Éditeur(s) : HAL CCSD Springer International Publishing
Résumé : Industrial agriculture has clearly reached its limits. Industrial agriculture is not able anymore to satisfy the basic needs of the growing worldwide population while ensuring the conditions of reproduction of natural assets. New production models have to be designed to protect and reclame polluted and degraded agricultural areas. Agroecology is considered as a promising way to achieve ecologically-intensive agrosystems, since the seminal contribution of Altieri in 1995. Nevertheless agroecology has not fully emerged as a scientific discipline yet. Agroecology is more that a traditional scientific discipline because agroecology breaks the frontiers between biophysical sciences and social sciences. This chapter reviews the roots and evolution of agroecology in the first section. Here we propose a mathematical theory of viability to handle uncertainty and complexity within agrosystems. This theory allows to define a kern of viability in which the agrosystem stay viable in the long term (section “Scientific stakes: New frontiers”). However, agroecological innovations create new uncertainties and controversies that must be solved. Some solutions can be found individually while other solutions must by co-constructed using innovative collective actions and hydrid forums (Callon et al. 2001, section “Scientific controversy and uncertainty”). Such collective knowledge makes agroecology as the starting point of a representative democracy by setting up adaptive governance on territories (section “How to manage agrosystems in the context of global changes?”).
Sustainable Agriculture Reviews 14

ISBN : 978-3-319-06015-6
hal-01195372
https://hal.archives-ouvertes.fr/hal-01195372
DOI : 10.1007/978-3-319-06016-3_1
PRODINRA : 270790

Éditeur(s) : Université des Antilles Études caribéennes
Résumé : It is increasingly recognized that maintaining biodiversity is of fundamental importance toward sustaining human livelihoods. One of the major assets of the region identified as “Latin America and the Caribbean” (LAC) is its biological wealth; by extension, the continued biodiversity loss of the LAC region is seen as one of the world’s principal environmental problems. The marine resources of Caribbean Sea are of vital economic, ecological and social importance to the LAC region, and are under particular threat. Marine turtles play vital roles throughout the Caribbean Sea both in terms of ecological functions and human welfare. Conservation efforts in this direction can often depend on the ability to place a value on welfare changes associated with the loss of ecosystem goods and services into which biodiversity plays an integral role.Using the ecosystem service categories of the Millennium Ecosystem Assessment, this paper discusses from an inter-disciplinary perspective the methodologies associated with linking marine turtles, ecosystem services and human welfare. While the main economic benefit to be currently valued may stem from the eco-tourism potential surrounding turtle nesting sites, for a true picture of the environmental resources upon which this service depends, it is necessary to also identify the other provisioning, regulating and cultural services of the resource. In this way, human welfare impacts can be more truly judged, and effective resource management can be undertaken.
La préservation de la biodiversité est d'une importance fondamentale pour le maintien des moyens de subsistance de l'homme. L'un des atouts majeurs de l’ensemble régional que constitue l'Amérique latine et les Caraïbes (LAC) demeure sa richesse biologique, par extension, toute dégradation de sa biodiversité pose des problèmes environnementaux d’ordre mondial. Les ressources marines de la mer des Caraïbes, qui sont particulièrement menacées, sont d'une importance économique, écologique et sociale vitale pour la région. Les tortues marines jouent un rôle essentiel dans la mer des Caraïbes à la fois en termes de fonctions écologiques et de bien-être humain.En ce sens, les efforts de conservation peuvent de la capacité de chiffrer la valeur sur le bien-être des changements associés à la perte de biens et de services des écosystèmes dans lesquels la biodiversité est partie intégrante. En utilisant les catégories de services des écosystèmes du Millennium Ecosystem Assessment, la présente étude aborde, dans une perspective interdisciplinaire, les méthodologies associées aux interrelations entre les tortues marines, les services écosystémiques et le bien-être de l'homme.Si le principal avantage économique actuellement identifié repose sur le potentiel écotouristique, autour des sites de nidification des tortues, pour une image fidèle des ressources environnementales sur lesquelles ce service repose, il est nécessaire d'identifier également les autres apports de la ressource, en termes de régulations, de services culturels. De cette façon, les impacts sur le bien-être humain peuvent être mieux appréhendés et les ressources peuvent être gérées de façon plus efficace.
Caraïbes

Droits : info:eu-repo/semantics/openAccess
urn:doi:10.4000/etudescaribeennes.10990
http://journals.openedition.org/etudescaribeennes/10990

