Éditeur(s) : HAL CCSD Springer Verlag (Germany) Springer Verlag
Résumé : International audience
Replenished axial melt lenses at fast-spreading mid-oceanic ridges may move upward and intrude into the overlying hydrothermally altered sheeted dikes, resulting in high-grade contact metamorphism with the potential to trigger anatexis in the roof rocks. Assumed products of this process are anatectic melts of felsic composition and granoblastic, two-pyroxene hornfels, representing the residue after partial melting. Integrated Ocean Drilling Program Expeditions 309, 312, and 335 at Site 1256 (eastern equatorial Pacific) sampled such a fossilized oceanic magma chamber. In this study, we simulated magma chamber roof rock anatectic processes by performing partial melting experiments using six different protoliths from the Site 1256 sheeted dike complex, spanning a lithological range from poorly to strongly altered basalts to partially or fully recrystallized granoblastic hornfels. Results show that extensively altered starting material lacking primary magmatic minerals cannot reproduce the chemistry of natural felsic rocks recovered in ridge environments, especially elements sensitive to hydrothermal alteration (e.g., K, Cl). Natural geochemical trends are reproduced through partial melting of moderately altered basalts from the lower sheeted dikes. Two-pyroxene hornfels, the assumed residue, were reproduced only at low melting degrees (<20 vol%). The overall amphibole absence in the experiments confirms the natural observation that amphibole is not produced during peak metamorphism. Comparing experimental products with the natural equivalents reveals that water activity (aH2O) was significantly reduced during anatectic processes, mainly based on lower melt aluminum oxide and lower plagioclase anorthite content at lower aH2O. High silica melt at the expected temperature (1000–1050 °C; peak thermal overprint of two-pyroxene hornfels) could only be reproduced in the experimental series performed at aH2O = 0.1.
ISSN: 0010-7999

hal-01174139
https://hal.archives-ouvertes.fr/hal-01174139
DOI : 10.1007/s00410-015-1136-5

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Rainbow is a dome-shaped massif at the 36°14′N nontransform offset along the Mid-Atlantic Ridge. It hosts three ultramafic-hosted hydrothermal sites: Rainbow is active and high temperature; Clamstone and Ghost City are fossil and low temperature. The MoMARDREAM cruises (2007, 2008) presented here provided extensive rock sampling throughout the massif that constrains the geological setting of hydrothermal activity. The lithology is heterogeneous with abundant serpentinites surrounding gabbros, troctolites, chromitites, plagiogranites, and basalts. We propose that a W dipping detachment fault, now inactive, uplifted the massif and exhumed these deep-seated rocks. Present-day deformation is accommodated by SSW-NNE faults and fissures, consistent with oblique teleseismic focal mechanisms and stress rotation across the discontinuity. Faults localize fluid flow and control the location of fossil and active hydrothermal fields that appear to be ephemeral and lacking in spatiotemporal progression. Markers of high-temperature hydrothermal activity (∼350°C) are restricted to some samples from the active field while a more diffuse, lower temperature hydrothermal activity (<220°C) is inferred at various locations through anomalously high As, Sb, and Pb contents, attributed to element incorporation in serpentines or microscale-sulfide precipitation. Petrographic and geochemical analyses show that the dominant basement alteration is pervasive peridotite serpentinization at ∼160–260°C, attributed to fluids chemically similar to those venting at Rainbow, and controlled by concomitant alteration of mafic-ultramafic units at depth. Rainbow provides a model for fluid circulation, possibly applicable to hydrothermalism at oceanic detachments elsewhere, where both low-temperature serpentinization and magmatic-driven high-temperature outflow develop contemporaneously, channeled by faults in the footwall and not along the detachment fault.
ISSN: 1525-2027

hal-01115281
https://hal.archives-ouvertes.fr/hal-01115281
https://hal.archives-ouvertes.fr/hal-01115281/document
https://hal.archives-ouvertes.fr/hal-01115281/file/Andreani_et_al-2014-Geochemistry%2C_Geophysics%2C_Geosystems.pdf
DOI : 10.1002/2014GC005269

Éditeur(s) : HAL CCSD
Résumé : Geothermal energy is considered as a green and infinite energy source at human scale. Currently, the yield of geothermal power plants is limited to temperatures of the operating fluid which 350 °C. From tectonic and volcanic activity at mid-ocean ridges, Iceland is a location where supercritical fluid extraction (T> 375 °C) can considered for the near future. Exploiting such fluids could theoretically multiply by a factor of ten the electrical power delivered by geothermal wells. Can such fluids circulate at the base of brittle oceanic crust? This work investigates the petrophysical properties of basalts in order to constrain geophysical observations in Iceland and predict the behavior of very high temperature geo-hydrothermal reservoirs. The first approach consisted in studying the physical properties of rocks that have hosted deep hydrothermal circulations at oceanic ridges. The study of these rocks at ODP Site 1256 shows that the porosity measured both in the field and in the lab is associated with amphibolite facies alteration minerals (T> 500 ° C). The second approach was to recreate in the laboratory the conditions of pressure, temperature and pore fluid pressure of high temperature to supercritical hydrothermal systems to predict the mechanical and electrical properties of basalts under these conditions. The mechanical results indicate that the brittle/ductile transition occurs at a temperature of about 550° C, where a strong permeability decrease is expected. The implementation and calibration of a new cell for measuring electrical conductivity at high temperature provide the first results for the interpretation of geophysical data. When applied to basaltic crustal conditions in Iceland, these results indicate that hydrothermal fluids could circulate, at least temporarily, in a supercritical state up to 5 km depth.
La géothermie est considérée comme une source d'énergie propre et inépuisable à échelle humaine. Actuellement, le rendement des centrales géothermiques est limité à l'exploitation de fluides de températures inférieures à 350 °C. L'association de l'activité tectonique et volcanique aux dorsales océaniques fait de l'Islande un lieu où l'extraction de fluides supercritiques (T> 375 °C) peut être envisagée. Cette exploitation pourrait multiplier par dix la puissance électrique délivrée par le système géothermal. Ces fluides peuvent-ils circuler dans la croûte océanique ? Ce travail propose de contraindre les observations géophysiques et de prédire le fonctionnement des réservoirs géo-hydrothermaux de très haute température par l'étude des propriétés physiques des basaltes. La première approche est focalisée sur l'étude de roches ayant accueilli une circulation hydrothermale par le passé. L'étude de ces roches au site ODP 1256, montre que leur porosité est associée à la présence de minéraux d'altération hydrothermale du facies amphibolite (T> 500 °C). La seconde approche a consisté à recréer, en laboratoire, les conditions des systèmes hydrothermaux, à très haute température, afin de prédire les propriétés mécaniques et électriques des basaltes dans ces conditions. Les résultats mécaniques indiquent que la transition fragile/ductile, souvent associée à une forte décroissance de perméabilité, intervient à une température d'environ 550 °C. La mise en place d'une cellule de mesure de la conductivité électrique de haute température a fourni les premiers résultats utiles à l'analyse des données géophysiques. Appliqués aux conditions de la croûte basaltique Islandaise, ces résultats indiquent que des fluides hydrothermaux pourraient circuler au moins transitoirement à l'état supercritique jusqu'à ~ 5 km de profondeur.
https://tel.archives-ouvertes.fr/tel-00591798

tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798/document
https://tel.archives-ouvertes.fr/tel-00591798/file/THESE_MV_pro.pdf

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
The transition between the small melt lens observed on top of fast spreading ridge magma chambers and the overlying sheeted dike complex marks the interface between magma and the hydrothermal convective system. It is therefore critical to our understanding of fast spreading ridge accretion processes. We present maps of two areas of the Oman ophiolite where this transition zone is observed as continuous outcrops. Our observations, which include the base of the sheeted dike being crosscut by gabbros, are consistent with episodic dike injections in a steady state model but also suggest that the root of these dikes is commonly erased by vertical movements of the top of the melt lens. Dike assimilation is a possible mechanism for incorporating hydrated phases, which result from hydrothermal alteration, to the melt lens during upward migrations of its upper boundary. Upward migrations are also responsible for a granoblastic overprint of the root of the dikes that is also observed in the stoped diabase xenoliths. This granoblastic overprint attests to reheating of previously hydrothermally altered lithologies which can even trigger hydrous partial melting due to the lowering of the solidus of mafic lithologies by the presence of a water activity. Clinopyroxenes present in these granoblastic lithologies are typically low in Ti and Al content, thus strongly contrasting with corresponding magmatic clinopyroxene. This may attest to the recrystallization of clinopyroxenes after amphiboles under the peculiar conditions present at the root zone of the sheeted dike complex. Downward migrations of the top of the melt lens result in the crystallization of the isotropic gabbros at its roof, which represent the partly fossilized melt lens. Melt lens fossilization eventually occurs when magma supply is stopped or at the melt lens margins where the thermal conditions become cooler. Melt lens migration, recrystallization of hydrothermally altered sheeted dikes during reheating stages, and assimilation processes observed in the Oman ophiolite are consistent with the observations made in IODP Hole 1256D. We propose a general dynamic model in which the melt lens at fast spreading ridges undergoes upward and downward movements as a result of either eruption/replenishment stages or variations in the hydrothermal/magmatic fluxes.
ISSN: 1525-2027

hal-00445249
https://hal.archives-ouvertes.fr/hal-00445249
DOI : 10.1029/2009GC002652

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
In ophiolites and in present-day oceanic crust formed at fast spreading ridges, oceanic plagiogranites are commonly observed at, or close to the base of the sheeted dike complex. They can be produced either by differentiation of mafic melts, or by hydrous partial melting of the hydrothermally altered sheeted dikes. In addition, the hydrothermally altered base of the sheeted dike complex, which is often infiltrated by plagiogranitic veins, is usually recrystallized into granoblastic dikes that are commonly interpreted as a result of prograde granulitic metamorphism. To test the anatectic origin of oceanic plagiogranites, we performed melting experiments on a natural hydrothermally altered dike, under conditions that match those prevailing at the base of the sheeted dike complex. All generated melts are water saturated, transitional between tholeiitic and calc-alkaline, and match the compositions of oceanic plagiogranites observed close to the base of the sheeted dike complex. Newly crystallized clinopyroxene and plagioclase have compositions that are characteristic of the same minerals in granoblastic dikes. Published silicic melt compositions obtained in classical MORB fractionation experiments also broadly match the compositions of oceanic plagiogranites; however, the compositions of the coexisting experimental minerals significantly deviate from those of the granoblastic dikes. Our results demonstrate that hydrous partial melting is a likely common process in the root zone of the sheeted dike complex, starting at temperatures exceeding 850A degrees C. The newly formed melt can either crystallize to form oceanic plagiogranites or may be recycled within the melt lens resulting in hybridized and contaminated MORB melts. It represents the main MORB crustal contamination process. The residue after the partial melting event is represented by the granoblastic dikes. Our results support a model with a dynamic melt lens that has the potential to trigger hydrous partial melting reactions in the previously hydrothermally altered sheeted dikes. A new thermometer using the Al content of clinopyroxene is also elaborated.
ISSN: 0010-7999

hal-00534058
https://hal.archives-ouvertes.fr/hal-00534058
DOI : 10.1007/s00410-010-0502-6

