Éditeur(s) : HAL CCSD Springer/Terra Scientific Publishing Company
Résumé : International audience
We report oil the discovery of magnetite nanoparticles ranging in size from 2 to 14 full in the mineralized zones of the Pena Colorada iron-ore deposit, southern Mexico. Micrometric scale magnetite was magnetically reduced and divided into distinct size ranges: 85-56 mu m, 56-30 mu m, 30-22 mu m, 22-15 mu m, 15-10 mu m, 10-7 mu m and 7-2 mu m. Nanometric-scale magnetite in the size range 2-14 nm was identified. The magnetite was characterized by X-ray diffraction, transmitted and reflected light microscope, high-resolution transmission electron microscopy (TEM), high angle annular dark field, Mossbauer spectroscopy and its magnetic properties. Crystallographic identification of nanostructures Was performed using high-resolution TEM. Characteristic changes were observed when the particles make the size transition from micro- to nanometric sizes, as follows: (1) frequency-dependent magnetic Susceptibility percentage (chi FD%) measurements Show high Values (13%) for the 2-14 nm fractions attributed to dominant fractions of superparamagnetic particles; (2) variations of chi FD% < 4.5% in fractions of 56-0.2 mu m occur in association with the presence of microparticles formed by magnetite aggregates of nanoparticles (< 15 nm) embedded in berthierine; (3) Mossbauer spectroscopy results identified a superparamagnetic fraction; (4) nanometric and 0.2-3 mu m grain size magnetite particles require a magnetic field up to 152 mT to reach saturation during the isothermal remanent magnetization experiment; (5) coercivity and remanent magnetization of the magnetite increase when the particle size decreases, probably due to parallel Coupling effects; (6) two-magnetic Susceptibility versus temperature experiments of the same 2-14 nm sample show that the reversibility during the second heating is due to the formation of new magnetite nanoparticles and growth of those already present. during the first heating process.
ISSN: 1343-8832

hal-00413053
https://hal.archives-ouvertes.fr/hal-00413053

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Laboratory models have been conducted to improve our understanding of the role that the resistance of the slab to bending and its coupling to the ambient mantle play in subduction dynamics over geological time scales. Our models are set up with a viscous plate of silicone (lithosphere) subducting under negative buoyancy in a viscous layer of glucose syrup (mantle). For our study, the lithosphere/upper mantle viscosity contrast has been systematically varied, from similar to 10 to similar to 10(5) in order to explore the parameter space between weak and strong slab dynamics. We found that subduction is characterized by a retreating mode for viscosity ratios > 10(4), by the coexistence of a retreating mode and an advancing mode for viscosity ratios between similar to 10(4) and similar to 10(2), and quasi-stationary, Rayleigh-Taylor like behaviour for ratios < 10(2). By combining our experimental results and kinematic data from current subduction zones in four reference frames which differ in the amount of net rotation, we infer that a lithosphere/upper mantle viscosity contrast of 150-500 is necessary to obtain realistic trench/subducting plate velocity ratios as well as the variability of subduction styles observed in nature.
ISSN: 0012-821X

hal-00412008
https://hal.archives-ouvertes.fr/hal-00412008
DOI : 10.1016/j.epsl.2008.04.006

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
IODP Site U1309 was drilled at Atlantis Massif, an oceanic core complex, at 30 degrees N on the Mid-Atlantic Ridge (MAR). We present the results of a bulk rock geochemical study (major and trace elements) carried out on 228 samples representative of the different lithologies sampled at this location. Over 96% of Hole U1309D is made up of gabbroic rocks. Diabases and basalts cross-cut the upper part of the section; they have depleted MORB compositions similar to basalts sampled at MAR 30 degrees N. Relics of mantle were recovered at shallow depth. Mantle peridotites show petrographic and geochemical evidence of extensive melt-rock interactions. Gabbroic rocks comprise: olivine-rich troctolites (>70% modal olivine) and troctolites having high Mg# (82-89), high Ni (up to 2300 ppm) and depleted trace element compositions (Yb 0.06-0.8 ppm); olivine gabbros and gabbros (including gabbronorites) with Mg# of 60-86 and low trace element contents (Yb 0.125-2.5 ppm); and oxide gabbros and leucocratic dykes with low Mg# (<50), low Ni (similar to 65 ppm) and high trace element contents (Yb up to 26 ppm). Troctolites and gabbros are amongst the most primitive and depleted oceanic gabbroic rocks. The main geochemical characteristics of Site U1309 gabbroic rocks are consistent with a formation as a cumulate sequence after a common parental MORB melt, although (lack of systematic) downhole variations indicate that the gabbroic series were built by multiple magma injections. In detail, textural and geochemical variations in olivine-rich troctolites and gabbronorites suggest chemical interaction (assimilation?) between the parental melt and the intruded lithosphere. Site U1309 gabbroic rocks do not represent the complementary magmatic product of 30 degrees N volcanics, although they sample the same mantle source. The bulk trace element composition of Site U1309 gabbroic rocks is similar to primitive MORB melt compositions; this implies that there was no large scale removal of melts from this gabbro section. The occurrence of such a large magmatic sequence implies that a high magmatic activity is associated with the formation of Atlantis Massif. Our results suggest that almost all melts feeding this magmatic system stays trapped into the intruded lithosphere.
ISSN: 0012-821X

hal-00413562
https://hal.archives-ouvertes.fr/hal-00413562
DOI : 10.1016/j.epsl.2008.12.034

