Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
Using first principle simulations we calculated the elasticity of chlorite. At a density ρ~ 2.60 g cm−3, the elastic constant tensor reveals significant elastic anisotropy: VP ~27%, VS1 ~56%, and VS2 ~43%. The shear anisotropy is exceptionally large for chlorite and enhances upon compression. Upon compression, the shear elastic constant component C44 and C55 decreases, whereas C66 shear component stiffens. The softening in C44 and C55 is reflected in shear modulus, G, and the shear wave velocity, VS. Our results on elastic anisotropy at conditions relevant to the mantle wedge indicates that a 10-20 km layer of hydrated peridotite with serpentine and chlorite could account for the observed shear polarization anisotropy and associated large delay times of 1-2 s observed in some subduction zone settings. In addition, chlorite could also explain the low VP/VS ratios that have been observed in recent high-resolution seismological studies.
ISSN: 0094-8276

hal-01053707
https://hal.archives-ouvertes.fr/hal-01053707
https://hal.archives-ouvertes.fr/hal-01053707/document
https://hal.archives-ouvertes.fr/hal-01053707/file/Mookherjee_et_al-2014-Geophysical_Research_Letters.pdf
DOI : 10.1002/2014GL059334

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
In this paper, we determine dislocation core structures and Peierls stresses of wadsleyite, a high-pressure mineral present in the Earth mantle. We use a Peierls-Nabarro model combined with a finite-element method in which we introduce two-dimensional generalized stacking fault energies. Several potential slip planes of wadsleyite are considered. The results show that dislocations in this mineral can exhibit complex dislocation cores with linear or non-collinear dissociation and even three-dimensional dislocation cores. The calculation of the Peierls stresses gives information on the potential activity of slip systems governing the plasticity of wadsleyite. Our study confirms experimental observations that 1/2 < 1 1 1 >{1 0 1} is the easiest slip system in this structure at high-pressure and that [1 0 0](0 1 0) is the second easiest. Both these easily slip systems have dislocations that dissociate into collinear partial dislocations. In contrast [0 1 0] dislocations with very large Burgers vector (11.2 angstrom) are stabilized by complex dissociations involving four partial dislocations.
ISSN: 1359-6454

hal-00475548
https://hal.archives-ouvertes.fr/hal-00475548
DOI : 10.1016/j.actamat.2009.10.047

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We investigated the response of the crystal structure, lattice parameters, and unit-cell volume of hydrous layered silicate phlogopite at conditions relevant to subduction zone settings. We have used first principles simulation based on density functional theory to calculate the equation of state and full elastic constant tensor. Based on the generalized gradient approximation, the full single crystal elastic constant tensor with monoclinic symmetry shows significant anisotropy with the compressional elastic constants: c11 = 181 GPa, c22 = 185 GPa, c33 = 62 GPa, the shear elastic constants c44 = 14 GPa, c55 = 20 GPa, c66 = 68 Ga, and c46 = −6 GPa; the off diagonal elastic constants c12 = 48 GPa, c13 = 12 GPa, c23 = 12 GPa, c15 = −16 GPa, c25 = −5 GPa and c35 = −1 GPa at zero pressure. The elastic anisotropy of phlogopite is larger than most of the layered hydrous phases relevant in the subduction zone conditions. The shear anisotropy, AVS for phlogopite is ∼77% at zero pressure condition and although it decreases upon compression it remains relatively high compared to other hydrous phases relevant in the subduction zone settings. We also note that the shear elastic constants for phlogopite are relatively low. Phlogopite also has a high isotropic bulk VP/VS ratio ∼2.0. However, the VP/VS ratio also exhibits significant anisotropy with values as low as 1.49. Thus, phlogopite bearing metasomatized mantle could readily explain unusual VP/VS ratio as observed from seismological studies from the mantle wedge regions of the subduction zone.
ISSN: 0031-9201

hal-01115670
https://hal.archives-ouvertes.fr/hal-01115670
DOI : 10.1016/j.pepi.2014.05.004

