Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
Garnet growth in high-pressure, mafic garnet granulites formed by dehydration melting of hornblende-gabbronorite protoliths in the Jijal complex (Kohistan palaeo-island arc complex, north Pakistan) was investigated through a microstructural EBSD-SEM and HRTEM study. Composite samples preserve a sharp transition in which the low-pressure precursor is replaced by garnet through a millimetre-sized reaction front. A magmatic foliation in the gabbronorite is defined by mafic-rich layering, with an associated magmatic lineation defined by the shape-preferred orientation (SPO) of mafic clusters composed of orthopyroxene (Opx), clinopyroxene (Cpx), amphibole (Amp) and oxides. The shape of the reaction front is convoluted and oblique to the magmatic layering. Opx, Amp and, to a lesser extent, Cpx show a strong lattice-preferred orientation (LPO) characterized by an alignment of [001] axes parallel to the magmatic lineation in the precursor hornblende-gabbronorite. Product garnet (Grt) also displays a strong LPO. Two of the four < 111 > axes are within the magmatic foliation plane and the density maximum is subparallel to the precursor magmatic lineation. The crystallographic relationship < 111 >(Grt)//[001](Opx,Cpx,Amp) deduced from the LPO was confirmed by TEM observations. The sharp and discontinuous modal and compositional variations observed at the reaction front attest to the kinetic inhibition of prograde solid-state reactions predicted by equilibrium-phase diagrams. The P-T field for the equilibration of Jijal garnet granulites shows that the reaction affinities are 5-10 kJ mol.(-1) for the Grt-in reaction and 0-5 kJ mol.(-1) for the Opx-out reaction. Petrographic and textural observations indicate that garnet first nucleated on amphibole at the rims of mafic clusters; this topotactic replacement resulted in a strong LPO of garnet. Once the amphibole was consumed in the reaction, the parallelism of [001] axes of the mafic-phase reactants favoured the growth of garnet crystals with similar orientations over a pyroxene substrate. These aggregates eventually sintered into single-crystal garnet. In the absence of deformation, the orientation of mafic precursor phases conditioned the nucleation site and the crystallographic orientation of garnet because of topotaxial transformation reactions and homoepitaxial growth of garnet during the formation of high-pressure, mafic garnet-granulite after low-pressure mafic protoliths.
ISSN: 0263-4929

hal-00411323
https://hal.archives-ouvertes.fr/hal-00411323
DOI : 10.1111/J.1525-1314.2008.00789.x

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The kinetics of hydrogenation of dry iron-bearing olivine single crystals was determined by performing hydration experiments under hydrothermal conditions at high pressure. The experiments were performed in a multi-anvil press at 3 GPa, for a temperature range between 900 and 1200 °C and for various durations. The oxygen fugacity was buffered along Ni-NiO joint. Polarized Fourier transform infrared spectroscopy and recent empirical calibration were used to quantify the hydroxyl distributions in the samples along crystallographic axes after the experiments. The chemical diffusion coefficients are similar (barely slower) than in olivine hydrated at lower pressure (0.2 and 0.3 GPa) for the same diffusion mechanism. Under the given experimental conditions, the anisotropy of diffusion is the same as for proton-vacancy mechanism, with diffusion along the [0 0 1] axis faster than along the [1 0 0]. However, the anisotropy at 3 GPa is weaker compared to measurements at lower pressures and the analysis of concentration profiles using 3D models shows that an isotropic solution could also be relevant. Fits of the diffusion data to an Arrhenius law yield activation energies for the slightly faster [0 0 1] axis of the crystallographic axes around 198 ± 5 kJ mol−1, a value only slightly lower than the results from previous experimental studies for natural iron-bearing olivine hydrogenated at lower confining pressure. At 3 GPa, hydrogenation can be well approximated by a single mechanism controlled by coupled diffusion of protons and octahedral vacancies (di- and tri-valent ions). The diffusion rates are fast enough to alter hydrogen concentration within olivine in xenoliths ascending from the mantle or experiencing hydrogen-rich metasomatism events, but too slow to permit complete homogenization of hydrogen in olivine-rich rocks at kilometer scale in less than one My.
ISSN: 0031-9201

hal-01412663
https://hal.archives-ouvertes.fr/hal-01412663
DOI : 10.1016/j.pepi.2016.08.005

