Éditeur(s) : HAL CCSD AGU and the Geochemical Society
Résumé : International audience
Analysis of the microstructures in the km-scale mantle shear zone that separates the northern and the central parts of the Lanzo peridotite massif provides evidence of an evolution in time and space of deformation processes accommodating shearing in the shallow mantle within an extensional setting. This shear zone displays an asymmetric distribution of deformation facies. From south to north, gradual reorientation of the foliation of coarse porphyroclastic plagioclase-bearing peridotites is followed by development of protomylonites, mylonites, and mm-scale ultramylonite bands. A sharp grain size gradient marks the northern boundary. Early deformation under near-solidus conditions in the south is recorded by preservation of weakly deformed interstitial plagioclase and almost random clinopyroxene and plagioclase crystal orientations. Feedback between deformation and melt transport probably led to melt focusing and strain weakening in the shear zone. Overprint of melt-rock reaction microstructures by solid-state deformation and decrease in recrystallized grain size in the protomylonites and mylonites indicate continued deformation under decreasing temperature. Less enriched peridotite compositions and absence of ultramafic dykes or widespread melt-impregnation microstructures north of the shear zone and clinopyroxene and amphibole enrichment in the mylonites and ultramylonites suggest that the shear zone acted as both a thermal barrier and a high-permeability channel for late crystallizing fluids. These observations, together with chemical data indicating faster cooling of central Lanzo relative to the northern body, corroborate that this shear zone is a mantle detachment fault. All deformation facies have crystal preferred orientations consistent with deformation by dislocation creep with dominant activation of the (010)[100] and (100)[001] systems in olivine and orthopyroxene, respectively. Dynamic recrystallization produces dispersion of olivine CPO but not a change of dominant deformation mechanism. Evidence for activation of grain boundary sliding is limited to mm-scale ultramylonite bands, where solid-state reactions produced very fine grained polymineralic aggregates. Except for these latest stages of deformation, strain localization does not result from the microstructural evolution; the grain size decrease is a consequence of the need to deform a rock volume whose strength continuously increases because of decreasing temperature conditions. Strain localization in the intermediate levels thus essentially results from the more localizing behavior of both the deep, partially molten, and shallow parts of this extensional shear zone distribution.
ISSN: 1525-2027

hal-00644844
https://hal.archives-ouvertes.fr/hal-00644844
DOI : 10.1029/2011GC003627

Résumé : Durant le mois de mai 1975, une mission m'a été confiée pour participer à la cinquante huitième campagne de recherche du navire océanographique nord-américain "Oregon II". Organisée par le Centre National des Pêches de Miami cette expédition comprenait, du 5 au 19 mai, un plan de chalutages expérimentaux sur le plateau continental guyano-brésilien entre 5° de latitude nord et l'équateur (Cayenne-Belem). Le but principal de la mission était l'analyse de la composition du stock des espèces commerciales de crevettes et celle de l'ichthyofaune associée. Parallèlement, de nombreux relevés bathymétriques, sédimentologiques et hydrologiques ont été effectués. Intégré à bord au sein de l'équipe chargée de l'étude faunistique et écologique des fonds de pêche, je me suis en outre intéressé, dans la mesure du possible, aux travaux concernant les caractéristiques physiques de la région.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/00047/15783/13184.pdf
http://archimer.ifremer.fr/doc/00047/15783/

