Résumé : From the PNCR, GAP MPs free to vote conscience on gay rights bill By Johann Earle Stabroek News June 11, 2003 The PNCR will allow its members to vote their conscience on the controversial Constitution (Amendment) Act of 2001 which seeks to prevent discrimination against persons on the basis of their sexual orientation and other grounds. A number of religious organisations are opposed to the passage of the bill because it includes sexual orientation as one of the grounds. They are concerned that it could lead to a legalisation of homosexual relations and demands for recognition of gay marriages among other things. PNCR Member of Parliament (MP) Vincent Alexander told a forum at the National Library on Saturday, that the Bill did not seek to legalise homosexuality, but to ensure that persons would not be discriminated against based on their sexual preferences. He was one of two parliamentarians who showed up - the other being PNCR member, Myrna Peterkin. The forum was organised by Students Against Sexual Orientation Discrimination (SASOD), a group comprising fifteen students from the University of Guyana which was formed about two weeks ago. Alexander expects the vote on the bill to come up before the National Assembly in a matter of months. Paul Hardy, Leader of the Guyana Action Party (GAP), told Stabroek News that his party would not be using the so-called parliamentary whip. He added that GAP took a decision that every member should vote according to his or her own conscience. “We have no right to deny the rights of others based on sexual orientation. [The Bill] will guarantee rights to the homosexual.” GAP is in Parliament as part of an alliance with the Working People’s Alliance. GAP/WPA has two MPs. The bill was met with rejection from some members of the religious community in 2001 and as a result of this, the President did not assent to it. In a statement on Monday, the Central Islamic Organisa-tion of Guyana (CIOG) said that it stood in firm opposition to the Bill. The CIOG says the general purpose of the bill may be commendable and that the organisation’s objection is not based on a willingness to promote discrimination. Rather, the CIOG said, it was based on the fact that specific legal protection on the basis of sexual orientation without definition or qualification gives tacit legitimacy to practices which are considered criminal in Islam. “It is foreseeable that such a legal nod of approval (subtle as it may be) of these practices may pave the way for greater social (or even legal) acceptability in the future which, from the perspective of all Muslims including those in Guyana, is an undesirable and sinful outcome,” the CIOG statement said. At Saturday’s event, Muslim teacher Moulana Mohamed Ali Zenjibari spoke of instances of abuse, discrimination and harsh penalties meted out to gay and lesbian persons in countries such as Iran and Saudi Arabia and noted that the Quran did not sanction such punishments for homosexual behaviour. President of the CIOG, Fazeel Ferouz told Stabroek News that a meeting to discuss a strategy with regards to the bill was planned for tomorrow with various religious groups. Stabroek News tried to get a comment on the issue from the PPP/C but to no avail. ROAR leader, Ravi Dev said that his party was now having discussions on the issue. ROAR feels that it is an important question which has to do with morality and should be discussed across the country. He added legislators had to be in tune with their constituents on the issue. SASOD is lobbying for the legislation through the sensitisation of MPs. Keimo Benjamin, a law student at UG, gave a presentation based on the jurisprudential aspects of the discussion on sexual orientation. He argued that morality should not be the only guiding principle on which to base the laws. Sexual activities between two consenting male adults in private could not be equated with a violation of a person’s rights, he said, making the point that the thrust of his presentation was not whether homosexuality was wrong, but whether it violated the rights of others. He said that the attitudes of some towards this subject were based on preconceived notions and prejudices. He cited studies to show that the suppression of certain perceived deviant sexual impulses in persons might do more harm than good. One Harvard University study of teens who said they were gay indicated that those teens were three times more likely to commit suicide. Vidyaratha Kissoon, of Help and Shelter, in his contribution on Saturday, expressed his displeasure at the low turnout at the forum and urged the parliamentarians who showed up to take the message to their colleagues. He noted that because of homophobia, the numerical minority was terrified of speaking out against instances of discrimination. Gays and lesbians in Guyana were subjected to ridicule and abuse, and walk the streets at night not looking for sex necessarily, but for the companionship of persons who empathise with them. During his presentation, Joel Simpson, another member of SASOD, outlined a number of changes made within national jurisdictions that had international implications. One such crucial change was South Africa’s 1996 adoption of a new constitution, making that country the first in the world to expressly include sexual orientation as a prohibited ground of discrimination. It was the first time a developing country had taken the lead with respect to the rights of sexual minorities. He also said that according to Douglas Sanders, a Canadian jurist, the rights of homosexual, bisexual or transsexual men and women had never been officially recognised by the United Nations, despite the fact that international laws on the issue began to emerge at the close of the Second World War. Simpson said that under Article 170 (5), as amended by Section 8 of the Constitution (Amendment) (No. 4) Act 2000, the President is required to assent to any bill which is returned by the National Assembly unaltered after a two-thirds majority within 90 days of its presentation to him. To the parliamentarians present, Simpson stressed that the onus was now on them to adequately represent their constituents which include lesbian, gay, bisexual and transsexual Guyanese. http://www.landofsixpeoples.com/news301/ns306115.htm and Vote on sexual orientation should be a matter of conscience - MP Alexander By Esther Elijah Guyana Chronicle June 8, 2003 PEOPLE’S National Congress (PNC/R) Member of Parliament Mr. Vincent Alexander, said the Opposition will vote on “conscience” when the piece of legislation on sexual orientation is again brought before the National Assembly. “With specific reference to my party, when this Bill gets back to the Parliament in the spirit of the arguments here, we will not use the `whip’. Our party will not say we have to vote for the provision (in the Sexual Orientation Bill). We will allow our members to vote as a matter of conscience,” he told participants gathered in the Conference Room of the National Library. “We feel this is a matter of conscience. You may end up with a collective position but you have to deal with us individually,” Alexander said at a poorly attended public consultation aimed at gaining support for sexual orientation to be considered a fundamental right in Guyana. Alexander, one of the main persons who sat on the Constitutional Reform Commission that addressed this controversial clause, said the legislation was not meant to legalise homosexual activities in Guyana. “It was intended to ensure that persons who have an orientation - a way of thinking - which may or may not lead to a certain activity, to not be discriminated against, in terms of their rights,” he explained. Alexander noted that very often, discussions on the sexual orientation provision in the Bill have led to seepages into other areas where debates centre on the “right to be homosexual.” “I am saying the Bill does not comment on that… However, law is peculiar, especially in a Common Law system. Once you venture out and change the law, very often you open other windows which we cannot definitively say exist or does not exist in advance,” he said. “The fear of some people is that the legislators might say one thing and the Courts will eventually say something else. While some people can’t argue against the law, per say, they will say this has opened a window of opportunity not meant to be opened. So, it is better to stay without a window than open it and then have a possibility of something you didn’t intend to happen - happening sometime in the future.” Alexander added: “I want to say I’ve found this activity to have been rich from the perspective of the amount of research which was done by student (speakers). Without any comment as to whether I agree with the arguments, I would wish that much more research on other issues be done by students, and that at the University (of Guyana) students would find it convenient to have forums on other issues, with the same depth of research for their own intellectual development.” Alexander and other Opposition M.P, Lurlene Nestor were the only three Parliamentarians in attendance at the session organised by the recently formed `Students Against Sexual Orientation Discrimination’ (SASOD), a group that has a membership of 15 mostly University of Guyana (UG) students from various faculties. SASOD was established two weeks ago. With the exception of members of the press, the consultation only managed to attract 11 persons, a handful of who were SASOD members. While congratulating the students for an “insightful” presentation, Nestor pointed out that whether or not she chooses to agree with their position is “another issue” and she is entitled to her “own view”. “The issue of sexual orientation is very `toucheous’ …while we agree with the human rights provisions and all that as a society, we must also revert to our own society. Some of the very critical questions that I would want to ask is whether or not at the society (level) we are ready for that kind of thing,” she remarked. “We cannot, at (any) time, ignore the religious groups in our society. If we look at statistics going back to 1992 from a survey done by the Bureau of Statistics, we would see that a small section of the Guyanese population might be considered as people who do not subscribe to a religious view. While the laws are not necessarily based on moral values, we must acknowledge the fact that we might want to revert to many of the cases that (concern) laws that protect public morality.” Nestor told the speakers at the consultation these were some of the issues that they needed to deal with. She highlighted, too, that what must be examined is the effects of same-sex marriages on society and how this issue must be tackled. “These are some of the things we should consider and I don’t think you dealt with that in the presentations,” Nestor stated, adding that the issues must be addressed “frontally.” “Do we think that with the coming to being of this Bill that there might be quite a number of challenges to the Constitution in relation to the same issue of a man marrying a man? What do we do at the society (level)? Do we recognise that?” were the questions directed at the five speakers at the session. Nestor continued: “There is some argument that says, `Oh the Bill does not promote homosexuality or does not encourage a man to marry (another) man, but if you look at Section (15) that talks about `non-discrimination’ then how can we not, with the passage of this Bill, allow a man not to marry (another) man.” According to Nestor, matters of this nature constitute some of the “inconsistencies” of the Bill. On the argument raised by presenters at the session on who determines what is morality, Nestor said in the concept of democracy it is the people who are the determinants based on a “line of thinking.” She also rebutted on grounds that put the spotlight on teachers who may have been caught “interfering” with their young students and who may subsequently be dismissed from their jobs. “Could you imagine such a person interfering with a boy below age 10 - and by virtue of the fact that the Bill is there, the judges (in the case) will have to use their discretion in terms of what happens. We will have more Constitutional changes and problems (arising with the passage of the Bill).” SASOD member and law student, Joel Simpson, in reply, said he doesn’t think any homosexual in Guyana wants to “run into a church and ask that people marry them or anything of that sort.” At one point likening the church to a “club”, Simpson claimed the church has the right to exclude whomever it wants. He further stated that in accordance with the Constitution, people of the same sex do not currently have the right to marry, and will also not be able to do such an act with the passage of the Bill. However, Simpson said it is possible that the law, with the passage of the Bill, would have to recognise same-sex domestic partnerships in relation to employment benefits, sharing of properties, etc. Simpson said he believes there should be a realm of “public” and “private” morality between consenting adults, and implied that the Bill did not fully give “rights” to homosexuals. But, Nestor interjected: “I am informing you further…that the Sexual Orientation provision has, in fact, in some way recognised the rights of homosexuals and we must accept that.” Meanwhile, there was no vocal Christian representative(s) at the consultation and apart from the two Opposition representatives none other participant gave comments or directed questions at the presenters. Other speakers in support of the sexual orientation clause were: Moulana Mohammed Ali Zenjiban, Assistant Director of the International Islamic College; Denuka Radzik from Red Thread, Keimo Benjamin, UG law student and Vidyartha Kissoon from Help & Shelter. The Sunday Chronicle has been reliably informed that the Georgetown Ministers Fellowship, representing groups of Christian leaders staunchly against sexual orientation as a right in Guyana, have recently prepared a detailed 16-page document outlining issues arising from research to further boost their argument against the inclusion of the clause. The document is yet to be made public. http://www.landofsixpeoples.com/news301/nc306083.htm

