Éditeur(s) : HAL CCSD Wiley
Résumé : The intensification of the hydrological cycle, with an observed and modeled increase in drought incidence and severity, underscores the need to quantify drought effects on carbon cycling and the terrestrial sink. FLUXNET, a global network of eddy covariance towers, provides dense data streams of meteorological data, and through flux partitioning and gap filling algorithms, estimates of net ecosystem productivity (FNEP), gross ecosystem productivity (P), and ecosystem respiration (R). We analyzed the functional relationship of these three carbon fluxes relative to evaporative fraction (EF), an index of drought and site water status, using monthly data records from 238 micrometeorological tower sites distributed globally across 11 biomes. The analysis was based on relative anomalies of both EF and carbon fluxes and focused on drought episodes by biome and climatic season. Globally P was ≈50% more sensitive to a drought event than R. Network-wide drought-induced decreases in carbon flux averaged −16.6 and −9.3 g C m−2 month−1 for P and R, i.e., drought events induced a net decline in the terrestrial sink. However, in evergreen forests and wetlands drought was coincident with an increase in P or R during parts of the growing season. The most robust relationships between carbon flux and EF occurred during climatic spring for FNEP and in climatic summer for P and R. Upscaling flux sensitivities to a global map showed that spatial patterns for all three carbon fluxes were linked to the distribution of croplands. Agricultural areas exhibited the highest sensitivity whereas the tropical region had minimal sensitivity to drought. Combining gridded flux sensitivities with their uncertainties and the spatial grid of FLUXNET revealed that a more robust quantification of carbon flux response to drought requires additional towers in all biomes of Africa and Asia as well as in the cropland, shrubland, savannah, and wetland biomes globally.
ISSN: 1354-1013

hal-01032076
https://hal.archives-ouvertes.fr/hal-01032076
DOI : 10.1111/j.1365-2486.2009.01991.x

Éditeur(s) : HAL CCSD
Résumé : Differentiation of the lithospheric mantle occurred principally through partial melting and extraction of melts. Harzburgites are generally considered as melting residues whereas lherzolites are regarded as pristine mantle weakly affected by melting. However, some orogenic peridotites show evidence of igneous refertilization. In this context, this work re-investigates the nature of the Lherz lherzolites (Pyrenees), type-locality of lherzolites, described as a piece of preserved fertile mantle. Structural and geochemical data show that these lherzolites are not pristine but formed through a refertilization reaction between MORB-like melts and refractory lithosphere. Moreover, the Lherz peridotites were partly used to infer the composition of the primitive upper mantle and these results may have important implications for the nature of the late veneer. Additionally, crystal-preferred orientations of minerals (CPO) highlight a strong feedback between melt percolation and finite strain in the percolated rocks. CPO variations are ruled by a subtle balance between instantaneous melt fraction and local strain rate. This work also investigated the effect of melt percolation on Hf, Nd and Sr isotopes. Isotope systematics in Lherz shows that strong isotopic decoupling may arise in a percolation front. The modelling suggests that decoupled isotopic signatures are generated during porous flow and governed by the melt/matrix elements concentrations, chemical diffusivities or efficiency of isotopic homogenization. Melt-rock interactions can generate “intraplate-like” isotopic signatures. This suggests that a part of isotopic signatures of mantle-related rocks could be generated by diffusional processes associated with melt transport.
La différenciation du manteau lithosphérique s'est principalement effectuée par fusion partielle et extraction de magmas. Les harzburgites sont généralement considérées comme des résidus de fusion tandis que les lherzolites représentent un manteau originel peu affecté par la fusion. Cependant, certaines péridotites orogéniques montrent des évidences de refertilisation magmatique. Dans ce contexte, ce travail remet en cause la nature primitive des lherzolites de Lherz (Pyrénées), lithotype de la lherzolite. Les données structurales et géochimiques montrent que ces lherzolites ne représentent pas du manteau préservé mais qu'elles se sont formées par une réaction de refertilisation entre un liquide de type MORB et une lithosphère réfractaire. De plus, les orientations préférentielles de réseau (OPR) des minéraux montrent une forte interdépendance entre la percolation magmatique et la déformation finie observée dans les roches percolées. Les variations d'OPR semblent contrôlées par un équilibre subtil entre fraction de liquide instantanée et taux de déformation local. Ce travail a également abordé les effets de la percolation magmatique sur la variabilité isotopique des roches mantelliques. Les résultats montrent qu'un fort découplage isotopique peut s'observer dans un front de percolation. Les modèles suggèrent que le découplage des signatures isotopiques se produit pendant la percolation, gouverné par le rapport des concentrations en éléments (magma/matrice), la diffusivité et le processus d'homogénéisation isotopique. Les réactions magma/roche peuvent générer des signatures isotopiques de type intraplaque. Ceci suggère qu'une part des signatures isotopiques des roches ou laves dérivées du manteau pourrait être produite par des processus diffusionnels associés à du transport de magma.
https://tel.archives-ouvertes.fr/tel-00431325

tel-00431325
https://tel.archives-ouvertes.fr/tel-00431325
https://tel.archives-ouvertes.fr/tel-00431325/document
https://tel.archives-ouvertes.fr/tel-00431325/file/theseleroux08.pdf