Résumé : The development of large pelagic fishing in the French Antilles is an integral part of a difficult economic situation of the fishing sector in Martinique where this development can seem like a solution to increasingly acute problems. Indeed, for the regulatory authorities as well as for many participants in the sector, it is imperative to find solutions to the lack of profitability of a part of the fishing ships and to confront the regular increase of the share of imports in supplying Martinique with seafood. This question about the possibilities of developing large pelagic fishing is not new since it is already mentioned in the Notice from the Economic and Social Committee of the Martinique Region in 1982. We will not show in this document a detailed analysis of small-scale fishing in Martinique. Since the latter has been abundantly studied by the team of the Caribbean Oceanological and Halieutic Research Centre (PROHC) between 1985 and 1987, we will take up these principal conclusions (with which we are in full agreement) and bring them up to date based on data collected during our mission from 11 to 24 April 1988. The first section devoted to the supply structure (local fishing and imports) will attempt to define under what conditions large pelagic fishing can be developed. The second section will address marketing and demand. Indeed, at the same time as the problems of developing large pelagic fishing, we are faced with the question of the organisation of seafood markets. This organisation is a fundamental issue for the small-scale fishing sector in the French Antilles since its long-term future depends upon it by setting different prices and amounts exchanged according to the structure it is given. We will come to a conclusion on the economic conditions of developing a large pelagic fishery and organising a market, this based on research and study work already done. We will indicate which investigations must be conducted to complete the set of factors for decision support in this area. To perform this assessment, we reconstructed from the long series 1970-1986 (sometimes with significant inadequacies): these are presented as an appendix.
(OCR non controlé) Le développement de la pêche de grands pélagiques dans les Antilles Françaises s'inscrit dans un contexte économique difficile du secteur de la pêche en Martinique où ce développement peut apparaître comme une solution à des problèmes de plus en plus aigus. En effet, pour les autorités de tutelle ainsi que pour de nombreux intervenants dans le secteur, il est impératif de trouver des solutions au manque de rentabilité d'une partie des unités de pêche et de faire face à l'augmentation régulière de la part des importations dans l'approvisionnement de la Martinique en produits de la mer. Cette question sur les possibilités d'un développement de la pêche de grands pélagiques n'est pas nouvelle puisqu'elle est déjà évoquée dans l'Avis du Comité Economique et Social de la Région Martinique en 1982. On ne présentera pas dans ce document une analyse détaillée de la pêche artisanale en Martinique. Celle-ci ayant été abondamment étudiée par l'équipe du Pôle de Recherche Océanologique et Halieutique Caraïbe (PROHC) entre 1985 et 1987, on reprendra ces principales conclusions (avec lesquelles nous sommes en plein accord) en les actualisant à partir des informations recueillies lors de notre mission du 11 au 24 avril 1988. La première section consacrée à la structure d'offre (pêche locale et importations) s'attachera à définir dans quelles conditions peut être développée une pêche de grands pélagiques. Là seconde section traitera de la commercialisation et de la demande. En effet parallèlement aux problèmes de développement d'une pêche de grands pélagiques, se pose la question de l'organisation du marché des produits de la mer. Cette organisation est un enjeu primordial pour le secteur de la pêche artisanale dans les Antilles Françaises puisqu'elle conditionne son avenir à long terme en définissant des prix et des quantités échangées différents suivant la structure qu'on lui donne. On conclura sur les conditions économiques du développement d'une pêche de grands pélagiques et de l'organisation d'un marché, ceci à partir des travaux de recherche et des études déjà réalisés. On indiquera quelles investigations doivent être menées pour compléter l'ensemble des éléments d'aide à la décision dans ce domaine. Pour effectuer cette évaluation, on a reconstituer des séries longues 1970-1986 (parfois avec des carences importantes) : celles-ci sont présentées en annexe.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/1988/rapport-2519.pdf
http://archimer.ifremer.fr/doc/00000/2519/

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
We herein focus on understanding what controls the detachment and migration of oceanic crustal slices along subduction zones. We provide evidence for the coeval Middle to Late Cretaceous exhumation of oceanic blueschists in the same Neotethyan subduction zone, across more than 3000 km, from depths around 30-40 km, over a short time interval (similar to 25 Ma) compared to the duration of subduction (>100 Ma). We stress the importance of such a geodynamic process and suggest that this exhumation was promoted by a regional-scale change in the long-term interplate mechanical coupling. On the basis of geological and geophysical evidence, we propose that the upward migration of oceanic fragments in subduction zones is normally inhibited and only occurs discontinuously, as the subduction channel opens up in response to a major change in plate geodynamics, slab geometry and dynamics, mantle wedge and slab hydration, or a combination of these.
ISSN: 1525-2027

hal-00420898
https://hal.archives-ouvertes.fr/hal-00420898
DOI : 10.1029/2009GC002428

Éditeur(s) : HAL CCSD Elsevier
Résumé : Understanding the pattern in spatial distribution of soil microbial processes is critical to understand the environmental factors that regulate them as well as to scale up these processes to ecosystem. Soil samples from a I ha tropical rainforest plot (Paracou, French Guiana) were analyzed according a nested sampling approach using different separation distances ranging from 0.4 to 40 m. The variability of substrate induced respiration (SIR) and of denitrification enzyme activity (DEA) was characterized in relation to various soil properties (total C and N contents, NIRS related index of soil organic matter quality, SOMQ and index of tree influence potential, IP). The variability of SIR and DEA was higher than that of environmental properties. The patterns of accumulated variance as a function of distance varied among the soil properties. The variability of SIR and DEA mainly occurred at small (1 m) scale (and at the 10-40 m-scales for SIR), probably reflecting the quality of litter input that results of the influence of local assemblage of different tree species, though changes in the soil N and C contents. Indeed, total soil C and N contents explained the microbial properties at every scale. Coefficients of codispersion showed that neither SOMQ nor IP did correlate with SIR and DEA, and confirmed that total C and N contents explained microbial properties in a scale dependent and complex manner. Such spatial dependency underlines the importance of soil heterogeneity in this tropical forest with implications for sampling strategies when studying the microbial processes and their response to disturbances. (C) 2012 Elsevier B.V. All rights reserved.
ISSN: 0016-7061

hal-01032409
https://hal.archives-ouvertes.fr/hal-01032409
DOI : 10.1016/j.geoderma.2012.12.009

