Éditeur(s) : Elsevier
Résumé : Dissolved and particulate Hg fluxes in the Lot-Garonne-Gironde fluvial-estuarine system were obtained from observation of daily discharge and suspended particulate matter (SPM) concentrations. In addition to the measurements of the total dissolved (< 0.45 gm) and particulate Hg (> 0.45 gm), called HgTD and HgTp respectively, the dissolved inorganic Hg species (HgRD) were determined monthly. Geochemical background values for HgTp in sediments and SPM were similar to crustal values and to typical concentrations in SPM of non-contaminated river systems, respectively. The Riou Mort watershed already known as the origin of important historical polymetallic (e.g., Cd, Zn) pollution was identified as an important Hg point source. In the downstream Lot River, Hg concentrations were clearly higher than those in other moderately contaminated systems. The mean relative contribution of HgRD to HgTD in the Lot River and in the Garonne River was close to 25% and 50%, respectively, and showed no correlation with water discharge or SPM concentration. Depending on the origin and nature of SPM, HgTp concentrations were correlated or not with particulate organic C (POC). Maximum HgTp concentrations were measured in samples containing low POC concentrations and were attributed to sediment resuspension. In contrast, high POC concentrations (6-17%) during algal blooms were associated with low/moderate HgTp concentrations (< 0.5 mg kg(-1)) at different sites, suggesting that Hg concentrations in fluvial phytoplankton may be limited by bioavailability of dissolved Hg and/or physiologically controlled Hg accumulation. Mercury was mostly (up to 98%) transported in the particulate phase with estimated annual Hg fluxes at the outlet of the Lot River system ranging from 35 to 530 kg a(-1) for the past decade. The minimum anthropogenic component (58-84% of total Hg fluxes) could not be explained by present Riou Mort point source contributions, suggesting important Hg release from contaminated sediment as a major source and from downstream point sources (e.g., coal-fired power plants and/or metal processing industries). HgTp concentrations and fluxes were strongly related to hydrologic variations and were clearly increased by riverbed dredging during lock construction. Therefore, the estimated Hg stocks in the Lot River sediment (5-13 tons) represent an important potential Hg source for the downstream fluvial-estuarine system.
Applied Geochemistry (0883-2927) (Elsevier), 2006-03 , Vol. 21 , N. 3 , P. 515-527

Droits : 2006 Elsevier Ltd All rights reserved
http://archimer.ifremer.fr/doc/2006/publication-1343.pdf
DOI:10.1016/j.apgeochem.2005.12.004
http://archimer.ifremer.fr/doc/00000/1343/

Éditeur(s) : Pergamon-elsevier Science Ltd
Résumé : Society's needs for a network of in situ ocean observing systems cross many areas of earth and marine science. Here we review the science themes that benefit from data supplied from ocean observatories. Understanding from existing studies is fragmented to the extent that it lacks the coherent long-term monitoring needed to address questions at the scales essential to understand climate change and improve geo-hazard early warning. Data sets from the deep sea are particularly rare with long-term data available from only a few locations worldwide. These science areas have impacts on societal health and well-being and our awareness of ocean function in a shifting climate. Substantial efforts are underway to realise a network of open-ocean observatories around European Seas that will operate over multiple decades. Some systems are already collecting high-resolution data from surface, water column, seafloor, and sub-seafloor sensors linked to shore by satellite or cable connection in real or near-real time, along with samples and other data collected in a delayed mode. We expect that such observatories will contribute to answering major ocean science questions including: How can monitoring of factors such as seismic activity, pore fluid chemistry and pressure, and gas hydrate stability improve seismic, slope failure, and tsunami warning? What aspects of physical oceanography, biogeochemical cycling, and ecosystems will be most sensitive to climatic and anthropogenic change? What are natural versus anthropogenic changes? Most fundamentally, how are marine processes that occur at differing scales related? The development of ocean observatories provides a substantial opportunity for ocean science to evolve in Europe. Here we also describe some basic attributes of network design. Observatory networks provide the means to coordinate and integrate the collection of standardised data capable of bridging measurement scales across a dispersed area in European Seas adding needed certainty to estimates of future oceanic conditions. Observatory data can be analysed along with other data such as those from satellites, drifting floats, autonomous underwater vehicles, model analysis, and the known distribution and abundances of marine fauna in order to address some of the questions posed above. Standardised methods for information management are also becoming established to ensure better accessibility and traceability of these data sets and ultimately to increase their use for societal benefit. The connection of ocean observatory effort into larger frameworks including the Global Earth Observation System of Systems (GEOSS) and the Global Monitoring of Environment and Security (GMES) is integral to its success. It is in a greater integrated framework that the full potential of the component systems will be realised. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.
Progress In Oceanography (0079-6611) (Pergamon-elsevier Science Ltd), 2011-10 , Vol. 91 , N. 1 , P. 1-33