Résumé : If Sea Bass fish farming (Dicentrarchus labrax L.) is currently experiencing an increase in Southern Europe, it is vital, in order to better reflect raising structures, to control its wastes. In order to do so, quantifying this species' wastes is essential to be able to present simple excretion ratios, easily useable by the farmer. Those ratios have been based on nitrogen, phosphorus and carbon masses established on intensive farming and 4 batches belonging to his stock (averaging 24, 5 to 362, 5 g). Each batch was followed up during the course of 1 month and fish farming in its entirety for 2 months. Mass assessments for nitrogen and phosphorus were level ((intrants = extrants) but never precise, contrary to what can be found in bibliography. The main wastes defined were linked to the biomasses found as well as the food quantity fed. Sea Bass carbon excretion could not be clearly defined. According to these follow ups, phosphorus would be the element better utilized by Sea Bass considering nutritional provision. Nitrogen, phosphorus and carbon quantities rejected through farming are very high since for nitrogen and carbon, 90% of the ingestion would be rejected in the environment.
INTRODUCTION : Les pêcheries de langoustine de Mer Celtique se situent essentiellement dans les subdivisions Vllg et Vllh. La réglementation communautaire sur les maillages à langoustine y a été appliquée à partir de 1978. L'emploi d'un maillage dérogataire pour la pêche de la langoustine n'est possible que si le pourcentage d'espèces protégées par une taille marchande pêchées en même temps que la langoustine est inférieur à un seuil déterminé en relation avec le maillage en vigueur. L'application de cette réglementation s'est effectuée suivant un calendrier particulier Avec un pourcentage d'espèces protégées supérieur à 60 %, la pêche est considérée comme dirigée vers le poisson et le maillage est celui de la réglementation générale, soit 80 mm. En fait, comme cela a été mentionné à maintes reprises, sous la pression de cette réglementation contraignante, les flottilles et les techniques de pêche ont évolué très rapidement si bien que le pouvoir de capture de ces navires, aussi bien sur la langoustine que sur le poisson, a considérablement augmenté. Dans la majorité des cas, la flexibilité est devenue la règle et l'adoption du maillage de 80 mm tend à se généraliser. Ces navires s'orientent toujours momentanément vers la pêche la plus rentable, la langoustine demeurant l'espèce-cible, même si elle ne constitue pas toujours pondéralement l'essentiel des captures. Un des reproches majeurs fait aux langoustiniers de Mer Celtique était la destruction possible d'immatures de poissons. Une évaluation de ces rejets a été réalisée en 1980, soit donc avec un maillage situé entre 55 et 60 mm. Pour la plupart des espèces, les rejets sont anecdotiques en raison vraisemblablement d'une distribution spatiale différente des immatures et des adultes. Dans le cas du merlan, les immatures sont concentrés dans les zones côtières en hiver et ne sont capturés que si les langoustiniers sont amenés à abandonner la zone des bancs centraux en raison, en particulier, du mauvais temps. Seuls le merlu et la cardine présentent des pourcentages de rejets très importants car ils sont inféodés aux mêmes fonds vaseux que la langoustine, et leurs migrations trophiques, s'il en existe, ont lieu dans ces aires de dépôts sédimentaires au pied des hauts fonds. Dans ces premières évaluations, le volume observé des rejets de merlu étaient pour le moins inquiétant et laissait supposer, soit qu'il existait sur le fond au moment du recrutement des quantités énormes d'immatures soit que la sélectivité du chalut était abaissée par la présence de la langoustine. Ce deuxième point a été vérifié depuis et il semble que la sélectivité du merlu avec ou sans chalut à langoustine soit strictement la même. Les rejets de langoustine n'ont pas été comptabilisés car les valeurs auraient été inexploitables en raison de la différence entre la taille marchande communautaire, soit 25 mm de longueur céphalothoracique et la taille française soit 34, 5 mm. Ils seraient respectivement de 1, 75 % en nombre dans le premier cas contre 55 % dans le deuxième. En raison des modifications importantes intervenues dans l'aménagement des pêches dans cette zone, il était indispensable de refaire une évaluation pondérale des rejets : Pour obtenir des compositions en taille des espèces ne se prêtant pas aux analyses habituelles sur les âges. Pour calculer des courbes de tri manuel sur les espèces dont il est difficile d'évaluer les rejets en routine, mais seulement dans la mesure où les rejets se superposent à la fraction commerciale de la capture.

Droits : info:eu-repo/semantics/openAccess
http://archimer.ifremer.fr/doc/1985/rapport-1753.pdf
http://archimer.ifremer.fr/doc/00000/1753/

Éditeur(s) : Walter De Gruyter & Co
Résumé : The section of the Liguro-Provencal basin north of the Balearic Islands is one of the most productive sites in the whole Mediterranean Sea, with intense phytoplankton bloom lasting about 2 months in late winter-early spring. The phytoplankton species composition of the area was investigated using light and electron microscopy to analyze bottle and net samples collected at several stations in spring 2000 and 2003. Serial dilution cultures established from bottle samples were also examined. A total of 168 phytoplankton taxa was identified, consisting of 73 Coscinodiscophyceae, 47 Dinophyceae, 25 Coccolithophyceae and 4 Prymnesiophyceae, 5 Prasinophyceae, 3 Chrysophyceae, 2 Cryptophyceae, 2 Dictyochophyceae, 1 Euglenophyceae, 1 Pelagophyceae, 1 Choanoflagellidea, 1 Filosea and 3 incertae sedis. We also provided a brief taxonomic description and original micrographs for 25 of the smallest and/or less known species identified in the study area, which may go undetected during routine microscopical analysis of fixed samples. Among these, 10 species were recorded for the first time in the Mediterranean Sea, confirming the need of detailed studies to reveal the biodiversity and biogeography of Mediterranean phytoplankton.
Botanica Marina (0006-8055) (Walter De Gruyter & Co), 2011-06 , Vol. 54 , N. 3 , P. 243-267

Droits : 2011 by Walter de Gruyter
http://archimer.ifremer.fr/doc/00038/14916/12245.pdf
DOI:10.1515/BOT.2011.033
http://archimer.ifremer.fr/doc/00038/14916/

Éditeur(s) : Geological Society of America
Résumé : The landward termination of Walvis Ridge consists of two east-trending basement ridges of probable basaltic composition enclosing a relatively important sedimentary basin. East of long. 10° E., the southern ridge disappears under the sediments of the continental margin. The trends of the basement ridges are in good agreement with the inferred direction of initial opening. Since its formation, the Walvis Ridge has probably dammed sediment coming from the south. The proposed identification of layer A, a very strong horizon over which the reflectors are nearly undisturbed, may indicate that no major tectonic phase has affected this area since the shift of the pole of opening for the south Atlantic in Late Cretaceous-early Tertiary time. [NOT CONTROLLED OCR]
Geological Society of America Bulletin (Geological Society of America), 1974 , Vol. 85 , P. 619-632

Droits : Geological Society of America
http://archimer.ifremer.fr/doc/1974/publication-5147.pdf
http://archimer.ifremer.fr/doc/00000/5147/

