Éditeur(s) : HAL CCSD
Résumé : 20 pp
We first analyze some atmospheric parameters measured in 2004 at the top of La Soufrière volcano: wind speed, pressure and temperature. Next, we study the stochastic process of the wind speed modulus which is of interest for prediction of pollution induced by the plume. We fit to the data various models : FARIMA, periodic trend plus multifractional Brownian noise, multifractal continuous cascades. The estimations show that they evoluate during some transition phases in response to environment changes. Thus, we finally suggest, for future works, some settings that should be more appropriate: time series with regime changes and stochastic processes in random environment.
https://hal.archives-ouvertes.fr/hal-00165572

hal-00165572
https://hal.archives-ouvertes.fr/hal-00165572
https://hal.archives-ouvertes.fr/hal-00165572/document
https://hal.archives-ouvertes.fr/hal-00165572/file/Windsouf_v11.pdf

Éditeur(s) : HAL CCSD Society for Range Management
Résumé : Grasslands and agroecosystems occupy one-third of the terrestrial area, but their contribution to the global carbon cycle remains uncertain. We used a set of 316 site-years of CO(2) exchange measurements to quantify gross primary productivity, respiration, and light-response parameters of grasslands, shrublands/savanna, wetlands, and cropland ecosystems worldwide. We analyzed data from 72 global flux-tower sites partitioned into gross photosynthesis and ecosystem respiration with the use of the light-response method (Gilmanov, T. G., D. A. Johnson, and N. Z. Saliendra. 2003. Growing season CO(2) fluxes in a sagebrushsteppe ecosystem in Idaho: Bowen ratio/energy balance measurements and modeling. Basic and Applied Ecology 4:167-183) from the RANGEFLUX and WORLDGRASSAGRIFLUX data sets supplemented by 46 sites from the FLUXNET La Thuile data set partitioned with the use of the temperature-response method (Reichstein, M., E. Falge, D. Baldocchi, D. Papale, R. Valentini, M. Aubinet, P. Berbigier, C. Bernhofer, N. Buchmann, M. Falk, T. Gilmanov, A. Granier, T. Grunwald, K. Havrankova, D. Janous, A. Knohl, T. Laurela, A. Lohila, D. Loustau, G. Matteucci, T. Meyers, F. Miglietta, J.M. Ourcival, D. Perrin, J. Pumpanen, S. Rambal, E. Rotenberg, M. Sanz, J. Tenhunen, G. Seufert, F. Vaccari, T. Vesala, and D. Yakir. 2005. On the separation of net ecosystem exchange into assimilation and ecosystem respiration: review and improved algorithm. Global Change Biology 11: 1.424-1439). Maximum values of the quantum yield (alpha = 75 mmol.mol(-1)), photosynthetic capacity (A(max) = 3.4 mg CO(2) . m(-2).s-1), gross photosynthesis (P(g,max) = 1.16 g CO(2) . m(-2).d(-1)), and ecological light-use efficiency (epsilon(ecol) = 59 mmol . mol(-1)) of managed grasslands and high-production croplands exceeded those of most forest ecosystems, indicating the potential of nonforest ecosystems for uptake of atmospheric CO(2). Maximum values of gross primary production (8 600 g CO(2) . m(-2).yr(-1)), total ecosystem respiration (7 900 g CO(2) . m(-2).yr(-1)), and net CO(2) exchange (2 400 g CO(2) . m(-2).yr(-1)) were observed for intensively managed grasslands and high-yield crops, and are comparable to or higher than those for forest ecosystems, excluding some tropical forests. On average, 80% of the nonforest sites were apparent sinks for atmospheric CO(2), with mean net uptake of 700 g CO(2) . m(-2).yr(-1) for intensive grasslands and 933 g CO(2) . m(-2).d(-1) for croplands. However, part of these apparent sinks is accumulated in crops and forage, which are carbon pools that are harvested, transported, and decomposed off site. Therefore, although agricultural fields may be predominantly sinks for atmospheric CO(2), this does not imply that they are necessarily increasing their carbon stock.
ISSN: 1550-7424

hal-01190754
https://hal.archives-ouvertes.fr/hal-01190754
DOI : 10.2111/rem-d-09-00072.1
PRODINRA : 214043

Éditeur(s) : American Geophysical Union
Résumé : [1] Extreme weather events such as tropical cyclones are difficult to observe with conventional means. Satellite-based observations provide essential measurements of key parameters governing tropical cyclones. They are critical for short-term forecasting. Radiometers onboard the Defense Meteorological Satellite Program satellite series, WindSat and Tropical Rainfall Measuring Mission satellites, scatterometers onboard the ERS, ADEOS, and QuikScat satellites offer unprecedented synoptic observations of surface wind and atmospheric liquid water content, revealing the storm structures with good accuracy. However, satellite estimates do not provide direct measurements of geophysical parameters and can suffer from limitations linked to the sensors characteristics, such as the signal wavelength and polarization or the measurement incidence angle. For example, measurements at Ku band are strongly affected by rain. Still, each observing system can offer specific information that can be combined with the others. In particular, we highlight the capabilities of dual-frequency altimeter to provide very high resolution measurements of rain rate, surface wind speed, and wave characteristics. A method is proposed to obtain continuous along-track 5 km resolution measurements of these parameters in the tropical cyclone Isabel. The results shows that dual-frequency altimeters can provide useful information to complement and validate the operational fields provided by the atmospheric numerical models and by NOAA observing systems.
Journal of Geophysical Union - Research C - Oceans (0148-0227) (American Geophysical Union), 2006 , Vol. 111 , N. C1 , P. NIL_38-NIL_50

