Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
From outcrops located in Provence (South-East France), we describe the distribution, the microstructures, and the petrophysical properties of deformation band networks related to both contractional and extensional tectonic events. In contraction, pervasively distributed networks of reverse-sense compactional shear bands are observed in all folded sand units of the foreland, whereas localized networks of clustered reverse-sense shear bands are only observed close to a large-scale thrust. In extensional setting, networks of clustered normal-sense shear bands are generally observed adjacent to map-scale faults (100 m–10 km scale), although some randomly distributed bands are also observed between these faults. Normal-sense cataclastic faults, i.e. zone of deformation bands containing a localized slip-surface, are also observed to be restricted to sand units, suggesting that faults initiated in the sands during extension, but not during contraction. Shear bands and faults show cataclastic microstructures with high-permeability reduction whereas compactional shear bands show crush microbreccia or protocataclastic microstructures with moderate permeability reduction. This basin-scale analysis underlines the major role of tectonic settings (thrust-fault versus normal-fault andersonian-stress regime) and the influence of inherited large-scale faults on the formation/localization of low-permeability shear bands. We also provide a geometrical analysis of the band network properties (spacing, thickness, shear/compaction ratio, degree of cataclasis, petrophysical properties) with respect to the median grain size, porosity and grain sorting of host sand. This analysis suggests that grain size, although less important than stress-state conditions and the presence of large-scale faults, has a non-negligible effect on band network geometry. No correlations are observed between the grain sorting, porosity and band network geometry.
ISSN: 0264-8172

hal-01116421
https://hal.archives-ouvertes.fr/hal-01116421
DOI : 10.1016/j.marpetgeo.2013.12.020

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Coastal aquifers often display seawater intrusion resulting in the formation of a salty water wedge progressing inland. This study investigates the mass transfers in the mixing zone at the freshwater-seawater interface where the water is out of equilibrium with the rock-forming carbonates. Investigations were conducted in two boreholes, separated by 5 m, at the Ses Sitjoles test site (Mallorca Island, Spain) where repeated electrical conductivity logs of the formation and the saturating fluid, as well as regular pore-water sampling and permanent downhole multi-parameter monitoring of the water were performed over a period of 9 a. In the mixing zone, the significant acidification, the calcite saturation index profile and the Ca concentration profile cannot be explained by conservative mixing nor by dissolution-precipitation reactions only. Conversely, the analysis of organic C content and of the distinctly different time-resolved pH profiles measured in the two boreholes suggests the development of perennial biomass that triggers calcite dissolution. Moreover, the presence of biomass seems to be correlated with the permeability and vertical connectivity at the meter-scale. It is speculated that the mechanism could be self-activated because the microbiological activity induces calcite dissolution and tends to increase porosity and permeability that favors biomass development.
ISSN: 0883-2927

hal-00937665
https://hal.archives-ouvertes.fr/hal-00937665
DOI : 10.1016/j.apgeochem.2013.09.011

Éditeur(s) : HAL CCSD Geological Society of America
Résumé : International audience
On the New Jersey shelf (offshore North America), the presence of pore water fresher than seawater is known from a series of boreholes completed during the 1970s and 1980s. To account for this fresh water, a fi rst hypothesis involves possible present-day active dynamic connections with onshore aquifers, while a second involves meteoritic and/or sub- ice-sheet waters during periods of lowered sea level. Expedition 313 drilled three boreholes on the middle shelf, offering a unique opportunity for the internal structure of the siliciclastic system to be accessed, at scales ranging from the depositional matrix to the continental margin. This enables the stratigraphic architecture to be correlated with the spatial distribution and salinity of saturating fl uids. Expedition 313 revealed both very low salinities (<3 g/L) at depths exceeding 400 m below the seafl oor and evidence for a multilayered reservoir organization, with freshand/ or brackish-water intervals alternating vertically with salty intervals. In this study we present a revised distribution of the salinity beneath the middle shelf. Our observations suggest that the processes controlling salinity are strongly infl uenced by lithology, porosity, and permeability. Saltier pore waters generally occur in coarse-grained intervals and fresher pore waters occur in fi ne-grained intervals. The transition from fresher to saltier intervals is often marked by cemented horizons that probably act as permeability barriers. In the lowermost parts of two holes, the salinity varies independently of lithology, suggesting different mechanisms and/or sources of salinity. We present an interpretation of the sedimentary facies distribution, derived from core, logs, and seismic profi le analyses, that is used to discuss the marginscale two-dimensional reservoir geometry and permeability distribution. These proposed geometries are of primary importance when considering the possible pathways and emplacement mechanisms for the fresh and salty water below the New Jersey shelf.
EISSN: 1553-040X

insu-00858241
https://hal-insu.archives-ouvertes.fr/insu-00858241
DOI : 10.1130/GES00855.1

