Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In petroleum industry, the difference between pore pressure (Pp) and minimum horizontal stress Sh (termed the seal or retention capacity) is of major consideration because it is often assumed to represent how close a system is to hydraulic failure and thus the maximum hydrocarbon column height that can be maintained. While Sh and Pp are often considered to be independent parameters, several studies in the last decade have demonstrated that Sh and Pp are in fact coupled. However, the nature of this coupling relationship remains poorly understood. In this paper, we explore the influences of the spatial pore pressure distribution on Sh/Pp coupling and then on failure pressure predictions and trap integrity evaluation. With analytical models, we predict the fluid pressure sustainable within a reservoir before failure of its overpressured shale cover. We verify our analytical predictions with experiments involving analogue materials and fluids. We show that hydraulic fracturing and seal breach occur for fluid pressure greater than it would be expected from conventional retention capacity. This can be explained by the impact of the fluid overpressure field in the overburden and the pressure diffusion around the reservoir on the principal stresses. We calculate that supralithostatic pressure could locally be reached in overpressured covers. We also define the retention capacity of a cover (RC) surrounding a fluid source or reservoir as the difference between the failure pressure and the fluid overpressure prevailing in shale at the same depth. In response to a localized fluid pressure rise, we show that the retention capacity does not only depend on the pore fluid overpressure of the overburden but also on the tensile strength of the cover, its Poisson's ratio, and the depth and width of the fluid source.
ISSN: 0264-8172

hal-00590497
https://hal.archives-ouvertes.fr/hal-00590497
DOI : 10.1016/j.marpetgeo.2010.08.007

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
We present a 2-D Contact Dynamics discrete element model for simulating initiation and motion of rock avalanches, integrating hillslope geometry, Mohr-Coulomb rock behavior, pore pressure before avalanche triggering, and avalanche trigger. Avalanche motion is modeled as a dense granular flow of dry frictional and cohesive particles. On the basis of granular physics and shear experiments, we review some of the theories for the unexpectedly long runout of rock avalanches. Different causes are evoked, according to the strength (strong or weak) of the slip surface relative to the bulk. "Mechanical fluidization'' and "acoustic fluidization'' theories state that agitation of rock particles reduces frictional strength, increasing runout. Conversely, granular mechanics suggests that, as "shear-strain'' rate increases, granular material becomes more agitated, more dissipative, and more resistant. Another theory states that dynamic fragmentation of clasts creates an isotropic pressure that drives longer runout. In contrast, granular mechanics suggests that fragmentation may induce fluidization and strengthening of the granular material, while particle size reduction (among others) induces weakening of the granular flow and enhances long runout. Runout is also enhanced for column-like rock masses collapsing from steep hillslopes. Long runout may also be linked to thermal weakening mechanisms at the slip surface (e.g., thermal pressurization, and shear melting), which may lower drastically the shear strength. The model is illustrated with a hypothetical example of a rain-triggered avalanche, mobilizing shallowly dipping layers. Several phases are identified, including slope failure, avalanche triggering resulting from slip weakening, and avalanche motion in which rocks are folded and sheared.
ISSN: 0148-0227

hal-00420883
https://hal.archives-ouvertes.fr/hal-00420883
DOI : 10.1029/2008JF001072

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Large sand intrusions often exhibit conical morphologies analogous to magmatic intrusions such as saucer-shaped or cup-shaped sills. Whereas some physical processes may be similar, we show with scaled experiments that the formation of conical sand intrusions may be favoured by the pore-pressure gradients prevailing in the host rock before sand injection. Our experiments involve injecting air into a permeable and cohesive analogue material to produce hydraulic fractures while controlling the pore pressure field. We control the state of overpressure in the overburden by applying homogeneous basal pore pressure, and then adding a second local pore pressure field by injecting air via a central injector to initiate hydraulic fractures near the injection point. In experiments involving small vertical effective stresses (small overburden, or high pore fluid overpressure), the fracturing pressure (lambda(fract)) is supralithostatic and two dipping fractures are initiated at the injection point forming a conical structure. From theoretical considerations, we predict that high values of lambda(fract), are due to strong cohesion or high pore fluid overpressure distributed in the overburden. Such conditions are favoured by the pore pressure/stress coupling induced by both pore pressure fields. The dips of cones can be accounted for elastic-stress rotation occurring around the source. Contrary to magmatic chamber models, the aqueous fluid overpressure developed in a parent sandbody (and prevailing before the formation of injectites) may diffuse into the surrounding overburden, thus favouring stress rotation and the formation of inclined sheets far from the parent source. For experiments involving higher vertical effective stresses (thick overburden or low pore fluid overpressure), the fracturing pressure is lower than the lithostatic stress, and a single fracture is opened in mode I which then grows vertically. At a critical depth, the fracture separates into two dilatant branches forming a flat cone. We make use of a P.I.V. (Particle Imaging Velocimetiy) technique to analyse plastic deformation, showing that these inclined fractures are opened in mixed modes. Close to the surface, they change into steep shear bands where fluids can infiltrate. The final morphology of the fracture network is very similar to the common tripartite architecture of various injection complexes, indicating that different mechanisms may be involved in the formation of dykes. Feeder dykes under the sill zones may open as tensile fractures, while overlying dykes may be guided by the deformation induced by the growth of sills. These deformation conditions may also favour the formation of fluid escape structures and pockmarks. (C) 2011 Elsevier B.V. All rights reserved.
ISSN: 0012-821X

hal-00745640
https://hal.archives-ouvertes.fr/hal-00745640
DOI : 10.1016/j.epsl.2011.10.029