Droits : 2006 American Geophysical Union
http://archimer.ifremer.fr/doc/2006/publication-1033.pdf
DOI:10.1029/2005JC003068
http://archimer.ifremer.fr/doc/00000/1033/

Éditeur(s) : HAL CCSD
Résumé : The field campaign on the Sète coast deployed during the winter 2009 was used to understand the hydrodynamics on a double barred beach in the surf zone during storm periods. The large set of measurements collected at several position and depth were also useful to improve the 3D circulation model Symphonie that takes into account the atmospherics and wave forcings. Once implemented on the beach and supplemented with some additional parameterizations concerning the roller effects and the bottom friction, the model was tuned and validated in the surf zone. The role of the different processes was then analysed. Thus, the roller and the bottom friction are of primary importance in the dynamics of the circulation. Thanks to its 3D nature and once associated with a sediment transport model and a morphodynamic model, Symphonie will offer a good representation of the sediment transport.
Coastal Dynamics 2013
Arcachon, France

hal-00855035
https://hal.archives-ouvertes.fr/hal-00855035

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Sedimentary rocks and detrital minerals sample large areas of the continental crust, and they are increasingly seen as a reliable archive for its global evolution. This study presents two approaches to model the growth of the continental crust through the sedimentary archive. The first builds on the variations in U-Pb, Hf and O isotopes in global databases of detrital zircons. We show that uncertainty in the Hf isotope composition of the mantle reservoir from which new crust separated, in the 176Lu/177Hf ratio of that new crust, and in the contribution in the databases of zircons that experienced ancient Pb loss(es), adds some uncertainty to the individual Hf model ages, but not to the overall shape of the calculated continental growth curves. The second approach is based on the variation of Nd isotopes in 645 worldwide fine-grained continental sedimentary rocks with different deposition ages, which requires a correction of the bias induced by preferential erosion of younger rocks through an erosion parameter referred to as K. This dimensionless parameter relates the proportions of younger to older source rocks in the sediment, to the proportions of younger to older source rocks present in the crust from which the sediment was derived. We suggest that a Hadean/Archaean value of K = 1 (i.e., no preferential erosion), and that post-Archaean values of K = 4–6, may be reasonable for the global Earth system. Models built on the detrital zircon and the fine-grained sediment records independently suggest that at least 65% of the present volume of continental crust was established by 3 Ga. The continental crust has been generated continuously, but with a marked decrease in the growth rate at ~ 3 Ga. The period from > 4 Ga to ~ 3 Ga is characterised by relatively high net rates of continental growth (2.9–3.4 km3 yr− 1 on average), which are similar to the rates at which new crust is generated (and destroyed) at the present time. Net growth rates are much lower since 3 Ga (0.6–0.9 km3 yr− 1 on average), which can be attributed to higher rates of destruction of continental crust. The change in slope in the continental growth curve at ~ 3 Ga is taken to indicate a global change in the way bulk crust was generated and preserved, and this change has been linked to the onset of subduction-driven plate tectonics. At least 100% of the present volume of the continental crust has been destroyed and recycled back into the mantle since ~ 3 Ga, and this time marks a transition in the average composition of new continental crust. Continental crust generated before 3 Ga was on average mafic, dense, relatively thin (< 20 km) and therefore different from the calc-alkaline andesitic crust that dominates the continental record today. Continental crust that formed after 3 Ga gradually became more intermediate in composition, buoyant and thicker. The increase in crustal thickness is accompanied by increasing rates of crustal reworking and increasing input of sediment to the ocean. These changes may have been accommodated by a change in lithospheric strength at around 3 Ga, as it became strong enough to support high-relief crust. This time period therefore indicates when significant volumes of continental crust started to become emergent and were available for erosion and weathering, thus impacting on the composition of the atmosphere and the oceans.
ISSN: 0037-0738

hal-01622696
https://hal.archives-ouvertes.fr/hal-01622696
DOI : 10.1016/j.sedgeo.2017.06.001

Éditeur(s) : HAL CCSD
Résumé : In order to minimize CO2 atmospheric concentration, a solution consists in sequestrating CO2 in geological reservoirs. To estimate long term risks, it is necessary to quantify the couplings between reaction processes as well as structural and hydrodynamical modifications. We realised two experimental benches enabling injecting CO2-enriched-brine in conditions corresponding to in situ storage (T < 200 oC and P < 200 bar) and developed
an experimental protocol using X-Ray microtomography and fluid and rock analyses in order to measure the variations of physical and chemical parameters.
The study of carbonated reservoirs near the injection well, allows quantifying different k-phi relationships depending on the dissolution processes and triggered by the local fluid chemical composition and initials conditions. Away from the injection well, we observe carbonate precipitation decreasing the permeability. The study of fracturated caprock samples shows that alternative percolation of CO2-enriched-brine and CO2 gas increases the fracture permeability.
The study of silicated rocks indicates carbonate precipitation in zeolite sandstone and sintered dunite grains. Nevertheless, in zeolite sandstone we also observe the precipitation of clay particles located in the uid pathways which decrease strongly the permeability.
Afin de minimiser la concentration en CO2 dans l'atmosphère une solution consiste à le séquestrer dans les réservoirs géologiques. Pour évaluer les risques à long terme, il est nécessaire de quantifier les couplages entre les processus réactionnels et les modifications structurales et hydrodynamiques. Dans cette optique, nous avons construit deux dispositifs expérimentaux permettant d'injecter des saumures chargées en CO2 dans les conditions de stockage (T < 200 °C et P < 200 bar) et mis en oeuvre un protocole expérimental utilisant la microtomographie RX et l'analyse des roches et des fuides pour quantifier les variations des paramètres physiques et chimiques. Dans le cas des réservoirs carbonatés, on observe, près du puits d'injection, une forte variabilité des relations k-phi en fonction du régime de dissolution contrôlé par la chimie locale du fluide, ainsi que par les conditions initiales. A plus grande distance, on observe des processus de précipitation diminuant fortement la perméabilité. L'étude des roches de couverture fracturées (argilite) a montré qu'une percolation alternée d'une saumure chargée en CO2 et de CO2 gaz augmentait la perméabilité de fracture. Dans le cas des roches silicatées, la précipitation de carbonates est mise en évidence aussi bien dans les grès à zéolites que dans les frittés de dunite de San Carlos. Cependant, dans les grès à zéolites, la précipitation d'une phase argileuse est observée dans les chemins d'écoulement et engendre une forte diminution de la perméabilité.
https://tel.archives-ouvertes.fr/tel-00416408