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Four fibers from banana-trees (leaf, trunk) and coconut-tree (husk, fabric) were examined before their incorporation in cementitious matrices, in order to prepare insulating material for construction. Their botanical compositions have been determined following a method described previously. Thermal degradation of these fibers were studied between 200 and 700 °C under nitrogen gas flow. Temperature of pyrolysis was the experimental parameter investigated. The solid residues obtained were analyzed by classical elemental analysis, Fourier Transform Infra Red (FTIR) spectroscopy and were observed by Scanning Electron Microscopy (SEM). This study has shown (1) the relation between botanical, chemical composition with both localization of fibers in the tree and type of tree; (2) the rapid and preferential decomposition of banana fibers with increasing temperature of pyrolysis and (3) the rough samples are made of hollow fibers.
ISSN: 0960-8524

hal-00809780
https://hal.univ-antilles.fr/hal-00809780
DOI : 10.1016/j.biortech.2005.11.030

Éditeur(s) : HAL CCSD eLife Sciences Publication
Résumé : International audience
Larval recruitment, the transition of pelagic larvae into reef-associated juveniles, is a critical step for the resilience of marine fish populations but its molecular control is unknown. Here, we investigate whether thyroid-hormones (TH) and their receptors (TR) coordinate the larval recruitment of the coral-reef-fish Acanthurus triostegus. We demonstrate an increase of TH-levels and TR-expressions in pelagic-larvae, followed by a decrease in recruiting juveniles. We generalize these observations in four other coral reef-fish species. Treatments with TH or TR-antagonist, as well as relocation to the open-ocean, disturb A. triostegus larvae transformation and grazing activity. Likewise, chlorpyrifos, a pesticide often encountered in coral-reefs, impairs A. triostegus TH-levels, transformation, and grazing activity, hence diminishing this herbivore’s ability to control the spread of reef-algae. Larval recruitment therefore corresponds to a TH-controlled metamorphosis, sensitive to endocrine disruption. This provides a framework to understand how larval recruitment, critical to reef-ecosystems maintenance, is altered by anthropogenic stressors.
ISSN: 2050-084X

Droits : http://creativecommons.org/licenses/by/
hal-01633712
http://hal.upmc.fr/hal-01633712
http://hal.upmc.fr/hal-01633712/document
http://hal.upmc.fr/hal-01633712/file/elife-27595-v1.pdf
DOI : 10.7554/eLife.27595

Éditeur(s) : HAL CCSD Ecological Society of America
Résumé : Reliable assessment of fish origin is of critical importance for exploited species, since nursery areas must be identified and protected to maintain recruitment to the adult stock. During the last two decades, otolith chemical signatures (or "fingerprints") have been increasingly used as tools to discriminate between coastal habitats. However, correct assessment of fish origin from otolith fingerprints depends on various environmental and methodological parameters, including the choice of the statistical method used to assign fish to unknown origin. Among the available methods of classification, Linear Discriminant Analysis (LDA) is the most frequently used, although it assumes data are multivariate normal with homogeneous within-group dispersions, conditions that are not always met by otolith chemical data, even after transformation. Other less constrained classification methods are available, but there is a current lack of comparative analysis in applications to otolith microchemistry. Here, we assessed stock identification accuracy for four classification methods (LDA, Quadratic Discriminant Analysis [QDA], Random Forests [RF], and Artificial Neural Networks [ANN]), through the use of three distinct data sets. In each case, all possible combinations of chemical elements were examined to identify the elements to be used for optimal accuracy in fish assignment to their actual origin. Our study shows that accuracy differs according to the model and the number of elements considered. Best combinations did not include all the elements measured, and it was not possible to define an ad hoc multielement combination for accurate site discrimination. Among all the models tested, RF and ANN performed best, especially for complex data sets (e. g., with numerous fish species and/or chemical elements involved). However, for these data, RF was less time-consuming and more interpretable than ANN, and far more efficient and less demanding in terms of assumptions than LDA or QDA. Therefore, when LDA and QDA assumptions cannot be reached, the use of machine learning methods, such as RF, should be preferred for stock assessment and nursery identification based on otolith microchemistry, especially when data set include multispecific otolith signatures and/or many chemical elements.
ISSN: 1051-0761

hal-00644549
https://hal.archives-ouvertes.fr/hal-00644549
DOI : 10.1890/09-1887.1