Éditeur(s) : HAL CCSD Institute of Electrical and Electronics Engineers
Résumé : International audience
The state-space modeling of partially observed dynamical systems generally requires estimates of unknown parameters. The dynamic state vector together with the static parameter vector can be considered as an augmented state vector. Classical filtering methods, such as the extended Kalman filter (EKF) and the bootstrap particle filter (PF), fail to estimate the augmented state vector. For these classical filters to handle the augmented state vector, a dynamic noise term should be artificially added to the parameter components or to the deterministic component of the dynamical system. However, this approach degrades the estimation performance of the filters. We propose a variant of the PF based on convolution kernel approximation techniques. This approach is tested on a simulated case study.
ISSN: 0018-9251

inria-00459886
https://hal.inria.fr/inria-00459886
DOI : 10.1109/TAES.2009.5259183

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Tectonically controlled landforms develop morphologic features that provide useful markers to investigate crustal deformation and relief growth dynamics. In this paper, we present results of morphotectonic experiments obtained with an innovative approach combining tectonic and surface processes (erosion, transport, and sedimentation), coupled with accurate model monitoring techniques. This approach allows for a qualitative and quantitative analysis of landscape evolution in response to active deformation in the three end-member geological settings: compression, extension, and strike–slip.Experimental results outline first that experimental morphologies evolve significantly at a short time scale. Numerous morphologic markers form continuously, but their lifetime is generally short because erosion and sedimentation processes tend to destroy or bury them. For the compressional setting, the formation of terraces above an active thrust appears mainly controlled by narrowing and incision of the main channel through the uplifting hanging-wall and by avulsion of deposits on fan-like bodies. Terrace formation is irregular even under steady tectonic rates and erosional conditions. Terrace deformation analysis allows retrieving the growth history of the structure and the fault slip rate evolution. For the extensional setting, the dynamics of hanging-wall sedimentary filling appears to control the position of the base level, which in turn controls footwall erosion. Two phases of relief evolution can be evidenced: the first is a phase of relief growth, and the second is a phase of upstream propagation of topographic equilibrium that is reached first in the sedimentary basin. During the phase of relief growth, the formation of triangular facets occurs by degradation of the fault scarp, and their geometry (height) becomes stationary during the phase of upstream propagation of the topographic equilibrium. For the strike–slip setting, the complex morphology of the wrench zone, composed of several interacting fault segments, enhances the interactions with the drainage network. Because of the widening of the main fault zone toward the surface, a significant amount of distributed deformation is observed along the wrench zone. Locally, where two terminations of fault segments interact, less than a quarter of the far field displacement can remain measurable using fault offsets, leading to a systematic underestimation of the real fault slip rate.These different experimental examples illustrate the great potential of the approach coupling deformation mechanisms and erosion–transport–sedimentation processes to investigate qualitatively and quantitatively the morphotectonic evolution of tectonically controlled landscapes.
ISSN: 0169-555X

hal-01243587
https://hal.archives-ouvertes.fr/hal-01243587
DOI : 10.1016/j.geomorph.2015.02.011

Éditeur(s) : Université des Antilles Études caribéennes
Résumé : Dès l’annonce du projet de loi portant sur le Mariage pour tous en septembre 2012, de nombreux chrétiens martiniquais se sont mobilisés contre une réforme, qui portait à leurs yeux, atteinte à leurs convictions religieuses. Avec ce cadre d’action spirituel, ils ont rassemblé de nombreux sympathisants. Dans une société très croyante, la légitimité sociale des conservateurs leur a permis de rassembler des ressources matérielles et humaines stratégiques qui ont renforcé l’attractivité du mouvement. Pendant la période de mobilisation, certains opposants à la loi Taubira ont proféré dans les médias des propos violents et dégradants envers les homosexuels qui ont encouragé des militants de la diversité sexuelle à se mobiliser contre l’homophobie. Dans un contexte antillais plutôt hostile à l’homosexualité, ce cadre d’action n’a pas reçu autant de soutien social et politique que celui des conservateurs, rendant impossible la mobilisation des ressources nécessaires à rassembler en masse des militants contre l’homophobie.
Desde el anuncio del proyecto de ley « Matrimonio para todos » en septiembre 2012, numerosos cristianos martiniquenos protestaron contra una reforma opuesta según ellos a sus convicciones religiosas. Con ese campo de action espiritual, numerosas personas compartieron su protesta. En una sociedad muy religiosa, la legitimidad social de los conservadores les permitió movilizar recursos materiales y humanos estratégicos que incrementaron la importancia del movimiento. Durante el periodo de protesta, algunos oponentes a la Ley Taubira hicieron discursos violentes y degradantes a propósito de los homosexuales, lo cual aliento los militantes de la diversidad sexual a protestar en contra de la homofobia. En un contexto antillano hostil a la homosexualidad, ese campo de acción no recibió tanto apoyo social y politico como los conservadores, lo que volvió imposible la movilización de los recursos necesarios para juntar numerosos militantes contra la homofobia.
Martinique

