-relaxation experiments, were consumed in the phase transformation, probably enhancing the transformation rate. CPO patterns vary as a function of the water content: with increasing water content the density of [1 0 0] axes parallel to the shear direction decreases, and the density of [0 0 1] axes increases. Viscoplastic self-consistent modeling of CPO evolution using previously reported glide systems for wadsleyite, i.e., [1 0 0]{0 k 1} and 1/2 (1 1 1){1 0 1}, cannot reproduce the measured CPO, unless the [0 0 1](0 1 0) system, for which dislocations have not been observed by TEM, is also activated. In addition, wadsleyite grain growth suggests the participation of diffusion-assisted processes in deformation. Calculated anisotropies for P and S-waves using measured CPO are always below 1%. This very low anisotropy is due to both the low finite strain achieved in the experiments, which leads to weak wadsleyite CPO, and to the diluting effect of added majorite. The present experiments emphasize the importance of stress, grain size evolution and water content in the forsterite to wadsleyite phase transformation and subsequent deformation in the transition zone.
ISSN: 0031-9201

hal-00617430
https://hal.archives-ouvertes.fr/hal-00617430
DOI : 10.1016/j.pepi.2010.11.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The seismic anisotropy of the deep Earth is reviewed as a profile from the upper mantle to the solid inner core at the centre of the Earth. The upper mantle is by far the most anisotropic region of the Earth, followed the D” layer above the core mantle boundary. In contrast it is shown that many minerals that are present in the upper mantle, transition zone, lower mantle, D” layer and solid inner core are elastically anisotropic to different degrees. The anisotropy of hydrous phases present in subduction zones is briefly introduced. The basic concepts of single crystal and polycrystalline elasticity and the extrapolation of elastic properties to high temperature and pressure are presented. The specific features of elastic wave propagation in an anisotropic medium of any arbitrary symmetry are illustrated using mantle and inner core phases. The roles of crystal preferred orientation, water and melt in producing seismic anisotropy in the upper mantle are discussed.
Treatese of Geophysics, vol.2

hal-00408321
https://hal.archives-ouvertes.fr/hal-00408321
DOI : 10.1016/B978-044452748-6.00045-6

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
[1] The Pyrenees, north of the North Pyrenean fault, display a complex structure involving a succession of peridotite massifs, basement massifs, and mid-Cretaceous to Late Cretaceous basins located in a narrow domain, which was affected by a mid-Cretaceous, preorogenic, high-temperature, low-pressure metamorphism. The Late Cretaceous basins were interpreted either as pull-apart basins formed during transcurrent motion of Iberia relative to Eurasia or as remnants of a larger extensional basin. Recent models support that peridotite massifs result from the exhumation of the mantle during this preorogenic event. The northern boundary of the Agly basement massif shows evidence of ductile deformation of the basal formations of the Agly sedimentary cover. Macroscopic and microscopic kinematics indicators consistent with asymmetry of crystallographic fabrics suggest normal sense of shear and thus suggest detachment, at least partial, of the Mesozoic cover from its basement. Triassic to Early Cretaceous limestones are mylonitic and consistently shows a foliation, a NS- to NE-trending lineation, shear criteria suggesting top-to-the-north shearing and locally boudinage. At the microscopic scale, mylonites are characterized by a very fine grain size, frequently <10 µm. They contain larger, partially recrystallized calcite parent grains and undeformed quartz grains with calcite fringes crystallized in pressure shadows. In these mylonites, calcite systematically shows a weak but well-defined crystallographic-preferred orientations, suggesting HT dislocation creep combined to diffusion creep and possibly grain boundary sliding in the finest fraction of the mylonites. Paleotemperatures determined using Raman spectrometry suggest synkinematic temperature conditions in the range 340-390°C, in good agreement with observed microstructures and calcite CPO. The mylonitic fabric in Mesozoic limestones is folded by EW-trending Pyrenean folds north of the Agly basement massif, attesting that this fabric formed before the Pyrenean orogeny. These data consistently support preorogenic extension under medium-temperature conditions of the northern Agly massif and likely of the massif itself. Since simultaneously (~100 Ma) a mid-Cretaceous basin opened south of the basement massif, we suggest a model of preorogenic exhumation of the Agly massif in response to the regional extension associated to the rotation of Iberia. This model may explain the exhumation of the North Pyrenean massifs during a single preorogenic event that allowed the opening of extensional basins and the exhumation of the lithospheric mantle. All these structures being subsequently reworked during the Pyrenean orogeny.
ISSN: 0278-7407

hal-00852833
https://hal.archives-ouvertes.fr/hal-00852833
DOI : 10.1002/tect.20015

