Éditeur(s) : Elsevier Science Bv
Résumé : The biodynamic and saturation models offer promising lines of enquiry to predict the bioaccumulation of metals by aquatic organisms. However, in order to construct these models, the accumulation strategies have to be defined for each metal/organism couple in controlled conditions. This study aims at modelling the waterborne bioaccumulation of Ni and the influence of the water's geochemical properties on this process in a crustacean that is widely distributed in Europe, Gammarus pulex. In the laboratory, G. pulex was exposed to several Ni concentrations (from 0.001 to 100 mg L(-1)) in aquatic microcosms. Our results show that G. pulex is very tolerant to Ni (LC50(48 h) = 477 mg L(-1) Ni). Time course experiments enabled the construction of a biodynamic model by determining the uptake (k(u)) and elimination (k(e)) rate constants. When the exposure concentration exceeded 1 mg L(-1) Ni, the metal uptake reached a maximum due to a limited number of binding sites for Ni. Therefore, the organism's maximal capacity to accumulate the metal (B(max)) and the half-saturation constant (K) were determined to establish the saturation model. We showed that the two models are comparable for the lowest exposure concentrations (<1 mg L(-1) Ni), with k(u)/k(e) = B(max)/K. Then, the bioaccumulation of Ni was recorded in waters exhibiting various concentrations of three major ions (Na(+), Mg(2+) and Ca(2+)). Only Ca had an inhibitory effect on the Ni uptake. This study reports for the first time the bioaccumulation of Ni in G. pulex. Because of its high tolerance to Ni and its high capacity to accumulate this metal, this crustacean could be used as an indicator of Ni bioavailability in freshwaters. (C) 2011 Elsevier B.V. All rights reserved.
Aquatic Toxicology (0166-445X) (Elsevier Science Bv), 2011-08 , Vol. 104 , N. 3-4 , P. 161-167

Droits : 2011 Elsevier B.V. All rights reserved.
http://archimer.ifremer.fr/doc/00041/15217/18005.pdf
DOI:10.1016/j.aquatox.2011.04.011
http://archimer.ifremer.fr/doc/00041/15217/

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : A differential effective medium (DEM) model is used to predict elastic properties for a set of porous and anisotropic aggregates, comprised of mixtures of calcite and muscovite. The DEM takes into consideration an anisotropic background medium with triclinic or higher symmetry, in which inclusions of idealized ellipsoidal shape are added incrementally. In general, the calculated elastic properties of a solid that contains inclusions representing "dry" pores/cracks are strongly dependent on the orientation and aspect ratio of the inclusions. Aspect ratios of inclusions in the synthetic aggregates, which consist of air-filled pores, are estimated from anisotropy of magnetic susceptibility (AMS) of samples whose pore space has been impregnated with a colloidal ferrofluid. The AMS derived pore shape geometry is used as an input value for inclusions in the DEM. Modeling results are compared with laboratory determined elastic properties, measured with ultrasonic waves. Calculated shear wave velocities agree in general well with laboratory measured S wave velocities, whereas calculated P wave velocities are typically 0.5-1.1 km/s higher than measured values. Differences between calculated and measured P wave velocities are attributed mainly to incomplete and biased ferrofluid saturation of pores. Spherical pores are preferably filled during imbibition, in comparison to thin cracks, which leads to overprediction of the calculated P wave velocities. The amount of ferrofluid that fills the pore space is dependent on the ratio of calcite to muscovite and the load used for compaction during sample synthesis. The permeability decreases with increasing muscovite content and increasing compaction load. Incomplete saturation of samples with high-muscovite content is confirmed by X-ray microtomography density contrast imaging of dry and ferrofluid saturated specimens.
ISSN: 0148-0227

hal-00617717
https://hal.archives-ouvertes.fr/hal-00617717
DOI : 10.1029/2010JB007750

Éditeur(s) : Université des Antilles Études caribéennes
Résumé : La problématique du transport à la Martinique demeure comme dans bien des cas des pays de la région une question cruciale et déterminante face à des mobilités intérieures de plus en plus sujettes à saturation exacerbées par la configuration territoriale d'une part, mais également des modes d'usage du véhicule de plus en plus systématique au regard des carences dans l'offre de transport. Cette contribution à pour but de mettre en exergue les facteurs de la systémogénèse de l'organisation spatiale et, par la même, des dysfonctionnements constatés du système transport sur l'île, ainsi que, les conséquences en terme d'environnement.
The issue of transport in Martinique remains in many cases the countries of the region a decisive and crucial issue facing internal mobility increasingly prone to saturation exacerbated by the territorial configuration on the one hand, but also modes of use of the vehicle more and more systematic in the light of deficiencies in the provision of transport. This contribution aims to highlight the factors of the guiding principles of the space organization, by the same failures of the transport system on the island, and that the consequences in terms of environment.
Martinique

Droits : info:eu-repo/semantics/openAccess
urn:doi:10.4000/etudescaribeennes.1042
http://journals.openedition.org/etudescaribeennes/1042