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The Ronda orogenic peridotite (southern Spain) contains a variety of pyroxene-rich rocks ranging from high-pressure garnet granulites and pyroxenites to low-pressure plagioclasespinel websterites. The 'asthenospherized' part of the Ronda peridotite contains abundant layered websterites ('group C' pyroxenites), without significant deformation, that occur as swarms of layers showing gradual modal transitions towards their host peridotites. Previous studies have suggested that these layered pyroxenites formed by the replacement of refractory spinel peridotites. Here, we present a major- and trace-element, and numerical modelling study of a layered outcrop of group C pyroxenite near the locality of Tolox aimed at constraining the origin of these pyroxenites after host peridotites by pervasive pyroxene-producing, refertilization meltrock reactions. Mg-number [=Mg/(Mg + Fe) cationic ratio] numerical modelling shows that decreasing Mg-number with increasing pyroxene proportion, characteristic of Ronda group C pyroxenites, can be accounted for by a melt-consuming reaction resulting in the formation of mildly evolved, relatively low Mg-number melts (similar to 0.65) provided that the melt fraction during reaction and the time-integrated melt/rock ratio are high enough (>0.1 and >1, respectively) to balance Mg-Fe buffering by peridotite minerals. This implies strong melt focusing caused by melt channelling in high-porosity domains resulting from compaction processes in a partial melted lithospheric domain below a solidus isotherm represented by the Ronda peridotite recrystallization front. The chondrite-normalized rare earth element (REE) patterns of group C whole-rocks and clinopyroxenes are convex-upward. Numerical modeling of REE variations in clinopyroxene produced by a pyroxene-forming, melt-consuming reaction results in curved trajectories in the (Ce/Nd)(N) vs (Sm/Yb)(N) diagram (where N indicates chondrite normalized). Based on (Ce/Nd)(N) values, two transient, enriched domains between the light REE (LREE)-depleted composition of the initial peridotite and that of the infiltrated melt may be distinguished in the reaction column: (1) a lower domain characterized by convex-upward REE patterns similar to those observed in Ronda group C pyroxeniteperidotite; (2) an upper domain characterized by melts with strongly LREE-enriched compositions. The latter are probably volatile-rich, small-volume melt fractions residual after the refertilization reactions that generated group C pyroxenites, which migrated throughout the massifincluding the unmelted lithospheric spinel-tectonite domain. The Ronda mantle domains affected by pyroxenite- and dunite- or harzburgite-forming reactions (the 'layered granular' subdomain and 'plagioclase-tectonite' domain) are on average more fertile than the residual, 'coarse granular' subdomain at the recrystallization front. This indicates that refertilization traces the moving boundaries of receding cooling of a thinned and partially melted subcontinental lithosphere. This refertilization process may be widespread during transient thinning and melting of depleted subcontinental lithospheric mantle above upwelling asthenospheric mantle.
ISSN: 0022-3530

hal-00412200
https://hal.archives-ouvertes.fr/hal-00412200
DOI : 10.1093/petrology/egn014

Éditeur(s) : HAL CCSD
Résumé : International audience
We consider a nonlocal problem involving the fractional pp-Laplacian operator in bounded smooth domains. A non-existence result is obtained via a comparison process. This result extends those done for the fractional Laplacian.
Rivista di Matematica della Università di Parma

hal-01679139
https://hal.archives-ouvertes.fr/hal-01679139

Éditeur(s) : Gauthier-Villars
Résumé : Mud fields located In the inner part of shelves in front of large estuaries are preferential environments for the investigation of the mechanisms and evolution in time of the supply of such sedimentary bodies. The study of different constituents of the particulate organic matter trapped in the sediments of the West Gironde mud patch contributes to the knowledge of the input origins. This study was carried out with different techniques, including pyrolysis-gas chromatography-mass spectrometry and high performance liquid chromatography, on samples from a core collected in the centre of the mud field. At the bottom of the core, the increase of sugars, amino-sugars and some aromatic hydrocarbons may indicate a more marine character of organic components. The same appears to be the case at the top of the core, where, despite a finer sedimentation, biochemical characteristics could show a more pronounced marine influence than in the middle part. In the middle part of the core, on the other hand, the increase in phenols could result from an increase in lignin-derived. terrestrial inputs. The increase in pyrolysis-derived cyclopentenone may indicate the same terrestrial influence, because this component has its origin in aliphatic polycarboxylic acids resulting from sail leaching. The continental character of the sedimentation is also reflected in the increase of the silt-clay fractions representative of suspended matter originating in the Gironde estuary, associated with a slight carbonate decrease. The taxonomic significance of some phenols is noteworthy: this is especially the case of the cinnamyls which, in the middle part of the core, emphasize the input of herbaceous debris and of the hydroxybenzyls which, at the bottom, provide evidence of the algal origin of part of the organic material. Thus, by means of pyrolysis results and HPLC phenol analysis, it is possible to establish the more or less continental signature of organic components trapped in the ''Ouest-Gironde'' mud patch. This study of organic matter, which confirms earlier sedimentological and micropaleontological data, constitutes a new approach, adapted to the identification of the origin of carbon sources.
Oceanolica Acta (0399-1784) (Gauthier-Villars), 1997 , Vol. 20 , N. 5 , P. 687-695

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00093/20426/18093.pdf
http://archimer.ifremer.fr/doc/00093/20426/