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
To quantify the seismic properties of lower crustal rocks and to better constrain the origin of the lower crustal seismic reflectivity, we determined the complete 3-D seismic properties of a lower crustal section. Eight representative samples of the main lithologic and structural units outcropping in the Val Sesia (Ivrea zone) were studied in detail. The seismic velocities were calculated using the single crystal stiffness coefficients and the lattice preferred orientation (LPO) of each mineral in all samples. The 21 stiffness coefficients characterizing the elastic behaviour of each rock are determined. Mafic and ultramafic rocks such as pyroxenite and pyroxene-bearing gabbros display complex shear wave properties. These rocks are weakly birefringent (maximum 0.1 kms-1) and it is difficult to find consistent relationships between the seismic properties and the rock structure. On the other hand, seismic properties of deformed felsic rocks are essentially controlled by mica. They display strong S-wave birefringence (0.3 km s-1) and relatively high Vp anisotropy (7.6 per cent). Amphibole also strongly influences the rock birefringence patterns. For both kind of rocks, the foliation is highly birefringent and the fast polarized shear wave is systematically oriented parallel to the foliation. We show that the number of mineral phases in the rock strongly controls the anisotropy. The seismic anisotropy has a complex role in the P-wave reflectivity. Compared to the isotropic case, anisotropy enhances the reflection coefficient for about 60 per cent of the possible lithological interfaces. For 40 per cent of the interfaces, the reflection coefficient is much lower when one considers the medium as anisotropic.
ISSN: 0956-540X

hal-01389122
http://hal.univ-reunion.fr/hal-01389122
http://hal.univ-reunion.fr/hal-01389122/document
http://hal.univ-reunion.fr/hal-01389122/file/Barruol_3D_velocities_GJI1993.pdf
DOI : 10.1111/j.1365-246X.1993.tb01519.x

Éditeur(s) : HAL CCSD
Résumé : International audience
This paper presents the background for the calculation of anisotropic piezoelectric properties of single crystals and the graphical display of the results in two or three dimensions, and the calculation of the aggregate properties from constituent crystals and the texture of the aggregate in a coherent manner. The texture data can be obtained from a wide range of sources, including pole figure diffraction and single orientation measurements (electron backscattered diffraction, electron channelling pattern, Laue Pattern, optical microscope universal-stage). We consider the elastic wave propagation in piezoelectric crystals as an example of the interaction of electrical (2nd rank tensor), piezoelectric (3rd rank tensor) and elastic properties (4th rank tensor). In particular, we give explicit formulae for the calculation of the Voigt averaged tensor from individual orientations or from an orientation distribution function. For the latter we consider numerical integration and an approach based on the expansion into spherical harmonics. We illustrate the methods using single crystals, polycrystalline quartz measured using electron channelling patterns and ideal Curie limiting groups applied to quartz aggregates. This paper also serves as a reference paper for the mathematical tensor capabilities of the texture analysis software MTEX
Geological Society Special Publication, 409

hal-01277789
https://hal.archives-ouvertes.fr/hal-01277789
DOI : 10.1144/SP409.2

Éditeur(s) : HAL CCSD Geological Society, London
Résumé : This collection of papers presents recent advances in the study of deformation mechanisms and rheology and their applications to tectonics. Many of the contributions exploit new petrofabric techniques, particularly electron backscatter diffraction, to help understand the evolution of rock microstructure and mechanical properties.
Deformation Mechanisms, Rheology and Tectonics: Microstructures, Mechanics and Anistropy;Geological

hal-00685575
https://hal.archives-ouvertes.fr/hal-00685575

Éditeur(s) : HAL CCSD Geological Society of London
Résumé : International audience
Since the early descriptions published by Callaway in 1884, the gently dipping mylonites exposed along the Moine Thrust at the Stack of Glencoul have drawn generations of geologists to the northern part of the Assynt district. These mylonites, derived from Cambrian quartzites (footwall) and Moine pelites and psammites (hanging wall), have figured prominently in: a) early research into the influence of crystal plastic deformation and recrystallization on microstructural and crystal fabric evolution; b) debates on the kinematic interpretation of macro- and micro-structures and crystal fabrics; and c) debates on the tectonic significance of such kinematic data. In this paper first we briefly review the historical aspects of this research and then, using both previously published and unpublished data, document the finite strain and quartz fabric development at this classic mylonite locality. A tectonic interpretation of these data, together with quantitative estimates of flow vorticities associated with mylonite formation at the Stack of Glencoul, are presented in a companion paper by Law (2010).
Continental Tectonics and Mountain Building: The Legacy of Peach and Horne, Geological Society Speci