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Energy dissipation is observed on seismic data when a wave propagates through a porous medium, involving different frequency regimes depending on the nature of rock and fluid types. We focus here on the role of partial fluid saturation in unconsolidated porous media, looking in particular at P-wave phase velocity and attenuation. The study consists in running an experiment in a sand-filled tank partially saturated with water. Seismic propagation in the tank is generated in the kHz range by hitting a steel ball on a granite plate. Seismic data are recorded by buried accelerometers and injecting or extracting water controls the partial saturation. Several imbibition/drainage cycles were performed between the water and gas residual saturations. A Continuous Wavelet Transform applied on seismic records allowed us to extract the direct P-wave at each receiver.We observe an hysteresis in phase velocities and inverse quality factors between imbibition and drainage. Phase velocities and inverse quality factors are then jointly inverted to get a final poro-visco-elastic model of the partially saturated sand that satisfactorily reproduces the data. The model formulation consists in generalizing the Biot theory to effective properties of the fluid and medium (permeability and bulk modulus) in order to properly explain the phase velocity variation as a function of the saturation. The strong level of attenuation measured experimentally is further explained by an anelastic effect due to grain to grain sliding, adding to Biot's losses. This study shows that fluid distribution at microscopic scale has strong influence on the attenuation of direct P-waves at macroscopic scale and confirms that seismic prospection may be a powerful tool for the characterization of transport phenomena in porous media.
ISSN: 0956-540X

hal-00779920
https://hal.archives-ouvertes.fr/hal-00779920
https://hal.archives-ouvertes.fr/hal-00779920/document
https://hal.archives-ouvertes.fr/hal-00779920/file/Barriere_et_al_HAL.pdf
DOI : 10.1111/j.1365-246X.2012.05691.x

Éditeur(s) : HAL CCSD
Résumé : Volatile-rich, silica-undersaturated alkaline lavas record the important role of fluids during fluid-rock and magma-rock interactions in the mantle, which are key processes to understand the dynamics of the convective mantle and lithosphere-asthenosphere interactions in intracontinental settings. The aim of this thesis is to bring new constraints on the genesis of alkaline magmas by characterizing the crystallization conditions, the source and the partial melting processes taking part in the genesis of olivine nephelinites, pyroxene nephelinites and basanites from the Jbel Saghro volcanic field in the Moroccan Anti Atlas.The petrological and geochemical study of rocks and minerals coupled with the analysis of fluid inclusions constrains the pre-eruptive conditions of Saghro nephelinites to 1.7–2.2 GPa and ~1350 °C. Minerals show that nephelinitic magmas are rich in volatile elements (Cl, F, S), and fluid inclusions indicate that magmas were saturated with a CO2-rich fluid at pressures > 590 MPa. The various mineralogical assemblages and the presence of peridotite xenoliths suggest a rapid ascent for olivine nephelinites and more complex processes at depth for pyroxene nephelinites.Fractional crystallization and partial melting modelling of Saghro mafic lavas indicate that they are low-degree melts (0.6–2.5 %) of an amphibole-bearing carbonated peridotite enriched in incompatible elements, at the garnet-spinel transition (~80–85 km). Saghro nephelinites display a temporal evolution with a slight increase of the degree of melting and a decrease of the amount of residual amphibole from the oldest (olivine nephelinites, 9.6 Ma) to the most recent (pyroxene nephelinites, 2.9 Ma). Basanites form a system that is independent from nephelinites and are slightly higher-degree melts. Important variations in their chemical composition suggest variable amounts of fractional crystallization during ascent.The peculiar characteristics of Saghro nephelinites and basanites (enrichment in incompatible elements, negative anomalies in K, Zr, Hf and Ti, high Ca/Al and Zr/Hf ratios) indicate that their source was affected by carbonatitic metasomatism. The influence of this metasomatism is stronger for pyroxene nephelinites than for olivine nephelinites. These results suggest fluid-rock interactions beneath the Northwest African Craton, leading to the formation of a metasomatized mantle by CO2-rich carbonatitic components at the lithosphere-asthenosphere transition. The origin of the metasomatism inducing source enrichment and the formation of amphibole veins could be attributed to the melting of relict subducted oceanic lithosphere. The relatively low melting temperatures (< 1350 °C) suggest the absence of a thermal anomaly beneath the Jbel Saghro, and thus support a lithosphere delamination model as precursor of Saghro volca0,3nism. However, the increasing degree of partial melting over time, also observed in the Middle Atlas, together with the isotopic and geochemical similarities with Canary Islands alkaline lavas does not allow us to discard the influence of a deviation of the Canary mantle plume beneath northwest Africa.
Les laves alcalines sous-saturées riches en éléments volatils sont les marqueurs du rôle important des fluides dans le manteau et des interactions fluide-roche et magma-roche, processus clés pour comprendre la dynamique du manteau convectif et les interactions asthénosphère-lithosphère en domaine intracontinental. L’objectif de cette thèse est d’apporter de nouvelles contraintes sur la genèse des magmas alcalins en caractérisant les conditions de cristallisation, la source et les processus de fusion partielle à l’origine des néphélinites à olivine, des néphélinites à pyroxène et des basanites du champ volcanique du Jbel Saghro dans l’Anti-Atlas marocain.L’étude pétrologique et géochimique des roches et des minéraux, couplée à l’analyse des inclusions fluides a permis de contraindre les conditions pré-éruptives des néphélinites de Saghro à 1.7–2.2 GPa et ~1350 °C. Les minéraux montrent que les magmas néphélinitiques sont riches en éléments volatils (Cl, F, S), et les inclusions fluides indiquent que les magmas étaient saturés en fluide riche en CO2 à des pressions > 590 MPa. Les différents assemblages minéralogiques des néphélinites et la présence de xénolites péridotitiques suggèrent une ascension rapide des néphélinites à olivine et des processus plus complexes en profondeur pour les néphélinites à pyroxène.La modélisation des processus de cristallisation fractionnée et de fusion partielle des laves mafiques de Saghro a permis de déterminer qu’elles sont issues de faibles taux de fusion partielle (0.6–2.5 %) d’une péridotite carbonatée enrichie en éléments incompatibles, au niveau de la transition grenat–spinelle (~80–85 km) et en présence d’amphibole. Les néphélinites de Saghro montrent une évolution temporelle avec une légère augmentation du taux de fusion et une diminution de la quantité d’amphibole au résidu des plus anciennes (néphélinites à olivine, 9.6 Ma) aux plus récentes (néphélinites à pyroxène, 2.9 Ma). Les basanites forment un système indépendant des néphélinites et sont issues de taux de fusion plus élevés. Les fortes variations dans leur composition chimique suggèrent qu’elles ont subi de la cristallisation fractionnée lors de leur ascension.Les caractéristiques particulières des néphélinites et basanites de Saghro (enrichissement en éléments incompatibles, anomalies négatives en K, Zr, Hf et Ti, rapports Ca/Al et Zr/Hf élevés) indiquent que leur source a subi un métasomatisme principalement carbonatitique. L’influence de ce métasomatisme est plus forte pour les néphélinites à pyroxène que pour les néphélinites à olivine, impliquant une évolution temporelle de l’intensité du métasomatisme. Ces résultats suggèrent des interactions fluide-roche sous le craton Nord-Ouest Africain, entraînant la formation d'un manteau métasomatisé par des composants carbonatitiques riches en CO2 au niveau de la transition lithosphère-asthénosphère. L’origine du métasomatisme provoquant l’enrichissement de la source et la formation de veines d’amphibole pourrait être liée à la fusion de reliquats de croûte océanique subductée. Les températures de fusion relativement faibles (< 1350 °C) suggèrent l’absence d’anomalie thermique sous le Jbel Saghro, et favorisent donc un modèle de délamination de la lithosphère comme initiateur du volcanisme. Cependant, l’augmentation du taux de fusion partielle au cours du temps, également observée dans le Moyen Atlas, et les similitudes isotopiques et géochimiques avec les laves alcalines des îles Canaries ne permettent pas d’exclure une influence du panache des Canaries sur la source du volcanisme alcalin du Jbel Saghro.
https://tel.archives-ouvertes.fr/tel-01615888

