Éditeur(s) : HAL CCSD Elsevier
Résumé : The Borborema Province, in the NE of Brazil, is a rather complex piece in the Brazil-Africa puzzle as it represents the junction of the Dahomeyide/Pharusian, Central African, Aracuai and Brasilia fold belts located between the West-African/Sao Luis, Congo/Sao Francisco and Amazonas craton. The correlation between the Dahomeyides from W-Africa (Ghana, Benin, Togo, and Mali) and the Borborema Province involves the Medio Coreau and Central Ceara domains. The inferred continuation of the main oceanic suture zone exposed in the Dahomeyides of W Africa is buried beneath the Phanerozoic Parnaiba Basin in Brazil (northwest of the Medio Coreau domain) where some high density gravity anomalies may represent hidden remnants of an oceanic suture. In addition to this major suture a narrow, nearly continuous strip composed of mainly mafic pods containing relics of eclogite-facies assemblages associated with partially migmatized granulite-facies metapelitic gneisses has been found further east in the NW Borborema Province. These high pressure mafic rocks, interpreted as retrograded eclogites, are located between the Transbrasiliano Lineament and the Santa Quiteria continental arc and comprise primitive to evolved arc-related rocks with either arc- or MORB-type imprints that can indicate either deep subduction of oceanic lithosphere or roots of continental and oceanic magmatic arcs. Average peak P-T conditions under eclogite-facies metamorphism (T=770 degrees C and P = 17.3 kbar) were estimated using garnet-clinopyroxene thermometry and Jd content in clinopyroxene. Transition to granulite-facies conditions, as well as later widespread re-equilibration under amphibolite facies, were registered both in the basic and the metapelitic rocks and suggest a clockwise P-T path characterized by an increase in temperature followed by strong decompression. A phenomenon possibly related to the exhumation of a highly thickened crust associated with the suturing of the Medio Coreau and Central Ceara domains, two distinct crustal blocks separated by the Transbrasiliano Lineament.
ISSN: 1342-937X

hal-00413584
https://hal.archives-ouvertes.fr/hal-00413584
DOI : 10.1016/j.gr.2009.01.003

Éditeur(s) : HAL CCSD
Résumé : HYDRO
The objective of this study was to examine the water relations and hydraulic architecture and vulnerability to cavitation in Virola surinamensis and V. michelii and to compare to similar measurements in Eperua falcata. In several previous reports Virola was seen to have a rather narrow range of xylem pressure potentials ( Yx) near zero in the course of a wet-season day while having water fluxes quite close to Eperua. We tested the hypothesis that the narrow range of Yx might be consistent with very high hydraulic conductivities of stems, roots and shoots and high vulnerability to cavitation in Virola compared to Eperua. When this hypothesis proved false we concluded that the previous determinations of Y x might be wrong in Virola due to latex. We re-examined the determination of Yx in Virola by the pressure chamber technique and compared results to determination of Yleaf by the thermocouple psychrometer technique and found that the likely range of Yx are more negative than previously reported. Problems concerning the determination of Yx in species with latex are discussed.
Journal of Sigmoidal Plant Hydraulics

hal-01032396
https://hal.archives-ouvertes.fr/hal-01032396

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In orogenic systems, thrust faults play a major role in stacking different tectonic units and may act as conduits for the expulsion of large amounts of fluid of different origins (metamorphic, diagenetic, meteoric). This study focuses on the Monte Perdido thrust unit emplaced in the Paleogene Jaca thrust-sheet-top basin, in the SW-central Pyrenees. We aim to decipher the mechanisms and P-T conditions of deformation in fault zones and characterize the related fluid involvement, through combined microstructural, geochemical and microthermometry analyses. Two thrust faults cutting platform limestones, marls and siliciclastic turbidites of the lower part of the basin-fill (Paleocene-lower Eocene) have been studied. The fault zones are characterized by metre-thick shear zones with highly deformed, foliated clay-rich sediments. Foliation is underlined by preferentially oriented phyllosilicates. Several generations of shear and extension calcite, quartz and chlorite-bearing veins attest to fluid-rock interactions during a multi-stage deformation. Microstructural observations and stable isotope analyses on calcite from veins and host sediments suggest that deformation was aseismic and dominated by diffusive mass transfer from pressure solution sites along cleavage and stylolites to the precipitation sites in veins, with mineralizing fluids in equilibrium with the host sediments. Our results suggest an essentially closed hydrologic system, and imply the absence of significant fluid flow along the studied fault zones. Microthermometric study on fluid inclusions present in calcite and quartz veins, and calcite-quartz oxygen isotopic fractionation determined for the first generation shear veins, allow a geothermal gradient of 34 degrees C/km to be estimated. Analytical results demonstrate an evolution of the fault zones in three stages. The first stage was related to the emplacement of the Monte Perdido thrust unit during the middle Eocene at a temperature of similar to 208 degrees C and a burial depth of similar to 5.7 km. The second stage corresponds to a fault reactivation at a temperature of similar to 240 degrees C and a burial depth of similar to 6.5 km. The latter deformation may have been related to folding of the Monte Perdido thrust unit during the emplacement of the underlying Gavarnie thrust unit during the late Eocene-early Oligocene, with deeper burial resulting from aggradation of the thrust-sheet-top basin-fill. The last event corresponds to the formation of a dilatant vein system likely related to the exhumation of the massif.
ISSN: 0191-8141

hal-00644828
https://hal.archives-ouvertes.fr/hal-00644828
DOI : 10.1016/j.jsg.2011.06.006

