Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In fold-and-thrust belts, shortening is mainly accommodated by thrust faults which are preferential zones for recrystallisation and mass transfer. This study focuses on a detachment fault related to the emplacement of the Monte Perdido thrust unit in the southern Pyrenees. The studied fault zone consists of a 10 m thick intensively foliated phyllonite developed within the Millaris marls, of Eocene age. The lithological homogeneity of the hanging wall and footwall allows us to compare the Millaris marls outside the fault zone with the highly deformed marls located in the fault zone and to quantify the chemical, mineralogical and volumetric changes related to deformation processes along the fault. The Millaris marls are composed of detrital quartz, illite, chlorite, minor albite and pyrite, in a micritic calcite matrix. In the fault zone, the cleavage planes are marked by clay minerals and calcite ± chlorite veins attest to fluid-mineral interactions during deformation. The mineral proportions in all samples from both the fault zone and Millaris marls have been quantified by two methods: (1) X-ray diffraction and Rietveld refinement, and (2) bulk chemical analyses as well as microprobe analyses to calculate modal composition. The excellent agreement between the results of these two methods allows us to estimate mineralogical variations using a modification of the Gresens' equation. During fault activation, up to 45 wt% of calcite was lost while the amounts of quartz and chlorite remained unchanged. Illite content remained constant to slightly enriched. The mineralogical variations were coupled with a significant volume loss (up to 45%) mostly due to the dissolution of micritic calcite grains. Deformation was accompanied by pressure solution and phyllosilicates recrystallisation. These processes accommodated slip along the fault. They required fluids as catalyst, but they did not necessitate major chemical transfers.
ISSN: 0264-8172

hal-00976361
https://hal.archives-ouvertes.fr/hal-00976361
DOI : 10.1016/j.marpetgeo.2013.12.016

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Microstructures, U-Pb SHRIMP zircon ages and temperature estimates were used to constrain the fabric evolution and timing of mylonitisation in the Patos shear zone (NE Brazil). Melt-bearing HT-mylonitic orthogneiss displays solid-state fabrics with coarse quartz ribbons and sutured grain boundaries. K-feldspar is often fractured and shows peripheral myrmekite. The textures typically become magmatic at the contacts with the Espinho Branco anatexite. Zircon crystals from two samples of the leucosome show Paleoproterozoic (ca. 2.2 Ga) inherited cores that are enveloped by recrystallised Neoproterozoic rims. These zircon grains define a discordia with lower intercept ages of 558 and 562 Ma but with large analytical errors. A leucogranite with transitional contacts with host diatexites provides a well-constrained zircon mean age of 566 ± 6 Ma (n = 15, 95% conf.), which is considered the best estimate for the peak metamorphic conditions. The transition from HT-mylonites to fine-grained mylonites and ultramylonites is marked by a progressive grain size reduction assisted by recrystallisation. Quartz crystallographic fabrics display [0 0 0 1] concentrations between Z and Y. K-feldspar and plagioclase fabrics record the activity of the (0 1 0)[0 0 1] and (0 1 0)[1 0 0] slip systems and, in the lower-temperature tectonites, the (1 0 0)[0 1 0] slip system. These results suggest a diachronic evolution in which an initial HT northern domain was deformed by intracrystalline slip and melt-assisted granular flow, followed by medium- to low-temperature solid-state creep in the southern shear zone domain. The mylonites therefore record the rheological heterogeneities responsible for the formation of a late continental shear zone that nucleated under partially molten conditions and was later reactivated through melt-absent strain localization following exhumation.
ISSN: 0301-9268

hal-01053497
https://hal.archives-ouvertes.fr/hal-01053497
DOI : 10.1016/j.precamres.2013.12.020