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
To better understand the microstructural evolution of a "serpentinized" mantle rock and the influence of various hydrous phases on the seismic properties of the mantle wedge, we have conducted the detailed microstructural analyses of a sample of tremolite-chlorite-antigorite schist collected from the Moses Rock dike (central part of the Colorado Plateau). We performed differential effective media (DEM) modelling to study the effect of three hydrous phases forming two-phase aggregates with olivine, considering the crystallographic preferred orientation (CPO) of each phase and the shape ratio of the hydrous phases. We have demonstrated that in a partially serpentinized peridotite, the olivine CPO characteristic of [100](010) dislocation glide is still preserved, and the high-temperature asthenospheric flow is preserved with a foliation normal to that of antigorite schist. The transformation of olivine into antigorite occurs predominantly (~ 75%) by the relationship (100)ol || (001)atg with [001]ol || [010]atg, with the (010)ol || (001)atg and [001]ol || [010]atg relationship observed in areas of weak antigorite CPO. Chlorite results from the phase transformation of olivine in a relatively static environment, as shown by the correlation between the olivine-chlorite CPOs with (100)ol || (100)ch, (010)ol || (001)ch and (001)ol || (010)ch. The fluid percolation that caused the localized metasomatism and partial hydration of the mantle occurred possibly along trans-lithospheric shear zones. The presence of chlorite induces the most important drop on the P-wave velocities and may help to explain some local low velocities in the fore-arc mantle wedges, but is unlikely to be of global importance due to its very high Vp/Vs ratio ~ 1.9. On the other hand, antigorite is the only phase that causes important modification on the propagation directions of P and S-waves, and the only phase to explain the polarization of the fastest shear waves parallel to the subduction trench.
ISSN: 0040-1951

hal-00858061
https://hal.archives-ouvertes.fr/hal-00858061
DOI : 10.1016/j.tecto.2013.03.022

Éditeur(s) : HAL CCSD Nature Publishing Group
Résumé : International audience
The variation of elastic- wave velocities as a function of the direction of propagation through the Earth's interior is a widely documented phenomenon called seismic anisotropy. The geometry and amount of seismic anisotropy is generally estimated by measuring shearwave splitting, which consists of determining the polarization direction of the fast shear- wave component and the time delay between the fast and slow, orthogonally polarized, waves. In subduction zones, the teleseismic fast shear- wave component is oriented generally parallel to the strike of the trench(1), although a few exceptions have been reported (Cascadia(2) and restricted areas of South America(3,4)). The interpretation of shear- wave splitting above subduction zones has been controversial and none of the inferred models seems to be sufficiently complete to explain the entire range of anisotropic patterns registered worldwide(1). Here we show that the amount and the geometry of seismic anisotropies measured in the forearc regions of subduction zones strongly depend on the preferred orientation of hydrated faults in the subducting oceanic plate. The anisotropy originates from the crystallographic preferred orientation of highly anisotropic hydrous minerals (serpentine and talc) formed along steeply dipping faults and from the larger- scale vertical layering consisting of dry and hydrated crust - mantle sections whose spacing is several times smaller than teleseismic wavelengths. Fault orientations and estimated delay times are consistent with the observed shear- wave splitting patterns in most subduction zones.
ISSN: 0028-0836

hal-00412016
https://hal.archives-ouvertes.fr/hal-00412016
DOI : 10.1038/nature07376

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
During the early years of the Iceland Deep Drilling Project (IDDP), development of three distinctive technological and scientific approaches were formalised and then carried out until 2010 within a European funded project called HiTI (high temperature instruments for supercritical geothermal reservoir characterisation and exploitation). These approaches were: (1) development of several downhole instruments allowing them to function up to 300 ◦C and 400 ◦C, (2) identification of two new Na/Li cation ratio geothermometric relationships valid at very high temperature, (3) tracer testing with high temperature tolerant organic isomers and finally and (4) basalt rock deformation and petrophysical properties laboratory investigations at high temperature and pressure conditions.
ISSN: 0375-6505

hal-00921127
https://hal-brgm.archives-ouvertes.fr/hal-00921127
DOI : 10.1016/j.geothermics.2013.07.008