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study presents microstructural evidence for deformation-controlled melt organization and for changes in olivine deformation associated with the presence of melt in an 80 m vertical section of the crust-mantle transition zone in the Oman ophiolite. This zone represents an 'end member' case for analyzing feedbacks between deformation and melt distribution in the upper mantle, since it experienced strong shear strains in presence of large melt fractions. It is characterized by a subhorizontal compositional layering at the mm to meter scale, from weakly impregnated dunites to olivine-rich gabbros, which parallels a pervasive foliation containing a strong stretching lineation. The parallelism between the compositional layering and the foliation, the diffuse limits of the layers, the alignment of elongated plagioclase-rich aggregates devoid of internal deformation structures with the elongation of olivine crystals in the dunitic layers, and the sharp compositional changes across some, but not all layer limits suggest deformation plays an essential role on the development of the layering. The variation on a mm-scale of the olivine crystal preferred orientation (CPO) symmetry as a function of the modal content: from axial-[100] symmetry in layers with <70% modal olivine to axial-[010] in more gabbroic levels (<40% olivine), which is repeated over the entire section, implies deformation in presence of variable melt fractions. Axial-[100] olivine CPO in olivine-rich layers is consistent with deformation by dislocation creep under high temperature, low pressure, dry conditions. Axial-[010] olivine CPO patterns imply additional sliding along preferentially wetted (010) grain boundaries, increase in the activity of [001] glide, or transpression localized in the melt-rich layers. Since the change in CPO symmetry is not accompanied by dispersion, instantaneous melt fractions must have remained <30-40% in all layers. The continuous variation in olivine CPO symmetry with decreasing olivine content implies therefore that the former depends on the cumulated strain in presence of melt rather than on the instantaneous melt fraction.
ISSN: 0012-821X

hal-00795508
https://hal.archives-ouvertes.fr/hal-00795508
DOI : 10.1016/j.epsl.2012.10.003

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Tilt fluctuations can potentially reflect the response of hydrosystems to important rainfall. In this context, long baseline tiltmeters have been installed in an underground tunnel penetrating the Fontaine de Vaucluse karst to study the medium deformation related to solicitations exerted by water infiltrating the hydrosystem. The instruments monitor the tilt as well as its spatial variation. Northward tilts reaching a 1 μrad amplitude are observed consecutively to rainfalls. The tilt amplitude is highly correlated with the Fontaine de Vaucluse outlet flow fluctuations. The measured tilt signal is also relatively homogeneous over a 150 m length. Different types of structure likely to produce such observations are tested in order to identify their location with respect to the tiltmeters, their dimension as well as the amount of water level variation in the structure. Following rainfalls, the infiltration of water modifies the pore pressure, inducing a medium deformation. The hypothesis of an homogeneous surface loading on the Vaucluse plateau is first refuted since the related tilt is much lower than the one measured. The water supplied by rainfalls has to accumulate in discontinuities in order to generate a higher tilt. So, the deformation related to a pressure exerted on a fracture filled by water is assessed. A first study reveals the interest of the tilt homogeneity information that constrains strongly the fracture properties. Thus, the fracture must be located at a distance more than a few hundreds metres from the tiltmeters in order to produce a tilt homogeneous in space. If the fracture is initially dry, it must also be filled on a height higher than 150 m consecutive to a rainfall in order to generate a tilt amplitude in the same magnitude as the one measured. Then, we explore the influence of water level variations on the tilt produced by a fracture located at the interface between the saturated and unsaturated zones, which are thereby permanently flooded. Since several parameters of that model satisfactorily explain the field observations, we discuss how simultaneous geodetical observations could provide complementary information that would further constrain the geometry of the structure at the origin of the medium deformation.
ISSN: 0956-540X

insu-01408482
https://hal-insu.archives-ouvertes.fr/insu-01408482
https://hal-insu.archives-ouvertes.fr/insu-01408482/document
https://hal-insu.archives-ouvertes.fr/insu-01408482/file/Lesparre-2017.pdf
DOI : 10.1093/gji/ggw446

Éditeur(s) : HAL CCSD MDPI
Résumé : International audience
The future of tropical managed forests is threatened by climate change. In anticipation of the increase in the frequency of drought episodes predicted by climatic models for intertropical regions, it is essential to study commercial trees' resilience and vulnerability to water stress by identifying potential interaction effects between selective logging and stress due to a lack of water. Focusing on 14 species representing a potential or acknowledged commercial interest for wood production in the Guiana Shield, a joint model coupling growth and mortality for each species was parametrized, including a climatic variable related to water stress and the quantity of aboveground biomass lost after logging. For the vast majority of the species, water stress had a negative impact on growth rate, while the impact of logging was positive. The opposite results were observed for the mortality. Combining results from growth and mortality models, we generate vulnerability profiles and ranking from species apparently quite resistant to water stress (Chrysophyllum spp., Goupia glabra Aubl., Qualea rosea Aubl.), even under logging pressure, to highly vulnerable species (Sterculia spp.). In light of our results, forest managers in the Guiana Shield may want to conduct (i) a conservation strategy of the most vulnerable species and (ii) a diversification of the logged species. Conservation of the already-adapted species may also be considered as the most certain way to protect the tropical forests under future climates.
ISSN: 1999-4907

hal-01315432
https://hal-sde.archives-ouvertes.fr/hal-01315432
DOI : 10.3390/f7050105