Droits : 2011 Published by Elsevier Ltd. All rights reserved.
http://archimer.ifremer.fr/doc/00044/15557/15923.pdf
DOI:10.1016/j.pocean.2011.05.001
http://archimer.ifremer.fr/doc/00044/15557/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In this study, we report new U-Pb zircon ages and amphibole and biotite 40Ar-39Ar cooling ages for igneous and metaigneous rocks from the eastern portion of the Borborema Province (NE Brazil). We combine these results with preliminary thermobarometric estimates and existing data to place constraints on the timing and duration of the Brasiliano-Pan-African Orogeny in northeastern Brazil and on the subsequent late- to post-orogenic history. The Alcantil orthogneiss contains a complex zircon population, but the youngest concordant analyses yielded an age of 632 ± 17 Ma (2σ). These grains have low Th/U ratios (<0.1), and the age of 632 Ma is therefore interpreted as dating the metamorphic event responsible for the acquisition of the gneissic fabric. In the Caruaru biotite amphibole orthogneiss, concordant analyses provided an age of 618 ± 4 Ma (2σ), which we relate to emplacement of the protolith of the Caruaru orthogneiss. Together with available U-Pb data from the literature, the 632-600 Ma age range is regarded as dating development of a regional flat-lying foliation coeval with high-grade metamorphism (upper amphibolite facies conditions). The 586 ± 3 Ma age (2σ) of the Panelas pluton is similar to those of other granitic plutons associated with a voluminous plutonism of high-K calc-alkaline to shoshonitic nature that occurred at 590-580 Ma. This plutonism slightly predated or was synchronous with development of large strike-slip shear zones. Amphibole grains yielded 40Ar-39Ar ages ranging from 584 ± 4 Ma to about 530 Ma, suggesting that regional temperatures remained near the closing temperature of this mineral (≈500 °C) for a long time. Most 40Ar-39Ar biotite ages range from 552 to 533 Ma, but two samples yielded plateau ages of 519 ± 5 Ma and 509 ± 5 Ma. The inferred rather slow cooling of the studied region possibly reflects low rates of unroofing, allowing persistence of a protracted thermal anomaly caused by the massive injection of magmas at the end of the Neoproterozoic.
ISSN: 0895-9811

hal-00745698
https://hal.archives-ouvertes.fr/hal-00745698
DOI : 10.1016/j.jsames.2012.06.003

Éditeur(s) : HAL CCSD
Résumé : This work provides new constraints on the interactions between deformation and percolation of melt or fluids, as well as on the implications of these processes for the seismic properties of the mantle wedge. It is based on the analysis of spinel peridotites from the massif of Ronda (Spain) and two xenolith suites from active subduction zones (Kamchatka, Papua New Guinea). A coupled structural, petrological and geochemical study of these samples shows that they underwent a reactive percolation of melts or Si-rich fluids, which was synchronous to a deformation event occurring under high temperature and low stress conditions, consistent with the PT conditions at the base of the lithosphere or in the asthenosphere. This reactive percolation is responsible for enrichment in pyroxenes, mainly orthopyroxene, which is often localized in bands parallel to the high-temperature foliation. This enrichment is associated with grain size reduction and dispersion of the crystallographic orientation of olivine. The dominant slip system in olivine is {0kl}[100], which results in fast S-wave polarization parallel to the flow direction in the mantle. The decrease in the intensity of the olivine crystal preferred orientations associated with the enrichment in pyroxene results in significant decrease of the anisotropy that may induce an underestimation of the thickness of the anisotropic layer by up to 33%. The observed orthopyroxene enrichment also lowers the Vp/Vs ratio, but cannot explain Vp/Vs < 1.7 mapped locally in the fore-arc mantle in Japan and the Andes. Such low Vp/Vs ratios may however be explained by considering the intrinsic anisotropy of the peridotites, which is generally ignored in large-scale Vp/Vs ratio mapping of the mantle wedge. Infrared analyses show that olivine from the both xenolith collections contains less water than the theoretical saturation calculated for their estimated equilibrium temperature in the spinel stability field. These low water content are similar to those observed in spinel peridotites from other subduction zones and probably record both the low solubility of water in olivine at relatively low pressure and dehydration during exhumation of the xenoliths. These measured water contents as well as theoretical saturation estimations are not sufficient to change the dominant slip direction of in olivine from [100] to [001].
Ce travail apporte de nouvelles contraintes sur les interactions entre déformation et processus d'hydratation et de percolation de magma ou de fluides dans le manteau à l'aplomb d'une zone de subduction et leurs implications sur les propriétés sismiques dans le coin mantellique. Il se base sur l'analyse de péridotites à spinelle provenant du massif de Ronda (Espagne) et deux séries de xénolites issues de zones de subduction actives (Kamchatka, Papouasie-Nouvelle-Guinée). L'étude structurale, pétrologique et géochimique de ces échantillons montrent qu'ils ont subit une percolation réactive de magma ou de fluide synchrone d'une déformation de haute température basse contrainte cohérente avec les condition PT de la base de la lithosphère ou de l'asthénosphère. Cette percolation réactive est responsable d'un enrichissement en pyroxènes, qui est souvent localisé dans des bandes parallèles à la foliation. Cet enrichissement est associé à une dispersion de l'orientation cristallographique de l'olivine. Les systèmes de glissement dominant dans l'olivine sont dans tous les cas {0kl}[100], ce qui implique que la direction de polarisation rapide des ondes S dans la partie supérieure du coin mantellique est parallèle à la direction d'écoulement dans le manteau. La décroissance de l'intensité des OPR de l'olivine associée à l'enrichissement en pyroxènes a pour conséquence une réduction non négligeable de l'anisotropie sismique qui peut induire jusqu'à 33% d'erreur sur l'interprétation de l'épaisseur de la couche anisotrope. Un enrichissement en orthopyroxène peut aussi entraîner une baisse du rapport Vp/Vs, mais ne peut expliquer les rapports Vp/Vs <1,7 cartés dans certains avant-arcs. Cependant de telles valeurs peuvent être expliquées si l'anisotropie des péridotites du coin mantellique est prise en compte. Les analyses par spectroscopie infra-rouge montrent que les olivines des deux séries de xénolites étudiées contiennent moins d'eau que la saturation théorique calculée pour leurs températures d'équilibre dans le domaine du spinelle. Ces faibles concentrations en eau sont similaires à celles observées dans les olivines des péridotites à spinelle des autres zones de subduction. Elles enregistrent probablement la faible solubilité de l'eau dans l'olivine à des pressions relativement basses et la déshydratation au cours de l'exhumation des xénolites. Ces teneurs en eau mesurées ainsi que les estimations de la saturation théorique ne sont pas suffisantes pour changer la direction de glissement dominante dans l'olivine de [100] à [001].
https://tel.archives-ouvertes.fr/tel-00689832