Éditeur(s) : Terrapub
Résumé : A series of empirical expressions for predicting gas hydrate stability, its volume fraction out of pore space and gas hydrate mass-density were established in different systems in consideration of gas composition (CH4, C2H6, H2S) and salinity (NaCl, seawater), and pore size at temperature between 273.15 and 300 K, based on our gas hydrate thermodynamic model (Sultan et al., 2004b, c). Six of the developed expressions for predicting gas hydrate stability were validated against the available published experimental data and they were also compared with other models. At temperature 273.15 to 290.15 K, the ARDPs (Average Relative Deviation of Pressures between the prediction and the experimental data) have shown that these empirical expressions are in agreement with the experimental data as well as other models, indicating their reliability of predicting gas hydrate stability for these systems. At higher temperatures, the empirical predictions for gas hydrate stability do not well reproduce the experimental data, because they are based on van der Waals model. The empirical expressions for predicting gas hydrate stability in the systems of CH4 + H2S + H2O, CH4 + seawater + poresize, CH4 + H2S + NaCl and CH4 + CO2 + NaCl, and for evaluating gas hydrate fraction and its density need further validation due to lack of available published experimental data. However, the empirical expressions for gas hydrate fraction and its density show that the effects of pore size and salinity are negligible; gas hydrate fraction will increase if methane concentration continuously increases relatively in excess of methane solubility and decreases with pressure within gas hydrate stability zone, which is well consistent with data of natural gas hydrates in Cascadia; gas hydrate density tends to increase with ethane percentage and decrease with pressure.
Geochemical Journal (0016-7002) (Terrapub), 2008-03 , Vol. 42 , N. 2 , P. 163-175

Droits : 2008 TERRAPUB. The Geochemical Society of Japan.
http://archimer.ifremer.fr/doc/2008/publication-4958.pdf
http://archimer.ifremer.fr/doc/00000/4958/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We performed torsional deformation experiments on pre-hydrated fine-grained olivine aggregates using an innovative experimental assembly to investigate water weakening in mantle rocks at high shear strains. San Carlos olivine powder was cold-pressed and then hot-pressed under hydrous conditions, producing aggregates with average grain sizes of 7 or 15 μm. Deformation experiments were performed in a high-resolution gas-medium apparatus equipped with a torsional actuator, under a confining pressure of 300 MPa, a temperature of 1200 °C, and constant shear strain rates ranging from 8 × 10−5 to 1.4 × 10−4 s−1. Maximum shear stresses range from 150 to 195 MPa. These values are 30% lower relative to those determined in previous torsion experiments on dry, fined-grained dunites under similar conditions. Textures and microstructures of the starting and deformed specimens were characterized by scanning and transmission electron microscopy. All deformed aggregates exhibit a shape-preferred orientation marking a foliation and lineation, as well as a reduction in mean grain size from 15 μm down to 3-4 μm due to dynamic recrystallization. Olivine crystallographic fabrics developed rapidly (γ < 0.1), but their strength, characterized by the J-index, is low compared to naturally deformed peridotites or to polycrystalline olivine deformed at similar finite shear strains under dry conditions. The crystallographic fabrics are consistent with deformation by a dislocation accommodated creep mechanism with activation of multiple {0 k l}[1 0 0] systems, among which the (0 1 0)[1 0 0] slip system is dominant, and minor participation of the (0 1 0)[0 0 1] slip system. Transmission electron microscopy confirmed the occurrence of dislocations with [1 0 0] and [0 0 1] Burgers vectors in most grains. Analysis of unpolarized infrared spectra indicates that hydrogen concentration in the olivine lattice is below the saturation level of 18 ppm wt H2O, which is similar to those typically observed in spinel-bearing peridotite xenoliths, and also provide evidence for water-rich inter-granular material trapped in pores and grain boundaries. Seismic properties computed from the CPO observations correspond to those most commonly observed in naturally deformed mantle peridotites with fast P-wave propagation and S-wave polarization subparallel to the shear direction. These torsion experiments on fine-grained olivine polycrystals under hydrous conditions indicate that water weakening under lithospheric conditions is linked to various defects with hydrogen in the olivine structure, as well as with water-derived species in grain boundaries or pores.
ISSN: 0031-9201

hal-00745170
https://hal.archives-ouvertes.fr/hal-00745170
DOI : 10.1016/j.pepi.2012.05.001

Éditeur(s) : HAL CCSD
Résumé : International audience
In most rock mechanical testing devices, the texture developed during deformation is only observed after the failure, and the detailed mapping of cracks and pore structure evolution, just before or after rupture, remains speculative. Computerized X-ray tomography (CT X-ray) offers a way to observe 'in vivo' some characteristics of a tested sample in the course of its deformation. Therefore we developed an X-ray transparent tri-axial cell that was included in a medical purpose X-ray scanner with a volumetric resolution of the order of 1 mm3. This technique is described and applied to a porous calcarenite, which is regularly scanned for porosity evolution during mechanical testing. The experiment is performed at low confining pressure (2-10 MPa). During testing, an axial load is applied until failure and is then progressively decreased. In these experiments, the peak stress is preceded by phase of diffuse dilatancy. After failure localization, the axial stress is unloaded until the stress reaches isotropy. During this unloading phase, the previous diffuse dilatancy is lost due to an elastic relaxation. Then, the stress is completely relaxed. At this moment the dilatancy increases again and the residual dilatancy is larger than that reached at the peak stress. When observed "post mortem" at microscopic scale, the dilatant structures are comprised of cataclastic deformation bands and cracks in some larger crystals.
International Journal of Rock Mechanics and Mining Science

hal-00767563
https://hal.archives-ouvertes.fr/hal-00767563
DOI : 10.1016/j.ijrmms.2012.07.020