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Detailed structural and petrological mapping in the Beni Bousera peridotite (Rif Belt, northern Morocco) shows that this orogenic peridotite massif is composed of four tectono-metamorphic domains with consistent kinematics, marked by a pervasive, shallowly dipping foliation with a NW-SE stretching lineation that progressively rotates towards a NNE-SSW orientation in the lowermost part of the massif. From top to bottom, these domains are garnet-spinel mylonites, Ariègite subfacies fine-grained porphyroclastic spinel peridotites, Ariègite-Seiland subfacies porphyroclastic, and Seiland subfacies coarse-porphyroclastic to coarse-granular spinel peridotites. Microstructures and crystal preferred orientations point to deformation dominantly by dislocation creep in all domains, but the continuous increase in average olivine grain size indicates decreasing plastic work rates from top to bottom. This evolution in deformation conditions is consistent with the change in synkinematic pressure and temperature conditions, from 900°C at 2*0 GPa in garnet-spinel mylonites to 1150°C at 1*8 GPa in the Seiland domain. A pervasive diffuse dunitic-websteritic layering subparallel to the foliation suggests deformation in the presence of melt in the Seiland domain. Gravitational instabilities owing to local melt accumulation may account for <200 m wide areas exhibiting a vertical lineation in this domain. To account for the consistent kinematics and the tectono-metamorphic evolution, which implies a temperature gradient of c. 125°C km−1 preserved across the Beni Bousera massif, we propose that the entire massif records the functioning of a low-angle shear zone, a few kilometres wide, which accommodated exhumation of the base of the lithosphere from ∼90 to ∼60 km depth. Partial melting in the Seiland domain may be explained by fast decompression of the footwall, without the need for exotic heat sources. Moreover, if the present-day orientation of the shear zone is similar to that when it was active in the mantle, the stretching lineations at high angle to the metamorphic gradient imply that shearing parallel to the trend of the belt accompanied thinning; that is, a transtensional deformation of the margin.
ISSN: 0022-3530

hal-00950056
https://hal.archives-ouvertes.fr/hal-00950056
DOI : 10.1093/petrology/egt067

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In the Schistes Lustres of Alpine Corsica (France) serpentinized mantle rocks are associated with continental basement and meta-volcanic/-seclimentary cover rocks. The relationships among these different lithologies are especially well exposed in the Monte San Petrone unit, where Alpine metamorphism reached lawsonite-eclogite conditions. The contact between serpentinites and slivers of continental basement, relatively flat-lying over several kilometers, is characterized by evidence of cataclastic deformation pre-dating Alpine High-Pressure ductile fabrics. The serpentinite/continental basement pair is stratigraphically overlain by metasediments with a typical Jurassic-Cretaceous supra-ophiolitic lithostratigraphy, with metaradiolarites passing upward to marbles and cal cschists. Noticeably, no evidence of cataclastic deformation is found in metasediments. These observations indicate that the lithostratigraphy of the Monte San Petrone unit was established during a pre-Alpine polyphase evolution, which culminated in extensive brittle deformation along a flat-lying detachment fault prior to the deposition of Jurassic sediments. We suggest that the inferred Mesozoic extensional tectonics were related to the opening of the Westem Tethys. The Mesozoic architecture of the Monte San Petrone area, which is typical of an Ocean-Continent Transition (OCT) zone, was preserved despite Alpine deformation and metamorphism, when the different lithologies (i.e. meta-ophiolites, continent-derived rocks and metasediments) underwent a common metamorphic evolution, culminating at T=490-550 degrees C and P= 2.2-2.6 GPa. Similar tectonostratigraphic associations are observed in other high-pressure terranes of Alpine Corsica, suggesting that inherited OCT-type domains may be common in Alpine-type orogens.
ISSN: 0024-4937

hal-00617744
https://hal.archives-ouvertes.fr/hal-00617744
DOI : 10.1016/j.lithos.2011.02.013

Éditeur(s) : HAL CCSD Elsevier
Résumé : Kyanite and zoisite eclogites from the Limousin area in the Variscan French Massif Central (FMC) have been formed by deep subduction to 100 km depth at peak pressure-temperature conditions around 660 degrees C and 2.9 GPa. They belong to a thin tectonic unit comprising ophiolitic bodies devoid of HP-UHP markers and forming a transported suture zone now separating the two main lithotectonic units of the FMC with contrasted tectono-metamorphic features (namely the lower and upper allochthons). Composition of kyanite-eclogites is similar to supra-subduction-zone basalts found in back-arc basins or island arcs (LREE depleted, negative Nb-Ta anomalies, epsilon Nd: +6 to + 9). Zoisite eclogites have the major-element fingerprint of ultrabasic iron-rich plagioclase cumulates common in continental intrusions or forming Fe-Ti oceanic gabbros. The distribution of immobile trace-elements is however more comparable to alkaline Si-undersaturated rocks, but the Sr-Nd isotopic composition (Sr-87/Sr-86: 0.706; epsilon Nd: -3 to -5) suggests the intervention of an old radiogenic crustal component during their petrogenesis. The chemical composition of hydrous zoisite eclogites does not correspond closely to a common magmatic precursor. It is thus suggested that, by analogy with well exposed worldwide HP-UHP terranes, at least a part of the trace-element signature and the isotopic compositions are controlled by channelled fluid-rock interaction at UHP conditions, leading to localised segregation of zoisite that hosts nearly all Sr and LREE budgets of the bulk eclogite. Sr-Nd isotopic composition of these samples is thus controlled by zoisite and probably represents the isotopic composition of the fluid phase present during UHP recrystallisation. Zircons extracted from a zoisite eclogite were dated in-situ by LA-ICP-MS. Crystallisation of the magmatic precursor is bracketed between 489 and 475 Ma and the UHP event is dated at 412 +/- 10 Ma, in agreement with published ages for the Eo-Variscan HP stage in the FMC. A late resetting of the U-Pb isotopic system at 382 +/- 7 Ma is related to an anatectic high pressure-medium pressure event, well known in the Limousin area. The oceanic eclogites dated in this study are tentatively linked to the Galicia-South Brittany Lower Paleozoic Ocean; they show evidence of the existence of an intra-oceanic subduction zone at the Lower Ordovician and of partial closure of this oceanic domain by ocean-continent subduction during Early Devonian.
ISSN: 0024-4937

hal-00512835
https://hal.archives-ouvertes.fr/hal-00512835
DOI : 10.1016/j.lithos.2010.05.013