Éditeur(s) : HAL CCSD Mineralogical Society of America
Résumé : International audience
To test if hydrogen incorporation by ionic diffusion can occur between a volatile-rich kimberlitic liquid and forsterite, results of high-pressure and high-temperature experiments using a piston-cylinder apparatus at 1200–1300 °C and 1 GPa for durations of 1 min, 5 h, and 23 h, are reported here. Kimberlitic liquid in the system CaO-MgO-Al2O3-SiO2-CO2-H2O and synthetic forsterite single crystals were chosen as a first simplification of the complex natural kimberlite composition. Unpolarized Fourier transform infrared spectroscopy was used to quantify the concentrations of OH in the crystallographically oriented forsterite. Scanning electron microscopy, electron backscattered diffraction, electron microprobe analyses, and transmission electron microscopy were performed to identify the run products. After 5 and 23 h, a forsterite overgrowth crystallized with the same orientation as the initial forsterite single crystal. The kimberlitic liquid has crystallized as micrometer-scale euhedral forsterite neocrystals with random crystallographic orientations, as well as a nanoscale aluminous phase and a calcic phase. Despite theoretical water-saturation of the system and long duration, none of the initial forsterite single crystals display signs of hydration such as hydrogen diffusion profile from the border toward the center of the crystal. Most likely, the presence of CO2 in the system has lowered the H2O fugacity to such an extent that there is no significant hydration of the starting forsterite single crystal or its overgrowth. Also, the presence of CO2 enhances rapid forsterite crystal growth. Forsterite growth rate is around 2 × 108 μm3/h at 1250 °C. These experimental results suggest a deep mantle origin of the high OH content found in natural mantle-derived xenoliths transported in kimberlites, as reported from the Kaapvaal craton. In agreement with previous studies, it also points out to the fact that significant hydration must take place in a CO2-poor environment.
ISSN: 0003-004X

hal-01217157
https://hal.archives-ouvertes.fr/hal-01217157
DOI : 10.2138/am-2015-5200

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Heletz sandstone (Israel) reactivity is studied by means of CO2-rich brine percolation experiments and modeling. Experiments are performed at in situ temperature and pressure conditions with two distinctly different injection flow rates and for two different brine compositions: the genuine Heletz brine and a similar brine but in equilibrium with gypsum. The Heletz sandstone is composed of quartz, dolomite, ankerite, K-feldspar, clay minerals and minor amounts of gypsum and pyrite. The main reaction is the dissolution of the carbonates which is fastest for the highest flow rate injection and for the genuine Heletz brine. Permeability increases during the five percolation experiments, regardless of flow rate and brine type. This increase in permeability is associated to a decrease in porosity during the gypsum-equilibrated brine experiments due to gypsum precipitation. The precipitation of secondary minerals (kaolinite, muscovite and smectite) is mainly controlled by the dissolution of K-feldspar and largest at low flow rate injection, indicating that these precipitation processes are diffusion-controlled and localized in immobile zones where favorable chemical micro-environments exist. These processes are quantified by means of a reactive transport model. These results indicated that the CO2 injection at the Heletz site should trigger both permeability increase in interface between brine and CO2, which may extend over a large extension and where mixing processes are very active, especially near the well under intermittent injection conditions.
ISSN: 1750-5836

hal-01356329
https://hal.archives-ouvertes.fr/hal-01356329
DOI : 10.1016/j.ijggc.2015.10.023