Droits : info:eu-repo/semantics/openAccess
urn:doi:10.4000/etudescaribeennes.7141
http://journals.openedition.org/etudescaribeennes/7141

Éditeur(s) : HAL CCSD
Résumé : The ovary is not solely the unique source of oocytes necessary for fertilization but also a crucial conductor of endocrine regulations of the reproductive system. In the fetal ovary, oocytes grouped in clusters are surrounded by somatic pre-granulosa cells, altogether delineated by a basement membrane and constituting ovarian cords. The formation of the definitive ovarian functional units requires their fragmentation into follicles formed by a single oocyte surrounded by granulosa cells and delineated by a basement membrane. This partitioning occurs within a tiny period and is dependent on the correct timing of the meiotic process, on an apoptotic wave that specifically targets oocytes and the remodelling of the basement membrane. Follicle formation is a crucial event of ovarian development because the follicle stock formed at the end of this process is non-renewable. Therefore, any disturbance of this process can lead to reproductive abnormalities in adulthood. Recent data on endocrine disruptors displaying estrogenic activity have involved the fragile estrogenic homeostasis in the process. We aimed at better understanding how the endogen estrogen 17b-estradiol (E2) contributes to follicle formation. To assess it, Sprague-Dawley rats were treated with E2 at different doses during follicle formation, /i.e./ in the 3 days following birth. We show that although this treatment impairs the development of the hepatic and ovarian detoxification systems, the female neonate is able to increase its estrogen clearance capabilities. Nevertheless, E2 treatment within this critical period triggers a dose-dependent decrease of oocyte number per ovary. Regardless of the E2 dose, puberty is advanced. All treated females are at least transiently fertile, yet these reproductive capabilities rapidly decline. A high (10 µg/day) dose of E2 leads to a secondary infertility characterized by anovulation that probably result from a dysfunction of the whole reproductive tract. By contrast, a lower (0.1 µg/day) dose of E2, that does not significantly modify neonatal oocyte survival, leads to a progressive reproductive senescence likely due to ovarian failure. Long-term troubles may originate from precocious E2 impact on the ovary since it disturbs ovarian transcriptome and produces many lesions on ovarian cell DNA.
L'ovaire est au cœur de la physiologie de la reproduction féminine. Il est à la fois à l'origine des ovocytes nécessaires à la fécondation et acteur des régulations endocrines du système reproducteur. Les ovocytes de l'ovaire fœtal sont groupés en amas bordés de cellules somatiques et d'une membrane basale, formant les cordons ovariens. Ces cordons ovariens se fragmentent pour former les follicules ovariens: un ovocyte bordé de cellules somatiques et d'une membrane basale. Cette fragmentation se déroule sur une courte période (/in utero/ chez la femme et juste après la naissance chez les rongeurs) et fait intervenir une vague de mort cellulaire programmée touchant les ovocytes pendant leur méiose et un remodelage de la membrane basale. La formation des follicules est une période cruciale du développement ovarien puisque le stock de follicules formés à l'issue de ce processus est non renouvelable. Son altération peut donc être à l'origine de troubles de la fonction de reproduction chez le futur adulte. Il existe une fragile homéostasie œstrogénique en place au moment de la formation folliculaire: chez la femme, l'ovaire se développe /in utero/, sous l'influence des œstrogènes circulants maternels et la production ovarienne fœtale. Chez les rongeurs, les follicules se forment lors de la levée de l'imprégnation hormonale maternelle au moment de la naissance. Nous avons souhaité comprendre comment le 17b-œstradiol (E2), œstrogène endogène, pouvait contribuer à la mise en place des follicules. Pour cela, des rattes Sprague-Dawley ont été traitées pendant la période de formation des follicules avec de l'E2 à différentes doses entre 0.01 et 10 µg/jour. Nos travaux démontrent que le traitement de rattes par des œstrogènes entre leur naissance et 3 jours induit une réduction dose-dépendante de leur nombre d'ovocytes. Bien que le traitement entrave le développement normal du système de détoxication hépatique et ovarien, l'animal est capable d'accroître ses capacités d'élimination des œstrogènes. Ces capacités sont toutefois insuffisantes pour bloquer les effets du traitement. Quelle que soit la dose d'E2 utilisée (0.1 ou 10 µg/jour), la puberté est plus précoce chez les femelles exposées mais toutes sont fertiles, au moins transitoirement. Cependant le traitement induit une dégradation rapide des capacités reproductives. L'E2 modifie la dynamique folliculaire chez l'adulte, longtemps après l'arrêt du traitement. Si une forte dose d'E2 réduit la survie des ovocytes lors de la formation des follicules et conduit à une infertilité secondaire due à un dysfonctionnement général du tractus reproducteur, une dose faible n'affecte pas la survie des ovocytes à court terme mais conduit à une sénescence reproductive précoce vraisemblablement d'origine ovarienne. L'origine de ces troubles pourrait résider dans les effets précoces de l'exposition à E2 : cette molécule altère le transcriptome ovarien et induit de nombreuses lésions de l'ADN des cellules ovariennes.
https://tel.archives-ouvertes.fr/tel-00953657