Éditeur(s) : HAL CCSD
Résumé : Geological storage of CO2 is one of diverse technologies being explored to reduce atmospheric carbon fromindustrial processes (i.e. fossil fuel combustion). One of the specific features of CO2 injection is the possibility ofgeochemical reactions (dissolution – precipitation) between mobile reactive brine (e.g. formation water enrichedin CO2) and the host rock during the spatial and temporal evolution of CO2. That leads to modifications in thepore structure, which in turn change the flow dynamics of the reservoir (e.g. the permeability k). Then, thesesstructural modifications can largely control the injectivity, so that the pressure field in the reservoir and also theCO2 propagation. Accordingly, it is crucial to explore the changes in the reservoir properties (e.g. structural andhydrodynamic) induced during a CO2 injection and specially the relationships between them (e.g. k or reactivesurface-Sr versus porosity-φ , k versus rock heterogeneity), for developing predictive modelling tools of thetransport and reaction processes occurring during a CO2 injection and reliable risk assessment. In the case ofcarbonate rocks, the application of the predictive models of transport and reaction is still challenging, because oftheir high heterogeneity so that the incertitude in the reaction kinetics of carbonate minerals.From this perspective, we realized brine-enriched in CO2 percolation experiments through carbonate rocksamples in thermodynamic conditions expected during CO2 injection in deep reservoirs (T = 100°C et P =12MPa). The permeability changes k(t) is monitored during the experiments and the porosity variationφ (t) iscalculated from chemical analyses of the sampled outlet fluids, using ICP-EAS. The pore structure modificationsare investigated from high resolution X ray micro tomography images acquired from the synchrotron ofGrenoble (ESRF). Depending to the dissolution regime, controlled by the reservoir rock fabric and the chemicalcomposition of the brine (e.g. PCO2), we observed that a modification of pore structure can either improve(atypical result in dissolution context) or impair the value of the permeability k.
Le stockage géologique du CO2 est l’une des diverses technologies étant explorées afin deréduire les émissions de carbone atmosphérique des processus industriels (i.e. combustion del’énergie fossile). L’une des spécifiques caractéristiques de l’injection du CO2 en profondeurreste la possibilité de réactions géochimiques (dissolution-précipitation) entre la saumureréactive mobile (e.g. eau de formation enrichie en CO2) et la roche encaissante durantl’évolution spatiale et temporelle du CO2, conduisant à des modifications dans la structure despores et par conséquent dans les propriétés d’écoulement du réservoir (e.g. la perméabilité k).Donc, ces changements structuraux peuvent largement contrôler l’injectivité, ainsi que lechamp de pression dans le réservoir et aussi la propagation du CO2. Il demeure ainsi cruciald’explorer les changement dans les propriétés de réservoirs (e.g. structurales ethydrodynamiques) induits durant une injection de CO2 et explicitement les relations existantesentre eux (e.g. k ou surface réactive-Sr versus porosité-φ , k versus hétérogénéité de la roche),afin de développer des outils de modélisation prédictive des processus de transport etréactionnels se produisant durant une injection de CO2 et d’évaluer de façon fiable les risques.Dans le cas des réservoirs carbonatés, l’application des modèles prédictifs de transport réactifdemeure toujours un enjeu, car contrainte par la forte hétérogénéité en leur sein ainsi que parl’incertitude dans la cinétique de réactions des minéraux carbonatés dans ce contexte. Danscette optique, nous avons réalisé des expériences de percolation à travers des échantillons deroches carbonatées dans les conditions thermodynamiques de stockage en profondeur (T =100°C et P =12 MPa). L’évolution de la perméabilité k(t) est suivie au cours desexpériences ; et la variation de la porosité φ (t) est calculée à partir des résultats d’analyseschimiques au ICP-AES des fluides de sortie échantillonnés. L’investigation des modificationsapportées à la structure des pores est réalisée par le biais de la Micro-Tomographie hauterésolution à rayon X, acquise au synchrotron de Grenoble (e.g. ESRF).Dépendant du régime de dissolution, contrôlé par la fabrique de la roche réservoir et lacomposition chimique de la saumuré chargée en CO2 (e.g. PCO2 engagée), on a observéqu’une modification de la structure de la roche peut soit améliorer soit détériorer (résultatatypique en contexte de dissolution) la valeur de la perméabilité k.
https://hal.archives-ouvertes.fr/tel-01142136

tel-01142136
https://hal.archives-ouvertes.fr/tel-01142136
https://hal.archives-ouvertes.fr/tel-01142136/document
https://hal.archives-ouvertes.fr/tel-01142136/file/thesemangane2013.pdf