Éditeur(s) : HAL CCSD
Résumé : Croton urucurana Baillon (Euphorbiaceae), plant species popularly known in Brazil as “sangra-d’água”, is commonly found in Mato Grosso do Sul State (midwestern Brazil), where its latex is popularly used to treat several types of cancer. Despite the ethnopharmacological significance of the species, no phytochemical or cytotoxic studies of its latex have been published. In this context, the aim of the present study was to assess the cytotoxic activity of crude extracts, fractions and isolated compound from the latex of C. urucurana and to investigate the effects of crourorb A1 on the viability, apoptosis, cell cycle and cell migration of human hepatocarcinoma cell lines (Huh-7). Also, we have evaluated the viability of Huh-7 cells treated with crourorb A1 in 3D collagen gels. The cytotoxicity was detected using the sulforhodamine B (SRB) assay against six human cancer cells lines and one nontumor NIH/3T3 cell line (murine fibroblast). Studies on the mechanism of cell death of crourorb A1 were conducted in different test systems in vitro. The bioactive ethyl acetate phase obtained from the latex of C. urucurana afforded a novel cyclic peptide, [1−9-NαC]-crourorb A1, that proved active against NCIADR/ RES (ovary, multidrug-resistance phenotype) cells with the same potency as doxorubicin (positive control) and inactive up to the highest concentration tested against nontumor NIH/3T3 cells (GI50 = > 250 μg/mL). Crourorb A1 treatment decreases the cell viability of Huh-7 at dose and time dependent manner associated with induction of apoptosis by caspase 3/7 activation and increasing expression of pro-apoptotic proteins: Bak, Bid, Bax, Puma, Bim, and Bad and clived-caspase3 protein. The JNK/MAP pathway is involved in this induced cell death. Crourorb A1 effect is also associated with G2/M phase cell cycle arrest. In parallel, we observed that crourorb A1 treatment resulted in an increase of cyclin-dependent kinase (CDK1), cyclin B1 and cyclin D1 expressions. A significant reduction of Huh-7 cells migration by crourorb A1 can be assessed and we also show that cells grown on 3D collagen gels exhibited increased resistance to crourorb A1 when compared to 2D cell culture.
Croton urucurana Baillon (Euphorbiaceae), est une plante très connue et utilisée en médecine traditionnelle au Brésil, la «sangra-d’água» retrouvée dans l'État du Mato Grosso do Sul (région Centre-Ouest du Brésil). Son latex est abondamment utilisé en médecine traditionnelle dans le traitement de plusieurs types de cancer. En dépit de son importance ethnopharmacologique, on ne trouve aucune étude sur sa composition chimique ou sur sa potentielle activité anti-cancéreuse. L’objectif de ce travail a été d'évaluer l'activité cytotoxique des extraits totaux, fractions d’extraits et de molécules purifiées, isolées du latex de C. urucurana. Nous avons étudié plus particulièrement les effets du crourorb A1 sur la viabilité, l'apoptose, le cycle cellulaire et la migration de cellules issues de carcinome hépatocellulaire humaine (Huh-7). Nous avons également évalué l’effet du crourorb A1sur la viabilité des cellules Huh-7 cultivées dans les gels de collagène en 3D. L' activité cytotoxique ont été réalisées par le test à la sulforhodamine B sur six lignées cellulaire cancéreuses et sur une lignée cellulaire non cancéreuse de fibroblastes murins, les cellules NIH/3T3. L'étude phytochimique de la fraction ‘acétate d'éthyle’ du latex de C. urucurana bioguidé a permis d’obtenir un nouveau cyclopeptide que nous avons nommé [1-9-NαC]-crourorb A1. Le crourorb présente une cytotoxicité puissante sur la lignée cellulaire cancéreuse NCI-ADR/RES (ovaire, le phénotype de multirésistance) à un niveau équivalent à celle de la doxorubicine (témoin positif). Ce composé est de plus pratiquement inactif (GI50 = >250 μg/mL) sur la lignée non cancéreuse NIH/3T3. L'évaluation de la cytotoxicité in vitro du crourorb A1 (test wst1) sur les cellules Huh-7 a démontré que la viabilité des cellules est inhibée de manière dose et temps-dépendant. Nous avons mesuré une forte activation des caspases 3 et 7 et une nette augmentation de l’expression des protéines pro-apoptotiques (Bak, Bid, Bax, Puma, Bim et Bad) ainsi que de la caspase 3 clivée par le crourorb A1. Nous avons également déterminé que la voie de signalisation JNK-MAPkinase semble nécessaire à l’induction de la mort cellulaire des cellules Huh-7 traitées au crourorb A1. Le crourob A1 induit un arrêt du cycle cellulaire en phase G2/M. En parallèle, les expressions de la cycline-dépendante kinase CDK1, des cyclines B1 et D1 sont augmentées après traitement au crourorb A1. De plus, le crourorb A1 a un effet inhibiteur significatif de la migration des cellules Huh-7, en présence ou absence de mitomycine C. Nous avons également confirmé, l’effet inhibiteur du crourob A1 sur la viabilité des cellules Huh7 cultivées en 3D dans les gels de collagène 1 et démontré que les cellules cultivées en 3D semblent plus résistantes au crourorb A1 par rapport aux cultures en monocouche 2D.
Croton urucurana Baillon (Euphorbiaceae) é uma espécie arbórea conhecida popularmente no Brasil como “sangra d´água”, comumente encontrada no estado de Mato Grosso do Sul, onde seu látex tem sido utilizado na medicina popular no tratamento de vários tipos de câncer. Apesar de sua importância etnofarmacológica, não há relatos de estudos relacionados à sua composição química ou atividades anticâncer na literatura. Nesse contexto, o objetivo do presente estudo foi avaliar a atividade citotóxica de extratos, fases, frações e da substância isolada do látex de C. ururucurana e investigar os mecanismos celulares e moleculares in vitro responsáveis pela citotoxicidade da substância isolada considerando seu potencial apoptótico e influência sobre a progressão do ciclo celular em uma linhagem de hepatocarcinoma celular humano (Huh-7), bem como, os efeitos desta substância sobre a migração e viabilidade de células Huh-7 cultivadas em geis de colágeno em 3D. O ensaio de citotoxicidade in vitro foi realizado com o corante sulforrodamina B (SRB) em seis linhagens de células neoplásicas humanas e uma linhagem de células não neoplásicas NIH/3T3 (fibloblasto murinho). Os estudos de mecanismos de ação com crourorb A1 foram conduzidos em diferentes sistemas-teste in vitro. O estudo fitoquímico biomonitorado da fase bioativa acetato de etila do látex de C. urucurana resultou no isolamento de um novo ciclopeptídeo denominado [19-NαC]-crourorb A1, que apresentou potente atividade citotóxica frente à linhagem de células neoplásicas NCI-ADR/RES (ovário com fenótipo de resistência a múltiplos fármacos), com a mesma potência que a doxorrubicina (controle positivo), e foi inativa até a maior concentração testada (GI50 = >250 μg/mL) frente à linhagem de células não neoplásicas 3T3. A exposição de células Huh-7 ao crourorb A1 resultou em uma diminuição da viabilidade celular de maneira dose e tempo-dependentes. Nós observamos um aumento da atividade de caspases 3 e 7 e um aumento da expressão de proteínas próapoptóticas (Bak, Bid, Bax, Puma, Bim e Bad) e caspase 3 clivada após tratamento com crourorb A1. Além disso, observamos que a via de sinalização celular MAP/JNK foi necessária para induzir a morte celular em células Huh-7 tratadas com crourorb A1. Os efeitos de crourorb A1 foram também associados com o acúmulo de células na fase G2/M do ciclo celular. Em paralelo, as expressões da cinase dependente da ciclina (CDK1), ciclina B1 e ciclina D1 foram aumentadas após tratamento com crourorb A1. Foi demonstrado também o envolvimento de crourorb A1 na redução da migração de células Huh-7 cultivadas na presença e ausência de mitomicina C. A avaliação da viabilidade de células Huh-7 cultivadas em geis de colágeno em 3D apontou uma maior resistência destas células ao crourorb A1 quando comparadas com a cultura de células em 2D.
https://tel.archives-ouvertes.fr/tel-01478286