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
In the Oman ophiolite crustal section, a contact zone between the gabbro unit and the volcanics and diabase sheeted dikes, called the root zone of the sheeted dike complex, has been recently mapped at a fine scale in a selected area. The Oman ophiolite is derived from a fast spreading ridge which had a melt lens located between the main gabbro unit and the root zone of the sheeted dike complex. With a few exceptions accounted for, this horizon has a fairly constant thickness, similar to 100 m, and a crude internal pseudo-stratigraphy. At the base of the root zone are isotropic ophitic gabbros interpreted as a thermal boundary layer. This layer is transitional between the magmatic system of the melt lens, convecting at 1200 degrees C, and a high-temperature (< 1100 degrees C) hydrothermal system, convecting within the root zone. Above this level, the isotropic gabbros have been, locally, largely molten due to an influx of seawater, at similar to 1100 degrees C, thus generating varitextured ophitic and pegmatitic gabbros. These latter gabbros constitute the upper part of the root zone and are associated with trondjhemitic intrusions as screens in the lower sheeted dikes. Diorites and trondjhemites were also generated by hydrous melting, at temperatures below 1000 degrees C. The whole root zone is a domain of very sharp average thermal gradient (similar to 7 degrees C/m). At the top of the root zone, a new thermal boundary layer, with diabase dikes hydrated in amphibolite facies conditions, separates the preceding high- temperature convective system from the well-known greenschist facies (< 450 degrees C) hydrothermal system operating throughout the sheeted dike complex, up to the seafloor. The isotropic gabbros near the base of the root zone are intruded by protodikes with distinctive microgranular margins and an ophitic center. Protodike swarms are exceptional because, intruding a medium at similar to 1100 degrees C, they are largely destroyed by dike-in-dike intrusions and by hydrous melting. However, they demonstrate that this zone was generated by melt conduits issued from the underlying melt lens. Each dike of the sheeted dike complex is thus fed by one protodike. As this zone has been recently drilled by IODP in the eastern Pacific Ocean, a brief comparison is proposed.
ISSN: 1525-2027

hal-00411331
https://hal.archives-ouvertes.fr/hal-00411331
DOI : 10.1029/2007GC001918

Éditeur(s) : Université d'Angers
Résumé : In oyster farming areas, organic matter fluxes toward sediment is increased. Pacific oysters (Crassostrea gigas) reject organic-rich faeces and pseudofaeces as a result of filtration process. Organic matter can be consumed by benthic fauna, but in excess it can entails the reduction of benthic faunal species richness, abundance and biomass. Organic matter degradation also induces hypoxic (or anoxic) conditions in the sediment, and production of ammonia and sulfides in toxic concentrations. The main objective of this study is to assess the effects of oyster farming on benthic intertidal ecosystems in the Pertuis Charentais. Benthic macrofauna, living (stained) foraminifera, and physicochemical characteristics of the water column and sediment were used as indicators to evaluate these effects. A multidisciplinary approach was conducted across the Pertuis Charentais at 3 different spatial scales: an oyster trestle (micro-scale), an oyster culture area (meso-scale) and various sites across the Pertuis Charentais (macro-scale). The study was also realised at 4 different temporal scales: some months for the spatial micro-scale, every two weeks for 2 years at meso-scale and once per season during one year at macro-scale. In this study, I found that oyster farming enriches sediment in fine particles, organic matter (up to 12 %), particulate organic carbon (15-20 µg mg 1) and leads to high microphytobenthic biomass. Moreover, the association of seasonnal warming (during spring and summer), remineralisation of accumulated organic matter and short-term hypoxic conditions leads to sulfides and ammonium production. Consequently, the benthic biodiversity decreases and the population dynamic is disturbed. The population dynamic disturbance is characterised by fast abundance rises followed by high mortality rates. In these conditions, tolerant benthic macrofaunal (Cirratulidae, Spionidae and Capitellidae) and foraminiferal (Ammonia tepida and Cribroelphidium gunteri) species are promoted. AMBI index confirms "medium" ecological quality of oyster farming areas. On the contrary, across the control sites, sensible species are maintained (Amphipods, Rosalina cf. vilardeboana). Comparison of oyster farming techniques shows that on-bottom culture is less disturbing for benthic ecosystem than off-bottom culture. Axial tomodensitometry, an innovative method, was used to describe in 3D the sedimentary column organisation. I show that oyster farming modifies the sedimentary column functioning. Indeed, the macrofaunal diversity decrease leads to the modification of the functional diversity of assemblages. Thus, the vertical distribution of living foraminifera is limited in oyster farming areas, because their distribution is tightly related to macrofaunal bioturbating modes.
Dans les zones ostréicoles, les flux de matière organique sont importants, l'huître Crasssotrea gigas rejetant sous forme de pseudo-fécès et de fécès de grandes quantités de matière organique. De ce fait, bien que cette matière organique puisse être consommée par la faune benthique, sa surabondance peut provoquer une réduction de la richesse spécifique, de l'abondance et de la biomasse et provoquer sur le plan des processus biogéochimiques des déplétions en oxygène et l'apparition de substances comme l'ammonium et les sulfures dont les concentrations peuvent devenir toxiques. L'objectif principal de cette étude était donc de déterminer l'impact de l'ostréiculture, grâce à plusieurs indicateurs, sur le compartiment benthique d'un écosystème littoral comme les pertuis charentais. Pour évaluer ces effets, la macrofaune benthique et les foraminifères vivants benthiques ont été utilisés en association avec des mesures des paramètres physico-chimiques de la colonne d'eau et du sédiment. Une approche pluridisciplinaire a ainsi été menée dans les pertuis charentais à trois échelles spatiales différentes : à l'échelle d'une table ostréicole (micro-échelle), à l'échelle d'un site ostréicole (méso-échelle) et à l'échelle des pertuis charentais (macro-échelle). Dans les trois cas, un suivi dans le temps a été associé à une étude de distribution spatiale, quelques mois à micro-échelle, tous les quinze jours pendant deux années à méso-échelle et une fois par saison pendant une année à macro-échelle. Ces différentes approches ont permis d'avoir une vision pertinente de la dynamique et de la réponse fonctionnelle de la faune benthique aux changements induits par la présence de l'ostréiculture. La présence des cultures ostréicoles dans les pertuis charentais enrichit les sédiments en particules fines, en matière organique (12 %), en carbone organique particulaire (15-20 µg mg-1) et favorise une production microphytobenthique élevée. Pendant la période chaude de l'année printemps-été, la reminéralisation de la matière organique accumulée associée à des hypoxies temporaires a favorisé la production de sulfures et d'ammonium. Dans les stations soumises à l'ostréiculture, la diversité des assemblages diminue. La dynamique des espèces est caractérisée par des augmentations rapides des abondances suivies d'épisodes de mortalité. Les espèces tolérantes de la macrofaune benthique (Cirratulidae, Spionidae et Capitellidae) et des foraminifères vivants benthiques (Ammonia tepida et Cribroelphidium gunteri) sont favorisées. Le calcul de l'indice AMBI confirme la qualité écologique moyenne de ces sites. Au contraire, dans la station témoin, les espèces sensibles sont favorisées (Amphipodes, Rosalina cf. vilardeboana). La comparaison de la technique de culture sur table et de culture à plat a montré que la culture des huîtres à plat est moins perturbante pour le milieu. L'étude de la bioturbation a montré l'influence qui existe entre le mode de bioturbation des différents groupes de la macrofaune et la répartition verticale des foraminifères vivants dans la colonne sédimentaire. La diminution de la diversité des assemblages de la macrofaune dans les zones soumises à l'ostréiculture modifient la diversité fonctionnelle de ces assemblages et affectent le fonctionnement de la colonne sédimentaire, limitant la répartition verticale des foraminifères dans ces zones.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/2007/these-2582.pdf
http://archimer.ifremer.fr/doc/00000/2582/