Éditeur(s) : HAL CCSD
Résumé : The coastal intrusion of brine threatens populations. This is particularly prejudicial in carbonate environments. We have studied the Miocene coral reef of S-E Majorca for better understanding the relation between geological structure and intrusion. For that purpose, we have used multi-scalar and multi-disciplinary methods. The measurements in 25 boreholes over the whole coral platform have allowed defining the stratigraphic structure and some elements of the regional tectonic. The reef progrades in the NE-SW direction, starting from the Aquitanian to terminates at the Messinian. The Messinian Salinity Crisis involves a disappearance of the Mediterranean corals and results in a Terminal Carbonate Complex which overlays a great part of the previously living corals of Majorca. At the experimental site scale, the study of the mineral composition, the texture, and the diagenesis have allowed characterization of the carbonate sequence heterogeneity. Layers of mineralization accompanied by dolomitization and low porosity correspond to postdepositional eustatic levels. The causes for the existence and the orientation of fractures are studied. The permeability to porosity relation is approached. The porosity structure is studied by comparison between primary and secondary porosity. This study contributes to the knowledge of the world best documented site for the evolution of carbonate reef reservoirs, with applications for brine intrusion and for hydrocarbon extraction.
Les intrusions d'eau salée en zone côtière constituent une menace pour la population. Celles-ci sont particulièrement dommageables en contexte carbonaté. Nous avons étudié le récif corallien Miocène du sud-est de Majorque afin de comprendre la relation entre structure géologique et intrusion. Pour cela nous avons utilisé des méthodes multi-scalaires et multi-disciplinaires. Les mesures dans 25 forages sur l'ensemble de la plateforme corallienne ont permis de préciser la structure stratigraphique et certains éléments de la tectonique régionale. Le récif prograde dans la direction NE-SO, en partant de l'Aquitanien pour aboutir au Messinien. La Crise de Salinité Messinienne entraîne une disparition des coraux méditerranéens et se traduit par un Complexe Carbonaté Terminal qui s'étend sur une grande partie des coraux autrefois vivants de Majorque. A l'échelle du site expérimental, l'étude de la composition minérale, de la texture et de la diagenèse ont permis de caractériser l'hétérogénéité de la séquence carbonatée. Des couches de minéralisation accompagnées de dolomitisation et de faible porosité correspondent à différents niveaux eustatiques post-dépositionnels. Les causes de l'existence et de l'orientation des fractures sont étudiées. La relation de perméabilité à porosité est précisée. La structure de porosité est étudiée par comparaison entre la porosité primaire et la porosité secondaire. Cette étude contribue à la connaissance du site le mieux documenté au monde pour l'évolution des réservoirs carbonatés récifaux, avec applications pour les intrusions d'eau salée et l'extraction des hydrocarbures.
https://tel.archives-ouvertes.fr/tel-00440019

tel-00440019
https://tel.archives-ouvertes.fr/tel-00440019
https://tel.archives-ouvertes.fr/tel-00440019/document
https://tel.archives-ouvertes.fr/tel-00440019/file/thesemariasube.pdf

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
To test the impact of fluid flow on the reactivity of porous (ultra-)mafic rocks, reactive percolation experiments were realized during which CO2-enriched water was injected at two different injection rates (Q = 0.1 and 1 mL h−1) through sintered analogues of olivine-accumulation zones in basaltic flows at temperature and fluid composition conditions (T = 180 °C; NaHCO3 buffered solution) favorable for CO2-mineralization (carbonation).All experiments resulted in silicate dissolution, carbonate precipitation upstream and (proto-)serpentine formation downstream indicating a decrease in the fluid reactivity along flow paths. The measured bulk carbonation rates ranged from 4 to 7 × 10−8 s−1; these values were significantly lower than previously published values of olivine carbonation rate obtained on powders in closed batch and flow-through reactors. Our study show complex couplings, at pore scale, between fluid flow, localization of reaction zones, and chemical reaction kinetics which in turn control hydrodynamic properties, carbonation rate and efficiency and fluid reactivity. This results in carbonation rates being higher when injection rates are high and permeability ultimately controlling carbonation reactions by limiting fluid input. During experiments, notable changes in permeability occurred for only minor changes in porosity indicating a control by the geometry of the porous network: heterogeneities in the distribution of flow paths favored the localization of precipitated minerals which in turn resulted in the closure of flow paths. This mechanism was particularly efficient at low injection rates. These results imply that controlling the injection rate could allow enhancing/limiting the efficiency of in situ carbonation.
ISSN: 0883-2927