NNT : 2015MONTS070
tel-01615888
https://tel.archives-ouvertes.fr/tel-01615888
https://tel.archives-ouvertes.fr/tel-01615888/document
https://tel.archives-ouvertes.fr/tel-01615888/file/53752_CHAMBOREDON_2015_archivage_cor.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A set of four reactive flow-through experiments at temperature T = 100 degrees C and total pressure P=12 MPa was performed in limestone reservoir samples. By using various ranging from 0.7 to 10 MPa, these experiments mimic mass transfers occurring (1) near the injection well, where the brine is almost saturated with CO2 (i.e. P-CO2 approximate to P), and (2) at increasing distances from the injection well, where the fluid displays lower values and higher divalent cation concentrations due rock dissolution along the fluid pathway. Results for P-CO2 = 10 MPa show non-uniform dissolution features associated with transport-controlled mass transfer, while reaction-controlled uniform dissolution is observed for P-CO2 = 2.5 MPa. The experiment with P-CO2 = 6 MPa allows investigating in detail the transition from transport-to reaction-controlled dissolution. Conversely, the experiment reproducing conditions far from the injection well (P-CO2 = 0.7 MPa), shows a decrease of porosity triggered by the precipitation of Mg-rich calcite. For all the dissolution experiments, the time-resolved porosity phi(t) can be modeled by a simple non-linear equation including parameters that characterise the dissolution regime triggered by the reactivity of the inlet fluid (measured by the Damkohler number, Da). Furthermore, all dissolution experiments display power scaling between permeability (k) and porosity (phi) with distinctly different scaling exponents characterising the reactivity of the fluid percolating the sample, independently from the decrease with time of the reactive surface area. It is shown also that dissolution at moderate positive values of Da seems the most efficient to increase permeability and promote a rapid spreading of the reaction front, while inducing minimal modification of the porosity in the vicinity of the CO2 injection well. These results can be used to parameterize the k-phi function for modeling the earliest dissolution processes occurring in the vicinity of the reaction front.
ISSN: 0009-2541

hal-00445277
https://hal.archives-ouvertes.fr/hal-00445277
DOI : 10.1016/j.chemgeo.2009.03.028

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
Electrical resistivity soundings are used by geophysicists to determine the structure and composition of the Earth's crust and mantle and to explore natural resources (ore, oil, gas, water). Their interpretations in terms of composition and in-situ physical conditions depend mainly on laboratory measurements of electrical conductivity of rocks at simulated crustal conditions of temperature, pressure, saturation and pore pressures. These measurements present a numbers of limitations, in particular, in the case where conductive pore fluids are present, as in the case of deep reservoir conditions, where temperature exceeds 250 A degrees C. Here, we present a new cell capable of measuring electrical conductivity of large saturated samples at confining pressure up to 200 MPa, pore pressure up to 50 MPa, and temperature up to 500 A degrees C. The measurement cell has been developed in a commercial, internally heated, gas pressure apparatus (Paterson press). It is based on the concept of "guard ring" electrode, which is adapted to samples that are jacketed by a very conductive, metallic material. Numerical modeling of the current flow in the electrical cell allowed defining the optimal cell geometry. Calibration tests have been performed on Fontainebleau sandstones saturated with electrolytes of different conductivities, up to 350 A degrees C. The resulting electrical formation factor and temperature dependence of electrical conductivity are in very good agreement with previous studies. This new cell will improve the exploration and exploitation of deep fluid reservoirs, as in unconventional, high enthalpy geothermal fields. In particular, the investigations address possible effects of fluid-rock interactions on electrical resistivity of a reservoir host rock.
ISSN: 0169-3913

hal-00681997
https://hal.archives-ouvertes.fr/hal-00681997
DOI : 10.1007/s11242-011-9846-2