NNT : 2016REN1B010
tel-01478286
https://tel.archives-ouvertes.fr/tel-01478286
https://tel.archives-ouvertes.fr/tel-01478286/document
https://tel.archives-ouvertes.fr/tel-01478286/file/DE-MATOS-CANDIDO-BACANI-Priscila.pdf

Éditeur(s) : HAL CCSD De Gruyter
Résumé : COST Action E35 : Fracture mechanics and micromechanics of wood and wood composites with regard to wood machining
The data available in the literature concerning wood cutting forces permits to build models or to simulate the main wood machining processes ( milling, sawing, peeling, etc.). This approach contributes to a better understanding of formation of wood surfaces and chips and the data may be helpful to optimise cutting geometry, reduce tool wear, improve tool material, and to size tool-machines. The models may also be useful for industrial application in two ways: ( 1) providing data to optimise the settings for a given operation ( batch approach), and ( 2) building predictive models that could be the basis of an online control system for the machining processes ( interactive approach). A prerequisite for this is that numerous machining tests on different wood materials are performed based on experiences with different kind of tools and experimental devices. With a focus on potential industrial applications, the emphasis of this review was on the wood peeling process, which is a very demanding special case of wood cutting. Although not so many industrial machines are equipped with expensive force sensors, there is a lot of high quality information available about cutting forces which may be useful to improve the scientific or technological knowledge in wood machining. Alternative parameters, such as vibration or sound measurements, appear to be promising substitutes in the praxis, particularly to feed online control systems of any wood cutting process.
ISSN: 0018-3830

hal-01032121
https://hal.archives-ouvertes.fr/hal-01032121
DOI : 10.1515/HF.2009.014

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
Coupling between erosion and tectonics is thought to play a determinant role in orogenic evolution. Here, we investigate the interplay in this coupling between the assumed erosion law and the crustal rheology at the margin of a collisional plateau, like the Himalaya of Central Nepal. Lithospheric deformation is calculated over a time scale of 100 kyr by a 2D finite element model that incorporates the rheological layering of the crust and the main features of the convergence across the range. For the upper boundary condition, two surface processes were tested: a linear diffusion model and a 1D1/2 integrative model including fluvial incision along the fluvial network and hillslope erosion by landsliding. Model results and their sensitivity to the chosen combinations of erosion law and crustal properties are discussed in light of the constraining geologic and geomorphologic observations. In contrast with the conclusions of Cattin and Avouac [2000] , where a compliant quartz-rich crustal rheology and diffusion law were required, we combine a composite quartz-diabase rheology for the crust with fluvial incision erosion law to account for erosion and elevation profiles across the Himalaya of Central Nepal. More generally, it is proposed that, because of the interplay between the dominant denudation conditions and the rheology of the crust, both well documented erosion rates and processes can provide significant constraints on crustal properties within an active orogen.
ISSN: 0094-8276

hal-00788697
https://hal.archives-ouvertes.fr/hal-00788697
https://hal.archives-ouvertes.fr/hal-00788697/document
https://hal.archives-ouvertes.fr/hal-00788697/file/godard_et_al.pdf
DOI : 10.1029/2004GL021006

Éditeur(s) : HAL CCSD
Résumé : International audience
The Madeira deposit (Sn, Nb, Ta) at Pitinga, Amazonia, in Brazil, is associated with the albite-enriched facies of the A-type Madeira granite (~1,820 Ma). Fluorine (cryolite), Y, REE, Li, Zr, and Th are potential by-products of the disseminated ore. We studied the xenotime from the core albite-enriched (CAG), transitional albite-enriched granite (TAG) and pegmatitic albite-enriched granite (PAG). In all these rocks, xenotime is magmatic, has high HREE contents (0.37 to 0.54 atoms per formula unit; LREE are not detected), and low U, Th and Ca content. The CAG xenotime is the richest in REE, followed by that in the PAG and TAG units. Fluorine was detected in all xenotime crystals from CAG (up to 5.10%) and from PAG (up to 1.40%) and in most crystals from TAG (up to 0.68%). Where the xenotime is richer in F, the Na and Si increase, the P, Ca, and the effectiveness of a thorite-type substitution decrease. Fluorine controls the ratio REE/Y; the richer the xenotime in F, the richer it is in REE, in particular Er and Yb. The cell parameters a and c are significantly shortened in F-rich xenotime. There is no evidence of OH in the structure. We contend that fluorine substitutes for O to form PO3F tetrahedra, as in bobdownsite. The formation of the PO3F tetrahedra in the xenotime accounts well for the compatibility between the crystallographic characteristics and the chemical composition.
The Canadian Mineralogist

insu-00805907
https://hal-insu.archives-ouvertes.fr/insu-00805907
DOI : 10.3749/canmin.50.6.1453

Éditeur(s) : Texas A & M University, Ocean Drilling Program, College Station, TX, United States (USA)
Résumé : This chapter presents major oxide and trace element determinations of igneous whole-rock compositions from sites drilled during Leg 60 and electron microprobe mineral and glass analyses of samples from Sites 454 and 458. Interarc basin basalts from the Mariana Trough (Sites 454 and 456) are similar in all respects to depleted mid-ocean ridge basalts. Basaltic andesites and andesites from Site 458 (Mariana fore-arc region) are more depleted than mid-ocean ridge basalts and show different geochemical behavior for Zr-, Hf, and Ti when compared on an extended Coryell- Masuda plot. [NOT CONTROLLED OCR]
Initial Reports of the Deep Sea Drilling Project (Texas A & M University, Ocean Drilling Program, College Station, TX, United States (USA)), 1981 , Vol. 60 , P. 657-677