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
A series of two-stage torsion experiments on Carrara marble were conducted to constrain the influence of known prior deformation on rheological response and microstructural evolution. Comparison with previous experimental data on Carrara marble flow and fabric evolution during single-stage torsion deformation experiments provided direct insights into the significance of initial deformation at various conditions. Our experiments were conducted at 727 degrees C temperature and 300 MPa confining pressure, while maintaining a constant strain rate of 3 x 10(-4) s(-1) on the periphery of the cylindrical samples. Under these conditions, the marble is known to deform in power-law (n = 6-10) ductile flow. All torsion experiments were performed with a Paterson type gas-medium testing machine equipped with a torsion actuator module.;Prior (D1) and subsequent (D2) deformation are accomplished by two torsion experiments in sequence on same sample segments. The effect of D1 strain history is investigated during D2 by applying counter-clockwise torsion to a sandwich sample consisting of three segments with different D1 rotation sense. D2 samples experienced continued, first and reversed shearing deformation in top, centre and bottom segments, respectively. D2 bulk strain was chosen equal to D1 strain in top and bottom segments.;D1 experiments followed the typical single-stage deformation behaviour of Carrara marble under the applied experimental conditions. Yielding was followed by strain hardening until a peak stress was reached at a shear strain around 1, after which work softening occurred. Weakening gradually evolved into a constant stress regime. During hardening, a shear microstructure and crystallographic preferred orientation (CPO) developed. Afterwards the volume fraction of smaller dynamic recrystallised grains increased continuously, resulting in a recrystallisation microstructure and CPO at shear strains of 5 and higher. The new D2 experiments displayed a strain variation between homogeneously deformed sample segments that increased with increasing D1 strain. The stress-strain behaviour of the D2 bulk sandwich samples showed less pronounced work-hardening and -softening when compared with single-stage deformation experiments. Furthermore, constant flow stress was attained at increasingly lower strain with increasing D1 strain. In most D2 segments, fabric development is equivalent to single-stage experiments at corresponding absolute strain. The fabrics differed markedly from those in single-stage experiments in the case of reversed two-stage deformation at moderate strain (D1 shear strain 1 and 2.6). Experiments show that grain shape by shearing of relict grains is defined by finite strain and thus affected by strain reversal. Recrystallisation is controlled by absolute strain and not influenced by strain reversal.
ISSN: 0040-1951

hal-00617686
https://hal.archives-ouvertes.fr/hal-00617686
DOI : 10.1016/j.tecto.2010.09.029

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
This special issue in honour of the late Olivier Jaoul brings together contributions from experimental and theoretical mineralogy, the area of most of Olivier's own work, focused for the most part on the Earth's mantle. The volume is divided into three sections; diffusion, deformation and seismic properties. New technological developments have often had a strong impact on research in this area, as again shown by Olivier's constant search to improve the resolution of the short diffusion profiles typical of major cations in mantle silicates. In the section on diffusion the impact of improved computer performance for modelling diffusion and point defect configurations on one hand, and high pressure experimental techniques on the other hand, highlight the continued development in this area. The section on deformation deals with wide range of subjects, including the deformation of olivine and quartz and the relation between deformation and diffusion, both subjects close to Olivier's personal interests. This illustrates the new possibilities to undertake deformation experiments at mantle pressures and temperatures, as well as improvement in high-fidelity viscoelastic measurements at high temperature. In the last section on seismic properties we discover theoretical developments on predicting properties near the Earth's surface and a new experimental application, which allows the determination of sound velocity at very high pressures with implications for the Earth's inner core.
ISSN: 0031-9201

hal-00475657
https://hal.archives-ouvertes.fr/hal-00475657
DOI : 10.1016/j.pepi.2008.09.009

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : A differential effective medium (DEM) model is used to predict elastic properties for a set of porous and anisotropic aggregates, comprised of mixtures of calcite and muscovite. The DEM takes into consideration an anisotropic background medium with triclinic or higher symmetry, in which inclusions of idealized ellipsoidal shape are added incrementally. In general, the calculated elastic properties of a solid that contains inclusions representing "dry" pores/cracks are strongly dependent on the orientation and aspect ratio of the inclusions. Aspect ratios of inclusions in the synthetic aggregates, which consist of air-filled pores, are estimated from anisotropy of magnetic susceptibility (AMS) of samples whose pore space has been impregnated with a colloidal ferrofluid. The AMS derived pore shape geometry is used as an input value for inclusions in the DEM. Modeling results are compared with laboratory determined elastic properties, measured with ultrasonic waves. Calculated shear wave velocities agree in general well with laboratory measured S wave velocities, whereas calculated P wave velocities are typically 0.5-1.1 km/s higher than measured values. Differences between calculated and measured P wave velocities are attributed mainly to incomplete and biased ferrofluid saturation of pores. Spherical pores are preferably filled during imbibition, in comparison to thin cracks, which leads to overprediction of the calculated P wave velocities. The amount of ferrofluid that fills the pore space is dependent on the ratio of calcite to muscovite and the load used for compaction during sample synthesis. The permeability decreases with increasing muscovite content and increasing compaction load. Incomplete saturation of samples with high-muscovite content is confirmed by X-ray microtomography density contrast imaging of dry and ferrofluid saturated specimens.
ISSN: 0148-0227

hal-00617717
https://hal.archives-ouvertes.fr/hal-00617717
DOI : 10.1029/2010JB007750