Droits : All rights reserved by the source institution.
http://ufdc.ufl.edu/AA00014700/00001

Éditeur(s) : Oxford Univ Press
Résumé : Biological reference points are important tools for fisheries management. Reference points are not static, butmay change when a population's environment or the population itself changes. Fisheries-induced evolution is one mechanism that can alter population characteristics, leading to "shifting" reference points by modifying the underlying biological processes or by changing the perception of a fishery system. The former causes changes in "true" reference points, whereas the latter is caused by changes in the yardsticks used to quantify a system's status. Unaccounted shifts of either kind imply that reference points gradually lose their intended meaning. This can lead to increased precaution, which is safe, but potentially costly. Shifts can also occur in more perilous directions, such that actual risks are greater than anticipated. Our qualitative analysis suggests that all commonly used reference points are susceptible to shifting through fisheries-induced evolution, including the limit and "precautionary" reference points for spawning-stock biomass, B-lim and B-pa, and the target reference point for fishing mortality, F-0.1. Our findings call for increased awareness of fisheries-induced changes and highlight the value of always basing reference points on adequately updated information, to capture all changes in the biological processes that drive fish population dynamics.
Ices Journal Of Marine Science (1054-3139) (Oxford Univ Press), 2013-07 , Vol. 70 , N. 4 , P. 707-721