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Despite many studies, our understanding of silica precipitation from natural waters remains limited, in particular for geothermal waters. Here we present a detailed study on the kinetics of silica polymerization as a function of fluid temperature and pH using high-temperature (250-260 °C) seawater-derived geothermal fluids as those discharged from the Bouillante geothermal site.We monitored the on-site decrease in monomeric silica concentration(initial SiO2 concentration of about 600 mg/l)with time using the molybdenum blue spectrophotometric method on samples of separated water collected from the high-pressure separator at 167 °C and cooled to 25, 50, 75, and 90 °C and for pH values ranging from 5 to 8. During all these experiments, only silica polymerization was observed, with the formation of colloidal particles in suspension in the solutions. No scaling of amorphous silica was formed. The collected data were after modeled in order to determine the useful kinetic parameters for predicting and preventing amorphous silica precipitation in the production wells during fluid exploitation in the specific context of Bouillante. Results under the investigated experimental conditions show that the kinetics of silica precipitation is affected more strongly by pH than by temperature change. The reaction in the acidic Bouillante solution begins with a transition period that significantly decreases the kinetics of silica polymerization. Modeling the experimental data indicates that the silica polymerization up to the state of equilibrium is characterized by a 2nd-order kinetic law relative to dissolved silica; this could indicate that the polymerization is controlled mainly by the formation of dimers. However, the first hour of the experiments is better characterized by a 4th-order kinetic law, suggesting more complex polymerization reactions in the initial stage with the formation of nanocolloidal particles containing 3 to 4 monomers. In both cases, the corresponding kinetics rate constant k is linearly dependent on pH for pH between 5 and 7. The activation energy Ea for the overall reaction, calculated using the Arrhenius equation under the considered pH and temperature conditions, ranges between 41±9.8 and 54±9.6 kJ/mol. To complete this work, the colloid particles formed at the end of the kinetics experiments were extracted and analyzed by SEM and TEM microscopy, X-ray Diffraction and the BET method. Results show that the size of the colloids increase and their specific surface decrease with increasing pH and are thus dependent on pH. Globally, our work provides a reliable database for understanding silica polymerization kinetics in natural geothermal brines or geologic waters characterized by a near neutral pH and moderate dissolved silica concentrations.
ISSN: 0009-2541

hal-01403092
https://hal-brgm.archives-ouvertes.fr/hal-01403092
DOI : 10.1016/j.chemgeo.2016.08.031

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The Ronda orogenic peridotite (southern Spain) contains a variety of pyroxene-rich rocks ranging from high-pressure garnet granulites and pyroxenites to low-pressure plagioclasespinel websterites. The 'asthenospherized' part of the Ronda peridotite contains abundant layered websterites ('group C' pyroxenites), without significant deformation, that occur as swarms of layers showing gradual modal transitions towards their host peridotites. Previous studies have suggested that these layered pyroxenites formed by the replacement of refractory spinel peridotites. Here, we present a major- and trace-element, and numerical modelling study of a layered outcrop of group C pyroxenite near the locality of Tolox aimed at constraining the origin of these pyroxenites after host peridotites by pervasive pyroxene-producing, refertilization meltrock reactions. Mg-number [=Mg/(Mg + Fe) cationic ratio] numerical modelling shows that decreasing Mg-number with increasing pyroxene proportion, characteristic of Ronda group C pyroxenites, can be accounted for by a melt-consuming reaction resulting in the formation of mildly evolved, relatively low Mg-number melts (similar to 0.65) provided that the melt fraction during reaction and the time-integrated melt/rock ratio are high enough (>0.1 and >1, respectively) to balance Mg-Fe buffering by peridotite minerals. This implies strong melt focusing caused by melt channelling in high-porosity domains resulting from compaction processes in a partial melted lithospheric domain below a solidus isotherm represented by the Ronda peridotite recrystallization front. The chondrite-normalized rare earth element (REE) patterns of group C whole-rocks and clinopyroxenes are convex-upward. Numerical modeling of REE variations in clinopyroxene produced by a pyroxene-forming, melt-consuming reaction results in curved trajectories in the (Ce/Nd)(N) vs (Sm/Yb)(N) diagram (where N indicates chondrite normalized). Based on (Ce/Nd)(N) values, two transient, enriched domains between the light REE (LREE)-depleted composition of the initial peridotite and that of the infiltrated melt may be distinguished in the reaction column: (1) a lower domain characterized by convex-upward REE patterns similar to those observed in Ronda group C pyroxeniteperidotite; (2) an upper domain characterized by melts with strongly LREE-enriched compositions. The latter are probably volatile-rich, small-volume melt fractions residual after the refertilization reactions that generated group C pyroxenites, which migrated throughout the massifincluding the unmelted lithospheric spinel-tectonite domain. The Ronda mantle domains affected by pyroxenite- and dunite- or harzburgite-forming reactions (the 'layered granular' subdomain and 'plagioclase-tectonite' domain) are on average more fertile than the residual, 'coarse granular' subdomain at the recrystallization front. This indicates that refertilization traces the moving boundaries of receding cooling of a thinned and partially melted subcontinental lithosphere. This refertilization process may be widespread during transient thinning and melting of depleted subcontinental lithospheric mantle above upwelling asthenospheric mantle.
ISSN: 0022-3530

hal-00412200
https://hal.archives-ouvertes.fr/hal-00412200
DOI : 10.1093/petrology/egn014