Éditeur(s) : HAL CCSD
Résumé : International audience
We present a new 3-D GPS velocity solution for 182 sites for the region encompassing the Western Alps, Pyrenees, and southern France. The velocity field is based on a Precise Point Positioning (PPP) solution, to which we apply a common-mode filter, defined by the 26 longest time series, in order to correct for network-wide biases (reference frame, unmodeled large-scale processes, etc.). We show that processing parameters, such as troposphere delay modeling, can lead to systematic velocity variations of 0.1–0.5 mm yr−1 affecting both accuracy and precision, especially for short (< 5 years) time series. A velocity convergence analysis shows that minimum time-series lengths of  ∼  3 and  ∼  5.5 years are required to reach a velocity stability of 0.5 mm yr−1 in the horizontal and vertical components, respectively. On average, horizontal residual velocities show a stability of  ∼  0.2 mm yr−1 in the Western Alps, Pyrenees, and southern France. The only significant horizontal strain rate signal is in the western Pyrenees with up to 4  ×  10−9 yr−1 NNE–SSW extension, whereas no significant strain rates are detected in the Western Alps (< 1  ×  10−9 yr−1). In contrast, we identify significant uplift rates up to 2 mm yr−1 in the Western Alps but not in the Pyrenees (0.1 ± 0.2 mm yr−1). A correlation between site elevations and fast uplift rates in the northern part of the Western Alps, in the region of the Würmian ice cap, suggests that part of this uplift is induced by postglacial rebound. The very slow uplift rates in the southern Western Alps and in the Pyrenees could be accounted for by erosion-induced rebound.
ISSN: 1869-9529

hal-01395116
https://hal.archives-ouvertes.fr/hal-01395116
https://hal.archives-ouvertes.fr/hal-01395116/document
https://hal.archives-ouvertes.fr/hal-01395116/file/nguyen2016.pdf
DOI : 10.5194/se-7-1349-2016

Éditeur(s) : Copernicus Gesellschaft Mbh
Résumé : The distributions of the bio-essential trace element dissolved cobalt (DCo) and the apparent particulate Co (PCo) are presented along the GEOTRACES-A02 deep section from 64(o) N to 50(o) S in the western Atlantic Ocean (longest section of international GEOTRACES marine environment program). PCo was determined as the difference between total cobalt (TCo, unfiltered samples) and DCo. DCo concentrations ranged from 14.7 pM to 94.3 pM, and PCo concentrations from undetectable values to 18.8 pM. The lowest DCo concentrations were observed in the subtropical domains, and the highest in the low-oxygenated Atlantic Central Waters (ACW), which appears to be the major reservoir of DCo in the western Atlantic. In the Antarctic Bottom Waters, the enrichment in DCo with aging of the water mass can be related to suspension and redissolution of bottom sediments a well as diffusion of DCo from abyssal sediments. Mixing and dilution of deep water masses, rather than scavenging of DCo onto settling particles, generated the meridional decrease of DCo along the southward large-scale circulation in the deep western Atlantic. Furthermore, the apparent scavenged profile of DCo observed in the deep waters likely resulted from the persistence of relatively high concentrations in intermediate waters and low DCo concentrations in underlaying bottom waters. We suggest that the 2010 Icelandic volcanic eruption could have been a source of DCo that could have been transported into the core of the Northeast Atlantic Deep Waters. At intermediate depths, the high concentrations of DCo recorded in the ACW linearly correlated with the apparent utilization of oxygen (AOU), indicating that remineralization of DCo could be significant (representing up to 37% of the DCo present). Furthermore, the preferential remineralization of phosphate (P) compared to Co in these low-oxygenated waters suggests a decoupling between the deep cycles of P and Co. The vertical diffusion of DCo from the ACW appears to be a significant source of DCo into the surface waters of the equatorial domain. Summarizing, the dilution due to mixing processes rather than scavenging of DCo and the above-mentioned remineralization could be the two major pathways controlling the cycling of DCo into the intermediate and deep western Atlantic.
Biogeosciences (1726-4170) (Copernicus Gesellschaft Mbh), 2014 , Vol. 11 , N. 6 , P. 1561-1580