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Fault affecting silicoclastic sediments are commonly enriched in clay minerals. Clays are sensitive to fluid–rock interactions and deformation mechanisms; in this paper, they are used as proxy for fault activity and behavior. The present study focuses on clay mineral assemblages from the Point Vert normal fault zone located in the Annot sandstones, a Priabonian-Rupelian turbidite succession of the Alpine foredeep in SE France. In this area, the Annot sandstones were buried around 6–8 km below the front of Alpine nappes soon after their deposition and exhumed during the middle-late Miocene. The fault affects arkosic sandstone beds alternating with pelitic layers, and displays throw of about thirty meters. The fault core zone comprises intensely foliated sandstones bounding a corridor of gouge about 20 cm thick. The foliated sandstones display clay concentration along S–C structures characterized by dissolution of K-feldspar and their replacement by mica, associated with quartz pressure solution, intense microfracturation and quartz vein precipitation. The gouge is formed by a clayey matrix containing fragments of foliated sandstones and pelites. However, a detailed petrographical investigation suggests complex polyphase deformation processes. Optical and SEM observations show that the clay minerals fraction of all studied rocks (pelites and sandstones from the damage and core zones of the fault) is dominated by white micas and chlorite. These minerals have two different origins: detrital and newly-formed. Detrital micas are identified by their larger shape and their chemical composition with a lower Fe–Mg content than the newly-formed white micas. In the foliated sandstones, newly-formed white micas are concentrated along S–C structures or replace K-feldspar. Both types of newly formed micas display the same chemical composition confirmed microstructural observations suggesting that they formed in the same conditions. They have the following structural formulas: Na0.05 K0.86 (Al 1.77 Fe0.08 Mg0.15) (Si3.22 Al0.78) O10 (OH)2. They are enriched in Fe and Mg compared to the detrital micas. Newly-formed chlorites are associated with micas along the shear planes. According to microprobe analyses, they present the following structural formula: (Al1,48 Fe2,50 Mg1,84) (Si2,82 Al1,18) O10 (OH)8. All these data suggest that these clay minerals are synkinematic and registered the fault activity. In the gouge samples, illite and chlorite are the major clay minerals; smectite is locally present in some samples.In the foliated sandstones, Kubler Index (KI) ((001) XRD peak width at half height) data and thermodynamic calculations from synkinematic chlorite chemistry suggest that the main fault deformation occurred under temperatures around 220 °C (diagenesis to anchizone boundary). KI measured on pelites and sandstones from the hanging and footwall, display similar values coherent with the maximal burial temperature of the Annot sandstones in this area. The gouge samples have a higher KI index, which could be explained by a reactivation of the fault at lower temperatures during the exhumation of the Annot sandstones formation
ISSN: 0191-8141

hal-01172423
https://hal.archives-ouvertes.fr/hal-01172423
DOI : 10.1016/j.jsg.2015.03.012

Éditeur(s) : HAL CCSD
Résumé : The Restefond fault, located in the Late Eocene-Early Oligocene Alpine foreland basin, affects the well lithified and low porosity Grès d'Annot. The fault core zone is characterized by the occurrence of highly deformed sandstone lenses. Deformation inside the lenses corresponds to mm to sub-mm-spaced cleavage planes rich in phyllosilicates and up to cm-thick and dm-long quartz-calcite pure extensional veins. The cleavages are mostly composed of newly-formed synkinematic white mica and chlorite. By using thermodynamic thermometers based on the chemical composition of chlorite, a temperature of 200 ± 20 °C of fault activity was computed. This temperature shows that the Restefond fault was active at burial conditions comprised between 6.5 and 8 km, assuming a mean geothermal gradient between 25 and 30 °Ckm−1. The petrophysic properties of sandstones from the core zone and in the hanging and foot wall of the fault were determined on drilled plugs following three spacial directions. The permeability of the highly deformed sandstone from the core zone is about one order of magnitude higher than in the host rock. This increase in permeability occurs in the direction parallel to the S-C structures and is explained by the occurrence of well-connected micropores localized between platy phyllosilicates. This study shows that the fault petrophysic properties are mostly controlled by the precipitation of synkinematic phyllosilicates under deep burial conditions.
Swiss Journal of Geosciences

hal-00795551
https://hal.archives-ouvertes.fr/hal-00795551
DOI : 10.1007/s00015-012-0099-z

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We analyzed twelve fault gouge samples from the Bogd fault in south-western Mongolia to understand the origin and behavior of clay minerals. The investigation relies on x-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and high energy synchrotron x-ray diffraction methods to investigate microstructure and preferred orientation. Smectite (montmorillonite), illite-smectite mixed layers, illite-mica and kaolinite are the major clay components, in addition to quartz and feldspars, which are present in all samples. The observations suggest that the protoliths and the fault rocks were highly altered by fluids. The fluid-rock interactions allow clay minerals to form, as well as alter feldspars to precipitate kaolinite and montmorillonite. Thus, newly formed clay minerals are heterogeneously distributed in the fault zone. The decrease of montmorillonite component of some of the highly deformed samples also suggests that dehydration processes during deformation were leading to illite precipitation. Based on synchrotron x-ray diffraction data, the degree of preferred orientation of constituent clay minerals is weak, with maxima for (001) ranging from 1.3 to 2.6 multiples of a random distribution (m.r.d). Co-existing quartz and feldspars have random orientation distributions. Microstructure and texture observations of the gouges from the foliated microscopic zone, alternating with micrometric isotropic clay-rich area, also indicate that the Bogd fault experienced brittle and ductile deformation episodes. The clay minerals may contribute to a slip weakening behavior of the fault.
ISSN: 0191-8141

insu-00667194
https://hal-insu.archives-ouvertes.fr/insu-00667194
DOI : 10.1016/j.jsg.2011.10.006