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Volumetrically minor microsyenites, alkali microgranite and related trachytic dykes intrude early Pliocene OIB-like alkali basaltic and basanitic flows of the Meseta del Lago Buenos Aires in Central Patagonia (47 degrees S-71 degrees 30'W), and occur together with scarce trachytic lava flows. Whole-rock K-Ar ages between 3.98 and 3.08 Ma indicate that the emplacement of these felsic rocks occurred more or less synchronously with that of the post-plateau basaltic sequence that they intrude, during a bimodal mafic-felsic magmatic episode devoid of intermediate compositions. Chemically, these rocks have A(1)-type granitoid affinities and are characterized by high silica and alkali contents (60-68 wt.% SiO2; 8.7-10.8 wt.% Na2O+K2O), major and trace elements patterns evidencing evolution by low-pressure fractional crystallization, and Sr and Nd isotopic signatures similar to those of coeval basalts ((Sr-87/Sr-86)o=0.70488-0.70571; (Nd-143/Nd-144)(o)=0.512603-0.512645). Nevertheless, some of them have the most radiogenic Sr values ever reported for a magmatic rock in the Meseta and even in the whole Neogene Patagonian Plateau Lavas province ((Sr-17/Sr-86)(o)= 0.70556-0.70571; (Nd-143/Nd-144)(o)=0.512603-0.512608). In addition, very high contents of strongly incompatible elements in the most evolved rocks, together with Sr isotopic ratios higher than those of coeval basalts, suggest the occurrence of open-system magmatic processes. Continuous fractional crystallization from a primitive basaltic source, similar to post-plateau coeval basalts, towards alkali granites combined with small rates of assimilation of host Jurassic tuffs (AFC) in a shallow magmatic reservoir, best explains the geochemical and petrographic features of the felsic rocks. Therefore, A(1)-type magmatic rocks can be generated by open-system crystallization of deep asthenospheric melts in back-are tectonic settings. In Central Patagonia, these similar to 3-4 Ma old alkaline intrusions occur aligned along a similar to N160-170 trending lineament, the Zeballos Fault Zone, stacking the morphotectonic front of one segment of the Patagonian Cordillera. Intrusion along this fault zone
ISSN: 0024-4937

hal-00412030
https://hal.archives-ouvertes.fr/hal-00412030
DOI : 10.1016/j.lithos.2007.07.002

Éditeur(s) : HAL CCSD Elsevier Masson
Résumé : In Vietnam, the Triassic Indosinian collision affected coevally the Truong Son belt and the Kontum Massif,which were not independent tectonic units, but parts of the same Gondwana-derived Indochina continental block. This thermotectonic event took place synchronously throughout Vietnam, during the Lower Triassic 250-240-Ma time interval, as demonstrated by numerous geochronological data, combining Ar-Ar and U-Pb dating methods. Structural and kinematic investigations, in the Indosinian metamorphic rocks, reveal that the collisional process resulted from a consistent northwest-striking convergence of Indochina with respect to the adjacent blocks. It is suggested that this motion was taken up by a pair of opposite subduction zones: to the north, beneath South China, and to the west, beneath western Indochina, along the Song Ma and Po Ko sutures, respectively. Tectonic markers, calc-alkaline subduction-related volcanism and granitic intrusions and the generation of high-pressure rocks that have been recently discovered support this geodynamic setting, at least along Po Ko. Along the northwest-trending Song Ma zone, the obliquity of the convergence during subduction and subsequent collision resulted in the development, within the Truong Son Belt, of a set of subparallel dextral mylonitic shear zones, under amphibolite-facies metamorphism. The intermediate segments remained weakly metamorphic or even almost devoid of metamorphism. Along Po Ko, the convergence was near-orthogonal, with a left-lateral strike-slip component; the ongoing continental subduction resulted in the reworking of the Kontum granulitic basement and the development of Indosinian HP granulitic conditions; the subsequent extension-related exhumation operated approximately in the same northwestwards direction. This Indosinian evolution, applied on a continental crust that had been probably affected, as in South China, by a Caledonian-related event, as judged by the general unconformity of the Lower Devonian sediments, the widespread occurrence of magmatic crystallisation ages of ca 450 Ma (Ordovician-Silurian), and by the approximately similar age of the primary granulitic episode in the Kontum Massif. The similarities of the Devonian facies over central, northern Vietnam and South China imply a land connection, possibly as a consequence of a Caledonian collision along Song Ma, but this does not preclude a further oceanic opening and a closure during the Indosinian.
ISSN: 1631-0713

hal-00411591
https://hal.archives-ouvertes.fr/hal-00411591
DOI : 10.1016/j.crte.2007.10.005

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We have inferred the deformation mechanisms of antigorite by high-resolution EBSD mapping of samples from Cerro del Almirez ultramafic massif (Betic Cordillera, SE Spain). Textural relations and phase diagram calculations constrain the foliation development conditions to the subduction prograde path at up to 600-630 °C and 1.6-1.9 GPa. Deformation was followed by static annealing of antigorite at ca. 680 °C. The Crystal Preferred Orientation (CPO) of antigorite is characterised by a strong alignment of (001) poles normal to the foliation plane and a weaker, but clear, parallelism between [100] axes and the macroscopic lineation defined by the elongation of magnetite aggregates. Analysis of misorientations across subgrains shows predominance of [010] rotation axis, consistent with activation of the [100](001) slip system. However, tilt subgrain boundaries subparallel to (100), probably formed by edge dislocations of this system, are subsidiary. Most subgrain boundaries are subparallel to (001) planes. They are interpreted as (001) twins wherein continuing viscoplastic deformation resulted in a slight increase of the misorientation between the twins. Modelling of the evolution of the antigorite CPO using a lower bound approach and considering different deformation regimes and sets of basal and non-basal slip systems has shown that intensities of [100] and [010] maxima reflect the relative strength of the antigorite [100](001) and [010](001) systems. Activation of other basal or non-basal slip systems does not change significantly the CPO patterns, but results in less concentrated CPO. 3D transpression models better reproduce the CPO of natural antigorite serpentinites. We propose that the widespread occurrence of strong CPO in high-pressure antigorite serpentinite is consistent with deformation by dislocation creep with dominant glide on [hk0](001), together with the activation of twinning, implying that a power law rheology would better account for the mechanical behaviour of antigorite serpentinite deep in the subduction channel and mantle wedge.
ISSN: 0012-821X

hal-00795511
https://hal.archives-ouvertes.fr/hal-00795511
DOI : 10.1016/j.epsl.2012.06.049