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
A set of synthetic aggregates, containing mixtures of calcite and muscovite, were compacted with varying uniaxial loads ranging from 20 MPa up to 400 MPa. Their elastic properties have been measured using compressional and shear waves in confining hydrostatic pressures up to 475 MPa. Measured seismic velocities are shown to depend on 1) the ratio of calcite to muscovite, 2) the uniaxial load used during sample manufacturing, and 3) the porosity amount prior to velocity measurements. The matrix framework may also affect the seismic velocities, but this effect is not easily quantifiable. In general, measured seismic velocities decrease with increasing muscovite content and porosity. Elastic properties have been calculated based on texture measurements, which were obtained by neutron diffraction. The calculated velocities are based on the calcite and muscovite single crystal elastic tensors, their orientation distribution functions, and their modal fractions. A large discrepancy is apparent between calculated and measured velocities, where the former always overestimate the actual velocities. Shear waves display less of a difference between calculated and measured values, than do compressional waves, indicating that waves propagating by shearing are less affected by sample porosity and matrix framework. A better agreement between measured and calculated seismic velocities arises when the initial porosity is taken into account, using a differential effective medium model. Seismic anisotropy is evident from both measured and calculated velocities, and is low for samples containing pure calcite, but becomes prominent as the muscovite concentration increases. The intensity of anisotropy further depends on the uniaxial load used during sample compaction and the initial porosity.
ISSN: 0148-0227

hal-00512666
https://hal.archives-ouvertes.fr/hal-00512666
DOI : 10.1029/2009JB006523

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Recent research has demonstrated the importance of dermal exposure for some semivolatile organic compounds (SVOCs) present in the gas phase of indoor air. Though models for estimating dermal intake from gaseous SVOCs exist, their predictions can be subject to variations in input parameters, which can lead to large variation in exposure estimations. In this sensitivity analysis for a steady state model, we aimed to assess these variations and their determinants using probabilistic Monte Carlo sampling for 8 SVOCs from different chemical families: phthalates, bisphenols, polycyclic aromatic hydrocarbons (PAHs), organophosphorus (OPs), organochlorines (OCs), synthetic musks, polychlorinated biphenyls (PCBs) and polybromodiphenylethers (PBDEs). Indoor SVOC concentrations were found to be the most influential parameters. Both Henry's law constant (H) and octanol/water partition coefficient (Kow) uncertainty also had significant influence. While exposure media properties such as volume fraction of organic matter in the particle phase (fom-part), particle density (ρpart), concentration ([TSP]) and transport coefficient (ɣd) had a slight influence for some compounds, human parameters such as body weight (W), body surface area (A) and daily exposure (t) make a marginal or null contribution to the variance of dermal intake for a given age group. Inclusion of a parameter sensitivity analysis appears essential to reporting uncertainties in dermal exposure assessment.
ISSN: 0160-4120

hal-01635769
https://hal.archives-ouvertes.fr/hal-01635769
https://hal.archives-ouvertes.fr/hal-01635769/document
https://hal.archives-ouvertes.fr/hal-01635769/file/Pelletier%202017%20Dermal%20expo%20rev2.pdf
DOI : 10.1016/j.envint.2017.02.005

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
A CO2-rich brine core-flood experiment in calcite limestone for conditions representative of underground storage (P = 12 MPa and T = 100°C) was performed in order to explore the dissolution mechanisms arising at moderate CO2 partial pressure (0.3 MPa). An increase of the total porosity (φT) accompanied by a persistent permeability (k) decrease was measured. The mechanisms controlling this atypical anticorrelated k − φT relationship were investigated from the analysis of high-resolution X-ray microtomography images of the sample acquired before and after the experiment. All the evidences converge to the conclusion that the ubiquitous decrease of permeability measured during the 44 h of dissolution is due to the clogging of a fraction of the macroporosity by microporous material triggered by the rearrangement of the detached undissolved particles. This mechanism results in the development of low permeability zones bridging the macroporosity.
ISSN: 0094-8276

hal-00903585
https://hal.archives-ouvertes.fr/hal-00903585
DOI : 10.1002/grl.50595

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Large sand intrusions often exhibit conical morphologies analogous to magmatic intrusions such as saucer-shaped or cup-shaped sills. Whereas some physical processes may be similar, we show with scaled experiments that the formation of conical sand intrusions may be favoured by the pore-pressure gradients prevailing in the host rock before sand injection. Our experiments involve injecting air into a permeable and cohesive analogue material to produce hydraulic fractures while controlling the pore pressure field. We control the state of overpressure in the overburden by applying homogeneous basal pore pressure, and then adding a second local pore pressure field by injecting air via a central injector to initiate hydraulic fractures near the injection point. In experiments involving small vertical effective stresses (small overburden, or high pore fluid overpressure), the fracturing pressure (lambda(fract)) is supralithostatic and two dipping fractures are initiated at the injection point forming a conical structure. From theoretical considerations, we predict that high values of lambda(fract), are due to strong cohesion or high pore fluid overpressure distributed in the overburden. Such conditions are favoured by the pore pressure/stress coupling induced by both pore pressure fields. The dips of cones can be accounted for elastic-stress rotation occurring around the source. Contrary to magmatic chamber models, the aqueous fluid overpressure developed in a parent sandbody (and prevailing before the formation of injectites) may diffuse into the surrounding overburden, thus favouring stress rotation and the formation of inclined sheets far from the parent source. For experiments involving higher vertical effective stresses (thick overburden or low pore fluid overpressure), the fracturing pressure is lower than the lithostatic stress, and a single fracture is opened in mode I which then grows vertically. At a critical depth, the fracture separates into two dilatant branches forming a flat cone. We make use of a P.I.V. (Particle Imaging Velocimetiy) technique to analyse plastic deformation, showing that these inclined fractures are opened in mixed modes. Close to the surface, they change into steep shear bands where fluids can infiltrate. The final morphology of the fracture network is very similar to the common tripartite architecture of various injection complexes, indicating that different mechanisms may be involved in the formation of dykes. Feeder dykes under the sill zones may open as tensile fractures, while overlying dykes may be guided by the deformation induced by the growth of sills. These deformation conditions may also favour the formation of fluid escape structures and pockmarks. (C) 2011 Elsevier B.V. All rights reserved.
ISSN: 0012-821X

hal-00745640
https://hal.archives-ouvertes.fr/hal-00745640
DOI : 10.1016/j.epsl.2011.10.029