tel-00416408
https://tel.archives-ouvertes.fr/tel-00416408
https://tel.archives-ouvertes.fr/tel-00416408/document
https://tel.archives-ouvertes.fr/tel-00416408/file/These_Luquot.pdf

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
Progress in seismic methodology and ambitious large-scale seismic projects are enabling high-resolution imaging of the continental crust. The ability to constrain interpretations of crustal seismic data is based on laboratory measurements on rock samples and calculations of seismic properties. Seismic velocity calculations and their directional dependence are based on the rock microfabric, which consists of mineral aggregate properties including crystallographic preferred orientation (CPO), grain shape and distribution, grain boundary distribution, and misorientation within grains. Single-mineral elastic constants and density are crucial for predicting seismic velocities, preferably at conditions that span the crust. However, high-temperature and high-pressure elastic constant data are not as common as those determined at standard temperature and pressure (STP; atmospheric conditions). Continental crust has a very diverse mineral composition; however, a select number of minerals appear to dominate seismic properties because of their high-volume fraction contribution. Calculations of microfabric-based seismic properties and anisotropy are performed with averaging methods that in their simplest form takes into account the CPO and modal mineral composition, and corresponding single crystal elastic constants. More complex methods can take into account other microstructural characteristics, including the grain shape and distribution of mineral grains and cracks and pores. Dynamic or active wave propagation schemes have recently been developed, which offer a complementary method to existing static averaging methods generally based on the use of the Christoffel equation. A challenge for the geophysics and rock physics communities is the separation of intrinsic factors affecting seismic anisotropy, due to properties of crystals within a rock and apparent sources due to extrinsic factors like cracks, fractures, and alteration. This is of particular importance when trying to deduce crustal composition and the state of deformation from seismic parameters.
ISSN: 8755-1209

Droits : info:eu-repo/semantics/OpenAccess
hal-01685568
https://hal.archives-ouvertes.fr/hal-01685568
https://hal.archives-ouvertes.fr/hal-01685568/document
https://hal.archives-ouvertes.fr/hal-01685568/file/Almqvist_et_al-2017-Reviewssur Geophysics.pdf
DOI : 10.1002/2016RG000552

Éditeur(s) : HAL CCSD
Résumé : The presence of obstacles met in natural environment by the flow, influences the dispersion of air pollutants which it carries. This thesis, based on spatiotemporal micro-meteorological measurements in tropical region, aims at studying the dispersion of compounds emitted by the ecosystem mangrove according to the weather conditions. At a daily scale, the meteorological analysis reveals, besides the presence of Trade Winds, the existence of thermal flows of which nocturnal thermodynamic parameters have been defined. The field observation has shown that the weak intensity of the wind disadvantages the dispersion of compounds emitted during the night. At a finer scale, the existence of a spectral gap separating large scale phenomena of those related to turbulence has been demonstrated. These last ones were treated by spectral and statistical approaches to quantify the turbulent fluxes of momentum and sensible heat during the night, for an averaged duration of 13 minutes. The stratification of the surface layer has been considered and determined by Monin-Obukhov similarity theory. The measurements acquired at night and the application of Kolmogorov theory allowed us to deduct the dissipation rate of energy and the size of the vortices at 5.5 meters in height. This work has also led us, by gas chromatography coupled to mass spectrometry, to identify, in mangrove, sulphurated volatil organic compounds, organohalogen, BTEX, ... All these results will later serve to feed dispersion models related to the studied ecosystem.
La présence d'obstacles rencontrés en milieu naturel par l'écoulement, influence la dispersion des polluants qu'il transporte. Cette thèse, fondée sur des mesures micro-météorologiques spatio-temporelles en région tropicale, vise à étudier la dispersion de composés émis par l'écosystème mangrove en fonction des conditions météorologiques. A l'échelle journalière, l'analyse météorologique révèle, outre la présence des Alizés, l'existence d'écoulements thermiques dont des paramètres thermodynamiques nocturnes ont été définis. L'observation terrain nous a montré que la faible intensité du vent défavorise la dispersion des composés émis durant la nuit. A une échelle plus fine, l'existence d'un trou spectral séparant les phénomènes de grande échelle de ceux liés à la turbulence a été mise en évidence. Ces derniers ont été traités par des approches spectrale et statistique pour quantifier les flux turbulents de quantité de mouvement et de chaleur sensible, pendant la nuit, pour une durée de moyenne de l'ordre de 13 minutes. L'état de stratification de la couche de surface a été pris en compte et déterminé par la théorie de similitude de Monin-Obukhov. Les mesures nocturnes effectuées et l'application de la théorie de Kolmogorov ont permis de déduire les taux de dissipation de l'énergie et la taille des tourbillons à 5,5 m d'altitude. Ce travail a également conduit, par l'analyse chromatographique en phase gazeuse couplée à la spectrométrie de masse, à l'identification, en mangrove, de composés organiques volatils soufrés, des organohalogénés, des BTEX, ... L'ensemble de ces résultats servira ultérieurement à alimenter les modèles de dispersion spécifiques liés aux écosystèmes étudiés.
https://tel.archives-ouvertes.fr/tel-00665882