Éditeur(s) : HAL CCSD Springer-Verlag
Résumé : International audience
High-resolution borehole strainmeters are usually installed in tectonically active regions in order to detect slow-slip events, and to estimate slow transients related to earthquake swarms. However, they are also sensitive to other numerous influences, internal or external. Furthermore, the quality of their coupling to the rock through cementation, and the mechanical properties of the rock mass around them, have a critical influence on their records. Many of the existing strainmeters present such problems, and the correction for these effects often remains a challenge. In this paper, we present the analysis of the records of a high-resolution borehole dilatometer (Sacks–Evertson), located in the seismically active rift of Corinth (Greece) (station TRZ in the Trizonia island). We show that the instrument suffers from an only partial-solid coupling, and that the nearby sea tides have a direct (through elastic response) and indirect (through pore-pressure diffusion) effect on the dilatation signal, which adds up to the solid tidal strain source. We propose a methodology that allows, in a first step, to better separate the internal (solid tide) from the external (air pressure, sea level) influences, by calculating a frequency-dependent transfer function outside the range of the tidal periods. We then extrapolate this function, in particular at the tidal periods. In a second step, the resulting variation with frequency of the coupling coefficients with sea level led us to estimate the proportion of instrument not solidly cemented to rock (thus in contact with water pore pressure), which is about 90 % of the total height. Despite the small proportion of solid coupling, the sensor resolution remains very good up to a few tens of hours of a time period, thanks to the confining effects of the rocks on the local pore pressure. These results allow us to correct for the external effects, and reduce the associated variance by 80–90 % (in the period range of minutes to days). The empirical correction of the sea level effect could be explained using a simple Boussinesq’s approximation and 1D pore-pressure diffusion model, which contributed to better constraint of some of the poro-elastic parameters in the vicinity of the instrument. After correction, the solid tidal signal at the 24-h period is almost anti-correlated with those of the theoretical solid tide. This surprising result is consistent with a similar anti-correlation observed for the longest period surface waves (200 s) comparing the TRZ dilatometer signals to the strain measured by a nearby borehole strainmeter (MOK, 15 km). This could be related to the presence of a shallow fault close to the instrument, which would creep in response to seismic wave-related stress.
ISSN: 0033-4533

hal-01122853
https://hal.archives-ouvertes.fr/hal-01122853
DOI : 10.1007/s00024-013-0742-2

Éditeur(s) : HAL CCSD
Résumé : Geological storage of CO2 is one of diverse technologies being explored to reduce atmospheric carbon fromindustrial processes (i.e. fossil fuel combustion). One of the specific features of CO2 injection is the possibility ofgeochemical reactions (dissolution – precipitation) between mobile reactive brine (e.g. formation water enrichedin CO2) and the host rock during the spatial and temporal evolution of CO2. That leads to modifications in thepore structure, which in turn change the flow dynamics of the reservoir (e.g. the permeability k). Then, thesesstructural modifications can largely control the injectivity, so that the pressure field in the reservoir and also theCO2 propagation. Accordingly, it is crucial to explore the changes in the reservoir properties (e.g. structural andhydrodynamic) induced during a CO2 injection and specially the relationships between them (e.g. k or reactivesurface-Sr versus porosity-φ , k versus rock heterogeneity), for developing predictive modelling tools of thetransport and reaction processes occurring during a CO2 injection and reliable risk assessment. In the case ofcarbonate rocks, the application of the predictive models of transport and reaction is still challenging, because oftheir high heterogeneity so that the incertitude in the reaction kinetics of carbonate minerals.From this perspective, we realized brine-enriched in CO2 percolation experiments through carbonate rocksamples in thermodynamic conditions expected during CO2 injection in deep reservoirs (T = 100°C et P =12MPa). The permeability changes k(t) is monitored during the experiments and the porosity variationφ (t) iscalculated from chemical analyses of the sampled outlet fluids, using ICP-EAS. The pore structure modificationsare investigated from high resolution X ray micro tomography images acquired from the synchrotron ofGrenoble (ESRF). Depending to the dissolution regime, controlled by the reservoir rock fabric and the chemicalcomposition of the brine (e.g. PCO2), we observed that a modification of pore structure can either improve(atypical result in dissolution context) or impair the value of the permeability k.
Le stockage géologique du CO2 est l’une des diverses technologies étant explorées afin deréduire les émissions de carbone atmosphérique des processus industriels (i.e. combustion del’énergie fossile). L’une des spécifiques caractéristiques de l’injection du CO2 en profondeurreste la possibilité de réactions géochimiques (dissolution-précipitation) entre la saumureréactive mobile (e.g. eau de formation enrichie en CO2) et la roche encaissante durantl’évolution spatiale et temporelle du CO2, conduisant à des modifications dans la structure despores et par conséquent dans les propriétés d’écoulement du réservoir (e.g. la perméabilité k).Donc, ces changements structuraux peuvent largement contrôler l’injectivité, ainsi que lechamp de pression dans le réservoir et aussi la propagation du CO2. Il demeure ainsi cruciald’explorer les changement dans les propriétés de réservoirs (e.g. structurales ethydrodynamiques) induits durant une injection de CO2 et explicitement les relations existantesentre eux (e.g. k ou surface réactive-Sr versus porosité-φ , k versus hétérogénéité de la roche),afin de développer des outils de modélisation prédictive des processus de transport etréactionnels se produisant durant une injection de CO2 et d’évaluer de façon fiable les risques.Dans le cas des réservoirs carbonatés, l’application des modèles prédictifs de transport réactifdemeure toujours un enjeu, car contrainte par la forte hétérogénéité en leur sein ainsi que parl’incertitude dans la cinétique de réactions des minéraux carbonatés dans ce contexte. Danscette optique, nous avons réalisé des expériences de percolation à travers des échantillons deroches carbonatées dans les conditions thermodynamiques de stockage en profondeur (T =100°C et P =12 MPa). L’évolution de la perméabilité k(t) est suivie au cours desexpériences ; et la variation de la porosité φ (t) est calculée à partir des résultats d’analyseschimiques au ICP-AES des fluides de sortie échantillonnés. L’investigation des modificationsapportées à la structure des pores est réalisée par le biais de la Micro-Tomographie hauterésolution à rayon X, acquise au synchrotron de Grenoble (e.g. ESRF).Dépendant du régime de dissolution, contrôlé par la fabrique de la roche réservoir et lacomposition chimique de la saumuré chargée en CO2 (e.g. PCO2 engagée), on a observéqu’une modification de la structure de la roche peut soit améliorer soit détériorer (résultatatypique en contexte de dissolution) la valeur de la perméabilité k.
https://hal.archives-ouvertes.fr/tel-01142136