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Properties of composite materials depend on interatomic phenomena occurring between binder crystals. Experimental information of Atomic Force Microscopy (A.F.M.) is of prime importance; however understanding is helped by molecular modeling. As underlined in Section 1, the present study is able to simulate crystal interfaces in presence of a solution within apertures less than 1 Nanometer at a full atomic scale. Section 2 presents the case study of a gypsum solution between (120) gypsum faces, with related boundary conditions and atomic interactions. Section 3 deals with the mass equilibrium of the solution within interfaces <5 angstrom, using the original Semi Analytical Stochastic Perturbations (SASP) approach. This information becomes in Section 4 the key for explaining the peak of adhesion obtained in A.F.M. around an aperture of 3 A and gives enlightenments on gypsum cohesion. In conclusion, this illustration shows the potentialities of full atomic modeling which could not be attained by any numerical approach at a mesoscopic scale.
ISSN: 0008-8846

hal-00411868
https://hal.archives-ouvertes.fr/hal-00411868
DOI : 10.1016/j.cemconres.2007.09.022

Éditeur(s) : HAL CCSD
Résumé :   Diplôme : DEA
il s'agit d'un type de produit dont les métadonnées ne correspondent pas aux métadonnées attendues dans les autres types de produit : DISSERTATION
Links between architectural stages of development (ASD), photosynthetic capacities and leaf characteristics in Tachigali melinonii (Caesalpiniaceae) were investigated in the tropical forest of French Guiana. Three ASD were sampled under three light conditions to elucidate the impact of ASD- and light-related changes on photosynthetic functional traits. Photosynthetic parameters (maximum rate in RubisCO carboxylation (Vcmax) and maximum rate of electron transport (Jmax) were estimated by adjusting a biochemical model (Farquhar et al., 1980) to response curves of CO2 assimilation rate to intercellular CO2 concentration, under saturated light. In addition, N and C foliar concentrations were analysed and N allocations to the carboxylation and bioenergetic processus of photosynthesis were calculated using the model of Niinemets and Tenhunen (1997). The variations in ecophysiological parameters observed were due to leaf anatomical and structural changes instead of changes in photosynthetic components, suggesting adjustments to light conditions. Tachigali melinonii thus appears to display morphological and anatomical plasticity at different ASDs and under different light conditions.
Une espèce forestière de Guyane Française, Tachigali melinonii (Caesalipiniaceae), a été choisie afin de regarder la variation des traits fonctionnels relatifs à la photosynthèse en fonction de la disponibilité en lumière et en fonction de son stade de développement architectural. Du fait du tempérament de l'espèce vis-à-vis de la lumière de type «struggling gambler» (ombrage nécessaire aux jeunes stades puis développement en pleine lumière), trois stades clefs de développement parmi la séquence de différenciation de l'espèce ainsi que trois environnements lumineux ont été choisis. Les capacités photosynthétiques foliaires ont été estimées à partir de l'ajustement de paramètres du modèle biochimique de photosynthèse foliaire (Farquhar et al. 1980) sur des courbes de réponses de l'assimilation de CO² (A) à des concentrations intracellulaires en CO² (Ci) croissantes, en condition de lumière saturante. La vitesse maximale de carboxylation Vcmax et le flux maximal d'électrons photosynthétiques Jmax ont ainsi été estimés et ensuite reliés aux caractéristiques structurales foliaires, notamment la concentration en azote, en carbone ainsi qu'avec la densité et l’épaisseur. Les fractions d'azote allouées aux processus photosynthétiques de carboxylation et de bioénergétique ont été calculées. Des variations, dues à un effet du stade de développement sur les paramètres étudiés ainsi qu’à un effet de la quantité de lumière disponible, ont été constatées. Ces variations sont surtout liées à des ajustements anatomiques et structuraux foliaires et non à des modifications de l’appareil photosynthétique. Tachigali melinonii semble donc modifier ses caractéristiques structurales foliaires en fonction de son stade de développement, ce qui suppose un contrôle ontogénique partiel, et en fonction de la disponibilité en lumière.
https://hal.archives-ouvertes.fr/hal-01189520