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
We investigated the deformation mechanisms and the seismic properties of 10 eclogite samples from different localities (Alps, Norway, Mali and eastern China) through the analysis of their microstructures and lattice-preferred orientations (LPO). These samples are representative of various types and intensity of deformation under eclogitic metamorphic conditions. Omphacite and garnet LPO were determined from electron backscatter diffraction (EBSD) technique. Garnet appears to be almost randomly oriented whereas omphacite develops strong LPO, characterized by the [001]-axes concentrated sub-parallel to the lineation, and the (010)-poles concentrated sub-perpendicular to the foliation. In order to analyze the deformation mechanisms that produced such omphacite LPO, we compare our observations to LPO simulated by viscoplastic self-consistent numerical models. A good fit to the measured LPO is obtained for models in which the dominant slip systems are 1/2h110i{11 ¯ 0}, [001] {110} and [001] (100). Dominant activation of these slip systems is in agreement with TEM studies of naturally deformed omphacite. Seismic properties of eclogite are calculated by combining the measured LPO and the single crystal elastic constants of omphacite and garnet. Although eclogite seismic anisotropies are very weak (less than 3% for both P-and S-wave), they are generally characterized by a maximum P-wave velocity sub-parallel to the lineation and by a minimum velocity approximately normal to foliation. The mean P-and S-wave velocities are high (respectively, 8.6 and 4.9 km/s). The S-wave anisotropy pattern displays complex relationships with the structural frame but the fast polarization plane generally tends to be parallel to the foliation. Calculated reflection coefficients show that an eclogite/crust interface is generally a good reflector (Rc > 0.1), whereas an eclogite body embedded in the upper mantle would be hardly detectable.
ISSN: 0040-1951

hal-01389715
http://hal.univ-reunion.fr/hal-01389715
http://hal.univ-reunion.fr/hal-01389715/document
http://hal.univ-reunion.fr/hal-01389715/file/Bascou_eclo-sismo_tphy2001_hal.pdf
DOI : 10.1016/S0040-1951(01)00156-1

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
TEM Study of Heavitree quartzite deformed at high temperatures and a pressure of 1.5 GPa with three different preparations: water-added, vacuum dried, and sodium doped show a wide range of dislocation microstructure. The vacuum dried sample has a very heterogeneous dislocation distribution varying from almost no dislocations to very high densities. Dislocation nucleation occurs by cross-slip mechanisms, such as Frank-Read sources and Orowan loops around hard inclusions. Shear bands develop in the basal plane composed of two closely spaced shear planes. Dislocations have straight segments and they are aligned along directions of dense packing, suggesting strong Peierls stress control due to the crystal structure. No voids, bubbles or dislocation walls where observed in the vacuum dried sample. The sodium-doped sample had a homogeneous high dislocation density. The water-added sample has a significantly lower, relatively uniform dislocation density. Bubbles associated with dislocations are seen in every grain. Dislocations were either present in loops around bubbles or as straight dislocations with small bubbles spaced along the dislocation line. Some of the long straight dislocations are aligned parallel to the c-axis. Sub-grains where very frequent, sometimes form cells of about 2 p,m in diameter with straight edges. Analysis of dislocations show 1/3 < a > and [c] dislocations in sub-grain walls and free 1/3 < a > dislocations on prism planes. There is clear evidence for dislocation climb with sub-grain walls, dislocation cells, dislocation junctions and dislocation debris of small loops. The major difference between vacuum dried and water-added samples are the homogeneity of the microstructure and evidence for climb in the water-added sample. Glide is clearly difficult, with a high Peierls stress in the vacuum dried sample as shown by areas of very low and very high dislocation density and the crystallographic control of dislocation line direction. The sodium-doped sample indicates that nucleation was easy by the high homogenous dislocation density, but no climb recovery has taken place. The density is high and the dislocations are strongly interacting causing tangles; no evidence for crystallographic control can be observed at these levels of strain. The activation energy for creep in Heavitree quartzite decreases with inferred water content of the specimens form 185 kJ mol(-1) for vacuum dried to 151 for 0.4 wt% water-added samples. Analysis of diffusion data for oxygen under hydrothermal conditions and inferred diffusion data for the hydrogarnet defect and dislocation velocity suggests activation energies for these processes are similar to the activation energy for the dislocation creep of Heavitree quartzite and other quartz aggregates. For data from the previously published experiments with the highest stress resolution there is a correlation between the A pre-factor in the power law creep equation and the activation energy for creep. It is speculated that the correlation may be due to variable hydrogarnet defect concentrations.
ISSN: 0031-9201

