Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
Progress in seismic methodology and ambitious large-scale seismic projects are enabling high-resolution imaging of the continental crust. The ability to constrain interpretations of crustal seismic data is based on laboratory measurements on rock samples and calculations of seismic properties. Seismic velocity calculations and their directional dependence are based on the rock microfabric, which consists of mineral aggregate properties including crystallographic preferred orientation (CPO), grain shape and distribution, grain boundary distribution, and misorientation within grains. Single-mineral elastic constants and density are crucial for predicting seismic velocities, preferably at conditions that span the crust. However, high-temperature and high-pressure elastic constant data are not as common as those determined at standard temperature and pressure (STP; atmospheric conditions). Continental crust has a very diverse mineral composition; however, a select number of minerals appear to dominate seismic properties because of their high-volume fraction contribution. Calculations of microfabric-based seismic properties and anisotropy are performed with averaging methods that in their simplest form takes into account the CPO and modal mineral composition, and corresponding single crystal elastic constants. More complex methods can take into account other microstructural characteristics, including the grain shape and distribution of mineral grains and cracks and pores. Dynamic or active wave propagation schemes have recently been developed, which offer a complementary method to existing static averaging methods generally based on the use of the Christoffel equation. A challenge for the geophysics and rock physics communities is the separation of intrinsic factors affecting seismic anisotropy, due to properties of crystals within a rock and apparent sources due to extrinsic factors like cracks, fractures, and alteration. This is of particular importance when trying to deduce crustal composition and the state of deformation from seismic parameters.
ISSN: 8755-1209

Droits : info:eu-repo/semantics/OpenAccess
hal-01685568
https://hal.archives-ouvertes.fr/hal-01685568
https://hal.archives-ouvertes.fr/hal-01685568/document
https://hal.archives-ouvertes.fr/hal-01685568/file/Almqvist_et_al-2017-Reviewssur Geophysics.pdf
DOI : 10.1002/2016RG000552

Éditeur(s) : HAL CCSD Wiley-Blackwell
Résumé : International audience
Although lawsonite-bearing rocks are rare in exhumed high-pressure (HP) terranes, they are considered to exert a primary role in subduction dynamics. Recent observations in natural settings have shown that fluid–rock interaction at HP conditions, including metasomatism, may lead to unusually high lawsonite amounts even in rocks that originally contained little or no lawsonite. This process may therefore bear important implications for element recycling in subduction zones. A detailed characterization of the geochemical fingerprints associated with lawsonite metasomatism is presented in this contribution. The studied rocks belong to the HP terranes of Alpine Corsica (France), which is the largest documented exposure for lawsonite metasomatism. Metasomatic lawsonite displays complex compositional zoning, including high trace element, Cr and Ti content. The trace element content is much higher compared with the average of non-metasomatic lawsonite, and is in line with the re-incorporation of large amounts of trace elements (e.g. REE, Sr, Pb, Th) in the rock during metasomatism, as shown by mass transfer calculations. Our data suggest that serpentinites represented the main fluid source for the metasomatism, with concurrent contribution of other, possibly Ca-rich lithologies, such as mafic or meta-sedimentary rocks. We propose that the breakdown of metasomatic lawsonite may contribute to the genesis of magmas and their characteristic geochemical signatures.
ISSN: 0263-4929

hal-01107395
https://hal.archives-ouvertes.fr/hal-01107395
DOI : 10.1111/jmg.12074

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : We present whole-rock major- and trace-element and Nd–Sr–Pb radiogenic isotope data for Cretaceous igneous suites from eastern Cuba. These rocks are related to the Greater Antilles paleo-island arc magmatism and have three different igneous styles. Group 1 consists of tholeiitic basalts and rare basaltic andesites that have normal mid-ocean ridge basalt (N-MORB)-like compositions similar to those found in back-arc basin basalts (TiO2 = 1·2–2·9 wt%; La/Yb(N) = 0·7–0·9, Th/Nb = 0·06–0·08, and initial 208Pb/ 204Pb = 37·65–37·74). Group 2 comprises basaltic and rare basaltic andesitic subvolcanic dykes with major- and trace-element and isotopic compositions similar to those of island arc tholeiites (TiO2 = 0·7–1·4 wt%; La/Yb(N) = 0·6–0·9, Th/Nb = 0·06–0·68, and initial 208Pb/ 204Pb = 37·74–38·25). Group 3 is composed of low-Ti (TiO2 = 0·3–0·9 wt%) calcalkaline igneous rocks that have an unambiguous subduction-related character (La/Yb(N) = 1·1–5·0, Th/Nb = 0·35–1·55, and initial 208Pb/ 204Pb = 37·94–38·39). The parental magmas of the three groups formed by variable melting degrees (< 5–25%) of spinel lherzolite, with more depleted mantle sources for Groups 2 and 3 than Group 1. The trace-element and radiogenic isotope compositions of primitive Group 3 samples are strongly bimodal. One subgroup of samples is characterized by low Ta/Yb (0·02–0·03) and Th/La (0·10–0·13), slightly subchondritic Nb/Ta (13·3–17·3), and relatively high initial 206Pb/204Pb (18·57–18·62) and {varepsilon}Nd (7·6–9·4). The remaining primitive Group 3 samples have higher Ta/Yb (0·06–0·11) and Th/La (0·24–0·32), and highly subchondritic Nb/Ta (7·6–9·1), coupled with lower initial 206Pb/204Pb (18·24–18·29) and {varepsilon}Nd (3·4–5·5). These signatures were induced by two distinct slab components that mainly reflect the contributions of Cretaceous Atlantic marine and North American continental sediments, respectively. Nb/Ta in the first subgroup was influenced by melting of rutile-bearing subducted crust, whereas in the second it was inherited from recycled continental sediments. The involvement of Atlantic and North American sediments in Cuban Cretaceous magmatism indicates that the Proto-Caribbean (North American-Proto Atlantic) lithosphere subducted beneath the Greater Antilles arc during the Late Cretaceous (pre-Campanian), consistent with geotectonic models involving onset of SW-dipping subduction beneath the Greater Antilles paleo-arc during the Aptian. The variable mantle source depletion and magnitude of the subduction component probably reflect different settings across the arc, from the arc front to a back-arc spreading ridge.
ISSN: 0022-3530

hal-00406373
https://hal.archives-ouvertes.fr/hal-00406373
DOI : 10.1093/petrology/egm040