Résumé : Au début du vingtième siècle, une rupture radicale et fondatrice de modernité artistique eut lieu au Brésil. Cette modernité se démarque de celle d’Europe par la prise de conscience des distances géographiques, culturelles et politiques vis à vis de l’Europe et surtout de l’ancienne puissance coloniale, le Portugal, par la recherche de son identité à travers la multiplicité des métissages du Nouveau Monde, ses mythes et son histoire réelle décolonisée. L’avant-garde brésilienne émerge autour de 1928, à travers les Manifestes anthropophages d’Oswald de Andrade (1890-1954) qui est donc le fondateur des anthropophagies, que l’on peut définir comme un indianisme à rebours. Le ″mauvais sauvage″ exerce sa critique contre les impostures du monde. « La ″Descente anthropophagique″ n’est pas une révolution littéraire, ni sociale, ni politique, ni religieuse. Elle est tout cela à la fois ! Sa loi est simple : Ne m’intéresse que ce qui n’est pas à moi ! Loi de l’homme, loi de l’anthropophagie ! » . Elle prescrit donc la dévoration des modèles importés et leur digestion dans l’hybridation au nom de l’identité brésilienne, par déplacement de concepts freudiens : « L’anthropophagie c’est la transformation permanente du Tabou (manger de l’homme) en Totem (de l’identité brésilienne) ! » . Ici l’influence notable de la psychanalyse et de l’anthropologie est à resituer : le déplacement du tabou anthropophage demeure une transgression symbolique, une métaphore, mais la référence anthropophagique ne concerne pas que la période précolombienne, car elle se réactualise. Nous nous proposons d’étudier ce phénomène à travers quatre questions : 1°- Quelles relations existent entre l’anthropophagie, l’histoire, l’esthétique et l’idéologie ? 2°- Quelle est la place des femmes artistes brésiliennes dans l’émergence de ce mouvement, compte tenu de leur présence décisive dès l’origine ?3°- Compte tenu de la résurgence rhizomique de l’anthropophagie dans la 2e moitié du XXe siècle, y compris jusqu’à aujourd’hui, quelle est la place des femmes artistes dans ce phénomène ? Y a-t-il continuité avec l’époque fondatrice ?4°- Etant donné ce qui précède, peut-on déduire qu’il existe un courant spécifiquement féminin dans l’anthropophagie d’hier et d’aujourd’hui ? Quelle est son importance réelle ? Quelles sont ses relations et postures par rapport à la postmodernité et à la mondialisation de l’art contemporain ?
At the beginning of the twentieth century, in Brazil, a radical artistic rupture took place, which marked the beginning of a new era. The resulting modernity differed from its European counterpart by the awareness of geographical, cultural and political distances that alienated Brazil from Europe and more specifically from its former colonial owner, Portugal. Brazilian modernity sought to define its identity through important basic elements that constitute the stuff that the New World is made of: cross-breeding, mythology and post-colonialism. The Brazilian avant-garde emerged around 1928 with the publication of The Anthropophagy Manifesto by Oswald de Andrade (1890-1954), who is thus the founder of the Anthropophagy, that we can define as a backward step into a reinvented form of ″Amerindianness″. The ″bad savage″ voices his criticism against impostures of the world. « Anthropophagy art is not a literary revolution, nor is it a social plea, nor a political pamphlet, nor a religious tract. It is all these things at the same time. Its law is simple: everything that is not me is of interest to me. The law of men is the law of Anthropophagy ». It thus prescribes eating up imported models and digesting them through the process of hybridization in the name of Brazilian identity. By displacing Freudian concepts, «Anthropophagy is the permanent transformation of the Taboo (man-eating) into a Totem (Brazilian identity) ». The permeating influences of psychoanalysis and anthropology need to be put in perspective: the displacement of the anthropophagous taboo remains a symbolic act of transgression, a metaphor, but the anthropophagic reference does not concern the pre-Columbian period, because it is updated. We propose to study this phenomenon through four questions: 1°- What are the relations between Anthropophagy, history, esthetics and ideology? 2°- What is the place of women Brazilian artists in the emergence of this movement, taking into account their decisive presence right from the start? 3°- Taking into account the resurgence of Anthropophagy from the second half of the 20th century onwards, what is the place of women artists in this phenomenon? Are they pursuing the same interests as the founders of the movement?4°- Can we deduce that there exists a specifically female genre within the anthropophagic movement of yesterday and of today? If so, what is its relevance? Where does it stand with respect to the contemporary concepts of post-modernity and globalization in the present-day art world?