NNT : 2013REN1S107
tel-00953657
https://tel.archives-ouvertes.fr/tel-00953657
https://tel.archives-ouvertes.fr/tel-00953657/document
https://tel.archives-ouvertes.fr/tel-00953657/file/CHALMEY_Clementine.pdf

Éditeur(s) : HAL CCSD Nature Publishing Group
Résumé : International audience
Abstract View references (45)Graphene oxide-iron oxide (GO-Fe3O4) nanocomposites were synthesised by co-precipitating iron salts onto GO sheets in basic solution. The results showed that formation of two distinct structures was dependent upon the GO loading. The first structure corresponds to a low GO loading up to 10wt%, associated with the beneficial intercalation of GO within Fe3O4nanoparticles and resulting in higher surface area up to 409m2g-1. High GO loading beyond 10 wt% led to the aggregation of Fe3O4 nanoparticles and the undesirable stacking of GO sheets. The presence of strong interfacial interactions (Fe-O-C bonds) between both components at low GO loading lead to 20% higher degradation of Acid Orange 7 than the Fe3O4 nanoparticles in heterogeneous Fenton-like reaction. This behaviour was attributed to synergistic structural and functional effect of the combined GO and Fe3O4 nanoparticles.
ISSN: 2045-2322

hal-01683208
https://hal.univ-antilles.fr/hal-01683208
DOI : 10.1038/srep04594

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
A series of graphene oxide (GO) and zinc partially substituted magnetite GO-Fe1-xZnxOy (0 ≤ x ≤ 0.285) catalysts were synthesised through a precipitation-oxidation method. The rate constants for the degradation of acid orange seven (AO7) proceeded at a significant faster rate under UV-irradiation (up to 670%) than the conventional heterogeneous Fenton-like reaction. The resultant catalysts were mesoporous, so there was no mass transfer limitation for AO7 to access active sites in the catalysts. Further, maximum increases of rate constant up to 220% occurred as the zinc molar concentration increased from x = 0 to x = 0.159. GO enhanced to incorporation of zinc into the combined metal oxide, whilst zinc limited crystal growth, thus forming smaller crystallite sizes. These features proved to be essential for the improved catalytic activity of the resultant catalysts. The optimised zinc molar value at x = 0.159 delivered the best catalytic activity. © The Royal Society of Chemistry 2016.
ISSN: 2046-2069

hal-01683215
https://hal.univ-antilles.fr/hal-01683215
DOI : 10.1039/c6ra04068c

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Thermogravimetric results on the thermal degradation of isolated components extracted from shells of tropical fruit stones and seeds allowed us to establish the dependence of the yield of char obtained by high-temperature pyrolysis (600-900 °C) of lignocellulosic raw materials on the content of components in precursors...
ISSN: 1387-1811

hal-00809743
https://hal.univ-antilles.fr/hal-00809743
DOI : 10.1016/S1387-1811(03)00288-9

Éditeur(s) : HAL CCSD
Résumé : Meteorological phenomena with scales lower than hurricanes, from extreme rainfalls to pollution peaks, represent important environmental and health risks in the Caribbean. These examples show the need to downscale large-scale meteorological data to island-scale fields.The main goal of the present numerical study is the analysis of the meso- and micro-scale mechanisms inducing diurnal and nocturnal circulations in the Guadeloupe archipelago. The Weather Research and Forecasting model is employed. The micro-scale results are obtained by the coupling of the 1-km simulated fields and the Large Eddy Simulation method. Then, in order to analyze the dispersion of a pollutants plume, the micro-scale outputs with 111 m of resolution are used to force the lagrangian particles dispersion model FLEXPART. The study has been conducted for three real cases of weather types linked with strong, medium and weak trade winds.The results of simulations, validated with available observed data, permitted to simulate all local circulations, including a nocturnal counter-current flow which may induce a pollution peak in the urban area of Pointe-à-Pitre city.These works, which may be applied to other Lesser Antilles islands, suggest many environmental and energy applications.
Les phénomènes météorologiques d'échelles inférieures aux cyclones, depuis les pluies intenses, jusqu'à la dégradation de la qualité de l'air, ont pour les Caraïbes une importance aiguë en termes de risques naturels ou de risques sur la santé. Ces exemples attestent de la nécessité d'utiliser des méthodes de descentes d'échelle pour exploiter l'information météorologique de grande échelle et dériver des scénarios locaux appliqués aux territoires insulaires. Les travaux présentés ont pour principaux objectifs la simulation numérique et l'analyse des mécanismes méso- et micro-échelles qui induisent des circulations locales diurnes et nocturnes sur l'archipel de la Guadeloupe, à l'aide du modèle numérique météorologique Weather Research and Forecasting. Les résultats des simulations micro-échelles sont obtenus par le couplage des champs modélisés à 1 km avec la méthode Large Eddy Simulation. Les sorties micro-échelles, à 111 m, sont ensuite utilisées pour forcer le modèle lagrangien de dispersion de particules FLEXPART afin d'étudier la dispersion d'un panache de polluants. L'étude a été menée pour trois cas réels de situations météorologiques correspondant à des alizés soutenus, moyens et faibles. Les résultats des simulations, après validation, et comparaison aux données d'observation disponibles, permettent de restituer l'ensemble des circulations locales et soulignent l'existence d'un écoulement nocturne à contre courant susceptible d'induire une forte pollution sur la zone urbaine de Pointe-à-Pitre. Cette étude, transposable aux autres îles des petites Antilles, laisse envisager de nombreuses applications environnementales et énergétiques.
https://hal.archives-ouvertes.fr/tel-01074600