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Synthetic hydroxylated titanium-bearing and undoped MgO-buffered forsterite crystals were heated at atmospheric pressure in air at temperatures from 800 to 1200 °C to determine hydrogen diffusion as a function of the type of point-defect mechanism by which the hydroxyl is incorporated. OH-stretching bands, measured by infrared spectroscopy, were assigned to the four substitution mechanisms: Ti-clinohumite point defects, silicon and magnesium vacancies, and point defects associated with trivalent cations. In the experiments at 800 to 1000 °C, hydrous defects related to trivalent cations and Mg-vacancies disappear first in the Ti-doped forsterite, followed by the hydrous defects related to Ti and a fraction of the hydrated Si-vacancies. Measured bulk diffusion coefficients for hydrogen exchange related to the latter process are one order of magnitude slower than previously reported and with higher activation energy (View the MathML source296±14 kJmol−1). After the elimination of the defects related to Ti, the hydroxyl concentration related to Si-vacancies remained constant for the duration of the experiments. This observation is in agreement with the very slow diffusivity of hydrogen in Si-vacancies measured in the undoped MgO-buffered dehydroxylation experiments at higher temperatures (from 1000 to 1200 °C), which were ∼3 orders of magnitude slower than previously reported at 1000 °C, and with an activation energy of View the MathML source461±11 kJmol−1. Hydrogen diffusion in forsterite is far more complex than previously assumed. This complexity can be used to gain more information on the timescales of the processes causing olivine to lose its structural “water”, but quantitative modeling will require not only the knowledge of the intrinsic diffusivities of the different hydrous defects but also their relative proportions and the possible reactions between them.
ISSN: 0012-821X

hal-01172253
https://hal.archives-ouvertes.fr/hal-01172253
DOI : 10.1016/j.epsl.2014.01.055

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This study presents the geochemical composition of superficial sediment under oxic and suboxic bottom water conditions along the Chilean continental margin (SE Pacific), where evidence for benthic chemosynthetic activity associated with diffuse seeping of chemically reduced fluids has been reported. The exploration was carried out at: (1) the Chilean Triple Junction (CTJ), at a water depth of ∼2900 m, with the additional indication of hydrothermal activity near a methane-rich cold-seep area (46°S) (German et al., 2010); and (2) the El Quisco methane seep site (EQSS), at ∼340 m water depth (33°S) (Melo et al., 2007; Krylova et al., 2014). While the deeper CTJ is located within an oxic environment (dissolved oxygen in the bottom waters: 164 μM), the shallower EQSS lies within a suboxic environment (dissolved oxygen in bottom water: 23 μM), located within the lower limit of the SE Pacific oxygen minimum zone (OMZ).Pore water from short cores was analyzed for dissolved major, minor, and trace elements (Cl, Na, Mg, K, Ca, Sr, Si, B, P, Ba, Pb, Mn, Fe, Cd, U, and Mo), δ13DIC, sulfide, sulfate, and methane. The solid sediment fraction was likewise analyzed for total organic carbon (TOC), metals, and redox potential. Elevated sediment temperatures were found in superficial sediments (5–13 °C) at the CTJ site, which could be due to warm fluids associated with the proximity of the ridge, where hydrothermal vents may occur. Reduced fluids were also present here, indicated by higher Mn fluxes toward the water column even in oxidized sediments (RPD > 8 cm), which contrasted with the lower fluxes in reduced sediments of the EQSS site (RPD ∼ 2 cm). 13C-depleted DIC, anomalously low pore water Cl (∼15 ppb), and low concentrations of other major elements may be the result of dilution by fluid seeping and precipitation of major elements, producing authigenic enrichment (Ca, Mg, Sr). The fluid could also: (a) be diluted by pure water produced during methane hydrate dissociation, as observed in other cold-seep areas; and (b) correspond to clay mineral dehydration, as reported in plate subduction systems. The reducing conditions established at the CTJ conduct the Cd enrichment at a similar magnitude of that seen at the shallower suboxic site (EQSS). Evidence of chimney or vent fauna was not observed. At the EQSS, higher TOC and total sulfide contents were consistent with enhanced deposition of organic matter and reducing conditions developed in the OMZ, favoring the authigenic enrichment of Cd, U and Pb. The geochemical evidence, based only on methane concentrations and δ13DIC, is insufficient to establish the presence of methane seeps, as previously reported.
ISSN: 0079-6611

hal-01412700
https://hal.archives-ouvertes.fr/hal-01412700
DOI : 10.1016/j.pocean.2016.09.002