Droits : 2013 International Council for the Exploration of the Sea. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com
http://archimer.ifremer.fr/doc/00151/26228/24302.pdf
DOI:10.1093/icesjms/fst077
http://archimer.ifremer.fr/doc/00151/26228/

Éditeur(s) : OMICS Publishing Group
Résumé : Coastal tropical shrimp farming may impact the adjacent ecosystems through the release of large quantities of effluents rich in nutrients. In New Caledonia, mangroves are considered as a natural biofilter to reduce impacts on the surrounding World Heritage listed lagoon. Our main objective was to understand the influence of effluent discharge on the biogeochemistry of mangrove sediments. A monitoring of the physico-chemical parameters of mangrove sediments was carried out during a whole year, including active and non active periods of the farm. The parameters studied were: i) benthic primary production (Chl-a concentrations), ii) physico-chemical parameters of sediments (redox potential, pH, salinity, TOC, TN, TS, δ13C and δ15N), iii) concentrations of dissolved nitrogen, iron and phosphorus. A mangrove developing in the same physiographic conditions, presenting the same zonation, and free of anthropogenic input was used as reference. The concentration of benthic Chl-a measured at sediment surface in the effluent receiving mangrove was twice to three times that measured in the control zone whatever the season. We thus suggest that nutrients inputs significantly increased the phytobenthic production in the effluent receiving mangrove during the whole year, even after the cessation of discharges and because of natural seasonal dynamic of phytobenthos. Although the flow of surface OM was increased, the OM content at depth was not higher than in the control mangrove. However, the contribution of mangrove detritus to the sedimentary organic pool was higher probably as a result of higher density and much greater individual size of the mangrove trees. Unlike the control mangrove sediment, the effluent receiving mangrove sediment was not stratified, redox potential values were high and presence of Fe3+ was detected down to 50 cm depth, probably as a result of a larger root system, allowing a better sediment oxygenation and accentuated OM decomposition processes, and thus limiting ecosystem saturation.
Journal of Aquaculture Research & Development (21559546) (OMICS Publishing Group), 2014-07-03 , Vol. 5 , N. 5 , P. 1-13

Droits : 2014 Marchand C, et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
http://archimer.ifremer.fr/doc/00251/36253/34801.pdf
DOI:10.4172/2155-9546.1000262
http://archimer.ifremer.fr/doc/00251/36253/

Éditeur(s) : HAL CCSD
Résumé : International audience
In vitro evaluation of P-glycoprotein (P-gp) inhibitory potential is now a regulatory issue during drug development, in order to predict clinical inhibition of P-gp and subsequent drug-drug interactions. Assays for this purpose, commonly based on P-gp-expressing cell lines and digoxin as a reference P-gp substrate probe, unfortunately exhibit high variability, raising thus the question of developing alternative or complementary tests for measuring inhibition of P-gp activity. In this context, the present study was designed to investigate the use of the fluorescent dye rhodamine 123 as a reference P-gp substrate probe for characterizing P-gp inhibitory potential of 16 structurally-unrelated drugs known to interact with P-gp. 14/16 of these P-gp inhibitors were found to increase rhodamine 123 accumulation in P-gp-overexpressing MCF7R cells, thus allowing the determination of their P-gp inhibitory potential, i.e., their half maximal inhibitor concentration (IC50) value towards P-gp-mediated transport of the dye. These IC50 values were in the range of variability of previously reported IC50 for P-gp and can be used for the prediction of clinical P-gp inhibition according to Food and Drug Administration (FDA) criteria, with notable sensitivity (80%). Therefore, the data demonstrated the feasibility of the use of rhodamine 123 for evaluating the P-gp inhibitory potential of drugs
Pharmaceutics

hal-01305488
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01305488
DOI : 10.3390/pharmaceutics8020012
PUBMED : 27077878

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Sedimentary rocks and detrital minerals sample large areas of the continental crust, and they are increasingly seen as a reliable archive for its global evolution. This study presents two approaches to model the growth of the continental crust through the sedimentary archive. The first builds on the variations in U-Pb, Hf and O isotopes in global databases of detrital zircons. We show that uncertainty in the Hf isotope composition of the mantle reservoir from which new crust separated, in the 176Lu/177Hf ratio of that new crust, and in the contribution in the databases of zircons that experienced ancient Pb loss(es), adds some uncertainty to the individual Hf model ages, but not to the overall shape of the calculated continental growth curves. The second approach is based on the variation of Nd isotopes in 645 worldwide fine-grained continental sedimentary rocks with different deposition ages, which requires a correction of the bias induced by preferential erosion of younger rocks through an erosion parameter referred to as K. This dimensionless parameter relates the proportions of younger to older source rocks in the sediment, to the proportions of younger to older source rocks present in the crust from which the sediment was derived. We suggest that a Hadean/Archaean value of K = 1 (i.e., no preferential erosion), and that post-Archaean values of K = 4–6, may be reasonable for the global Earth system. Models built on the detrital zircon and the fine-grained sediment records independently suggest that at least 65% of the present volume of continental crust was established by 3 Ga. The continental crust has been generated continuously, but with a marked decrease in the growth rate at ~ 3 Ga. The period from > 4 Ga to ~ 3 Ga is characterised by relatively high net rates of continental growth (2.9–3.4 km3 yr− 1 on average), which are similar to the rates at which new crust is generated (and destroyed) at the present time. Net growth rates are much lower since 3 Ga (0.6–0.9 km3 yr− 1 on average), which can be attributed to higher rates of destruction of continental crust. The change in slope in the continental growth curve at ~ 3 Ga is taken to indicate a global change in the way bulk crust was generated and preserved, and this change has been linked to the onset of subduction-driven plate tectonics. At least 100% of the present volume of the continental crust has been destroyed and recycled back into the mantle since ~ 3 Ga, and this time marks a transition in the average composition of new continental crust. Continental crust generated before 3 Ga was on average mafic, dense, relatively thin (< 20 km) and therefore different from the calc-alkaline andesitic crust that dominates the continental record today. Continental crust that formed after 3 Ga gradually became more intermediate in composition, buoyant and thicker. The increase in crustal thickness is accompanied by increasing rates of crustal reworking and increasing input of sediment to the ocean. These changes may have been accommodated by a change in lithospheric strength at around 3 Ga, as it became strong enough to support high-relief crust. This time period therefore indicates when significant volumes of continental crust started to become emergent and were available for erosion and weathering, thus impacting on the composition of the atmosphere and the oceans.
ISSN: 0037-0738

