Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Transmission electron microscopy observations on olivine crystals deformed at moderate (≤1273 K) temperature evidenced dislocations interactions explaining the hardening observed in the experiments, but also recovery mechanisms by the absorption or emission of point defects. Thus we investigate the possibility that, at geological strain-rates, these recovery processes allow steady-state deformation by dislocation creep at low to moderate temperatures in the lithospheric mantle. We test this hypothesis using a 2.5-D dislocation dynamics (DD) model, which combines dislocation glide and recovery by climb. This model shows that diffusion-controlled recovery processes allow for steady-state deformation by dislocation creep in the lithospheric mantle at stresses <500 MPa. For stresses of 50–200 MPa, steady-state strain-rates of 10−15 s−110−15 s−1 may be attained at temperatures as low as 900 K. Fitting of the DD model produces a flow law, which represents a lower bound for the lithospheric mantle strength, since the models describe the deformation of an olivine single crystal in an easy slip orientation. Comparison of strain-rates and Moho temperatures inferred for different geodynamic environments and the predictions of this model-based flow law implies, nevertheless, that, except in incipient rifts, most of the observed deformation may be produced by stress levels ≤200 MPa, consistent with those inferred to be produced by convection. This convergence suggests that the present models, which explicitly calculate the time-dependent dislocation dynamics, may provide a correct first order estimate of the mechanical behaviour of the lithospheric mantle, which cannot be derived directly from any existing data.
ISSN: 0012-821X

hal-01277178
https://hal.archives-ouvertes.fr/hal-01277178
https://hal.archives-ouvertes.fr/hal-01277178/document
https://hal.archives-ouvertes.fr/hal-01277178/file/Boioli.pdf
DOI : 10.1016/j.epsl.2015.10.012

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
Due to shallow penetration of millimeter waves (MMW) and convection in liquid medium surrounding cells, the problem of accurate assessment of local MMW heating in in vitro experiments remains unsolved. Conventional dosimetric MMW techniques, such as infrared imaging or fiber optic (FO) sensors, face several inherent limits. Here we propose a methodology for accurate local temperature measurement and subsequent specific absorption rate (SAR) retrieval using microscale thermocouples (TC). SAR was retrieved by fitting the measured initial temperature rise to the numerical solution of an equivalent thermal model. It was found that the accuracy of temperature measurement depends on thermosensor size, that is, the smaller TC, the more accurate the temperature measurement. SAR determined using TC with lead diameters of 25 and 75m demonstrated 98.5% and 80.4% match with computed SAR, respectively. However, both TC provided the same temperature rises in long run (>10min). FO probe failed to measure adequately local heating both for short and long exposures due to the relatively large size of the probe sensor (400m) and time constant (0.6s). Calculated SAR in the cell monolayer was almost two times lower than that in the surrounding liquid. It was shown that the impact of the cell monolayer on heating due to its small thickness (5 to 10m) can be considered as negligible. Moreover, we demonstrated the possibility of accurate measurement of MMW-induced thermal pulses (up to 10 degrees C) using 25m TC. Bioelectromagnetics. 38:11-21, 2017. (c) 2016 Wiley Periodicals, Inc.
ISSN: 0197-8462

hal-01436768
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01436768
DOI : 10.1002/bem.21999
PUBMED : 27571392

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
Abstract View references (60)Here we show the long term performance at high temperatures of a multi-tube module containing 8 membranes in 4 parallel lines with a total of 545 cm 2 area. The membranes were prepared via thin film dip coating of cobalt oxide silica (CoO xSi) sol-gel on tubular alumina supports. A preliminary study found that the sol-gel containing 20 mol% cobalt oxide formed the best microporous structure with the highest surface area and pore volume. All resulting membranes delivered permeances of ∼1 × 10 -7 mol m -2 s -1 Pa -1 at 500 °C, indicating a high repeatability for the membrane fabrication process. The permselectivities of helium (He) and hydrogen (H 2) over carbon dioxide (CO 2) and nitrogen (N 2) increased from 10-20 at 100 °C to values close to 1000 at 500 °C. Additionally, the apparent energies of activation (E act) for the smaller kinetic diameter gases He and H 2 at 12.2 and 19.5 kJ mol -1 were high and contrary to the negative values for larger gases N 2 and CO 2 at -1.8 and -7.4 kJ mol -1. These remarkable results were attributed to the molecular sieving mechanism of the microporous silica which was enhanced by the embedding of cobalt oxide into the matrix, delivering structural control with an average pore size of 3 Å. The E act for H 2 permeance was higher than that of He, indicating that the cobalt oxide played an important role in H 2 transport. Two membrane lines performed exceptionally well for binary gas mixture processing with H 2 purity reaching values close to 100% in the permeate stream for argon (Ar) concentrations of up to 80% in the retentate stream. A major finding here is that the binary gas selectivity was independent of temperature, contrary to the permselectivity observed for single gas permeance. Further, the H 2 flow rate was greatly affected by the concentration of Ar in the mixture, while the temperature dependency played only a marginal role. In particular, competitive adsorption in the percolative pathways containing pore constrictions or bottlenecks of the anisotropic CoO xSi matrix allowed Ar to impede H 2 diffusion. Finally, the CoO xSi membranes proved thermally stable and robust for 2000 h of testing for various thermal cycles up to 500 °C. © The Royal Society of Chemistry 2012.
Energy & Environmental Science