Éditeur(s) : HAL CCSD
Résumé : International audience
Mylonite-bearing crustal shear zones are exhumed extensions at depth of (potentially seismogenic) brittle faultsat shallow structural level. By concentrating deformation, shear zones play a major role in the rheology and mechanicalbehavior of the continental crust. Analysis of shear zone geometry and microstructures is a useful toolto decipher deformation kinematics, though finite strain estimation is still relatively qualitative. Timing of thedeformation has also been the focus of numerous studies using the complete spectrum of geochronometers. However,only rare examples provide geochronological data that can be unambiguously linked with deformation. Thus,time-scales over which major mylonite zones develop and remain active under ductile conditions as well as theirstrain rates often remain poorly documented. Several sections across the South Armorican Shear Zone (SASZ),a crustal-scale, several km-thick dextral shear zone were investigated by structural, petrological and Ar/Ar radiochronologicalmethods. Finite strain profiles on these sections showed a strong deformation partitioning towardsthe ultramylonite core of the SASZ, with a decrease, of both the C’/S mean angle (from ca. 45 to less than5) and the Quartz grain-size (from ca. 150 to 5 m). In parallel, conventional and in-situ Ar/Ar datings on thefabric-forming white micas were performed on compositionally complex white-micas. Inherited magmatic muscovitescarried by the foliation and newly-formed, syn-tectonic substituted phengites located along the shear bandsyielded 2 age groups for the less deformed samples. Along the shear zone cross-section, the difference betweenthese two ages evolves from 10-15 Ma in weakly deformed domains to zero toward the SASZ core. In addition, thevery fine-grained syn-tectonic phengites yielded the same ca. 300-298 Ma age irrespectively of their distance to thecore of the shear zone, even in slightly deformed rocks distant by several km. These results support a new modelof crustal-scale shear zone activity, where the whole body of the shear zone is active throughout its history, i.e.the actively deforming zone does not get progressively narrower. The strain distribution nevertheless evolves withtime, with an increasingly larger fraction partitioned in the ultramylonitic core. Besides, combination of the finitestrain estimations and the Ar/Ar ages enables us to assess the range of strain rates associated with mylonitization.
EGU General Assembly 2014
Vienne, Austria

insu-01565057
https://hal-insu.archives-ouvertes.fr/insu-01565057

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Wasilewski et al. (1979) concluded that no magnetic remanence existed in the uppermost mantle and that even if present, such sources would be at temperatures too high to contribute to long wavelength magnetic anomalies (LWMA). However, new collections of unaltered mantle xenoliths indicate that the uppermost mantle could contain ferromagnetic minerals. 1. The analysis of some LWMA over cratons and forearcs suggest magnetic sources in the uppermost mantle. 2. The most common ferromagnetic phase in the uppermost mantle is stoichiometric magnetite. Assuming a 30 km-thick crust, and crustal and mantle geotherms of 15 °C/km and 5 °C/km, respectively, the 600 °C Curie temperature implies a 30 km-thick layer of mantle. 3. The uppermost mantle is cooler than 600 °C in Archean and Proterozoic shields (> 350 °C), subduction zones (> 300 °C) and old oceanic basins (> 250 °C). 4. Recently investigated sets of unaltered mantle xenoliths contain pure magnetite inclusions in olivine and pyroxene formed in equilibrium with the host silicate. 5. The ascent of mantle xenoliths occurs in less than a day. Diffusion rates in olivine suggest that the growth of magnetite possible within this time frame cannot account for the size and distribution of magnetite particles in our samples. 6. Demagnetization of natural remanent magnetization (NRM) of unaltered mantle xenoliths unambiguously indicates only a single component acquired upon cooling at the Earth's surface. This is most easily explained as a thermoremanent magnetization acquired by pre-existing ferromagnetic minerals as xenoliths cool rapidly at the Earth's surface from magmatic temperatures, acquired during ascent. 7. Modern experimental data suggest that the wüstite-magnetite oxygen buffer and the fayalite-magnetite-quartz oxygen buffer extend several tens of km within the uppermost mantle. 8. The magnetic properties of mantle xenoliths vary consistently across tectonic settings. In conclusion, the model of a uniformly non-magnetic mantle should be revisited. Keywords
ISSN: 0040-1951

hal-01053923
https://hal.archives-ouvertes.fr/hal-01053923
DOI : 10.1016/j.tecto.2014.01.004