tel-00689832
https://tel.archives-ouvertes.fr/tel-00689832
https://tel.archives-ouvertes.fr/tel-00689832/document
https://tel.archives-ouvertes.fr/tel-00689832/file/These-Soustelle2010.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The formation age of the Siberian cratonic mantle is not well established as yet. Re–Os data on various mantle-derived materials have shown that it contains Archaean components, but the reported Re-depletion ages show a broad variation range (3.4 to 1 Ga) and are commonly ≤ 2 Ga for peridotite xenoliths. We report Hf and Nd isotope data for cpx and garnet separated from nine refractory spinel and garnet peridotite xenoliths from the Udachnaya kimberlite. The cpx from low-opx spinel harzburgites show extremely high εHf values, from + 607 to + 2084, which testify to long-term evolution of these rocks with high Lu/Hf ratios, consistent with their residual origin and near absence of post-melting enrichments in the Lu–Hf system. Such high εHf values are unusual for cpx from other cratonic peridotites and are higher than those reported for depleted cpx in off-cratonic peridotites. The clinopyroxenes from low-opx spinel harzburgites yield Hf model ages from 1.9 to 1.7 Ga while the cpx from high-opx spinel harzburgites yield Hf model ages from 3.0 to 1.9 Ga. When plotted together, they define a Lu/Hf isochron with an age of 1.80 Ga, which we consider as a robust estimate of the formation age (melt extraction event) because it is obtained on residual rocks that show no evidence for HREE and Hf enrichments and because the model ages for three out of four individual samples are similar to each other. The cpx have high εNd of + 94 to + 123, which are inconsistent with their low Sm/NdPM of < 1 and yield no meaningful age estimates. The consistently high, positive εNd in these cpxs can be interpreted in terms of long-term evolution of refractory peridotites with high Sm/Nd, followed by relatively recent LREE enrichments.We infer that a significant part of the lithospheric mantle in the central Siberian craton may have been formed during a major event (or a series of events) at around 1.8 Ga. Older ages reported for the central Siberian craton may refer to less common materials from cratonic or other domains formed in the Archaean that were later incorporated into the cratonic roots. The transition from the “Archaean” to “modern” tectonic regimes in Siberia and possibly elsewhere may have taken place at 1.8–1.9 Ga rather than at ~ 2.5 Ga, i.e. in the second half of the Paleoproterozoic rather than at the Archaean–Proterozoic boundary, at which time the asthenospheric mantle became generally too cold to experience high-degree melting on a large scale. The ~ 1.8 Ga formation age of the Siberian cratonic mantle is coeval with that for a major part of the ancient continental crust in the central Siberian craton. The temporal crust–mantle links may be explained either by the generation of the initial source materials for continental crust in the same melting event that formed the residual peridotites or, alternatively, by subduction and melting of pre-existing proto-lithosphere destabilized by a major mantle upwelling that formed the residual mantle.
ISSN: 0009-2541

hal-01115519
https://hal.archives-ouvertes.fr/hal-01115519
DOI : 10.1016/j.chemgeo.2014.10.018

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The Ryukyu subduction is known to generate very few earthquakes in its central segment contrarily to its two extremities. We focus in this study on the southernmost part of the Ryukyu subduction zone offshore east Taiwan. Our first task was to build a homogeneous earthquake catalogue for the period 1900–2007. The new catalogue provides homogenized M′W magnitudes and shows that several M′W≥ 7.0 earthquakes occurred offshore Hualien and Suao cities. We then focused on the 1920 June 5 earthquake (reported surface wave magnitude 8.1) previously located beneath the accretionary prism. The revised moment magnitude has been estimated in our catalogue at 7.7 ± 0.2. It is the biggest earthquake ever recorded in the Taiwan area but the fault that has produced this earthquake has not yet been identified with confidence. We relocated this event using regional phases (seismological bulletins archived at the Central Weather Bureau of Taiwan) about 50 km NNE and shallower of its former location, that is, within the Ryukyu Arc basement. According to earthquake bulletin information, revised magnitude, new hypocentral determination and known regional faults, we propose four potential active faults as candidates for the slip associated to this event: (1) the interplate seismogenic zone (ISZ), (2) an out-of-sequence thrust cutting through the forearc and branching on the ISZ, (3) a NS strike-slip fault cutting through the Ryukyu arc and (4) a N–S, westward dipping thrust fault, affecting the Philippine Sea Plate east of the Luzon Arc. The best compromise is to consider a rupture along the ISZ with a shallow nucleation possibly along a splay-fault followed by a downward and lateral propagation of the rupture that would explain the lack of significant seafloor motion and subsequent tsunami. We also estimate the maximum seismic coupling of the ISZ in the region east of Taiwan to about 0.4. In parallel, the evidences of aseismic slip occurring along the ISZ allow us to conclude that this region should only be affected by M < 8 earthquakes.
ISSN: 0956-540X

hal-00545459
https://hal.archives-ouvertes.fr/hal-00545459
https://hal.archives-ouvertes.fr/hal-00545459/document
https://hal.archives-ouvertes.fr/hal-00545459/file/theunisseGJI2010.pdf
DOI : 10.1111/j.1365-246X.2010.04813.x