Droits : Texas A & M University, Ocean Drilling Program, College Station, TX, United States (USA)
http://archimer.ifremer.fr/doc/1981/publication-5308.pdf
http://archimer.ifremer.fr/doc/00000/5308/

Éditeur(s) : Elsevier Science Bv
Résumé : Climatic and anthropogenic changes are able to engender modifications in the aerosol composition at different geographical and temporal scales The present study addresses this question for the trace metal concentrations (TM = Al, Fe, Mn, Co, Ni, Cu, Pb, Cd and Zn) of aerosol from the North-western Mediterranean coast of France (Cap Ferrat, nearby Nice) between 1986 and 2008. From seasonal variations (2006-08) and decadal trends (1986-2008) of TM concentrations. three groups of elements can be distinguished They consist of different aerosol sources: crustal-derived elements (Al, Fe. Mn and Co), trace metals of anthropogenic origin (Pb, Cd and Zn) and a third, intermediate, group of trace metals that presented both anthropogenic and natural/crustal influences (Ni and Cu). Reproducible seasonal patterns were observed for crustal and intermediate elements with highest concentrations between May and November. while anthropogenic trace metals did not show a pronounced seasonal cycle Nevertheless, highest concentrations of anthropogenic trace metals occurred mostly in autumn/winter. Aerosol concentrations of anthropogenic TMs decreased remarkably over the last two decades, while crustal trace metals did not show any evolution Nickel and copper aerosol concentrations remained constant, as well. Lead concentrations decreased from 1986 (29.34 ng m(-3)) to 2008 (3.33 ng m(-3)). overall by 90%. Cadmium and zinc aerosol concentrations decreased by 66 and 54%, respectively, between 1998 and 2006-08. from 0.27 to 0.09 ng m(-3) and from 23.9 to 10.9 ng m(-3). respectively. These findings demonstrate the response of the atmospheric environment to the implementation of antipollution policies Possible changes of trace metal emissions sources and local influences are discussed (C) 2010 Elsevier B V. All rights reserved.
Science Of The Total Environment (0048-9697) (Elsevier Science Bv), 2010-06 , Vol. 408 , N. 13 , P. 2629-2638

Droits : 2010 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/00006/11688/8503.pdf
DOI:10.1016/j.scitotenv.2010.02.042
http://archimer.ifremer.fr/doc/00006/11688/

Éditeur(s) : HAL CCSD
Résumé : International audience
The core of South East Asia is composed of a mosaic of continental blocks, among which the Indochina and theSouth China blocks (present day northern Vietnam), amalgamated during the Permian and/or the Triassic. LatePermian to Late Triassic geodynamic evolution of these two blocks remains controversial. The main discussionpoints concern the existence and the closure of an oceanic domain separating the Indochina and the South Chinablocks during this period. Especially, the polarity and the timing of the subduction zone that led to the collisionbetween the blocks as well as the present location of the suture delimiting them are a matter of debate. Despite thevaluable information they can provide, the sedimentary basins from northern Vietnam have been neglected in theprevious studies dealing with the geodynamic evolution of South East Asia.To determine the geodynamic evolution of the area, the basins of Sam Nua and Song Da, presently locatedin North Vietnam, have been investigated using a combined approach involving sedimentology, geochronology(U-Pb/zircon) and geochemistry (whole-rock major and trace elements composition of both volcanic and volcaniclasticrocks). The palaeoenvironment evolution, the main unconformities, their age and the tectonic affinitiesof the interbedded volcanic and volcaniclastics series have been characterized for these two basins. Our resultsdemonstrate (i) that the Song Da Basin exhibits a palaeogeographic affinity with the South China block, (ii) theoccurrence of extensive calk-alkaline volcanism and associated volcaniclastic deposits in the Sam Nua Basin,related to the existence of an active magmatic arc during the Early and the lower Middle Triassic, (iii) a Southdipping (present day coordinate) oceanic lithosphere beneath the Indochina block, deduced from the location ofthe magmatic arc south of the potential suture zones, (iv) that an angular unconformity postdates the lower MiddleTriassic volcaniclastic deposits in the Sam Nua basin. This unconformity, crosscutting the subduction relateddeposits, is interpreted as the result of the collision between the Indochina and the South China blocks.
European Geoscience Union General Assembly 2015
Vienne, Austria