hal-00413112
https://hal.archives-ouvertes.fr/hal-00413112
DOI : 10.1016/j.pepi.2008.07.009

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
B-type olivine fabrics are pervasive within highly depleted dunites of the small-sized Imono peridotite body located within the subduction-type Sanbagawa metamorphic belt of the southwest Japan arc. The dunites contain various microstructures, ranging from porphyroclastic to fine-grained intensely sheared textures. The Mg/(Mg+Fe) atomic ratios (Fo number) of olivine within these dunites are consistently around 0.9, as are the Cr/(Cr+Al) atomic ratios (Cr number) of chromian spinel, suggesting their evolution from a highly depleted magma (boninite). These data provide strong thermal constraints on the formation of the highly depleted dunites,as their formation requires hot, hydrous, shallow mantle (> 1250 degrees C at < 30 km depth) in the mantle wedge. Because the Sanbagawa metamorphic belt finally entrained these peridotites during progressive retrogression, B-type olivine fabrics probably developed in the fore-arc side of the subduction zone, above or along the subducting slab, possibly in association with dehydration fluids derived from the slab. The previously documented small magnitude of S-wave splitting can be explained by the seismic properties of B-type peridotites within an anisotropic layer of approximately several kilometers in thickness, oriented by flow parallel to the subducting slab, under maximum temperatures of 880-1030 degrees C depending on the flow stress. These findings indicate that such a B-type layer could constitute a dominant source of seismic S- and P-wave anisotropy in mantle wedge regions. (c) 2008 Elsevier B.V. All rights reserved.
ISSN: 0012-821X

hal-00412594
https://hal.archives-ouvertes.fr/hal-00412594
DOI : 10.1016/j.epsl.2008.06.014

Éditeur(s) : HAL CCSD American Geophysical Union (AGU)
Résumé : International audience
We make this reply to Philippe Oliver's comments on the deformation of the Mesozoic cover of the northern Agly massif.
ISSN: 0278-7407

hal-00903419
https://hal.archives-ouvertes.fr/hal-00903419
https://hal.archives-ouvertes.fr/hal-00903419/document
https://hal.archives-ouvertes.fr/hal-00903419/file/Vauchez_et_al-2013-Tectonics.pdf
DOI : 10.1002/tect.20061

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
Upon subduction, the oceanic crust transforms to blueschists and eclogites, with seismic properties that gradually become similar to those of the surrounding mantle. In order to evaluate the anisotropy of blueschists and glaucophane-bearing eclogites, the elastic constants of glaucophane single-crystal plates from the Sesia-Lanzo Zone (Aosta Valley, Western Alps) were measured using Brillouin spectroscopy at ambient conditions. The mean P- and S-wave velocities are 7.8 and 4.6 km s−1 respectively, and the anisotropy is high (38.1% (AVP) and 27.3% (AVS)). Glaucophane develops strong LPO, characterized by the [001]-axes concentrated sub-parallel to the lineation, and the {110} poles concentrated sub-perpendicular to the foliation in both blueschist and eclogite rocks. The measured LPO is in good agreement with viscoplastic selfconsistent numerical models. Seismic properties of glaucophane-bearing blueschist and eclogite are calculated by combining measured LPO and the single-crystal elastic moduli of glaucophane with the other main mineral constituents of the rock: mostly epidote for blueschist, and omphacite and garnet for eclogite. Blueschists present stronger anisotropies (AVP=16.1% and AVS=10.3%) than eclogites (AVP=2.9% and AVS=1.7%). The shear-wave splitting and resulting delay times for a 7-km thick layer of eclogite or blueschist are low for the eclogite (b0.03 s), but signi!cant for blueschist (0.16 s). Application to the subducted oceanic crust yields a decrease of velocity contrast with the surrounding mantle and of anisotropy at depth depending on the temperature of the slab. The details of the velocity variations in subducted oceanic crust are dif!cult to reconcile with the blueschist-eclogite transition as probed by exhumed metamorphic rocks and may require additional phases such as lawsonite or chemical variations such as oxidation state.
ISSN: 0040-1951

hal-00564518
https://hal.archives-ouvertes.fr/hal-00564518
DOI : 10.1016/j.tecto.2010.09.011