Éditeur(s) : HAL CCSD
Résumé : International audience
Volumes of magma intruded in and emitted by volcanoes through time can be estimated by reconstruction of vol-cano's morphology and time sequence. Classical approaches for quantifying magma volumes on active volcanoes are based on the difference between pre-and post-eruption digital elevation models (DEM), but this kind of approach needs the pre-eruptive surfaces to be available. For old and eroded volcanoes these surfaces are poorly constrained. However, because the geometrical form of many volcanic edifices exhibits a remarkable symmetry we propose, here, a new approach using primary volcanic landforms in order to estimate the amount of the both erupted and eroded material and to locate eruptive centers. A large fraction of composite volcanoes have near constant slope on their flanks and a form that is concave upwards near their summits. But many phenomena can lead to non-symetrical edifices and complex morphologies can result, for example from parasitic centers of volcanism on the flanks, from alternation of short effusive and explosive construction phases, from flank or caldera collapses, or from glacial and other types of erosion. In this study we propose that, on the first order approximation, complex morphologies can be modeled by piling regular cones. In this model, cones centers and slopes are derived by fitting primary volcanic landform with a linear function :elevation=f(distance from center). Such an approach allows to estimate both errors on location of the eruptive center and on the volume of the resulting cones. This model can then be used for quantifying volume of erupted and eroded material, and for quantifying catastrophic events as giant landslides or flank collapse. This approach is tested on four different active volcanoes : Mount Mayon (Philippines), Mount Fuji (Japan), Mount Etna (Sicily) and Mount Teide (Canary Island) to estimate errors in volume between modeled and actual edifices. It is then used on volcanoes of La Réunion hotspot to reconstruct the Piton des Neiges and Piton de la Fournaise volcanoes at its different stages of growing.
EGU 2014
Vienna, Austria

hal-01386609
http://hal.univ-reunion.fr/hal-01386609

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Lead in homes is a well-known source of childhood lead exposure,which is still of concern due to the health effects of low lead doses. This study aims to describe lead contamination in the homes of children aged 6 months to 6 years in France (without overseas). Between October 2008 and August 2009 ,484 housing units were investigated. Lead in tap water and total and leachable lead levels from floor dust, outdoor soils and paint chips were measured. X-ray fluorescence measurements were carried out on non-metallic and metallic substrates. Nationwide results are provided. The indoor floor dust lead (PbD) geometric mean (GM) was 8.8 microg/m2 (0.8 microg/ft2) and 6.8 mmicrog/m2 (0.6 mg/ft2) for total and leachable lead respectively; 0.21% of homes had an indoor PbD loading above 430.5 microg/m2 (40 microg/ft2). The outdoor play area concentration GM was 33.5microg/kg and 21.7microgkg in total and leachable lead respectively; 1.4% of concentrations were higher than or equal to 400microg/kg. Outdoor floor PbD GM was 44.4 mg/m2 (4.1 mg/ft2) that was approximately 3.2 times higher than the GM of indoor PbD. Lead-based paint (LBP) was present in 25% of dwellings, LBP on only non-metallic substrates was present in 19% of homes and on metallic substrates in 10% of dwellings. The GM of lead concentrations in tap water was below 1 microg/L; 58% of concentrations were lower than 1 microg/L and 2.9% were higher than or equal to 10 mg/L. The age cut-off for homes with lead would be 1974 for paint and 1993 for indoor floor dust. This study provides, for the first time, a look at the state of lead contamination to which children are exposed in French housing. Moreover, it provides policy makers an estimate of the number of French dwellings sheltering children where abatement should be conducted.
Environmental Research

hal-00714516
https://hal.archives-ouvertes.fr/hal-00714516

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We report new data on the geochemical evolution, metasomatic and deformation processes in the lower layers of cratonic lithospheric mantle based on a detailed study of extraordinarily fresh and large deformed peridotite xenoliths from the Udachnaya kimberlite pipe, Siberia. Based on our T-P estimates, the deformed peridotites are localized in a depth range of 170 to 220 km near the base of cratonic mantle. The degree of deformation is not correlated with the depth and equilibration temperatures of the xenoliths. The deformed peridotites are depleted in magmaphile major elements indicating their residual nature, but are enriched in incompatible trace elements, Fe and K. The deformed peridotites experienced a complex evolution, i.e., they were formed initially as high-degree melt extraction residues and later were subjected to three main stages of metasomatic modification. (1) An old, mostly cryptic metasomatism by melt/fluid of carbonatitic composition, which formed garnets with sinusoidal REE patterns (Smn/Ern > 1). (2) Silicate metasomatism, which led to the most significant changes in mineralogical and chemical composition of the deformed peridotites. (3) Fe and Ti metasomatism just before the entrainment of the deformed rocks into kimberlite magma. Enrichment of the peridotites in large-ion lithophile elements (K, Rb, Ba) is related to the formation of kelyphitic rims around garnet. The nature of the metasomatic agent of silicate metasomatism was evaluated from mass-balance of measured and calculated whole-rock compositions, ratios of highly incompatible elements (D < 0.1) and fractional crystallization modeling. All this evidence indicates that the agent of silicate metasomatism had a composition intermediate between that of kimberlites and HIMU OIB. The metasomatic processes responsible for the formation of deformed peridotites and precipitation of megacryst suites cannot be widespread at the base of the cratonic mantle. Rather, they are local features only existing in the cratonic mantle below kimberlite fields and localized along the metasomatic vein system.
ISSN: 0024-4937