hal-00564962
https://hal.archives-ouvertes.fr/hal-00564962

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We present an integrated study of geochemistry, petrofabrics and seismic properties of strongly sheared eclogites from the Chinese Continental Scientific Drilling (CCSD) project in the Sulu ultrahigh-pressure (UHP) metamorphic terrane, eastern China. First, geochemical data characterize diverse protoliths of the studied eclogites. The positive Eu- and Sr-anomalies, negative Nb anomaly and flat portion of heavy rare earth elements in coarse-grained rutile eclogites (samples B270 and B295) suggest a cumulate origin in the continental crust, whereas the negative Nb anomaly and enrichment of light rare earth elements in retrograde eclogites (samples B504, B15 and B19) imply an origin of continental basalts or island arc basalts. Second, P-wave velocities (V-p) of three typical eclogite samples were measured under confining pressures up to 500 MPa and temperatures to 700 degrees C. At 500 MPa and room temperature, the mean V-p reaches 8.50-8.53 km/s in samples B270 and B295 but drops to 7.86 km/s in sample B504, and the P-wave anisotropy changes from 1.7-2.7% to 5.5%, respectively. The pressure and temperature derivatives of V-p are larger in the retrograde eclogite than in fresh ones. Third, the electron backscatter diffraction (EBSD) measurements of the eclogites reveal random crystal preferred orientation (CPO) of garnet and pronounced CPO of omphacite, which is characterized by a strong concentration of [001]-axes sub-parallel to the lineation and of (010)-poles perpendicular to the foliation. The asymmetric CPO of omphacite in sample B270 recorded a top-to-the-south shear event during subduction of the Yangtze plate. The calculated fastest V-p is generally sub-parallel to the lineation, but a different deformation environment during exhumation could form second-order variations in omphacite CPO and affect the V-p distribution in eclogites (e.g., the fastest V-p is at similar to 35 degrees from the foliation in sample 13295). Comparison between measured and calculated seismic properties indicates that the CPO of omphacite controls the seismic anisotropy of eclogites at high pressure, and compositional layering and retrograde minerals will increase the anisotropy. Calculated P-wave velocities agree well with velocities measured at 500 MPa and room temperature for fresh eclogites, but much higher than those of retrograde eclogite. As a case study, the laboratory-derived V-p-P and V-p-T relationships were used to estimate P-wave velocities of eclogites and peridotites beneath the Western Superior Province, Canada. The results indicate that besides the fabric-induced anisotropy, the direction dependence of pressure and temperature derivatives of V-p can significantly increase seismic anisotropy of eclogites with depth, which results in eclogites being an important candidate for the seismic anisotropy in the upper mantle. Due to their very high density and velocity, garnet-rich eclogites within peridotite could be detected in seismic reflections in subduction zones.
ISSN: 0040-1951

hal-00463512
https://hal.archives-ouvertes.fr/hal-00463512
DOI : 10.1016/j.tecto.2008.09.027

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
We predict the IR-TO, IR-LO and Raman modes (wave numbers and intensities) of magnesite (MgCO3) up to 50 GPa, at T = 0 K, using the density-functional perturbation theory up to a third order perturbation, under the harmonic assumption. The predicted IR-TO and Raman mode wave numbers, the mode Grüneisen parameters and the Davydov splittings are systematically compared with experimental data for all modes up to the pressures of 10-30 GPa and for some modes up to 50 GPa. Existing experiments allow extending this comparison only to IR-LO wave numbers of the E u (ν3) asymmetric-stretch mode, confirming the odd experimental behavior of this mode at very high pressures. Predicted IR-TO, IR-LO and Raman intensities up to 50 GPa are just tabulated, but data are missing for their comparison with precise experiments. However, the generally good agreement observed between numerical results and experimental data, when their comparison is possible, suggests that first-principles methods are a major help to predict the entire spectrum up to very high pressures.
ISSN: 0342-1791

hal-00527834
https://hal.archives-ouvertes.fr/hal-00527834
DOI : 10.1007/s00269-010-0395-y