hal-01189520
https://hal.archives-ouvertes.fr/hal-01189520
PRODINRA : 44951

Éditeur(s) : HAL CCSD
Résumé : Water vapour is highly variable in the atmosphere with concentration reaching saturation in the tropics and with dry areas over elevated continental region. Good knowledge of the amount of integrated water vapour in the air is necessary to predict phase changes and in particular precipitation. Water vapour variability measurements are still insufficient with standard observing systems. Moreover accurate GPS antenna positioning is affected by the refractivity index variation in the troposphere. Consequently, vertical positioning component estimation is difficult. This variation is directly linked to distribution of variables such as pressure, temperature and humidity along the path between satellite and receiver. Here we study more specifically heavy rains et notably Cevenols events. This thesis work consists to check the GPS measurement validity to quantify water vapour in comparison with measurements from radiosoundings and meteorological model outputs. GPS observations and flux surface information have been analysed to see if water vapour quantification by GPS allowed characterising heavy rain events (cumulative rainfall amount greater than 150 mm). Then, we tested the GPS data assimilation impact on cumulative precipitation forecasts using the high resolution Meteo France AROME model (2.5 km). Finally the quality and the contribution of GPS measurement on sea is evaluated for water vapour measurement. This study has been realised in the framework of VAPIMED experiment.
La vapeur d'eau varie largement dans l'atmosphère avec des concentrations allant de la saturation dans les tropiques à des zones presque sèches au-dessus des zones continentales élevées. Une bonne connaissance du contenu en vapeur d'eau dans l'air est nécessaire pour la prévision des changements de phases, notamment les précipitations. La mesure de la variabilité de la vapeur d'eau est une lacune des systèmes d'observation. Par ailleurs, il est apparu que le positionnement précis des antennes GPS était affecté par la variation de l'indice de réfraction dans la troposphère, ce qui rend particulièrement difficile l'estimation de la composante verticale. Cette variation est directement liée à la distribution des variables pression, température et humidité sur les trajets satellite-récepteur. On s'intéresse ici à l'étude des précipitations intenses et notamment aux épisodes Cévenols. Ce travail de thèse consiste à vérifier la validité de la mesure GPS pour la quantification de la vapeur d'eau en la comparant avec des mesures issues de radiosondage et des sorties de modèle météorologique. On cherche à analyser si la quantification de vapeur d'eau par GPS permet de caractériser les forts événements précipitants (cumuls supérieurs à 150 mm) à l'aide d'observations conjointes sur les flux de surface. On étudie ensuite l'impact de l'assimilation de données GPS issues d'un réseau GPS dense sur la prévision des cumuls de pluies dans le modèle à hauterésolution (2.5 km) AROME de Météo France. Finalement on évalue la qualité et l'apport de la mesure de vapeur d'eau par GPS en mer dans le cadre d'une campagne de mesure VAPIMED).
https://tel.archives-ouvertes.fr/tel-00444081

Droits : info:eu-repo/semantics/OpenAccess
tel-00444081
https://tel.archives-ouvertes.fr/tel-00444081
https://tel.archives-ouvertes.fr/tel-00444081/document
https://tel.archives-ouvertes.fr/tel-00444081/file/These_KBoniface.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
To evaluate the performance of downhole and surface geophysical monitoring methods, a series of shallow gas injection-monitoring experiments has been performed in a coastal saline aquifer at Maguelone, France. The recorded data include pressure measurements with a Westbay multilevel completion and CO2 saturation at an observation well derived from electrical resistivity with a modified Waxman-Smits (MWS) model. In this work, the aim is to develop a simulation model capturing the gas transport behavior and consistent with field data. For this purpose, the simulation of the CO2 injection experiment is carried out with two conceptual models, a homogeneous model and a heterogeneous model treated with multiple realization Monte Carlo simulations. Numerical simulator TOUGH2 with the equation of state module EOS7C is used for the simulations. Comparison of the model results with field data suggests that the pressure responses are captured with relatively good accuracy. Similarly, the model also provides an overall reasonable agreement and correct order of magnitude for predicted gas saturation values. However, as the heterogeneity pattern in the field data remains largely unknown, the model predictions can only be used to capture the mean behavior as well as to provide insights into how heterogeneity can influence the system behavior, by means of sensitivity analyses of the influence of heterogeneities on individual realizations.
ISSN: 1750-5836

hal-01467240
https://hal.archives-ouvertes.fr/hal-01467240
DOI : 10.1016/j.ijggc.2016.09.006

Éditeur(s) : HAL CCSD
Résumé : Karst systems are the most important groundwater reservoirs in Mediterranean area. Beyond saturated zone, unsaturated zone constitute an entity where water storage and transfer play a major role in a global behavior of spring water. This structure and functioning are complex and not well known because of the high heterogeneity created and organized by groundwater flow. In this study, we used gravimetric and hydrogeologic method to directly observe and quantify water storage and transfer processes in unsaturated zone of karst system. Surface to depth gravity measurements on several karst system allow quantifying seasonal water storage changes in unsaturated zone. We show that these variations occur in the first tens meters of unsaturated zone. Furthermore, water storage capacity of unsaturated zone seems to be influenced by lithology (limestone or dolomite). Finally, direct observations of water flow in unsaturated zone are done using caves access. We show that some characteristics of unsaturated water flow such as bipolar slow-fast flow can be widespread for whatever depth of measurement and recharge area. Model of this flow, using a simple modeling scheme, show the complexity of water transfer processes in unsaturated zone of karst system.
Les aquifères karstiques constituent l'essentiel des ressources en eau du pourtour Méditerranéen. Au-delà de la zone saturée de ces systèmes, la zone non saturée constitue une entité importante quant au transfert et au stockage temporaire de l'eau. La structure et le fonctionnement de cette entité du karst sont complexes et mal connus à cause du processus de karstification qui hiérarchise la circulation hydrodynamique en son sein. Dans cette étude nous utilisons des méthodes géodésiques et hydrogéologiques afin d'observer de façon directe et de quantifier les processus de transfert et de stockage de la zone non saturée. Les mesures gravimétriques en surface et profondeur sur différents systèmes karstiques ont permis de quantifier les variations du stockage en eau saisonnier dans la zone non saturée. La gravimétrie différentielle montre que ces variations sont réparties dans les quelques premiers mètres de la zone non saturée. Il semble, de plus, que la capacité de stockage de la zone non saturée soit fonction de la lithologie de l'encaissant (calcaire et dolomie). Enfin, des observations directes du flux d'eau en zone non saturée ont été effectuées par le biais de mesures dans différentes cavités. Nous montrons que certaines caractéristiques du flux d'eau en zone non saturée, comme la présence d'un flux bipolaire lent-rapide, peuvent être généralisées quelque soit la profondeur de mesure et la surface d'impluvium. La modélisation de ce flux, à partir d'un schéma simple, a montré la complexité des processus de transfert engendrés au sein de la zone non saturée.
https://tel.archives-ouvertes.fr/tel-00829346

tel-00829346
https://tel.archives-ouvertes.fr/tel-00829346
https://tel.archives-ouvertes.fr/tel-00829346/document
https://tel.archives-ouvertes.fr/tel-00829346/file/manuscrit_deville_finish.pdf