hal-00941010
https://hal.archives-ouvertes.fr/hal-00941010
DOI : 10.1016/j.lithos.2012.11.014

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The mantle above a subducting slab is the site of complex interactions between deformation, partial melting, fluid migration and magma transport. To constrain these interactions and their effects on olivine deformation, we analyze microstructures, crystal preferred orientations, and water contents of peridotite xenoliths entrained by andesites of the Avacha volcano, southern Kamchatka arc. These xenoliths are refractory spinel harzburgites that have coarse-grained microstructures with widely spaced subgrain boundaries and sinuous grain boundaries in olivine, consistent with deformation by dislocation creep under low deviatoric stress (< 13 MPa) and with a significant contribution from diffusional processes. Analysis of crystal preferred orientations (CPO) indicates dominant activation of high-temperature, low-stress {0kl}[100] slip systems in olivine and of(100)[001] in orthopyroxene. In most samples, coarse opx crystals, elongated parallel to the lineation, enclose small olivine grains in crystallographic continuity with neighbouring crystals, indicating crystallization of orthopyroxene at the expense of olivine as a result of reactive percolation of Si-rich fluids coeval with the high-temperature deformation. Secondary crystallization of interstitial orthopyroxene led locally to development of opx-rich lenses parallel to the foliation, characterized by a decrease in olivine grain size and dispersion of the olivine CPO without changing the dominant slip systems. Half of the samples also show acicular orthopyroxene aggregates with which is associated a fine-grained matrix composed of rounded strain-free olivine, orthopyroxene, spinel, and rare amphibole crystals. This matrix occurs pervasively along grain boundaries or forms millimeter-scale irregular lenses and anastomosing veinlets that crosscut the coarse crystals and their ductile deformation structures. Both acicular orthopyroxene and the fine-grained matrix are interpreted as resulting from reactive transport of H2O-rich fluids under static conditions, probably in the lithospheric mantle. Infrared analyses show that olivine contains 1-8 center dot 6 ppm by weight of water. These low water contents are similar to those observed in spinel peridotites from other subduction zones and probably record both the low solubility of water in olivine at low pressure and dehydration during exhumation of the xenoliths. Water contents in orthopyroxene are highly variable (25-506 ppm H2O), probably recording spatially heterogeneous interaction with fluids or melts and compositional disequilibrium in the studied samples. Change in the dominant percolation mechanism from porous flow to fracturing suggests cooling, consistent with the low temperatures estimated from pyroxene thermometry (< 800-900 degrees C). The Avacha xenoliths therefore record pervasive deformation of a region of the mantle under asthenospheric conditions, followed by its accretion to the base of the lithosphere, probably as a result of cooling of the mantle wedge. Percolation of Si-rich fluids or hydrous melts is recorded at all stages; this probably enhanced diffusion and lowered deviatoric stresses during ductile deformation, but did not change the dominant slip direction in olivine from [100] to [001].
ISSN: 0022-3530

hal-00456053
https://hal.archives-ouvertes.fr/hal-00456053
DOI : 10.1093/petrology/egp085

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : We present a preliminary probabilistic tsunami hazard assessment of Canadian coastlines from local and far-field, earthquake, and large submarine landslide sources. Analyses involve published historical, palaeotsunami and palaeoseismic data, modelling, and empirical relations between fault area, earthquake magnitude, and tsunami run-up. The cumulative estimated tsunami hazard for potentially damaging run-up (≥1.5 m) of the outer Pacific coastline is ~40-80 % in 50 years, respectively one and two orders of magnitude greater than the outer Atlantic (~1-15 %) and the Arctic (<1 %). For larger run-up with significant damage potential (≥3 m), Pacific hazard is ~10-30 % in 50 years, again much larger than both the Atlantic (~1-5 %) and Arctic (<1 %). For outer Pacific coastlines, the ≥1.5 m run-up hazard is dominated by far-field subduction zones, but the probability of run-up ≥3 m is highest for local megathrust sources, particularly the Cascadia subduction zone; thrust sources further north are also significant, as illustrated by the 2012 Haida Gwaii event. For Juan de Fuca and Georgia Straits, the Cascadia megathrust dominates the hazard at both levels. Tsunami hazard on the Atlantic coastline is dominated by poorly constrained far-field subduction sources; a lesser hazard is posed by near-field continental slope failures similar to the 1929 Grand Banks event. Tsunami hazard on the Arctic coastline is poorly constrained, but is likely dominated by continental slope failures; a hypothetical earthquake source beneath the Mackenzie delta requires further study. We highlight areas susceptible to locally damaging landslide-generated tsunamis, but do not quantify the hazard.
ISSN: 0921-030X

hal-00963614
https://hal.archives-ouvertes.fr/hal-00963614
DOI : 10.1007/s11069-013-0809-5