Droits : info:eu-repo/semantics/OpenAccess
NNT : 11AGUY0438
tel-00665882
https://tel.archives-ouvertes.fr/tel-00665882
https://tel.archives-ouvertes.fr/tel-00665882/document
https://tel.archives-ouvertes.fr/tel-00665882/file/ThA_seCdAlexis.pdf

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
In situ mineralization of CO2 in ultramafic rock-hosted aquifers is one of the promising solutions for decreasing CO2 concentrations in the atmosphere. Naturally altered ultramafic rocks suggest that carbonation processes are controlled by local heterogeneities in the structure of the rock and fluid transport at the water-rock interfaces. We studied the role of rock crystallographic anisotropy relative to the global fluid flow direction on the mineralization of CO2 by means of electron microscope analyses from the macro- to the micrometer scale (EBSD-FIB). The sample used for the measurements was a hot pressed olivine core percolated by water enriched in CO2 (pCO2 = 10 MPa) at 180 °C. During the percolation experiment, olivine was dissolved and two types of carbonates, dolomite, and magnesite, were precipitated on olivine surfaces. The results showed that the dissolution of olivine is controlled by its crystallographic properties as shown by the development of etch-pits only on the (010)ol planes and with elongated shapes parallel to the [010]ol axes. In contrast, the precipitation of carbonates is governed by hydrodynamic properties. Carbonates are heterogeneously distributed in the percolated rock. They are mainly located along the moderate (for dolomite) and the minor (for magnesite) flow paths, both oriented parallel to the principal fluid flow direction, which allow carbonates to be supplied with divalent cations (e.g., Ca2+, Mg2+, and Fe2+). In these flow paths, carbonate growth is systematically oriented normal to the flow that facilitates the development of chemical gradients with cationic supersaturation conditions for carbonate precipitation near the walls.In natural systems, the (010)ol planes are parallel to the Moho and the (100)ol planes are vertical; our study suggests that flow of CO2-rich fluids will induce precipitation of carbonates localized along, and preferentially clogging, vertical flow paths while favoring olivine dissolution along horizontal fluid pathways. This dual control of structure and fluid flow on carbonation mechanisms could be an important parameter allowing sustainable CO2 storage in peridotites, while limiting the risks of leakage toward the surface.
ISSN: 0003-004X

hal-01143393
https://hal.archives-ouvertes.fr/hal-01143393
DOI : 10.2138/am-2015-4913

Éditeur(s) : Pergamon-elsevier Science Ltd
Résumé : The south-west lagoon of New Caledonia is a wide semi-open coral reef lagoon bounded by an intertidal barrier reef and bisected by numerous deep inlets. This paper synthesizes findings from the 2000-2008 French National Program EC2CO-PNEC relative to the circulation and the transport of suspended particles in this lagoon. Numerical model development (hydrodynamic, fine suspended sediment transport, wind-wave, small-scale atmospheric circulation) allowed the determination of circulation patterns in the lagoon and the charting of residence time, the later of which has been recently used in a series of ecological studies. Topical studies based on field measurements permitted the parameterisation of wave set-up induced by the swell breaking on the reef barrier and the validation of a wind-wave model in a fetch-limited environment. The analysis of spatial and temporal variability of suspended matter concentration over short and long time-scales, the measurement of grain size distribution and the density of suspended matter (1.27 kg 1(-1)), and the estimation of erodibility of heterogeneous (sand/mud, terrigenous/biogenic) soft bottoms was also conducted. Aggregates were shown to be more abundant near or around reefs and a possible biological influence on this aggregation is discussed. Optical measurements enabled the quantification of suspended matter either in situ (monochromatic measurements) or remotely (surface spectral measurements and satellite observations) and provided indirect calibration and validation of a suspended sediment transport model. The processes that warrant further investigation in order to improve our knowledge of circulation and suspended sediment transport in the New Caledonia lagoon as well as in other coral reef areas are discussed, as are the relevance and reliability of the numerical models for this endeavour.
Marine Pollution Bulletin (0025-326X) (Pergamon-elsevier Science Ltd), 2010 , Vol. 61 , N. 7-12 , P. 269-296

Droits : 2010 Elsevier Ltd All rights reserved.
http://archimer.ifremer.fr/doc/00014/12526/9401.pdf
DOI:10.1016/j.marpolbul.2010.06.023
http://archimer.ifremer.fr/doc/00014/12526/