Droits : Author(s) 2014. CC Attribution 3.0 License.
http://archimer.ifremer.fr/doc/00241/35223/33727.pdf
DOI:10.5194/bg-11-1561-2014
http://archimer.ifremer.fr/doc/00241/35223/

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Random walk (RW) or Continuous Time Random Walk (CTRW) are recurring Monte Carlo methods used to model convective and diffusive transport in complex heterogeneous media. Many applications can be found, including fluid mechanic, hydrology, and chemical reactors modeling. These methods are easy to implement, very versatile and flexible enough to become appealing for many applications because they generally overlook of deeply simplify the building of explicit complex meshes required by deterministic methods. RW and CTRW provide a good physical understanding of the interactions between the space scales of het-erogeneities and the transport phenomena under consideration. In addition, they can result in efficient up-scaling methods, especially in context of flow and transport in fractured media. In the present study, we review the applications of RW or CTRW for several situations coping with various spatial scales, and different insights into up-scaling applications. RW and CTRW advantages and downsides are also discussed, thus providing a few avenues for further works and applications.
ISSN: 0169-3913

hal-01449131
https://hal.archives-ouvertes.fr/hal-01449131
https://hal.archives-ouvertes.fr/hal-01449131/document
https://hal.archives-ouvertes.fr/hal-01449131/file/0025972-02.pdf
DOI : 10.1007/s11242-016-0693-z

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
A versatile sol-gel route has been developed for the preparation of hierarchical porous silica membrane material with highly dispersed platinum nanoparticles (Pt-NPs). The outstanding feature of the "one pot" synthesis developed in this work lies in the successful preparation of a stable complex suspension made of silica sol, multi-scale porogens and Pt nanoparticles. The multi-scale porogens were based on non-ionic triblock copolymers and aqueous latex suspension to create mesopores and macropores, respectively, with finely tuned pore size and organization. For further functionalization of the membranes, Pt nanoparticles of about 4 nm in diameter were prepared by irradiating with microwaves (MW) the Pt precursors added in the starting suspension. This original path is suggested to enable a pre-organization of Pt nanoparticles in the ordered mesoporous structure. The suspensions were then deposited as thin films on either dense or macroporous supports, and further thermally treated at 450°C to remove the porogen units. Hierarchical porous layers composed of micropores (<2 nm), ordered mesopores (∼4 nm) and macropores (∼70 nm) with or without Pt were prepared and characterized. The resulting membranes are foreseen to exhibit great potential as multifunctional membranes for gas separation coupled with catalytic reaction. © The Royal Society of Chemistry 2008.
ISSN: 0959-9428

hal-01680586
https://hal.univ-antilles.fr/hal-01680586
DOI : 10.1039/b807029f

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Grey (Halichoerus grypus) and harbour seals (Phoca vitulina) are sympatric seal species, but they display distinct strategies of habitat use and connectivity between haulout sites. The distribution patterns and variations in relative abundance of both species were investigated along the French coast of the English Channel, at the southern limit of their range where seal numbers are increasing. Regular censuses conducted at all main haulout sites in mainland France showed significant seasonal variations at most sites, with more harbour seals counted during summer (breeding and moulting seasons), and more grey seals during summer only in the eastern English Channel. Trends in maximum haulout numbers at haulout sites showed a significant increase over the last five years, ranging from 9.7 to 30.9% per year for harbour seals, and from 5.8% (in the western English Channel) to 49.2% (in the eastern English Channel) per year for grey seals. These rates of increase in grey seal numbers are not linked to local pup production and most probably result from seal movements from the southwest British Isles and the North Sea, respectively. Aerial surveys conducted across the English Channel showed that most seal observations at sea were concentrated in the north-eastern English Channel. Telemetry showed that the 28 harbour seals tracked remained highly coastal, within a radius of 100 km from their haulout sites, and did not move to other known colonies. Grey seals moved much greater distances, reaching up to 1200 km from their capture site. More than half of the 45 grey seals tracked crossed the English Channel, especially during the breeding season, moving to known colonies in the southwest British Isles and the North Sea. Combining individual tracks and long-term surveys of the seal populations allowed a better understanding of the dynamics of these populations and their connectivity at a larger regional scale. The findings provide direct information for the management of grey and harbour seals within the frame of the Marine Strategy Framework Directive, and highlight focus areas where potential interactions between the two species should be monitored.
ISSN: 0967-0645

hal-01509674
https://hal.archives-ouvertes.fr/hal-01509674
DOI : 10.1016/j.dsr2.2017.04.004