hal-01683199
https://hal.univ-antilles.fr/hal-01683199
DOI : 10.1039/c2ee03247c

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The diffusion of titanium along with Ni, Co and Mn in pure synthetic forsterite has been studied as a function of temperature, oxygen fugacity, crystallographic orientation and chemical potentials in the four-component system MgO–SiO2–TiO2–TiO1·5. In over 100 different experimental conditions, no Ti diffusion profiles with the classical shape of the error function were observed. Instead, the profiles vary between ‘stepped’ at high fO2 (probably owing to diffusion on octahedral sites and trapping in tetrahedral sites), to hockey-stick shapes at low fO2 owing to concentration-dependent diffusion. The profile shapes vary systematically between these end-members according to oxygen fugacity. These profile shapes are also reproduced in experiments using natural San Carlos olivine. The change in profile shape is interpreted to be a function of valence-state change from Ti4+ to Ti3+, shown by a sigmoidal log fO2–diffusivity relationship. To distinguish between Ti4+ and Ti3+ in forsterite, a diffusion profile was also investigated using ‘hydroxylation spectroscopy’ whereby a crystal from a diffusion experiment was hydroxylated by annealing in an H2O-rich fluid at moderate pressure and temperature. The point defects associated with the added structural OH were then determined by infrared spectroscopy, providing evidence for the presence of Ti4+ and Ti3+ at intermediate oxygen fugacity. The transition from Ti4+ to Ti3+ occurs at considerably higher fO2 in these diffusion experiments than in equilibrium experiments in similar systems. Titanium diffusion, qualified using a mobility parameter (M), is fastest along the c-axis, at high activity of silica, low oxygen fugacity and high temperature. The rate of Ti diffusion is broadly similar to those of Mn, Ni and Co, and closer to published rates of Mg self-diffusion in olivine than Si self-diffusion. The observed Ti3+ and Ti4+ diffusion occurs on the M-sites. From statistical examination of the large Mn, Ni and Co diffusivity dataset, we determine that there is a 102/3 dependence of diffusion on aSiO2; the cations diffuse more rapidly at high aSiO2. In addition, diffusivity has a 10–1/8 dependence on fO2, suggested to be the result of increased concentration of loosely bound Ti3+–vacancy pairs, which enhance the mobility of other cations. This behaviour is likely to be present in natural systems where trivalent (e.g. Fe3+, Al3+, Cr3+) and divalent cations diffuse together. Consideration should be given to diffusive interference by highly charged, fast-moving cations when extracting time scales from frozen diffusion profiles.
ISSN: 0022-3530

hal-01531344
https://hal.archives-ouvertes.fr/hal-01531344
DOI : 10.1093/petrology/egw067

Éditeur(s) : HAL CCSD American Chemical Society
Résumé : International audience
Aromatic amines and structurally related heterocyclic aromatic amines (HAAs) are produced during the combustion of tobacco or during the high-temperature cooking of meat. Exposure to some of these chemicals may contribute to the etiology of several common types of human cancers. 2-Amino-9H-pyrido[2,3-b]indole (AαC) is the most abundant HAA formed in mainstream tobacco smoke: it arises in amounts that are 25-100 times greater than the levels of the arylamine, 4-aminobiphenyl (4-ABP), a human carcinogen. 2-Amino-3,8-dimethylimidazo[4,5-f]quinoxaline (MeIQx) is a prevalent HAA formed in cooked meats. AαC and MeIQx are rodent carcinogens; however, their carcinogenic potency in humans is unknown. A preliminary assessment of the carcinogenic potential of these HAAs in humans was conducted by examining the capacity of primary human hepatocytes to form DNA adducts of AαC and MeIQx, in comparison to 4-ABP, followed by the kinetics of DNA adduct removal by cellular enzyme repair systems. The principal DNA adducts formed were N-(deoxyguanosin-8-yl) (dG-C8) adducts. Comparable levels of DNA adducts were formed with AαC and 4-ABP, whereas adduct formation was ∼5-fold lower for MeIQx. dG-C8-AαC and dG-C8-4-ABP were formed at comparable levels in a concentration-dependent manner in human hepatocytes treated with procarcinogens over a 10,000-fold concentration range (1 nM-10 μM). Pretreatment of hepatocytes with furafylline, a selective inhibitor of cytochrome P450 1A2, resulted in a strong diminution of DNA adducts signifying that P450 1A2 is a major P450 isoform involved in bioactivation of these procarcinogens. The kinetics of adduct removal varied for each hepatocyte donor. Approximately half of the DNA adducts were removed within 24 h of treatment; however, the remaining lesions persisted over 5 days. The high levels of AαC present in tobacco smoke and its propensity to form persistent DNA adducts in human hepatocytes suggest that AαC can contribute to DNA damage and the risk of hepatocellular cancer in smokers.
ISSN: 0893-228X

inserm-00869907
http://www.hal.inserm.fr/inserm-00869907
DOI : 10.1021/tx4002226
PUBMED : 23898916