Droits : info:eu-repo/semantics/OpenAccess
tel-01074600
https://hal.archives-ouvertes.fr/tel-01074600
https://hal.archives-ouvertes.fr/tel-01074600/document
https://hal.archives-ouvertes.fr/tel-01074600/file/rcece_thesis.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : In the context of an ongoing monitoring study on the impacts of gold-mining activities on critical ecosystem processes, we explored the use of soil Denitrifying Enzyme Activity (DEA) and Substrate Induced Respiration (SIR) as ecosystem indicators in tropical rainforests of French Guiana. We also propose DEA/SIR ratio as ecosystem attribute able to describe the state of an ecosystem and to reflect changes in ecological processes. With this purpose, we measured SIR, DEA and DEA/SIR ratio in five gold-mining areas and five surrounding natural reference rainforests. We also measured indicators in two conditions of spontaneous regeneration of vegetation (stratified or not) and two conditions of soil rehabilitation (prior preparation of soils or not). We showed a high variability of DEA, SIR and DEA/SIR ratio in the natural reference forests. This pointed out the necessity to identify relevant reference systems - i.e. proving a close match in all relevant ecological dimensions - to compare with closed perturbed systems in order to assess the levels of alterations after disturbances. Results showed a high impact of gold mine on microbial processes with a strong decrease of DEA (10-fold lower), SIR (2-fold lower) and DEA/SIR ratio (8-fold lower) in perturbed areas in comparison with natural reference forests. The type of spontaneous vegetation (stratified or not) influenced the values of indicators as well as prior rehabilitation of soils, demonstrating the capacity of DEA. SIR and DEA/SIR ratio to respond in proportion to the perturbation (robustness) and to the different levels of restoration (sensitivity). The systematic decrease of the ratio DEA/SIR observed in the studied perturbed situations demonstrates clearly that the structure of microbial communities has been also modified. The ratio DEA/SIR proved to be robust and sensitive, and able to describe in fairly fine way changes of soil microbial communities in terms of structure and function in gold mine areas and during processes of restoration. We propose to use DEA, SIR and DEA/SIR ratio as bioindicators of both structural and functional aspects of C and N cycling in soils. Together with others bioindicators based on key supporting functions in soils, these indicators should accurately evaluate the ecological potential of natural ecosystems and the levels of degradation in case of land-use changes. (C) 2012 Elsevier Ltd. All rights reserved.
ISSN: 1470-160X

hal-01190730
https://hal.archives-ouvertes.fr/hal-01190730
DOI : 10.1016/j.ecolind.2012.01.021
PRODINRA : 213639

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A data stream is a potentially uninterrupted flow of data. Mining this flow makes it necessary to cope with uncertainty, as only a part of the stream can be stored. In this paper, we evaluate a statistical technique which biases the estimation of the support of patterns, so as to maximize either the precision or the recall, as chosen by the user, and limit the degradation of the other criterion. Theoretical results show that the technique is not far from the optimum, from the statistical standpoint. Experiments performed tend to demonstrate its potential, as it remains robust even under significant distribution drifts.
ISSN: 0031-3203