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In many orogens, high-pressure (HP) metamorphic rocks such as eclogite occur as lenses in quartzofeldspathic gneiss that equilibrated at much lower pressures. The pressure–temperature–time (P–T–t) history of eclogite relative to host gneiss provides information about mechanisms and timescales of exhumation of orogenic crust. The Montagne Noire of the southern Massif Central, France, is an eclogite–bearing gneiss (migmatite) dome located at the orogen-foreland transition of the Variscan belt. Results of our study show that it contains the youngest eclogite in the orogen, similar in age to migmatite and granite that crystallized under low-pressure conditions. P–T conditions for an exceptionally unaltered eclogite from the central Montagne Noire were estimated using a pseudosection supplemented by garnet–clinopyroxene and Zr-in-rutile thermometry. Results indicate peak P∼1.4 GPaP∼1.4 GPa and View the MathML sourceT∼725°C for Mg-rich garnet rim (50 mol% pyrope) + omphacite (36 mol% jadeite) + rutile + quartz. U–Pb geochronology (LA-ICP-MS) of 16 zoned zircon grains yielded ∼360 Ma (4 cores) and ∼315 Ma (12 rims and cores). Rare earth element abundances determined by LA-ICP-MS for dated zircon are consistent with crystallization of ∼315 Ma zircon under garnet-stable, plagioclase-unstable conditions that we interpret to indicate high pressure; in contrast, the ∼360 Ma zircon core corresponds to crystallization under lower pressure plagioclase-stable conditions. Based on garnet zoning and inclusion suites, rutile textures and Zr zoning, P–T results, and zircon petrochronology, we interpret the ∼315 Ma date as the age of eclogite-facies metamorphism that only slightly preceded dome formation and crystallization at 315–300 Ma. This age relation indicates that eclogite formation at high pressure and migmatite dome emplacement at low pressure were closely spaced in time. We propose that collapse-driven material transfer from the hot orogen to the cool foreland resulted in thickening of the orogen edge, leading to eclogite facies metamorphism of the deep crust. Soon after, the low-viscosity partially molten crust flowed from the plateau toward the foreland, incorporating and exhuming eclogite. The P–T–t history of the Montagne Noire eclogite shows that some dome material ascended from >40 km depth to shallow crustal levels, likely in a single decompression event, and that migmatite domes are therefore very efficient at exhuming the deep crust.
ISSN: 0012-821X

hal-01243499
https://hal.archives-ouvertes.fr/hal-01243499
DOI : 10.1016/j.epsl.2015.08.026

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
New U–Pb monazite, zircon, and xenotime ages date the Late Carboniferous crystallization of the anatectic Vialais granite in the Montagne Noire Axial Zone and the high-temperature deformation and metamorphism of the augen gneiss (Ordovician granite protolith) from which the granite was likely derived. The U–Pb monazite ages obtained from the augen gneiss (308 ± 3 Ma), late kinematic Vialais granite (303 ± 4 Ma), and post-kinematic leucogranite (298 ± 2 Ma), bracket the high-temperature deformation and metamorphism at ~ 310–300 Ma, clearly postdating regional contraction and nappe emplacement (> 320 Ma). The planar–linear and locally linear fabrics in the augen gneiss outline a regional-scale double dome structure (Caroux and Espinouse sub-domes) containing smaller (km-scale) upright folds. Compared to the Caroux sub-dome, the larger, migmatitic Espinouse sub-dome contains abundant leucosome, leucogranite bodies and late-kinematic intrusions (Vialais granite). The Vialais granite displays a weak magmatic foliation that defines the main layering of the Espinouse migmatite. Ellipsoidal quartz–sillimanite nodules concentrated above the roof of the granite recorded an increment of strain (vertical shortening, E–NE elongation) during granite emplacement and crystallization, consistent with the extension event that exhumed the domes. These new geochronological and structural data suggest that the Montagne Noire double dome formed in a pull-apart structure within a dextral strike–slip system. Upright folding in the sub-domes has been traditionally assigned to a regional contraction event; alternatively, we propose that local contraction is associated with the convergence of low-viscosity crust beneath the upper crust pull-apart. Dynamic models of extension of hot crust indicate that contraction at depth is generated by flow of low-viscosity orogenic crust converging and rising to fill the gap created by upper crust extension. This interpretation solves the long-standing problem of apparent coeval contraction and extension in the Montagne Noire double dome and establishes migmatite dome emplacement in strike–slip corridors as a style of late Variscan tectonics.
ISSN: 0040-1951

insu-01112009
https://hal-insu.archives-ouvertes.fr/insu-01112009
DOI : 10.1016/j.tecto.2014.12.002