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The indoor gas-phase concentrations of semi-volatile organic compounds (SVOCs) can be predicted from their respective concentrations in airborne particles by applying the particle/gas partitioning equilibrium. The temperature used for partitioning is often set to 25 °C. However, indoor temperatures frequently differ from this reference value. This assumption may result in errors in the predicted equilibrium gas-phase SVOC concentrations. To improve the prediction model, the temperature dependence of the particle/gas partition coefficient must be addressed. In this paper, a theoretical relationship between the particle/gas partition coefficient and temperature was developed based on the SVOC absorptive mechanism. The SVOC particle/gas partition coefficients predicted by employing the derived theoretical relationship agree well with the experimental data retrieved from the literature (R > 0.93). The influence of temperature on the equilibrium gas-phase SVOC concentration was quantified by a dimensionless analysis of the derived relationship between the SVOC particle/gas partition coefficient and temperature. The predicted equilibrium gas-phase SVOC concentration decreased by between 31% and 53% when the temperature was lowered by 6 °C, while it increased by up to 750% when the indoor temperature increased from 15 °C to 30 °C.
ISSN: 0048-9697

hal-01313749
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01313749
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01313749/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01313749/file/Temperature%20dependence%20of%20the%20particle%20gas%20partition%20coefficient_accepted.pdf
DOI : 10.1016/j.scitotenv.2016.04.106

Éditeur(s) : HAL CCSD
Résumé : International audience
The strength of the lithospheric mantle controls the mode of lithosphere deformation: the presence or absence ofa high strength brittle mantle respectively leads to localized or distributed rifting. However, first order geophysicaldata question the existence of such a brittle mantle. Here we use 2-D finite-element large strain modelling toquantify the impact of a ductile localizing mantle – instead of brittle – in triggering continental rifting. As a novelty,the mantle rheology considers the effect of grain boundary sliding during strain-induced grain size reduction,which may promote a significant strength drop and subsequent strain localization at low mantle temperature (<700-800°C). Our results reveal that such ductile localizing mantle implies varying modes of continental rifting thatmainly depend on both the amount of weakening in the ductile mantle and the strength of the lower ductile crust. Amedium to strong lower crust implies coupling between the upper crust and ductile localizing mantle, yielding tonarrow continental rifting. In contrast, a weak lower crust implies decoupling between the upper crust and ductilelocalizing mantle, giving rise to a switch from distributed faulting at incipient strain to localized faulting at largestrain. Ductile strain localization in the lithospheric mantle is therefore sufficient to trigger continental rifting,although a critical amount of weakening is required. Such ductile localizing mantle provides a relevant geologicaland mechanical alternative to the brittle mantle. It moreover provides a wider variety of modes of upper crustalfaulting that are commonly observed in nature.
EGU General Assembly 2014
Vienne, Austria

insu-01565161
https://hal-insu.archives-ouvertes.fr/insu-01565161

Éditeur(s) : Soc Geol France
Résumé : The Lesser Antilles subduction zone has produced no recent strong thrust earthquakes, making it difficult to quantify the seismic hazard from such events. The Lesser Antilles arc has a low subduction rate and an accretionary wedge that is very wide at its southern end. To investigate the effect of the wedge on seismogenesis, numerical models of forearc thermal structure were constructed along six transects perpendicular to the arc in order to determine the thermally predicted width of the seismogenic zone. The geometry of each section is constrained by published seismic profiles and crustal models derived from gravity and seismic data and by earthquake hypocenters at depth. A major constraint on the deep part of the model is that mantle temperature beneath the volcanic arc should achieve a temperature of 1,100 degrees C to generate partial melts. Predicted surface heat flow is compared to the available heat flow observations. Thermal modeling results indicate a systematic southward increase in the width of the seismogenic zone, more than doubling in width from north to south and corresponding to a dramatic southward increase in forearc width (distance from the arc to the deformation front of the accretionary wedge). The minimum width of the seismogenic zone (distance between the intersections of the subduction interface with the 150 degrees C and 350 degrees C isotherms) increases from about 80 km, north of 16 degrees N, to 230 km, at 13 degrees N. The maximum width (between the 100 degrees C and 450 degrees C isotherms) ranges from about 150 km in the north to up to 320 km in the south. This large variation in the width of the seismogenic zone is a consequence of the increasing width of the accretionary wedge to the south, caused by the increased thickness of sediment on the subducting plate. There is good agreement between the thermally predicted seismogenic limits and the sparse distribution of recorded thrust earthquakes, which are observed only in the northern portion of the arc. Possible scenarios for mega-thrust earthquakes are discussed. Depending on the segment length (along-strike) of the rupture plane, the occurrence of an event of magnitude 8-9 cannot be excluded.
L’absence de grands séismes récents à mécanismes chevauchants dans la zone de subduction des Petites Antilles rend difficile l’évaluation de l’aléa sismique lié à de tels événements. L’arc des Petites Antilles est caractérisé par une faible vitesse de subduction et par la présence d’un prisme d’accrétion très développé à son extrémité méridionale. Afin d’évaluer les effets de la largeur de ce prisme sur la genèse des séismes, nous avons étudié six sections perpendiculaires à l’arc, du nord au sud de celui-ci, pour déterminer la largeur de la zone sismogène prédite par les modèles thermiques appliqués à chacune de ces coupes. La géométrie de ces dernières est contrainte par les profils sismiques publiés, par les modèles de structure crustale déduits des données gravitaires et sismiques, et enfin par la distribution des hypocentres des séismes. Un contrôle important permettant de tester la validité des modèles thermiques en profondeur est qu’une température minimale de 1 100oC, compatible avec la fusion partielle du manteau hydraté, doit être atteinte sous l’arc volcanique actif. Par ailleurs, le flux thermique en surface prédit par ces modèles doit être compatible avec les mesures de flux de chaleur. Les modèles thermiques retenus d’après ces critères montrent une augmentation du simple au double vers le sud de la largeur de la zone sismogène, qui correspond à un élargissement considérable de la taille du domaine avant-arc. En effet, la largeur minimale de la zone sismogène (définie comme la distance entre les intersections de l’interface des plaques avec les isothermes 150o et 350oC) augmente d’environ 80 km au nord de 16oN jusqu’à 230 km à 13oN. La largeur maximale de cette zone (définie par les intersections de l’interface avec les isothermes 100o et 450oC) augmente, quant à elle, d’environ 150 km au nord jusqu’à 320 km au sud de l’arc. Cette variation considérable est la conséquence de l’augmentation de la largeur du prisme d’accrétion, elle-même causée par l’accumulation croissante des sédiments déposés sur la plaque plongeante. Les largeurs de la zone sismogène prédites à l’aide des modèles thermiques sont en bon accord avec les rares données disponibles sur les séismes à mécanismes chevauchants dans la partie nord de l’arc. Les scénarios possibles relatifs à des méga-séismes de ce type n’excluent pas de futurs événements atteignant des magnitudes de 8 à 9.
Bulletin De La Societe Geologique De France (0037-9409) (Soc Geol France), 2013 , Vol. 184 , N. 1-2 , P. 47-59