Éditeur(s) : Université de Paris 7
Résumé : The Seine estuary and its adjacent region Pays de Caux are two significant sources of mercury for coastal marine environments. It is carried through fluvial means for the Seine bay and through karstic fresh water emergences for Pays de Caux's coastal area. Mercury cycle in the Seine estuary and bay is affected by additional anthropical activities. The estuary's maximal turbidity area acts like a trap and a chemical reactor for fluvial mercury. Within this area, we can confirm: (i) the non conservative behaviour of dissolved mercury; (ii) mercury enrichment of particles when comparing the Seine's and marine environment and we suggest mercury particle redistribution from the organic fraction to the oxyhydroxydes fraction. A large fraction of mercury is exported in this state towards coastal areas. Mercury reduction in surface coastal waters and its atmospherical recycling are major phenomena. Photoreduction and biological reduction play quantitative roles equivalent to total mercury recycling via the atmosphere corresponding approximately to 30 % of fluvial exchanges. We are demonstrating that reactive forms of mercury are supporting photoreduction. Mercury behaviour within Pays de Caux's karst depends of the hydrogeological context of the system (time and flow speed, turbidity, flow); regardless of the speciation and/or partition in underground waters, the total amount of mercury in intertidal areas is quantitatively the same as in the Seine estuary. Mercury brought through intertidal emergences (karstic exudations) is not « filtered » by a maximal turbidity area and is more widely bio-available for mussels than in the Seine estuary. Even being free from growth factor influences through simple models, mussels found in Pays de Caux still show one of the highest mercury contamination on the French coast; for the first time this places the emphasis on how much mercury is brought from underground waters to the coastal environment. Surface complexation modelisation tests are able to reproduce the major part of mercury partition in the Seine estuary and bay if a very low mercury exchangeable fraction and minimum complexation parameters are taken into account; thermodynamic calculations also suggest that a strong or highly concentrated « dissolved » ligand must be present in the water in order to compete with chlorocomplex formations and explain our measures.
L'estuaire de la Seine et la région adjacente du Pays de Caux sont deux sources significatives en mercure pour le milieu marin côtier. Les apports sont d'une part fluviatiles en ce qui concerne la Baie de Seine et karstiques via des émergences d'eau douce pour la zone côtière du Pays de Caux. Le cycle du mercure en estuaire et baie de Seine est perturbé par les apports liés aux activités anthropiques. La zone de turbidité maximum de l'estuaire joue le rôle de piège et de réacteur chimique pour le mercure fluviatile. Au sein de cette zone, nous mettons en évidence : (i) un comportement non-conservatif du mercure dissous; (ii) un enrichissement en mercure des particules par rapport à celles de la Seine et du milieu marin et suggérons une redistribution du mercure particulaire de la fraction organique vers la fraction oxyhydroxydes. C'est sous cette forme qu'une fraction importante du mercure est exportée vers la zone côtière. La réduction du mercure dans les eaux côtières de surface et son recyclage atmosphérique sont des phénomènes majeurs. En effet, la photoréduction et la réduction biologique jouent des rôles quantitativement équivalents avec un recyclage total du mercure via l'atmosphère correspondant à environ 30% des apports fluviatiles. Nous montrons que les formes réactives du mercure constituent le substrat de la photoréduction. Le comportement du mercure au sein du karst du Pays de Caux dépend du contexte hydrogéologiques du système (temps et vitesse de circulation, turbidité, débit) ; quelle que soit la spéciation et/ou la partition dans les eaux souterraines, l'apport en mercure total à la zone intertidale est quantitativement du même ordre de grandeur que les apports de la Seine. Le mercure apporté par les émergences intertidales (exutoires karstiques) n'est pas « filtré » par une zone de turbidité maximale et se trouve plus largement biodisponible pour les moules qu'en estuaire de Seine. En s'affranchissant, par des modèles simples, de l'influences des facteurs de croissance, les moules du Pays de Caux affichent toujours une contamination par le mercure parmi les plus élevées du littoral français; ceci met pour la première fois l'emphase sur l'importance de l'apport en mercure par des eaux souterraines dans un environnement côtier. Les essais de modélisation de complexation de surface reproduisent la majeure partie de la partition du mercure dans l'estuaire et la baie de Seine si l'on tient compte d'une fraction échangeable en mercure très faible et de paramètres de complexation minimums ; les calculs thermodynamiques suggèrent aussi qu'un ligand « dissous » fort ou présent à de fortes concentrations doit être présent dans l'eau afin d'entrer en compétition avec la formation de chlorocomplexes et expliquer nos mesures.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/2001/these-1842.pdf
http://archimer.ifremer.fr/doc/00000/1842/

Éditeur(s) : HAL CCSD
Résumé : EGU2012-6377- Geophysical Research Abstracts vol. 14
The hot geothermal fluid produced by the wells of the Bouillante power station, in Guadeloupe, contains various dissolved species such as silica or some metals (Zn, Pb, etc). During the exploitation, the geothermal fluid is flashing and cooling (from 260 to 160°C for the high-pressure steam-liquid separation and down to 110°C for the low-pressure phase separation of a part of the separated liquid at 160°C). Consequently, the dissolved species can form scale deposits such as amorphous silica or poly-metallic sulphides, according to the exploitation conditions, and cause serious scaling problems on the production and the surface installations. These minerals could also precipitate during the partial underground re-injection of the production fluids which is being set up in the Bouillante power station. In this study, in order to predict and prevent the possible silica precipitation at temperature lower than 160°C, during the partial underground reinjection of the production fluids of Bouillante or their thermal valorization down to 110°C temperatures, we propose to investigate on site the kinetics of silica precipitation as a function of temperature and pH. The experiments presented here were carried out on site on samples of separated waters collected after the steam-water separator at 160°C, containing about 600 ppm of SiO2, at four cooling temperatures: 22, 50, 75 and 90°C, and for pH ranging from 4 to 9. These experiments showed that the silica deposition was always initiated by a polymerization mechanism characterized by an order 2 kinetic law and the formation of a white colloidal gel, which slowed down the silica precipitation under solid form. This latter was observed much later, after the polymerization stage, and only in particular conditions (long time of atmospheric exposure, water stagnation,. . . ). The results also confirmed that the silica precipitation kinetics is strongly dependent on pH. In acidic solution, a transition period is observed before the beginning to the silica polymerization. At neutral-basic pH, there is no transition period and the rate of polymerization is maximal for pH close to 8. The undergoing modeling of these experimental data and specific surface area measurements on the colloidal gel will allow us to determinate the kinetics parameters useful for the prediction and prevention of silica precipitation under the specific exploitation conditions of Bouillante power station. This work is financially supported by ADEME (French Agency for Energy and Environment), BRGM and UAG.
EGU General Assembly 2012
Vienne, Austria