Éditeur(s) : HAL CCSD
Résumé : International audience
Metamorphic soles correspond to m to 500 m thick highly strained metamorphic rock units found beneath myloniticbanded peridotites at the base of large-scale ophiolites, as exemplified in Oman. Metamorphic soles aremainly composed of metabasalts deriving from the downgoing oceanic lithosphere and metamorphosed up togranulite-facies conditions by heat transfer from the mantle wedge. Pressure–temperature peak conditions areusually estimated at 1.00.2 GPa and 800100ºC. The absence of HP–LT metamorphism overprint implies thatmetamorphic soles have been formed and exhumed during subduction infancy. In this view, metamorphic soleswere strongly deformed during their accretion to the mantle wedge (corresponding, now, to the base of the ophiolite).Therefore, metamorphic soles and banded peridotites are direct witnesses of the dynamics of early subductionzones, in terms of thermal structure, fluid migration and rheology evolution across the nascent slab interface.Based on fieldwork and EBSD analyses, we present a detailed (micro–) structural study performed on samplescoming from the Sumeini window, the better-preserved cross-section of the metamorphic sole of Oman. Largedifferences are found in the deformation (CPO, grain size, aspect ratio) of clinopyroxene, amphibole and plagioclase,related to mineralogical changes linked with the distance to the peridotite contact (e.g., hardening due to theappearance of garnet and clinopyroxene).To model the incipient slab interface in laboratory, we carried out 5 hydrostatic annealing and simple-shear experimentson Griggs solid-medium apparatus. Deformation experiments were conducted at axial strain rates of 10-6s-1. Fine-grained amphibolite was synthetized by adding 1 wt.% water to a (Mid-Ocean Ridge) basalt powder asa proxy for the metamorphic sole (amphibole + plagioclase + clinopyroxene garnet assemblage). To synthetizegarnet, 2 experiments were carried out in hydrostatic conditions and with deformation at 800C with confiningpressure of 2 GPa. Another simple-shear experiment has been carried out at 800C and 1 GPa with fined-grainednatural garnet. With the aim of mimicking the early slab interface (between the metamorphic sole and bandedperidotites at the base of the ophiolite), 2 simple-shear deformation experiments with 2 layers have been carriedout at 800C and confining pressure of 1 GPa. The bottom layer was made of hydrated basalt powder and the toplayer was made of olivine.Fined-grained garnet-free amphibolite is significantly weaker than dunite but the appearance of harder mineralsin the amphibolite (garnet and clinopyroxene) has major implications on its rheological evolution. These resultsallow liking field observations of strain localization at the interface to the metamorphic sole formation
European Geosciences Union General Assembly 2016
Vienne, Austria

insu-01309394
https://hal-insu.archives-ouvertes.fr/insu-01309394

Éditeur(s) : HAL CCSD De Gruyter
Résumé : International audience
Wallaba (Eperua falcata) is a tropical wood which is known to have naturally low swelling characteristics. Samples of wallaba heartwood were subjected to differential solvent extraction. Wood pieces that were extracted with methanol experienced significantly higher swelling after rehydration from oven dry to 96% relative humidity in comparison to non-extracted samples and samples extracted with other solvents. Methanol soluble wallaba heartwood extract was purified by high pressure liquid chromatography and the compounds present were characterised by nuclear magnetic resonance spectroscopy. Methanol extract was found to contain a very high relative proportion of polar compounds which are proposed to bind to the polymeric cell wall by multiple hydrogen bonds restricting the association of water and therefore acting as natural anti-swelling agents.
ISSN: 0018-3830

hal-00856942
https://hal.archives-ouvertes.fr/hal-00856942
https://hal.archives-ouvertes.fr/hal-00856942/document
https://hal.archives-ouvertes.fr/hal-00856942/file/Chemical_extractives_tropical_wood_Royer_al.pdf

Résumé : La gestion du foncier martiniquais est un sujet complexe, sensible et à forte densité politique. La superficie de la Martinique est de 1 100km2, soit l’une des plus petites régions françaises, avec la plus forte densité de population, soumise à de multirisques (cyclonique, sismique, volcanique, technologique, inondation, pollution de l’air, des sols et de l’eau, tsunami…).La triangulation urbanistique composée d’une multiplicité d’acteurs, de textes et de réglementations et d’un millefeuille institutionnel (6 niveaux d’administration : commune, intercommunalité, département, région, Etat, Europe) annihile toute responsabilité et obère un développement endogène de ce micro territoire.Un juste équilibre entre développement économique, social, culturel et environnemental doit être trouvé en conciliant les objectifs économiques et sociaux liés au développement insulaire.La remarquable biodiversité de la Martinique constitue un atout touristique indéniable, menacé par de fortes pressions anthropiques foncières.Cette recherche démontre la pertinence de la réglementation applicable au foncier à la Martinique et l’influence du développement durable sur cette réglementation. La thèse propose des solutions pérennes à mettre en œuvre pour pallier les incohérences juridiques révélées par l’étude.
Management of land in Martinique is a complex, sensitive and highly political topic.The total area of the island is 1 100 km2 (square meters), e.g, one of the smallest French areas, with the highest concentration of population, submitted to multirisk desasters (cyclonic, seismic, volcanic, technological, flood, air, ground and water pollutions, tsunami…).The urban triangulation made up of a multiplicity of actors, texts and regulations, as well as a multi-level institutional cream cake (6 levels of administration: the city, the intercity, the Department, the Regional Council, the State and Europe), destroys all kind of responsibility and obstruct an endogenous development of this micro territory.A fair balance between economic, social, cultural and environmental development is necessary, by reconciling with the economic and social goals related to the insular development.The astonishing biodiversity of the island of Martinique represents an obvious tourist asset, threatened by strong land anthropic pressures.This research study highlights the relevance of the regulation applicable to the land in Martinique as well as the influence of sustainable development on this regulation. This thesis suggests perennial solutions to implement, in order to mitigate the legal inconsistencies pointed out by the study.