Droits : 2013 Societe Geologique de France
http://archimer.ifremer.fr/doc/00140/25140/29432.pdf
DOI:10.2113/gssgfbull.184.1-2.47
http://archimer.ifremer.fr/doc/00140/25140/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Thermal diffusivity of synthetic quartz single-crystals and natural polycrystalline aggregates were measured using a modified Angstrom method at ambient pressure and up to 800 degrees C in order to investigate the effect of crystal preferred orientation on thermal diffusivity of quartz rich rocks. The thermal diffusivity tensor of quartz was determined by measuring the thermal diffusivity of an oriented synthetic quartz single-crystal along the [100] and [001] directions. A naturally deformed, fine-grained quartzite mylonite, was used to compare the single crystal properties with aggregate properties. Using the crystal preferred orientations (CPO) measured by the Electron Back Scattered Diffraction (EBSD) method and the measured thermal diffusivity tensor of quartz, the three-dimensional aggregate thermal diffusivity was modelled using volume averaging models. In order to test the validity of these models that are only based on the properties of the constituent minerals, the thermal diffusivity was then measured on oriented cores as a function of temperature, along three orthogonal directions, parallel to the (X-lineation, Y, Z-pole to foliation) structural frame. Both modelled and direct measurement of thermal diffusivity show an anisotropy of thermal diffusivity, heat transport being more effective parallel to Y-direction and less effective parallel to the lineation X-direction. Thermal diffusivities measured in a given direction on the natural rock are lower by less than 10% than the modelled thermal diffusivity in the same direction, showing that rock imperfections have a weak effect on heat transport. In addition, the modelled thermal diffusivity anisotropy based on the characterization of crystal orientations and thermal diffusivity tensor shows a good agreement with measurements in both alpha and beta stability field. This validation of the petrophysical simulation allows for evaluating the 3D thermal diffusivity of quartz rich rocks in different crustal conditions. The 3D thermal diffusivity of five naturally deformed quartzites displaying quartz fabrics expected in different crustal pressure and temperature ranges were simulated. The resulting thermal diffusivity anisotropies of quartzites range between 40% and 10%, depending on temperature, crystallographic fabric patterns and fabric strength. Under crustal conditions, quartzites deformed in the granulite facies display a high thermal diffusivity in the (XZ) foliation plane, whereas quartzites deformed in greenschist facies have highest thermal diffusivity in the (Z) direction normal to the foliation plane.
ISSN: 0040-1951

hal-00413568
https://hal.archives-ouvertes.fr/hal-00413568
DOI : 10.1016/j.tecto.2008.11.006

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Electrical resistivity soundings are used by geophysicists to determine the structure and composition of the Earth's crust and mantle and to explore natural resources (ore, oil, gas, water). Their interpretations in terms of composition and in-situ physical conditions depend mainly on laboratory measurements of electrical conductivity of rocks at simulated crustal conditions of temperature, pressure, saturation and pore pressures. These measurements present a numbers of limitations, in particular, in the case where conductive pore fluids are present, as in the case of deep reservoir conditions, where temperature exceeds 250 A degrees C. Here, we present a new cell capable of measuring electrical conductivity of large saturated samples at confining pressure up to 200 MPa, pore pressure up to 50 MPa, and temperature up to 500 A degrees C. The measurement cell has been developed in a commercial, internally heated, gas pressure apparatus (Paterson press). It is based on the concept of "guard ring" electrode, which is adapted to samples that are jacketed by a very conductive, metallic material. Numerical modeling of the current flow in the electrical cell allowed defining the optimal cell geometry. Calibration tests have been performed on Fontainebleau sandstones saturated with electrolytes of different conductivities, up to 350 A degrees C. The resulting electrical formation factor and temperature dependence of electrical conductivity are in very good agreement with previous studies. This new cell will improve the exploration and exploitation of deep fluid reservoirs, as in unconventional, high enthalpy geothermal fields. In particular, the investigations address possible effects of fluid-rock interactions on electrical resistivity of a reservoir host rock.
ISSN: 0169-3913

hal-00681997
https://hal.archives-ouvertes.fr/hal-00681997
DOI : 10.1007/s11242-011-9846-2