hal-00697627
https://hal-brgm.archives-ouvertes.fr/hal-00697627

Éditeur(s) : HAL CCSD
Résumé : International audience
The challenge is to implement research that can estimate the consequences ofclimate changes in terms of impact on terrestrial environments and resources.Emphasis should be placed on regions dependent on natural resources and forwhich demographic pressure is strong. Simulations obtained from climate modelprojections (using different Representative Concentration Pathways (RCPs))predict that the Mediterranean basin and its southern periphery are particularlyvulnerable to water resources and environmental impact (IPCC, AR5, 2013).An annual rainfall decrease by 30% is found for the projection period 2070-2099(IPCC, AR5, 2013) associated with a decrease in water resources by 30 to 50%(Milano, 2012). In addition, several studies using regional atmospheric modelsindicate an increase in the precipitation inter-annual variability with extremeevents and a spatial heterogeneous signature, superimposed on a decrease in thetotal precipitation amount (Giorgi and Lionello, 2008; Raible et al. 2010).Currently, regional climate projections are highly sensitive to the climate modelused. In particular, spatial resolution as well as local climate conditions seemto impact significantly on the simulations (Jacob et al. 2014).The Mediterranean region, at the interface between arid and temperate climateswith several mountainous areas, is a complex climate system affected by theinteractions between mid-latitude and sub-tropical processes. In this context,Morocco, located at the transition between a temperate climate to the North anda tropical climate to the south constitutes a key area for an impact and sensitivitystudy to global climate changes. The climate is influenced by the Atlantic Ocean,the Mediterranean Sea and the Sahara, together with a very steep orography inthe Atlas region. The precipitation distribution is therefore characterised by greatspatial variability, and exhibits a marked seasonality, a strong inter-annualvariability (Ouda et al. 2005) and in general a pronounced gradient from northto south and west to east. At a broader scale, Morocco is located on the subtropicalsubsidence path and between the Acores High and the Saharan Low (Agoussine,2003). Several studies have also identified strong links with inter-annualprecipitation variability and NAO index (Knippertz, 2003) as well as remoteclimate modes (Esper et al. 2007).Continental climate variability at a local/regional scale, if it is to be integratedin climate predictions, needs to be supported by long-term observation.Meteorological stations in Morocco provide climatic data mainly for the last40 years with only a few stations located in the mountainous region (Tramblayet al. 2012; 2013; Driouech et al. 2010). This climate database is also supportedby the IAEA network providing stations for which isotope tracers have beenapplied to daily/monthly rain and water vapour samples over 2 to 3 years between2000 and 2004. Besides the poor coverage of instrumented areas, lacustrinesystems can provide a climatic data set that offers access to short and long-termtime series of climate parameters when knowledge of modern lake water balanceis combined with lacustrine sedimentary-climate records. Lake sediment recordsideally provide high resolution climate/environmental information of the last10,000 years (Magny et al. 2013). This time interval (corresponding to theHolocene) is a key period to investigate short and long-term climate variabilityand to improve prediction in a warming climate.In this study we present an integrated approach focusing on a mountainous lake(Aguelmam Azigza). The modern lake system study is based on site monitoring(2012-2016) and available regional hydro-climatic data. These data show thatlake level changes during the instrumented period were mainly driven byprecipitation following the high inter-annual variability. These data are thencompared with accurately dated short sediment cores retrieved in the same lake.Micro-scale geochemical and sedimentological analyses of these sequencesenable us to identify various sedimentary facies that can be linked with periodsof high (low) lake levels over the past decades.
The Mediterranean Region under Climate ChangeLa méditerranée face au changement climatique

insu-01394690
https://hal-insu.archives-ouvertes.fr/insu-01394690
https://hal-insu.archives-ouvertes.fr/insu-01394690/document
https://hal-insu.archives-ouvertes.fr/insu-01394690/file/Vidaletal.2016-COP22-Chap1.pdf