hal-01622696
https://hal.archives-ouvertes.fr/hal-01622696
DOI : 10.1016/j.sedgeo.2017.06.001

Éditeur(s) : HAL CCSD Royal Society of Chemistry
Résumé : International audience
Abstract View references (60)Here we show the long term performance at high temperatures of a multi-tube module containing 8 membranes in 4 parallel lines with a total of 545 cm 2 area. The membranes were prepared via thin film dip coating of cobalt oxide silica (CoO xSi) sol-gel on tubular alumina supports. A preliminary study found that the sol-gel containing 20 mol% cobalt oxide formed the best microporous structure with the highest surface area and pore volume. All resulting membranes delivered permeances of ∼1 × 10 -7 mol m -2 s -1 Pa -1 at 500 °C, indicating a high repeatability for the membrane fabrication process. The permselectivities of helium (He) and hydrogen (H 2) over carbon dioxide (CO 2) and nitrogen (N 2) increased from 10-20 at 100 °C to values close to 1000 at 500 °C. Additionally, the apparent energies of activation (E act) for the smaller kinetic diameter gases He and H 2 at 12.2 and 19.5 kJ mol -1 were high and contrary to the negative values for larger gases N 2 and CO 2 at -1.8 and -7.4 kJ mol -1. These remarkable results were attributed to the molecular sieving mechanism of the microporous silica which was enhanced by the embedding of cobalt oxide into the matrix, delivering structural control with an average pore size of 3 Å. The E act for H 2 permeance was higher than that of He, indicating that the cobalt oxide played an important role in H 2 transport. Two membrane lines performed exceptionally well for binary gas mixture processing with H 2 purity reaching values close to 100% in the permeate stream for argon (Ar) concentrations of up to 80% in the retentate stream. A major finding here is that the binary gas selectivity was independent of temperature, contrary to the permselectivity observed for single gas permeance. Further, the H 2 flow rate was greatly affected by the concentration of Ar in the mixture, while the temperature dependency played only a marginal role. In particular, competitive adsorption in the percolative pathways containing pore constrictions or bottlenecks of the anisotropic CoO xSi matrix allowed Ar to impede H 2 diffusion. Finally, the CoO xSi membranes proved thermally stable and robust for 2000 h of testing for various thermal cycles up to 500 °C. © The Royal Society of Chemistry 2012.
Energy & Environmental Science

hal-01683199
https://hal.univ-antilles.fr/hal-01683199
DOI : 10.1039/c2ee03247c

Éditeur(s) : Elsevier
Résumé : Because Vibrio aestuarianus is known to cause serious infections in Pacific oyster Crassostrea gigas, a real-time PCR assay was developed targeting the dnaJ gene of this bacterium. Only V. aestuarianus strains isolated from C. gigas mortality events in different geographic areas and the reference strain tested positive, whereas no amplification products was obtained with type strains belonging to 23 other species of Vibrio. Sensitivity and reproducibility of the method were assessed using either seawater or oyster homogenate samples spiked with one V aestuarianus strain. All these samples were stored at -20 degrees C in order to mimic retrospective or grouped natural sample analysis without quantification bias due to prolonged freezing. Analysis of standard curves revealed excellent correlation values between light microscopy cell enumerations and PCR Threshold Cycle (Ct) values, and acceptable PCR reaction efficiencies for all type of samples. Quantification curves of both sample types were equivalent, with a detection level as low as 1.6 V. aestuarianus cells in the PCR reaction tube, corresponding to 1.6.10(2) cells ml(-1) and 1.6.10(2) cells mg(-1) in seawater and entire oyster samples, respectively, taking into account the dilution factor used for appropriate template DNA preparation. Comparison of PCR assay reproducibility according to the complexity of samples revealed that seawater samples gave more reproducible quantification measures than samples from oyster homogenate, with precision of measured Ct values inferior to 0.4 and 0.6 respectively at 99% confidence. Use of the real-time PCR assay allowed us to monitor V. aestuarianus load in oysters naturally infected with this pathogen. Furthermore, we were able to detect V aestuarianus in samples of seawater in which oysters had been reared and in algal cultures used for feeding oysters. Because of the rapidity and reliability of the real-time PCR assay method used in this study, just a few hours are needed compared with the two days required using the classic culture method, this technique will be particularly valuable in mollusc pathology laboratories, for monitoring the source and course of infections by V. aestuarianus in pathogenesis and epidemiologic studies, as well as for designing appropriate prophylactic control measures. (C) 2009 Elsevier B.V. All rights reserved.
Journal of Microbiological Methods (0167-7012) (Elsevier), 2009-05 , Vol. 77 , N. 2 , P. 191-197

Droits : 2009 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/2009/publication-6447.pdf
DOI:10.1016/j.mimet.2009.01.021
http://archimer.ifremer.fr/doc/00000/6447/