Éditeur(s) : HAL CCSD Geological Society of America
Résumé : If the net flux to the island arc crust is primitive arc basalt, the evolved composition of most arc magmas entails the formation of complementary thick ultramafic keels at the root of the island arc crust. Dunite, wehrlite, and Cr-rich pyroxenite from the Jijal complex, constituting the Moho transition zone of the Kohistan paleo–island arc (northern Pakistan), are often mentioned as an example of high-pressure cumulates formed by intracrustal fractionation of mantle-derived melts, which were later extracted to form the overlying mafic crust. Here we show that calculated liquids for Jijal pyroxenites-wehrlites are strongly rare earth element (REE) depleted and display flat or convex-upward REE patterns. These patterns are typical of boninites and are therefore unlike those of the overlying mafic crust that have higher REE concentrations and are derived from light rare earth element (LREE)–enriched melts similar to island arc basalt. This observation, along with the lower 208Pb/204Pb and 206Pb/204Pb ratios of Jijal pyroxenites-wehrlites relative to gabbros, rejects the hypothesis that gabbros and ultramafic rocks derive from a common melt via crystal fractionation. In the 208Pb/204Pb versus 206Pb/204Pb diagram, ultramafic rocks and gabbros lie on the same positive correlation, suggesting that their sources share a common enriched mantle 2 (EM2) signature but with a major depleted component contribution for the ultramafic rocks. These data are consistent with a scenario whereby the Jijal ultramafic section represents a Moho transition zone formed via melt-rock reaction between subarc mantle and incoming melt isotopically akin to Jijal gabbroic rocks. The lack in the Kohistan arc of cogenetic ultramafic cumulates complementary to the evolved mafic plutonic rocks implies either (1) that a substantial volume of such ultramafic cumulates was delaminated or torn out by subcrustal mantle flow from the base of the arc crust in extraordinarily short time scales (0.10–0.35 cm/yr), or (2) that the net flux to the Kohistan arc crust was more evolved than primitive arc basalt.
ISSN: 0091-7613

hal-00406688
https://hal.archives-ouvertes.fr/hal-00406688
DOI : 10.1130/G23675A.1

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The Aegean domain is a key area for understanding the processes of back-arc extension. Observed deformation pattern and present day kinematics result from the interaction between the southward retreat of the Hellenic trench and the westward escape of Anatolia. Lithosphere-scale analogue models were employed to display that the overall pattern of Aegean extension requires not only the combination of trench retreat and Anatolia escape since middle Miocene but also the presence of an inherited lithosphere-scale mechanical discontinuity: the Vardar Suture Zone (VSZ). The reactivation in dextral shear of the eastern branch of the VSZ accommodates both the trench retreat (NS stretching) and the westward escape of Anatolia (EW shortening) in the Cyclades area since middle Miocene. Additionally, our model shows that the North Anatolian Fault (NAF) is a late structure in the evolution of the Aegean, initiated around 10 Ma after the onset of Anatolia escape. The displacement field at the surface of the model allows the identification of sub-domains, which result from strain partitioning instead of being "rigid microplates", directly comparable to the present-day displacement field (GPS) of the Aegean and western Anatolia. Our model provides a simple but powerful way to look at the dynamics of Aegean extension in two main stages. From middle Eocene to middle Miocene, extension was only driven by the southward retreat of the Hellenic trench at a rate lower than 1 cm*y− 1. Since middle Miocene, the combination of slab rollback with Anatolia westward escape resulted in a southwest direction of trench retreat, with an accelerating rate of up to 3 cm*y− 1.
ISSN: 0040-1951

insu-01066042
https://hal-insu.archives-ouvertes.fr/insu-01066042
https://hal-insu.archives-ouvertes.fr/insu-01066042/document
https://hal-insu.archives-ouvertes.fr/insu-01066042/file/Philippon-brun-tect-2014-HAL.pdf
DOI : 10.1016/j.tecto.2014.04.039

Éditeur(s) : HAL CCSD
Résumé : The heterogeneous nature and sometimes karstified carbonate environments has a direct impact on many environmental issues, such as coastal aquifers affected by saltwater intrusion. At the south of the island of Mallorca (Spain), the Llucmajor carbonate platform offers a privileged site for the study of such intrusions including the experimental site of Campos who meets the intrusion at shallow depth. The characterization of heterogeneous properties passes through a preliminary description of the properties of carbonate reservoirs, including those of the porosity. According to the wide range of sizes of heterogeneities from micrometer to hundreds of meters, the use of multiscale methods is required. This thesis focused on the determination of multiscale porosities from the microporosity to karstic porosity, and of relationships between observation scale changes of these properties. At the micron scale, high-resolution X-ray microtomography allows to extract the microporosity and the microporous network connectivity. At lower resolution (mm), X-ray tomography is also used to study the micro- and macro-porous network at the core scale which is already allocated to number of observations and measurements, including petrophysical. At the borehole scale, the wall images are used to identify the dissolved zones from centimeter macropores to plurimetric karstic cavities. At the larger scale, surface geophysics study the lateral extension of the karsts and heterogeneities. Finally, the porous structure of the studied site is integrated with its wide range of scales into the regional geology of the Llucmajor platform. Thus, the hydrogeophysical observatory set up on the site of Campos to monitor the spreading of salt water in the aquifer is integrated in its geological and petrophysical context, in order to refine the interpretation of its variations of salinity measurements during the time.
La nature hétérogène et parfois karstifiée des milieux carbonatés a un impact direct sur nombre de problématiques environnementales, comme celle des aquifères côtiers affectés par une intrusion d'eau salée. Au sud de l'ile de Majorque (Baléares, Espagne), la plate-forme carbonatée de Llucmajor offre un site privilégié pour l'étude de telles intrusions notamment avec le site expérimental de Campos, qui rencontre l'intrusion à faible profondeur. La caractérisation des propriétés hétérogènes du réservoir passe par une description préalable des propriétés des réservoirs carbonatés et notamment celle de la porosité. Au regard de la large gamme d'échelles d'hétérogénéités allant du micromètre à la centaine de mètre, l'utilisation de méthodes multi-échelles est nécessaire. Ce travail de thèse a porté sur la caractérisation multi-échelle de la porosité, allant de la microporosité à la porosité karstique, et l'établissement de relations entre les changements d'échelles d'observation de ces propriétés. A très petite échelle, la microtomographie haute-résolution à rayons X extrait à l'échelle du micron la microporosité et la connectivité des réseaux microporeux. A plus basse fréquence (celle du mm), la tomographie est également utilisée afin d'étudier le réseau micro- et macroporeux à l'échelle des carottes, à laquelle sont réalisées nombre d'observations et de mesures, notamment pétrophysiques. A l'échelle du puits, les images de paroi permettent d'identifier les zones de dissolution allant des macropores centimétriques aux cavités karstiques plurimétriques. A plus grande échelle, la géophysique de surface permet d'étudier l'extension latérale de ces karsts et hétérogénéités. Enfin, la structure poreuse du site étudié sur cette vaste gamme d'échelles est intégrée à la géologie régionale de la plate-forme de Llucmajor. Ainsi, l'observatoire installé sur le site pour surveiller la propagation de l'eau salée dans l'aquifère a pu être replacé dans son contexte géologique et pétrophysique, afin d'affiner l'interprétation de ses mesures de variations de salinité au cours du temps.
https://tel.archives-ouvertes.fr/tel-00633488