Éditeur(s) : HAL CCSD Nature Publishing Group
Résumé : International audience
Temperature and fluid pressure conditions control rock deformation and mineralization on geological faults, and hence the distribution of earthquakes1. Typical intraplate continental crust has hydrostatic fluid pressure and a near-surface thermal gradient of 31 ± 15 degrees Celsius per kilometre2, 3. At temperatures above 300–450 degrees Celsius, usually found at depths greater than 10–15 kilometres, the intra-crystalline plasticity of quartz and feldspar relieves stress by aseismic creep and earthquakes are infrequent. Hydrothermal conditions control the stability of mineral phases and hence frictional–mechanical processes associated with earthquake rupture cycles, but there are few temperature and fluid pressure data from active plate-bounding faults. Here we report results from a borehole drilled into the upper part of the Alpine Fault, which is late in its cycle of stress accumulation and expected to rupture in a magnitude 8 earthquake in the coming decades4, 5. The borehole (depth 893 metres) revealed a pore fluid pressure gradient exceeding 9 ± 1 per cent above hydrostatic levels and an average geothermal gradient of 125 ± 55 degrees Celsius per kilometre within the hanging wall of the fault. These extreme hydrothermal conditions result from rapid fault movement, which transports rock and heat from depth, and topographically driven fluid movement that concentrates heat into valleys. Shear heating may occur within the fault but is not required to explain our observations. Our data and models show that highly anomalous fluid pressure and temperature gradients in the upper part of the seismogenic zone can be created by positive feedbacks between processes of fault slip, rock fracturing and alteration, and landscape development at plate-bounding faults.
ISSN: 0028-0836

hal-01685757
https://hal.archives-ouvertes.fr/hal-01685757
DOI : 10.1038/nature22355

Éditeur(s) : HAL CCSD
Résumé : International audience
The giant Imiter silver mine located at the northern edge of the West African craton in Morocco is assumed to be a late Neoproterozoic epithermal deposit mainly characterized by a hypogene paragenesis of Agrich sulphides and sulfosalts, and Ag-Hg alloys occuring preferentially in quartz-rich veins. The secondary enrichment zone at Imiter reaches a thickness of 50 to 150 m below ground surface. The upper levels, famous because of giant native silver crystals, grade up to 300 kg/t. Metallographic observations, SEM-EDS and XRD analyses reveal the presence of a quite complex secondary paragenesis made of acanthite, cinnabar, imiterite, perroudite, cerussite, mimetite, iron oxyhydroxides, synchisite and coronadite. Supergene alteration processes of the giant Imiter silver mine deposit consist of the remobilisation of the primary hypogene paragenesis by (i) deep and old basinal brines and (ii) downward infiltrations of surficial waters becoming progressively more reduced and F-enriched in response to fluid-rock interactions. Development of such a supergene mineralization strongly suggests prevalence of arid to semiarid conditions.
Let's talk ore deposits, proceeding of the eleventh biennial sga meeting
Antofagasta, Chile

hal-00601984
https://hal-brgm.archives-ouvertes.fr/hal-00601984
https://hal-brgm.archives-ouvertes.fr/hal-00601984/document
https://hal-brgm.archives-ouvertes.fr/hal-00601984/file/SGA2011_0234.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
People are exposed to multiple pollutants, especially indoors. In the perspective of a cumulative risk assessment, a multi-residue analytical method was developed to assess the contamination of indoor suspended particulate matter by 55 semi-volatile organic compounds (SVOCs) including musk fragrances, organochlorines (OCs), organophosphates (OPs), polycyclic aromatic hydrocarbons (PAHs), polybromodiphenylethers (PBDEs), polychlorobiphenyls (PCBs), phthalates and pyrethroids. It is based on thermal desorption (TD) coupled with gas chromatography/mass spectrometry (GC/MS). Once the thermal desorption conditions were optimized, the method was validated in terms of quantification limits and accuracy using a standard reference material (SRM 2585). Instrumental quantification limits were 10pg (some OCs, some pyrethroids, musk fragrances, OPs, PAHs, PBDEs and PCBs), 100pg (phthalates and other OCs) and 1000pg (other pyrethroids) corresponding respectively to method quantification limits of 1, 10, and 100pg/m(3) for a sampled air volume of 20m(3). Calibration quadratic curves for ranges of 10-1000, 100-10,000, and 1000-100,000pg, depending on the substance, exhibit determination coefficients above 0.999. Recoveries were between 61 and 96% for chlorinated pesticides, PAHs, PBDEs and PCBs present in the SRM 2585. A test of the method on indoor particulate matter samples (PM(10)) collected on quartz fiber filters in French dwellings demonstrated its ability to quantify SVOCs from a small amount of PM.
ISSN: 0021-9673

hal-00732133
https://hal.archives-ouvertes.fr/hal-00732133
DOI : 10.1016/j.chroma.2012.07.025
PUBMED : 22840824