Éditeur(s) : HAL CCSD
Résumé : The effects of climate change on extreme events are difficult to assess because extremes present large variability and consequently, it is difficult to identify significant trends in relation to the lack of instrumental long time series. Here we present a record of these extreme storm events in the French Mediterrannean coast over the past 7000 years based on a long sediment core from lagoonal environment in Gulf of Lions. Using a high resolution multiproxies approach on core associating grain size, faunal to reconstruct Mid to Late Holocene history of backbarrier deposits in relation to landfalling activity. Even if change in lagoon geomorphological setting over the Holocene does not allow to compare storm events in terms of intensity trough time, we have recorded six periods of increase in storm activity at 6200, 5500, 4400, 3200, 1500 yr cal B.P. and over the LIA (450 and 100 yr cal B.P.). These evidences of changes in coastal hydrodynamic, inversely correlated to periods of aridification in Western Mediterranean region, are in phase with those observed over the North Atlantic and correspond to Holocene cooling events. This increase in storm activity during Holocene cold events over Mediterranean region was probably due to thermal gradient increase leading to enhanced lower tropospheric baroclinicity over a large Central Atlantic-European domain. This study demonstrates that temperatures in North Atlantic region influence the severe storm activity and therefore the Mediterranean climate at Holocene timescale.
Les effets du changement climatique sur les événements extrêmes sont difficiles à estimer car ces phénomènes présentent une large variabilité, et par conséquent il est délicat d'identifier des tendances significatives compte tenu de l'absence de longues séries de données instrumentales. Dans cette étude, nous présentons un enregistrement de ces tempêtes extrêmes sur la côte Méditerranéenne française au cours des 7000 dernières années à partir de carottes sédimentaires prélevées dans un système lagunaire du Golfe du Lion. L'utilisation d'une approche multi-traceur à haute résolution avec des analyses granulométriques, faunistiques, géochimiques (XRF), en minéraux argileux associées à des données chronologiques de radiocarbone et de 210Pb, 137Cs ; nous a permis de reconstruire l'histoire, au cours de l'Holocène, des dépôts lagunaires en relation avec l'activité des tempêtes. Bien que les paramètres morphologiques de cet environnement lagunaire aient changé durant l'Holocène, ne permettant pas de comparer ces événements au cours du temps en terme d'intensité, nous enregistrons six périodes d'augmentation de l'activité des tempêtes datées à 6200, 5500, 4400, 3200, 1500 an cal B.P. et durant le Petit Age Glaciaire (de 450 à 100 an cal B.P.). Ces changements de l'activité hydrodynamique côtière, en antiphase avec les périodes d'aridifications en Méditerranée de l'Ouest, sont corrélées avec celles observées dans le bassin Nord Atlantique et correspondent aux événements de refroidissement Holocène. L'augmentation de l'activité des tempêtes dans la cette région de la Méditerranée durant les périodes froides, associée à une diminution des températures au pôle Nord, est probablement liée à l'augmentation du gradient thermique qui, par interaction barocline, favorise les cycles d'évolution des tempêtes dans toute l'Europe et la Méditerranée de l'Ouest. Cette étude démontre ainsi que la température dans la région Nord Atlantique influence l'activité des tempêtes extrêmes et donc du climat Méditerranéen à l'échelle de l'Holocène.
https://tel.archives-ouvertes.fr/tel-00437757

tel-00437757
https://tel.archives-ouvertes.fr/tel-00437757
https://tel.archives-ouvertes.fr/tel-00437757/document
https://tel.archives-ouvertes.fr/tel-00437757/file/Sabatier_these.pdf

Éditeur(s) : HAL CCSD
Résumé : International audience
The present research work is a part of the KUNSHEN Franco-Taiwanese research project which aims at investigating the hydro/morphodynamics of barrier islands driven by typhoon events. This study focuses on the impact of the Talim tropical storm on the Wan-tzu-liao sand barrier (Taiwan) in terms of water level rising and watertable overheight. In-situ measurements are provided by a cross-shore network of pressure sensors extended from the intertidal zone to the top of the barrier. Extreme offshore wave conditions are encountered during Talim, with significant wave height greater than 10m at the storm peak. It is shown that measured setups are smaller than those predicted by usual empirical parameterization. Groundwater dynamics is strongly affected by the storm, with watertable overheight of the order of one meter under the barrier top. Watertable dynamics is influenced by waves, tides and rainfalls.
Coastal Dynamics 2013

hal-00831573
https://hal.archives-ouvertes.fr/hal-00831573

Éditeur(s) : HAL CCSD
Résumé : Background Acute splenic sequestration is one of the major clinical forms of sickle cell disease. This potentially life-threatening complication is defined by a rapid sequestration of sickle red blood cells in the spleen. Approximately 30% of young patients will develop this complication and 49% of them will have recurrences. Methods The decision tree method is a statistical method that can act as a medical decision tool in the case of a complex biological problem. The decision tree method is used here to determine the variables involved in the severity and recurrence of acute splenic sequestration crises. Results A prior decision tree shows that platelet level, variation in spleen size, patient age and hygrometry also called relative humidity define acute splenic sequestration severity. A second one shows that spleen size variation, atmospheric pressure and patient age define recurrence. Conclusions For the first time, biological and environmental parameters are combined to discover some interesting rules which can lead to more accurate evaluations of acute splenic sequestration severity and recurrence. Thus, this method provides a sharp diagnostic tool which could improve medical treatment for better patient care.
https://hal.archives-ouvertes.fr/hal-00201460

hal-00201460
https://hal.archives-ouvertes.fr/hal-00201460
https://hal.archives-ouvertes.fr/hal-00201460v2/document
https://hal.archives-ouvertes.fr/hal-00201460/file/DT_Marianne_v2.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Forecasting of sea-state characteristics, with warning time of a few hours, appears a necessity in Operational Oceanography. linking sophisticated marine monitoring systems with forecasting modeling tools. In this paper, instead of using conventional numerical models, a Takagi-Sugeno-rule-based Fuzzy Inference System (FIS) was developed aiming at forecasting wave parameters based on the wind speed and direction, and the lagged-wave characteristics. Initial and final antecedent fuzzy membership functions were identified using the subtractive clustering method. The model was applied on the wind and wave dataset recorded in years 2000-2006 by an oceanographic buoy deployed in the Aegean Sea. The model showed perfect fit for the training period (2000-2005; 12,274 data points), and expanded its hindcasting ability during 2006 (1044 data points), as the verification part of the series. Model results, for a lead time of 3 h, showed good agreement between the predicted and the observed significant wave height (RMSE=0.216) and zero-up-crossing period (RMSE=0.315). According to other model performance criteria, the fuzzy model slightly underpredicted both wave characteristics (the linear regression slope was 0.911 for wave height and 0.788 for wave period), and reduced its forecasting ability at higher prediction intervals (+6 to + 12 h). Overall, model results illustrated that the developed FIS could serve as a valuable tool for the operational prediction of wave characteristics in Northern Aegean Sea, through the utilization of the POSEIDON network.
ISSN: 0029-8018