insu-01137675
https://hal-insu.archives-ouvertes.fr/insu-01137675

Éditeur(s) : HAL CCSD International Medical Press
Résumé : International audience
Background: Although the role of clinical/biological factors associated with mortality has already been explored in HIV-infected patients on antiretroviral therapy (ART), to date little attention has been given to the potential role of social vulnerability. This study aimed to construct an appropriate measure of social vulnerability and to evaluate whether this measure is predictive of increased mortality risk in ART-treated patients followed up in the ANRS CO8 APROCO-COPILOTE cohort.Methods: The cohort enrolled 1,281 patients initiating a protease inhibitor-based regimen in 1997–1999. Clinical/laboratory data were collected every 4 months. Self-administered questionnaires collected psycho-social/behavioural characteristics at enrolment (month [M] 0), M4 and every 8–12 months thereafter. A multiple correspondence analysis using education, employment and housing indicators helped construct a composite indicator measuring social vulnerability. The outcome studied was all-cause deaths occurring after M4. The relationship between social vulnerability and mortality, after adjustment for other predictors, was studied using a shared-frailty Cox model, taking into account informative study dropout.Results: Over a median (IQR) follow-up of 7.9 (3.0–11.2) years, 121 deaths occurred among 1,057 eligible patients, corresponding to a mortality rate (95% CI) of 1.64 (1.37, 1.96)/100 person-years. Leading causes of death were non-AIDS defining cancers (n=26), AIDS (n=23) and cardiovascular diseases (n=12). Social vulnerability (HR [95% CI] =1.2 [1.0, 1.5]) was associated with increased mortality risk, after adjustment for other known behavioural and bio-medical predictors.Conclusions: Social vulnerability remains a major mortality predictor in ART-treated patients. A real need exists for innovative interventions targeting individuals cumulating several sources of social vulnerability, to ensure that social inequalities do not continue to lead to higher mortality.
ISSN: 1359-6535

hal-01299300
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01299300
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01299300/document
https://hal-univ-rennes1.archives-ouvertes.fr/hal-01299300/file/Twelve-year%20mortality%20in%20HIV-infected%20patients_accepted.pdf
DOI : 10.3851/IMP2960

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The minerals constituting the Earth's upper mantle are nominally anhydrous silicates (NAMs). However they do contain hydrogen as a trace element, decorating point defects in their crystalline structure. Experimental petrology and mineralogy have quantified the maximum concentration under several compositional and thermodynamic conditions, but systematic studies on the hydrogen concentration in minerals from mantle-derived rocks have only recently been carried out. Here, we have compiled the distribution of hydrogen in upper mantle peridotite xenoliths, from which several conclusions can be drawn. NAMs from peridotite xenoliths contain a few ppm wt. H2O in their structure. From the current database, the hydrogen concentrations in olivine regularly increase with increasing depth. The amount of hydrogen in NAMs from peridotite xenoliths from subduction contexts is not higher than in other geological context for similar temperature and pressure conditions. The highest hydrogen concentrations is found in peridotitic olivines from cratonic mantle, and are likely due to the depth of origin. The increasing hydrogen concentration in olivine with increasing depth is likely controlled by the increase of H partitioning into olivine at the expense of orthopyroxene as imposed by a decrease in Al content in opx with depth. However, the sparse data could also indicate that the bulk hydrogen concentration slightly increases with depth > 150 km. In this case, it would suggest, locally (Udachnaya for example), a possible increase in water fugacity due to fluid saturation. Even if the most abundant mineral in mantle rocks is olivine, the bulk hydrogen concentration in peridotites is controlled by the amount of hydrogen stored in pyroxenes. However, hydrogen concentration in olivine remains crucial for consequences on physical properties such as rheology and electrical conductivity. Kinetics of hydrogen transport is reviewed and hydrous melt/fluid percolation appears necessary to homogenize the hydrogen distribution at km-scale. Sampling of natural rock specimens is currently biased (e.g., in favor of optically attractive samples) and needs improvement, which will be achieved by increasing sample diversity (all type of grain sizes, lithologies, geological settings) and size of rock samples, as well as advances in analytical techniques. Acquisition of high quality data will be achieved by studying the co-existing minerals in mantle specimens, exploring each sample by linear and mapping measurements, and using appropriate FTIR calibrations for polarized and unpolarized radiation.
ISSN: 0024-4937

hal-01306676
https://hal.archives-ouvertes.fr/hal-01306676
DOI : 10.1016/j.lithos.2015.11.012

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
North Tanzanian Divergence is the first stage of continental break-up of East African Rift (<6 Ma) and is one of the most concentrated areas of carbonatite magmatism on Earth, with singular Oldoinyo Lengai and Kerimasi volcanoes. Hanang volcano is the southernmost volcano in the North Tanzanian Divergence and the earliest stage of rift initiation. Hanang volcano erupted silica-undersaturated alkaline lavas with zoned clinopyroxene, nepheline, andradite-schorlomite, titanite, apatite, and pyrrhotite. Lavas are low MgO-nephelinite with low Mg# and high silica content (Mg# = 22.4–35.2, SiO2 = 44.2–46.7 wt%, respectively), high incompatible element concentrations (e.g. REE, Ba, Sr) and display Nb–Ta fractionation (Nb/Ta = 36–61). Major elements of whole rock are consistent with magmatic differentiation by fractional crystallization from a parental melt with melilititic composition. Although fractional crystallization occurred at 9–12 km and can be considered as an important process leading to nephelinite magma, the complex zonation of cpx (e.g. abrupt change of Mg#, Nb/Ta, and H2O) and trace element patterns of nephelinites recorded magmatic differentiation involving open system with carbonate–silicate immiscibility and primary melilititic melt replenishment. The low water content of clinopyroxene (3–25 ppm wt. H2O) indicates that at least 0.3 wt% H2O was present at depth during carbonate-rich nephelinite crystallization at 340–640 MPa and 1050–1100 °C. Mg-poor nephelinites from Hanang represent an early stage of the evolution path towards carbonatitic magmatism as observed in Oldoinyo Lengai. Paragenesis and geochemistry of Hanang nephelinites require the presence of CO2-rich melilititic liquid in the southern part of North Tanzanian Divergence and carbonate-rich melt percolations after deep partial melting of CO2-rich oxidized mantle source.
ISSN: 0010-7999

hal-01467390
https://hal.archives-ouvertes.fr/hal-01467390
DOI : 10.1007/s00410-016-1273-5