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
[1] The Pyrenees, north of the North Pyrenean fault, display a complex structure involving a succession of peridotite massifs, basement massifs, and mid-Cretaceous to Late Cretaceous basins located in a narrow domain, which was affected by a mid-Cretaceous, preorogenic, high-temperature, low-pressure metamorphism. The Late Cretaceous basins were interpreted either as pull-apart basins formed during transcurrent motion of Iberia relative to Eurasia or as remnants of a larger extensional basin. Recent models support that peridotite massifs result from the exhumation of the mantle during this preorogenic event. The northern boundary of the Agly basement massif shows evidence of ductile deformation of the basal formations of the Agly sedimentary cover. Macroscopic and microscopic kinematics indicators consistent with asymmetry of crystallographic fabrics suggest normal sense of shear and thus suggest detachment, at least partial, of the Mesozoic cover from its basement. Triassic to Early Cretaceous limestones are mylonitic and consistently shows a foliation, a NS- to NE-trending lineation, shear criteria suggesting top-to-the-north shearing and locally boudinage. At the microscopic scale, mylonites are characterized by a very fine grain size, frequently <10 µm. They contain larger, partially recrystallized calcite parent grains and undeformed quartz grains with calcite fringes crystallized in pressure shadows. In these mylonites, calcite systematically shows a weak but well-defined crystallographic-preferred orientations, suggesting HT dislocation creep combined to diffusion creep and possibly grain boundary sliding in the finest fraction of the mylonites. Paleotemperatures determined using Raman spectrometry suggest synkinematic temperature conditions in the range 340-390°C, in good agreement with observed microstructures and calcite CPO. The mylonitic fabric in Mesozoic limestones is folded by EW-trending Pyrenean folds north of the Agly basement massif, attesting that this fabric formed before the Pyrenean orogeny. These data consistently support preorogenic extension under medium-temperature conditions of the northern Agly massif and likely of the massif itself. Since simultaneously (~100 Ma) a mid-Cretaceous basin opened south of the basement massif, we suggest a model of preorogenic exhumation of the Agly massif in response to the regional extension associated to the rotation of Iberia. This model may explain the exhumation of the North Pyrenean massifs during a single preorogenic event that allowed the opening of extensional basins and the exhumation of the lithospheric mantle. All these structures being subsequently reworked during the Pyrenean orogeny.
ISSN: 0278-7407

hal-00852833
https://hal.archives-ouvertes.fr/hal-00852833
DOI : 10.1002/tect.20015

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
Located east of Guadeloupe, the island of La Désirade exhibits the oldest rocks of the Lesser Antilles arc and the eastern Caribbean plate. An old magmatic basement is composed of (1) late Jurassic ophiolitic complex with meta-basaltic pillow lavas and interbedded radiolarites, (2) acid igneous complex comprising meta-quartz-diorite and meta-rhyolitic lavas flows, and (3) meta-diabasic/microdioritic dyke swarm complex. We present and discuss the discovery of synmetamorphic thrust tectonics in this island. Based on detailed structural analysis we evidenced two main compressive events. The first event (D1) is characterized by pervasive folding associated with thrust development. In the northeastern part of the island, a major thrust fault, the Grand Abaque Thrust, has been discovered which displaces for several kilometers the acid igneous complex onto the ophiolitic unit. The second deformation event (D2) is featured by a main pervasive cleavage S2 observed at the regional scale associated with upright folding (F2) and by the development of two sets of conjugated steeply dipping strike-slip shear zones, dextral 130°N and sinistral 20°N striking, respectively. Microstructural observations indicate that Greenschist facies metamorphism is clearly contemporaneous with the development of D1 and D2 superimposed tectonic structures. Ar/Ar geochronology was performed on two bulk of adularia minerals sampled in the northeast volcanic complex within a deformed zone related to a D2 event. These analyses yield well-defined and concordant plateau ages at 106.2 ± 1.7 Ma and 107.2 ± 1.8 Ma. Thus, shortening and thickening tectonics occurred during Lower Cretaceous (Albian). In the available framework of Caribbean geodynamics, the synmetamorphic thrust tectonics we discovered in the French Lesser Antilles is related to the collision between an Aptian-Albian oceanic plateau and the Andean-Cordilleran east-dipping subduction zone. Our results support subduction polarity reversal during Lower Cretaceous.
ISSN: 0278-7407

hal-00620555
https://hal.archives-ouvertes.fr/hal-00620555
DOI : 10.1029/2011TC002875