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The occurrence of cyanobacterial blooms is drastically increasing in temperate countries and drinking water resources are threatened. As a result, cyanotoxins should be considered in water treatment to protect human health. This study presents a state of the art on cyanotoxins in water and their behaviour towards chlorination, a common drinking water disinfection process. Chlorination efficiency on cyanotoxins alteration depends on pH, chlorine dose and oxidant nature. Microcystins and cylindrospermopsin are efficiently transformed by chlorine, with respectively 6 and 2 by-products identified. In addition, chlorination of microcystins and cylindrospermopsin is associated with a loss of acute toxicity. Even though they have been less investigated, saxitoxins and nodularins are also altered by chlorine. For these toxins, no by-products have been identified, but the chlorinated mixture does not show acute toxicity. On the contrary, the fact that anatoxin-a has a very slow reaction kinetics suggests that this toxin resists chlorination.
ISSN: 0041-0101

hal-01122372
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01122372
DOI : 10.1016/j.toxicon.2009.10.028
PUBMED : 19874838

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We present an integrated study of geochemistry, petrofabrics and seismic properties of strongly sheared eclogites from the Chinese Continental Scientific Drilling (CCSD) project in the Sulu ultrahigh-pressure (UHP) metamorphic terrane, eastern China. First, geochemical data characterize diverse protoliths of the studied eclogites. The positive Eu- and Sr-anomalies, negative Nb anomaly and flat portion of heavy rare earth elements in coarse-grained rutile eclogites (samples B270 and B295) suggest a cumulate origin in the continental crust, whereas the negative Nb anomaly and enrichment of light rare earth elements in retrograde eclogites (samples B504, B15 and B19) imply an origin of continental basalts or island arc basalts. Second, P-wave velocities (V-p) of three typical eclogite samples were measured under confining pressures up to 500 MPa and temperatures to 700 degrees C. At 500 MPa and room temperature, the mean V-p reaches 8.50-8.53 km/s in samples B270 and B295 but drops to 7.86 km/s in sample B504, and the P-wave anisotropy changes from 1.7-2.7% to 5.5%, respectively. The pressure and temperature derivatives of V-p are larger in the retrograde eclogite than in fresh ones. Third, the electron backscatter diffraction (EBSD) measurements of the eclogites reveal random crystal preferred orientation (CPO) of garnet and pronounced CPO of omphacite, which is characterized by a strong concentration of [001]-axes sub-parallel to the lineation and of (010)-poles perpendicular to the foliation. The asymmetric CPO of omphacite in sample B270 recorded a top-to-the-south shear event during subduction of the Yangtze plate. The calculated fastest V-p is generally sub-parallel to the lineation, but a different deformation environment during exhumation could form second-order variations in omphacite CPO and affect the V-p distribution in eclogites (e.g., the fastest V-p is at similar to 35 degrees from the foliation in sample 13295). Comparison between measured and calculated seismic properties indicates that the CPO of omphacite controls the seismic anisotropy of eclogites at high pressure, and compositional layering and retrograde minerals will increase the anisotropy. Calculated P-wave velocities agree well with velocities measured at 500 MPa and room temperature for fresh eclogites, but much higher than those of retrograde eclogite. As a case study, the laboratory-derived V-p-P and V-p-T relationships were used to estimate P-wave velocities of eclogites and peridotites beneath the Western Superior Province, Canada. The results indicate that besides the fabric-induced anisotropy, the direction dependence of pressure and temperature derivatives of V-p can significantly increase seismic anisotropy of eclogites with depth, which results in eclogites being an important candidate for the seismic anisotropy in the upper mantle. Due to their very high density and velocity, garnet-rich eclogites within peridotite could be detected in seismic reflections in subduction zones.
ISSN: 0040-1951

hal-00463512
https://hal.archives-ouvertes.fr/hal-00463512
DOI : 10.1016/j.tecto.2008.09.027