Éditeur(s) : HAL CCSD Wiley-Blackwell Wiley
Résumé : International audience
Rhodamine 123 is a fluorescent cationic dye commonly used as a mitochondrial probe and known or suspected to be transported by certain drug membrane transporters. The present study was designed to characterize the putative interactions of rhodamine 123 with human organic cation transporter (OCT) 1 and OCT2. Intracellular uptake of the dye was demonstrated to be enhanced in both hOCT1- and hOCT2-overexpressing HEK293 cells when compared with control HEK293 cells. This increase of rhodamine 123 influxes was found to be a saturable carrier-mediated process, with low K(m) values (K(m) = 0.54 μm and K(m ) = 0.61 μm for transport of the dye in hOCT1- and hOCT2-positive HEK293 cells, respectively). Known inhibitors of hOCT1 and hOCT2 activities such as verapamil, amitriptyline, prazosin, and quinine were next demonstrated to decrease rhodamine 123 accumulation in hOCT1- and hOCT2-overexpressing HEK293 cells. In addition, the dye was found to inhibit hOCT1- and hOCT2-mediated uptake of tetraethylammonium (TEA), a model substrate for both hOCT1 and hOCT2; rhodamine 123 appeared nevertheless to be a more potent inhibitor of hOCT1-mediated TEA transport (IC(50) = 0.37 μm) than of that mediated by hOCT2 (IC(50 ) = 61.5 μm). Taken together, these data demonstrate that rhodamine 123 is a high-affinity substrate for both hOCT1 and hOCT2. This dye may be therefore useful for fluorimetrically investigating cellular hOCT1 or hOCT2 activity, knowing, however, that other factors potentially contributing to cellular accumulation of rhodamine 123, including mitochondrial membrane potential or expression of the efflux transporter P-glycoprotein, have also to be considered.
ISSN: 0767-3981

inserm-00872840
http://www.hal.inserm.fr/inserm-00872840
DOI : 10.1111/j.1472-8206.2012.01071.x
PUBMED : 22913740

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Mapping forest aboveground biomass (AGB) has become an important task, particularly for the reporting of carbon stocks and changes. AGB can be mapped using synthetic aperture radar data (SAR) or passive optical data. However, these data are insensitive to high AGB levels (>150 Mg/ha, and >300 Mg/ha for P-band), which are commonly found in tropical forests. Studies have mapped the rough variations in AGB by combining optical and environmental data at regional and global scales. Nevertheless, these maps cannot represent local variations in AGB in tropical forests. In this paper, we hypothesize that the problem of misrepresenting local variations in AGB and AGB estimation with good precision occurs because of both methodological limits (signal saturation or dilution bias) and a lack of adequate calibration data in this range of AGB values. We test this hypothesis by developing a calibrated regression model to predict variations in high AGB values (mean >300 Mg/ha) in French Guiana by a methodological approach for spatial extrapolation with data from the optical geoscience laser altimeter system (GLAS), forest inventories, radar, optics, and environmental variables for spatial inter-and extrapolation. Given their higher point count, GLAS data allow a wider coverage of AGB values. We find that the metrics from GLAS footprints are correlated with field AGB estimations (R 2 =0.54, RMSE=48.3 Mg/ha) with no bias for high values. First, predictive models, including remote-sensing, environmental variables and spatial correlation functions, allow us to obtain "wall-to-wall" AGB maps over French Guiana with an RMSE for the in situ AGB estimates of ~51 Mg/ha and R²=0.48 at a 1-km grid size. We conclude that a calibrated regression model based on GLAS with dependent environmental data can produce good AGB predictions even for high AGB values if the calibration data fit the AGB range. We also demonstrate that small temporal and spatial mismatches between field data and GLAS footprints are not a problem for regional and global calibrated regression models because field data aim to predict large and deep tendencies in AGB variations from environmental gradients and do not aim to represent high but stochastic and temporally limited variations from forest dynamics. Thus, we advocate including a greater variety of data, even if less precise and shifted, to better represent high AGB values in global models and to improve the fitting of these models for high values.
ISSN: 0303-2434

Droits : http://creativecommons.org/licenses/by/
hal-01381116
https://hal.archives-ouvertes.fr/hal-01381116
https://hal.archives-ouvertes.fr/hal-01381116/document
https://hal.archives-ouvertes.fr/hal-01381116/file/Fayad2016a.pdf
DOI : 10.1016/j.jag.2016.07.015