hal-00456020
https://hal.archives-ouvertes.fr/hal-00456020
DOI : 10.1016/j.oceaneng.2009.08.016

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The western margin of the Gulf of Mexico (Veracruz State, Mexico) displays an extensive Neogene gravitational system, whereby the Neogene siliciclastic sediments are detached from underlying Mesozoic carbonates along decollement surface in Oligocene underpressured clays. Rapidly subsiding half-grabens develop above the footwall associated with major listric faults, whereas mini-basins develop in the deepest parts of the slope, in conjunction with the growth of west-verging compressional features. Between the high-angle normal faults in the west and the thrust anticlines in the east, a wide roll-over structure has grown progressively, resulting in a major topographic break in the morphology of the slope profile. Coupled forward kinematic modelling (Thrustpack) and stratigraphic modelling (Dionisos), calibrated against seismic profiles and two key nearshore wells, have been applied to representative regional transects across the margin, in order to quantify the vertical (subsidence) and horizontal (gravitational) deformations, and to discuss the impact of various key parameters on the distribution of debris flow depositions. These simulations are compared with data from distant ODP wells and discussed in the scope of current exploration strategies in both the US and Mexican portions of the Gulf of Mexico basin.
ISSN: 0040-1951

hal-00424595
https://hal.archives-ouvertes.fr/hal-00424595
DOI : 10.1016/j.tecto.2008.06.017

Éditeur(s) : Amer Geophysical Union
Résumé : An analysis is presented for the spatial and intensity distributions of North Atlantic extreme atmospheric events crossing the buoyant Amazon-Orinoco freshwater plume. The sea surface cooling amplitude in the wake of an ensemble of storm tracks traveling in that region is estimated from satellite products for the period 1998-2012. For the most intense storms, cooling is systematically reduced by approximate to 50% over the plume area compared to surroundings open-ocean waters. Historical salinity and temperature observations from in situ profiles indicate that salt-driven vertical stratification, enhanced oceanic heat content, and barrier-layer presence within the plume waters are likely key oceanic factors to explain these results. Satellite SMOS surface salinity data combined with in situ observations are further used to detail the oceanic response to category 4 hurricane Igor in 2010. Argo and satellite measurements confirm the haline stratification impact on the cooling inhibition as the hurricane crossed the river plume. Over this region, the SSS mapping capability is further tested and demonstrated to monitor the horizontal distribution of the vertical stratification parameter. SMOS SSS data can thus be used to consistently anticipate the cooling inhibition in the wake of TCs traveling over the Amazon-Orinoco plume region.
Journal Of Geophysical Research-oceans (0148-0027) (Amer Geophysical Union), 2014-12 , Vol. 119 , N. 12 , P. 8271-8295

Droits : 2014. American Geophysical Union. All Rights Reserved.
http://archimer.ifremer.fr/doc/00252/36326/34855.pdf
http://archimer.ifremer.fr/doc/00252/36326/34856.pdf
DOI:10.1002/2014JC010107
http://archimer.ifremer.fr/doc/00252/36326/

Éditeur(s) : HAL CCSD
Résumé : 1 page
The main aim of this study, co-funded by BRGM, Regional Council of Guadeloupe, European Union, ADEME and UAG, was to examine the silica deposition mechanisms and estimate their deposition kinetics at acidic and basic pH conditions, during the cooling from 260 to 25°C of separated waters, discharged from production wells, located in the Bouillante geothermal field. The acquisition of this type of information is very useful not only for the geothermal exploitation but especially, if production fluids are re-injected in the ground, as this is envisaged in the Bouillante geothermal field. The different on site experiments showed that, in these conditions, the silica deposition was always initiated by a silica polymerization mechanism and the formation of a white colloidal gel, which slowed down the silica precipitation. In agreement with the literature data, this polymerization mechanism is characterized by an order 2 kinetic law, strongly dependant on pH. The determination of the specific surface area by specific mercury porosimetry for this gel (250 m2/g) in the UAG laboratories, allowed estimating the corresponding kinetic constant at 25°C. Other experiments at different final temperatures (50, 75 and 100°C) are necessary in order to define this constant as a function of the temperature. The silica precipitation under amorphous silica form was observed much later, after the polymerization stage, and only in particular conditions (long time of atmospheric exposure, water stagnation...). The pH of the Bouillante geothermal fluid is estimated to be close to 5.3±0.3, at 260°C, in the reservoir conditions. If this parameter, very influent on the kinetics of silica deposition, can be preserved at values less than 7 during the re-injection of the production fluids in the ground at relatively high temperatures (150-160°C), it is strongly probable that no chemical treatment is necessary to avoid silica precipitation.
19ème Conférence Géologique de la Caraïbe - 2011
Gosier, Guadeloupe, France

hal-00575943
https://hal-brgm.archives-ouvertes.fr/hal-00575943