Résumé : Ce travail décrit la mise au point d'un milieu gélosé semi-sélectif visant à mettre en évidence les Vibrio penaecida en élevage larvaire de pénéides. Le ZoBell-Mannitol-Saccharose-Bleu de bromothymol (ZMSB) a un pH élevé, une forte teneur en sels et ne possède que deux sucres acidifiables, le mannitol et le saccharose. Ce milieu peut être utilisé pour la sélection d'un grand nombre d'espèces du genre Vibrio. La salinité et le ph séparent le germe cherché d'une fraction importante d'espèces de Vibrio, et l'acidification du mannitol et du saccharose révèlent (par le changement de couleur du milieu) les Vibrio de type penaecida qui présentent cette caractéristique. De plus, un milieu minimum comme le ZoBell, additionné de glycérol, permet d'augmenter considérablement la production de pigments noirs (grisâtres) insolubles qui s'accumulent sous forme cristalline chez certaines colonies bactériennes comme Vibrio nigripulchritudo, facilitant ainsi la distinction d'espèces physiologiquement proches comme V. penaecida. Les différents aspects des souches testées sont alors observés par repiquages à l'aide de tampons et permettent d'obtenir des images comparables par superposition. Sur les 26 souches testées une seule présente un aspect comparable à V. penaecida sur ZMSB. Ce Vibrio (V. nigripulchritudo) est facilement différenciable de V. penaecida par culture en milieu ZoBell additionné de glycérol. On peut donc conclure à une bonne spécificité du milieu en question et du procédé de repiquage utilisé. En cas de doutes, la présence de V. penaecida est confirmées par quelques tests biochimiques simples. Un protocoles de fabrication d'un sérum anti V. penaecida est également testé.

Droits : 1997 The author, Univ. Caen, Ifremer
http://archimer.ifremer.fr/doc/00032/14340/11624.pdf
http://archimer.ifremer.fr/doc/00032/14340/

Éditeur(s) : Pergamon-elsevier Science Ltd
Résumé : The EUNIS (European Union Nature Information System) habitat classification system aims to provide a common European reference set of habitat types within a hierarchical classification, and to cover all terrestrial, freshwater and marine habitats of Europe. The classification facilitates reporting of habitat data in a comparable manner, for use in nature conservation (e.g. inventories, monitoring and assessments), habitat mapping and environmental management. For the marine environment the importance of a univocal habitat classification system is confirmed by the fact that many European initiatives, aimed at marine mapping, assessment and reporting, are increasingly using EUNIS habitat categories and respective codes. For this reason substantial efforts have been made to include information on marine benthic habitats from different regions, aiming to provide a comprehensive geographical coverage of European seas. However, there still remain many concerns on its applicability as only a small fraction of Europe's seas are fully mapped and increasing knowledge and application raise further issues to be resolved. This paper presents an overview of the main discussion and conclusions of a workshop, organised by the MeshAtlantic project, focusing upon the experience in using the EUNIS habitats classification across different countries and seas, together with case studies. The aims of the meeting were to: (i) bring together scientists with exper_ience_in the use of the EUNIS marine classification and representatives from the European Environment Agency (EEA); (ii) agree on enhancements to EUNIS that ensure an improved representation of the European marine habitats; and (iii) establish practices that make marine habitat maps produced by scientists more consistent with the needs of managers and decision-makers. During the workshop challenges for the future development of EUNIS were identified, which have been classified into five categories: (1) structure and hierarchy; (2) biology; (3) terminology; (4) mapping; and (5) future development. The workshop ended with a declaration from the attendees, with recommendations to the EEA and European Topic Centre on Biological Diversity, to take into account the outputs of the workshop, which identify weaknesses in the current classification and include proposals for its modification, and to devise a process to further develop the marine component of the EUNIS habitat classification. (C) 2012 Elsevier Ltd. All rights reserved.
Marine Pollution Bulletin (0025-326X) (Pergamon-elsevier Science Ltd), 2012-12 , Vol. 64 , N. 12 , P. 2630-2638

Droits : 2012 Elsevier Ltd. All rights reserved.
http://archimer.ifremer.fr/doc/00125/23663/22686.pdf
DOI:10.1016/j.marpolbul.2012.10.010
http://archimer.ifremer.fr/doc/00125/23663/

Résumé : L'espèce Ludwigia leptocarpa (Onagracées) présente dans le paysage antillais est méconnue par la population locale. Pourtant, au Nigéria, ses feuilles sont préconisées pour traiter les rhumatismes, la dysenterie et pour leurs vertus laxative et vermifuge. L'absence de données phytochimiques sur cette plante justifie le choix de notre étude. Un criblage phytochimique réalisé sur les extraits bmts de feuilles, de fruits et de tiges a mis en évidence la présence de terpénoïdes dans les extraits hexane et dichlorométhane et des acides phénoliques et flavonoïdes dans les extraits méthanol et eau. L'évaluation du potentiel biologique des extraits apolaires des feuilles a révélé des activités antibiotique (E. coli et S. aureus) et anti-inflammatoire intéressantes. Les extraits plus polaires présentent des potentiels antioxydant, antibiotique (E. coli et S. aureus), antifongique (c. albicans et C. tropica/is), et antiviral (HSV-l) significatifs. L'étude des fractions volatiles de feuilles, de tiges et des parties aériennes par microextraction en phase solide a conduit à l'identification de 54 composés. Les analyses GC/MS menées sur les extraits apolaires de feuilles et de fruits ont mis en évidence la présence d'acides gras, de triterpènes et de stéroïdes. Le fractionnement et la purification des extraits polaires de feuilles ont mené à l'isolation et l'identification de 8 composés phénoliques parmi lesquels 1 acide polyhydroxylé, 3 acides phénoliques, 2 flavonoïdes et 2 tanins galliques. L'apport de nouvelles données scientifiques sur 1. leptocarpa contribue à la valorisation de cette matière végétale locale et laisse entrevoir des perspectives de recherche et d'application
Ludwigia Leptocarpa species (Onagraceae) is present in Caribean landscape, it remains unknown by French West Indies population. However, in Nigeria the leaves are recommended to treat rheumatism, dysentery and as laxative or deworming. The lack of data phytochemical on this plant justifies our study choice. A phytochemical screening carried out on crude extracts from leaves, fruits and stems highlighted terpenoids presence in hexane and dichloromethane crude extracts and phenolic compounds (phenolic acids and flavonoids) in methanol and water cmde extracts. The biological potentials evaluation of apolar extracts showed interesting antibiotic (E. coli and S. aureus) and inflammatory activities. Polar extracts present antioxidant, antibiotic (E. coli and S. aureus), antifungal (C albicans and C tropicalis), and viral (HSV-l) potential. Volatile fraction study of lcave, stems and aerial parts by Solid Phase MicroExtraction (SPME) 100 to theidentification of 54 compounds. GCIMS analysis conducted on leaves and fruits apolar extracts underlined the presence of fatty acid, triterpenes and steroids. Leaves polar extract fractionnation and purification resulted to isolation and identification of 8 phenolic componuds including 1 polyhydroxylated acid, 3 phenolic acids, 2 flavonoids and 2 gallic tannins. The addition of new scientific data on L. /eptocarpa contributes to the enhancement of this local plant rnaterial and suggests many opportunities for research and application