Éditeur(s) : HAL CCSD Elsevier
Résumé : This contribution reports our preliminary work to determine Cu isotope ratios for various granite rocks and examine the Cu isotope systematics within granite suites. A chemical procedure, modified from Marechal [Marechal, C.N., Telouk, R and Albarede, F., 1999. Precise analysis of copper and zinc isotopic compositions by plasma-source mass spectrometry. Chemical Geology, 156(1-4): 251-273.], Was used to separate Cu from rock matrix. Quantitative recovery (100.6 +/- 1.6%), with a low total procedural blank (2.65 +/- 0.66 ng) for Cu, has been achieved, allowing Cu isotopic measurements on samples with as little as 10 ppm Cu. The Cu isotope ratios (delta Cu-65 relative to NIST SRM 976) of 32 rock samples, ranging from mafic to felsic compositions, from 3 batholiths (2 I-type, 1 S-type) from the Lachlan Fold Belt in southeastern Australia. vary from -0.46 parts per thousand to 1.51 parts per thousand. Most of them cluster around zero, With mean values for the I-type and S-type granites of 0.03 +/- 0.15 parts per thousand and - 0.03 +/- 0.42 parts per thousand (2 sigma) respectively. These data, together with Cu isotope ratios of two loess samples, provide preliminary evidence that the baseline Cu isotopic composition of the crystalline part of upper continental crust is close to zero. The tight clustering of Cu isotope ratios of rocks from the I-type suites Suggests that high-temperature magmatic processes do not produce significant Cu isotope fractionation. However, two granites with abnormally heavy Cu isotope signatures (up to 1.51 parts per thousand) appears to be the result of localized hydrothermal alteration. Measurable variation in Cu isotopic composition of the S-type granite may reflect isotopic heterogeneity in the sedimentary Source region as a result of redox processes or may be due to hydrothermal overprinting. Thus, Cu isotope geochemistry may be a useful tracer for studying hydrothermal alteration and Source heterogeneity of granitic rocks.
ISSN: 0009-2541

hal-00413130
https://hal.archives-ouvertes.fr/hal-00413130
DOI : 10.1016/j.chemgeo.2008.06.047

Éditeur(s) : HAL CCSD Integrated Ocean Drilling Program
Résumé : In this report we present the results of laboratory measurements carried out to explore the electrical properties of gabbroic and troctolitic samples from Integrated Ocean Drilling Program (IODP) Hole U1309D in the Atlantis Massif, an oceanic core complex located at 30°N on the Mid-Atlantic Ridge. Oceanic core complexes are presumably localized in portions of heterogeneous oceanic crust that are relatively rich in igneous rocks and are the locus of significant hydrothermal activity. Electrical properties of igneous rocks are used to discuss the rocks' porosity structure as a function of mineralogy, alteration processes, and deformation. Electrical properties of the gabbroic suites sampled during IODP Expedition 304/305 can contribute to the understanding of these processes in the Atlantis Massif. We present the full suite of electrical data together with density and porosity measurements on the same suite of samples.
ISSN: 1930-1014

hal-00464179
https://hal.archives-ouvertes.fr/hal-00464179
DOI : 10.2204/iodp.proc.304305.204.2009

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : Mid-ocean ridges magmatism is, by and large, considered to be mostly dry. Nevertheless, numerous works in the last decade have shown that a hydrous component is likely to be involved in ocean ridges magmas genesis and/or evolution. The petrology and geochemistry of peculiar coarse grained gabbros sampled in the upper part of the gabbroic sequence from the northern Oman ophiolite (Wadi Rajmi) provide information on the origin and fate of hydrous melts in fast-spreading oceanic settings. Uncommon crystallization sequences for oceanic settings (clinopyroxene crystallizing before plagioclase), extreme mineral compositions (plagioclase An% up to 99, and clinopyroxene Mg # up to 96), and the presence of magmatic amphibole, imply the presence of a high water activity during crystallization. Various petrological and geochemical constraints point to hydration, resulting from the recycling of hydrothermal fluids. This recycling event may have occurred at the top of the axial magma chamber where assimilation of anatectic hydrous melts is recurrent along mid-ocean ridges or close to segments ends where fresh magma intrudes previously hydrothermally altered crust. In ophiolitic settings, hydration and remelting of hydrothermally altered rocks producing hydrous melts may also occur during the obduction process. Although dry magmatism dominates oceanic magmatism, the dynamic behavior of fast-spreading ocean ridge magma chambers has the potential to produce the observed hydrous melts (either in ophiolites or at spreading centers), which are thus part of the general mid-ocean ridges lineage.
ISSN: 1525-2027

hal-00939400
https://hal.archives-ouvertes.fr/hal-00939400
DOI : 10.1002/ggge.20137