tel-01142136
https://hal.archives-ouvertes.fr/tel-01142136
https://hal.archives-ouvertes.fr/tel-01142136/document
https://hal.archives-ouvertes.fr/tel-01142136/file/thesemangane2013.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : The Erro-Tobbio peridotites (Voltri Massif, Ligurian Alps) represent subcontinental lithospheric mantle tectonically exhumed during Permo-Mesozoic extension of the Europe-Adria lithosphere. Previous studies have shown that exhumation started during Permian times, and occurred along kilometer-scale lithospheric shear zones which enhanced progressive deformation and recrystallization from spinel- to plagioclase-facies conditions. Ongoing field and petrologic investigations have revealed that the peridotites experienced, during uplift, a composite history of diffuse melt migration and multiple episodes of ultramafic-mafic intrusions. In this paper we present the results of field, structural and petrologic-geochemical investigations into a sector of the Erro-Tobbio peridotite unit that preserves well this multiple intrusion history. Melt impregnation in the peridotites is evidenced by significant plagioclase enrichment and crystallization of unstrained orthopyroxene replacing kinked mantle olivine and clinopyroxene; impregnating melts were thus opx-saturated. Melt-rock interaction caused chemical changes in mantle minerals (e.g. Al decrease and REE increase in cpx; Ti and Cr# enrichment in spinel). Nevertheless, clinopyroxenes still exhibit LREE depletion (Ce;N;/Sm;N; = 0.006-0.011), indicating a depleted signature for the percolating melts. Melt impregnation was thus related to diffuse porous flow migration of depleted MORB-type melt fractions that modified their compositions towards opx saturation by mantle-melt interaction during ascent. The impregnated peridotites are intruded by a hectometer-scale stratified cumulate body, mostly consisting of troctolites and plagioclase wehrlites, showing gradational, interfingered contacts with the host mantle rocks. Subsequent intrusion events are revealed by the occurrence of olivine gabbros as decameter-wide lenses, variably thick (centimeter- to meter-scale) dykes and thin dykelets, which crosscut both the peridotite foliation and the magmatic layering in the cumulates. Overall, major and trace element compositions of minerals in the intrusives indicate that they represent variably differentiated cumulus products crystallized from rather primitive N-MORB-type aggregated melts. Slightly more evolved compositions are shown by olivine gabbros, relative to the troctolites and plagioclase wehrlites of the cumulate body. Mineral chemistry features (e.g. the Fo-An correlation and high Na, Ti, Mg# in cpx) indicate that the studied intrusive rocks crystallized at moderate pressure conditions (3-5 kbar, i.e. 9-15 km depth). Our study thus points to a progressive transition from porous flow melt migration to emplacement of magmas in fractures, presumably related to progressive change of lithospheric mantle rheology during extension-related uplift and cooling.
ISSN: 0024-4937

hal-00407669
https://hal.archives-ouvertes.fr/hal-00407669
DOI : 10.1016/j.lithos.2006.06.014

Éditeur(s) : HAL CCSD
Résumé : Geothermal energy is considered as a green and infinite energy source at human scale. Currently, the yield of geothermal power plants is limited to temperatures of the operating fluid which 350 °C. From tectonic and volcanic activity at mid-ocean ridges, Iceland is a location where supercritical fluid extraction (T> 375 °C) can considered for the near future. Exploiting such fluids could theoretically multiply by a factor of ten the electrical power delivered by geothermal wells. Can such fluids circulate at the base of brittle oceanic crust? This work investigates the petrophysical properties of basalts in order to constrain geophysical observations in Iceland and predict the behavior of very high temperature geo-hydrothermal reservoirs. The first approach consisted in studying the physical properties of rocks that have hosted deep hydrothermal circulations at oceanic ridges. The study of these rocks at ODP Site 1256 shows that the porosity measured both in the field and in the lab is associated with amphibolite facies alteration minerals (T> 500 ° C). The second approach was to recreate in the laboratory the conditions of pressure, temperature and pore fluid pressure of high temperature to supercritical hydrothermal systems to predict the mechanical and electrical properties of basalts under these conditions. The mechanical results indicate that the brittle/ductile transition occurs at a temperature of about 550° C, where a strong permeability decrease is expected. The implementation and calibration of a new cell for measuring electrical conductivity at high temperature provide the first results for the interpretation of geophysical data. When applied to basaltic crustal conditions in Iceland, these results indicate that hydrothermal fluids could circulate, at least temporarily, in a supercritical state up to 5 km depth.
La géothermie est considérée comme une source d'énergie propre et inépuisable à échelle humaine. Actuellement, le rendement des centrales géothermiques est limité à l'exploitation de fluides de températures inférieures à 350 °C. L'association de l'activité tectonique et volcanique aux dorsales océaniques fait de l'Islande un lieu où l'extraction de fluides supercritiques (T> 375 °C) peut être envisagée. Cette exploitation pourrait multiplier par dix la puissance électrique délivrée par le système géothermal. Ces fluides peuvent-ils circuler dans la croûte océanique ? Ce travail propose de contraindre les observations géophysiques et de prédire le fonctionnement des réservoirs géo-hydrothermaux de très haute température par l'étude des propriétés physiques des basaltes. La première approche est focalisée sur l'étude de roches ayant accueilli une circulation hydrothermale par le passé. L'étude de ces roches au site ODP 1256, montre que leur porosité est associée à la présence de minéraux d'altération hydrothermale du facies amphibolite (T> 500 °C). La seconde approche a consisté à recréer, en laboratoire, les conditions des systèmes hydrothermaux, à très haute température, afin de prédire les propriétés mécaniques et électriques des basaltes dans ces conditions. Les résultats mécaniques indiquent que la transition fragile/ductile, souvent associée à une forte décroissance de perméabilité, intervient à une température d'environ 550 °C. La mise en place d'une cellule de mesure de la conductivité électrique de haute température a fourni les premiers résultats utiles à l'analyse des données géophysiques. Appliqués aux conditions de la croûte basaltique Islandaise, ces résultats indiquent que des fluides hydrothermaux pourraient circuler au moins transitoirement à l'état supercritique jusqu'à ~ 5 km de profondeur.
https://tel.archives-ouvertes.fr/tel-00591798

tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798/document
https://tel.archives-ouvertes.fr/tel-00591798/file/THESE_MV_pro.pdf

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Electrical resistivity soundings are used by geophysicists to determine the structure and composition of the Earth's crust and mantle and to explore natural resources (ore, oil, gas, water). Their interpretations in terms of composition and in-situ physical conditions depend mainly on laboratory measurements of electrical conductivity of rocks at simulated crustal conditions of temperature, pressure, saturation and pore pressures. These measurements present a numbers of limitations, in particular, in the case where conductive pore fluids are present, as in the case of deep reservoir conditions, where temperature exceeds 250 A degrees C. Here, we present a new cell capable of measuring electrical conductivity of large saturated samples at confining pressure up to 200 MPa, pore pressure up to 50 MPa, and temperature up to 500 A degrees C. The measurement cell has been developed in a commercial, internally heated, gas pressure apparatus (Paterson press). It is based on the concept of "guard ring" electrode, which is adapted to samples that are jacketed by a very conductive, metallic material. Numerical modeling of the current flow in the electrical cell allowed defining the optimal cell geometry. Calibration tests have been performed on Fontainebleau sandstones saturated with electrolytes of different conductivities, up to 350 A degrees C. The resulting electrical formation factor and temperature dependence of electrical conductivity are in very good agreement with previous studies. This new cell will improve the exploration and exploitation of deep fluid reservoirs, as in unconventional, high enthalpy geothermal fields. In particular, the investigations address possible effects of fluid-rock interactions on electrical resistivity of a reservoir host rock.
ISSN: 0169-3913

hal-00681997
https://hal.archives-ouvertes.fr/hal-00681997
DOI : 10.1007/s11242-011-9846-2

Éditeur(s) : Université des Antilles Études caribéennes
Résumé : Las Islas Canarias, situadas en la región macaronésica, acogen ecosistemas terrestres y marinos de valiosa riqueza ecológica y paisajística, representativos de las áreas culturales y biogeográficas de su entorno; hasta el punto de albergar tres Reservas de la Biosfera reconocidas por la UNESCO. La diversidad y riqueza de este marco insular ya fue elogiada por grandes científicos como Alexander von Humboldt o Charles Darwin. Sin embargo, actualmente la presión ejercida sobre el medio por parte del desarrollo urbanístico y la industria turística, motor económico del archipiélago, pone en peligro estos frágiles ecosistemas; lo que ha generado un profundo debate entre crecimiento económico y turístico, y desarrollo sostenible y conservación. El presente artículo trata, desde una óptica divulgativa, de acercar al lector al medio que caracteriza las Islas Canarias e introducirlo en el marco donde se desarrolla parte importante de la actividad turística en España, uno de los países que más turistas recibe año a año.
Les îles Canaries, situées dans la région de la ‘Macaronésica’ (l’Est de l’Océan Atlantique), abritent des écosystèmes marins et terrestres très précieux, tant du point de vue écologique que paysager. Ils sont représentatifs de les zones biogéographiques de sa région et comptent trois Réserves da Biosphère reconnues par l’UNESCO. De grands scientifiques comme Alexander Von Humboldt et Charles Darwin ont fait l’éloge de la richesse de la biodiversité de cet archipel. Cependant, actuellement, la pression anthropique, notamment en liaison avec le développement touristique et tous les enjeux économiques qui l’accompagnent, mettent en danger les écosystèmes des Canaries ; ce constat a ouvert un large débat sur les enjeux autour des développements économique et touristiques et leurs dérives. Notre article propose de mettre l’accent sur les caractéristiques des îles Canaries et de replacer les processus de développements touristiques dans leur contexte pour ouvrir la réflexion sur les conditions nécessaires pour d’un développement durable.
The Canary Islands, located in the region of 'Macaronésica' (Este of Atlantic Ocean), are home to marine and terrestrial ecosystems very valuable, both ecological and landscape. They are representative of the bio-geographic zones of the region and there are three Biosphere Reserves da recognized by UNESCO. Great scientists such as Alexander Von Humboldt and Charles Darwin have praised the richness of the biodiversity of this archipelago. However, at present, anthropogenic pressure, including in relation to tourism development and all economic issues that accompany it, endanger ecosystems Canary Islands. This has opened a broad debate on the issues surrounding economic development and tourism and their excesses. Our article proposes to focus on the characteristics of the Canary Islands and put the process of tourist developments in their context to open reflection on the necessary conditions for sustainable development.
Canaries

Droits : info:eu-repo/semantics/openAccess
urn:doi:10.4000/etudescaribeennes.1302
http://journals.openedition.org/etudescaribeennes/1302