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
The Ama Drime range located at the transition between the high Himalayan range and south Tibet is a N-S active horst that offsets the South Tibetan Detachment System (STDS). Within the horst, a paragneissic unit, possibly attributed to the upper Himalayan crystalline series, overly the lower Himalayan crystalline series Ama Drime orthogneissic unit containing large metabasite layers and pods that have experienced pressure >= 1.4 GPa. Combining structural analysis with new and published pressure-temperature (P-T) estimates as well as U-Th/Pb, Ar-39/Ar-40 and (U-Th)/He ages, the P-T-deformation-time (P-T-D-t) paths of the main units within and on both sides of the horst are reconstructed. They imply that N-S normal faults initiated prior to 11 Ma and have accounted for a total exhumation <= 0.6 GPa (22 km) that probably occurred in two phases: the first one until similar to 9 Ma and the second one since 6 to 4 Ma at a rate of similar to 1 mm/yr. In the Ama Drime unit, 1 to 1.3 GPa (37 to 48 km) of exhumation occurred after partial melting since similar to 30 Ma until similar to 13 Ma, above the Main Central Trust (MCT) and below the STDS when these two fault systems were active together. The switch from E-W (STDS) to N-S (Ama Drime horst) normal faulting between 13 and 12 Ma occurs at the time of propagation of thrusting from the MCT to the Main Boundary Thrust. These data are in favor of a wedge extrusion or thrust system rather than a crustal flow model for the building of the Himalaya. We propose that the kinematics of south Tibet Cenozoic extension phases is fundamentally driven by the direction and rate of India underthrusting.
ISSN: 0278-7407

hal-00486405
https://hal.archives-ouvertes.fr/hal-00486405
DOI : 10.1029/2009TC002551

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Transmission electron microscopy observations on olivine crystals deformed at moderate (≤1273 K) temperature evidenced dislocations interactions explaining the hardening observed in the experiments, but also recovery mechanisms by the absorption or emission of point defects. Thus we investigate the possibility that, at geological strain-rates, these recovery processes allow steady-state deformation by dislocation creep at low to moderate temperatures in the lithospheric mantle. We test this hypothesis using a 2.5-D dislocation dynamics (DD) model, which combines dislocation glide and recovery by climb. This model shows that diffusion-controlled recovery processes allow for steady-state deformation by dislocation creep in the lithospheric mantle at stresses <500 MPa. For stresses of 50–200 MPa, steady-state strain-rates of 10−15 s−110−15 s−1 may be attained at temperatures as low as 900 K. Fitting of the DD model produces a flow law, which represents a lower bound for the lithospheric mantle strength, since the models describe the deformation of an olivine single crystal in an easy slip orientation. Comparison of strain-rates and Moho temperatures inferred for different geodynamic environments and the predictions of this model-based flow law implies, nevertheless, that, except in incipient rifts, most of the observed deformation may be produced by stress levels ≤200 MPa, consistent with those inferred to be produced by convection. This convergence suggests that the present models, which explicitly calculate the time-dependent dislocation dynamics, may provide a correct first order estimate of the mechanical behaviour of the lithospheric mantle, which cannot be derived directly from any existing data.
ISSN: 0012-821X

hal-01277178
https://hal.archives-ouvertes.fr/hal-01277178
https://hal.archives-ouvertes.fr/hal-01277178/document
https://hal.archives-ouvertes.fr/hal-01277178/file/Boioli.pdf
DOI : 10.1016/j.epsl.2015.10.012

Éditeur(s) : HAL CCSD Société géologique de France
Résumé : Rock foundations of the Kephren and Kheops pyramids are examined in comparison with other Fourth Dynasty monuments: the Sphinx, Queen Kentkawes' monument and the Abu Rawash monument. This study is based on geological and topographical observations, photomontages and field measurements. The results, which are correlated with those of former studies, demonstrate the existence of natural hills used as substrata in the construction of the two great pyramids. The minimum volume of these hills can be estimated at 12% and 23% respectively of the volumes of the Kephren and Kheops pyramids. The use of worked rock hills appears to be a construction method under the Fourth Dynasty.
EISSN: 1777-5817

hal-00512644
https://hal.archives-ouvertes.fr/hal-00512644

Éditeur(s) : HAL CCSD
Résumé : While often criticized, independence remains the ultimate criterion for evaluating board composition, whether for regulators or shareholder activists. In this study, we examine the relationship between board independence and firm operating performance in a panel of French listed companies, paying particular attention to heterogeneity and endogeneity concerns. We take advantage of an original database, with a time-series dimension that can be used to mitigate heterogeneity and dynamic endogeneity issues through GMM estimators. In addition, this database can be disaggregated at the individual (director) level. This design enables us to introduce firm fixed effects and individual fixed effects in (firm) performance equations, thereby controlling for heterogeneity at the firm and individual levels. To our knowledge, this is the first paper so far to provide a systematic account on this issue for France. Our main result is to document a significant negative relationship between accounting performance and the independence status (irrespective of the person). This result supports the argument of an information gap suffered by independent board members, as developed by Adams and Ferreira (2007).
https://hal.archives-ouvertes.fr/hal-00919408