http://www.theses.fr/2013AGUY0676/document

Éditeur(s) : HAL CCSD Oxford University Press (OUP): Policy B - Oxford Open Option B
Résumé : Variability of leaf traits related to photosynthesis was assessed in seedlings from 14 tree species growing in the tropical rain forest of French Guiana. Leaf photosynthetic capacity (maximum rate of carboxylation and maximum rate of electron transport) was estimated by fitting a biochemical model of photosynthesis to response curves of net CO2 assimilation rate versus intercellular CO2 mole fraction. Leaf morphology described by leaf mass per unit leaf area (LMA), density and thickness, as well as area- and mass-based nitrogen (N) and carbon (C) concentrations, were recorded on the same leaves. Large interspecific variability was detected in photosynthetic capacity as well as in leaf structure and leaf N and C concentrations. No correlation was found between leaf thickness and density. The correlations between area- and massbased leaf N concentration and photosynthetic capacity were poor. Conversely, the species differed greatly in relativeNallocation to carboxylation and bioenergetics. Principal component analysis (PCA) revealed that, of the recorded traits, only the computed fraction of total leafNinvested in photosynthesis was tightly correlated to photosynthetic capacity.We also used PCAto test to what extent species with similar shade tolerances displayed converging leaf traits related to photosynthesis. No clear-cut ranking could be detected among the shade-tolerant groups, as confirmed by a one-way ANOVA.We conclude that the large interspecific diversity in photosynthetic capacity was mostly explained by differences in the relative allocation of N to photosynthesis and not by leafNconcentration, and that leaf traits related to photosynthetic capacity did not discriminate shade-tolerance ranking of these tropical tree species.
ISSN: 0829-318X

hal-01031522
https://hal.archives-ouvertes.fr/hal-01031522

Éditeur(s) : HAL CCSD
Résumé : International audience
Environmental context The safeguarding of water supplies and drinking water is a major issue when considering human health risk management. In this context, an automatic and on-site fractionation system for the detection of organic contaminants has been developed. The main goal of this system is to establish an initial diagnosis by identifying a class of substances involved in a case of pollution. Abstract This paper proposes a new approach for the preconcentration, fractionation, prediction and detection of organic micropollutants in water. The main aim of this study was to implement an innovative fractionation method and a prediction model based on the physicochemical properties of compounds and interactions with the sorbent of solid-phase extraction cartridges. Two sorbents (Strata-SAX and Oasis-HLB) and three specific eluting solvents (mixture of methanol and sodium chloride and mixtures of acetonitrile and ultrapure water) were used to separate organic compounds into five specific fractions according to their physicochemical properties (anionic and cationic or neutral compounds with various polarity). More than 75 molecules (43 molecules individually studied and a mixture with 43 molecules, including 11 molecules individually studied) including pesticides, pharmaceuticals, endocrine disruptors and polycyclic aromatic hydrocarbons, with various properties were studied, and the results showed that the elution fraction can be predicted for more than 85% of the compounds. This methodology could simplify the analytical chain by reducing detailed analysis on limited categories of compounds, and could be used for a rapid and on-site screening of organic compounds. © CSIRO 2016.
Environmental Chemistry

hal-01373945
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01373945
DOI : 10.1071/EN15135

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We develop a block model for the Aegean and surrounding areas, constrained by Global Positioning System (GPS), in order to investigate the degree of coupling on the Hellenic subduction interface (i.e., the fraction of the motion across the plate boundary accommodated by elastic strain accumulation). We use previously published models, and seismicity to define the geometry of the interface separating the down-going Nubian slab from the overriding Aegean. This model provides a good fit to the GPS observations; for the ∼200,000 km2 Aegean block the wrms of the residual velocities is 1.4 mm/yr for 80 GPS velocity estimates, approximately the 95% level of the GPS velocity uncertainties. We investigate the degree of coupling on the seismically active plate interface, the Hellenic trench splay fault (believed to be the source of the 365 AD Great Crete Earthquake and Tsunami), and the Kephalonia transform fault by comparing the modeled GPS residual velocity field for a range of coupling values. The GPS observations are almost insensitive to coupling on the Kephalonia transform fault, because of the vertical dip of the fault that creates interseismic deformation only close to the fault where few GPS sites exist. The absence of resolvable shortening of the leading edge of the Aegean Plate precludes coupling of more than 0.2 (20% of the full Nubia-Aegean convergence rate) on the modeled plate interface. Because of the shallow dip of the plate interface and trench splay fault, and high rate of convergence, if these boundaries were fully coupled, high elastic strain rates would be expected to extend well into the overriding Aegean plate. Based on our preferred value for the degree of coupling (0.1), and assuming characteristic earthquake behavior, we estimate a recurrence time for great earthquakes with slip similar to that for the 365 Crete event of 5700-8300 yr, consistent with the absence of subsequent great earthquakes on this segment of the subduction zone.
ISSN: 0012-821X

hal-01053486
https://hal.archives-ouvertes.fr/hal-01053486
DOI : 10.1016/j.epsl.2013.10.018