lirmm-00365474
https://hal-lirmm.ccsd.cnrs.fr/lirmm-00365474

Éditeur(s) : HAL CCSD Springer
Résumé : International audience
Thermoelastic behavior of different marble types was analyzed using computational modeling and experimental measurements. Eight marble samples with different composition, grain size, grain boundary geometry, and texture were investigated. Calcitic and dolomitic marbles were considered. The average grain size varies from 75 μm to 1.75 mm; grain boundary geometry differs from nearly equigranular straight grain boundaries to inequigranular-interlobate grain boundaries. Four typical marble texture types were observed by EBSD measurements: weak texture; strong texture; girdle texture and high-temperature texture. These crystallographic orientations were used in conjunction with microstructure-based finite element analysis to compute the thermoelastic responses of marble upon heating. Microstructural response maps highlight regions and conditions in the marble fabric that are susceptible to degradation phenomena. This behavior was compared to the measured thermal expansion behavior, which shows increasing residual strains upon repetitive heating-cooling cycles. The thermal expansion behavior as a function of temperature changes can be classified into four categories: (a) isotropic thermal expansion with small or no residual strain; (b) anisotropic thermal expansion with small or no residual strain; (c) isotropic thermal expansion with a residual strain; and (d) anisotropic thermal expansion with residual strain. Thermal expansion coefficients were calculated for both simulated and experimental data and also modeled from the texture using the MTEX software. Fabric parameters control the amount and directional dependence of the thermal expansion. Marbles with strong texture show higher directional dependence of the thermal expansion coefficients and have smaller microstructural values of the maximum principal stress and strain energy density, the main precursors of microcracking throughout the marble fabric. In contrast, marbles with weak texture show isotropic thermal expansion behavior, have a higher propensity to microcracking, and exhibit higher values of maximum principal stress and strain energy density. Good agreement between the experimental and computational results is observed, demonstrating that microstructure-based finite-element simulations are an excellent tool for elucidating influences of rock fabric on thermoelastic behavior.
ISSN: 1866-6280

hal-00858095
https://hal.archives-ouvertes.fr/hal-00858095
DOI : 10.1007/s12665-013-2406-z

Éditeur(s) : HAL CCSD
Résumé : International audience
The carbon capture and storage is considered as one of the solutions of reducing the effects of global warming. It consists in injecting large quantities of CO 2 in supercritical form directly into deeply located geological formations. One of the methods involves sequestration in the carbonate sedimentary rocks (sandstones and limestones) which are considered as a promising solution. The morphology of the pore network and solid skeleton defines important macroscopic prop-erties of the rock (permeability, stiffness). Modelling at micro scale of random heterogeneous materials (porous media) should be based on morphological and statistical characterisation 1,2 of the investigated microstructure. The work is focused on a reconstruction method by grains deposit 3 , for various range of pa-rameters, to obtain equivalent model of natural rock samples (oolitic limestone and fontainebleau sandstone). Generated samples satisfy morphological and statistical informations 4 which were obtained by 3D image analysis of X-ray tomography of the natural rock samples. For validation of the modelling numerical computations of mechanical and transfer properties are also provided.
14th European Mechanics of Materials Conference - EMMC14
Gothembourg, Sweden

hal-01103163
https://hal.archives-ouvertes.fr/hal-01103163

Éditeur(s) : Université des Antilles Études caribéennes
Résumé : Tourism has been an important component of Caribbean island economy for more than three decades. The business model is based largely on the deployment of low-wage workers in destination surroundings which mimic the past colonial plantation era. Moreover, mass tourism has resulted in stretching the carrying capacity of some smaller island states to the limiting end. Large trans-national tourism corporations operating cruise ships and/or hotels are coercing sovereign governments to offer ever more fiscal concessions as incentives for business continuation. Additionally as the competition for tourism revenue is heightened by destinations outside the Caribbean, regional states are struggling to find new means to maintain and expand the tourism trade. Alternative tourism venues such as sex, gambling, tax evasion, medical, sports, culture and ecology are being implemented. Some of these offerings are indeed degrading to the people and their cultural tradition. And they do not improve the economic well-being of the people satisfactorily. A new strategy to replace classical as well as alternative tourism is urgently needed.
Le tourisme est une activité essentielle dans l'économie des îles de la Caraïbe depuis plus de trois décennies. Le modèle économique repose en grande partie sur la présence d'une main-d'œuvre insulaire peu coûteuse qui s'inscrit dans le prolongement des économies coloniales construites sur les plantations. Le tourisme de masse rencontre des limites en matière de capacité de charge sur les plus petits Etats insulaires. Les grandes sociétés transnationales de tourisme qui contrôlent les bateaux de croisières ou les hôtels contraignent les gouvernements souverains à faire toujours plus de concessions fiscales. La concurrence entre les destinations de la Caraïbe est exacerbée par la concurrence internationale autour des revenus du tourisme. Les Etats de la région peinent à trouver de nouvelles ressources pour maintenir et développer le secteur du tourisme. Les offres alternatives, entre le sexe, le jeu, l'évasion fiscale, le médical, le sport, la culture et l'écologie sont mises en œuvre. Certaines de ces offres sont, en effet, dégradantes pour les personnes et leur tradition culturelle et n'améliorent pas le bien-être économique de la population de manière satisfaisante. Une nouvelle stratégie pour remplacer le tourisme balnéaire classique ainsi que le tourisme alternative du moment s'impose d'urgence.
Caraïbes