hal-01115284
https://hal.archives-ouvertes.fr/hal-01115284
DOI : 10.1016/j.apgeochem.2014.11.024

Éditeur(s) : HAL CCSD
Résumé : The Restefond fault, located in the Late Eocene-Early Oligocene Alpine foreland basin, affects the well lithified and low porosity Grès d'Annot. The fault core zone is characterized by the occurrence of highly deformed sandstone lenses. Deformation inside the lenses corresponds to mm to sub-mm-spaced cleavage planes rich in phyllosilicates and up to cm-thick and dm-long quartz-calcite pure extensional veins. The cleavages are mostly composed of newly-formed synkinematic white mica and chlorite. By using thermodynamic thermometers based on the chemical composition of chlorite, a temperature of 200 ± 20 °C of fault activity was computed. This temperature shows that the Restefond fault was active at burial conditions comprised between 6.5 and 8 km, assuming a mean geothermal gradient between 25 and 30 °Ckm−1. The petrophysic properties of sandstones from the core zone and in the hanging and foot wall of the fault were determined on drilled plugs following three spacial directions. The permeability of the highly deformed sandstone from the core zone is about one order of magnitude higher than in the host rock. This increase in permeability occurs in the direction parallel to the S-C structures and is explained by the occurrence of well-connected micropores localized between platy phyllosilicates. This study shows that the fault petrophysic properties are mostly controlled by the precipitation of synkinematic phyllosilicates under deep burial conditions.
Swiss Journal of Geosciences

hal-00795551
https://hal.archives-ouvertes.fr/hal-00795551
DOI : 10.1007/s00015-012-0099-z

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The interplay between fault zone cataclasis and cementation is important since both processes can drastically reduce the permeability of faults in porous sandstones. Yet the prediction of fault cementation in high-porosity sandstone reservoirs remains elusive. Nevertheless, this process has rarely been investigated in shallowly buried faults (<2 km; T°<80 °C) where its sealing capacity could be acquired early in the geological history of a reservoir. In this paper, the macro- and microscopic analysis of a fault zone in the porous Cenomanian quartz arenite sands of Provence (France) shows that silica diagenesis occurs in the most intensely-deformed cataclastic parts of the fault zone. This fault zone shows 19–48% of its total thickness occupied by low-porosity quartz-cemented cataclastic shear bands whose porosities range from 0 – ca. 5%. The analysis of the weathering profile around the fault zone reveals the presence of groundwater silcretes in the form of tabular, tightly silicified concretions cross-cut by the fault. Detailed transmitted light, cold-cathodoluminescence and scanning electron microscopy analyses of the silica cements (from the fault and the silcrete) reveal that all the silica cements originate from groundwater diagenetic processes. This study therefore shows that silica cementation can occur specifically in fault zones and as groundwater silcrete in the shallow context of a groundwater system, generated at the vicinity of an erosional unconformity.
ISSN: 0191-8141

hal-01278286
https://hal.archives-ouvertes.fr/hal-01278286
DOI : 10.1016/j.jsg.2015.10.001

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Field observations of highly porous and permeable sandstone in the Orange area (S-E Basin, France) show that networks of shear-enhanced compaction bands can form in a contractional regime at burial depths of about 400 m ± 100 m. These bands show equal compaction and shear displacements, are organized in conjugate and densely distributed networks, and are restricted to the coarse-grained (mean grain diameter of 0.6 ± 0.1 mm) and less porous (porosity of 26 ± 2%) sand layers. The bands are crush microbreccia with limited grain comminution and high grain microfracture density. They show reductions of permeability (mD) ranging from 0 to little more than 1 order of magnitude. They show no control on the alteration products related to meteoric water flow, which suggests that these shear-enhanced compaction bands have no or only negligible influence on subsurface fluid flow. Their selective occurrence and small (20%) reduction in transmissibility in densely populated layers prevented them from compartmentalizing the sandstone reservoirs. A comparison with compaction-band populations in the Navajo and Aztec sandtsones (western U.S.) emphasizes the role of burial depth and the presence of chemical compaction processes for the sealing potential of deformation bands.
ISSN: 0191-8141

hal-00807309
https://hal.archives-ouvertes.fr/hal-00807309
DOI : 10.1016/j.jsg.2012.11.008