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The In-Ezzane volcanic district (EZD), located at the triple junction of Algeria, Niger and Libya belongs to the Eastern Hoggar, covers 350 km2 and includes 9 volcanic edifices that are probably aligned along NW-SE faults, parallel to the Tafassasset valley. The low volume (0.7 and 1 km3) of emitted lavas, the similar morphology of the monogenic cones and the lack of differentiated rocks indicate that the volcanic activity of the EZD was restricted in time and volume. The new K-Ar age (i.e. 2.86 ± 0.07 Ma) indicates that the EZD is contemporaneous with the last alkali volcanism paroxysm in Hoggar and with the nearby Libyan volcanics. The EZD alkali basalts (mainly basanite) show a remarkable homogeneous compositions both in major elements (44.8 ⩽ SiO2 ⩽ 45.8 wt.%; 5.2 ⩽ (Na2O + K2O) ⩽ 6.2 wt.%), trace elements (4.3 ⩽ Th ⩽ 5.5 ppm; 34.7 ⩽ La ⩽ 44.7 ppm; 16.1 < La/Yb(N) < 21.6) and radiogenic isotopes (0.70285 < 87Sr/86Sr < 0.70303; 0.51298 < 143Nd/144Nd < 0.51301; (19.212 < 206Pb/204Pb < 19.340, 15.589 < 207Pb/204Pb < 15.602 and 38.834 < 208Pb/204Pb < 38.903). Relative to the Hoggar alkaly basalts the EZD basalts appear systematically impoverished in incompatible elements and show a depleted signature both in Sr and Nd isotopes (almost MORB-like). The Pb isotopes are relatively enriched and intermediate between tholeiites and alkali basalts of the Hoggar. This unusual geochemical signature, is uneasy to reconcile with the known characteristics of the Hoggar swell, and would rather fingerprint a circum cratonic mantle lying beneath the west border of the Murzuq craton (Libya).
ISSN: 0899-5362

hal-01054340
https://hal.archives-ouvertes.fr/hal-01054340
DOI : 10.1016/j.jafrearsci.2013.12.001

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
At Cima di Gagnone, garnet peridotite and chlorite harzburgite lenses within pelitic schists and gneisses correspond to eclogite-facies breakdown products of hydrated peridotites and are suitable for studying dehydration of serpentinized mantle. Thermobarometry and pseudosection modelling yield peak temperatures of 750-850°C and pressures <3 GPa. The minimum temperature recorded by the garnet peridotite corresponds to the maximum conditions experienced by the chlorite harzburgite, suggesting that these rocks recrystallized cofacially at ∼800°C. Alternatively, they might have decoupled during subduction, as achieved in tectonically active plate interface boundaries. The major and rare earth element (REE) variability of the peridotites was mostly acquired during pre-subduction mantle evolution as a result of partial melting and reactive melt flow. The ultramafic suite is also characterized by fluid-mobile element enrichments (B, Pb, As, Sb, Cs, Li, U, Be), which confirm derivation from variably serpentinized protoliths. Similarity in the U, Pb, B, Li and Sr contents of the Gagnone peridotites to present-day oceanic serpentinites suggests that these elements were partly taken up during initial serpentinization by seawater-derived fluids. Positive Be, As and Sb anomalies suggest involvement of fluids equilibrated with crustal (metasedimentary) reservoirs during subsequent subduction metamorphism and peridotite entrainment in (meta)sediments. Fluid-mobile element enrichment characterizes all peak eclogitic minerals, implying that multiple hydration events and element influx pre-dated the eclogite-facies dehydration. Peak anhydrous minerals retain B, Li, As and Sb concentrations exceeding primitive mantle values and may introduce geochemical anomalies into the Earth's mantle. The relatively low contents of large ion lithophile elements and light REE in the Gagnone peridotites with respect to much higher enrichments shown by metasomatized garnet peridotite pods hosted in migmatites (Ulten Zone, Eastern Alps) suggest that the crustal rocks at Gagnone did not experience partial melting. The Gagnone garnet peridotite, despite showing evidence for chlorite dehydration, retains significant amounts of fluid-mobile elements documenting that no partial melting occurred upon chlorite breakdown. We propose that the Gagnone ultramafic rocks represent a prime example of multi-stage peridotite hydration and subsequent dehydration in a plate interface setting.
ISSN: 0022-3530

hal-01054319
https://hal.archives-ouvertes.fr/hal-01054319
DOI : 10.1093/petrology/egt068