Éditeur(s) : Université des Antilles Études caribéennes
Résumé : Par sa maîtrise des mediascapes, que représentent en particulier la télévision et Internet, le basket africain-américain et sa culture ont su s’imposer progressivement dans le paysage du basket hexagonal, devenant ainsi aujourd'hui la référence majeure pour grand nombre de pratiquants français. Certains jeunes pratiquants de banlieue parisienne, qui se sont attribué à juste titre le surnom de « Cain-ris », s’approprient fortement les normes et les valeurs de ce mouvement sportif et culturel étatsunien, modifiant ainsi leurs pratiques culturelles et leur identité. Cet article a donc pour objectif d’analyser la complexité de cette identité « Cain-ri », une identité créée dans ce contexte spécifique de mondialisation et qui prend racine de part et d’autre de l’Atlantique.
By means of its control over mediascapes, especially represented both by television and Internet, American basketball and its culture has gradually grown in the landscape of hexagonal basketball, becoming today the major reference for a large number of French players. Certain young players from Parisian suburbs, who rightly made theirs the nickname of "Cain-ris", strongly appropriate to themselves the standards and values of this sports and cultural movement from the US, modifying this way their cultural practices and their identity. The objective of the article is then to analyze the complexity of this “Cain-ri” identity, an identity created within the specific context of globalization, taking roots on both sides of the Atlantic Ocean

Droits : info:eu-repo/semantics/openAccess
urn:doi:10.4000/etudescaribeennes.5891
http://journals.openedition.org/etudescaribeennes/5891

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
The natural river water certified reference material SLRS-5 (NRC-CNRC) was routinely analysed in this study for major and trace elements by ten French laboratories. Most of the measurements were made using ICP-MS. Because no certified values are assigned by NRC-CNRC for silicon and 35 trace element concentrations (rare earth elements, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y and Zr), or for isotopic ratios, we provide a compilation of the concentrations and related uncertainties obtained by the participating laboratories. Strontium isotopic ratios are also given. Le matériau de référence certifié d'eau de rivière naturelle SLRS-5 (NRC-CNRC) est analysé régulièrement comme contrôle qualité par dix laboratoires français étudiant les éléments majeurs et en trace dans les solutions naturelles. La plupart des mesures sont réalisées par ICP-MS. Le silicium et 35 éléments en trace (terres rares, Ag, B, Bi, Cs, Ga, Ge, Li, Nb, P, Rb, Rh, Re, S, Sc, Sn, Th, Ti, Tl, W, Y et Zr) ne sont pas certifiés par NRC-CNRC. Aucun rapport isotopique n'est disponible. Nous proposons, pour ces éléments, des valeurs moyennes et leurs incertitudes associées obtenues par les différents laboratoires participants. Le rapport isotopique de Sr est aussi mesuré.
ISSN: 1639-4488

hal-00906166
https://hal.archives-ouvertes.fr/hal-00906166
DOI : 10.1111/j.1751-908X.2013.00232.x

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
People are exposed to multiple pollutants, especially indoors, in particular through ingestion of indoor settled dust. In the perspective of a cumulative risk assessment, a multi-residue analytical method based on pressurized liquid extraction (PLE) and gas chromatography/tandem mass spectrometry (GC/MS/MS) was developed for the simultaneous analysis in indoor dust of several classes of semi-volatile organic compounds (SVOCs) of health concern, from trace to highly concentrated compounds, including musk fragrances, organochlorines (OCs), organophosphates (OPs), polycyclic aromatic hydrocarbons (PAHs), polybromodiphenylethers (PBDEs), polychlorobiphenyls (PCBs), phthalates and pyrethroids. The method was validated in terms of limits of quantification (LOQ), and accuracy and precision via spiking experiments on an inert material (Celite(®) 545) and replicate analysis of the standard reference material SRM 2585 supplied by the National Institute of Standards and Technology (NIST). Method LOQs for 200 mg samples of sieved dust were 26 ng g(-1) for PCBs and some OCs, 65 ng g(-1) for musks, OPs, PAHs, PBDEs, pyrethroids, other OCs and some phthalates, 132 ng g(-1) for butylbenzylphthalate (BBP), 197 ng g(-1) for tributylphosphate and 1579 ng g(-1) for other phthalates. Quadratic calibration curves were established for each compound by analyzing at least five calibration solutions and exhibited determination coefficients higher than 0.999. The method was successfully applied to the SRM 2585 and seven real indoor dust samples. The results obtained on SRM 2585 demonstrate both excellent reproducibility and agreement with the indicative, reference or certified values and provide, for the first time, indicative concentrations for chlorpyrifos, diazinon, diisononylphthalate (DiNP) and tetramethrin. The results obtained on real dust samples illustrate the ability of the proposed method to quantify a wide range of SVOCs in a single analysis, making it appropriate for environmental monitoring programs or large-scale studies with a large number of samples.
ISSN: 0021-9673

hal-00994493
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00994493
DOI : 10.1016/j.chroma.2014.02.004
PUBMED : 24598454

Résumé : This guide is intended to facilitate the implementation of specifications for marine environmental monitoring in New Caledonia. It is intended for public or private environmental actors. He provides a set of information on marine monitoring: summary of environmental regulations and the practical implications, definitions of terms, proposed general approach for the establishment of a monitoring, sampling strategy elements, method to develop reference frames, recommendations for the management and exploitation of data collected. The guide also provides lists of suggested environmental parameters to monitor for different pressures and general state of the environment, as well as, a set of methodology sheets for parameters and (when available) the reference values. This guide produced in 2011 based on technical and scientific knowledge that can evolve and is intended to be updated in the future.
Ce guide est destiné à faciliter la réalisation de cahiers des charges pour les suivis environnementaux marins en Nouvelle-Calédonie. Il s’adresse aux acteurs environnementaux publics ou privés. Il leur fournit un ensemble d’informations relatives aux suivis marins : résumé de la réglementation environnementale et de ces implications concrètes, définitions de termes, proposition de démarche générale pour la mise en place d’un suivi, éléments de stratégie d’échantillonnage, méthode pour concevoir des grilles de lecture, préconisations en matière de gestion et de valorisation des données récoltées. Le guide fournit également des listes de paramètres conseillés pour suivre différentes pressions et l’état général du milieu ainsi qu’une série de fiches méthodologiques pour les paramètres et (quand elles existent) des valeurs de référence. Ce guide produit en 2011 s’appuie sur des techniques et des connaissances scientifiques qui peuvent évoluer et est destiné à subir des modifications dans les années à venir.