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Secondary migration is defined as the movement of hydrocarbons through relatively permeable rocks from source to trap: a two-phase flow within a porous medium. Depending on the geometry and capillary pressure distributions of carrier beds, secondary migration has both vertical and lateral components. The present paper focuses on that part of the migration where the movement is mainly vertical. Its objective is to propose a description of the dynamics governing the vertical part of secondary migration based on the main physical aspects of two-phase flow in a homogeneous porous medium. The study is illustrated by laboratory observations performed in a vertical, 2-D Hele-Shaw cell filled with a transparent porous medium where the flow of dyed oil invading a wetting fluid is visually observed. These observations help us to understand the effect of buoyant, capillary and viscous forces on the resulting flow, the relative importance of which is characterized by non-dimensional numbers. Extrapolating these observations to natural media, it is proposed that vertical secondary migration can be described as a percolation of disconnected and vertically-elongated stringers. These stringers do not move continuously but as a succession of snap-off and re-feeding events which result in a jerky upward movement. Using parameters characterizing the physical properties of the fluid and of the porous medium, the geometry and the dynamic behavior of the stringers are estimated. The width of stringers occurring during secondary migration in geological media is centimetric and their vertical size ranges from several centimeters to a few meters. An upper limit of the mean upward velocity of stringers is proposed, as well as an estimate of their spatial density and of the minimum, average horizontal distance (decametric) between two stringers. The stringers are sparsely distributed, resulting in a low average oil loss and a high efficiency of the vertical migration process.
ISSN: 0264-8172

hal-00831370
https://hal.archives-ouvertes.fr/hal-00831370
https://hal.archives-ouvertes.fr/hal-00831370/document
https://hal.archives-ouvertes.fr/hal-00831370/file/pekins-V-edited.pdf
DOI : 10.1016/j.marpetgeo.2013.04.020

Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Although magmatism may occur during the earliest stages of continental rifting, its role in strain accommodation remains weakly constrained by largely 2-D studies. We analyze seismicity data from a 13 month, 39-station broadband seismic array to determine the role of magma intrusion on state-of-stress and strain localization, and their along-strike variations. Precise earthquake locations using cluster analyses and a new 3-D velocity model reveal lower crustal earthquakes beneath the central basins and along projections of steep border faults that degas CO2. Seismicity forms several disks interpreted as sills at 6-10 km below a monogenetic cone field. The sills overlie a lower crustal magma chamber that may feed eruptions at Oldoinyo Lengai volcano. After determining a new ML scaling relation, we determine a b-value of 0.87±0.03. Focal mechanisms for 65 earthquakes, and 13 from a catalogue prior to our array reveal an along-axis stress rotation of ∼60° in the magmatically active zone. New and prior mechanisms show predominantly normal slip along steep nodal planes, with extension directions ∼N90°E north and south of an active volcanic chain consistent with geodetic data, and ∼N150°E in the volcanic chain. The stress rotation facilitates strain transfer from border fault systems, the locus of early-stage deformation, to the zone of magma intrusion in the central rift. Our seismic, structural, and geochemistry results indicate that frequent lower crustal earthquakes are promoted by elevated pore pressures from volatile degassing along border faults, and hydraulic fracture around the margins of magma bodies. Results indicate that earthquakes are largely driven by stress state around inflating magma bodies.
ISSN: 1525-2027

hal-01667198
https://hal.archives-ouvertes.fr/hal-01667198
DOI : 10.1002/2017GC007027

Éditeur(s) : Pergamon-elsevier Science Ltd
Résumé : Society's needs for a network of in situ ocean observing systems cross many areas of earth and marine science. Here we review the science themes that benefit from data supplied from ocean observatories. Understanding from existing studies is fragmented to the extent that it lacks the coherent long-term monitoring needed to address questions at the scales essential to understand climate change and improve geo-hazard early warning. Data sets from the deep sea are particularly rare with long-term data available from only a few locations worldwide. These science areas have impacts on societal health and well-being and our awareness of ocean function in a shifting climate. Substantial efforts are underway to realise a network of open-ocean observatories around European Seas that will operate over multiple decades. Some systems are already collecting high-resolution data from surface, water column, seafloor, and sub-seafloor sensors linked to shore by satellite or cable connection in real or near-real time, along with samples and other data collected in a delayed mode. We expect that such observatories will contribute to answering major ocean science questions including: How can monitoring of factors such as seismic activity, pore fluid chemistry and pressure, and gas hydrate stability improve seismic, slope failure, and tsunami warning? What aspects of physical oceanography, biogeochemical cycling, and ecosystems will be most sensitive to climatic and anthropogenic change? What are natural versus anthropogenic changes? Most fundamentally, how are marine processes that occur at differing scales related? The development of ocean observatories provides a substantial opportunity for ocean science to evolve in Europe. Here we also describe some basic attributes of network design. Observatory networks provide the means to coordinate and integrate the collection of standardised data capable of bridging measurement scales across a dispersed area in European Seas adding needed certainty to estimates of future oceanic conditions. Observatory data can be analysed along with other data such as those from satellites, drifting floats, autonomous underwater vehicles, model analysis, and the known distribution and abundances of marine fauna in order to address some of the questions posed above. Standardised methods for information management are also becoming established to ensure better accessibility and traceability of these data sets and ultimately to increase their use for societal benefit. The connection of ocean observatory effort into larger frameworks including the Global Earth Observation System of Systems (GEOSS) and the Global Monitoring of Environment and Security (GMES) is integral to its success. It is in a greater integrated framework that the full potential of the component systems will be realised. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.
Progress In Oceanography (0079-6611) (Pergamon-elsevier Science Ltd), 2011-10 , Vol. 91 , N. 1 , P. 1-33