http://www.theses.fr/2014AGUY0766/document

Éditeur(s) : HAL CCSD Springer
Résumé : International audience
This contribution is an attempt to present a self-contained and comprehensive survey of the mathematics and physics of material behavior of rocks in terms of texture and anisotropy. Being generally multi-phase and poly-crystalline, where each single crystallite is anisotropic with respect to its physical properties, texture, i.e., the statistical and spatial distribution of crystallographic orientations becomes a constitutive characteristic and determines the material behavior except for grain boundary effects, i.e., in first order approximation. This chapter is in particular an account of modern mathematical texture analysis, explicitly clarifying terms, providing definitions and justifying their application, and emphasizing its major insights. Thus, mathematical texture analysis is brought back to the realm of spherical Radon and Fourier transforms, spherical approximation, spherical probability, i.e., to themathematics of spherical tomography
Handbook of Geomathematics

hal-00564939
https://hal.archives-ouvertes.fr/hal-00564939

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
Wadsleyites with various iron contents were synthesized at ~12-14 GPa and 1400 °C under oxidizing and hydrous conditions in coexistence with enstatite. The samples were studied using micro-X-ray absorption near edge structure (XANES) and micro-Mössbauer spectroscopy to determine the ferric iron contents in polyphasic samples and secondary ion mass spectrometry (SIMS) to determine the water concentrations. XANES and Mössbauer analyses show that ferric iron content increases with increasing total iron content, and reaches a maximum of ~30% Fe3+/Fetotal. Two XANES results were cross-checked by Mössbauer analysis and both methods are in reasonable agreement. The use of Fourier transform infrared spectroscopy reveals a new protonation scheme in wadsleyite, with a significant proportion of protons associated with the high-frequency band at 3611 cm−1 and a new band located at 3500 cm−1. The intensity of these two bands is higher for Fe3+-rich wadsleyite. SIMS analyses show that water contents in wadsleyite vary from 4500 to 9400 ppm H2O by weight. Pyroxene water contents range from 790 to 1600 ppm wt H2O. The concentration of water in both phases decreases with increasing iron content. The partition coefficient of water between wadsleyite and pyroxene varies between 5 and 9 and increases with increasing Fe-number of wadsleyite [i.e., XFe/(XFe + XMg) × 100 ratio]. The divalent cation concentrations (i.e., Mg2+ + Fe2+), the Si as well as the H content in wadsleyite decrease with increasing Fe3+ content, indicating an incorporation mechanism via substitution into the metal (Me = Mg2+ and Fe2+) and Si sites with a ratio of 5/3 for (Fe3++H+):Me and of 5/1 for (Fe3++H+):Si, similarly as in the dry system. Thus, coupled substitution of Fe3+ and H+ does not affect the incorporation mechanism of Fe3+, but does affect the location of H+, which is partly incorporated at tetrahedral edges forming [FeSi′-(OH)o*]X neutral defects substituting for Si. In this model 25% of the ferric iron occupies the tetrahedral sites.
ISSN: 0003-004X

hal-00758071
https://hal.archives-ouvertes.fr/hal-00758071
DOI : 10.2138/am.2012.3869