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Talc is a hydrous magnesium rich layered silicate that is widely disseminated in the Earth from the seafloor to over 100 km depth, in ultra-high pressure metamorphism of oceanic crust. In this paper we determine the single crystal elastic constants at pressures from 0 to 12 GPa of talc triclinic (C 1¯) and monoclinic (C2/c) polytypes using ab initio methods. We find that talc has an extraordinarily high elastic anisotropy at zero pressure that reduces with increasing pressure. The exceptional anisotropy is complemented by a negative Poisson's ratio for many directions in crystal space. Calculations show that talc is not only one of very few common minerals to exhibit auxetic behaviour, but the magnitude of this effect may be the largest reported so far for a mineral. The compression (Vp) and shear (Vs) wave velocity anisotropy is 80% and 85% for the triclinic polytype. At pressures where talc is known be stable in the Earth (up to 5 GPa) the Vp and Vs anisotropy is reduced to about 40% for both velocities, which is still a very high value. Vp is slow parallel to the c-axis and fast perpendicular to it. This remains unchanged with increasing pressure and is observed in both polytypes. The shear wave splitting (difference between fast and slow S-wave velocities) at low pressure has high values in the plane normal to the c-axis, with a maximum near the alow asterisk-axis in the triclinic and the b-axis in the monoclinic polytype. The c-axis is the direction of minimum splitting. The pattern of shear wave splitting does not change significantly with pressure. The volume fraction of talc varies between 11 and 41% for hydrated mantle rocks, but the lack of data on the crystallographic preferred orientation (CPO) precludes a detailed analysis of the impact of talc on seismic anisotropy in subduction zones. However, it is highly likely that CPO can easily develop in zones of deformation due to the platy habit of talc crystals. For random aggregates of talc, the isotropic Vp, Vs and Vp/Vs ratio have significantly lower values than those of antigorite and may explain low-velocity regions in the mantle wedge. Vp/Vs ratios are more complex in anisotropic media because there are fast and slow S-waves, resulting in Vp/Vs1 and Vp/Vs2 ratios for every propagation direction, making interpretation difficult in deformed polycrystalline talc with a CPO. Talc on the subduction plate boundary can strongly influence guided wave velocity as CPO would develop in this region of intense shearing. The very low coefficient of friction (< 0.1) of talc above 100 °C could also explain silent earthquakes at shallow depths (ca 30 km) along the subduction plate boundaries, frequently responsible for tsunami.
ISSN: 0012-821X

hal-00411481
https://hal.archives-ouvertes.fr/hal-00411481
DOI : 10.1016/j.epsl.2008.07.047

Éditeur(s) : HAL CCSD
Résumé : International audience
The geology of the North Pyrenean Zone in the central Pyrenees allows for the observation in the field of theentire section of the Pyrenean rift, from the mantle to the crust and the Mesozoic cover (pre, syn and post rift).The good knowledge we have of the pre-Alpine history of the Pyrenees allows us to properly constrain the Alpinegeological evolution of the pre-Triassic rocks which record both Variscan and Alpine orogenic cycles.The mantle outcrop as kilometric to centimetric fragments of peridotite dispersed within a carbonate metamorphicbreccia. The study of peridotite serpentinisation shows several events of low-temperature serpentinisation, incontact with seawater. In some locallities, we can observe a mixture of fragments of variously serpentinizedperidotites. This suggests a tectonic context where fragments of peridotites from different structural levels weresampled more or less synchronously.The granulitic basement is characterized by a Variscan syndeformational HT event (300-280 Ma). So farwe have not found any trace of a Cretaceous HT event (> 500C). On the other hand, the basement is affectedby a regional metasomatism that began during the Jurassic and became more spatially focused with time until itwas restricted to the Pyrenean rift during the Aptien, Albian and Cenomanian. The talc-chlorite metasomatism(120-95 Ma) shows an evolution from a static toward a syn-deformation hydrothermal event, under a more or lessnormal geothermal gradient. Extensional deformation is recorded by the reworking of several inherited low-angleVariscan tectonic contacts, but also by dispersed high-angle extensional shear zones formed under greenshistconditions.The metamorphic Mesozoic cover of the basement massifs, which constitute the so-called Internal MetamorphicZone, is an allochtonous unit made of lenses of Mesozoic rocks enclosed into the breccia, whichlocally contains peridotite and basement clasts. The Mesozoic metamorphic carbonates show a first phase ofsyn-metamorphic (450-600C, P < 2 kb) ductile deformation, and subsequent phases of folding and fracturing.The datation of neoformed minerals give a 108-85 Ma time span for the metamorphism. We interpret this brecciaas an abandonment breccia which marks the emergence of the main detachment. The basal contact of the Mesozoiccover has a complex 3D geometry traced by Triassic evaporites. It corresponds to a major pre- and synorogenicpolyphased tectonic contact.All these data show a geometrically complex hyper-extended rift where the crust was not stretched under ahigh geothermal gradient but thinned by the tectonic extraction of relatively thin lenses and perhaps cut by highangle low-grade shear zones. The 3D geometry, as well as the strain records and the breccia lithologies stronglysuggest a non-cylindricity for the exhumation process, probably within a transtentional system
Geophysical Research Abstracts
Vienne, Austria