Éditeur(s) : HAL CCSD Society of Economic Geologists
Résumé : International audience
The ~8-Moz Sadiola Hill gold deposit is located in the Kédougou-Kénieba inlier, a window of deformed ca. 2200 to 2050 Ma rocks that crop out in eastern Senegal and western Mali. The geology of the inlier differs from other Paleoproterozoic granite-greenstone belts and sedimentary basins by the abundance of carbonate rocks. The Sadiola Hill gold deposit occurs within 3 km of the Senegal-Mali shear zone, and country rocks in the region have undergone polycyclic deformation. The lithostratigraphy of the open pit consists of impure limestones overlain by younger sequences of detrital sedimentary rocks, which include arenite, wacke, and siltstone. The sedimentary rocks have been subjected to regional greenschist-facies metamorphism and have been intruded by multiple generations of synkinematic, calc-alkaline stocks and dikes. The bulk of the ore is hosted within a N-S- to NNW-trending, 10- to 50-m-wide, brittle-ductile dilational shear zone defined as the Sadiola shear zone. Gold lodes also occur along an array of steep NNE-trending shear zones. Geometric and kinematic analyses indicate that the ore-hosting structures were undergoing sinistral displacement at the time of mineralization, locally defined as the D3s NNW-SSE-shortening event. Hydrothermal alteration is polyphase and includes an early high-temperature calc-silicate phase (i.e., porphyroblastic growth of actinolite-tremolite) followed by a potassic phase (i.e., biotite-calcite-quartz ± K-feldspar-tourmaline-actinolite) that was synchronous with ore mineral deposition. Paragenetic studies reveal a multistage ore development that includes an As-rich sulfide stage, followed by an Au-Sb stage. The ore is associated with a metal enrichment suite of Au-As-Sb ± Cu-Fe-W-Mo-Ag-Bi-Zn-Pb-Te. The Sadiola Hill deposit shares a similar relative timing and structural setting to that of other world-class orogenic gold systems in the West African craton (e.g., Ashanti, Loulo), with gold deposition occurring during a period of transcurrent tectonics, after the cessation of region-wide compressional deformation. The high-temperature paragenesis at Sadiola Hill is atypical of gold mineralization in the craton and indicates that the late Eburnean tectono-magmatic activity between ca. 2080 and 2060 Ma played an important role in the dynamics of hydrothermal fluid circulation along the Senegal-Mali shear zone.
ISSN: 0361-0128

hal-01583358
https://hal.archives-ouvertes.fr/hal-01583358
DOI : 10.2113/econgeo.112.1.23

Éditeur(s) : HAL CCSD Nature Publishing Group
Résumé : International audience
Carbon is transported from Earth's surface into its interior at subduction zones. Carbonates in sediments overlying hydrothermally altered rocks (including serpentinites) within the subducted slab are the main carriers of this carbon1. Part of the carbon is recycled back to the surface by volcanism, but some is transferred to the deep Earth1, 2. Redox transformations during shallow subduction control the transfer and long-term fate of carbon, but are poorly explored1, 3. Here we use carbon stable isotopes and Raman spectroscopy to analyse the reduction of carbonate in an exhumed serpentinite-sediment contact in Alpine Corsica, France. We find that highly crystalline graphite was formed during subduction metamorphism and was concentrated in the sediment, within a reaction zone in direct contact with the serpentinite. The graphite in this reaction zone has a carbon isotopic signature (δ13C) of up to 0.8±0.1‰, similar to that of the original calcite that composed the sediments, and is texturally associated with the calcium-bearing mineral wollastonite that is also formed in the process. We use mass-balance calculations to show that about 9% of the total carbonaceous matter in the sedimentary unit results from complete calcite reduction in the reaction zone. We conclude that graphite formation, under reducing and low-temperature conditions, provides a mechanism to retain carbon in a subducting slab, aiding transport of carbon into the deeper Earth.
ISSN: 1752-0894

hal-00903464
https://hal.archives-ouvertes.fr/hal-00903464
DOI : 10.1038/NGEO1827

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
ODP (Ocean Drilling Program)/IODP (Integrated Ocean Drilling Program) Site 1256 is located on the Cocos Plate in the Eastern Equatorial Pacific Ocean, in a 15 Ma old oceanic lithosphere formed at the EPR during a period of superfast spreading (>200 mm/yr). ODP/IODP Hole 1256D reached for the first time the contact between sheeted dikes and underlying gabbros. It consequently offers a unique opportunity to study in situ, in present-day oceanic crust, the root zone of the sheeted dike complex. This root zone is a thin, 100 m thick boundary layer between the magmatic system (i.e., the axial melt lens, similar to 1100 degrees C), and the overlying high temperature hydrothermal system (<= 450 degrees C). The understanding of interactions within this boundary layer is critical to that of crustal processes along mid-ocean ridges.;This work focuses on the petrophysical characterization of the root zone of the sheeted dike complex in order to further constrain the hydrothermal circulation system in the vicinity of the axial melt lens, as recorded in non-granoblastic dikes, granoblastic dikes, and varitextured gabbros. The petrophysical properties were determined from sample measurements in the laboratory and were compared to in situ downhole geophysical probing. The porosity structure is bipolar, depending on lithology, resulting in a layered system. Non-granoblastic dikes are generally altered in the greenschist fades (similar to>250 degrees C) with relatively high and interconnected (cementation index m similar to 1.72, electrical tortuosity tau similar to 28.3) porosity (1.5%). In contrast, gabbros are retrogressively metamorphosed in the amphibolite (similar to>450 degrees C) and greenschist facies, with lower porosity (1.3%) that involves numerous fissures and cracks, resulting in a more connected medium (m similar to 1.58, tau similar to 11.8) than non-granoblastic dikes. These cracks are more abundant but also tend to close with increasing depth as indicated in downhole geophysical data. Porosity and alteration, as viewed from surface electrical conductivity, appear to be directly correlated.
ISSN: 0040-1951

hal-00544556
https://hal.archives-ouvertes.fr/hal-00544556
DOI : 10.1016/j.tecto.2010.07.013