Droits : 2011 Ifremer, Melanopus, IRD
http://archimer.ifremer.fr/doc/00050/16163/13647.pdf
http://archimer.ifremer.fr/doc/00050/16163/

Éditeur(s) : HAL CCSD Société Géologique de France
Résumé : Based on a High-Resolution 3D seismic block acquired in the Gulf of Lion in 2004–2005 we investigated fluid pipes and pockmarks on the top of the interfluve between the Hérault canyon and the Bourcart canyon both created by turbidity currents and gravity flows from the shelf to the deep basin in the north-western Mediterranean Sea. Combining the geometry of the potential fluid pipes with the induced deformation of surrounding sediments leads then to the ability to differentiate between potential fluid sources (root vs source) and to better estimate the triggering mechanisms (allochtonous vs. autochtonous cause). We linked together a set of derived attributes, such as Chaos and RMS amplitude, to a 3D description of pipes along which fluids may migrate. As previously shown in other basins, the induced deformation, creating cone in cone or V-shaped structures, may develop in response to the fluid pipe propagation in unconsolidated sediments in the near surface. The level at the top of a cone structure is diachronous. It means that stratigraphic levels over this surface are deformed at the end of the migration. They collapse forming a depression called a pockmark. These pipes are the result of repeated cycles of fluid expulsion that might be correlated with rapid sea-level rise instead of sediment loading. The most recent event (MIS 2.2 stage) has led to the formation of a pockmark on the modern seafloor. It has been used as a reference for calculating the effect of a rapid sea-level rise on fluid expulsion. As all physical and geometrical parameters are constrained, we were able to define that a + 34 m of sea level rise may account for triggering fluid expulsion from a very shallow silty-sandy layer at 9 m below seafloor since the last glacial stage. This value is consistent with a sea level rise of about 102 m during this period. This study shows that the episodic nature of fluid release resulted from hydromechanical processes during sea-level rise due to the interactivity between high pressure regimes and principal in situ stresses.
ISSN: 0037-9409

hal-01667241
https://hal.archives-ouvertes.fr/hal-01667241
DOI : 10.1051/bsgf/2017190

Éditeur(s) : HAL CCSD John Libbey Eurotext
Résumé : International audience
French toxicological reference values (VTR) and French occupational exposure limit values (VLEP) are indicators that are widely used in risk assessment for, respectively, human and occupational health. Neither value can replace the other. However, the information obtained for one can be very useful for the other. We propose to clarify the fundamental differences and similarities between these two values. To achieve this, we review first their history and then the methods used to derive them; we conclude by proposing some improvements to harmonize them. A case study of formaldehyde illustrates our analysis.
ISSN: 1635-0421

hal-00936267
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00936267
DOI : 10.1684/ers.2013.0647

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The formation age of the Siberian cratonic mantle is not well established as yet. Re–Os data on various mantle-derived materials have shown that it contains Archaean components, but the reported Re-depletion ages show a broad variation range (3.4 to 1 Ga) and are commonly ≤ 2 Ga for peridotite xenoliths. We report Hf and Nd isotope data for cpx and garnet separated from nine refractory spinel and garnet peridotite xenoliths from the Udachnaya kimberlite. The cpx from low-opx spinel harzburgites show extremely high εHf values, from + 607 to + 2084, which testify to long-term evolution of these rocks with high Lu/Hf ratios, consistent with their residual origin and near absence of post-melting enrichments in the Lu–Hf system. Such high εHf values are unusual for cpx from other cratonic peridotites and are higher than those reported for depleted cpx in off-cratonic peridotites. The clinopyroxenes from low-opx spinel harzburgites yield Hf model ages from 1.9 to 1.7 Ga while the cpx from high-opx spinel harzburgites yield Hf model ages from 3.0 to 1.9 Ga. When plotted together, they define a Lu/Hf isochron with an age of 1.80 Ga, which we consider as a robust estimate of the formation age (melt extraction event) because it is obtained on residual rocks that show no evidence for HREE and Hf enrichments and because the model ages for three out of four individual samples are similar to each other. The cpx have high εNd of + 94 to + 123, which are inconsistent with their low Sm/NdPM of < 1 and yield no meaningful age estimates. The consistently high, positive εNd in these cpxs can be interpreted in terms of long-term evolution of refractory peridotites with high Sm/Nd, followed by relatively recent LREE enrichments.We infer that a significant part of the lithospheric mantle in the central Siberian craton may have been formed during a major event (or a series of events) at around 1.8 Ga. Older ages reported for the central Siberian craton may refer to less common materials from cratonic or other domains formed in the Archaean that were later incorporated into the cratonic roots. The transition from the “Archaean” to “modern” tectonic regimes in Siberia and possibly elsewhere may have taken place at 1.8–1.9 Ga rather than at ~ 2.5 Ga, i.e. in the second half of the Paleoproterozoic rather than at the Archaean–Proterozoic boundary, at which time the asthenospheric mantle became generally too cold to experience high-degree melting on a large scale. The ~ 1.8 Ga formation age of the Siberian cratonic mantle is coeval with that for a major part of the ancient continental crust in the central Siberian craton. The temporal crust–mantle links may be explained either by the generation of the initial source materials for continental crust in the same melting event that formed the residual peridotites or, alternatively, by subduction and melting of pre-existing proto-lithosphere destabilized by a major mantle upwelling that formed the residual mantle.
ISSN: 0009-2541

hal-01115519
https://hal.archives-ouvertes.fr/hal-01115519
DOI : 10.1016/j.chemgeo.2014.10.018