tel-00633488
https://tel.archives-ouvertes.fr/tel-00633488
https://tel.archives-ouvertes.fr/tel-00633488/document
https://tel.archives-ouvertes.fr/tel-00633488/file/TheseHebert.pdf

Éditeur(s) : HAL CCSD
Résumé : Both short-term and long-term morphodynamics of sand barrier systems forced by moderate storm conditions have been studied significantly in the literature. However, the dynamics of the emerged beach -- from a seaside water depth of ~ 1.5 metres below the lowest tide to the back-barrier -- impacted by typhoons remain scarcely documented. This study focuses on the analysis and a better understanding of the morphologic changes of such an emerged beach, when it is forced by one typhoon, several typhoons or the combination of a summer season of typhoons and a winter season of Monsoon wave/ wind conditions. The monitoring of near-shore hydrodynamics and beach morphodynamics was performed in the Wan-Tzu-Liao sand barrier from November 2011 to August 2012. Waves, currents and water level were measured at an offshore buoy (Cigu buoy; 18 m of water depth; 1.5 km seaward the studied zone), a current profiler (4 m of water depth), and a serie of pressure sensors deployed along a cross-shore section from the lower intertidal zone up to the eolian dune. Tide was obtained from a tide gauge inside the lagoon and wind conditions were obtained respectively from an inland station and the offshore Cigu buoy. Morphodynamic changes were monitoring thanks to DGDPS surveys performed on a grid including a 300 meters long portion of sand barrier extending from the subtidal zone to the back-barrier, as well as along two cross-shore and two long-shore profiles located within the grid. Surveys were performed each week during winter and just before and after each storm during the typhoons summer season. This field methodology provided a new and very robust dataset in order to quantify sand barrier dynamics exposed to high-energy events at various time scales. Amongst the eight typhoons recorded, TALIM is the most significant and representative. Offshore wave height reached 10.34 m (Tp = 14.6 s) at Cigu buoy and 2.3 m in 4 m of water depth. Morphological changes recorded 6 m of retreat for the dune front, a 20 m large dune breaching and the occurence of a wash-over fan in the lagoon. These changes form a well-known morphodynamic responses to moderate storms. More surprisingly, TALIM drove a significant nourishment of the supratidal zone, as well as a positive sand balance on the whole sand barrier. Five other typhoons resulted in the same type of morphological responses while two typhoons resulted in a strong erosion of the whole emerged beach. During winter and spring (moderate wave conditions and strong Monsoon winds), sand moved from the beach front to the back-barrier. For the whole year, the sand barrier recorded a 12 m landward migration concomitantly with a 12 m widening without abrasion of the dune elevation.
American Geophysical Union, Fall Meeting 2013

hal-01012312
https://hal.archives-ouvertes.fr/hal-01012312

Éditeur(s) : HAL CCSD European Geosciences Union
Résumé : International audience
Earth deformation is a multi-scale process ranging from seconds (seismic deformation) to millions of years (tectonic deformation). Bridging short- and long-term deformation and developing seismotectonic models has been a challenge in experimental tectonics for more than a century. Since the formulation of Reid's elastic rebound theory 100 years ago, laboratory mechanical models combining frictional and elastic elements have been used to study the dynamics of earthquakes. In the last decade, with the advent of high-resolution monitoring techniques and new rock analogue materials, laboratory earthquake experiments have evolved from simple spring-slider models to scaled analogue models. This evolution was accomplished by advances in seismology and geodesy along with relatively frequent occurrences of large earthquakes in the past decade. This coincidence has significantly increased the quality and quantity of relevant observations in nature and triggered a new understanding of earthquake dynamics. We review here the developments in analogue earthquake modelling with a focus on those seismotectonic scale models that are directly comparable to observational data on short to long timescales. We lay out the basics of analogue modelling, namely scaling, materials and monitoring, as applied in seismotectonic modelling. An overview of applications highlights the contributions of analogue earthquake models in bridging timescales of observations including earthquake statistics, rupture dynamics, ground motion, and seismic-cycle deformation up to seismotectonic evolution.
ISSN: 1869-9510

hal-01553120
https://hal.archives-ouvertes.fr/hal-01553120
https://hal.archives-ouvertes.fr/hal-01553120/document
https://hal.archives-ouvertes.fr/hal-01553120/file/rosenau2017.pdf
DOI : 10.5194/se-8-597-2017