Éditeur(s) : HAL CCSD
Résumé : A section of ancient fast-spreading ocean crust was sampled at Wadi Gideah, located in the Wadi Tayin Massif of the Oman ophiolite. This sample suite was used for generating a coherent data set combining various petro-geochemical and structural investigations, with the aim of building a reference section for advancing our understanding of crustal accretion processes at fast-spreading mid-ocean ridges. Additionally, this study focuses on one outcrop that represents part of the fossil axial melt lens (AML).Major and trace element analyses reveal a trend of chemical evolution up section in the lower crust, with a marked difference between the layered gabbros and the foliated gabbros above. Petrological modeling shows that the chemical evolution up section can be produced by hydrous fractionation crystallization, with melt H2O contents of ~0.8 wt% and 0.8 to 1.2 wt% for the lower and upper crust, respectively. Together with the observed very steep bulk Zr/Hf vs. Zr gradient, high F and Cl content of magmatic amphibole, general Nb-Ta depletion of melts compared with NMORB, and high Sr87/Sr86 ratio compared with modern fast-spread crust, this suggests that Wadi Gideah layered gabbros were accreted by crystallization of ascending melts in sills, in a context of subduction initiation. The distinct changes in chemical trends and average grain size at the layered to foliated gabbro transition are tentatively explained by enhanced hydrothermal cooling deeper than the AML. The gabbro/dike transition displays complex structural and lithological relationships that, together with fractional crystallization modeling, point to episodic vertical movements of the AML. Plagioclase crystallographic preferred orientations (CPO) measured over the whole gabbro section are always consistent with magmatic flow. The CPO strength generally increases downward, with more scattering in the layered gabbro section. From the top to the bottom of the layered gabbros, CPO become progressively more prolate, possibly reflecting increasing shear induced by active mantle flow underneath.Wadi Gideah lower crust recorded a formation history consistent with a hybrid accretion model, combing several processes such as downward magmatic flow and/or upward melt migration in the upper foliated gabbros, sill intrusions in the layered gabbros, and deep hydrothermal circulation. The latter was presumably focused in channels, preserved today as several, up to 100 m wide zones of extensively altered former layered gabbro, cross-cutting the magmatic layering. These metagabbros display significantly higher Sr87/Sr86 ratio, late stage magmatic phases, and evidence for high temperature partial melting.
Une coupe d'ancienne croute océanique rapide a été échantillonnée dans le Wadi Gideah, situé dans le Massif de Wadi Tayin de l'Ophiolite d'Oman. Cette série d'échantillons a permis de générer un jeu de données cohérent, combinant des études pétro-géochimiques et structurales, dans le but de construire une coupe de référence pour mieux contraindre notre compréhension des processus d'accrétion crustale aux dorsales océaniques rapides. Ce travail intègre aussi l'étude détaillée d'un affleurement représentant en partie la lentille magmatique axiale (LMA) fossile.Les analyses d'éléments majeurs et traces révèlent une évolution chimique dans la croûte inférieure, avec une nette différence entre les gabbros lités et les gabbros foliés sus-jacents. La modélisation pétrologique montre que l'évolution chimique vers le haut peut être produite par cristallisation fractionnée hydratée, avec des teneurs en H2O des magmas de ~0.8 wt% dans la croute inférieure et 0.8 to 1.2 wt% dans la croute supérieure. Combiné aux forts gradients de Zr/Hf vs. Zr, aux teneurs élevées de F et Cl dans les amphiboles magmatiques, à l'appauvrissement général en Nb-Ta des magmas comparé aux NMORB, et aux rapports Sr87/Sr86 élevés comparés à la croûte rapide moderne, ceci suggère que les gabbros lités du Wadi Gideah ont été formés par la cristallisation des magmas ascendants dans des sills, dans un contexte d'initiation de subduction. Les changements de signature géochimique et de taille de grain à la transition entre gabbros lités et gabbros foliés témoignent possiblement d'un fort refroidissement hydrothermal plus profond que la LMA. La transition complexe filonien/gabbro montre des relations structurale et lithologiques complexes, qui, combinées o la modélisation de la cristallisation fractionnée, traduisent les mouvements verticaux épisodiques de la LMA. Les orientations préférentielles cristallographiques (OPC) des plagioclases mesurées sur l'ensemble de la coupe dans les gabbros témoignent toujours d'une déformation magmatique. L'intensité des OPC a tendance à augmenter vers le bas, avec une plus forte variabilité dans les gabbros lités. Dans les gabbros lités, les OPC sont de plus en plus linéaires vers le bas, résultant possiblement d'un cisaillement plus fort induit par l'écoulement actif du manteau sous-jacent.La croûte inférieure dans le Wadi Gideah a enregistré une histoire compatible avec un modèle d'accrétion hydride, combinant plusieurs processus tels que l'écoulement magmatique vers le bas et/ou la migration de liquides magmatiques vers le haut dans les gabbros foliés supérieurs, l'intrusion de sills dans les gabbros lités, et une circulation hydrothermale profonde. Cette dernière était probablement concentrée dans des chenaux, préservés aujourd'hui sous la forme de plusieurs zones, dont l'épaisseur atteint 100 m, de gabbros lités fortement altérés, recoupant le litage magmatique. Ces métagabbros ont des rapports Sr87/Sr86 élevés, comportent des phases magmatiques tardives et montrent des évidences de fusion partielle.
https://hal.archives-ouvertes.fr/tel-01302675