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Particle/gas and dust/gas partition coefficients (Kp and Kd) are two key parameters that address the partitioning of semi-volatile organic compounds (SVOCs) between gas-phase, airborne particles, and settled dust in indoor environment. A number of empirical equations to calculate the values of Kp and Kd have been reported in the literature. Therefore, the difficulty lies in the selection of a specific empirical equation in a given situation. In this study, we retrieved from the literature 38 empirical equations for calculating Kp and Kd values from the SVOC saturation vapor pressure and octanol/air partition coefficient. These values were calculated for 72 SVOCs: 9 phthalates, 9 polybrominated diphenyl ethers (PBDEs), 11 polychlorinated biphenyls (PCBs), 22 biocides, 14 polycyclic aromatic hydrocarbons (PAHs), 3 alkylphenols, 2 synthetic musks, tributylphosphate, and bisphenol A. The mean and median values of log10 Kp or log10 Kd for most SVOCs were of the same order of magnitude. The distribution of log10 Kp values was fitted to either a normal distribution (for 27 SVOCs) or a log-normal distribution (for 45 SVOCs). This work provides a reference distribution of the log10 Kp for 72 SVOCs, and its use may reduce the bias associated with the selection of a specific value or equation
ISSN: 0045-6535

hal-01295671
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01295671
DOI : 10.1016/j.chemosphere.2016.03.007
PUBMED : 27016817

Éditeur(s) : HAL CCSD Walter de Gruyter
Résumé :  
A method for measuring shrinkage resulting from drying in the three anisotropic directions is developed and tested. Measurements are performed on sawn discs, a technique which simplifies preparation and enables large numbers of measurements. Shrinkage values can be represented as a map of the disc surface. The results indicate that comparisons between shrinkage distribution and tension wood distribution on the discs show a clear relationship and can be measured with relatively high accuracy in reference to the "shrinkage map". In the long term, this method could be useful in the timber industry as a means for choosing the direction in which logs are cut depending on their type of wood composition.
Holzforschung

hal-01032055
https://hal.archives-ouvertes.fr/hal-01032055
DOI : 10.1515/HF.2003.100

Éditeur(s) : Université des Antilles Études caribéennes
Résumé : La prostitution est une problématique très intéressante d’une part parce qu’elle est transversale à tous les temps, à toutes les classes sociales, à tous les espaces, et d’autre part parce qu’il s’agit d’un fléau qui se conjugue le plus souvent au féminin. Il s’agit à mon sens du versant spécifique d’une problématique universelle dont personne ne peut s’affranchir sans mettre en jeu l’ensemble de la condition humaine. En effet, la prostitution est le lieu où convergent et se concentrent de façon exacerbée tous les maux d’une société. La femme est malgré elle au centre de ce système dans lequel on retrouve les frustrations, les rapports de domination, de pouvoir, la violence, la misère, la corruption, l’aliénation… La prostitution, tout comme le concept de genre, est une construction sociale, dans laquelle les femmes sont enfermées réellement et symboliquement.D’autre part, si les maux d’une société sont décuplés dans le système de la prostitution, nulle part ailleurs n’existe un tel abîme entre fantasme et réalité. C’est le lieu des fausses représentations et des euphémismes comme le montrent ces deux expressions édulcorées « zones de tolérance » et « femmes publiques ». A Cuba, malgré les tentatives d’éradication de la prostitution dans les premières décennies qui suivirent le triomphe de la Révolution de 1959, la chute du bloc soviétique et la période de pénurie qui s’ensuivit donnèrent lieu à un retour de cette prostitution, sous de nouvelles formes qui persistent aujourd’hui. Cependant, il fut une époque, celle de la première République (1902-1958) durant laquelle Cuba, rongée par un système néocolonial, connût une recrudescence de ce phénomène, dans des proportions jamais égalées. Une époque somme toute récente où les zones de tolérance, espaces où étaient regroupées les maisons closes, occupaient une grande partie de La Havane coloniale ainsi que des quartiers entiers à travers l’île. A l’intérieur de ces zones très lucratives dont profitaient à la fois les proxénètes, policiers, politiques et hommes d’affaires, les femmes cubaines, mais également, dans une grande proportion des Françaises victimes de la traite des Blanches, se trouvaient au cœur d’un système qui étaient à lui seul le symptôme de la frustration néocoloniale, mais également de l’exacerbation du patriarcat.Cette problématique, on ne peut plus actuelle, convoque la pluridisciplinarité, c’est pourquoi j’ai eu recours à des témoignages de prostituées depuis le début du siècle jusqu’à la Révolution, recueillis et publiés à Cuba. Je me suis penchée sur les différents discours sur la prostitution de l’époque, discours politiques et féministes. Les rapports de police, les plaintes déposées par des femmes, les comptes rendus de procès, et les descriptions des médecins-hygiénistes sont autant de sources qui viennent corroborer les témoignages.
The republican era in Cuba is a complex and difficult one for the Cuban population. 1898 remains engraved in people’s memories as being a time of great disillusion for a population who, having freed itself from Spanish colonial domination, was deprived of independence by the United States of America. Three years of American intervention sufficed to put power bases into place, guarantee maximal exploitation conditions and organize the legal framework of the American domination over Cuba by means of the Platt Amendment in 1901. The protectorate set up by the United States, followed by a neocolonial system in 1934, relies upon the collaboration of presidents and corrupt governments succeeding each other in power. Corruption, nepotism and violence are put in place in a society in which inequality is dramatically worsening and all moral values are disintegrating. In this context and in a Cuban society governed with patriarchal rules, women are the first victims of the system. After the wars of independence, the only options they have are marriage, work or prostitution. Legitimate marriage is only available to a privileged few. With regards to employment, only 9.8% of women have the opportunity to work and this percentage didn’t change until 1959. It was at this time that prostitution reached unprecedented levels. It wasn’t just the case of a few marginalized women but of thousands of mothers, wives, widows and working women who were trapped in this alienating condition, forced to sell their bodies. Legislation and violence are used to control and restrict the work space for prostitutes, removing these ‘streetwalkers’ from the public eye, grouping them together in tolerance zones with very strict rules, which are in reality in the hands of Cuban and French procurers, and subjecting them to constant inspections carried out by hygienists who physically and symbolically assault women’s bodies. What is more, speeches about prostitution, whether made by politicians, feminists, journalists, doctors or mere observers, contribute significantly to a certain representation of these women. While debates about prostitution have recently shaken public opinion, this work refers back to an episode of Cuba’s history which brings us to reflect upon the evolution of the phenomenon and on its protean nature.
Cuba