Droits : info:eu-repo/semantics/openAccess
urn:doi:10.4000/etudescaribeennes.7524
http://journals.openedition.org/etudescaribeennes/7524

Éditeur(s) : Pergamon-elsevier Science Ltd
Résumé : We report rare earth element (REE) and neodymium (Nd) isotope data for the organic fraction of sediments collected from various depositional environments, i.e. rivers (n=25), estuaries (n=18), open-ocean settings (n=15), and cold seeps (n=12). Sedimentary Organic Matter (SOM) was extracted using a mixed hydrogen peroxide/nitric acid solution (20%-H2O2 – 0.02M-HNO3), after removal of carbonate and oxy-hydroxide phases with dilute hydrochloric acid (0.25M-HCl). A series of experimental tests indicate that extraction of sedimentary organic compounds using H202 may be complicated occasionally by partial dissolution of sulphide minerals and residual carbonates. However, this contamination is expected to be minor for REE because measured concentrations in H2O2 leachates are about two-orders of magnitude higher than in the above mentioned phases. The mean REE concentrations determined in the H2O2 leachates for samples from rivers, estuaries, coastal seas and open-ocean settings yield relatively similar levels, with ΣREE = 109 ± 86 ppm (mean ± s; n=58). The organic fractions leached from cold seep sediments display even higher concentration levels (285 ± 150 ppm; mean ± s; n=12). The H2O2 leachates for most sediments exhibit remarkably similar shale-normalized REE patterns, all characterized by a mid-REE enrichment compared to the other REE. This suggests that the distribution of REE in leached sedimentary organic phases is controlled primarily by biogeochemical processes, rather than by the composition of the source from which they derive (e.g. pore, river or sea- water). The Nd isotopic compositions for organic phases leached from river sediments are very similar to those for the corresponding detrital fractions. In contrast, the SOM extracted from marine sediments display εNd values that typically range between the εNd signatures for terrestrial organic matter (inferred from the analysis of the sedimentary detrital fractions) and marine organic matter (inferred from the analysis of local surface seawater). A notable exception is the case of organic matter (OM) fractions leached from cold seep sediment samples, which sometimes exhibit εNd values markedly different from both terrigenous and surface seawater signatures. This suggests that a significant fraction of organic compounds in these sediments may be derived from chemosynthetic processes, recycling pore water REE characterized by a distinct isotopic composition. Overall, our results confirm that organic matter probably plays an important role in the oceanic REE budget, through direct scavenging and remineralization within the water column. Both the high REE abundances and the shape of shale-normalized patterns for leached SOM also suggest that OM degradation in sub-surface marine sediments during early diagenesis could control, to a large extent, the distribution of REE in pore waters. Benthic fluxes of organic-bound REE could hence substantially contribute to the exchange processes between particulates and seawater that take place at ocean margins. Neodymium isotopes could provide useful information for tracing the origin (terrestrial versus marine) and geographical provenance of organic matter, with potential applications in paleoceanography. In particular, future studies should further investigate the potential of Nd isotopes in organic compounds preserved in sedimentary records for reconstructing past variations of surface ocean circulation.
Geochimica Et Cosmochimica Acta (0016-7037) (Pergamon-elsevier Science Ltd), 2014-09 , Vol. 140 , P. 177-198

Droits : 2014 Elsevier Ltd. All rights reserved.
http://archimer.ifremer.fr/doc/00191/30250/28682.pdf
DOI:10.1016/j.gca.2014.05.016
http://archimer.ifremer.fr/doc/00191/30250/

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Chlordecone (CLD) was an organochlorine insecticide whose previous use resulted in an extensive pollution of the environment with severe health effects and social consequences. A closely related compound, 5b-hydrochlordecone (5b-hydroCLD), has been searched for and often detected in environmental matrices from the geographical area where CLD was applied. The current consensus considered that its presence was not the result of a biotic or abiotic dechlorination of CLD in these matrices but rather the consequence of its presence as impurity (synthesis by-product) in the CLD released into the environment. The aim of the present study was to determine if and to what extent degradation of CLD into 5b-hydroCLD occurred in the field. To test this hypothesis, the ratios of 5b-hydroCLD and CLD concentrations in a dataset of 810 soils collected between 2006 and 2012 in Martinique were compared to the ratios measured in 3 samples of the CLD dust commercial formulations applied in the banana fields of French West Indies (FWI) and 1 sample of the technical-grade CLD corresponding to the active ingredient used in such formulations. Soil data were processed with a hierarchical Bayesian model to account for random measurement errors and data censoring. Any pathway of CLD transformation into 5b-hydroCLD occurring over the long term in FWI soils would indeed change the ratio of 5b-hydroCLD/CLD compared to what it was in the initially applied formulations. Results showed a significant increase of the 5b-hydroCLD/CLD ratio in the soils-25 times greater in soil than in commercial formulations-which suggested that natural CLD transformation into 5b-hydroCLD over the long term occurred in these soils. Results from this study may impact future decisions for the remediation of the polluted areas.
ISSN: 0944-1344

hal-01347150
https://hal.archives-ouvertes.fr/hal-01347150
https://hal.archives-ouvertes.fr/hal-01347150/document
https://hal.archives-ouvertes.fr/hal-01347150/file/Devault_15973.pdf
DOI : 10.1007/s11356-015-4865-0