Droits : 2011 Published by Elsevier Ltd. All rights reserved.
http://archimer.ifremer.fr/doc/00044/15557/15923.pdf
DOI:10.1016/j.pocean.2011.05.001
http://archimer.ifremer.fr/doc/00044/15557/

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Underground CO2 sequestration is highly recommended as an effective means of significantly decreasing CO2 concentration in the atmosphere. Mineral storage is the more secure technology, but requires the presence of high concentration of divalent cations in the pore-fluid. Results from CO2 percolation experiments through chlorite/zeolite-rich sandstone samples from the Pretty Hill Formation (Otway Basin, Australia) are presented. The dissolution of the laumontite (7 wt.%) and chamosite (7 wt.%) are the potential sources of calcium, iron and magnesium required for carbonate precipitation. The percolation experiment was setup to reproduce, at laboratory scale, the in situ temperature and pressure conditions (T = 95 degrees C and P = 10 MPa). The fluid injected at constant flow rate is a rock-equilibrated brine subsequently enriched in CO2 up to partial pressure of 6 MPa. We observe feldspars, laumontite and chamosite dissolution, kaolinite and silica precipitation and a noticeable sink of CO2 in the sample which is attributed to the precipitation of both amorphous carbon due to the reduction of CO2 and Fe-rich carbonate. Permeability decreases of about one order of magnitude due to the localization of the kaolinite precipitation in the main flow paths, while porosity increases. The high reactivity of this sandstone makes this reservoir a valuable target for CO2 mineralization, but the associated permeability decrease may limit the injection rate and the spreading of the CO2 in the reservoir.
ISSN: 0009-2541

hal-00712829
https://hal.archives-ouvertes.fr/hal-00712829
DOI : 10.1016/j.chemgeo.2011.11.018

Éditeur(s) : HAL CCSD Nature Publishing Group
Résumé : International audience
Temperature and fluid pressure conditions control rock deformation and mineralization on geological faults, and hence the distribution of earthquakes1. Typical intraplate continental crust has hydrostatic fluid pressure and a near-surface thermal gradient of 31 ± 15 degrees Celsius per kilometre2, 3. At temperatures above 300–450 degrees Celsius, usually found at depths greater than 10–15 kilometres, the intra-crystalline plasticity of quartz and feldspar relieves stress by aseismic creep and earthquakes are infrequent. Hydrothermal conditions control the stability of mineral phases and hence frictional–mechanical processes associated with earthquake rupture cycles, but there are few temperature and fluid pressure data from active plate-bounding faults. Here we report results from a borehole drilled into the upper part of the Alpine Fault, which is late in its cycle of stress accumulation and expected to rupture in a magnitude 8 earthquake in the coming decades4, 5. The borehole (depth 893 metres) revealed a pore fluid pressure gradient exceeding 9 ± 1 per cent above hydrostatic levels and an average geothermal gradient of 125 ± 55 degrees Celsius per kilometre within the hanging wall of the fault. These extreme hydrothermal conditions result from rapid fault movement, which transports rock and heat from depth, and topographically driven fluid movement that concentrates heat into valleys. Shear heating may occur within the fault but is not required to explain our observations. Our data and models show that highly anomalous fluid pressure and temperature gradients in the upper part of the seismogenic zone can be created by positive feedbacks between processes of fault slip, rock fracturing and alteration, and landscape development at plate-bounding faults.
ISSN: 0028-0836

hal-01685757
https://hal.archives-ouvertes.fr/hal-01685757
DOI : 10.1038/nature22355

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
The mantle above a subducting slab is the site of complex interactions between deformation, partial melting, fluid migration and magma transport. To constrain these interactions and their effects on olivine deformation, we analyze microstructures, crystal preferred orientations, and water contents of peridotite xenoliths entrained by andesites of the Avacha volcano, southern Kamchatka arc. These xenoliths are refractory spinel harzburgites that have coarse-grained microstructures with widely spaced subgrain boundaries and sinuous grain boundaries in olivine, consistent with deformation by dislocation creep under low deviatoric stress (< 13 MPa) and with a significant contribution from diffusional processes. Analysis of crystal preferred orientations (CPO) indicates dominant activation of high-temperature, low-stress {0kl}[100] slip systems in olivine and of(100)[001] in orthopyroxene. In most samples, coarse opx crystals, elongated parallel to the lineation, enclose small olivine grains in crystallographic continuity with neighbouring crystals, indicating crystallization of orthopyroxene at the expense of olivine as a result of reactive percolation of Si-rich fluids coeval with the high-temperature deformation. Secondary crystallization of interstitial orthopyroxene led locally to development of opx-rich lenses parallel to the foliation, characterized by a decrease in olivine grain size and dispersion of the olivine CPO without changing the dominant slip systems. Half of the samples also show acicular orthopyroxene aggregates with which is associated a fine-grained matrix composed of rounded strain-free olivine, orthopyroxene, spinel, and rare amphibole crystals. This matrix occurs pervasively along grain boundaries or forms millimeter-scale irregular lenses and anastomosing veinlets that crosscut the coarse crystals and their ductile deformation structures. Both acicular orthopyroxene and the fine-grained matrix are interpreted as resulting from reactive transport of H2O-rich fluids under static conditions, probably in the lithospheric mantle. Infrared analyses show that olivine contains 1-8 center dot 6 ppm by weight of water. These low water contents are similar to those observed in spinel peridotites from other subduction zones and probably record both the low solubility of water in olivine at low pressure and dehydration during exhumation of the xenoliths. Water contents in orthopyroxene are highly variable (25-506 ppm H2O), probably recording spatially heterogeneous interaction with fluids or melts and compositional disequilibrium in the studied samples. Change in the dominant percolation mechanism from porous flow to fracturing suggests cooling, consistent with the low temperatures estimated from pyroxene thermometry (< 800-900 degrees C). The Avacha xenoliths therefore record pervasive deformation of a region of the mantle under asthenospheric conditions, followed by its accretion to the base of the lithosphere, probably as a result of cooling of the mantle wedge. Percolation of Si-rich fluids or hydrous melts is recorded at all stages; this probably enhanced diffusion and lowered deviatoric stresses during ductile deformation, but did not change the dominant slip direction in olivine from [100] to [001].
ISSN: 0022-3530

hal-00456053
https://hal.archives-ouvertes.fr/hal-00456053
DOI : 10.1093/petrology/egp085