http://www.theses.fr/2011AGUY0503/document

Éditeur(s) : HAL CCSD
Résumé : The mantle deformation processes that control the thinning and break-up of continental lithosphere remain poorly understood. Our knowledge is restricted to either lithospheric scale thermo-mechanical models --that use experimentally derived flow laws--, geophysical imaging and/or rare xenoliths from active continental rifts, such as the East African Rift System. The originality of this work relies on the study of the two largest outcrops of diamond facies subcontinental lithospheric mantle in the world: the Beni Bousera and Ronda peridotite massifs in N Morocco and S Spain, respectively. The structures and petrologic and metamorphic zoning preserved in these massifs --implying a polybaric and polythermal evolution-- provides a unique opportunity to investigate the thermo-mechanical evolution of thick subcontinental lithospheric mantle in extensional settings. In this thesis we studied the deformation mechanisms in both peridotites and pyroxenites to constrain the modes of exhumation of subcontinental lithospheric mantle from garnet-, to spinel-, and finally, to plagioclase lherzolite facies conditions. We combined field mapping of tectonometamorphic domains and structural mapping of ductile structures, microstructural analysis, crystal preferred orientations (CPO) measurements and conventional thermobarometric calculations and thermodynamic modeling (Perple_X) to unravel the pressure and temperature conditions of deformation. We showed that exhumation from garnet- to spinel lherzolite facies conditions was accommodated by fast shearing --in thermal disequilibrium--along a lithospheric scale transtensional shear zone. In this context, the petrological zoning and the large temperature gradient (ca. 100ºC/km) preserved in the Beni Bousera massif represent the mechanical juxtaposition of progressively deeper and hotter lithospheric levels at depths of ca. 60 km in the latest Oligocene (ca. 25 Ma). Final exhumation from spinel- to plagioclase facies lherzolite and emplacement into the crust is best recorded in the Ronda massif where it occurred by inversion and lithospheric scale folding of the highly attenuated continental lithosphere in a back-arc region, probably in relation with southward slab rollback and subsequent collision with the palaeo-Maghrebien passive margin in the early Miocene (21-23 Ma).
Les processus de déformation contrôlant l'amincissement de la lithosphère continentale sont encore mal contraints. Nos connaissances sont principalement basées sur la modélisation thermomécanique d'extension à l'échelle de la lithosphère--utilisant des lois rhéologiques derivées expérimentalement, l'imagerie géophysique et l'analyse de xénolithes provenant de rift continentaux actifs à ce jour, tels que le Rift Est-Africain. L'originalité de ce travail reside dans l'étude des deux plus grands massifs de péridotites sous-continentales ayant enregistrées des conditions primaires du facies à diamant: les massifs de Beni Bousera au nord du Maroc et de Ronda au sud de l'Espagne, respectivement. Les structures et la zonation petrologique et métamorphique --impliquant une évolution polybarique et polythermique-- préservéees dans ces massifs offrent une opportunité unique pour étudier l'évolution thermo-mécanique du manteau sous-continental dans un contexte extensif. Dans ce travail, nous avons étudié les mécanismes de déformation des péridotites et des pyroxénites afin de contraindre les modes d'exhumation du manteau lithosphérique sous-continental, depuis des conditions du facies des lherzolites à grenat, jusqu'au facies à spinelle et enfin à plagioclase. Nous avons combiné la cartographie des faciès tectono-métamorphiques et des structures ductiles de déformation, l'analyse des microstructures, la mesure d'orientations préférentielles de réseau (OPR), et la géothermobarométrie conventionelle couplée à la modélisation thermodynamique (PerpleX) afin de contraindre les conditions de pression et température de la déformation. Nous avons montré que l'exhumation précoce du facies à grenat au facies à spinelle était accomodée par une faille transtensive affectant le manteau lithosphérique. Dans ce contexte, la zonation tectono-métamorphique et le gradient thermique important (ca. 100ºC/km) préservés à Beni Bousera résultent de la juxtaposition mécanique de domaines lithosphériques initialement équilibrés à différentes pressions et températures, fossilisée à une profondeur de ca. 60 km durant l'Oligocène supérieur (ca. 25 Ma). L'exhumation finale du facies de lherzolite à spinelle au facies à plagioclase et l'emplacement final dans la croûte, mieux enregistrés dans Ronda, se sont produits par inversion et plissement de la section lithosphérique fortement amincie dans un contexte arrière-arc, probablement lors du retrait vers le sud de la lithosphère subduite et la collision de l'arc avec les paléo-marges maghrébines au Miocène inférieur (21-23 Ma).
https://tel.archives-ouvertes.fr/tel-00767700

tel-00767700
https://tel.archives-ouvertes.fr/tel-00767700
https://tel.archives-ouvertes.fr/tel-00767700/document
https://tel.archives-ouvertes.fr/tel-00767700/file/THESE_Frets.pdf