Éditeur(s) : HAL CCSD American Chemical Society
Résumé : Experiments were conducted to assess the potential impact of fractured well-cement degradation on leakage rate. Permeability was monitored while CO2-enriched reservoir-equilibrated brine was flowed at constant rate through a single fracture in a class G cement core under conditions mimicking geologic sequestration environments (temperature 60 °C, pressure 10 MPa). The results demonstrate that, at least for the conditions used in the experiment, an initial leakage in a 42 μm aperture fracture (permeability = 1.5 × 10-10 m2) can be self-mitigated due to the decrease of the fracture hydraulic aperture after about 15 h. This decrease results from the development of continuous highly hydrated amorphous Si-rich alteration products at the edge of the fracture and the dense carbonation of the bulk cement that mitigate the penetration of the alteration front.
ISSN: 0013-936X

hal-00950088
https://hal.archives-ouvertes.fr/hal-00950088
DOI : 10.1021/es401317c

Éditeur(s) : HAL CCSD MDPI AG, Basel, Switzerland
Résumé : International audience
Abstract View references (46)This work shows the preparation of silica membranes by a two-step sol-gel method using tetraethyl orthosilicate in ethanolic solution by employing nitric acid and ammonia as co-catalysts. The sols prepared in pH 6 resulted in the lowest concentration of silanol (Si-OH) species to improve hydrostability and the optimized conditions for film coating. The membrane was tested to desalinate 0.3-15 wt % synthetic sodium chloride (NaCl) solutions at a feed temperature of 22 °C followed by long term membrane performance of up to 250 h in 3.5 wt % NaCl solution. Results show that the water flux (and salt rejection) decrease with increasing salt concentration delivering an average value of 9.5 kg m-2 h-1 (99.6%) and 1.55 kg m-2 h-1 (89.2%) from the 0.3 and 15 wt % saline feed solutions, respectively. Furthermore, the permeate salt concentration was measured to be less than 600 ppm for testing conditions up to 5 wt % saline feed solutions, achieving below the recommended standard for potable water. Long term stability shows that the membrane performance in water flux was stable for up to 150 h, and slightly reduced from thereon, possibly due to the blockage of large hydrated ions in the micropore constrictions of the silica matrix. However, the integrity of the silica matrix was not affected by the long term testing as excellent salt rejection of >99% was maintained for over 250 h. © 2013 by the authors; licensee MDPI, Basel, Switzerland.
ISSN: 2077-0375

hal-01683203
https://hal.univ-antilles.fr/hal-01683203
DOI : 10.3390/membranes3030136

Éditeur(s) : HAL CCSD
Résumé : International audience
The porosity (from values of <1% up to more than 50%, with a mean value of 36.5%) and permeability (from very low values to 20.4 D, with a mean value around 800 mD) of 38 plugs, with a diameter 40 mm, have been measured. These plugs were taken approximately every 1.5 m along a 100 m-long core, sampling a series of reefal carbonate platform lithofacies. A non-unique relationship between porosity and permeability is obtained. In addition, the porosity was measured from processing X-ray micro-tomography images with resolutions ranging from 0.42 to 190.0 µm and sampling volumes ranging from less than 1 µm3 to few cm3. Depending on the structure of the pore network, the computed porosity is, in some cases, controlled by the X-ray image resolution and the sampled volume. While high resolution is required to image micro-porous material, large samples with lower resolution images are necessary for identifying distributed vugs and millimetre-scale structures. This study shows that multi-resolution X-ray micro-tomography is an effective tool for characterizing the multi-scale pore structure of carbonate rocks and understanding how it may control key petrophysical parameters such as porosity and permeability.
Geological Society Special Publication

hal-01174157
https://hal.archives-ouvertes.fr/hal-01174157
DOI : 10.1144/SP406.12