Éditeur(s) : HAL CCSD
Résumé : International audience
The purpose of our study is to model a geothermal reservoir. When geothermal reservoir are assumed to be composed of pure water, the transfer of mass and energy is classically described by two balance equations: mass balance equation and the energy balance equation. In addition to those equations, fluid velocity ist classically given by the Darcy law while thermodynamic properties, inferred from theoretical or empirical equations of state, are used to close the mathematical system. Once this system is closed, there exist different solutions. The first one is to solve for pressure and temperature with a variable switch to saturation in the two-phase region (e.g. TOUGH2). The second one is to solve for pressure and enthalpy to increase stability of phase transition between single and two-phase states (e.g. Hydrotherm). We adopted the second option and chose te use a splitting method to get rid of the complexity of coupling equations and a finite volume method for the spatial discretization. Selecting object-oriented languages, we developed a multi-language framework, combining Python, Fortran and a C++ implementation of IAPWS (from the freesteam project) including the supercritical equations, in porous media velocity is given by Darcy law and to close the system physical properties are determined by the IAPWS-IF97 thermodynamic formulation. We resolve the equations in pressure and enthalpy instead of pressure and temperature in order to increase stability and to handle easier the passage from a single-phase to a two-phase system. We solve the system by using a splitting method - to get rid of the complexity of coupling equations - and a finite volume method. We offer some freedom to users thanks to the implementation of several methods like explicit or implicit Euler, Runge-Kutta or BDF2 for time solvers or GMRES and BICGSTAB for the linear solver. We can handle several boundary conditions like no-flow - describing a boundary which can not exchange matter with the exterior - or like a mixed-therm condition - a Dirichlet condition to the pressure and a Dirichlet or an outflow condition to the temperature in order to describe a recharge or a discharge zone - ... We're developing a multi-language framework, combining Python, Fortran and the C++ implementation of IAPWS (from the freesteam project). All these languages are object-oriented. We've applied this simulation model to the dogger in Paris, France, to several one-dimensional systems and a two-dimensional one made by Coumou with the CSMP++ platform. The dogger is a reservoir exploited to produce heat by pumping water at 70 and reinjecting it in the reservoir at 40. In the one-dimensional systems we wanted to observe the process of heat transfer from a higher temperature boundary to a smaller one in a high-energy domain. The last simulation shows the natural convection of water in a fault. For every simulation we compared the solutions we found with an other code (TOUGH2 or CSMP++) and they agreed. The next step will be to model the geothermal plant in Guadeloupe, West Indies. It's the only place in France - and in the West Indies so far - producing electricity with the earth power. The temperature can reach up to 1000 and the pressure range is around a few hundreds MPa. In some surface zones we can see two-phase water at atmospheric pressure. In the 1980s Bouillante was a laboratory for France. Since 1995 Bouillante has given 30GWh electricity a year to the Guadeloupeans.
PROCEEDINGS, Thirty-Ninth Workshop on Geothermal Reservoir Engineering
Stanford, United States

Droits : info:eu-repo/semantics/OpenAccess
hal-00944133
https://hal-brgm.archives-ouvertes.fr/hal-00944133
https://hal-brgm.archives-ouvertes.fr/hal-00944133/document
https://hal-brgm.archives-ouvertes.fr/hal-00944133/file/Copol.pdf

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
Progress in seismic methodology and ambitious large-scale seismic projects are enabling high-resolution imaging of the continental crust. The ability to constrain interpretations of crustal seismic data is based on laboratory measurements on rock samples and calculations of seismic properties. Seismic velocity calculations and their directional dependence are based on the rock microfabric, which consists of mineral aggregate properties including crystallographic preferred orientation (CPO), grain shape and distribution, grain boundary distribution, and misorientation within grains. Single-mineral elastic constants and density are crucial for predicting seismic velocities, preferably at conditions that span the crust. However, high-temperature and high-pressure elastic constant data are not as common as those determined at standard temperature and pressure (STP; atmospheric conditions). Continental crust has a very diverse mineral composition; however, a select number of minerals appear to dominate seismic properties because of their high-volume fraction contribution. Calculations of microfabric-based seismic properties and anisotropy are performed with averaging methods that in their simplest form takes into account the CPO and modal mineral composition, and corresponding single crystal elastic constants. More complex methods can take into account other microstructural characteristics, including the grain shape and distribution of mineral grains and cracks and pores. Dynamic or active wave propagation schemes have recently been developed, which offer a complementary method to existing static averaging methods generally based on the use of the Christoffel equation. A challenge for the geophysics and rock physics communities is the separation of intrinsic factors affecting seismic anisotropy, due to properties of crystals within a rock and apparent sources due to extrinsic factors like cracks, fractures, and alteration. This is of particular importance when trying to deduce crustal composition and the state of deformation from seismic parameters.
ISSN: 8755-1209

Droits : info:eu-repo/semantics/OpenAccess
hal-01685568
https://hal.archives-ouvertes.fr/hal-01685568
https://hal.archives-ouvertes.fr/hal-01685568/document
https://hal.archives-ouvertes.fr/hal-01685568/file/Almqvist_et_al-2017-Reviewssur Geophysics.pdf
DOI : 10.1002/2016RG000552