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
To test if hydrogen incorporation by ionic diffusion can occur between a volatile-rich kimberlitic liquid and forsterite, results of high-pressure and high-temperature experiments using a piston-cylinder apparatus at 1200–1300 °C and 1 GPa for durations of 1 min, 5 h, and 23 h, are reported here. Kimberlitic liquid in the system CaO-MgO-Al2O3-SiO2-CO2-H2O and synthetic forsterite single crystals were chosen as a first simplification of the complex natural kimberlite composition. Unpolarized Fourier transform infrared spectroscopy was used to quantify the concentrations of OH in the crystallographically oriented forsterite. Scanning electron microscopy, electron backscattered diffraction, electron microprobe analyses, and transmission electron microscopy were performed to identify the run products. After 5 and 23 h, a forsterite overgrowth crystallized with the same orientation as the initial forsterite single crystal. The kimberlitic liquid has crystallized as micrometer-scale euhedral forsterite neocrystals with random crystallographic orientations, as well as a nanoscale aluminous phase and a calcic phase. Despite theoretical water-saturation of the system and long duration, none of the initial forsterite single crystals display signs of hydration such as hydrogen diffusion profile from the border toward the center of the crystal. Most likely, the presence of CO2 in the system has lowered the H2O fugacity to such an extent that there is no significant hydration of the starting forsterite single crystal or its overgrowth. Also, the presence of CO2 enhances rapid forsterite crystal growth. Forsterite growth rate is around 2 × 108 μm3/h at 1250 °C. These experimental results suggest a deep mantle origin of the high OH content found in natural mantle-derived xenoliths transported in kimberlites, as reported from the Kaapvaal craton. In agreement with previous studies, it also points out to the fact that significant hydration must take place in a CO2-poor environment.
ISSN: 0003-004X

hal-01217157
https://hal.archives-ouvertes.fr/hal-01217157
DOI : 10.2138/am-2015-5200

Éditeur(s) : HAL CCSD Springer/Terra Scientific Publishing Company
Résumé : International audience
Titanian clinohumite is an accessory phase found in peridotites, and it can be a key repository of volatile and other trace elements in sub-arc mantle. To characterize spectroscopic variations due to volatile elements in the phase, we have investigated the infrared spectroscopic characteristics of a suite of naturally occurring Ti clinohumite minerals with varying F and Ti concentrations. Samples were ultramafic rocks from Cerro del Almirez, Spain and Cima di Gagnone, Switzerland. The infrared spectra corresponding to OH vibrations showed systematic variation in regard to the abundance of F in Ti clinohumite. In particular, the intensity ratios of infrared absorption spectra at 3,565 and 3,390 cm-1 correlated linearly with the abundance of F independently of the crystal orientation. Raman spectra did not corroborate the Fourier transform infrared (FTIR) results. This intensity ratio provides an alternative analytical criterion for the characterization of Ti clinohumite.
ISSN: 1343-8832

hal-01133685
https://hal.archives-ouvertes.fr/hal-01133685
DOI : 10.1186/1880-5981-66-60

Éditeur(s) : Wiley-blackwell
Résumé : Aims Exopolysaccharides (EPS) are industrially valuable molecules with numerous useful properties. This study describes the techniques used for the identification of a novel Vibrio bacterium and preliminary characterization of its EPS. Methods and Results Bioprospection in marine intertidal areas of New Caledonia followed by screening for EPS producing brought to selection of the isolate NC470. Phylogenetic analysis (biochemical tests, gene sequencing and DNADNA relatedness) permitted to identify NC470 as a new member of the Vibrio genus. The EPS was produced in batch fermentation, purified using the ultrafiltration process and analysed by colorimetry, Fourier Transform Infrared spectroscopy, gas chromatography, Nuclear Magnetic Resonance and HPLC-size exclusion chromatography. This EPS exhibits a high N-acetyl-hexosamines and uronic acid content with a low amount of neutral sugar. The molecular mass was 672x103Da. These data are relevant for possible technological exploitation. Conclusions We propose the name Vibrio neocaledonicus sp. nov for this isolate NC470, producing an EPS with an unusual sugar composition. Comparison with other known polymers permitted to select applications for this polymer. Significance and Impact of the Study This study contributes to evaluate the marine biodiversity of New Caledonia. It also highlights the biotechnological potential of New Caledonia marine bacteria.
Journal Of Applied Microbiology (1364-5072) (Wiley-blackwell), 2013-06 , Vol. 114 , N. 6 , P. 1702-1712