Éditeur(s) : HAL CCSD
Résumé : Eight drill cores cutting through the Mn-carbonate bearing black shales from the Bangombé Plateau were studied. Mn-carbonates (up to 80 m thick) are underlain by laminated pyrite rich shales with organic carbon contents of about 4 wt. % and MnO contents of about 6 wt. %. Mn and Fe, S poor shales are intercalated. Mn-carbonate rich shales (20-29 wt. % MnO) have low contents of phyllosilicates, but are rich in organic carbon (about 7 wt. %) with moderate S contents (about 2 wt. %). All shale facies were deposited in a closed basin through suspension settling and precipitations under anoxic conditions. The Mn-carbonates, towards the top, were formed most likely under suboxic conditions. Pyrite and Mn-carbonates are characterized by bacteriomorphous structures. The latter are composed of micrometric carbonates finely intergrown with clays, quartz and organic matter. They formed around and corroded the dolomite and/or organic matter. Mn-carbonates and pyrite both form also several tenths of micrometer large agglomerates and sub-automorphous grains. The agglomerates can be attributed to evolving diagenesis. Carbonate chemistry varies mainly from rhodochrosite to dolomite. The present results point to primary microbial Mn-carbonate formation. No signs for a Mn-oxide precursor were detected. Slumping and shearing structures, distortion and disruption of thin pyrite beds indicate synsedimentary deformations.
13th Biennial SGA Meeting
Nancy, France

hal-01356155
https://hal.archives-ouvertes.fr/hal-01356155

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
The chemical and isotopic compositions of clay minerals such as illite and chlorite are commonly used to quantify diagenetic and low-grade metamorphic conditions, an approach that is also used in the present study of the Monte Perdido thrust fault from the South Pyrenean fold-and-thrust belt. The Monte Perdido thrust fault is a shallow thrust juxtaposing upper Cretaceous-Paleocene platform carbonates and Lower Eocene marls and turbidites from the Jaca basin. The core zone of the fault, about 6 m thick, consists of intensely deformed clay-bearing rocks bounded by major shear surfaces. Illite and chlorite are the main hydrous minerals in the fault zone. Illite is oriented along cleavage planes while chlorite formed along shear veins (<50 μm in thickness). Authigenic chlorite provides essential information about the origin of fluids and their temperature. δ18O and δD values of newly formed chlorite support equilibration with sedimentary interstitial water, directly derived from the local hanging wall and footwall during deformation. Given the absence of large-scale fluid flow, the mineralization observed in the thrust faults records the P-T conditions of thrust activity. Temperatures of chlorite formation of about 240°C are obtained via two independent methods: chlorite compositional thermometers and oxygen isotope fractionation between cogenetic chlorite and quartz. Burial depth conditions of 7 km are determined for the Monte Perdido thrust reactivation, coupling calculated temperature and fluid inclusion isochores. The present study demonstrates that both isotopic and thermodynamic methods applied to clay minerals formed in thrust fault are useful to help constrain diagenetic and low-grade metamorphic conditions.
ISSN: 0010-7999

hal-00757736
https://hal.archives-ouvertes.fr/hal-00757736
DOI : 10.1007/s00410-011-0718-0

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Tsavorite, the vanadian variety of green grossular, is a high value economic gemstone. It is hosted exclusively in the metasedimentary formations from the Neoproterozoic Metamorphic Mozambique Belt. The deposits are mined in Kenya, Tanzania and Madagascar and other occurrences are located in Pakistan and East Antarctica. They are located within metasomatized graphitic rocks such as graphitic gneiss and calc-silicates, intercalated with meta-evaporites. Tsavorite is found as primary deposits either in nodule (type I) or in quartz vein (type II), and in placers (type III). The primary mineralizations (types I and II) are controlled by lithostratigraphy and/or structure. For the African occurrences, the protoliths of the host-rocks were deposited at the beginning of the Neoproterozoic within a marine coastal sabkha environment, located at the margin of the Congo-Kalahari cratons in the Mozambique Ocean. During the East African-Antarctican Orogeny, the rocks underwent high amphibolite to granulite facies metamorphism and the formation of tsavorite deposits occurred between 650 and 550 Ma. The nodules of tsavorite were formed during prograde metamorphism, calcium coming from sulphates and carbonates, whereas alumina, silicates, vanadium and chromium probably came from clays and chlorite. The veins were formed during the deformation of the metasedimentary platform units which experienced shearing, leading to the formation of fault-filled veins. Metasomatism developed during retrograde metamorphism. The metasedimentary sequences are characterized by the presence of evaporitic minerals such as gypsum and anhydrite, and scapolite. Evaporites are essential as they provide calcium and permit the mobilization of all the chemical elements for tsavorite formation. The H2S-S8 metamorphic fluids characterized in primary fluid inclusions of tsavorites and the δ11B values of coeval dravite confirm the evaporitic origin of the fluids. The V2O3 and Cr2O3 contents of tsavorite range respectively from 0.05 to 7.5 wt.%, while their δ18O values are in the range of 9.5-21.1‰. The genetic model proposed for tsavorite is metamorphic, based on chemical reactions developed between an initial assemblage composed of gypsum and anhydrite, carbonates and organic matter deposited in a sabkha-like sedimentary basin.
ISSN: 0169-1368

hal-00853279
https://hal.archives-ouvertes.fr/hal-00853279
DOI : 10.1016/j.oregeorev.2013.01.016