insu-01510371
https://hal-insu.archives-ouvertes.fr/insu-01510371

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Rainbow is a dome-shaped massif at the 36°14′N nontransform offset along the Mid-Atlantic Ridge. It hosts three ultramafic-hosted hydrothermal sites: Rainbow is active and high temperature; Clamstone and Ghost City are fossil and low temperature. The MoMARDREAM cruises (2007, 2008) presented here provided extensive rock sampling throughout the massif that constrains the geological setting of hydrothermal activity. The lithology is heterogeneous with abundant serpentinites surrounding gabbros, troctolites, chromitites, plagiogranites, and basalts. We propose that a W dipping detachment fault, now inactive, uplifted the massif and exhumed these deep-seated rocks. Present-day deformation is accommodated by SSW-NNE faults and fissures, consistent with oblique teleseismic focal mechanisms and stress rotation across the discontinuity. Faults localize fluid flow and control the location of fossil and active hydrothermal fields that appear to be ephemeral and lacking in spatiotemporal progression. Markers of high-temperature hydrothermal activity (∼350°C) are restricted to some samples from the active field while a more diffuse, lower temperature hydrothermal activity (<220°C) is inferred at various locations through anomalously high As, Sb, and Pb contents, attributed to element incorporation in serpentines or microscale-sulfide precipitation. Petrographic and geochemical analyses show that the dominant basement alteration is pervasive peridotite serpentinization at ∼160–260°C, attributed to fluids chemically similar to those venting at Rainbow, and controlled by concomitant alteration of mafic-ultramafic units at depth. Rainbow provides a model for fluid circulation, possibly applicable to hydrothermalism at oceanic detachments elsewhere, where both low-temperature serpentinization and magmatic-driven high-temperature outflow develop contemporaneously, channeled by faults in the footwall and not along the detachment fault.
ISSN: 1525-2027

hal-01115281
https://hal.archives-ouvertes.fr/hal-01115281
https://hal.archives-ouvertes.fr/hal-01115281/document
https://hal.archives-ouvertes.fr/hal-01115281/file/Andreani_et_al-2014-Geochemistry%2C_Geophysics%2C_Geosystems.pdf
DOI : 10.1002/2014GC005269

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Kimberlites of the Udachnaya-East pipe (Siberia) include a uniquely dry and serpentine-free rock type with anomalously high contents of chlorine (Cl ≤ 6.1 wt%), alkalies (Na2O + K2O ≤ 10 wt%) and sulfur (S ≤ 0.50 wt%), referred to as a “salty” kimberlite. The straightforward interpretation is that the Na-, K-, Cl- and S-rich components originate directly from a carbonate-chloride kimberlitic magma that is anhydrous and alkali-rich. However, because brines and evaporites are present on the Siberian craton, previous studies proposed that the kimberlitic magma was contaminated by the assimilation of salt-rich crustal rocks. To clarify the origin of high Cl, alkalies and S in this unusual kimberlite, here we determine its sulfur speciation and isotopic composition and compare it to that of non-salty kimberlites and kimberlitic breccia from the same pipe, as well as potential contamination sources (hydrothermal sulfides and sulfates, country-rock sediment and brine collected in the area). The average δ34S of sulfides is − 1.4 ± 2.2‰ in the salty kimberlite, 2.1 ± 2.7‰ in the non-salty kimberlites and 14.2 ± 5.8‰ in the breccia. The average δ34S of sulfates in the salty kimberlites is 11.1 ± 1.8‰ and 27.3 ± 1.6‰ in the breccia. In contrast, the δ34S of potential contaminants range from 20 to 42‰ for hydrothermal sulfides, from 16 to 34‰ for hydrothermal sulfates, 34‰ for a country-rock sediment (Chukuck suite) and the regional brine aquifer. Our isotope analyses show that (1) in the salty kimberlites, neither sulfates nor sulfides can be simply explained by brine infiltration, hydrothermal alteration or the assimilation of known salt-rich country rocks and instead, we propose that they are late magmatic phases; (2) in the non-salty kimberlite and breccia, brine infiltration lead to sulfate reduction and the formation of secondary sulfides – this explains the removal of salts, alkali-carbonates and sulfates, as well as the minor olivine serpentinization; (3) hydrothermal sulfur was added to the kimberlitic breccia, but not to the massive kimberlites. In situ measurements of sulfides confirm this scenario, clearly showing the addition of two sulfide populations in the breccia (pyrite-pyrrhotites with average δ34S of 7.9 ± 3.4‰ and chalcopyrites with average δ34S of 38.0 ± 0.4‰) whereas the salty and non-salty kimberlites preserve a unique population of djerfisherites (Cl- and K-rich sulfides) with δ34S values within the mantle range. This study provides the first direct evidence of alkaline igneous rocks in which magmatic sulfate is more abundant than sulfide. Although sulfates have been rarely reported in mantle materials, sulfate-rich melts may be more common in the mantle than previously thought and could balance the sulfur isotope budget of Earth's mantle.
ISSN: 0009-2541

hal-01571982
https://hal.archives-ouvertes.fr/hal-01571982
DOI : 10.1016/j.chemgeo.2016.10.037

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
We analyse P-wave receiver functions across the western Gulf of Aden and southern Red Sea continental margins in Western Yemen to constrain crustal thickness, internal crustal structure and the bulk seismic velocity characteristics in order to address the role of magmatism, faulting and mechanical crustal thinning during continental breakup. We analyse teleseismic data from 21 stations forming the temporary Young Conjugate Margins Laboratory (YOCMAL) network together with GFZ and Yemeni permanent stations. Analysis of computed receiver functions shows that (1) the thickness of unextended crust on the Yemen plateau is ∼35km; (2) this thins to ∼22km in coastal areas and reaches less than 14km on the Red Sea coast, where presence of a high-velocity lower crust is evident. The average Vp/Vs ratio for the western Yemen Plateau is 1.79, increasing to ∼1.92 near the Red Sea coast and decreasing to 1.68 for those stations located on or near the granitic rocks. Thinning of the crust, and by inference extension, occurs over a ∼130-km-wide transition zone from the Red Sea and Gulf of Aden coasts to the edges of the Yemen plateau. Thinning of continental crust is particularly localized in a <30-km-wide zone near the coastline, spatially co-incident with addition of magmatic underplate to the lower crust, above which on the surface we observe the presence of seaward dipping reflectors (SDRs) and thickened Oligo-Miocene syn-rift basaltic flows. Our results strongly suggest the presence of high-velocity mafic intrusions in the lower crust, which are likely either synrift magmatic intrusion into continental lower crust or alternatively depleted upper mantle underplated to the base of the crust during the eruption of the SDRs. Our results also point towards a regional breakup history in which the onset of rifting was synchronous along the western Gulf of Aden and southern Red Sea volcanic margins followed by a second phase of extension along the Red Sea margin.
ISSN: 0956-540X

hal-00825194
https://hal.archives-ouvertes.fr/hal-00825194
https://hal.archives-ouvertes.fr/hal-00825194/document
https://hal.archives-ouvertes.fr/hal-00825194/file/RF_Hakim2012_GJI.pdf
DOI : 10.1093/gji/ggt072