Éditeur(s) : Elsevier
Résumé : Until recently, it was considered impossible to feed newly hatched marine fish species with a compound diet. Substituting a compound diet for live prey was performed several weeks after hatching, depending on the species. Compound diets were well ingested at the early stage but larvae died with a gut full of food, suggesting that larvae were unable to digest the compound diet. The hypothesis was that younger larvae have insufficient digestive enzymes to thrive on compound diets, and that exogenous enzymes, provided from live prey, are necessary for early stages.The organogenesis of marine fish larvae is not completely achieved at hatching and histological studies have revealed that the anatomy of the digestive tract undergoes developmental changes over some weeks. Nevertheless, biochemical studies over 20 years have shown that most of the digestive enzymes are present in young larvae. Recent studies have provided better understanding of digestion mechanisms in larvae and have led to proposed dietary compositions meeting larvae nutritional requirements. Pancreatic digestive enzymes are detected before mouth opening. Their synthesis is not induced by diet ingestion, but secretory mechanisms in the pancreas, and so enzymatic action, become efficient chronologically after those of synthesis. Inadequate diets can delay the onset of secretion mechanisms. The ratio of secreted enzymes to total enzymes indicates the nutritional value of the diet ingested by the larvae.At the intestinal level, cytosolic enzymes, which are peptidases, exhibit high activity in the early stages, suggesting a high capacity in larvae to digest protein hydrolysate. Indeed, larvae growth and survival is improved by the incorporation of a moderate concentration of peptide or hydrolysate in the diet. Peptidase activity abruptly decreases around day 25 in sea bass, concurrent with an increase in enzymes of the brush border membranes. This corresponds to a normal maturation process of enterocytes. Compound diets can slightly delay the onset of this maturation process, and inadequate diet can prevent it, leading to near death of the larvae. A proper onset of the maturation process has been associated with high larvae survival.The early developmental stage larvae exhibit high hydrolytic capacity, related to their weight. Enzyme activity pattern is age-dependent, but can be modulated by diet composition. Thus, larvae have the ability to digest and thrive on compound diet, if this diet is well adapted. Larvae have different specificities in digestion and nutritional requirements when compared to juveniles. Taking these specificities into consideration, recent research has led to the formulation of a compound diet that was well adapted for larvae from mouth opening, and could totally replace live prey.
Aquaculture (0044-8486) (Elsevier), 2001-08 , Vol. 200 , N. 1-2 , P. 161-180

Droits : 2001 Elsevier Science B.V. All rights reserved
http://archimer.ifremer.fr/doc/2001/publication-447.pdf
DOI:10.1016/S0044-8486(01)00699-8
http://archimer.ifremer.fr/doc/00000/447/

Éditeur(s) : HAL CCSD Taylor & Francis
Résumé : International audience
ternational Ocean Discovery Program (IODP) Expedition 352 recovered a high-fidelity record of volcanism related to subduction initiation in the Bonin fore-arc. Two sites (U1440 and U1441) located in deep water nearer to the trench recovered basalts and related rocks; two sites (U1439 and U1442) located in shallower water further from the trench recovered boninites and related rocks. Drilling in both areas ended in dolerites inferred to be sheeted intrusive rocks. The basalts apparently erupted immediately after subduction initiation and have compositions similar to those of the most depleted basalts generated by rapid sea-floor spreading at mid-ocean ridges, with little or no slab input. Subsequent melting to generate boninites involved more depleted mantle and hotter and deeper subducted components as subduction progressed and volcanism migrated away from the trench. This volcanic sequence is akin to that recorded by many ophiolites, supporting a direct link between subduction initiation, fore-arc spreading, and ophiolite genesis.
ISSN: 0020-6814

hal-01685628
https://hal.archives-ouvertes.fr/hal-01685628
DOI : 10.1080/00206814.2016.1276482

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The oxygen fugacity and therefore the iron redox state of a melt is known to have a strong influence on the liquid line of descent of magmas and thus on the composition of the coexisting melts and crystals. We present a new method to estimate this critical parameter from electron probe microanalyses of two of the most common minerals of basaltic series, plagioclase and clinopyroxene. This method is not based on stoichiometric calculations, but on the different partitioning behaviour of Fe3+ and Fe2+ between both minerals and a melt phase: plagioclase can incorporate more Fe3+ than Fe2+, while clinopyroxene can incorporate more Fe2+ than Fe3+. For example, the effect of oxidizing a partly molten basaltic system (Fe3+ is stabilized with respect to Fe2+) results in an increase of FeOtotal in plagioclase, but a decrease in the associated clinopyroxene. We propose an equation, based on published partition coefficients, that allows estimating the redox state of a melt from these considerations. An application to a set of experimental and natural data attests the validity of the proposed model. The associated error can be calculated and is on average <1 log unit of the prevailing oxygen fugacity.;In order to reduce the number of different variables influencing the Fe2+/Fe3+ mineral/melt equilibrium, our model is restricted to basaltic series with SiO2<60% that have crystallized at intermediate to low pressure (<0.5 GPa) and under relatively oxidizing conditions (Delta FMQ>0; where FMQ is the fayalite-magnetite-quartz oxygen buffer equilibrium), but it may be parameterized for other conditions. A spreadsheet is provided to assist the use of equations, and to perform the error propagation analysis.
ISSN: 0377-0273

hal-00475550
https://hal.archives-ouvertes.fr/hal-00475550
DOI : 10.1016/j.jvolgeores.2009.11.023