tel-01302675
https://hal.archives-ouvertes.fr/tel-01302675
https://hal.archives-ouvertes.fr/tel-01302675/document
https://hal.archives-ouvertes.fr/tel-01302675/file/Th%C3%A8se_Tim-Mueller_2015.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Kimberlites of the Udachnaya-East pipe (Siberia) include a uniquely dry and serpentine-free rock type with anomalously high contents of chlorine (Cl ≤ 6.1 wt%), alkalies (Na2O + K2O ≤ 10 wt%) and sulfur (S ≤ 0.50 wt%), referred to as a “salty” kimberlite. The straightforward interpretation is that the Na-, K-, Cl- and S-rich components originate directly from a carbonate-chloride kimberlitic magma that is anhydrous and alkali-rich. However, because brines and evaporites are present on the Siberian craton, previous studies proposed that the kimberlitic magma was contaminated by the assimilation of salt-rich crustal rocks. To clarify the origin of high Cl, alkalies and S in this unusual kimberlite, here we determine its sulfur speciation and isotopic composition and compare it to that of non-salty kimberlites and kimberlitic breccia from the same pipe, as well as potential contamination sources (hydrothermal sulfides and sulfates, country-rock sediment and brine collected in the area). The average δ34S of sulfides is − 1.4 ± 2.2‰ in the salty kimberlite, 2.1 ± 2.7‰ in the non-salty kimberlites and 14.2 ± 5.8‰ in the breccia. The average δ34S of sulfates in the salty kimberlites is 11.1 ± 1.8‰ and 27.3 ± 1.6‰ in the breccia. In contrast, the δ34S of potential contaminants range from 20 to 42‰ for hydrothermal sulfides, from 16 to 34‰ for hydrothermal sulfates, 34‰ for a country-rock sediment (Chukuck suite) and the regional brine aquifer. Our isotope analyses show that (1) in the salty kimberlites, neither sulfates nor sulfides can be simply explained by brine infiltration, hydrothermal alteration or the assimilation of known salt-rich country rocks and instead, we propose that they are late magmatic phases; (2) in the non-salty kimberlite and breccia, brine infiltration lead to sulfate reduction and the formation of secondary sulfides – this explains the removal of salts, alkali-carbonates and sulfates, as well as the minor olivine serpentinization; (3) hydrothermal sulfur was added to the kimberlitic breccia, but not to the massive kimberlites. In situ measurements of sulfides confirm this scenario, clearly showing the addition of two sulfide populations in the breccia (pyrite-pyrrhotites with average δ34S of 7.9 ± 3.4‰ and chalcopyrites with average δ34S of 38.0 ± 0.4‰) whereas the salty and non-salty kimberlites preserve a unique population of djerfisherites (Cl- and K-rich sulfides) with δ34S values within the mantle range. This study provides the first direct evidence of alkaline igneous rocks in which magmatic sulfate is more abundant than sulfide. Although sulfates have been rarely reported in mantle materials, sulfate-rich melts may be more common in the mantle than previously thought and could balance the sulfur isotope budget of Earth's mantle.
ISSN: 0009-2541

hal-01571982
https://hal.archives-ouvertes.fr/hal-01571982
DOI : 10.1016/j.chemgeo.2016.10.037

Éditeur(s) : HAL CCSD Springer/Terra Scientific Publishing Company
Résumé : International audience
This study of the Cajati deposit provides evidence that the ore was neither purely hydrothermal, nor volcanic in origin, as previous workers have proposed. The ores were formed from magnetite-rich magmas, hydrothermally altered and intruded at an indicated crustal depth in excess of 500 m. The mineralogical and textural association between magnetite and magnesioferrite in the carbonatite, and between the titanomagnetite and magnesioferrite-Ti mineralization in the pyroxenite of hedenbergite, seems to be analog mineralizations strongly related to the ionic substitution of Fe2+ by Mg. Relatively high Q ratios (>= 5) for Jacupirangite-pyroxenite may indicate a thermo remanent magnetization (TRM) by the ore during post-metamorphic cooling, however it call also be developed from chemical remanent magnetization (CRM). Vector plots for the pyroxenite samples show reasonably linear and stable magnetic components. The intensity decay Curves show that only two components of magnetizations are likely present. Continuous susceptibility measurements with increasing temperature show that the main magnetic phase seems to be magnetite. Maghemite is probably produced during the cooling process. Susceptibility recorded from low temperature (liquid nitrogen (- 196 degrees C)) to room temperature produces typical Curves. indicating Verwey transition of magnetite. Hysteresis parameters point Out that nearly all values fill in a novel region of the Day plot, parallel to but below magnetite SD + MD mixing curves.
ISSN: 1343-8832

hal-00420922
https://hal.archives-ouvertes.fr/hal-00420922

Éditeur(s) : HAL CCSD
Résumé : This PhD work is based on field, petrographic, and geochemical observations of rocks originated at the base of the sheeted dike complex, in the Oman ophiolite and at IODP Site 1256, coupled with an experimental study. It provides new constrains on processes that occur at the magma / hydrothermal system transition in oceanic crust formed at fast spreading ridges. The base of the sheeted dike complex is truncated by intrusive isotropic gabbros, and therefore reheated and recrystallized to the "granoblastic dikes" under temperatures up to 1030°C. Xenoliths of granoblastic microgabbros and microgabbronorites derived from the granoblastic dikes are commonly observed in the about 100 meters thick horizon of isotropic gabbro that underlies the sheeted dike complex. These features can be explained by upward migrations of the melt lens that is present at fast spreading centers. The occurrence of several assimilation features (xenoliths and granoblastic patches) in the isotropic gabbro horizon supports the hypothesis that this horizon represents the fossilization of the upper melt lens. The experimental study was designed to simulate experimentally the effect of partial melting of hydrothermally altered sheeted dikes. The results show that melting starts at 850°C, confirm the residual origin of granoblastic dikes and xenoliths, and attest to the anatectic origin of the oceanic plagiogranites that are commonly present close to the base of the sheeted dike complex. The major and trace element composition of the experimental anatectic melt that represents the main contaminant for primitive MORBs at fast spreading ridges has been determined. The upper axial melt lens at fast spreading mid-ocean ridges is herein described as a dynamic system that can migrate vertically, and which fossilizes when moving off-axis.
Ce travail de thèse est basé sur des observations de terrain, sur une étude pétrographique et géochimique des roches formées à la base du complexe filonien dans l'ophiolite d'Oman et au niveau du Site IODP 1256, ainsi que sur une étude expérimentale. De nouvelles contraintes sont apportées sur les processus se produisant à la transition magma / système hydrothermal dans la croute océanique formée au niveau des dorsales à expansion rapide. L'intrusion de gabbros isotropes dans la base du complexe filonien a provoqué son réchauffement et sa recrystallization en « dikes granoblastiques » jusqu'à des températures de 1030°C. Des xénolites de microgabbro à orthopyroxene dérivées des dikes granoblastiques sont souvent observées dans le niveau de gabbros isotropes épais de 100 mètres environ qui est présent à la base du complexe filonien. Ces différentes caractéristiques sont à relier à des migrations verticales vers le haut du sommet de la lentille magmatique supérieure qui est observée aux dorsales rapides. Les nombreuses évidences d'assimilation (xénolites et patchs granoblastiques) dans le niveau des gabbros isotropes appuient l'hypothèse que ce niveau représente la fossilisation de la lentille magmatique supérieure. L'étude expérimentale a consisté à tester l'effet de la fusion partielle du complexe filonien préalablement hydrothermalisé. Les résultats montrent que la fusion commence à 850°C, confirment l'origine résiduelle des dikes granoblastiques et des xénolites associées, et attestent de l'origine anatectique des plagiogranites océaniques qui sont couramment observés à proximité de la base du complexe filonien. La composition en éléments majeurs et traces du liquide anatectique a été déterminée. Ce liquide représente le principal contaminant pour les MORBs primitifs émis au niveau des dorsales rapides. La lentille magmatique supérieure présente au niveau des dorsales médio-océaniques à expansion rapide est ici décrite comme un système dynamique qui peut migrer verticalement, et qui est fossilisée lorsqu'elle se déplace hors axe.
https://tel.archives-ouvertes.fr/tel-00448699