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The platinum-group element (PGE) systematics of continental mantle peridotites show large variability, reflecting petrogenetic processing of the upper mantle during partial melting and melt/fluid percolation inside the lithosphere. By removing Pd-Cu-Ni rich sulfides, partial melting events that have stabilized the sub-continental mantle lithosphere fractionated PPGEs (Palladium-group PGE; Pt, Pd) relative to IPGEs (Iridium-group PGE; Os, Ir, Ru, Rh). Residual base-metal sulfides (BMS) survive as enclosed IPGE-enriched Monosulfide Solid Solutions (Mss), which otherwise decompose into Ru-Os-Ir-rich refractory platinum-group minerals (PGMs) once the partial melts become S-undersaturated. The small-scale heterogeneous distribution of these microphases may cause extreme nugget effects, as seen in the huge variations in absolute PGE concentrations documented in cratonic peridotites. Magmas fluxing through the lithospheric mantle may change the initial PGE budgets inherited from the melting events, resulting in the great diversity of PGE systematics seen in peridotites from the sub-continental lithosphere. For instance, melt-rock reactions at increasing melt/rock ratios operate as open-system melting processes removing residual BMS/PGMs. Highly percolated peridotites are characterized by extreme PGE depletion, coupled with PGE patterns and Os-isotope compositions that gradually evolve toward that of the percolating melt. Reactions at decreasing melt-rock ratios (usually referred to as "mantle metasomatism") precipitate PPGE-enriched BMS that yield suprachondritic Pd/Ir and occasionally affect Pt/Ir and Rh/Ir ratios as well. Moreover, volatile-rich, small volume melts fractionate Os relative to Ir and S relative to Se, thereby producing rocks with supra-chondritic Os/Ir and S/Se coupled with supra-chondritic Pd/Ir and Pt/Ir. Major magmatic inputs at the lithosphere-asthenosphere boundary may rejuvenate the PGE systematics of the depleted mantle. Integrated studies of "refertilized" peridotites with worldwide provenance provide evidence for mixing between old PGM-rich harzburgitic protoliths and newly-precipitated BMS. Long-lived PGMs carry the Os-isotope compositions of ancient melt‐depletion events into seemingly undepleted fertile lherzolites. Another diagnostic feature of major refertilization processes is the increasing modal abundance of Pt-Pd-Te-Bi or Pt-As-S microphases. Due to regional-scale refertilization processes, sizeable (> 100 km) domains of the upper lithospheric mantle are now significantly enriched in Pd, Au, Cu, Se, and other incompatible chalcophile elements that are of considerable importance in PGE-ore forming events.
ISSN: 0024-4937

hal-00828626
https://hal.archives-ouvertes.fr/hal-00828626
DOI : 10.1016/j.lithos.2012.08.017

Éditeur(s) : HAL CCSD
Résumé : International audience
Mylonite-bearing crustal shear zones are exhumed extensions at depth of (potentially seismogenic) brittle faultsat shallow structural level. By concentrating deformation, shear zones play a major role in the rheology and mechanicalbehavior of the continental crust. Analysis of shear zone geometry and microstructures is a useful toolto decipher deformation kinematics, though finite strain estimation is still relatively qualitative. Timing of thedeformation has also been the focus of numerous studies using the complete spectrum of geochronometers. However,only rare examples provide geochronological data that can be unambiguously linked with deformation. Thus,time-scales over which major mylonite zones develop and remain active under ductile conditions as well as theirstrain rates often remain poorly documented. Several sections across the South Armorican Shear Zone (SASZ),a crustal-scale, several km-thick dextral shear zone were investigated by structural, petrological and Ar/Ar radiochronologicalmethods. Finite strain profiles on these sections showed a strong deformation partitioning towardsthe ultramylonite core of the SASZ, with a decrease, of both the C’/S mean angle (from ca. 45 to less than5) and the Quartz grain-size (from ca. 150 to 5 m). In parallel, conventional and in-situ Ar/Ar datings on thefabric-forming white micas were performed on compositionally complex white-micas. Inherited magmatic muscovitescarried by the foliation and newly-formed, syn-tectonic substituted phengites located along the shear bandsyielded 2 age groups for the less deformed samples. Along the shear zone cross-section, the difference betweenthese two ages evolves from 10-15 Ma in weakly deformed domains to zero toward the SASZ core. In addition, thevery fine-grained syn-tectonic phengites yielded the same ca. 300-298 Ma age irrespectively of their distance to thecore of the shear zone, even in slightly deformed rocks distant by several km. These results support a new modelof crustal-scale shear zone activity, where the whole body of the shear zone is active throughout its history, i.e.the actively deforming zone does not get progressively narrower. The strain distribution nevertheless evolves withtime, with an increasingly larger fraction partitioned in the ultramylonitic core. Besides, combination of the finitestrain estimations and the Ar/Ar ages enables us to assess the range of strain rates associated with mylonitization.
EGU General Assembly 2014
Vienne, Austria