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : A differential effective medium (DEM) model is used to predict elastic properties for a set of porous and anisotropic aggregates, comprised of mixtures of calcite and muscovite. The DEM takes into consideration an anisotropic background medium with triclinic or higher symmetry, in which inclusions of idealized ellipsoidal shape are added incrementally. In general, the calculated elastic properties of a solid that contains inclusions representing "dry" pores/cracks are strongly dependent on the orientation and aspect ratio of the inclusions. Aspect ratios of inclusions in the synthetic aggregates, which consist of air-filled pores, are estimated from anisotropy of magnetic susceptibility (AMS) of samples whose pore space has been impregnated with a colloidal ferrofluid. The AMS derived pore shape geometry is used as an input value for inclusions in the DEM. Modeling results are compared with laboratory determined elastic properties, measured with ultrasonic waves. Calculated shear wave velocities agree in general well with laboratory measured S wave velocities, whereas calculated P wave velocities are typically 0.5-1.1 km/s higher than measured values. Differences between calculated and measured P wave velocities are attributed mainly to incomplete and biased ferrofluid saturation of pores. Spherical pores are preferably filled during imbibition, in comparison to thin cracks, which leads to overprediction of the calculated P wave velocities. The amount of ferrofluid that fills the pore space is dependent on the ratio of calcite to muscovite and the load used for compaction during sample synthesis. The permeability decreases with increasing muscovite content and increasing compaction load. Incomplete saturation of samples with high-muscovite content is confirmed by X-ray microtomography density contrast imaging of dry and ferrofluid saturated specimens.
ISSN: 0148-0227

hal-00617717
https://hal.archives-ouvertes.fr/hal-00617717
DOI : 10.1029/2010JB007750

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Heletz sandstone (Israel) reactivity is studied by means of CO2-rich brine percolation experiments and modeling. Experiments are performed at in situ temperature and pressure conditions with two distinctly different injection flow rates and for two different brine compositions: the genuine Heletz brine and a similar brine but in equilibrium with gypsum. The Heletz sandstone is composed of quartz, dolomite, ankerite, K-feldspar, clay minerals and minor amounts of gypsum and pyrite. The main reaction is the dissolution of the carbonates which is fastest for the highest flow rate injection and for the genuine Heletz brine. Permeability increases during the five percolation experiments, regardless of flow rate and brine type. This increase in permeability is associated to a decrease in porosity during the gypsum-equilibrated brine experiments due to gypsum precipitation. The precipitation of secondary minerals (kaolinite, muscovite and smectite) is mainly controlled by the dissolution of K-feldspar and largest at low flow rate injection, indicating that these precipitation processes are diffusion-controlled and localized in immobile zones where favorable chemical micro-environments exist. These processes are quantified by means of a reactive transport model. These results indicated that the CO2 injection at the Heletz site should trigger both permeability increase in interface between brine and CO2, which may extend over a large extension and where mixing processes are very active, especially near the well under intermittent injection conditions.
ISSN: 1750-5836

hal-01356329
https://hal.archives-ouvertes.fr/hal-01356329
DOI : 10.1016/j.ijggc.2015.10.023

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Here we show that copper substitution in perovskite-type barium strontium cobalt copper oxide (BSCC) membranes confers extremely high oxygen fluxes well beyond the state of art, reaching 27.5 ml cm−2 min−1at 950 °C. A key feature of BSCC is the formation of a mixed matrix catalyst-perovskite membrane caused by the segregation of copper, leading to the formation of an intergranular network of copper-rich oxide between perovskite grains. BSCC membranes delivered pressure normalised oxygen flux (i.e. permeance) of up to 86 times higher, above pressure difference of 18 kPa, as compared to best perovskite membrane, BBSC, due to the catalytic effect of segregated copper oxide. Unlike conventional dual-phase membranes which contain ion and electron conducting phases, this work shows for the first time perovskite-type membranes consisting of a mixed matrix of oxygen ion/electron conducting (perovskite) and catalytic (copper oxide) phases, thus paving the way to the development of high performance membranes for oxygen separation from air for clean energy applications. © 2016 Elsevier B.V.
ISSN: 0376-7388

hal-01683219
https://hal.univ-antilles.fr/hal-01683219
DOI : 10.1016/j.memsci.2016.12.035