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Miocene (17-11 Ma) magmatic activity in the Kabylies emplaced K-rich (and minor medium-K) calc-alkaline plutonic and volcanic rocks in five zones, delineating a ∼450 km long EW trending strip located along the northern coast of Algeria, between Annaba and Algiers. Their most likely source is the Kabylian subcontinental lithospheric mantle previously metasomatized during the Paleogene subduction of the Tethys oceanic lithosphere. Our preferred tectono-magmatic model involves a Tethyan slab detachment combined with African mantle delamination and crustal stacking, leading to the superimposition of the African continental crust over the Kabylian metasomatized lithospheric mantle. At ca. 17 Ma, the asthenospheric upwelling arising from lithospheric delamination and Tethyan slab tear triggered the thermal erosion of the latter mantle, inducing its partial melting. The corresponding mafic medium-K calc-alkaline magmas interacted with the African basement units during their ascent, generating intermediate to felsic K-rich calc-alkaline melts that display a characteristic trace element and isotopic crustal signature. Later on, slab tears propagated eastward and westward, promoting slab rollback perpendicular to plate convergence and inducing the emplacement of magmatic rocks of decreasing ages from central-eastern Algeria towards Tunisia and Morocco.
ISSN: 0899-5362

hal-01467997
https://hal.archives-ouvertes.fr/hal-01467997
DOI : 10.1016/j.jafrearsci.2016.10.005

Éditeur(s) : HAL CCSD Geological Society of London
Résumé : The Borborema and Benin–Nigeria provinces of NE Brazil and NW Africa, respectively, are key areas in the amalgamation of West Gondwana by continental collision during the Brasiliano/Pan-African orogenies. Both are underlain by complex basement: Nigeria has c. 3.05 Ga Archaean crust but no known Palaeoproterozoic rocks >2.0 Ga; in NE Brazil, 2.6–3.5 Ga Archaean rocks form small cores within Palaeoproterozoic gneiss terrains affected by plutonism at c. 2.17 Ga. Both regions exhibit Late Palaeoproterozoic (c. 1.8 Ga) rift-related magmatism and metasedimentary sequences overlying the basement. The Seridó Group of NE Brazil (<0.65 Ga) is similar to the Igarra Sequence in SW Nigeria. The Ceará Group, which may date back to c. 0.85 Ga, is a passive margin deposit on crust thinned during initiation of an oceanic domain. In both provinces, basement and sedimentary cover were involved in tangential tectonics that resulted in crust-thickening by nappe-stacking associated with closure of this ocean. Frontal collision between c. 0.66 and 0.60 Ga later evolved to an oblique collision, generating north–south continental strike-slip shear zones at c. 0.59 Ga. In NE Brazil, the main Pan-African suture is probably buried beneath the Parnaíba Basin. The Transbrasiliano Lineament, interpreted as the prolongation of the Kandi–4°50 Lineament in Hoggar, may represent a cryptic suture.
West Gondwana: Pre-cenozoic correlations across the south atlantic region

hal-00412234
https://hal.archives-ouvertes.fr/hal-00412234
DOI : 10.1144/SP294.4

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report gabbroic dikes in the plagioclase tectonite domains of the Ojén and Ronda massifs (Betic Cordillera, southern Spain), which record crystallization at low-pressure syn-, or slightly postkinematic to the late ductile history of the Betic Peridotite in the westernmost Mediterranean. We present mineral major and trace element compositional data of discordant gabbroic dikes in the Ojén massif and gabbroic patches in the Ronda massif, complemented by the whole rock and electron backscattered diffraction (EBSD) data of the Ojén occurrence. In the Ojén massif, gabbro occurs as 1–3 centimeter wide discordant dikes that crosscut the plagioclase tectonite foliation at high angle. These dikes are composed of cm-scale igneous plagioclase and clinopyroxene crystals that show shape preferred orientations subparallel to the lineation of the host peridotite and oblique to the trend of the dike. Intrusion of Ojén gabbro dikes is coherent with the stress field that formed the high temperature, ductile plagioclase tectonite foliation and then attests for a mantle igneous event prior to the intracrustal emplacement of the massif. In the Ronda massif, gabbroic rocks crystallized in subcentimeter wide anastomozing veins, or as interstitial patches in the host dunite. They are mostly composed of plagioclase and clinopyroxene. Plagioclase composition is bytownitic in the Ojén, and andesinic in the Ronda massif. Clinopyroxene in both places shows identical, light Rare-Earth Element (LREE) depleted trace element patterns. The calculated trace element composition of melts in exchange equilibrium with the studied igneous clinopyroxenes reflects LREE-enriched character coupled with negative Eu anomaly, and indicates that gabbro-forming melts in Ronda and Ojén share a common melt source with an island arc tholeiitic affinity. Geothermobarometric data and liquidus mineralogy indicate that gabbro crystallization occurred at shallow depths (0.2–0.5 GPa) in a 7–16 km thick lithospheric section. These data suggest that gabbro-forming melts in the Betic Peridotite record a mantle igneous event at very shallow depths and provide evidence for the hyperextension of the continental lithosphere compatible with extreme backarc basin extension induced by the slab rollback of the Cenozoic subduction system in the westernmost Mediterranean.
ISSN: 0040-1951

hal-01172246
https://hal.archives-ouvertes.fr/hal-01172246
DOI : 10.1016/j.tecto.2015.03.011