tel-00448699
https://tel.archives-ouvertes.fr/tel-00448699
https://tel.archives-ouvertes.fr/tel-00448699/document
https://tel.archives-ouvertes.fr/tel-00448699/file/France_2009_PhD.pdf

Éditeur(s) : HAL CCSD Oxford University Press (OUP): Policy B - Oxford Open Option A Oxford University Press (OUP)
Résumé : International audience
Peridotites exhumed in the footwall of axial detachment faults at slow-spreading ridges are highly serpentinized. Most mid-ocean ridge detachment settings are magmatically active and hydrous fluid circulation in and near the fault has been shown to be influenced by the presence of melt or magmatic lithologies. Our working area along the Southwest Indian Ridge (62–65°E) is nearly amagmatic and represents an end-member to study the hydrous alteration of exhumed peridotites without these magmatic influences. We use an integrated petrological approach combining microstructural, mineralogical and chemical observations to unravel the sequence of serpentinization in 272 dredged samples of variably serpentinized peridotites and to document the circulation of serpentinizing fluids in and near the exhumation faults. We find that serpentine recrystallization and veins overprint the initial serpentinite mesh texture in ∼25% of the samples. Oxygen isotope data suggest that this sequence developed at relatively high temperatures (271–336°C) and under increasing fluid–rock ratios, from near stoichiometry for mesh texture formation to >10 during recrystallization. Increasing fluid supersaturation relative to serpentine favors the replacement of mesh texture lizardite by chrysotile and polygonal or polyhedral serpentine. We attribute local recrystallization into antigorite to moderate Si-metasomatism, possibly following pyroxene serpentinization. We do not observe the more pronounced Si-metasomatism leading to talc replacing serpentine that is reported for the more magmatically active Mid-Atlantic Ridge detachment settings and is attributed to prior leaching of magmatic rocks. Scales of preferential fluid pathways in our samples evolved from pervasive and close-spaced (<500 µm) microfractures during the formation of the initial serpentine mesh texture, to centimeter-thick planar domains of enhanced fluid flux, spaced at ∼10 cm intervals and probably grouped in corridors that may be up to ∼100 m across. Serpentine minerals are enriched in some fluid-mobile elements (Cl, B, U) relative to the peridotite protolith, and several elements (Al, Fe, Si, Cu, As, Sb, REE) are redistributed at the millimeter to decimeter scale. Serpentinizing fluids were seawater-derived, probably mildly alkaline (small to no europium anomalies), reducing and H2-enriched (formation of magnetite). These fluids may have been similar to, though warmer than, those venting at the ultramafic-hosted Lost City hydrothermal fluid (30°N, Mid-Atlantic Ridge).
ISSN: 0022-3530

hal-01174047
https://hal.archives-ouvertes.fr/hal-01174047
DOI : 10.1093/petrology/egv014

Éditeur(s) : HAL CCSD Nature Publishing Group
Résumé : International audience
Temperature and fluid pressure conditions control rock deformation and mineralization on geological faults, and hence the distribution of earthquakes1. Typical intraplate continental crust has hydrostatic fluid pressure and a near-surface thermal gradient of 31 ± 15 degrees Celsius per kilometre2, 3. At temperatures above 300–450 degrees Celsius, usually found at depths greater than 10–15 kilometres, the intra-crystalline plasticity of quartz and feldspar relieves stress by aseismic creep and earthquakes are infrequent. Hydrothermal conditions control the stability of mineral phases and hence frictional–mechanical processes associated with earthquake rupture cycles, but there are few temperature and fluid pressure data from active plate-bounding faults. Here we report results from a borehole drilled into the upper part of the Alpine Fault, which is late in its cycle of stress accumulation and expected to rupture in a magnitude 8 earthquake in the coming decades4, 5. The borehole (depth 893 metres) revealed a pore fluid pressure gradient exceeding 9 ± 1 per cent above hydrostatic levels and an average geothermal gradient of 125 ± 55 degrees Celsius per kilometre within the hanging wall of the fault. These extreme hydrothermal conditions result from rapid fault movement, which transports rock and heat from depth, and topographically driven fluid movement that concentrates heat into valleys. Shear heating may occur within the fault but is not required to explain our observations. Our data and models show that highly anomalous fluid pressure and temperature gradients in the upper part of the seismogenic zone can be created by positive feedbacks between processes of fault slip, rock fracturing and alteration, and landscape development at plate-bounding faults.
ISSN: 0028-0836

hal-01685757
https://hal.archives-ouvertes.fr/hal-01685757
DOI : 10.1038/nature22355