Éditeur(s) : HAL CCSD Oxford University Press (OUP)
Résumé : International audience
Tilt fluctuations can potentially reflect the response of hydrosystems to important rainfall. In this context, long baseline tiltmeters have been installed in an underground tunnel penetrating the Fontaine de Vaucluse karst to study the medium deformation related to solicitations exerted by water infiltrating the hydrosystem. The instruments monitor the tilt as well as its spatial variation. Northward tilts reaching a 1 μrad amplitude are observed consecutively to rainfalls. The tilt amplitude is highly correlated with the Fontaine de Vaucluse outlet flow fluctuations. The measured tilt signal is also relatively homogeneous over a 150 m length. Different types of structure likely to produce such observations are tested in order to identify their location with respect to the tiltmeters, their dimension as well as the amount of water level variation in the structure. Following rainfalls, the infiltration of water modifies the pore pressure, inducing a medium deformation. The hypothesis of an homogeneous surface loading on the Vaucluse plateau is first refuted since the related tilt is much lower than the one measured. The water supplied by rainfalls has to accumulate in discontinuities in order to generate a higher tilt. So, the deformation related to a pressure exerted on a fracture filled by water is assessed. A first study reveals the interest of the tilt homogeneity information that constrains strongly the fracture properties. Thus, the fracture must be located at a distance more than a few hundreds metres from the tiltmeters in order to produce a tilt homogeneous in space. If the fracture is initially dry, it must also be filled on a height higher than 150 m consecutive to a rainfall in order to generate a tilt amplitude in the same magnitude as the one measured. Then, we explore the influence of water level variations on the tilt produced by a fracture located at the interface between the saturated and unsaturated zones, which are thereby permanently flooded. Since several parameters of that model satisfactorily explain the field observations, we discuss how simultaneous geodetical observations could provide complementary information that would further constrain the geometry of the structure at the origin of the medium deformation.
ISSN: 0956-540X

insu-01408482
https://hal-insu.archives-ouvertes.fr/insu-01408482
https://hal-insu.archives-ouvertes.fr/insu-01408482/document
https://hal-insu.archives-ouvertes.fr/insu-01408482/file/Lesparre-2017.pdf
DOI : 10.1093/gji/ggw446

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We developed a new granular material (MatIV) to study experimentally landscape evolution in active mountain belt piedmonts. Its composition and related physical properties have been determined using empirical criteria derived from the scaling of deformation, erosion-transport and sedimentation natural processes. MatIV is a water-saturated composite material made up with 4 granular components (silica powder, glass microbeads, plastic powder and graphite) whose physical, mechanical and erosion-related properties were measured with different laboratory tests. Mechanical measurements were made on a modified Hubbert-type direct shear apparatus. Erosion-related properties were determined using an experimental set-up that allows quantifying the erosion/sedimentation budget from tilted relaxation topographies. For MatIV, we also investigated the evolution of mean erosion rates and stream power erosion law exponents in 1D as a function of slope.;Our results indicate that MatIV satisfies most of the defined criteria. It deforms brittlely according to the linear Mohr-Coulomb failure criterion and localizes deformation along discrete faults. Its erosion pattern is characterized by realistic hillslope and channelized processes (slope diffusion, mass wasting, channel incision). During transport, eroded particles are sorted depending on their density and shape, which results in stratified alluvial deposits displaying lateral fades variations. To evaluate the degree of similitude between model and nature, we used a new experimental device that combines accretionary wedge deformation mechanisms and surface runoff erosion processes. Results indicate that MatIV succeeded in producing detailed morphological and sedi-mentological features (drainage basin, channel network, terrace, syntectonic alluvial fan). Geometric, kinematic and dynamic similarity criteria have been investigated to compare precisely model to nature. Although scaling is incomplete, it yields particularly informative orders of magnitude. With all these characteristics, MatIV appears as a very promising material to investigate experimentally a wide range of scientific questions dealing with relief dynamics and interactions between tectonics, erosion and sedimentation processes.
ISSN: 0040-1951

hal-00669904
https://hal.archives-ouvertes.fr/hal-00669904
DOI : 10.1016/j.tecto.2011.09.029

Éditeur(s) : HAL CCSD Elsevier
Résumé : Adequate hydrogeophysical monitoring of CO2 geological storage remains a challenge as different parameters might be modified during storage. That implies to compare real-time measurements to an adequate baseline. At the Maguelone shallow experimental site a representative baseline for electrical resistivity was built from a large number of downhole geophysical measurements. At this coastal site this issue is particularly important due to the production of biogenic gas from the subsurface sediments. For this, a modified petrophysical model based on the Waxman-Smits model is proposed to estimate gas saturation found to vary from 2 to 7% within shallow sand layers.
ISSN: 1876-6102

hal-01412685
https://hal.archives-ouvertes.fr/hal-01412685
https://hal.archives-ouvertes.fr/hal-01412685/document
https://hal.archives-ouvertes.fr/hal-01412685/file/pezard2015.pdf
DOI : 10.1016/j.egypro.2015.07.910

Éditeur(s) : HAL CCSD Springer Verlag
Résumé : International audience
In ophiolites and in present-day oceanic crust formed at fast spreading ridges, oceanic plagiogranites are commonly observed at, or close to the base of the sheeted dike complex. They can be produced either by differentiation of mafic melts, or by hydrous partial melting of the hydrothermally altered sheeted dikes. In addition, the hydrothermally altered base of the sheeted dike complex, which is often infiltrated by plagiogranitic veins, is usually recrystallized into granoblastic dikes that are commonly interpreted as a result of prograde granulitic metamorphism. To test the anatectic origin of oceanic plagiogranites, we performed melting experiments on a natural hydrothermally altered dike, under conditions that match those prevailing at the base of the sheeted dike complex. All generated melts are water saturated, transitional between tholeiitic and calc-alkaline, and match the compositions of oceanic plagiogranites observed close to the base of the sheeted dike complex. Newly crystallized clinopyroxene and plagioclase have compositions that are characteristic of the same minerals in granoblastic dikes. Published silicic melt compositions obtained in classical MORB fractionation experiments also broadly match the compositions of oceanic plagiogranites; however, the compositions of the coexisting experimental minerals significantly deviate from those of the granoblastic dikes. Our results demonstrate that hydrous partial melting is a likely common process in the root zone of the sheeted dike complex, starting at temperatures exceeding 850A degrees C. The newly formed melt can either crystallize to form oceanic plagiogranites or may be recycled within the melt lens resulting in hybridized and contaminated MORB melts. It represents the main MORB crustal contamination process. The residue after the partial melting event is represented by the granoblastic dikes. Our results support a model with a dynamic melt lens that has the potential to trigger hydrous partial melting reactions in the previously hydrothermally altered sheeted dikes. A new thermometer using the Al content of clinopyroxene is also elaborated.
ISSN: 0010-7999

hal-00534058
https://hal.archives-ouvertes.fr/hal-00534058
DOI : 10.1007/s00410-010-0502-6