Éditeur(s) : HAL CCSD
Résumé : Annual report
We present here the results of CRS reprocessing of a 3D real dataset acquired in 2001 on the Tournemire site in France, which is an experimental site for the Institut de Radioprotection et de Sûreté Nucléaire (IRSN) to test geophysical imaging process in the context of geological nuclear waste storage. The main objective was to evaluate the ability of the methodology to recognize, in the carbonate cover of the experimental site clay layer, the prolongation of weak vertical-displacement faults seen in a tunnel within that clay layer. Previous seismic processing using the conventional common midpoint (CMP) approach did not provide satisfactory results in this cover, although the fault has beenrecognized in the carbonates underlying the clay layer. An original strategy was elaborated to define the best-possible parameters of the 3D Common-Reflection-Surface (CRS) stack. The procedure in- cluded refining the velocity search along a velocity guide, using a first CRS stack as the base of a subsequent curvature-parameter search, or a parameter smoothing before stacking. An optimal ap- proach was elaborated on a subset of the data, and furthermore applied to the whole dataset. The resulting image shows improved event continuity in the carbonate cover, which allowed for horizon picking after depth migration, as well as the estimation of post-stack geometrical attributes, such as coherency. The processing indicates a zone of degraded quality of reflection events lying in the N-S direction, above the known fault zone within the underlying formations. Such feature corresponds to an alteration zone at the earth surface. Further investigation at a higher resolution scale is planned to confirm whether this zone could be a spot of possible leakage
https://hal.archives-ouvertes.fr/hal-00857376

hal-00857376
https://hal.archives-ouvertes.fr/hal-00857376

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The present work is concerned with the study of the tribological properties of various fluorinated carbon phases obtained at room temperature and then post-treated under fluorine atmosphere at different temperatures. The tribological tests evidence good intrinsic properties for all the compounds (friction coefficient in the range 0.07-0.09). Differences appear after few cycles. Friction measurements after 100 cycles and complementary Raman analyses of the tribofilm remaining in the wear scar point out that long term tribologic properties of the fluorinated compounds strongly depend on the evolution undergone by the materials under friction. The release of HF molecules, the loss of fluorine and partial rebuilding of graphitic phases are at the origin of the degradation of the friction properties. The good properties of the compounds post-treated at temperature in the range 150-300 °C are attributed to the chemical and structural stability of these compounds under friction.
ISSN: 0022-3697

hal-00756133
https://hal.archives-ouvertes.fr/hal-00756133
https://hal.archives-ouvertes.fr/hal-00756133/document
https://hal.archives-ouvertes.fr/hal-00756133/file/Delbe_6346.pdf
DOI : 10.1016/j.jpcs.2006.01.084

Éditeur(s) : HAL CCSD Montpellier : CIRAD
Résumé :  
Afin d'assurer l'aménagement durable de la Guyane, il convient de mettre en place une surveillance du territoire. En effet, dans la forêt tropicale humide qui couvre 96 % de la superficie de ce département et s'avère difficilement accessible, beaucoup d'activités restent mal connues et certaines sont même exercées illégalement. C'est souvent le cas de l'orpaillage qui, lorsqu'il est illicite, dégrade le milieu naturel et pollue fortement les rivières, du fait de l'utilisation de techniques inadaptées et des conditions précaires inhérentes aux chantiers clandestins. La surveillance des activités d'orpaillage, légales ou illégales, est du ressort du gestionnaire forestier en charge du respect de la loi sur l'ensemble des forêts. L'Onf-Guyane a pour mission de gérer ce vaste territoire qui représente environ 7,5 millions d'hectares. Actuellement, la recrudescence des conflits provoqués par les exploitations illégales exige des moyens opérationnels de surveillance. Cet article propose une technique qui fait appel à l'imagerie satellitaire optique. Malgré l'ennuagement important de ces régions équatoriales, l'imagerie satellitaire est fiable. L'obtention régulière d'informations constitue un atout pour la gestion du territoire guyanais.
ISSN: 0006-579X

hal-01032180
https://hal.archives-ouvertes.fr/hal-01032180