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The kinetics of hydrogenation of dry iron-bearing olivine single crystals was determined by performing hydration experiments under hydrothermal conditions at high pressure. The experiments were performed in a multi-anvil press at 3 GPa, for a temperature range between 900 and 1200 °C and for various durations. The oxygen fugacity was buffered along Ni-NiO joint. Polarized Fourier transform infrared spectroscopy and recent empirical calibration were used to quantify the hydroxyl distributions in the samples along crystallographic axes after the experiments. The chemical diffusion coefficients are similar (barely slower) than in olivine hydrated at lower pressure (0.2 and 0.3 GPa) for the same diffusion mechanism. Under the given experimental conditions, the anisotropy of diffusion is the same as for proton-vacancy mechanism, with diffusion along the [0 0 1] axis faster than along the [1 0 0]. However, the anisotropy at 3 GPa is weaker compared to measurements at lower pressures and the analysis of concentration profiles using 3D models shows that an isotropic solution could also be relevant. Fits of the diffusion data to an Arrhenius law yield activation energies for the slightly faster [0 0 1] axis of the crystallographic axes around 198 ± 5 kJ mol−1, a value only slightly lower than the results from previous experimental studies for natural iron-bearing olivine hydrogenated at lower confining pressure. At 3 GPa, hydrogenation can be well approximated by a single mechanism controlled by coupled diffusion of protons and octahedral vacancies (di- and tri-valent ions). The diffusion rates are fast enough to alter hydrogen concentration within olivine in xenoliths ascending from the mantle or experiencing hydrogen-rich metasomatism events, but too slow to permit complete homogenization of hydrogen in olivine-rich rocks at kilometer scale in less than one My.
ISSN: 0031-9201

hal-01412663
https://hal.archives-ouvertes.fr/hal-01412663
DOI : 10.1016/j.pepi.2016.08.005

Éditeur(s) : HAL CCSD
Résumé : International audience
Tin mineralization in Achmmach deposit (NE of Moroccan Central Massif) is associated with tourmaline-rich alteration halos and faults, within N70 shear zones, hosted in sandstones and metapelites of the Upper Visean-Namurian. Such deposits were reported as late-Variscan in age and related to the emplacement of late orogenic granite not outcropping in the studied area.From field constraints, it appears that the late Variscan phase is marked by a transition from transpression to extension with conditions of deformation evolving from ductile to brittle environments. During the transpressive phase (horizontal shortening direction roughly trending E-W), pervasive tourmaline is deposited under the form of metasomatic halos around fractures in the upper levels relative to the deep batholith. This hydrothermal activity is coeval with ductile shear zones within a large corridors trending N70. Tourmaline-rich alteration appears as a hardening stage contributing to the modification of the tectonic style of rocks. Thereafter, a strong brecciation occurs in response of re-using and re-opening of the strike-slip structure. The result is (1) the formation of dextral (N070, N020) and sinistral (N120) shears, and (2) the circulation of fluids within early tourmalinites and formation of tourmaline-rich breccia. Subsequently, during the late orogenic extensional phase, tourmalinite breccias reopened as normal faults acting as overpressure fluid pathways for developing other breccias and veins. Such event is marked by deposition of tin mineralization i.e., cassiterite followed by sulphides, and then fluorite and carbonates at the end.From analysis of the shear-zone structure and superimposition of tourmalines and tin mineralization in the same structures, it is possible to suggest a structural control continuum. Such control is well expressed during metasomatism and deposition of hydrothermal tourmaline under the transpressive phase. Thereafter, under the extensive phase allowing open-space, tin-mineralization were trapped.This study has been supported by AI MA/09/210
24ème RST
Pau, France

insu-01546927
https://hal-insu.archives-ouvertes.fr/insu-01546927

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
An active seismic experiment has been conducted across the southern Ryukyu margin east of Taiwan over the whole trench-arc-backarc system in May 2009. Twenty-four ocean bottom seismometers (OBS) were deployed from the Ryukyu trench to the southern Okinawa trough over the Ryukyu arc and forearc. Wide angle seismic data were recorded by the OBS array while coincident reflection seismic data were acquired using a 6 km long streamer and a 6600 cubic inch seismic airgun array. Results from tomographic inversion of 21091 travel time picks along this line allowed us to image crustal structures of the Ryukyu margin down to a depth of 25 km. The transect has been designed to provide a better seismic velocity structure of the subduction zone in a highly deformed area that has produced an M8 earthquake in 1920. The line crosses a seismic cluster of earthquakes which source mechanisms are still poorly understood. The subducting oceanic crust of the Huatung Basin is about 5-6 km thick. The underlying mantle exhibits low seismic velocities around 7.8 km/s suggesting some hydrothermal alterations or alteration of the upper mantle through faults generated by the flexure of the subducting plate as it enters the subduction. Low velocities, up to 4.5 km/s, associated with the accretionary wedge are well imaged from the trench back to the Nanao forearc. A major result concerns the abrupt termination of the buttress at the rear of the accretionary wedge. Despite the low resolution of the tomographic inversion near the subduction interface, several lines of evidence supporting the presence of a low velocity zone beneath the toe of the forearc buttress could be established. The Moho beneath the Ryukyu non-volcanic arc is located at a depth around 25 km depth.
ISSN: 0040-1951

hal-00795573
https://hal.archives-ouvertes.fr/hal-00795573
DOI : 10.1016/j.tecto.2011.10.010