Éditeur(s) : HAL CCSD
Résumé : International audience
The deformation of natural systems in response to subsurface water storage and redistribution provides insightsinto the main water flow path within heterogeneous systems, including the role of faults or fractures. A longbaseline tiltmeter was installed in the low-noise underground laboratory of Rustrel (LSBB) to study the responseof the Fontaine de Vaucluse (FDV) karst hydrosystem to water cycle. Tilt data and piezometric levels recorded in aborehole close to the LSBB show a strong correlation with the discharge of the system observed at the FDV spring30 km away. Over several months, tilt data were recorded on three base lines, thus allowing, for the first time,to study the tilt gradient variation that appears homogeneous. Such information provides a significant constrainton hydrological processes leading to the measured deformation. Several deformation models were tested usingthe ADELI code to estimate the type of hydro-mechanical structure that could reproduce the measured tilt andits gradient. On one hand, models show that uniform loading at the surface produces a much smaller signal thanobserved on measured data. On the other hand, the deformation related to the filling of a fracture following aprecipitation event requires unrealistic fracture size. Finally, we found that a suitable hydro-mechanical modelcorresponds to the loading of numerous fractures at the interface between the saturated and unsaturated zones. Sucha configuration predicts a tilt distribution in agreement with observations. This study suggests that tilt networksinto a karst system should provide key observation for deciphering hydrological processes
Geophysical Research Abstracts
Vienne, Austria

insu-01308594
https://hal-insu.archives-ouvertes.fr/insu-01308594

Éditeur(s) : HAL CCSD
Résumé : International audience
The purpose of our study is to model a geothermal reservoir. When geothermal reservoir are assumed to be composed of pure water, the transfer of mass and energy is classically described by two balance equations: mass balance equation and the energy balance equation. In addition to those equations, fluid velocity ist classically given by the Darcy law while thermodynamic properties, inferred from theoretical or empirical equations of state, are used to close the mathematical system. Once this system is closed, there exist different solutions. The first one is to solve for pressure and temperature with a variable switch to saturation in the two-phase region (e.g. TOUGH2). The second one is to solve for pressure and enthalpy to increase stability of phase transition between single and two-phase states (e.g. Hydrotherm). We adopted the second option and chose te use a splitting method to get rid of the complexity of coupling equations and a finite volume method for the spatial discretization. Selecting object-oriented languages, we developed a multi-language framework, combining Python, Fortran and a C++ implementation of IAPWS (from the freesteam project) including the supercritical equations, in porous media velocity is given by Darcy law and to close the system physical properties are determined by the IAPWS-IF97 thermodynamic formulation. We resolve the equations in pressure and enthalpy instead of pressure and temperature in order to increase stability and to handle easier the passage from a single-phase to a two-phase system. We solve the system by using a splitting method - to get rid of the complexity of coupling equations - and a finite volume method. We offer some freedom to users thanks to the implementation of several methods like explicit or implicit Euler, Runge-Kutta or BDF2 for time solvers or GMRES and BICGSTAB for the linear solver. We can handle several boundary conditions like no-flow - describing a boundary which can not exchange matter with the exterior - or like a mixed-therm condition - a Dirichlet condition to the pressure and a Dirichlet or an outflow condition to the temperature in order to describe a recharge or a discharge zone - ... We're developing a multi-language framework, combining Python, Fortran and the C++ implementation of IAPWS (from the freesteam project). All these languages are object-oriented. We've applied this simulation model to the dogger in Paris, France, to several one-dimensional systems and a two-dimensional one made by Coumou with the CSMP++ platform. The dogger is a reservoir exploited to produce heat by pumping water at 70 and reinjecting it in the reservoir at 40. In the one-dimensional systems we wanted to observe the process of heat transfer from a higher temperature boundary to a smaller one in a high-energy domain. The last simulation shows the natural convection of water in a fault. For every simulation we compared the solutions we found with an other code (TOUGH2 or CSMP++) and they agreed. The next step will be to model the geothermal plant in Guadeloupe, West Indies. It's the only place in France - and in the West Indies so far - producing electricity with the earth power. The temperature can reach up to 1000 and the pressure range is around a few hundreds MPa. In some surface zones we can see two-phase water at atmospheric pressure. In the 1980s Bouillante was a laboratory for France. Since 1995 Bouillante has given 30GWh electricity a year to the Guadeloupeans.
PROCEEDINGS, Thirty-Ninth Workshop on Geothermal Reservoir Engineering
Stanford, United States

Droits : info:eu-repo/semantics/OpenAccess
hal-00944133
https://hal-brgm.archives-ouvertes.fr/hal-00944133
https://hal-brgm.archives-ouvertes.fr/hal-00944133/document
https://hal-brgm.archives-ouvertes.fr/hal-00944133/file/Copol.pdf