Éditeur(s) : HAL CCSD
Résumé : In order to minimize CO2 atmospheric concentration, a solution consists in sequestrating CO2 in geological reservoirs. To estimate long term risks, it is necessary to quantify the couplings between reaction processes as well as structural and hydrodynamical modifications. We realised two experimental benches enabling injecting CO2-enriched-brine in conditions corresponding to in situ storage (T < 200 oC and P < 200 bar) and developed
an experimental protocol using X-Ray microtomography and fluid and rock analyses in order to measure the variations of physical and chemical parameters.
The study of carbonated reservoirs near the injection well, allows quantifying different k-phi relationships depending on the dissolution processes and triggered by the local fluid chemical composition and initials conditions. Away from the injection well, we observe carbonate precipitation decreasing the permeability. The study of fracturated caprock samples shows that alternative percolation of CO2-enriched-brine and CO2 gas increases the fracture permeability.
The study of silicated rocks indicates carbonate precipitation in zeolite sandstone and sintered dunite grains. Nevertheless, in zeolite sandstone we also observe the precipitation of clay particles located in the uid pathways which decrease strongly the permeability.
Afin de minimiser la concentration en CO2 dans l'atmosphère une solution consiste à le séquestrer dans les réservoirs géologiques. Pour évaluer les risques à long terme, il est nécessaire de quantifier les couplages entre les processus réactionnels et les modifications structurales et hydrodynamiques. Dans cette optique, nous avons construit deux dispositifs expérimentaux permettant d'injecter des saumures chargées en CO2 dans les conditions de stockage (T < 200 °C et P < 200 bar) et mis en oeuvre un protocole expérimental utilisant la microtomographie RX et l'analyse des roches et des fuides pour quantifier les variations des paramètres physiques et chimiques. Dans le cas des réservoirs carbonatés, on observe, près du puits d'injection, une forte variabilité des relations k-phi en fonction du régime de dissolution contrôlé par la chimie locale du fluide, ainsi que par les conditions initiales. A plus grande distance, on observe des processus de précipitation diminuant fortement la perméabilité. L'étude des roches de couverture fracturées (argilite) a montré qu'une percolation alternée d'une saumure chargée en CO2 et de CO2 gaz augmentait la perméabilité de fracture. Dans le cas des roches silicatées, la précipitation de carbonates est mise en évidence aussi bien dans les grès à zéolites que dans les frittés de dunite de San Carlos. Cependant, dans les grès à zéolites, la précipitation d'une phase argileuse est observée dans les chemins d'écoulement et engendre une forte diminution de la perméabilité.
https://tel.archives-ouvertes.fr/tel-00416408

tel-00416408
https://tel.archives-ouvertes.fr/tel-00416408
https://tel.archives-ouvertes.fr/tel-00416408/document
https://tel.archives-ouvertes.fr/tel-00416408/file/These_Luquot.pdf

Éditeur(s) : HAL CCSD
Résumé : Geothermal energy is considered as a green and infinite energy source at human scale. Currently, the yield of geothermal power plants is limited to temperatures of the operating fluid which 350 °C. From tectonic and volcanic activity at mid-ocean ridges, Iceland is a location where supercritical fluid extraction (T> 375 °C) can considered for the near future. Exploiting such fluids could theoretically multiply by a factor of ten the electrical power delivered by geothermal wells. Can such fluids circulate at the base of brittle oceanic crust? This work investigates the petrophysical properties of basalts in order to constrain geophysical observations in Iceland and predict the behavior of very high temperature geo-hydrothermal reservoirs. The first approach consisted in studying the physical properties of rocks that have hosted deep hydrothermal circulations at oceanic ridges. The study of these rocks at ODP Site 1256 shows that the porosity measured both in the field and in the lab is associated with amphibolite facies alteration minerals (T> 500 ° C). The second approach was to recreate in the laboratory the conditions of pressure, temperature and pore fluid pressure of high temperature to supercritical hydrothermal systems to predict the mechanical and electrical properties of basalts under these conditions. The mechanical results indicate that the brittle/ductile transition occurs at a temperature of about 550° C, where a strong permeability decrease is expected. The implementation and calibration of a new cell for measuring electrical conductivity at high temperature provide the first results for the interpretation of geophysical data. When applied to basaltic crustal conditions in Iceland, these results indicate that hydrothermal fluids could circulate, at least temporarily, in a supercritical state up to 5 km depth.
La géothermie est considérée comme une source d'énergie propre et inépuisable à échelle humaine. Actuellement, le rendement des centrales géothermiques est limité à l'exploitation de fluides de températures inférieures à 350 °C. L'association de l'activité tectonique et volcanique aux dorsales océaniques fait de l'Islande un lieu où l'extraction de fluides supercritiques (T> 375 °C) peut être envisagée. Cette exploitation pourrait multiplier par dix la puissance électrique délivrée par le système géothermal. Ces fluides peuvent-ils circuler dans la croûte océanique ? Ce travail propose de contraindre les observations géophysiques et de prédire le fonctionnement des réservoirs géo-hydrothermaux de très haute température par l'étude des propriétés physiques des basaltes. La première approche est focalisée sur l'étude de roches ayant accueilli une circulation hydrothermale par le passé. L'étude de ces roches au site ODP 1256, montre que leur porosité est associée à la présence de minéraux d'altération hydrothermale du facies amphibolite (T> 500 °C). La seconde approche a consisté à recréer, en laboratoire, les conditions des systèmes hydrothermaux, à très haute température, afin de prédire les propriétés mécaniques et électriques des basaltes dans ces conditions. Les résultats mécaniques indiquent que la transition fragile/ductile, souvent associée à une forte décroissance de perméabilité, intervient à une température d'environ 550 °C. La mise en place d'une cellule de mesure de la conductivité électrique de haute température a fourni les premiers résultats utiles à l'analyse des données géophysiques. Appliqués aux conditions de la croûte basaltique Islandaise, ces résultats indiquent que des fluides hydrothermaux pourraient circuler au moins transitoirement à l'état supercritique jusqu'à ~ 5 km de profondeur.
https://tel.archives-ouvertes.fr/tel-00591798

tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798/document
https://tel.archives-ouvertes.fr/tel-00591798/file/THESE_MV_pro.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The NW-trending Talas-Ferghana Fault (TFF) in Kyrgyzstan, Central Asia, is one of the largest intracontinental strike-slip faults in the world. It extends over a distance of more than 2000 km from southern Tourghai to western Tarim and exhibits a maximum dextral offset of ∼200 km during the late Palaeozoic to present. The history of the fault provides important insights for the understanding of the evolution of southern Central Asia but remains poorly constrained due to lack of reliable geochronological data. We present new Ar-Ar ages and structural data from the Kyrgyz West Tianshan, that elucidate the kinematic history of the TFF in the Palaeozoic and Mesozoic. 40Ar/39Ar ages on mylonitic white micas document a deformational history consisting of several episodes. A late Carboniferous age of 312 ± 4 Ma point to initiation of top-to-the-south and dextral transpressional deformation during a metamorphic overprint in Precambrian and Palaeozoic rocks along the northern compartment of the TFF. The main phase of dextral motion along the entire fault occurred in the Permian as suggested by minimum ages of 260-290 Ma obtained at two different locations in the NW and central parts of the TFF. Partial isotopic resetting occurred between 240 and 210 Ma and younger ages of <200-210 Ma are ascribed to late brittle reactivation and hydrothermal fluid flow in the Late Triassic to Early Jurassic times. The Jurassic trans-tensional phase is featured by emplacement of 195 ± 3 Ma pegmatitic dykes. The Ar-Ar mineral ages and structural data argue for a major phase of dextral shearing, affecting the entire region from the West Tianshan to Mongolia in the late Permian and leading to formation of almost equally spaced major NW-trending dextral strike-slip faults. The uniform character of this deformation indicates that the process of amalgamation in this part of the CAOB ended prior to the late Permian, and Central Asia evolved as a single coherent continental block since that time.
ISSN: 0743-9547

hal-00831326
https://hal.archives-ouvertes.fr/hal-00831326
DOI : 10.1016/j.jseaes.2013.02.012

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Major and trace element signatures and Sr-Nd-Pb isotope data for muscovite (Ms)-bearing amphibolite blocks and associated muscovite-bearing trondhjemite and quartz-muscovite rocks from the Sierra del Convento melange (eastern Cuba) indicate that Proto-Caribbean oceanic crust underwent wet partial melting processes during Mesozoic subduction and after accretion to the upper plate. Trace element normalized patterns of Ms-bearing amphibolites are enriched in light rare earth elements (LREE) and large-ion lithophile elements (LILE) and evidence variable trace element transfer from the Proto-Caribbean subducting slab to the mantle wedge. Ms-bearing trondhjemites show LREE enrichment and HREE depletion and have geochemical features similar to adakites, including SiO2>56 wt.%, high Na2O contents (5.5-9.0 wt.%) and high Sr/Y (16-644). We consider that the trondhjemites represent primary and natural melts formed by deep partial melting of the subducting slab which did not significantly react with the mantle wedge before intrusion in the subduction channel. The Ms-bearing trondhjemites show different geochemical and petrological signatures compared with the Ms-free tonalites-trondhjemites from Sierra del Convent, that are interpreted as primary slab melts. These differences support the idea that partial melting processes in the Sierra del Convento subduction channel were triggered by the infiltration of fluids derived from three distinct subducted sources: sediments, altered mid-ocean ridge basalts (MORB), and serpentinites. In this scenario, the pegmatitic quartz-muscovite rocks, which are highly enriched in LILE, probably represent the crystallization products of fluids derived by differentiation of the trondhjemitic melts.
ISSN: 0024-4937

hal-00669881
https://hal.archives-ouvertes.fr/hal-00669881
DOI : 10.1016/j.lithos.2011.07.011