hal-00919408
https://hal.archives-ouvertes.fr/hal-00919408
https://hal.archives-ouvertes.fr/hal-00919408v2/document
https://hal.archives-ouvertes.fr/hal-00919408/file/cahier_de_recherche_2014-01.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Background: Blood Lead Levels (BLLs) have substantially decreased in recent decades in children in France. However, further reducing exposure is a public health goal because there is no clear toxicological threshold. The identification of the environmental determinants of BLLs as well as risk factors associated with high BLLs is important to update prevention strategies. We aimed to estimate the contribution of environmental sources of lead to different BLLs in children in France.Methods: We enrolled 484 children aged from 6 months to 6 years, in a nationwide cross-sectional survey in 2008-2009. We measured lead concentrations in blood and environmental samples (water, soils, household settled dusts, paints, cosmetics and traditional cookware). We performed two models: a multivariate generalized additive model on the geometric mean (GM), and a quantile regression model on the 10th, 25th, 50th, 75th and 90th quantile of BLLs. Results: The GM of BLLs was 13.8 μg/L (=1.38 µg/dL) (95% Confidence Intervals (CI): 12.7-14.9) and the 90th quantile was 25.7 μg/L (CI: 24.2-29.5). Household and common area dust, tap water, interior paint, ceramic cookware, traditional cosmetics, playground soil and dust, and environmental tobacco smoke were associated with the GM of BLLs. Household dust and tap water made the largest contributions to both the GM and the 90th quantile of BLLs. The concentration of lead in dust was positively correlated with all quantiles of BLLs even at low concentrations. Lead concentrations in tap water above 5 µg/L were also positively correlated with the GM, 75th and 90th quantiles of BLLs in children drinking tap water.Conclusions: Preventative actions must target household settled dust and tap water to reduce the BLLs of children in France. The use of traditional cosmetics should be avoided whereas ceramic cookware should be limited to decorative purposes.
ISSN: 0160-4120

Droits : info:eu-repo/semantics/OpenAccess
hal-01099719
https://hal.archives-ouvertes.fr/hal-01099719
https://hal.archives-ouvertes.fr/hal-01099719/document
https://hal.archives-ouvertes.fr/hal-01099719/file/Manuscript_Etchevers_EI_V3_no%20%20changes%20marked.pdf
DOI : 10.1016/j.envint.2014.10.007

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Mass balances are often used to calculate sediment fluxes in foreland basins and denudation rates in adjacent mountain ranges on intermediate to long timescales (from a few tens of thousand to a million years). Here, we study the simple Quaternary catchment-alluvial fan system of the Kuitun River, in northern Tian Shan, to discuss some ideas about sediment storage, release, and bypass in relatively short (100 km long) sediment routing systems. This study shows that the Kuitun catchment and piedmont areas clearly present evidence of a significant and temporary storage of sediments during the Pleistocene. These sediments were then excavated and delivered farther into the foreland basin during the Holocene. The difference between the volumes of materials released from the catchment and piedmont areas (5.5 ± 1.7 km3) and the volume stored in a contemporaneous fan downstream (2.6 ± 0.6 km3) indicates that the latter did not trap the whole sediment load transported by the river. The alluvial fan was bypassed by 27 to 78% of this load toward its distal alluvial plain. If this value is well estimated, it implies a major volumetric partitioning of the deposits between the fan and the alluvial plain, with a very high sedimentation rate in the fan (1.97 ± 0.52 mm*y− 1) and a much lower one downstream (0.11 ± 0.11 mm*y− 1). However, this volumetric partitioning might only occur during periods with a very specific hydrological regime such as the Holocene deglaciation. Eventually, the peculiar sediment storage and release pattern within the Kuitun catchment and piedmont areas during the Pleistocene and Holocene complicates the calculation of mean paleodenudation rates using either sediment budgets or in situ produced cosmogenic nuclides.
ISSN: 0169-555X

insu-00985283
https://hal-insu.archives-ouvertes.fr/insu-00985283
https://hal-insu.archives-ouvertes.fr/insu-00985283/document
https://hal-insu.archives-ouvertes.fr/insu-00985283/file/jolivet-et_al-2014_HAL.pdf
DOI : 10.1016/j.geomorph.2014.01.024

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The Taleghan fault (TF) is a major active fault of the Central Alborz mountain range in Iran. Located 50 km northwestwards of Tehran, this 80-km-long fault represents one of the major structures threatening 15 million people living in the capital of Iran and the surrounding cities (e.g. Karaj). The TF could be the source of some of the strongest historical earthquakes recorded in the Tehran region, notably the 958 AD event (estimated magnitude M 7.7). To characterize the kinematics and activity of the fault, we carried out a detailed morphological and palaeoseismological study combining aerial photographs, digital elevation models and fieldwork. We show that, unliked described so far, the TF is not a reverse fault but a left-lateral strike-slip fault with a normal component. Its strike, dip and rake within its eastern part are 105, 60 and -20/-40, respectively. Our palaeoseismological analysis shows that a sequence of 2-3 events with magnitudes M-w >= 7 occurred during the past 5300 years. If we consider a three-event scenario, the average recurrence interval is similar to 2000 years, and the most recent event is younger than 80 AD. If we consider a two-event scenario, the time interval between the second and the first events ranges between 3760 and 830 years, and the elapsed time since the last event ranges between 3529 and 1599 years. Combined with morphotectonics data, our palaeoseismological analysis allows estimating a minimum horizontal slip rate of 0.6-1.6 mm yr(-1) and a minimum vertical slip rate of similar to 0.5 mm yr(-1). Taking the similar to 450-m total vertical displacement observed across the fault, we conclude that the kinematical change along the TF (from reverse to left-lateral + normal) occurred similar to 1 Ma.
ISSN: 0956-540X

hal-00420896
https://hal.archives-ouvertes.fr/hal-00420896
https://hal.archives-ouvertes.fr/hal-00420896v2/document
https://hal.archives-ouvertes.fr/hal-00420896/file/narariGJI2009.pdf
DOI : 10.1111/j.1365-246X.2009.04173.x