Éditeur(s) : HAL CCSD European Geosciences Union
Résumé : The properties of the subduction interplate domain are likely to affect not only the seismogenic potential of the subduction area but also the overall subduction process, as it influences its viability. Numerical simulations are performed to model the long-term equilibrium state of the subduction interplate when the diving lithosphere interacts with both the overriding plate and the surrounding convective mantle. The thermomechanical model combines a non-Newtonian viscous rheology and a pseudo-brittle rheology. Rock strength here depends on depth, temperature and stress, for both oceanic crust and mantle rocks. I study the evolution through time of, on one hand, the brittle-ductile transition (BDT) depth, zBDT, and, on the other hand, of the kinematic decoupling depth, zdec, simulated along the subduction interplate. The results show that both a high friction and a low ductile strength at the asthenospheric wedge tip shallow zBDT. The influence of the weak material activation energy is of second order but not negligible. zBDT becomes dependent on the ductile strength increase with depth (activation volume) if the BDT occurs at the interplate decoupling depth. Regarding the interplate decoupling depth, it is shallowed (1) significantly if mantle viscosity at asthenospheric wedge tip is low, (2) if the difference in mantle and interplate activation energy is weak, and (3) if the activation volume is increased. Very low friction coefficients and/or low asthenospheric viscosities promote zBDT = zdec. I then present how the subducting lithosphere age affects the brittle-ductile transition depth and the kinematic decoupling depth in this model. Simulations show that a rheological model in which the respective activation energies of mantle and interplate material are too close hinders the mechanical decoupling at the down-dip extent of the interplate, and eventually jams the subduction process during incipient subduction of a young (20-Myr-old) and soft lithosphere under a thick upper plate. Finally, both the BDT depth and the decoupling depth are a function of the subducting plate age, but are not influenced in the same fashion: cool and old subducting plates deepen the BDT but shallow the interplate decoupling depth. Even if BDT and kinematic decoupling are intrinsically related to different mechanisms of deformation, this work shows that they are able to interact closely. Comparison between modelling results and observations suggests a minimum friction coefficient of 0.045 for the interplate plane, even 0.069 in some cases, to model realistic BDT depths. The modelled zdec is a bit deeper than suggested by geophysical observations. Eventually, the better way to improve the adjustment to observations may rely on a moderate to strong asthenosphere viscosity reduction in the metasomatised mantle wedge.
ISSN: 1869-9510

hal-00795559
https://hal.archives-ouvertes.fr/hal-00795559
DOI : 10.5194/se-3-467-2012, 2012

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
Progress in seismic methodology and ambitious large-scale seismic projects are enabling high-resolution imaging of the continental crust. The ability to constrain interpretations of crustal seismic data is based on laboratory measurements on rock samples and calculations of seismic properties. Seismic velocity calculations and their directional dependence are based on the rock microfabric, which consists of mineral aggregate properties including crystallographic preferred orientation (CPO), grain shape and distribution, grain boundary distribution, and misorientation within grains. Single-mineral elastic constants and density are crucial for predicting seismic velocities, preferably at conditions that span the crust. However, high-temperature and high-pressure elastic constant data are not as common as those determined at standard temperature and pressure (STP; atmospheric conditions). Continental crust has a very diverse mineral composition; however, a select number of minerals appear to dominate seismic properties because of their high-volume fraction contribution. Calculations of microfabric-based seismic properties and anisotropy are performed with averaging methods that in their simplest form takes into account the CPO and modal mineral composition, and corresponding single crystal elastic constants. More complex methods can take into account other microstructural characteristics, including the grain shape and distribution of mineral grains and cracks and pores. Dynamic or active wave propagation schemes have recently been developed, which offer a complementary method to existing static averaging methods generally based on the use of the Christoffel equation. A challenge for the geophysics and rock physics communities is the separation of intrinsic factors affecting seismic anisotropy, due to properties of crystals within a rock and apparent sources due to extrinsic factors like cracks, fractures, and alteration. This is of particular importance when trying to deduce crustal composition and the state of deformation from seismic parameters.
ISSN: 8755-1209

Droits : info:eu-repo/semantics/OpenAccess
hal-01685568
https://hal.archives-ouvertes.fr/hal-01685568
https://hal.archives-ouvertes.fr/hal-01685568/document
https://hal.archives-ouvertes.fr/hal-01685568/file/Almqvist_et_al-2017-Reviewssur Geophysics.pdf
DOI : 10.1002/2016RG000552

Éditeur(s) : HAL CCSD
Résumé : International audience
Semi-volatile organic compounds (SVOCs) partition indoors between the gas phase, airborne particles, settled dust, and other surfaces. Unknown concentrations of SVOCs in the gas phase (Cg) can be predicted from their measured concentrations in airborne particles. In previous studies, the prediction of Cg depended largely on choosing a specific equation for the calculation of the particle/gas partition coefficient. Moreover, the prediction of Cg is frequently performed at a reference temperature rather than the real indoor temperature. In this paper, a probabilistic approach based on Monte Carlo simulation was developed to predict the distribution of SVOCs' Cg from their concentrations in airborne particles at the target indoor temperature. Moreover, the distribution of the particle/gas partition coefficient of each SVOC at the target temperature was used. The approach was validated using two measured datasets in the literature: the predicted Cg from concentrations measured in airborne particles and the measured Cg were generally of the same order of magnitude. The distributions of the Cg of 66 SVOCs in the French housing stock were then predicted. The SVOCs with the highest median Cg, ranging from 1 ng/m3 to > 100 ng/m3, included 8 phthalates (DEP, DiBP, DBP, DEHP, BBP, DMP, DiNP, and DMEP), 4 polycyclic aromatic hydrocarbons (fluorene, phenanthrene, fluoranthene, and anthracene), 2 alkylphenols (4-tert-butylphenol and 4-tert-octylphenol), 2 synthetic musks (galaxolide and tonalide), tributyl phosphate, and heptachlor. The nationwide, representative, predicted Cg values of SVOCs are frequently of the same order of magnitude in Europe and North America, whereas these Cg values in Chinese and Indian dwellings and the Cg of polybrominated diphenyl ethers in U.S. dwellings are generally higher. © 2016 Elsevier B.V.
Science of the Total Environment

hal-01467547
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01467547
DOI : 10.1016/j.scitotenv.2016.10.074
PUBMED : 27788447