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
The Tian Shan Mountains constitute central Asia's longest and highest mountain range. Understanding their Cenozoic uplift history thus bears on mountain building processes in general, and on how deformation has occurred under the influence of the India-Asia collision in particular. In order to help decipher the uplift history of the Tian Shan, we collected 970 samples for magnetostratigraphic analysis along a 4571-m-thick section at the Jingou River (Xinjiang Province, China). Stepwise alternating field and thermal demagnetization isolate a linear magnetization component that is interpreted as primary. From this component, a magnetostratigraphic column composed of 67 polarity chrons are correlated with the reference geomagnetic polarity timescale between ~1 Ma and ~23.6 Ma, with some uncertainty below ~21 Ma. This correlation places precise temporal control on the Neogene stratigraphy of the southern Junggar Basin and provides evidence for two significant stepwise increases in sediment accumulation rate at ~16–15 Ma and ~11–10 Ma. Rock magnetic parameters also undergo important changes at ~16–15 Ma and ~11–10 Ma that correlate with changes in sedimentary depositional environments. Together with previous work, we conclude that growth history of the modern Tian Shan Mountains includes two pulses of uplift and erosion at ~16–15 Ma and ~11–10 Ma. Middle to upper Tertiary rocks around the Tian Shan record very young (<~5 Ma) counterclockwise paleomagnetic rotations, on the order of 15° to 20°, which are interpreted as because of strain partitioning with a component of sinistral shear that localized rotations in the piedmont.
ISSN: 0278-7407

insu-00376345
https://hal-insu.archives-ouvertes.fr/insu-00376345
https://hal-insu.archives-ouvertes.fr/insu-00376345/document
https://hal-insu.archives-ouvertes.fr/insu-00376345/file/2007TC002137.pdf
DOI : 10.1029/2007TC002137

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The eastern part of the Cordillera Occidental of Ecuador comprises thick buoyant oceanic plateaus associated with island-arc tholeiites and subduction-related calc-alkaline series, accreted to the Ecuadorian Continental Margin from Late Cretaceous to Eocene times. One of these plateau sequences, the Guaranda Oceanic Plateau is considered as remnant of the Caribbean–Colombian Oceanic Province (CCOP) accreted to the Ecuadorian Margin in the Maastrichtien. Samples studied in this paper were taken from four cross-sections through two arc-sequences in the northern part of the Cordillera Occidental of Ecuador, dated as (Río Cala) or ascribed to (Macuchi) the Late Cretaceous and one arc-like sequence in the Chogòn-Colonche Cordillera (Las Orquídeas). These three island-arcs can clearly be identified and rest conformably on the CCOP. In all four localities, basalts with abundant large clinopyroxene phenocrysts can be found, mimicking a picritic or ankaramitic facies. This mineralogical particularity, although not uncommon in island arc lavas, hints at a contribution of the CCOP in the genesis of these island arc rocks. The complete petrological and geochemical study of these rocks reveals that some have a primitive island-arc nature (MgO values range from 6 to 11 wt.%). Studied samples display marked Nb, Ta and Ti negative anomalies relative to the adjacent elements in the spidergrams characteristic of subduction-related magmatism. These rocks are LREE-enriched and their clinopyroxenes show a tholeiitic affinity (FeOT–TiO2 enrichment and CaO depletion from core to rim within a single crystal). The four sampled cross-sections through the island-arc sequences display homogeneous initial Nd, and Pb isotope ratios that suggest a unique mantellic source for these rocks resulting from the mixing of three components: an East-Pacific MORB end-member, an enriched pelagic sediment component, and a HIMU component carried by the CCOP. Indeed, the ankaramite and Mg-basalt sequences that form part of the Caribbean-Colombian Oceanic Plateau are radiogenically enriched in 206Pb/204Pb and 207Pb/204Pb and contain a HIMU component similar to that observed in the Gorgona basalts and Galápagos lavas. The subduction zone that generated the Late Cretaceous arcs occurred far from the continental margin, in an oceanic environment. This implies that no terrigenous detrital sediments interacted with the source at this period. Thus, the enriched component can only result from the melting of subducted pelagic sediments. We have thus defined the East-Pacific MORB, enriched (cherts, pelagic sediments) and HIMU components in an attempt to constrain and model the genesis of the studied island-arc magmatism, using a compilation of carefully selected isotopic data from literature according to rock age and paleogeographic location at the time of arc edification. Tripolar mixing models reveal that proportions of 12–15 wt.% of the HIMU component, 7–15 wt.% of the pelagic sediment end-member and 70–75 wt.% of an East-pacific MORB end-member are needed to explain the measured isotope ratios. These surprisingly high proportions of the HIMU/CCOP component could be explained by the young age of the oceanic plateau (5–15 Ma) during the Late Cretaceous arc emplacement. The CCOP, basement of these arc sequences, was probably still hot and easily assimilated at the island-arc lava source.
ISSN: 0895-9811

insu-00353692
https://hal-insu.archives-ouvertes.fr/insu-00353692
DOI : 10.1016/j.jsames.2008.06.003

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A large sand injectite network is very well exposed in the area of Bevons, Southeast France. The associated sandstone turbiditic channel–fill and the host marls are the Aptian–Albian rocks of the Vocontian Basin. The sand injection network is composed of dykes, sills and sedimentary laccoliths ranging in thickness from mm to pluri–m. The dykes and sills have vertical and horizontal lengths of up to and over 100 m and 1 km, respectively. Outcrop observations show that the architecture and morphology of the sand injectites in the marls is governed by the local stress field during injection, pre–existing faults, the host–rock lithology, compaction, and distance to the potential sand source(s). The main set of dykes is oriented N50–60° perpendicular to the minimum compressive stress σ3 during sand injection. Two other sets of dykes are intruded along pre–existing syn–sedimentary faults oriented N140–150° (set 2) and N90° (set 3) during the Apto–Cenomanian interval. Sills and dykes thin laterally away from their potential sand sources and thin laterally away from them. The vertical thickness variations of the dykes and wings are more complex, as thinning away from the sand sources is often compensated by thickening toward the palaeo–surface. Based on field observations and measurements, we characterized the 3D architecture of the sand injectites and showed that the injectites probably formed due to a forceful injection from an overpressured sand body sealed by low–permeability lithologies.
ISSN: 0191-8141

hal-01243488
https://hal.archives-ouvertes.fr/hal-01243488
DOI : 10.1016/j.jsg.2015.07.001