Éditeur(s) : HAL CCSD
Résumé : In order to minimize CO2 atmospheric concentration, a solution consists in sequestrating CO2 in geological reservoirs. To estimate long term risks, it is necessary to quantify the couplings between reaction processes as well as structural and hydrodynamical modifications. We realised two experimental benches enabling injecting CO2-enriched-brine in conditions corresponding to in situ storage (T < 200 oC and P < 200 bar) and developed
an experimental protocol using X-Ray microtomography and fluid and rock analyses in order to measure the variations of physical and chemical parameters.
The study of carbonated reservoirs near the injection well, allows quantifying different k-phi relationships depending on the dissolution processes and triggered by the local fluid chemical composition and initials conditions. Away from the injection well, we observe carbonate precipitation decreasing the permeability. The study of fracturated caprock samples shows that alternative percolation of CO2-enriched-brine and CO2 gas increases the fracture permeability.
The study of silicated rocks indicates carbonate precipitation in zeolite sandstone and sintered dunite grains. Nevertheless, in zeolite sandstone we also observe the precipitation of clay particles located in the uid pathways which decrease strongly the permeability.
Afin de minimiser la concentration en CO2 dans l'atmosphère une solution consiste à le séquestrer dans les réservoirs géologiques. Pour évaluer les risques à long terme, il est nécessaire de quantifier les couplages entre les processus réactionnels et les modifications structurales et hydrodynamiques. Dans cette optique, nous avons construit deux dispositifs expérimentaux permettant d'injecter des saumures chargées en CO2 dans les conditions de stockage (T < 200 °C et P < 200 bar) et mis en oeuvre un protocole expérimental utilisant la microtomographie RX et l'analyse des roches et des fuides pour quantifier les variations des paramètres physiques et chimiques. Dans le cas des réservoirs carbonatés, on observe, près du puits d'injection, une forte variabilité des relations k-phi en fonction du régime de dissolution contrôlé par la chimie locale du fluide, ainsi que par les conditions initiales. A plus grande distance, on observe des processus de précipitation diminuant fortement la perméabilité. L'étude des roches de couverture fracturées (argilite) a montré qu'une percolation alternée d'une saumure chargée en CO2 et de CO2 gaz augmentait la perméabilité de fracture. Dans le cas des roches silicatées, la précipitation de carbonates est mise en évidence aussi bien dans les grès à zéolites que dans les frittés de dunite de San Carlos. Cependant, dans les grès à zéolites, la précipitation d'une phase argileuse est observée dans les chemins d'écoulement et engendre une forte diminution de la perméabilité.
https://tel.archives-ouvertes.fr/tel-00416408

tel-00416408
https://tel.archives-ouvertes.fr/tel-00416408
https://tel.archives-ouvertes.fr/tel-00416408/document
https://tel.archives-ouvertes.fr/tel-00416408/file/These_Luquot.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Lead in homes is a well-known source of childhood lead exposure, which is still of concern due to the health effects of low lead doses. This study aims to describe lead contamination in the homes of children aged 6 months to 6 years in France (without overseas). Between October 2008 and August 2009, 484 housing units were investigated. Lead in tap water and total and leachable lead levels from floor dust, outdoor soils and paint chips were measured. X-ray fluorescence measurements were carried out on non-metallic and metallic substrates. Nationwide results are provided. The indoor floor dust lead (PbD) geometric mean (GM) was 8.8 μg/m² (0.8 μg/ft²) and 6.8 μg/m² (0.6 μg/ft²) for total and leachable lead respectively; 0.21% of homes had an indoor PbD loading above 430.5 μg/m² (40 μg/ft²). The outdoor play area concentration GM was 33.5 mg/kg and 21.7 mg/kg in total and leachable lead respectively; 1.4% of concentrations were higher than or equal to 400 mg/kg. Outdoor floor PbD GM was 44.4 μg/m² (4.1 μg/ft²) that was approximately 3.2 times higher than the GM of indoor PbD. Lead-based paint (LBP) was present in 25% of dwellings, LBP on only non-metallic substrates was present in 19% of homes and on metallic substrates in 10% of dwellings. The GM of lead concentrations in tap water was below 1 μg/L; 58% of concentrations were lower than 1 μg/L and 2.9% were higher than or equal to 10 μg/L. The age cut-off for homes with lead would be 1974 for paint and 1993 for indoor floor dust. This study provides, for the first time, a look at the state of lead contamination to which children are exposed in French housing. Moreover, it provides policy makers an estimate of the number of French dwellings sheltering children where abatement should be conducted.
ISSN: 0013-9351

hal-00732138
https://hal.archives-ouvertes.fr/hal-00732138
DOI : 10.1016/j.envres.2012.04.005
PUBMED : 22551852