Droits : info:eu-repo/semantics/openAccess
urn:doi:10.4000/etudescaribeennes.6945
http://journals.openedition.org/etudescaribeennes/6945

Éditeur(s) : HAL CCSD MDPI AG, Basel, Switzerland
Résumé : International audience
Abstract View references (46)This work shows the preparation of silica membranes by a two-step sol-gel method using tetraethyl orthosilicate in ethanolic solution by employing nitric acid and ammonia as co-catalysts. The sols prepared in pH 6 resulted in the lowest concentration of silanol (Si-OH) species to improve hydrostability and the optimized conditions for film coating. The membrane was tested to desalinate 0.3-15 wt % synthetic sodium chloride (NaCl) solutions at a feed temperature of 22 °C followed by long term membrane performance of up to 250 h in 3.5 wt % NaCl solution. Results show that the water flux (and salt rejection) decrease with increasing salt concentration delivering an average value of 9.5 kg m-2 h-1 (99.6%) and 1.55 kg m-2 h-1 (89.2%) from the 0.3 and 15 wt % saline feed solutions, respectively. Furthermore, the permeate salt concentration was measured to be less than 600 ppm for testing conditions up to 5 wt % saline feed solutions, achieving below the recommended standard for potable water. Long term stability shows that the membrane performance in water flux was stable for up to 150 h, and slightly reduced from thereon, possibly due to the blockage of large hydrated ions in the micropore constrictions of the silica matrix. However, the integrity of the silica matrix was not affected by the long term testing as excellent salt rejection of >99% was maintained for over 250 h. © 2013 by the authors; licensee MDPI, Basel, Switzerland.
ISSN: 2077-0375

hal-01683203
https://hal.univ-antilles.fr/hal-01683203
DOI : 10.3390/membranes3030136

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Humans are exposed to a large number of contaminants, many of which may have similar health effects. This paper presents a framework for identifying pollutants to be included in a cumulative risk assessment approach. To account for the possibility of simultaneous exposure to chemicals with common toxic modes of action, the first step of the traditional risk assessment process, i.e. hazard identification, is structured in three sub-steps: (1a) Identification of pollutants people are exposed to, (1b) identification of effects and mechanisms of action of these pollutants, (1c) grouping of pollutants according to similarity of their mechanism of action and health effects. Based on this exposure-based grouping we can derive "multi-pollutant" toxicity reference values, in the "dose-response assessment" step. The approach proposed in this work is original in that it is based on real exposures instead of a limited number of pollutants from a unique chemical family, as traditionally performed. This framework is illustrated by the case study of semi-volatile organic compounds in French dwellings, providing insights into practical considerations regarding the accuracy of the available toxicological information. This case study illustrates the value of the exposure-based approach as opposed to the traditional cumulative framework, in which chemicals with similar health effects were not always included in the same chemical class.
ISSN: 0013-9351

hal-00982315
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00982315
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00982315/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-00982315/file/An_exposure-based_framework_for_grouping_pollutants_accepted.pdf
DOI : 10.1016/j.envres.2014.01.007

Éditeur(s) : Elsevier Science Bv
Résumé : For many trace elements, continental margins are the location of intense exchange processes between sediment and seawater, which control their distribution in the water column, but have yet to be fully understood. In this study, we have investigated the impact of fluid seepage at cold seeps on the marine cycle of neodymium. We determined dissolved and total dissolvable (TD) concentrations for REE and well-established tracers of fluid seepage (CH4, TDFe, TDMn), and Nd isotopic compositions in seawater samples collected above cold seeps and a reference site (i.e. away from any fluid venting area) from the Niger Delta margin. We also analyzed cold seep authigenic phases and various core-top sediment fractions (pore water, detrital component, easily leachable phases, uncleaned foraminifera) recovered near the hydrocast stations. Methane, TDFe and TDMn concentrations clearly indicate active fluid venting at the studied seeps, with plumes rising up to about 100 m above the seafloor. Depth profiles show pronounced REE enrichments in the non-filtered samples (TD concentrations) within plumes, whereas filtered samples (dissolved concentrations) exhibit slight REE depletion in plumes relative to the overlying water column and display typical seawater REE patterns. These results suggest that the net flux of REE emitted into seawater at cold seeps is controlled by the presence of particulate phases, most probably Fe-Mn oxyhydroxides associated to resuspended sediments. At the reference site, however, our data reveal significant enrichment for dissolved REE in bottom waters, that clearly relates to diffusive benthic fluxes from surface sediments. Neodymium isotopic ratios measured in the water column range from epsilon(Nd) similar to-15.7 to -10.4. Evidence that the epsilon(Nd) values for Antarctic Intermediate waters (AAIW) differed from those reported for the same water mass at open ocean settings shows that sediment/water interactions take place in the Gulf of Guinea. At each site, however, the bottom water epsilon(Nd) signature generally differs from that for cold seep minerals, easily leachable sediment phases, and detrital fractions from local sediments, ruling out the possibility that seepage of methane-rich fluids and sediment dissolution act as a substantial source of dissolved Nd to seawater in the Gulf of Guinea. Taken together, our data hence suggest that co-precipitation of Fe-Mn oxyhydroxide phases in sub-surface sediments leads to quantitative scavenging of dissolved REE at cold seeps, preventing their emission into bottom waters. Most probably, it is likely that diffusion from suboxic surface sediments dominates the exchange processes affecting the marine Nd cycle at the Niger Delta margin. (C) 2011 Elsevier B.V. All rights reserved.
Earth And Planetary Science Letters (0012-821X) (Elsevier Science Bv), 2011-12 , Vol. 312 , N. 3-4 , P. 443-452

Droits : 2011 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/00066/17754/15571.pdf
DOI:10.1016/j.epsl.2011.10.008
http://archimer.ifremer.fr/doc/00066/17754/