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Numerical programs for simulating flow and reactive transport in porous media are essential tools for predicting reservoir properties changes triggered by CO2 underground injection. At reservoir scale, meshed models in which equations are solved assuming that constant macroscopic properties can be defined in each cells, are widely used. However, the parameterization of the dissolution-precipitation problem and of the feedback effects of these processes on the flow field is still challenging. The problem arises from the mismatch between the scales at which averaged parameters are defined in the meshed model and the scale at which chemical reactions occur and modify the pore network geometry. In this paper we investigate the links between the dissolution mechanisms that control the porosity changes and the related changes of the reactive surface area and of the permeability. First, the reactive surface area is computed from X-ray microtomography data obtained before and after a set of dissolution experiments of pure calcite rock samples using distinctly different brine-CO2 mixtures characterizing homogeneous to heterogeneous dissolution regimes. The results are used to validate the power law empirical model relating the reactive surface area to porosity proposed by Luquot and Gauze (2009). Second, we investigate the spatial distribution of the effective hydraulic radius and of the tortuosity, two structural parameters that control permeability, in order to explain the different porosity-permeability relationships observed for heterogeneous and homogeneous dissolution regimes. It is shown that the increase of permeability is due to the decrease of the tortuosity for homogeneous dissolution, whereas it is due to the combination of tortuosity decrease and hydraulic radius increase for heterogeneous dissolution. For the intermediate dissolution regime, identified to be the optimal regime for increasing permeability with small changes in porosity, the increase of permeability results from a large increase in the mean effective hydraulic radius of the sample.
ISSN: 0169-7722

hal-00617671
https://hal.archives-ouvertes.fr/hal-00617671
DOI : 10.1016/j.jconhyd.2010.07.004

Éditeur(s) : HAL CCSD Wiley
Résumé : International audience
The way faults control upward fluid flow in nonmagmatic hydrothermal systems in extensional context is still unclear. In the Eastern Pyrénées, an alignment of twenty-nine hot springs (29 ∘ C to 73 ∘ C), along the normal Têt fault, offers the opportunity to study this process. Using an integrated multiscale geological approach including mapping, remote sensing, and macro-and microscopic analyses of fault zones, we show that emergence is always located in crystalline rocks at gneiss-metasediments contacts, mostly in the Têt fault footwall. The hot springs distribution is related to high topographic reliefs, which are associated with fault throw and segmentation. In more detail, emergence localizes either (1) in brittle fault damage zones at the intersection between the Têt fault and subsidiary faults or (2) in ductile faults where dissolution cavities are observed along foliations, allowing juxtaposition of metasediments. Using these observations and 2D simple numerical simulation, we propose a hydrogeological model of upward hydrothermal flow. Meteoric fluids, infiltrated at high elevation in the fault footwall relief, get warmer at depth because of the geothermal gradient. Topography-related hydraulic gradient and buoyancy forces cause hot fluid rise along permeability anisotropies associated with lithological juxtapositions, fracture, and fault zone compositions.
ISSN: 1468-8115

hal-01582968
https://hal-brgm.archives-ouvertes.fr/hal-01582968
https://hal-brgm.archives-ouvertes.fr/hal-01582968/document
https://hal-brgm.archives-ouvertes.fr/hal-01582968/file/Taillefer_et_al_Geofluids_2017.pdf
DOI : 10.1155/2017/8190109

Éditeur(s) : HAL CCSD
Résumé : Geothermal energy is considered as a green and infinite energy source at human scale. Currently, the yield of geothermal power plants is limited to temperatures of the operating fluid which 350 °C. From tectonic and volcanic activity at mid-ocean ridges, Iceland is a location where supercritical fluid extraction (T> 375 °C) can considered for the near future. Exploiting such fluids could theoretically multiply by a factor of ten the electrical power delivered by geothermal wells. Can such fluids circulate at the base of brittle oceanic crust? This work investigates the petrophysical properties of basalts in order to constrain geophysical observations in Iceland and predict the behavior of very high temperature geo-hydrothermal reservoirs. The first approach consisted in studying the physical properties of rocks that have hosted deep hydrothermal circulations at oceanic ridges. The study of these rocks at ODP Site 1256 shows that the porosity measured both in the field and in the lab is associated with amphibolite facies alteration minerals (T> 500 ° C). The second approach was to recreate in the laboratory the conditions of pressure, temperature and pore fluid pressure of high temperature to supercritical hydrothermal systems to predict the mechanical and electrical properties of basalts under these conditions. The mechanical results indicate that the brittle/ductile transition occurs at a temperature of about 550° C, where a strong permeability decrease is expected. The implementation and calibration of a new cell for measuring electrical conductivity at high temperature provide the first results for the interpretation of geophysical data. When applied to basaltic crustal conditions in Iceland, these results indicate that hydrothermal fluids could circulate, at least temporarily, in a supercritical state up to 5 km depth.
La géothermie est considérée comme une source d'énergie propre et inépuisable à échelle humaine. Actuellement, le rendement des centrales géothermiques est limité à l'exploitation de fluides de températures inférieures à 350 °C. L'association de l'activité tectonique et volcanique aux dorsales océaniques fait de l'Islande un lieu où l'extraction de fluides supercritiques (T> 375 °C) peut être envisagée. Cette exploitation pourrait multiplier par dix la puissance électrique délivrée par le système géothermal. Ces fluides peuvent-ils circuler dans la croûte océanique ? Ce travail propose de contraindre les observations géophysiques et de prédire le fonctionnement des réservoirs géo-hydrothermaux de très haute température par l'étude des propriétés physiques des basaltes. La première approche est focalisée sur l'étude de roches ayant accueilli une circulation hydrothermale par le passé. L'étude de ces roches au site ODP 1256, montre que leur porosité est associée à la présence de minéraux d'altération hydrothermale du facies amphibolite (T> 500 °C). La seconde approche a consisté à recréer, en laboratoire, les conditions des systèmes hydrothermaux, à très haute température, afin de prédire les propriétés mécaniques et électriques des basaltes dans ces conditions. Les résultats mécaniques indiquent que la transition fragile/ductile, souvent associée à une forte décroissance de perméabilité, intervient à une température d'environ 550 °C. La mise en place d'une cellule de mesure de la conductivité électrique de haute température a fourni les premiers résultats utiles à l'analyse des données géophysiques. Appliqués aux conditions de la croûte basaltique Islandaise, ces résultats indiquent que des fluides hydrothermaux pourraient circuler au moins transitoirement à l'état supercritique jusqu'à ~ 5 km de profondeur.
https://tel.archives-ouvertes.fr/tel-00591798

tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798
https://tel.archives-ouvertes.fr/tel-00591798/document
https://tel.archives-ouvertes.fr/tel-00591798/file/THESE_MV_pro.pdf

Éditeur(s) : HAL CCSD American Association of Petroleum Geologists
Résumé : In reservoir engineering, hydrodynamic properties can be estimated from downhole electrical data using heuristic models (e.g., Archie and Kozeny-Carman's equations) relating electrical conductivity to porosity and permeability. Although proven to be predictive for many sandstone reservoirs, the models mostly fail when applied to carbonate reservoirs that generally display extremely complex pore network structures. In this article, we investigate the control of the three-dimensional (3-D) geometry and morphology of the pore network on the electrical and flow properties, comparing core-scale laboratory measurements and 3-D x-ray microtomography image analysis of samples from a Miocene reefal carbonate platform located in Mallorca (Spain). The results show that micrometer- to centimeter-scale heterogeneities strongly influence the measured macroscopic physical parameters that are then used to evaluate the hydrodynamic properties of the rock, and therefore, existing models might not provide accurate descriptions because these heterogeneities occur at scales smaller than those of the integration volume of the borehole geophysical methods. However, associated with specific data processing, 3-D imagery techniques are a useful and probably unique mean to characterize the rock heterogeneity and, thus, the properties variability.
ISSN: 0149-1423

hal-00950066
https://hal.archives-ouvertes.fr/hal-00950066
DOI : 10.1306/05221312134

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A large sand injectite network is very well exposed in the area of Bevons, Southeast France. The associated sandstone turbiditic channel–fill and the host marls are the Aptian–Albian rocks of the Vocontian Basin. The sand injection network is composed of dykes, sills and sedimentary laccoliths ranging in thickness from mm to pluri–m. The dykes and sills have vertical and horizontal lengths of up to and over 100 m and 1 km, respectively. Outcrop observations show that the architecture and morphology of the sand injectites in the marls is governed by the local stress field during injection, pre–existing faults, the host–rock lithology, compaction, and distance to the potential sand source(s). The main set of dykes is oriented N50–60° perpendicular to the minimum compressive stress σ3 during sand injection. Two other sets of dykes are intruded along pre–existing syn–sedimentary faults oriented N140–150° (set 2) and N90° (set 3) during the Apto–Cenomanian interval. Sills and dykes thin laterally away from their potential sand sources and thin laterally away from them. The vertical thickness variations of the dykes and wings are more complex, as thinning away from the sand sources is often compensated by thickening toward the palaeo–surface. Based on field observations and measurements, we characterized the 3D architecture of the sand injectites and showed that the injectites probably formed due to a forceful injection from an overpressured sand body sealed by low–permeability lithologies.
ISSN: 0191-8141

hal-01243488
https://hal.archives-ouvertes.fr/hal-01243488
DOI : 10.1016/j.jsg.2015.07.001