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Heletz sandstone (Israel) reactivity is studied by means of CO2-rich brine percolation experiments and modeling. Experiments are performed at in situ temperature and pressure conditions with two distinctly different injection flow rates and for two different brine compositions: the genuine Heletz brine and a similar brine but in equilibrium with gypsum. The Heletz sandstone is composed of quartz, dolomite, ankerite, K-feldspar, clay minerals and minor amounts of gypsum and pyrite. The main reaction is the dissolution of the carbonates which is fastest for the highest flow rate injection and for the genuine Heletz brine. Permeability increases during the five percolation experiments, regardless of flow rate and brine type. This increase in permeability is associated to a decrease in porosity during the gypsum-equilibrated brine experiments due to gypsum precipitation. The precipitation of secondary minerals (kaolinite, muscovite and smectite) is mainly controlled by the dissolution of K-feldspar and largest at low flow rate injection, indicating that these precipitation processes are diffusion-controlled and localized in immobile zones where favorable chemical micro-environments exist. These processes are quantified by means of a reactive transport model. These results indicated that the CO2 injection at the Heletz site should trigger both permeability increase in interface between brine and CO2, which may extend over a large extension and where mixing processes are very active, especially near the well under intermittent injection conditions.
ISSN: 1750-5836

hal-01356329
https://hal.archives-ouvertes.fr/hal-01356329
DOI : 10.1016/j.ijggc.2015.10.023

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The oxygen fugacity and therefore the iron redox state of a melt is known to have a strong influence on the liquid line of descent of magmas and thus on the composition of the coexisting melts and crystals. We present a new method to estimate this critical parameter from electron probe microanalyses of two of the most common minerals of basaltic series, plagioclase and clinopyroxene. This method is not based on stoichiometric calculations, but on the different partitioning behaviour of Fe3+ and Fe2+ between both minerals and a melt phase: plagioclase can incorporate more Fe3+ than Fe2+, while clinopyroxene can incorporate more Fe2+ than Fe3+. For example, the effect of oxidizing a partly molten basaltic system (Fe3+ is stabilized with respect to Fe2+) results in an increase of FeOtotal in plagioclase, but a decrease in the associated clinopyroxene. We propose an equation, based on published partition coefficients, that allows estimating the redox state of a melt from these considerations. An application to a set of experimental and natural data attests the validity of the proposed model. The associated error can be calculated and is on average <1 log unit of the prevailing oxygen fugacity.;In order to reduce the number of different variables influencing the Fe2+/Fe3+ mineral/melt equilibrium, our model is restricted to basaltic series with SiO2<60% that have crystallized at intermediate to low pressure (<0.5 GPa) and under relatively oxidizing conditions (Delta FMQ>0; where FMQ is the fayalite-magnetite-quartz oxygen buffer equilibrium), but it may be parameterized for other conditions. A spreadsheet is provided to assist the use of equations, and to perform the error propagation analysis.
ISSN: 0377-0273

hal-00475550
https://hal.archives-ouvertes.fr/hal-00475550
DOI : 10.1016/j.jvolgeores.2009.11.023

Éditeur(s) : HAL CCSD Geological Society of London
Résumé : International audience
The mylonitic Cambrian quartzites, Moine Thrust Zone, NW Scotland, have long been used to study microstructural and petrofabric evolution and to develop understanding of grain-scale processes accommodating large-scale displacements. Today, structural geology is entering a new age of understanding of the basic processes involved in microstructural evolution due to the emergence of novel instrumental techniques and theoretical models. It seems apposite therefore to re-evaluate the microstructure of one example of this classic quartz mylonite from the Stack of Glencoul, Assynt, using arguably the most important of these new techniques, electron backscattered diffraction (EBSD). The three-dimensional (3D) microstructure and petrofabric of this rock was analysed using EBSD, to: 1) corroborate previous optical and X-ray texture goniometry measurements; 2) investigate the potential for sampling and/or tectonic sectioning bias that may be introduced inadvertently into any petrofabric analysis; and 3) predict its seismic properties. It is found that microstructures do differ between orthogonal structural sections, leading to variations in strengths of different components in the overall petrofabric that might impact on seismic properties. The results emphasize the true 3D nature of microstructures and petrofabrics, which can be recognized and accommodated more readily by this new generation of analytical techniques.
Continental Tectonics and Mountain Building: The Legacy of Peach and Horne

hal-00565749
https://hal.archives-ouvertes.fr/hal-00565749