Éditeur(s) : HAL CCSD
Résumé : The presence of biological matter (biofilms) in deep geological sites for storage of, for instance, toxic elements or groundwater in aquifers was clearly proved. That biomass triggers physical and chemical processes which greatly modify the durability and the sustainability of the sites. These processes, mainly from oxidative/reductive reactions, are poorly understood. This is mainly due to the fact that former studies were done at the macroscopic level far away from the micrometric scale where relevant processes induced by bacteria take place. Investigations at microscopic level are needed. Thus, we developed an experimental set-up based on the combined use of optical microscopy (transmission), atomic force microscopy (AFM) and electrical and electro-chemical AFM microscopy (EC_AFM) in order to get simultaneous information on topographic and electro-chemical processes. The first highly sensitive step was to use AFM with biological samples in liquid environment: wepresent here a study about AFM imaging of living, moving or self-immobilized bacteria, in their genuine physiological liquid medium and in true in vivo conditions. No external immobilization protocol, neither chemical nor mechanical was needed. For the first time, the native gliding movements of Gram negative Nostoc cyanobacteria upon the surface were studied by AFM. AFM height and mechanical stiffness data were simultaneously acquired. From these, mechanical parameters, inner turgor pressure and Young modulus, were derived for different bacterial species (Anabaenopsis circularis, Rhodococcus wratislaviensis). Our study revealed that AFM imaging is thus possible on moving living species. These results open a large window on new studies of both dynamical phenomena of practical and fundamental interests such as the formation of biofilms and dynamic properties of bacteria in real physiological conditions. The second delicate step was to combine AFM and optical measurements with electrical ones. We mounted a new experimental set-up coupling real-time (i) monitoring of optical properties as the optical density (OD) evolution related to bulk bacterial growth in liquid or as the counting of number of bacteria adhering on the surface of the sample as well and (ii) electrical and electrochemical measurements. Furthermore, these results will shortly be applied to the optimized monitoring of the in-situ activity of bacteria consuming oil pollutants, following this way, in real-time, the bioremediation of an oilcontaminated soil (ANR ECOTECH_BIOPHY program).
La présence de matière biologique (biofilms) dans les sites de stockage géologique profond, d'éléments toxiques ou encore de l'eau potable des aquifères est maintenant clairement démontrée. Cette biomasse est à l'origine de processus physiques et chimiques qui modifient considérablement la durabilité et la pérennité des sites concernés. Ces processus, principalement de type oxydo-réductif, sont encore mal compris. Ceci est principalement dû aux méthodes d'investigation, principalement macroscopiques, loin de l'échelle micrométrique caractéristique des bactéries. Seules des études, basées sur des méthodes d'investigation locale, peuvent apporter les informations requises. Ainsi, nous avons développé un dispositif expérimental basé sur l'utilisation combinée de la microscopie optique (en transmission), la microscopie à force atomique (AFM) et la microscopie AFM en mode électrique et électrochimique (EC_AFM) afin d'obtenir des informations simultanées sur la topographie de l'échantillon et sur les processus électrochimiques à l'échelle des bactéries. La première étape sensible consistait à utiliser l'AFM sur des échantillons biologiques en milieu liquide: nous présentons ici les résultats de l'imagerie AFM en milieu liquide de plusieurs types de bactéries dans leurs conditions physiologiques naturelles (conditions in vivo). Aucun protocole d'immobilisation, ni chimique ni mécanique, n'a été nécessaire; et pour la première fois, les mouvements de reptation de cyanobactéries Nostoc ont été étudiés par l'AFM. Les études AFM ont permis d'acquérir des données topographiques mais aussi mécaniques : nous avons pu ainsi mesurer le module d'Young, la pression de turgescence de différentes souches bactériennes (Anabaenopsis circularis, Rhodococcus wratislaviensis). Cette étude complète, a révélé que l'imagerie AFM est donc possible sur des espèces vivantes en mouvement. Ces résultats ouvrent une grande fenêtre sur de nouvelles études d'intérêts tels que la formation de biofilms et les propriétés dynamiques de bactéries dans des conditions physiologiques réelles. La deuxième étape délicate était de combiner l'AFM aux mesures optiques et électriques. Nous avons développé un nouveau dispositif expérimental permettant (i) le suivi de l'évolution de la croissance bactérienne par la mesure des propriétés optiques comme la densité optique DO (pour le développement bactérien en volume - milieu planctonique) , ou l'analyse de l'image du substrat par comptage du nombre de bactéries sur la surface de l'échantillon (biofilm), et (ii) les mesures électriques et électrochimiques. L'ensemble de ces résultats sera prochainement appliqué au développement de nouveaux outils de surveillance d'une biodépollution de terrain contaminé par les hydrocarbures, par le suivi in situ et en temps réel de l'activité de bactéries dépolluantes (ECOTECH_BIOPHY ANR).
https://tel.archives-ouvertes.fr/tel-01044714

tel-01044714
https://tel.archives-ouvertes.fr/tel-01044714
https://tel.archives-ouvertes.fr/tel-01044714/document
https://tel.archives-ouvertes.fr/tel-01044714/file/theseDhahri2013.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In this paper, we describe an outcrop to characterize the effect of fracture spacing and type on larger scale effective elasticity, which is measured for the first time in-situ with a Schmidt hammer. The outcrop is dominated by lime mudstones and belongs to the deformation zone of the St Clement fault, in southern France. Our results suggest that small spacing of faults, open fractures and styolites leads to lesser effective Young's modulus, whereas small sealed fracture spacing leads to greater effective Young's modulus. These relationships are compatible with theoretical models of effective elasticity. Using Amadei and Savage (1993) approach, we define a non-linear model that relates Schmidt hammer rebound to spacing by fracture type. A hemisphere with a radius of 40 to similar to 200 cm is the rheological volume characterized by the Schmidt hammer. Results of model inversion demonstrate that variations of Schmidt hammer rebound over the outcrop can be used to estimate fracture type and stiffness. Stiffness of sealed fractures is 2-3 orders of magnitude greater than the stiffness of faults, stylolites and open fractures. This result is consistent with an increase of the rate of interseismic stress build-up of major faults with sealing of fractures in their damage zone.
ISSN: 0191-8141

hal-00669954
https://hal.archives-ouvertes.fr/hal-00669954
DOI : 10.1016/j.jsg.2011.09.009