Droits : 2013 The Society for Applied Microbiology
http://archimer.ifremer.fr/doc/00144/25501/24036.pdf
DOI:10.1111/jam.12184
http://archimer.ifremer.fr/doc/00144/25501/

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
P>The Strait of Hormuz area is a transition zone between the continental collision of the Zagros (west) and the subduction of an oceanic part of the Arabian Plate beneath the Makran wedge (east). Geology and recent GPS measurements indicate that about 15 mm yr-1 of relative motion in N10 degrees E direction is accommodated by two major fault systems: (1) the NNW-trending Minab-Zendan-Palami (MZP) fault system that connects the Main Zagros Thrust (MZT) to the inner Makran thrust system and the Frontal subduction thrust and (2) the N-trending Sabzevaran-Kahnuj-Jiroft (SKJ) fault system that bounds the Jazmurian depression to the west. We use dense GPS measurements along four transects across these fault systems in order to determine the strains spatial distribution. The northern GPS transect confirms the total fault slip rates for both fault systems estimated by the tectonic analyses (about 10 and 7.3 mm yr-1 in N10 degrees direction across the MZP and SKJ fault systems, respectively). For both fault systems, the elastic deformation spreads over shear zones that are several tens of kilometres wide. However, transects located close to latitude 27 degrees N reveal a much narrower shear zone (similar to 10 km) for the MZP fault system. Moreover, we confirm that most of the present-day strain is transferred towards the frontal subduction thrust rather than towards the inner Makran thrusts. In order to complement this new GPS velocity field with spatially dense measurements, we processed a set of ERS radar images by the radar interferometry (InSAR) technique. We used both a 'stacking' and a 'persistant-scatterers' approach to differentiate the ground deformation signal which spatial gradient is expected to be very low, from the atmospheric signal. Results from these interferograms appear to be relatively in agreement with the GPS-determined strain distribution. Nevertheless, they confirm the absence of any superficial creep behaviour since no sharp discontinuity on interferometric phase can be noted on any interferogram. Finally, we use a purely kinematic 'block model' inversion process to calculate slip rates and locking depths for each fault system from our GPS measurements. These models suggest that the relative quiescence over the last 200 yr has certainly produced a slip deficit as high as 2 m. So, we may wonder if the MZP fault system is not late in the interseismic phase of its earthquake cycle.
ISSN: 0956-540X

hal-00429386
https://hal.archives-ouvertes.fr/hal-00429386
DOI : 10.1111/j.1365-246X.2009.04321.x

Éditeur(s) : HAL CCSD
Résumé : We introduce a general context involving a presheaf A and a subpresheaf B of A. We show that all previously considered cases of local analysis of generalized functions (defined from duality or algebraic techniques) can be interpretated as the B-local analysis of sections of A. But the microlocal analysis of the sections of sheaves or presheaves under consideration is dissociated into a "frequential microlocal analysis " and into a "microlocal asymptotic analysis". The frequential microlocal analysis based on the Fourier transform leads to the study of propagation of singularities under only linear (including pseudodifferential) operators in the theories described here, but has been extended to some non linear cases in classical theories involving Sobolev techniques. The microlocal asymptotic analysis can inherit from the algebraic structure of B some good properties with respect to nonlinear operations.
https://hal.archives-ouvertes.fr/hal-00190006

Droits : info:eu-repo/semantics/OpenAccess
hal-00190006
https://hal.archives-ouvertes.fr/hal-00190006
https://hal.archives-ouvertes.fr/hal-00190006/document
https://hal.archives-ouvertes.fr/hal-00190006/file/Regularity-Local-Microlocal-Analysis5.pdf
ARXIV : 0711.3688

Éditeur(s) : HAL CCSD Académie Serbe des Sciences et des Arts
Résumé : International audience
ISSN: 0561-7332

hal-01530760
https://hal.univ-antilles.fr/hal-01530760