insu-01565057
https://hal-insu.archives-ouvertes.fr/insu-01565057

Éditeur(s) : HAL CCSD
Résumé : A section of ancient fast-spreading ocean crust was sampled at Wadi Gideah, located in the Wadi Tayin Massif of the Oman ophiolite. This sample suite was used for generating a coherent data set combining various petro-geochemical and structural investigations, with the aim of building a reference section for advancing our understanding of crustal accretion processes at fast-spreading mid-ocean ridges. Additionally, this study focuses on one outcrop that represents part of the fossil axial melt lens (AML).Major and trace element analyses reveal a trend of chemical evolution up section in the lower crust, with a marked difference between the layered gabbros and the foliated gabbros above. Petrological modeling shows that the chemical evolution up section can be produced by hydrous fractionation crystallization, with melt H2O contents of ~0.8 wt% and 0.8 to 1.2 wt% for the lower and upper crust, respectively. Together with the observed very steep bulk Zr/Hf vs. Zr gradient, high F and Cl content of magmatic amphibole, general Nb-Ta depletion of melts compared with NMORB, and high Sr87/Sr86 ratio compared with modern fast-spread crust, this suggests that Wadi Gideah layered gabbros were accreted by crystallization of ascending melts in sills, in a context of subduction initiation. The distinct changes in chemical trends and average grain size at the layered to foliated gabbro transition are tentatively explained by enhanced hydrothermal cooling deeper than the AML. The gabbro/dike transition displays complex structural and lithological relationships that, together with fractional crystallization modeling, point to episodic vertical movements of the AML. Plagioclase crystallographic preferred orientations (CPO) measured over the whole gabbro section are always consistent with magmatic flow. The CPO strength generally increases downward, with more scattering in the layered gabbro section. From the top to the bottom of the layered gabbros, CPO become progressively more prolate, possibly reflecting increasing shear induced by active mantle flow underneath.Wadi Gideah lower crust recorded a formation history consistent with a hybrid accretion model, combing several processes such as downward magmatic flow and/or upward melt migration in the upper foliated gabbros, sill intrusions in the layered gabbros, and deep hydrothermal circulation. The latter was presumably focused in channels, preserved today as several, up to 100 m wide zones of extensively altered former layered gabbro, cross-cutting the magmatic layering. These metagabbros display significantly higher Sr87/Sr86 ratio, late stage magmatic phases, and evidence for high temperature partial melting.
Une coupe d'ancienne croute océanique rapide a été échantillonnée dans le Wadi Gideah, situé dans le Massif de Wadi Tayin de l'Ophiolite d'Oman. Cette série d'échantillons a permis de générer un jeu de données cohérent, combinant des études pétro-géochimiques et structurales, dans le but de construire une coupe de référence pour mieux contraindre notre compréhension des processus d'accrétion crustale aux dorsales océaniques rapides. Ce travail intègre aussi l'étude détaillée d'un affleurement représentant en partie la lentille magmatique axiale (LMA) fossile.Les analyses d'éléments majeurs et traces révèlent une évolution chimique dans la croûte inférieure, avec une nette différence entre les gabbros lités et les gabbros foliés sus-jacents. La modélisation pétrologique montre que l'évolution chimique vers le haut peut être produite par cristallisation fractionnée hydratée, avec des teneurs en H2O des magmas de ~0.8 wt% dans la croute inférieure et 0.8 to 1.2 wt% dans la croute supérieure. Combiné aux forts gradients de Zr/Hf vs. Zr, aux teneurs élevées de F et Cl dans les amphiboles magmatiques, à l'appauvrissement général en Nb-Ta des magmas comparé aux NMORB, et aux rapports Sr87/Sr86 élevés comparés à la croûte rapide moderne, ceci suggère que les gabbros lités du Wadi Gideah ont été formés par la cristallisation des magmas ascendants dans des sills, dans un contexte d'initiation de subduction. Les changements de signature géochimique et de taille de grain à la transition entre gabbros lités et gabbros foliés témoignent possiblement d'un fort refroidissement hydrothermal plus profond que la LMA. La transition complexe filonien/gabbro montre des relations structurale et lithologiques complexes, qui, combinées o la modélisation de la cristallisation fractionnée, traduisent les mouvements verticaux épisodiques de la LMA. Les orientations préférentielles cristallographiques (OPC) des plagioclases mesurées sur l'ensemble de la coupe dans les gabbros témoignent toujours d'une déformation magmatique. L'intensité des OPC a tendance à augmenter vers le bas, avec une plus forte variabilité dans les gabbros lités. Dans les gabbros lités, les OPC sont de plus en plus linéaires vers le bas, résultant possiblement d'un cisaillement plus fort induit par l'écoulement actif du manteau sous-jacent.La croûte inférieure dans le Wadi Gideah a enregistré une histoire compatible avec un modèle d'accrétion hydride, combinant plusieurs processus tels que l'écoulement magmatique vers le bas et/ou la migration de liquides magmatiques vers le haut dans les gabbros foliés supérieurs, l'intrusion de sills dans les gabbros lités, et une circulation hydrothermale profonde. Cette dernière était probablement concentrée dans des chenaux, préservés aujourd'hui sous la forme de plusieurs zones, dont l'épaisseur atteint 100 m, de gabbros lités fortement altérés, recoupant le litage magmatique. Ces métagabbros ont des rapports Sr87/Sr86 élevés, comportent des phases magmatiques tardives et montrent des évidences de fusion partielle.
https://hal.archives-ouvertes.fr/tel-01302675

tel-01302675
https://hal.archives-ouvertes.fr/tel-01302675
https://hal.archives-ouvertes.fr/tel-01302675/document
https://hal.archives-ouvertes.fr/tel-01302675/file/Th%C3%A8se_Tim-Mueller_2015.pdf