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Deformation of the continental lithosphere is traditionally modeled assuming that heat production in the subcontinental lithospheric mantle is negligible. Although this may be appropriate for highly depleted Archean lithosphere, studies of mantle xenoliths and lithospheric-derived mafic rocks suggest that heat productions of up to 0.4 ;μW/m3 may be attained in the mantle of Phanerozoic and Neoproterozoic regions due to modal metasomatism. To investigate the effect of a local enrichment in heat-producing elements within the lithospheric mantle on the continental deformation, we performed a series of 2D thermo-mechanical models simulating the deformation of a lithospheric plate 1000 km long, which contains in its central part a 200 km wide and 20 km-thick mantle layer with a heat production of 0.05;–0.25 ;μW/m3 between 40 and 80 km depth, leading to a local enhancement of the surface heat flow by 1;–5 mW/m2. Compression models show that a 20 km-thick layer with a heat production as low as 0.05 ;μW/m3 within the shallow lithospheric mantle leads to strain localization in both the enriched mantle and the overlying crust. Strain localization depends exponentially on the temperature increase in the lithosphere section, which is controlled by the volume of metasomatized mantle and the intensity of the metasomatic enrichment in heat-producing elements. A heat production of 0.25 μW/m3 between 60 and 80 km depth results, for instance, in strains within and above the metasomatized mantle 5 times higher than in the surrounding lithosphere. Strain localization also depends on the location of the heat-producing domain and on the plate rheological structure; deeper heat-producing domains and weaker plates leading to stronger localization. These results provide an explanation for strain localization in intraplate environments, leading to the formation of orogenic belts situated hundreds to thousands of kilometers away from known plate boundaries, as observed in the Neoproterozoic belts of Gondwana and in the present-day deformation of the Asian plate.
ISSN: 0012-821X

hal-00411386
https://hal.archives-ouvertes.fr/hal-00411386
DOI : 10.1016/j.epsl.2008.07.040

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Analogue and numerical models have shown that the strength of the lithospheric mantle controls the mode of lithosphere deformation. In extension, the presence or absence of a high strength brittle mantle respectively leads to localized or distributed rifting. However, first order geophysical data question the existence of such a brittle mantle. Here we use 2-D finite-element large strain modelling to quantify the impact of a ductile localizing mantle - instead of brittle - in triggering continental rifting. As a novelty, the mantle rheology considers the effect of grain boundary sliding during strain-induced grain size reduction, which may promote a significant strength drop and subsequent strain localization at low mantle temperature (< 700-800 °C). Our results reveal that such ductile localizing mantle implies varying modes of continental rifting that mainly depend on both the amount of weakening in the ductile mantle and the strength of the lower ductile crust. A medium to strong lower crust implies coupling between the upper crust and ductile localizing mantle, yielding to narrow continental rifting. In contrast, a weak lower crust implies decoupling between the upper crust and ductile localizing mantle, giving rise to a switch from distributed faulting at incipient strain to localized faulting at large strain. Ductile strain localization in the lithospheric mantle is therefore sufficient to trigger continental rifting, although a critical amount of weakening is required. Such ductile localizing mantle provides a relevant geological and mechanical alternative to the brittle mantle. It moreover provides a wider variety of modes of upper crustal faulting that are commonly observed in nature.
ISSN: 0040-1951

Droits : info:eu-repo/semantics/OpenAccess
insu-00924254
https://hal-insu.archives-ouvertes.fr/insu-00924254
https://hal-insu.archives-ouvertes.fr/insu-00924254/document
https://hal-insu.archives-ouvertes.fr/insu-00924254/file/Gueydan_precigout_2014_Tectonophysics.pdf
DOI : 10.1016/j.tecto.2013.11.029

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Upon subduction, the oceanic crust transforms to blueschists and eclogites, with seismic properties that gradually become similar to those of the surrounding mantle. In order to evaluate the anisotropy of blueschists and glaucophane-bearing eclogites, the elastic constants of glaucophane single-crystal plates from the Sesia-Lanzo Zone (Aosta Valley, Western Alps) were measured using Brillouin spectroscopy at ambient conditions. The mean P- and S-wave velocities are 7.8 and 4.6 km s−1 respectively, and the anisotropy is high (38.1% (AVP) and 27.3% (AVS)). Glaucophane develops strong LPO, characterized by the [001]-axes concentrated sub-parallel to the lineation, and the {110} poles concentrated sub-perpendicular to the foliation in both blueschist and eclogite rocks. The measured LPO is in good agreement with viscoplastic selfconsistent numerical models. Seismic properties of glaucophane-bearing blueschist and eclogite are calculated by combining measured LPO and the single-crystal elastic moduli of glaucophane with the other main mineral constituents of the rock: mostly epidote for blueschist, and omphacite and garnet for eclogite. Blueschists present stronger anisotropies (AVP=16.1% and AVS=10.3%) than eclogites (AVP=2.9% and AVS=1.7%). The shear-wave splitting and resulting delay times for a 7-km thick layer of eclogite or blueschist are low for the eclogite (b0.03 s), but signi!cant for blueschist (0.16 s). Application to the subducted oceanic crust yields a decrease of velocity contrast with the surrounding mantle and of anisotropy at depth depending on the temperature of the slab. The details of the velocity variations in subducted oceanic crust are dif!cult to reconcile with the blueschist-eclogite transition as probed by exhumed metamorphic rocks and may require additional phases such as lawsonite or chemical variations such as oxidation state.
ISSN: 0040-1951

hal-00564518
https://hal.archives-ouvertes.fr/hal-00564518
DOI : 10.1016/j.tecto.2010.09.011