Résumé : Favorisées par les gouvernants en quête d’un nouveau modèle post-industriel, les économies basées sur la connaissance vont devenir en quelques décennies le référentiel à atteindre pour le développement de territoires soumis aux pressions de la globalisation.Longtemps considérés comme des éléments indispensables à la production et à la transmission du savoir, les établissements d’enseignement supérieur et de recherche, comme les universités, ont été de plus en plus intégrés dans les analyses sur le développement territorial à mesure que s’imposait le paradigme américain de la valorisation des activités de la recherche publique. Cette nouvelle mission imposée aux établissements de recherche, suppose qu’ils sont des facteurs d’un développement localisé. Mais le rôle qui leur est assigné est-il justifié ? À travers l’impact singulier de la recherche publique, on peut analyser la place de ces établissements sur leur territoire d’accueil. Apres avoir fait un état de l’art en matière d’analyse d’impact nous utilisons le cadre méthodologique de l’étude d’un cas illustrant cette problématique. L’agglomération de Brest mise sur la forte concentration d’établissements de recherche à vocation maritime pour développer le cluster local. Bien que non généralisable, ce cas éclaire les recherches dans ce domaine. Au-delà, la thèse apporte une autre vision sur les réformes de type top down des systèmes d’enseignement supérieur et de recherche considérant le savoir comme n’importe quel bien économique. Or la connaissance n’est pas un bien comme les autres. Et c’est cette singularité qui explique les difficultés d’analyse dans le champ de l’économie de la connaissance.
Promoted by governments seeking for a new post-industrial model, the knowledge-based economies will become in a few decades the repository to reach for the development of territories subject to the pressures of globalization. Regarded as essential to the production and transmission of knowledge, higher education and research institutions, such as universities, have been increasingly integrated into the analysis of territorial development while was emerging the american paradigm for valorisation of public research activities. This new mission imposed on research institutions, assume they are factors of localized development. Is this assigned role justified? Through the singular impact of public research, we can analyze the role of these institutions on their home territory. After a state of the art on the impact assessments, we developed a methodological framework for case study illustrating this problem. In the agglomeration of Brest, there is a high concentration of research institutions with maritime vocation on which rely the local cluster. Although not generalizable, this case enlightens the research in this domain. In addition, the thesis sheds new light on the top-down reforms of higher education and research systems considering knowledge as any economic good. But knowledge is not a commodity like others. And that would explain the difficulties of analysis in the field of the knowledge economy.

http://www.theses.fr/2014AGUY0807/document

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report chlorine (Cl) and fluorine (F) abundances in minerals, interstitial glasses, and melt inclusions in 12 andesite-hosted, spinel harzburgite xenoliths and crosscutting pyroxenite veins exhumed from the sub-arc lithospheric mantle beneath Avacha volcano in the Kamchatka Arc (NE Russia). The data are used to calculate equilibrium mineral-melt partition coefficients (Dmineral/meltDmineral/melt) for Cl and F relevant to subduction-zone processes and unravel the history of volatile depletion and enrichment mechanisms in an arc setting.Chlorine is ∼100 times more incompatible in pyroxenes (View the MathML sourceDClmineral/melt = 0.005–0.008 [±0.002–0.003]) than F (View the MathML sourceDFmineral/melt = 0.50–0.57 [±0.21–0.24]), which indicates that partial melting of mantle sources leads to strong depletions in Cl relative to F in the residues. The data set in this study suggests a strong control of melt composition on View the MathML sourceDCl,Fpyroxene/melt, in particular H2O contents and Al/(Al + Si), which is in line with recent experiments. Fluorine is compatible in Ca-amphibole in the ‘wet’ sub-arc mantle (View the MathML sourceDFamphibole/melt = 3.5–3.7 [±1.5]) but not Cl (View the MathML sourceDClamphibole/melt = 0.03–0.05 [±0.01–0.03]), indicating that amphibole may fractionate F from Cl in the mantle wedge. The inter-mineral partition coefficients for Cl and F in this study are consistent amongst different harzburgite samples, whether they contain glass or not. In particular, disseminated amphibole hosts much of the Cl and F bulk rock budgets of spinel harzburgites (View the MathML sourceDClamphibole/pyroxene up to 14 and View the MathML sourceDFamphibole/pyroxene up to 40). Chlorine and fluorine are variably enriched (up to 1500 ppm Cl and 750 ppm F) in the parental arc picrite and boninite melts of primitive pyroxenite veins (and related melt inclusions) crosscutting spinel harzburgites.Based on the data in this study, the main inferences on the behaviour of Cl and F during melting and metasomatic processes in the sub-arc mantle are as follow:(i) Melting models show that most depleted mantle protoliths of intra-oceanic arc sources can have extremely low Cl/F (0.002–0.007) before being overprinted by subduction-derived components.(ii) Chlorine has a higher percolation distance in the mantle than F. Even for small fluid or melt volumes, Cl and F signatures of partial melting are overprinted by those of pervasive percolation, which increases Cl/F in percolating agents and bulk peridotites during chromatographic interaction and/or amphibole-forming metasomatic reactions. These processes ultimately control the bulk Cl and F compositions of the residual mantle lithosphere beneath arcs, and likely in other tectonic settings.(iii) Fluxed melting models suggest that Cl enrichment in arc picrite and boninite melts in this study, and in many arc melt inclusions reported in the literature, could be related to the infiltration of high Cl/F fluids derived from subducted serpentinite or altered crust in mantle wedge sources. However, these high Cl/F signatures should be re-evaluated with new models in light of the possible overprint of pervasive percolation effects in the mantle. The breakdown of amphibole (and/or mica) in the deep metasomatised mantle at higher pressure and temperature conditions than in the slab may explain, at least in part, the positive correlations between F abundances and Cl/F in primitive arc melt inclusions and slab depth.
ISSN: 0016-7037

hal-01553610
https://hal.archives-ouvertes.fr/hal-01553610
DOI : 10.1016/j.gca.2016.10.035