Éditeur(s) : HAL CCSD Elsevier
Résumé : We studied the evolution of the microstructure of ice-Ih during static recrystallization by stepwise annealing experiments. We alternated thermal annealing and electron backscatter diffraction (EBSD) analyses on polycrystalline columnar ice pre-deformed in uniaxial compression at temperature of −7 °C to macroscopic strains of 3.0–5.2. Annealing experiments were carried out at −5 °C and −2 °C up to a maximum of 3.25 days, typically in 5–6 steps. EBSD crystal orientation maps obtained after each annealing step permit the description of microstructural changes. Decrease in average intragranular misorientation at the sample scale and modification of the misorientation across subgrain boundaries provide evidence for recovery from the earliest stages of annealing. This initial evolution is similar for all studied samples irrespective of their initial strain or annealing temperature. After an incubation period ≥1.5 h, recovery is accompanied by recrystallization (nucleation and grain boundary migration). Grain growth proceeds at the expense of domains with high intragranular misorientations, consuming first the most misorientated parts of primary grains. Grain growth kinetics fits the parabolic growth law with grain growth exponents in the range of 2.4–4.0. Deformation-induced tilt boundaries and kink bands may slow down grain boundary migration. They are stable features during early stages of static recrystallization, only erased by normal growth, which starts after >24 h of annealing.
ISSN: 0191-8141

hal-01685644
https://hal.archives-ouvertes.fr/hal-01685644
DOI : 10.1016/j.jsg.2017.05.001

Éditeur(s) : HAL CCSD Society of Exploration Geophysicists
Résumé : low frequency seismic attenuation
International audience
The study of wave attenuation in partially saturated porous rocks over a broad frequency range provides valuable information about the fluid system of reservoirs, which are inherently multiple phase fluid system. Until now, not much laboratory data have been collected in the seismically relevant low frequency range and existing literature data on partially saturated rock are very limited. The main goal of our work is to experimentally measure the bulk seismic attenuation on fluid-bearing rocks, using natural rock samples in an efficient way at in situ conditions. We are currently fine-tuning our attenuation measurement prototype. Preliminary bench-top results are promising and show consistency with reported experimental data with dry, partially and fully fluid saturated rocks. Measurements with the machine are accurate and precise.
ISSN: 1052-3812

hal-00564863
https://hal.archives-ouvertes.fr/hal-00564863
DOI : 10.1190/1.3513397

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
We determine the elasticity of FeSiO3 perovskite for various spin configurations using density-functional theory calculations. The elastic moduli and the bulk seismic wave velocities are weakly affected by the spin transition. However we show that the intrinsic differences in seismic anisotropy between the high-spin and low-spin phases of Fe-bearing perovskite coupled with lattice preferred orientation that can develop due and during the convection may lead to distinct seismic signatures between the top and the bottom of the lower mantle. These signatures should be detectable in observations and they need to be taken into account in tomographic studies of the Earth's lower mantle.
ISSN: 0094-8276

hal-00512662
https://hal.archives-ouvertes.fr/hal-00512662
DOI : 10.1029/2010GL043320

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
The brittle to ductile transition (BDT) in rocks may strongly influence their transport properties (i.e., permeability, porosity topology ...) and the maximum depth and temperature where hydrothermal fluids may circulate. To examine this transition in the context of Icelandic crust, we conducted deformation experiments on a glassy basalt (GB) and a glass-free basalt (GFB) under oceanic crust conditions. Mechanical and micro-structural observations at a constant strain rate of 10(-5) s(-1) and at confining pressure of 100-300 MPa indicate that the rocks are brittle and dilatant up to 700-800 degrees C. At higher temperatures and effective pressures the deformation mode becomes macroscopically ductile, i.e., deformation is distributed throughout the sample and no localized shear rupture plane develops. The presence of glass is a key component reducing the sample strength and lowering the pressure of the BDT. In the brittle field, strength is consistent with a Mohr-Coulomb failure criterion with an internal coefficient of friction of 0.42 for both samples. In the ductile field, strength is strain rate-and temperature-dependent and both samples were characterized by the same stress exponent in the range 3 < n < 4.2 but by very different activation energy Q(GB) = 59 +/- 15 KJ/mol and Q(GFB) = 456 +/- 4 KJ/mol. Extrapolation of these results to the Iceland oceanic crust conditions predicts a BDT at similar to 100 degrees C for a glassy basalt, whereas the BDT might occur in non-glassy basalts at deeper conditions, i.e., temperatures higher than 550 +/- 100 degrees C, in agreement with the Icelandic seismogenic zone.
ISSN: 0148-0227

hal-00760905
https://hal.archives-ouvertes.fr/hal-00760905
DOI : 10.1029/2011JB008884