Éditeur(s) : HAL CCSD
Résumé : International audience
In this work, we have led an analysis of the error of different global solar radiation prediction models according to the global solar radiation variability. Different predictions models where performed such as machine learning techniques (Neural Networks, Gaussian processes and support vector machines) in order to forecast the Global Horizontal solar Irradiance (GHI). We also include in this study a simple linear autoregressive (AR) model as well as two naive models based on persistence of the GHI and persistence of the clear sky index (denoted herein scaled persistence model). The models are calibrated and tested with data from three 3 French islands: Corsica (42.15°N ; 9.08°E), Guadeloupe (16.25°N ; 61.58°W) and Reunion (21.15°S ; 55.5°E). Guadeloupe and Reunion are located in a subtropical climatic zone whereas Corsica is in a tempered climatic zone. Hence the global solar radiation variation differs significantly. The output error of the different models was quantified by the nRSME. In order to quantify the influence of the global solar radiation variability on the forecasting models error we performed a classification of typical days according to different typical days. Each class of typical day is defined by a variation of global solar radiation rate. For each class and for each location, the selected forecasting models where performed and the error was quantified. With this analysis a global solar radiation forecasting models can be selected according to the location, the global solar radiation fluctuations and hence the meteorological conditions. INTRODUCTION Large and frequent variations of solar radiation can be observed in tropical climates with amplitudes reaching 800 W/m² and occurring within a short time interval, from few seconds to few minutes, according to the geographical location. Such fluctuations can be due for example to the dynamic of clouds which can be very complex and depend on cloud type, size, speed and spatial distribution and, more generally, due to some specific local meteorological conditions. Thus, the solar energy forecasting, a process used to predict the amount of solar energy available in the current and near terms, might be a difficult task. Some of the best predictors found in literature are Autoregressive and moving average (ARMA) [5,7,8], Bayesian inferences [9,10], Markov chains [11], k-Nearest-Neighbors predictors [12] or artificial intelligence techniques as the Artificial Neural Network (ANN) [9-11]. Although these methodologies are potentially good in many areas, we observed in our previous studies on global radiation prediction [9,13,14] that the simple model based on the persistence of the clear sky index gives often very good results with acceptable errors [15] for short term forecasting time horizon (<= 1 hour). The goal of this paper is to determinate the influence of solar radiation variability regarding different classes of days on the expected error provided by different forecasting methods that the modeller can possibly implement. The paper is organized as follow: Section 2 describes the data we have used. Section 3 exposes the classification methodology and the results obtained for the three studied locations. In the two following sections, the forecasting methods are exposed and then 3 the errors on the forecasting results for each location and for each class are exposed.
The Third Southern African Solar Energy Conference (SASEC2015)
Kruger National Park, South Africa

Droits : info:eu-repo/semantics/OpenAccess
hal-01099487
https://hal.archives-ouvertes.fr/hal-01099487
https://hal.archives-ouvertes.fr/hal-01099487/document
https://hal.archives-ouvertes.fr/hal-01099487/file/article%20SASEC.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study presents microstructural evidence for deformation-controlled melt organization and for changes in olivine deformation associated with the presence of melt in an 80 m vertical section of the crust-mantle transition zone in the Oman ophiolite. This zone represents an 'end member' case for analyzing feedbacks between deformation and melt distribution in the upper mantle, since it experienced strong shear strains in presence of large melt fractions. It is characterized by a subhorizontal compositional layering at the mm to meter scale, from weakly impregnated dunites to olivine-rich gabbros, which parallels a pervasive foliation containing a strong stretching lineation. The parallelism between the compositional layering and the foliation, the diffuse limits of the layers, the alignment of elongated plagioclase-rich aggregates devoid of internal deformation structures with the elongation of olivine crystals in the dunitic layers, and the sharp compositional changes across some, but not all layer limits suggest deformation plays an essential role on the development of the layering. The variation on a mm-scale of the olivine crystal preferred orientation (CPO) symmetry as a function of the modal content: from axial-[100] symmetry in layers with <70% modal olivine to axial-[010] in more gabbroic levels (<40% olivine), which is repeated over the entire section, implies deformation in presence of variable melt fractions. Axial-[100] olivine CPO in olivine-rich layers is consistent with deformation by dislocation creep under high temperature, low pressure, dry conditions. Axial-[010] olivine CPO patterns imply additional sliding along preferentially wetted (010) grain boundaries, increase in the activity of [001] glide, or transpression localized in the melt-rich layers. Since the change in CPO symmetry is not accompanied by dispersion, instantaneous melt fractions must have remained <30-40% in all layers. The continuous variation in olivine CPO symmetry with decreasing olivine content implies therefore that the former depends on the cumulated strain in presence of melt rather than on the instantaneous melt fraction.
ISSN: 0012-821X

hal-00795508
https://hal.archives-ouvertes.fr/hal-00795508
DOI : 10.1016/j.epsl.2012.10.003