Éditeur(s) : HAL CCSD Elsevier
Résumé : International audience
The nucleation and growth processes of spherulitic alkali feldspar have been investigated in this study through X-ray microtomography and electron backscatter diffraction (EBSD) data. Here we present the first data on Shape Preferred Orientation (SPO) and Crystal Preferred Orientation (CPO) of alkali feldspar within spherulites. The analysis of synchrotron X-ray microtomography and EBSD datasets allowed us to study the morphometric characteristics of spherulites in trachytic melts in quantitative fashion, highlighting the three-dimensional shape, preferred orientation, branching of lamellae and crystal twinning, providing insights about the nucleation mechanism involved in the crystallization of the spherulites. The nucleation starts with a heterogeneous nucleus (pre-existing crystal or bubble) and subsequently it evolves forming “bow tie” morphologies, reaching radially spherulitic shapes in few hours. Since each lamella within spherulite is also twinned, these synthetic spherulites cannot be considered as single nuclei but crystal aggregates originated by heterogeneous nucleation. A twin boundary may have a lower energy than general crystal–crystal boundaries and many of the twinned grains show evidence of strong local bending which, combined with twin plane, creates local sites for heterogeneous nucleation.This study shows that the growth rates of the lamellae (10− 6–10− 7 cm/s) in spherulites are either similar or slightly higher than that for single crystals by up to one order of magnitude. Furthermore, the highest volumetric growth rates (10− 11–10− 12 cm3/s) show that the alkali feldspar within spherulites can grow fast reaching a volumetric size of ~ 10 μm3 in 1 s.
ISSN: 0024-4937

hal-01172356
https://hal.archives-ouvertes.fr/hal-01172356
DOI : 10.1016/j.lithos.2014.12.003

Éditeur(s) : HAL CCSD American Geophysical Union
Résumé : International audience
Progress in seismic methodology and ambitious large-scale seismic projects are enabling high-resolution imaging of the continental crust. The ability to constrain interpretations of crustal seismic data is based on laboratory measurements on rock samples and calculations of seismic properties. Seismic velocity calculations and their directional dependence are based on the rock microfabric, which consists of mineral aggregate properties including crystallographic preferred orientation (CPO), grain shape and distribution, grain boundary distribution, and misorientation within grains. Single-mineral elastic constants and density are crucial for predicting seismic velocities, preferably at conditions that span the crust. However, high-temperature and high-pressure elastic constant data are not as common as those determined at standard temperature and pressure (STP; atmospheric conditions). Continental crust has a very diverse mineral composition; however, a select number of minerals appear to dominate seismic properties because of their high-volume fraction contribution. Calculations of microfabric-based seismic properties and anisotropy are performed with averaging methods that in their simplest form takes into account the CPO and modal mineral composition, and corresponding single crystal elastic constants. More complex methods can take into account other microstructural characteristics, including the grain shape and distribution of mineral grains and cracks and pores. Dynamic or active wave propagation schemes have recently been developed, which offer a complementary method to existing static averaging methods generally based on the use of the Christoffel equation. A challenge for the geophysics and rock physics communities is the separation of intrinsic factors affecting seismic anisotropy, due to properties of crystals within a rock and apparent sources due to extrinsic factors like cracks, fractures, and alteration. This is of particular importance when trying to deduce crustal composition and the state of deformation from seismic parameters.
ISSN: 8755-1209

Droits : info:eu-repo/semantics/OpenAccess
hal-01685568
https://hal.archives-ouvertes.fr/hal-01685568
https://hal.archives-ouvertes.fr/hal-01685568/document
https://hal.archives-ouvertes.fr/hal-01685568/file/Almqvist_et_al-2017-Reviewssur Geophysics.pdf
DOI : 10.1002/2016RG000552